#------------------------------------------------------------------------------
#$Date: 2016-06-18 12:00:42 +0300 (Sat, 18 Jun 2016) $
#$Revision: 183730 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/54/7055433.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7055433
loop_
_publ_author_name
'Fan, Yan'
'Hu, Dong-Cheng'
'Yao, Xiao-Qiang'
'Yang, Yun-Xia'
'Liu, Jia-Cheng'
_publ_section_title
;
 Four cobalt(ii) complexes based on a new tricarboxylate with a
 naphthalene ring and different N-containing ligands: synthesis, crystal
 structures and magnetic properties
;
_journal_issue                   6
_journal_name_full               'New J. Chem.'
_journal_page_first              5010
_journal_paper_doi               10.1039/C6NJ00065G
_journal_volume                  40
_journal_year                    2016
_chemical_formula_sum            'C37 H26 Co N4 O9'
_chemical_formula_weight         729.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-06-13 deposited with the CCDC.
2016-03-23 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 94.838(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.136(2)
_cell_length_b                   9.3687(13)
_cell_length_c                   21.052(3)
_cell_measurement_reflns_used    6420
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.54
_cell_measurement_theta_min      2.38
_cell_volume                     3171.2(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0752
_diffrn_reflns_av_sigmaI/netI    0.0811
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            16215
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    0.608
_exptl_absorpt_correction_T_max  0.8932
_exptl_absorpt_correction_T_min  0.8628
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.528
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1500
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.564
_refine_diff_density_min         -0.580
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     461
_refine_ls_number_reflns         5470
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0758
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0867P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1425
_refine_ls_wR_factor_ref         0.1564
_reflns_number_gt                4010
_reflns_number_total             5470
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6nj00065g2.cif
_cod_data_source_block           mo_20141218a19_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7055431--7055434.cif.
;
_cod_original_cell_volume        3171.1(7)
_cod_original_sg_symbol_H-M      'P2(1)/c  '
_cod_database_code               7055433
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.0957(3) 0.5519(5) 0.93408(19) 0.0487(10) Uani 1 1 d .
C2 C -0.0093(3) 0.5975(4) 0.92565(19) 0.0460(10) Uani 1 1 d .
C3 C 0.0281(2) 0.7069(5) 0.9607(2) 0.0490(10) Uani 1 1 d .
H3 H -0.0008 0.7522 0.9913 0.059 Uiso 1 1 calc R
C4 C 0.1099(2) 0.7520(4) 0.95111(18) 0.0433(9) Uani 1 1 d .
C5 C 0.1527(2) 0.6842(4) 0.90432(19) 0.0432(9) Uani 1 1 d .
C6 C 0.1127(3) 0.5693(4) 0.8694(2) 0.0522(11) Uani 1 1 d .
H6 H 0.1404 0.5220 0.8387 0.063 Uiso 1 1 calc R
C7 C 0.0344(3) 0.5282(5) 0.8805(2) 0.0534(11) Uani 1 1 d .
H7 H 0.0097 0.4523 0.8576 0.064 Uiso 1 1 calc R
C8 C 0.1494(3) 0.8625(5) 0.9867(2) 0.0526(11) Uani 1 1 d .
H8 H 0.1216 0.9081 1.0179 0.063 Uiso 1 1 calc R
C9 C 0.2282(3) 0.9045(4) 0.9764(2) 0.0501(10) Uani 1 1 d .
H9 H 0.2540 0.9771 1.0009 0.060 Uiso 1 1 calc R
C10 C 0.2701(2) 0.8378(4) 0.92893(19) 0.0408(9) Uani 1 1 d .
C11 C 0.2348(2) 0.7287(4) 0.8939(2) 0.0460(10) Uani 1 1 d .
H11 H 0.2640 0.6835 0.8634 0.055 Uiso 1 1 calc R
C12 C 0.3938(2) 0.8423(4) 0.87413(18) 0.0387(9) Uani 1 1 d .
C13 C 0.3734(3) 0.8883(4) 0.8123(2) 0.0503(11) Uani 1 1 d .
