#------------------------------------------------------------------------------
#$Date: 2021-02-26 11:54:15 +0200 (Fri, 26 Feb 2021) $
#$Revision: 262257 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/06/1560671.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1560671
loop_
_publ_author_name
'Zhao, Hui'
'Sun, Xiao-Xia'
'Hu, Huai-Ming'
'An, Ran'
'Yang, Meng-Lin'
'Xue, Ganglin'
_publ_section_title
;
 Syntheses, structures and luminescent properties of lanthanide
 coordination polymers assembled from imidazophenanthroline derivative and
 oxalate ligands
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              67
_journal_page_last               73
_journal_paper_doi               10.1016/j.jssc.2016.09.033
_journal_volume                  245
_journal_year                    2017
_chemical_formula_moiety         'C40 H24 N8 O18 S4 Dy2, 4(H2 O)'
_chemical_formula_sum            'C40 H32 Dy2 N8 O22 S4'
_chemical_formula_weight         1429.98
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                98.705(2)
_cell_angle_beta                 91.312(2)
_cell_angle_gamma                115.134(2)
_cell_formula_units_Z            1
_cell_length_a                   9.8513(10)
_cell_length_b                   10.7632(11)
_cell_length_c                   12.1556(13)
_cell_measurement_reflns_used    3626
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.53
_cell_measurement_theta_min      2.36
_cell_volume                     1147.9(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0150
_diffrn_reflns_av_sigmaI/netI    0.0324
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            5747
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.29
_exptl_absorpt_coefficient_mu    3.509
_exptl_absorpt_correction_T_max  0.645
_exptl_absorpt_correction_T_min  0.526
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.069
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             700
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.529
_refine_diff_density_min         -0.509
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         3989
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0258
_refine_ls_R_factor_gt           0.0233
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0323P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0554
_refine_ls_wR_factor_ref         0.0566
_reflns_number_gt                3724
_reflns_number_total             3989
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2017-245-67.cif
_cod_data_source_block           nw2032_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1560671
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.953618(18) 0.753917(16) 0.603355(13) 0.01772(7) Uani 1 1 d . . .
S1 S 0.72210(10) 1.26739(9) 1.27118(8) 0.02018(19) Uani 1 1 d . . .
S2 S 0.24927(10) 1.06351(9) 1.50676(7) 0.01788(19) Uani 1 1 d . . .
N1 N 0.7543(3) 0.6717(3) 0.7358(3) 0.0239(7) Uani 1 1 d . . .
N2 N 0.9750(3) 0.9361(3) 0.7711(2) 0.0229(7) Uani 1 1 d . . .
N3 N 0.5328(3) 0.8165(3) 1.0649(2) 0.0240(7) Uani 1 1 d . . .
N4 N 0.6911(3) 1.0394(3) 1.0706(2) 0.0251(7) Uani 1 1 d . . .
H4 H 0.7335 1.1285 1.0913 0.030 Uiso 1 1 calc R . .
O1 O 0.7326(3) 1.3758(3) 1.3603(2) 0.0310(6) Uani 1 1 d . . .
O2 O 0.8474(3) 1.2290(3) 1.2810(2) 0.0236(6) Uani 1 1 d . . .
O3 O 0.7036(3) 1.2939(3) 1.1597(2) 0.0290(6) Uani 1 1 d . . .
O4 O 0.1722(3) 0.9375(3) 1.5531(2) 0.0252(6) Uani 1 1 d . . .
O5 O 0.1404(3) 1.0982(3) 1.4496(2) 0.0263(6) Uani 1 1 d . . .
O6 O 0.3549(3) 1.1807(3) 1.5874(2) 0.0269(6) Uani 1 1 d . . .
O7 O 0.9054(3) 0.5218(2) 0.6151(2) 0.0226(6) Uani 1 1 d . . .
O8 O 0.9537(3) 0.3422(3) 0.5449(2) 0.0265(6) Uani 1 1 d . . .
C1 C 0.6505(4) 0.5383(4) 0.7225(3) 0.0287(9) Uani 1 1 d . . .
