#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/24/1512439.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1512439
loop_
_publ_author_name
'Yue Zhao'
'Ling-Ling Zhai'
'Gao-Chao Lv'
'Xin Zhou'
'Wei-Yin Sun'
_publ_section_title
;
 Silver(I) complexes with oxazoline-containing bidentate ligands:
 Syntheses, structures and properties
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              38
_journal_page_last               45
_journal_paper_doi               10.1016/j.ica.2012.06.035
_journal_volume                  392
_journal_year                    2012
_chemical_formula_sum            'C48 H48 Ag3 F18 N8 O8 Sb3'
_chemical_formula_weight         1895.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.0250(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   31.9436(16)
_cell_length_b                   8.2466(4)
_cell_length_c                   11.1986(6)
_cell_measurement_reflns_used    4196
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.54
_cell_measurement_theta_min      2.55
_cell_volume                     2945.9(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_sigmaI/netI    0.0461
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            7556
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.28
_exptl_absorpt_coefficient_mu    2.449
_exptl_absorpt_correction_T_max  0.7256
_exptl_absorpt_correction_T_min  0.6670
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    2.137
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1824
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.151
_refine_diff_density_min         -1.335
_refine_diff_density_rms         0.145
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.05(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     398
_refine_ls_number_reflns         4153
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0509
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0892P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1216
_refine_ls_wR_factor_ref         0.1238
_reflns_number_gt                3873
_reflns_number_total             4153
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ICA-2012-392-38-45-3.cif
_cod_data_source_block           3
_cod_original_sg_symbol_H-M      C2
_cod_database_code               1512439
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.5000 0.36131(14) 0.5000 0.0549(3) Uani 1 2 d S
Ag2 Ag 0.28344(2) 0.74390(9) 0.19756(7) 0.0504(2) Uani 1 1 d .
C1 C 0.3440(2) 0.3014(10) 0.4189(7) 0.0349(18) Uani 1 1 d .
H1 H 0.3314 0.2775 0.4898 0.042 Uiso 1 1 calc R
C2 C 0.3851(2) 0.2568(11) 0.4046(7) 0.0357(17) Uani 1 1 d .
C3 C 0.4038(3) 0.2850(12) 0.2969(8) 0.0403(19) Uani 1 1 d .
H3 H 0.4312 0.2520 0.2860 0.048 Uiso 1 1 calc R
C4 C 0.3810(3) 0.3624(14) 0.2079(8) 0.047(2) Uani 1 1 d .
H4 H 0.3934 0.3842 0.1364 0.056 Uiso 1 1 calc R
C5 C 0.3401(3) 0.4093(12) 0.2200(8) 0.046(2) Uani 1 1 d .
H5 H 0.3250 0.4590 0.1569 0.055 Uiso 1 1 calc R
C6 C 0.3217(2) 0.3811(11) 0.3282(7) 0.0377(19) Uani 1 1 d .
C7 C 0.4082(2) 0.1651(11) 0.5024(7) 0.0369(18) Uani 1 1 d .
C8 C 0.4560(3) 0.0504(16) 0.6203(9) 0.058(2) Uani 1 1 d .
H8A H 0.4755 0.0970 0.6801 0.070 Uiso 1 1 calc R
H8B H 0.4675 -0.0505 0.5920 0.070 Uiso 1 1 calc R
C9 C 0.4132(3) 0.0223(16) 0.6715(9) 0.064(3) Uani 1 1 d .
H9A H 0.4085 -0.0918 0.6870 0.077 Uiso 1 1 calc R
H9B H 0.4104 0.0831 0.7448 0.077 Uiso 1 1 calc R
C10 C 0.2783(3) 0.4353(12) 0.3470(8) 0.0393(19) Uani 1 1 d .
C11 C 0.2186(3) 0.4375(14) 0.4446(9) 0.049(2) Uani 1 1 d .
H11A H 0.2194 0.4958 0.5199 0.059 Uiso 1 1 calc R
H11B H 0.1949 0.3635 0.4416 0.059 Uiso 1 1 calc R
C12 C 0.2160(3) 0.5517(16) 0.3413(9) 0.050(2) Uani 1 1 d .
H12A H 0.1956 0.5142 0.2800 0.060 Uiso 1 1 calc R
H12B H 0.2081 0.6594 0.3666 0.060 Uiso 1 1 calc R
C13 C 0.4262(3) 0.7811(12) 0.2105(8) 0.041(2) Uani 1 1 d .
H13 H 0.4377 0.8002 0.1372 0.050 Uiso 1 1 calc R
C14 C 0.3862(3) 0.8388(11) 0.2312(8) 0.0415(19) Uani 1 1 d .