H13 H 0.3259 0.9430 0.8026 0.060 Uiso 1 1 calc R
C14 C 0.4238(3) 0.8523(5) 0.7658(2) 0.0521(11) Uani 1 1 d .
H14 H 0.4098 0.8810 0.7239 0.063 Uiso 1 1 calc R
C15 C 0.4951(3) 0.7741(4) 0.78027(18) 0.0437(9) Uani 1 1 d .
H15 H 0.5296 0.7526 0.7484 0.052 Uiso 1 1 calc R
C16 C 0.5158(2) 0.7269(4) 0.84209(17) 0.0335(8) Uani 1 1 d .
C17 C 0.4636(2) 0.7597(3) 0.88959(17) 0.0325(8) Uani 1 1 d .
C18 C 0.5941(2) 0.6422(4) 0.85784(18) 0.0371(9) Uani 1 1 d .
C19 C 0.1622(2) 0.1852(4) 0.87197(19) 0.0450(10) Uani 1 1 d .
H19 H 0.1744 0.2298 0.9111 0.054 Uiso 1 1 calc R
C20 C 0.0898(2) 0.1063(5) 0.8601(2) 0.0505(11) Uani 1 1 d .
H20 H 0.0529 0.0970 0.8915 0.061 Uiso 1 1 calc R
C21 C 0.0727(2) 0.0421(4) 0.8020(2) 0.0411(9) Uani 1 1 d .
C22 C 0.1265(2) 0.0512(4) 0.75527(19) 0.0392(9) Uani 1 1 d .
H22 H 0.1146 0.0050 0.7165 0.047 Uiso 1 1 calc R
C23 C 0.1986(2) 0.1297(4) 0.76633(18) 0.0364(8) Uani 1 1 d .
H23 H 0.2354 0.1381 0.7348 0.044 Uiso 1 1 calc R
C24 C 0.2156(2) 0.1959(4) 0.82472(18) 0.0349(8) Uani 1 1 d .
C25 C 0.3086(2) 0.3938(4) 0.79654(18) 0.0401(9) Uani 1 1 d .
H25 H 0.2770 0.4272 0.7606 0.048 Uiso 1 1 calc R
C26 C 0.3816(2) 0.4458(4) 0.82100(17) 0.0389(9) Uani 1 1 d .
H26 H 0.4093 0.5229 0.8048 0.047 Uiso 1 1 calc R
C27 C 0.3520(2) 0.2695(4) 0.88019(18) 0.0371(9) Uani 1 1 d .
H27 H 0.3545 0.2008 0.9121 0.044 Uiso 1 1 calc R
C28 C -0.1004(2) 0.1414(4) 0.8004(2) 0.0527(11) Uani 1 1 d .
H28 H -0.0682 0.2086 0.7812 0.063 Uiso 1 1 calc R
C29 C -0.0719(2) 0.0042(4) 0.8108(2) 0.0425(9) Uani 1 1 d .
C30 C -0.1176(2) -0.0943(4) 0.84081(19) 0.0419(9) Uani 1 1 d .
H30 H -0.0971 -0.1860 0.8482 0.050 Uiso 1 1 calc R
C31 C 0.8220(2) 0.1775(4) 0.8193(2) 0.0473(10) Uani 1 1 d .
H31 H 0.8011 0.2689 0.8113 0.057 Uiso 1 1 calc R
C32 C 0.7766(2) 0.0810(4) 0.84909(17) 0.0343(8) Uani 1 1 d .
C33 C 0.8062(2) -0.0572(4) 0.85997(19) 0.0409(9) Uani 1 1 d .
H33 H 0.7746 -0.1237 0.8801 0.049 Uiso 1 1 calc R
C34 C 0.6312(2) 0.0233(4) 0.8704(3) 0.0603(13) Uani 1 1 d .
H34 H 0.6305 -0.0725 0.8588 0.072 Uiso 1 1 calc R
C35 C 0.5691(3) 0.0973(4) 0.8928(3) 0.0622(14) Uani 1 1 d .