H1 H 0.6541 0.4752 0.6626 0.034 Uiso 1 1 calc R . .
C2 C 0.5382(4) 0.4896(4) 0.7933(4) 0.0325(9) Uani 1 1 d . . .
H2 H 0.4711 0.3957 0.7821 0.039 Uiso 1 1 calc R . .
C3 C 0.5273(4) 0.5808(4) 0.8794(3) 0.0281(9) Uani 1 1 d . . .
H3 H 0.4519 0.5499 0.9270 0.034 Uiso 1 1 calc R . .
C4 C 0.6313(4) 0.7222(4) 0.8957(3) 0.0218(8) Uani 1 1 d . . .
C5 C 0.6268(4) 0.8283(4) 0.9800(3) 0.0232(8) Uani 1 1 d . . .
C6 C 0.7271(4) 0.9652(4) 0.9847(3) 0.0217(8) Uani 1 1 d . . .
C7 C 0.8497(4) 1.0115(4) 0.9167(3) 0.0224(8) Uani 1 1 d . . .
C8 C 0.9611(4) 1.1485(4) 0.9267(3) 0.0302(9) Uani 1 1 d . . .
H8 H 0.9555 1.2201 0.9769 0.036 Uiso 1 1 calc R . .
C9 C 1.0784(5) 1.1753(4) 0.8614(3) 0.0325(9) Uani 1 1 d . . .
H9 H 1.1553 1.2651 0.8682 0.039 Uiso 1 1 calc R . .
C10 C 1.0809(4) 1.0665(4) 0.7847(3) 0.0291(9) Uani 1 1 d . . .
H10 H 1.1610 1.0861 0.7408 0.035 Uiso 1 1 calc R . .
C11 C 0.8589(4) 0.9073(4) 0.8366(3) 0.0191(7) Uani 1 1 d . . .
C12 C 0.7442(4) 0.7623(4) 0.8220(3) 0.0200(8) Uani 1 1 d . . .
C13 C 0.5767(4) 0.9473(4) 1.1175(3) 0.0232(8) Uani 1 1 d . . .
C14 C 0.5059(4) 0.9841(4) 1.2167(3) 0.0213(8) Uani 1 1 d . . .
C15 C 0.3768(4) 0.8767(4) 1.2430(3) 0.0286(9) Uani 1 1 d . . .
H15 H 0.3419 0.7886 1.1990 0.034 Uiso 1 1 calc R . .
C16 C 0.2980(4) 0.8956(4) 1.3320(3) 0.0265(9) Uani 1 1 d . . .
H16 H 0.2110 0.8221 1.3465 0.032 Uiso 1 1 calc R . .
C17 C 0.3514(4) 1.0260(4) 1.3988(3) 0.0204(8) Uani 1 1 d . . .
C18 C 0.4803(4) 1.1352(4) 1.3765(3) 0.0221(8) Uani 1 1 d . . .
H18 H 0.5155 1.2224 1.4220 0.026 Uiso 1 1 calc R . .
C19 C 0.5573(4) 1.1153(4) 1.2866(3) 0.0208(8) Uani 1 1 d . . .
C20 C 0.9592(4) 0.4605(4) 0.5459(3) 0.0218(8) Uani 1 1 d . . .
O9 O 0.7343(4) 0.6172(3) 0.4735(3) 0.0387(7) Uani 1 1 d D . .
O10 O 0.0637(8) 0.5611(6) 0.1671(4) 0.1142(19) Uani 1 1 d D . .
O11 O 0.8093(6) 0.4967(6) 0.0190(6) 0.1033(18) Uani 1 1 d D . .
H9A H 0.683(7) 0.651(7) 0.444(5) 0.124 Uiso 1 1 d D . .
H9B H 0.744(8) 0.552(6) 0.433(5) 0.124 Uiso 1 1 d D . .
H10A H 0.027(9) 0.481(4) 0.125(6) 0.124 Uiso 1 1 d D . .
H10B H 0.059(9) 0.529(8) 0.227(4) 0.124 Uiso 1 1 d D . .