C15 C 0.3701(3) 0.8107(12) 0.3406(8) 0.043(2) Uani 1 1 d .
H15 H 0.3435 0.8495 0.3550 0.051 Uiso 1 1 calc R
C16 C 0.3924(3) 0.7260(13) 0.4306(8) 0.048(2) Uani 1 1 d .
H16 H 0.3812 0.7095 0.5046 0.058 Uiso 1 1 calc R
C17 C 0.4318(3) 0.6669(12) 0.4073(8) 0.045(2) Uani 1 1 d .
H17 H 0.4470 0.6072 0.4653 0.054 Uiso 1 1 calc R
C18 C 0.4488(3) 0.6964(10) 0.2977(8) 0.0385(18) Uani 1 1 d .
C19 C 0.4906(3) 0.6319(12) 0.2750(8) 0.0418(19) Uani 1 1 d .
C20 C 0.5481(3) 0.6178(15) 0.1661(11) 0.057(3) Uani 1 1 d .
H20A H 0.5710 0.6953 0.1694 0.069 Uiso 1 1 calc R
H20B H 0.5485 0.5580 0.0915 0.069 Uiso 1 1 calc R
C21 C 0.5515(3) 0.5037(14) 0.2724(9) 0.053(3) Uani 1 1 d .
H21A H 0.5544 0.3924 0.2463 0.064 Uiso 1 1 calc R
H21B H 0.5754 0.5314 0.3253 0.064 Uiso 1 1 calc R
C22 C 0.3612(3) 0.9225(11) 0.1354(8) 0.0407(19) Uani 1 1 d .
C23 C 0.3517(3) 1.0668(18) -0.0321(10) 0.063(3) Uani 1 1 d .
H23A H 0.3540 1.0077 -0.1063 0.076 Uiso 1 1 calc R
H23B H 0.3554 1.1816 -0.0469 0.076 Uiso 1 1 calc R
C24 C 0.3099(3) 1.0338(15) 0.0223(9) 0.056(3) Uani 1 1 d .
H24A H 0.2976 1.1330 0.0511 0.068 Uiso 1 1 calc R
H24B H 0.2903 0.9831 -0.0354 0.068 Uiso 1 1 calc R
F1 F 0.1457(3) -0.1150(15) 0.2277(13) 0.137(4) Uani 1 1 d .
F2 F 0.1543(3) 0.1948(13) 0.2766(11) 0.121(4) Uani 1 1 d .
F3 F 0.2193(3) 0.2118(13) 0.1496(14) 0.141(5) Uani 1 1 d .
F4 F 0.2105(3) -0.1005(14) 0.0899(9) 0.114(4) Uani 1 1 d .
F5 F 0.1472(3) 0.0932(18) 0.0580(10) 0.138(5) Uani 1 1 d .
F6 F 0.2192(3) -0.0067(15) 0.3126(8) 0.128(4) Uani 1 1 d .
F7 F 0.9485(3) 0.6923(17) -0.0803(8) 0.122(4) Uani 1 1 d .
F8 F 0.9782(4) 0.599(3) 0.1425(12) 0.178(7) Uani 1 1 d .
F9 F 0.9821(4) 0.867(3) 0.072(2) 0.258(13) Uani 1 1 d .
N1 N 0.4477(2) 0.1621(11) 0.5225(7) 0.0489(19) Uani 1 1 d .
N2 N 0.2585(2) 0.5523(11) 0.2965(6) 0.0390(15) Uani 1 1 d .
N3 N 0.5115(2) 0.5260(10) 0.3343(7) 0.0445(18) Uani 1 1 d .
N4 N 0.3214(2) 0.9223(10) 0.1221(7) 0.0424(17) Uani 1 1 d .
O1 O 0.3845(2) 0.0821(9) 0.5764(6) 0.0507(16) Uani 1 1 d .
O2 O 0.25803(17) 0.3506(9) 0.4292(5) 0.0457(14) Uani 1 1 d .
O3 O 0.5080(2) 0.6991(10) 0.1775(7) 0.067(2) Uani 1 1 d .
O4 O 0.3820(2) 1.0078(9) 0.0607(6) 0.057(2) Uani 1 1 d .
Sb1 Sb 0.182734(18) 0.04759(7) 0.18586(5) 0.04614(18) Uani 1 1 d .
Sb2 Sb 1.0000 0.67166(17) 0.0000 0.0680(3) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N3 109.2(4) 2_656 .
N3 Ag1 N1 100.2(3) 2_656 .
N3 Ag1 N1 128.9(3) . .