H35 H 0.5174 0.0597 0.9002 0.075 Uiso 1 1 calc R
C36 C 0.6697(2) 0.2436(4) 0.88808(18) 0.0360(8) Uani 1 1 d .
H36 H 0.7021 0.3258 0.8907 0.043 Uiso 1 1 calc R
C37 C 0.5193(2) 0.2910(3) 1.04292(17) 0.0309(8) Uani 1 1 d .
Co1 Co 0.51586(3) 0.39665(5) 0.93238(2) 0.02926(18) Uani 1 1 d .
N1 N 0.28930(17) 0.2817(3) 0.83463(14) 0.0358(7) Uani 1 1 d .
N2 N 0.40957(17) 0.3669(3) 0.87414(14) 0.0346(7) Uani 1 1 d .
N3 N 0.69556(18) 0.1165(3) 0.86804(15) 0.0371(7) Uani 1 1 d .
N4 N 0.59245(17) 0.2366(3) 0.90348(15) 0.0363(7) Uani 1 1 d .
O1 O -0.13063(19) 0.6241(4) 0.97847(18) 0.0685(9) Uani 1 1 d .
H1 H -0.1792 0.5991 0.9792 0.103 Uiso 1 1 calc R
O2 O -0.1313(2) 0.4611(4) 0.90238(16) 0.0710(9) Uani 1 1 d .
O3 O 0.34875(15) 0.8888(3) 0.92384(14) 0.0451(7) Uani 1 1 d .
O4 O 0.59190(15) 0.5438(3) 0.89927(13) 0.0403(6) Uani 1 1 d .
O5 O 0.65588(18) 0.6747(3) 0.83170(16) 0.0632(9) Uani 1 1 d .
O6 O 0.47139(15) 0.2278(3) 1.00409(12) 0.0402(6) Uani 1 1 d .
O7 O 0.55706(15) 0.4051(2) 1.02771(11) 0.0349(6) Uani 1 1 d .
O8 O 0.00240(15) -0.0417(3) 0.78872(15) 0.0546(8) Uani 1 1 d .
O9 O 0.71719(19) 0.9431(4) 0.49877(16) 0.0718(9) Uani 1 1 d .
H9C H 0.7071 1.0121 0.5304 0.086 Uiso 1 1 d R
H9A H 0.6781 0.9337 0.4588 0.086 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 123.0(4) . .
O2 C1 C2 123.4(4) . .
O1 C1 C2 113.6(4) . .
C3 C2 C7 119.3(4) . .
C3 C2 C1 121.8(4) . .
C7 C2 C1 118.9(4) . .
C2 C3 C4 121.3(4) . .
C2 C3 H3 119.3 . .
C4 C3 H3 119.3 . .
C8 C4 C5 118.8(4) . .
C8 C4 C3 122.2(4) . .
C5 C4 C3 119.0(4) . .
C4 C5 C11 119.7(4) . .
C4 C5 C6 118.4(4) . .
C11 C5 C6 121.9(4) . .
C7 C6 C5 120.8(4) . .
C7 C6 H6 119.6 . .
C5 C6 H6 119.6 . .
C6 C7 C2 121.2(4) . .
C6 C7 H7 119.4 . .
C2 C7 H7 119.4 . .
C9 C8 C4 121.1(4) . .
C9 C8 H8 119.4 . .
C4 C8 H8 119.4 . .
C8 C9 C10 119.8(4) . .
C8 C9 H9 120.1 . .
C10 C9 H9 120.1 . .
C11 C10 O3 124.7(4) . .
C11 C10 C9 121.3(4) . .
O3 C10 C9 114.0(3) . .
C10 C11 C5 119.4(4) . .
C10 C11 H11 120.3 . .
C5 C11 H11 120.3 . .
C17 C12 C13 121.4(4) . .
C17 C12 O3 117.7(3) . .
C13 C12 O3 120.7(3) . .
C14 C13 C12 119.2(4) . .
C14 C13 H13 120.4 . .
C12 C13 H13 120.4 . .
C13 C14 C15 120.5(4) . .