H11A H 0.764(9) 0.408(3) -0.008(7) 0.124 Uiso 1 1 d D . .
H11B H 0.843(8) 0.515(8) -0.042(4) 0.124 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Dy1 O2 137.56(9) 2_677 2_777
O5 Dy1 O8 112.27(9) 2_677 2_766
O2 Dy1 O8 88.10(9) 2_777 2_766
O5 Dy1 O7 146.79(9) 2_677 .
O2 Dy1 O7 74.48(9) 2_777 .
O8 Dy1 O7 69.11(8) 2_766 .
O5 Dy1 O4 77.21(9) 2_677 1_654
O2 Dy1 O4 74.60(9) 2_777 1_654
O8 Dy1 O4 71.80(9) 2_766 1_654
O7 Dy1 O4 130.19(8) . 1_654
O5 Dy1 O9 71.87(9) 2_677 .
O2 Dy1 O9 150.57(9) 2_777 .
O8 Dy1 O9 76.48(10) 2_766 .
O7 Dy1 O9 76.62(9) . .
O4 Dy1 O9 122.10(11) 1_654 .
O5 Dy1 N1 91.15(10) 2_677 .
O2 Dy1 N1 97.17(9) 2_777 .
O8 Dy1 N1 138.46(9) 2_766 .
O7 Dy1 N1 72.75(9) . .
O4 Dy1 N1 149.22(9) 1_654 .
O9 Dy1 N1 79.33(11) . .
O5 Dy1 N2 70.22(9) 2_677 .
O2 Dy1 N2 76.04(9) 2_777 .
O8 Dy1 N2 154.35(10) 2_766 .
O7 Dy1 N2 123.73(9) . .
O4 Dy1 N2 84.47(9) 1_654 .
O9 Dy1 N2 126.10(10) . .
N1 Dy1 N2 64.76(10) . .
O1 S1 O3 114.91(16) . .
O1 S1 O2 112.45(16) . .
O3 S1 O2 110.32(15) . .
O1 S1 C19 106.39(17) . .
O3 S1 C19 106.79(16) . .
O2 S1 C19 105.27(16) . .
O6 S2 O4 113.64(16) . .
O6 S2 O5 112.08(15) . .
O4 S2 O5 110.68(16) . .
O6 S2 C17 107.92(16) . .
O4 S2 C17 107.58(16) . .
O5 S2 C17 104.37(16) . .
C1 N1 C12 117.0(3) . .
C1 N1 Dy1 122.1(2) . .
C12 N1 Dy1 120.9(2) . .
C10 N2 C11 118.1(3) . .
C10 N2 Dy1 121.9(2) . .
C11 N2 Dy1 118.8(2) . .
C13 N3 C5 104.2(3) . .
C13 N4 C6 107.5(3) . .
C13 N4 H4 126.2 . .
C6 N4 H4 126.2 . .
S1 O2 Dy1 145.69(15) . 2_777
S2 O4 Dy1 153.63(16) . 1_456
S2 O5 Dy1 155.15(16) . 2_677
C20 O7 Dy1 118.0(2) . .
C20 O8 Dy1 118.8(2) . 2_766
N1 C1 C2 123.6(4) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 119.4(4) . .
C3 C2 H2 120.3 . .
C1 C2 H2 120.3 . .
C2 C3 C4 119.4(4) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C3 C4 C12 117.7(3) . .
C3 C4 C5 124.3(3) . .
C12 C4 C5 118.0(3) . .
C6 C5 N3 110.3(3) . .
C6 C5 C4 120.1(3) . .
N3 C5 C4 129.6(3) . .
N4 C6 C5 105.8(3) . .
N4 C6 C7 129.5(3) . .
C5 C6 C7 124.5(3) . .
C8 C7 C11 118.7(3) . .
C8 C7 C6 125.5(3) . .
C11 C7 C6 115.7(3) . .
C9 C8 C7 118.9(4) . .
C9 C8 H8 120.5 . .
C7 C8 H8 120.5 . .
C8 C9 C10 119.1(4) . .
C8 C9 H9 120.5 . .
C10 C9 H9 120.5 . .