N3 Ag1 N1 128.9(3) 2_656 2_656
N3 Ag1 N1 100.2(3) . 2_656
N1 Ag1 N1 92.0(4) . 2_656
N4 Ag2 N2 166.6(3) . .
C6 C1 C2 120.0(8) . .
C6 C1 H1 120.0 . .
C2 C1 H1 120.0 . .
C1 C2 C3 120.6(8) . .
C1 C2 C7 119.0(7) . .
C3 C2 C7 120.2(7) . .
C4 C3 C2 118.3(8) . .
C4 C3 H3 120.8 . .
C2 C3 H3 120.8 . .
C3 C4 C5 122.3(8) . .
C3 C4 H4 118.9 . .
C5 C4 H4 118.9 . .
C4 C5 C6 119.0(8) . .
C4 C5 H5 120.5 . .
C6 C5 H5 120.5 . .
C1 C6 C5 119.7(8) . .
C1 C6 C10 119.4(7) . .
C5 C6 C10 120.9(8) . .
N1 C7 O1 118.0(8) . .
N1 C7 C2 125.9(8) . .
O1 C7 C2 116.1(7) . .
N1 C8 C9 104.5(8) . .
N1 C8 H8A 110.9 . .
C9 C8 H8A 110.9 . .
N1 C8 H8B 110.9 . .
C9 C8 H8B 110.9 . .
H8A C8 H8B 108.9 . .
O1 C9 C8 102.4(7) . .
O1 C9 H9A 111.3 . .
C8 C9 H9A 111.3 . .
O1 C9 H9B 111.3 . .
C8 C9 H9B 111.3 . .
H9A C9 H9B 109.2 . .
N2 C10 O2 116.8(7) . .
N2 C10 C6 127.9(8) . .
O2 C10 C6 115.3(8) . .
O2 C11 C12 103.3(7) . .
O2 C11 H11A 111.1 . .
C12 C11 H11A 111.1 . .
O2 C11 H11B 111.1 . .
C12 C11 H11B 111.1 . .
H11A C11 H11B 109.1 . .
N2 C12 C11 104.6(8) . .
N2 C12 H12A 110.8 . .
C11 C12 H12A 110.8 . .
N2 C12 H12B 110.8 . .
C11 C12 H12B 110.8 . .
H12A C12 H12B 108.9 . .
C18 C13 C14 120.5(8) . .
C18 C13 H13 119.8 . .
C14 C13 H13 119.8 . .
C15 C14 C13 118.6(8) . .
C15 C14 C22 121.0(8) . .
C13 C14 C22 120.3(8) . .
C14 C15 C16 122.0(8) . .
C14 C15 H15 119.0 . .
C16 C15 H15 119.0 . .
C17 C16 C15 118.3(8) . .
C17 C16 H16 120.8 . .
C15 C16 H16 120.8 . .
C16 C17 C18 120.3(8) . .
C16 C17 H17 119.9 . .
C18 C17 H17 119.9 . .
C13 C18 C17 120.2(8) . .
C13 C18 C19 120.6(8) . .
C17 C18 C19 119.2(8) . .
N3 C19 O3 118.2(8) . .
N3 C19 C18 128.1(8) . .
O3 C19 C18 113.7(8) . .
O3 C20 C21 104.0(8) . .
O3 C20 H20A 111.0 . .
C21 C20 H20A 111.0 . .
O3 C20 H20B 111.0 . .
C21 C20 H20B 111.0 . .
H20A C20 H20B 109.0 . .
N3 C21 C20 105.1(7) . .
N3 C21 H21A 110.7 . .
C20 C21 H21A 110.7 . .
N3 C21 H21B 110.7 . .
C20 C21 H21B 110.7 . .
H21A C21 H21B 108.8 . .
N4 C22 O4 117.8(8) . .
N4 C22 C14 125.7(8) . .
O4 C22 C14 116.5(7) . .
O4 C23 C24 102.6(8) . .
O4 C23 H23A 111.3 . .
C24 C23 H23A 111.3 . .
O4 C23 H23B 111.3 . .
C24 C23 H23B 111.3 . .
H23A C23 H23B 109.2 . .
N4 C24 C23 103.0(8) . .
N4 C24 H24A 111.2 . .
C23 C24 H24A 111.2 . .
N4 C24 H24B 111.2 . .
C23 C24 H24B 111.2 . .
H24A C24 H24B 109.1 . .
C7 N1 C8 106.6(8) . .
C7 N1 Ag1 131.9(7) . .
C8 N1 Ag1 115.0(6) . .
C10 N2 C12 107.1(8) . .
C10 N2 Ag2 127.4(6) . .
C12 N2 Ag2 124.2(7) . .