C13 C14 H14 119.7 . .
C15 C14 H14 119.7 . .
C14 C15 C16 120.6(4) . .
C14 C15 H15 119.7 . .
C16 C15 H15 119.7 . .
C15 C16 C17 119.3(3) . .
C15 C16 C18 120.4(3) . .
C17 C16 C18 120.3(3) . .
C12 C17 C16 118.9(3) . .
C12 C17 C37 118.7(3) . 3_667
C16 C17 C37 122.3(3) . 3_667
O5 C18 O4 124.2(4) . .
O5 C18 C16 118.2(3) . .
O4 C18 C16 117.5(3) . .
C24 C19 C20 118.6(4) . .
C24 C19 H19 120.7 . .
C20 C19 H19 120.7 . .
C21 C20 C19 119.8(4) . .
C21 C20 H20 120.1 . .
C19 C20 H20 120.1 . .
C20 C21 C22 121.6(3) . .
C20 C21 O8 121.8(4) . .
C22 C21 O8 116.5(3) . .
C21 C22 C23 119.2(4) . .
C21 C22 H22 120.4 . .
C23 C22 H22 120.4 . .
C22 C23 C24 119.4(4) . .
C22 C23 H23 120.3 . .
C24 C23 H23 120.3 . .
C19 C24 C23 121.4(3) . .
C19 C24 N1 119.9(3) . .
C23 C24 N1 118.7(3) . .
C26 C25 N1 106.8(3) . .
C26 C25 H25 126.6 . .
N1 C25 H25 126.6 . .
C25 C26 N2 109.5(3) . .
C25 C26 H26 125.3 . .
N2 C26 H26 125.3 . .
N2 C27 N1 111.6(3) . .
N2 C27 H27 124.2 . .
N1 C27 H27 124.2 . .
C29 C28 C31 118.7(4) . 1_455
C29 C28 H28 120.7 . .
C31 C28 H28 120.7 1_455 .
C30 C29 C28 121.1(4) . .
C30 C29 O8 117.4(3) . .
C28 C29 O8 121.5(4) . .
C33 C30 C29 119.8(3) 1_455 .
C33 C30 H30 120.1 1_455 .
C29 C30 H30 120.1 . .
C32 C31 C28 120.5(4) . 1_655
C32 C31 H31 119.7 . .
C28 C31 H31 119.7 1_655 .
C31 C32 C33 120.4(3) . .
C31 C32 N3 121.0(3) . .
C33 C32 N3 118.5(3) . .
C30 C33 C32 119.5(4) 1_655 .
C30 C33 H33 120.3 1_655 .
C32 C33 H33 120.3 . .
C35 C34 N3 106.1(3) . .
C35 C34 H34 126.9 . .
N3 C34 H34 126.9 . .
C34 C35 N4 110.3(3) . .
C34 C35 H35 124.8 . .
N4 C35 H35 124.8 . .
N4 C36 N3 111.1(3) . .
N4 C36 H36 124.5 . .
N3 C36 H36 124.5 . .
O6 C37 O7 121.4(3) . .
O6 C37 C17 122.2(3) . 3_667
O7 C37 C17 116.5(3) . 3_667
O4 Co1 N2 113.08(11) . .
O4 Co1 O7 98.92(10) . .
N2 Co1 O7 140.84(11) . .
O4 Co1 N4 89.87(11) . .
N2 Co1 N4 102.54(12) . .
O7 Co1 N4 99.37(11) . .
O4 Co1 O6 156.48(10) . .
N2 Co1 O6 90.43(10) . .
O7 Co1 O6 59.30(9) . .
N4 Co1 O6 85.59(11) . .
O4 Co1 O7 85.52(9) . 3_667
N2 Co1 O7 84.47(10) . 3_667
O7 Co1 O7 75.86(10) . 3_667
N4 Co1 O7 172.73(10) . 3_667
O6 Co1 O7 96.41(9) . 3_667
C27 N1 C25 106.8(3) . .
C27 N1 C24 128.5(3) . .
C25 N1 C24 124.7(3) . .