N2 C10 C9 123.5(4) . .
N2 C10 H10 118.3 . .
C9 C10 H10 118.3 . .
N2 C11 C7 121.6(3) . .
N2 C11 C12 117.5(3) . .
C7 C11 C12 120.9(3) . .
N1 C12 C4 122.9(3) . .
N1 C12 C11 116.7(3) . .
C4 C12 C11 120.4(3) . .
N3 C13 N4 112.1(3) . .
N3 C13 C14 122.7(3) . .
N4 C13 C14 125.2(3) . .
C15 C14 C19 117.1(3) . .
C15 C14 C13 116.2(3) . .
C19 C14 C13 126.7(3) . .
C16 C15 C14 122.7(4) . .
C16 C15 H15 118.6 . .
C14 C15 H15 118.6 . .
C17 C16 C15 118.7(4) . .
C17 C16 H16 120.7 . .
C15 C16 H16 120.7 . .
C18 C17 C16 120.5(3) . .
C18 C17 S2 117.6(3) . .
C16 C17 S2 121.7(3) . .
C17 C18 C19 120.3(3) . .
C17 C18 H18 119.8 . .
C19 C18 H18 119.8 . .
C18 C19 C14 120.7(3) . .
C18 C19 S1 114.2(3) . .
C14 C19 S1 125.1(3) . .
O8 C20 O7 126.3(3) . .
O8 C20 C20 117.0(4) . 2_766
O7 C20 C20 116.6(4) . 2_766
Dy1 O9 H9A 124(5) . .
Dy1 O9 H9B 111(5) . .
H9A O9 H9B 116(6) . .
H10A O10 H10B 94(7) . .
H11A O11 H11B 92(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O5 2.311(2) 2_677
Dy1 O2 2.311(2) 2_777
Dy1 O8 2.337(2) 2_766
Dy1 O7 2.365(2) .
Dy1 O4 2.393(3) 1_654
Dy1 O9 2.401(3) .
Dy1 N1 2.516(3) .
Dy1 N2 2.543(3) .
S1 O1 1.433(3) .
S1 O3 1.449(3) .
S1 O2 1.466(2) .
S1 C19 1.789(4) .
S2 O6 1.449(3) .
S2 O4 1.453(3) .
S2 O5 1.469(3) .
S2 C17 1.772(3) .
N1 C1 1.345(5) .
N1 C12 1.355(4) .
N2 C10 1.328(5) .
N2 C11 1.362(5) .
N3 C13 1.332(5) .
N3 C5 1.387(5) .
N4 C13 1.352(5) .
N4 C6 1.364(4) .
N4 H4 0.8600 .
O2 Dy1 2.311(2) 2_777
O4 Dy1 2.392(2) 1_456
O5 Dy1 2.311(2) 2_677
O7 C20 1.254(4) .
O8 C20 1.250(4) .
O8 Dy1 2.337(2) 2_766
C1 C2 1.388(5) .
C1 H1 0.9300 .
C2 C3 1.361(5) .
C2 H2 0.9300 .
C3 C4 1.407(5) .
C3 H3 0.9300 .
C4 C12 1.408(5) .
C4 C5 1.430(5) .
C5 C6 1.373(5) .
C6 C7 1.432(5) .
C7 C8 1.399(5) .
C7 C11 1.404(5) .
C8 C9 1.370(5) .
C8 H8 0.9300 .
C9 C10 1.392(5) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.467(5) .
C13 C14 1.493(5) .
C14 C15 1.392(5) .
C14 C19 1.408(5) .
C15 C16 1.385(5) .
C15 H15 0.9300 .
C16 C17 1.384(5) .
C16 H16 0.9300 .
C17 C18 1.383(5) .
C18 C19 1.385(5) .
C18 H18 0.9300 .
C20 C20 1.536(7) 2_766
O9 H9A 0.84(2) .
O9 H9B 0.84(2) .
O10 H10A 0.85(2) .
O10 H10B 0.84(2) .
O11 H11A 0.87(2) .
O11 H11B 0.84(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O5 Dy1 N1 C1 117.0(3) 2_677 . . .