C19 N3 C21 106.4(8) . .
C19 N3 Ag1 135.6(6) . .
C21 N3 Ag1 117.9(6) . .
C22 N4 C24 107.1(8) . .
C22 N4 Ag2 123.1(6) . .
C24 N4 Ag2 127.7(6) . .
C7 O1 C9 105.8(7) . .
C10 O2 C11 105.9(7) . .
C19 O3 C20 106.2(8) . .
C22 O4 C23 107.2(7) . .
F5 Sb1 F6 177.6(6) . .
F5 Sb1 F3 92.9(7) . .
F6 Sb1 F3 88.1(6) . .
F5 Sb1 F2 89.6(5) . .
F6 Sb1 F2 92.6(5) . .
F3 Sb1 F2 88.5(6) . .
F5 Sb1 F1 88.2(7) . .
F6 Sb1 F1 90.9(6) . .
F3 Sb1 F1 178.0(7) . .
F2 Sb1 F1 89.9(5) . .
F5 Sb1 F4 88.8(5) . .
F6 Sb1 F4 89.1(5) . .
F3 Sb1 F4 91.6(5) . .
F2 Sb1 F4 178.4(5) . .
F1 Sb1 F4 90.1(5) . .
F7 Sb2 F7 169.4(9) 2_755 .
F7 Sb2 F8 94.8(5) 2_755 2_755
F7 Sb2 F8 88.6(5) . 2_755
F7 Sb2 F8 88.6(5) 2_755 .
F7 Sb2 F8 94.8(5) . .
F8 Sb2 F8 142.9(14) 2_755 .
F7 Sb2 F9 81.2(6) 2_755 2_755
F7 Sb2 F9 89.8(6) . 2_755
F8 Sb2 F9 77.0(10) 2_755 2_755
F8 Sb2 F9 139.7(12) . 2_755
F7 Sb2 F9 89.8(6) 2_755 .
F7 Sb2 F9 81.2(6) . .
F8 Sb2 F9 139.7(12) 2_755 .
F8 Sb2 F9 77.0(10) . .
F9 Sb2 F9 64.2(16) 2_755 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.344(8) 2_656
Ag1 N3 2.344(8) .
Ag1 N1 2.365(8) .
Ag1 N1 2.365(8) 2_656
Ag2 N4 2.110(8) .
Ag2 N2 2.111(8) .
C1 C6 1.376(12) .
C1 C2 1.382(11) .
C1 H1 0.9300 .
C2 C3 1.393(12) .
C2 C7 1.494(12) .
C3 C4 1.362(14) .
C3 H3 0.9300 .
C4 C5 1.374(13) .
C4 H4 0.9300 .
C5 C6 1.394(12) .
C5 H5 0.9300 .
C6 C10 1.482(11) .
C7 N1 1.271(11) .
C7 O1 1.339(10) .
C8 N1 1.445(13) .
C8 C9 1.527(14) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 O1 1.453(11) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 N2 1.271(12) .
C10 O2 1.349(10) .
C11 O2 1.468(11) .
C11 C12 1.491(16) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 N2 1.471(11) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C18 1.374(12) .
C13 C14 1.394(12) .
C13 H13 0.9300 .
C14 C15 1.373(12) .
C14 C22 1.474(12) .
C15 C16 1.391(13) .
C15 H15 0.9300 .
C16 C17 1.388(13) .
C16 H16 0.9300 .
C17 C18 1.389(12) .
C17 H17 0.9300 .
C18 C19 1.472(12) .
C19 N3 1.265(12) .
C19 O3 1.368(11) .
C20 O3 1.460(13) .
C20 C21 1.516(16) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 N3 1.496(11) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 N4 1.274(12) .
C22 O4 1.301(11) .
C23 O4 1.465(12) .
C23 C24 1.521(14) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 N4 1.479(12) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
F1 Sb1 1.863(10) .
F2 Sb1 1.851(8) .
F3 Sb1 1.847(10) .
F4 Sb1 1.880(9) .
F5 Sb1 1.820(8) .
F6 Sb1 1.844(8) .
F7 Sb2 1.840(8) .
F8 Sb2 1.872(14) .
F9 Sb2 1.898(18) .
Sb2 F7 1.840(8) 2_755
Sb2 F8 1.872(14) 2_755
Sb2 F9 1.898(18) 2_755
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C6 C1 C2 C3 -3.0(13) .
C6 C1 C2 C7 -177.8(8) .
C1 C2 C3 C4 2.1(13) .
C7 C2 C3 C4 176.9(9) .
C2 C3 C4 C5 -1.6(15) .
C3 C4 C5 C6 1.9(16) .