C27 N2 C26 105.3(3) . .
C27 N2 Co1 126.9(2) . .
C26 N2 Co1 127.8(2) . .
C36 N3 C34 107.4(3) . .
C36 N3 C32 127.4(3) . .
C34 N3 C32 125.2(3) . .
C36 N4 C35 105.1(3) . .
C36 N4 Co1 129.7(2) . .
C35 N4 Co1 125.1(3) . .
C1 O1 H1 109.5 . .
C10 O3 C12 119.7(3) . .
C18 O4 Co1 142.0(2) . .
C37 O6 Co1 83.9(2) . .
C37 O7 Co1 95.1(2) . .
C37 O7 Co1 107.5(2) . 3_667
Co1 O7 Co1 104.14(10) . 3_667
C21 O8 C29 118.1(3) . .
H9C O9 H9A 120.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.198(5) .
C1 O1 1.318(5) .
C1 C2 1.482(6) .
C2 C3 1.372(6) .
C2 C7 1.391(6) .
C3 C4 1.416(6) .
C3 H3 0.9300 .
C4 C8 1.400(6) .
C4 C5 1.403(6) .
C5 C11 1.424(6) .
C5 C6 1.427(6) .
C6 C7 1.359(6) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.366(6) .
C8 H8 0.9300 .
C9 C10 1.400(6) .
C9 H9 0.9300 .
C10 C11 1.357(5) .
C10 O3 1.369(4) .
C11 H11 0.9300 .
C12 C17 1.382(5) .
C12 C13 1.383(6) .
C12 O3 1.394(5) .
C13 C14 1.368(6) .
C13 H13 0.9300 .
C14 C15 1.376(6) .
C14 H14 0.9300 .
C15 C16 1.388(5) .
C15 H15 0.9300 .
C16 C17 1.395(5) .
C16 C18 1.504(5) .
C17 C37 1.501(5) 3_667
C18 O5 1.217(4) .
C18 O4 1.272(4) .
C19 C24 1.373(5) .
C19 C20 1.388(5) .
C19 H19 0.9300 .
C20 C21 1.369(6) .
C20 H20 0.9300 .
C21 C22 1.369(5) .
C21 O8 1.389(4) .
C22 C23 1.379(5) .
C22 H22 0.9300 .
C23 C24 1.383(5) .
C23 H23 0.9300 .
C24 N1 1.436(4) .
C25 C26 1.337(5) .
C25 N1 1.373(5) .
C25 H25 0.9300 .
C26 N2 1.384(5) .
C26 H26 0.9300 .
C27 N2 1.316(4) .
C27 N1 1.339(4) .
C27 H27 0.9300 .
C28 C29 1.376(6) .
C28 C31 1.387(6) 1_455
C28 H28 0.9300 .
C29 C30 1.370(5) .
C29 O8 1.389(4) .
C30 C33 1.370(5) 1_455
C30 H30 0.9300 .
C31 C32 1.351(5) .
C31 C28 1.387(6) 1_655
C31 H31 0.9300 .
C32 C33 1.392(5) .
C32 N3 1.438(5) .
C33 C30 1.370(5) 1_655
C33 H33 0.9300 .
C34 C35 1.337(6) .
C34 N3 1.361(5) .
C34 H34 0.9300 .
C35 N4 1.372(5) .
C35 H35 0.9300 .
C36 N4 1.316(5) .
C36 N3 1.341(4) .
C36 H36 0.9300 .
C37 O6 1.229(4) .
C37 O7 1.285(4) .
C37 C17 1.501(5) 3_667
Co1 O4 2.009(2) .
Co1 N2 2.041(3) .
Co1 O7 2.062(2) .
Co1 N4 2.067(3) .
Co1 O6 2.341(3) .
Co1 O7 2.389(2) 3_667
O1 H1 0.8200 .
O7 Co1 2.389(2) 3_667
O9 H9C 0.9524 .
O9 H9A 1.0115 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 C3 176.7(4) . .
O1 C1 C2 C3 -1.2(6) . .