O2 Dy1 N1 C1 -104.8(3) 2_777 . . .
O8 Dy1 N1 C1 -9.5(4) 2_766 . . .
O7 Dy1 N1 C1 -33.5(3) . . . .
O4 Dy1 N1 C1 -176.6(2) 1_654 . . .
O9 Dy1 N1 C1 45.7(3) . . . .
N2 Dy1 N1 C1 -175.6(3) . . . .
O5 Dy1 N1 C12 -60.7(3) 2_677 . . .
O2 Dy1 N1 C12 77.6(3) 2_777 . . .
O8 Dy1 N1 C12 172.8(2) 2_766 . . .
O7 Dy1 N1 C12 148.8(3) . . . .
O4 Dy1 N1 C12 5.8(4) 1_654 . . .
O9 Dy1 N1 C12 -132.0(3) . . . .
N2 Dy1 N1 C12 6.7(2) . . . .
O5 Dy1 N2 C10 -76.4(3) 2_677 . . .
O2 Dy1 N2 C10 77.4(3) 2_777 . . .
O8 Dy1 N2 C10 24.0(4) 2_766 . . .
O7 Dy1 N2 C10 137.6(3) . . . .
O4 Dy1 N2 C10 1.9(3) 1_654 . . .
O9 Dy1 N2 C10 -124.2(3) . . . .
N1 Dy1 N2 C10 -177.6(3) . . . .
O5 Dy1 N2 C11 90.7(3) 2_677 . . .
O2 Dy1 N2 C11 -115.5(3) 2_777 . . .
O8 Dy1 N2 C11 -168.9(2) 2_766 . . .
O7 Dy1 N2 C11 -55.3(3) . . . .
O4 Dy1 N2 C11 169.0(3) 1_654 . . .
O9 Dy1 N2 C11 42.8(3) . . . .
N1 Dy1 N2 C11 -10.5(2) . . . .
O1 S1 O2 Dy1 14.0(3) . . . 2_777
O3 S1 O2 Dy1 143.7(3) . . . 2_777
C19 S1 O2 Dy1 -101.4(3) . . . 2_777
O6 S2 O4 Dy1 117.5(3) . . . 1_456
O5 S2 O4 Dy1 -9.6(4) . . . 1_456
C17 S2 O4 Dy1 -123.1(3) . . . 1_456
O6 S2 O5 Dy1 13.3(4) . . . 2_677
O4 S2 O5 Dy1 141.3(4) . . . 2_677
C17 S2 O5 Dy1 -103.2(4) . . . 2_677
O5 Dy1 O7 C20 104.5(3) 2_677 . . .
O2 Dy1 O7 C20 -88.5(3) 2_777 . . .
O8 Dy1 O7 C20 5.5(2) 2_766 . . .
O4 Dy1 O7 C20 -35.0(3) 1_654 . . .
O9 Dy1 O7 C20 85.9(3) . . . .
N1 Dy1 O7 C20 168.7(3) . . . .
N2 Dy1 O7 C20 -149.4(2) . . . .
C12 N1 C1 C2 -1.7(6) . . . .
Dy1 N1 C1 C2 -179.4(3) . . . .
N1 C1 C2 C3 2.2(6) . . . .
C1 C2 C3 C4 -0.8(6) . . . .
C2 C3 C4 C12 -1.0(6) . . . .
C2 C3 C4 C5 177.1(4) . . . .
C13 N3 C5 C6 1.3(4) . . . .
C13 N3 C5 C4 -179.3(4) . . . .
C3 C4 C5 C6 -175.6(4) . . . .
C12 C4 C5 C6 2.5(5) . . . .
C3 C4 C5 N3 5.1(6) . . . .
C12 C4 C5 N3 -176.9(3) . . . .
C13 N4 C6 C5 2.3(4) . . . .
C13 N4 C6 C7 -172.6(4) . . . .
N3 C5 C6 N4 -2.2(4) . . . .
C4 C5 C6 N4 178.3(3) . . . .
N3 C5 C6 C7 173.0(3) . . . .