C2 C1 C6 C5 3.2(13) .
C2 C1 C6 C10 -177.0(8) .
C4 C5 C6 C1 -2.7(14) .
C4 C5 C6 C10 177.6(9) .
C1 C2 C7 N1 -155.0(9) .
C3 C2 C7 N1 30.1(14) .
C1 C2 C7 O1 23.4(12) .
C3 C2 C7 O1 -151.4(8) .
N1 C8 C9 O1 16.1(12) .
C1 C6 C10 N2 153.7(9) .
C5 C6 C10 N2 -26.6(14) .
C1 C6 C10 O2 -25.2(12) .
C5 C6 C10 O2 154.5(9) .
O2 C11 C12 N2 -15.0(10) .
C18 C13 C14 C15 0.7(14) .
C18 C13 C14 C22 -177.0(8) .
C13 C14 C15 C16 -0.4(15) .
C22 C14 C15 C16 177.3(9) .
C14 C15 C16 C17 -0.9(16) .
C15 C16 C17 C18 1.9(16) .
C14 C13 C18 C17 0.2(14) .
C14 C13 C18 C19 178.5(9) .
C16 C17 C18 C13 -1.6(15) .
C16 C17 C18 C19 -179.8(9) .
C13 C18 C19 N3 -164.3(10) .
C17 C18 C19 N3 13.9(15) .
C13 C18 C19 O3 16.2(13) .
C17 C18 C19 O3 -165.5(9) .
O3 C20 C21 N3 1.9(12) .
C15 C14 C22 N4 -28.1(15) .
C13 C14 C22 N4 149.6(10) .
C15 C14 C22 O4 149.7(10) .
C13 C14 C22 O4 -32.6(13) .
O4 C23 C24 N4 -14.6(12) .
O1 C7 N1 C8 5.2(12) .
C2 C7 N1 C8 -176.4(9) .
O1 C7 N1 Ag1 -144.1(7) .
C2 C7 N1 Ag1 34.4(14) .
C9 C8 N1 C7 -13.4(12) .
C9 C8 N1 Ag1 141.8(7) .
N3 Ag1 N1 C7 75.3(9) 2_656
N3 Ag1 N1 C7 -49.7(10) .
N1 Ag1 N1 C7 -154.6(10) 2_656
N3 Ag1 N1 C8 -72.0(8) 2_656
N3 Ag1 N1 C8 163.0(7) .
N1 Ag1 N1 C8 58.1(7) 2_656
O2 C10 N2 C12 -3.7(11) .
C6 C10 N2 C12 177.4(9) .
O2 C10 N2 Ag2 163.9(6) .
C6 C10 N2 Ag2 -15.0(14) .
C11 C12 N2 C10 12.0(11) .
C11 C12 N2 Ag2 -156.1(6) .
N4 Ag2 N2 C10 -23.5(19) .
N4 Ag2 N2 C12 142.1(12) .
O3 C19 N3 C21 -1.2(12) .
C18 C19 N3 C21 179.4(9) .
O3 C19 N3 Ag1 -177.3(7) .
C18 C19 N3 Ag1 3.3(16) .
C20 C21 N3 C19 -0.6(11) .
C20 C21 N3 Ag1 176.3(6) .
N3 Ag1 N3 C19 -61.1(9) 2_656
N1 Ag1 N3 C19 60.4(10) .
N1 Ag1 N3 C19 161.4(9) 2_656
N3 Ag1 N3 C21 123.2(7) 2_656
N1 Ag1 N3 C21 -115.4(7) .
N1 Ag1 N3 C21 -14.4(7) 2_656
O4 C22 N4 C24 -3.1(12) .
C14 C22 N4 C24 174.7(9) .
O4 C22 N4 Ag2 161.4(7) .
C14 C22 N4 Ag2 -20.8(13) .
C23 C24 N4 C22 11.4(12) .
C23 C24 N4 Ag2 -152.1(8) .
N2 Ag2 N4 C22 13.9(19) .
N2 Ag2 N4 C24 175.0(12) .
N1 C7 O1 C9 6.0(12) .
C2 C7 O1 C9 -172.6(8) .
C8 C9 O1 C7 -13.4(11) .
N2 C10 O2 C11 -6.5(10) .
C6 C10 O2 C11 172.6(7) .
C12 C11 O2 C10 13.2(9) .
N3 C19 O3 C20 2.5(13) .
C18 C19 O3 C20 -178.0(8) .
C21 C20 O3 C19 -2.5(12) .
N4 C22 O4 C23 -7.2(13) .
C14 C22 O4 C23 174.8(9) .
C24 C23 O4 C22 13.5(12) .