O2 C1 C2 C7 -2.7(6) . .
O1 C1 C2 C7 179.4(4) . .
C7 C2 C3 C4 1.0(6) . .
C1 C2 C3 C4 -178.3(4) . .
C2 C3 C4 C8 -179.4(4) . .
C2 C3 C4 C5 0.7(6) . .
C8 C4 C5 C11 -0.2(6) . .
C3 C4 C5 C11 179.7(4) . .
C8 C4 C5 C6 178.4(4) . .
C3 C4 C5 C6 -1.7(6) . .
C4 C5 C6 C7 1.0(6) . .
C11 C5 C6 C7 179.6(4) . .
C5 C6 C7 C2 0.7(7) . .
C3 C2 C7 C6 -1.8(6) . .
C1 C2 C7 C6 177.6(4) . .
C5 C4 C8 C9 0.1(6) . .
C3 C4 C8 C9 -179.8(4) . .
C4 C8 C9 C10 0.9(7) . .
C8 C9 C10 C11 -2.0(6) . .
C8 C9 C10 O3 -179.5(4) . .
O3 C10 C11 C5 179.1(3) . .
C9 C10 C11 C5 1.9(6) . .
C4 C5 C11 C10 -0.8(6) . .
C6 C5 C11 C10 -179.4(4) . .
C17 C12 C13 C14 -0.7(6) . .
O3 C12 C13 C14 173.5(4) . .
C12 C13 C14 C15 -1.4(6) . .
C13 C14 C15 C16 1.8(6) . .
C14 C15 C16 C17 0.0(5) . .
C14 C15 C16 C18 -179.6(3) . .
C13 C12 C17 C16 2.4(5) . .
O3 C12 C17 C16 -171.9(3) . .
C13 C12 C17 C37 -177.9(3) . 3_667
O3 C12 C17 C37 7.8(5) . 3_667
C15 C16 C17 C12 -2.0(5) . .
C18 C16 C17 C12 177.5(3) . .
C15 C16 C17 C37 178.3(3) . 3_667
C18 C16 C17 C37 -2.1(5) . 3_667
C15 C16 C18 O5 37.8(5) . .
C17 C16 C18 O5 -141.8(4) . .
C15 C16 C18 O4 -144.3(3) . .
C17 C16 C18 O4 36.1(5) . .
C24 C19 C20 C21 -0.4(6) . .
C19 C20 C21 C22 1.3(6) . .
C19 C20 C21 O8 177.8(4) . .
C20 C21 C22 C23 -1.6(6) . .
O8 C21 C22 C23 -178.3(3) . .
C21 C22 C23 C24 0.9(5) . .
C20 C19 C24 C23 -0.2(6) . .
C20 C19 C24 N1 177.3(3) . .
C22 C23 C24 C19 0.0(5) . .
C22 C23 C24 N1 -177.6(3) . .
N1 C25 C26 N2 0.6(4) . .
C31 C28 C29 C30 -2.0(6) 1_455 .
C31 C28 C29 O8 175.1(4) 1_455 .
C28 C29 C30 C33 1.2(6) . 1_455
O8 C29 C30 C33 -176.0(3) . 1_455
C28 C31 C32 C33 -1.5(6) 1_655 .
C28 C31 C32 N3 -179.1(4) 1_655 .
C31 C32 C33 C30 0.7(6) . 1_655
N3 C32 C33 C30 178.3(3) . 1_655
N3 C34 C35 N4 1.2(6) . .
N2 C27 N1 C25 0.6(4) . .
N2 C27 N1 C24 179.6(3) . .
C26 C25 N1 C27 -0.7(4) . .
C26 C25 N1 C24 -179.8(3) . .
C19 C24 N1 C27 58.7(5) . .
C23 C24 N1 C27 -123.7(4) . .
C19 C24 N1 C25 -122.5(4) . .
C23 C24 N1 C25 55.2(5) . .
N1 C27 N2 C26 -0.3(4) . .
N1 C27 N2 Co1 178.5(2) . .
C25 C26 N2 C27 -0.2(4) . .