C4 C5 C6 C7 -6.5(6) . . . .
N4 C6 C7 C8 0.2(6) . . . .
C5 C6 C7 C8 -173.9(4) . . . .
N4 C6 C7 C11 177.8(3) . . . .
C5 C6 C7 C11 3.7(5) . . . .
C11 C7 C8 C9 -2.6(6) . . . .
C6 C7 C8 C9 174.9(4) . . . .
C7 C8 C9 C10 1.9(6) . . . .
C11 N2 C10 C9 -0.8(6) . . . .
Dy1 N2 C10 C9 166.3(3) . . . .
C8 C9 C10 N2 -0.2(6) . . . .
C10 N2 C11 C7 0.1(5) . . . .
Dy1 N2 C11 C7 -167.5(2) . . . .
C10 N2 C11 C12 -178.9(3) . . . .
Dy1 N2 C11 C12 13.5(4) . . . .
C8 C7 C11 N2 1.6(5) . . . .
C6 C7 C11 N2 -176.1(3) . . . .
C8 C7 C11 C12 -179.4(3) . . . .
C6 C7 C11 C12 2.8(5) . . . .
C1 N1 C12 C4 -0.3(5) . . . .
Dy1 N1 C12 C4 177.5(3) . . . .
C1 N1 C12 C11 179.4(3) . . . .
Dy1 N1 C12 C11 -2.8(4) . . . .
C3 C4 C12 N1 1.5(5) . . . .
C5 C4 C12 N1 -176.6(3) . . . .
C3 C4 C12 C11 -178.1(3) . . . .
C5 C4 C12 C11 3.7(5) . . . .
N2 C11 C12 N1 -7.2(5) . . . .
C7 C11 C12 N1 173.9(3) . . . .
N2 C11 C12 C4 172.5(3) . . . .
C7 C11 C12 C4 -6.5(5) . . . .
C5 N3 C13 N4 0.2(4) . . . .
C5 N3 C13 C14 -179.4(3) . . . .
C6 N4 C13 N3 -1.6(4) . . . .
C6 N4 C13 C14 178.0(3) . . . .
N3 C13 C14 C15 -8.7(5) . . . .
N4 C13 C14 C15 171.8(4) . . . .
N3 C13 C14 C19 170.6(4) . . . .
N4 C13 C14 C19 -9.0(6) . . . .
C19 C14 C15 C16 1.4(6) . . . .
C13 C14 C15 C16 -179.3(3) . . . .
C14 C15 C16 C17 -1.2(6) . . . .
C15 C16 C17 C18 0.4(6) . . . .
C15 C16 C17 S2 174.5(3) . . . .
O6 S2 C17 C18 -28.9(3) . . . .
O4 S2 C17 C18 -151.9(3) . . . .
O5 S2 C17 C18 90.5(3) . . . .
O6 S2 C17 C16 156.9(3) . . . .
O4 S2 C17 C16 33.9(4) . . . .
O5 S2 C17 C16 -83.7(3) . . . .
C16 C17 C18 C19 0.2(5) . . . .
S2 C17 C18 C19 -174.1(3) . . . .
C17 C18 C19 C14 0.0(5) . . . .
C17 C18 C19 S1 -179.5(3) . . . .
C15 C14 C19 C18 -0.7(5) . . . .
C13 C14 C19 C18 180.0(3) . . . .
C15 C14 C19 S1 178.7(3) . . . .
C13 C14 C19 S1 -0.6(5) . . . .
O1 S1 C19 C18 0.1(3) . . . .
O3 S1 C19 C18 -123.1(3) . . . .
O2 S1 C19 C18 119.6(3) . . . .
O1 S1 C19 C14 -179.3(3) . . . .
O3 S1 C19 C14 57.5(3) . . . .
O2 S1 C19 C14 -59.8(3) . . . .
Dy1 O8 C20 O7 174.9(3) 2_766 . . .
Dy1 O8 C20 C20 -5.6(5) 2_766 . . 2_766
Dy1 O7 C20 O8 174.7(3) . . . .
Dy1 O7 C20 C20 -4.8(5) . . . 2_766