C25 C26 N2 Co1 -178.9(2) . .
O4 Co1 N2 C27 173.4(3) . .
O7 Co1 N2 C27 -44.3(4) . .
N4 Co1 N2 C27 78.2(3) . .
O6 Co1 N2 C27 -7.4(3) . .
O7 Co1 N2 C27 -103.8(3) 3_667 .
O4 Co1 N2 C26 -8.1(3) . .
O7 Co1 N2 C26 134.1(3) . .
N4 Co1 N2 C26 -103.4(3) . .
O6 Co1 N2 C26 171.1(3) . .
O7 Co1 N2 C26 74.7(3) 3_667 .
N4 C36 N3 C34 0.3(5) . .
N4 C36 N3 C32 -177.9(3) . .
C35 C34 N3 C36 -1.0(5) . .
C35 C34 N3 C32 177.4(4) . .
C31 C32 N3 C36 -33.9(6) . .
C33 C32 N3 C36 148.5(4) . .
C31 C32 N3 C34 148.1(4) . .
C33 C32 N3 C34 -29.5(6) . .
N3 C36 N4 C35 0.4(5) . .
N3 C36 N4 Co1 -176.1(2) . .
C34 C35 N4 C36 -1.0(6) . .
C34 C35 N4 Co1 175.7(3) . .
O4 Co1 N4 C36 16.6(3) . .
N2 Co1 N4 C36 130.3(3) . .
O7 Co1 N4 C36 -82.4(3) . .
O6 Co1 N4 C36 -140.3(3) . .
O7 Co1 N4 C36 -34.0(10) 3_667 .
O4 Co1 N4 C35 -159.3(4) . .
N2 Co1 N4 C35 -45.6(4) . .
O7 Co1 N4 C35 101.7(4) . .
O6 Co1 N4 C35 43.8(4) . .
O7 Co1 N4 C35 150.1(7) 3_667 .
C11 C10 O3 C12 9.4(5) . .
C9 C10 O3 C12 -173.2(3) . .
C17 C12 O3 C10 -112.8(4) . .
C13 C12 O3 C10 72.9(5) . .
O5 C18 O4 Co1 -148.2(3) . .
C16 C18 O4 Co1 34.0(6) . .
N2 Co1 O4 C18 12.9(4) . .
O7 Co1 O4 C18 -144.1(4) . .
N4 Co1 O4 C18 116.5(4) . .
O6 Co1 O4 C18 -165.0(3) . .
O7 Co1 O4 C18 -69.2(4) 3_667 .
O7 C37 O6 Co1 5.2(3) . .
C17 C37 O6 Co1 -175.3(3) 3_667 .
O4 Co1 O6 C37 20.9(4) . .
N2 Co1 O6 C37 -157.1(2) . .
O7 Co1 O6 C37 -3.23(18) . .
N4 Co1 O6 C37 100.4(2) . .
O7 Co1 O6 C37 -72.6(2) 3_667 .
O6 C37 O7 Co1 -5.9(3) . .
C17 C37 O7 Co1 174.5(3) 3_667 .
O6 C37 O7 Co1 100.7(3) . 3_667
C17 C37 O7 Co1 -78.9(3) 3_667 3_667
O4 Co1 O7 C37 -167.39(18) . .
N2 Co1 O7 C37 47.4(3) . .
N4 Co1 O7 C37 -76.0(2) . .
O6 Co1 O7 C37 3.09(18) . .
O7 Co1 O7 C37 109.6(2) 3_667 .
O4 Co1 O7 Co1 83.04(11) . 3_667
N2 Co1 O7 Co1 -62.17(18) . 3_667
N4 Co1 O7 Co1 174.40(10) . 3_667
O6 Co1 O7 Co1 -106.48(12) . 3_667
O7 Co1 O7 Co1 0.0 3_667 3_667
C20 C21 O8 C29 40.7(6) . .
C22 C21 O8 C29 -142.7(4) . .
C30 C29 O8 C21 -133.0(4) . .
C28 C29 O8 C21 49.8(6) . .
