#------------------------------------------------------------------------------
#$Date: 2016-02-21 02:03:34 +0200 (Sun, 21 Feb 2016) $
#$Revision: 176798 $
#$URL: svn://www.crystallography.net/cod/cif/2/23/85/2238569.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2238569
loop_
_publ_author_name
'Suresh, J.'
'Nagalakshmi, R. A.'
'Malathi, K.'
'Kumar, R. R.'
'Lakshman, P. L. N.'
_publ_section_title
;
 1',1''-Dimethyl-4'-phenyldispiro[11H-indeno[1,2-b]quinoxaline-11,2'-pyrrolidine-3',3''-piperidin]-4''-one
;
_journal_coeditor_code           TK5246
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o1433
_journal_paper_doi               10.1107/S160053681302223X
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          'C30 H28 N4 O'
_chemical_formula_moiety         'C30 H28 N4 O'
_chemical_formula_sum            'C30 H28 N4 O'
_chemical_formula_weight         460.56
_chemical_name_systematic
1',1''-Dimethyl-4'-phenyldispiro[11H-indeno[1,2-b]quinoxaline-11,2'-pyrrolidine-3',3''-piperidin]-4''-one
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.195(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.4470(6)
_cell_length_b                   8.4557(4)
_cell_length_c                   20.8580(9)
_cell_measurement_reflns_used    2000
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      31
_cell_measurement_theta_min      2
_cell_volume                     2371.62(19)
_computing_cell_refinement       'SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT (Bruker, 2004)'
_computing_molecular_graphics    'PLATON (Spek, 2009)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker Kappa APEXII'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0317
_diffrn_reflns_av_sigmaI/netI    0.0326
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            28395
_diffrn_reflns_theta_full        29.65
_diffrn_reflns_theta_max         29.65
_diffrn_reflns_theta_min         2.47
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.080
_exptl_absorpt_correction_T_max  0.974
_exptl_absorpt_correction_T_min  0.967
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.290
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             976
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.194
_refine_diff_density_min         -0.230
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         6662
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0829
_refine_ls_R_factor_gt           0.0501
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0621P)²+0.3850P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1195
_refine_ls_wR_factor_ref         0.1382
_reflns_number_gt                4394
_reflns_number_total             6662
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            tk5246.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2238569
_cod_database_fobs_code          2238569
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
C C1 0.36237(14) 0.57618(18) 0.06530(9) 0.0608(4) Uani d . 1 1
H H1A 0.3764 0.5501 0.1092 0.091 Uiso calc R 1 1
H H1B 0.4125 0.5310 0.0383 0.091 Uiso calc R 1 1
H H1C 0.2985 0.5346 0.0535 0.091 Uiso calc R 1 1
C C2 0.34240(11) 0.80537(17) -0.00602(7) 0.0444(3) Uani d . 1 1
H H2A 0.2771 0.7738 -0.0212 0.053 Uiso calc R 1 1
H H2B 0.3924 0.7701 -0.0362 0.053 Uiso calc R 1 1
C C3 0.34818(10) 0.98182(15) 0.00505(6) 0.0367(3) Uani d . 1 1
H H3 0.4176 1.0048 0.0159 0.044 Uiso calc R 1 1
C C4 0.28798(9) 1.00430(14) 0.06781(6) 0.0329(3) Uani d . 1 1
C C5 0.30193(10) 0.83818(15) 0.10348(6) 0.0355(3) Uani d . 1 1
C C6 0.35593(10) 0.84200(15) 0.16788(6) 0.0393(3) Uani d . 1 1
C C7 0.30027(11) 0.77358(16) 0.21664(6) 0.0408(3) Uani d . 1 1
C C8 0.33822(13) 0.75968(19) 0.27843(7) 0.0529(4) Uani d . 1 1
H H8 0.3010 0.7129 0.3108 0.063 Uiso calc R 1 1
C C9 0.43177(13) 0.8165(2) 0.29050(8) 0.0597(4) Uani d . 1 1
H H9 0.4581 0.8091 0.3317 0.072 Uiso calc R 1 1
C C10 0.48776(13) 0.8847(2) 0.24228(8) 0.0584(4) Uani d . 1 1
H H10 0.5509 0.9232 0.2516 0.070 Uiso calc R 1 1
C C11 0.45123(11) 0.89637(18) 0.18041(8) 0.0491(4) Uani d . 1 1
H H11 0.4898 0.9398 0.1479 0.059 Uiso calc R 1 1
C C12 0.20533(10) 0.75594(14) 0.12273(6) 0.0363(3) Uani d . 1 1
C C13 0.20671(10) 0.71782(15) 0.18953(6) 0.0392(3) Uani d . 1 1
C C14 0.05869(11) 0.59550(16) 0.17986(7) 0.0458(3) Uani d . 1 1
C C15 0.05754(11) 0.63118(16) 0.11364(7) 0.0431(3) Uani d . 1 1
C C16 -0.02353(12) 0.58276(19) 0.07619(9) 0.0541(4) Uani d . 1 1
H H16 -0.0262 0.6090 0.0329 0.065 Uiso calc R 1 1
C C17 -0.09862(13) 0.4972(2) 0.10312(10) 0.0672(5) Uani d . 1 1
H H17 -0.1520 0.4645 0.0779 0.081 Uiso calc R 1 1
C C18 -0.09591(14) 0.4583(2) 0.16794(11) 0.0701(5) Uani d . 1 1
H H18 -0.1470 0.3981 0.1854 0.084 Uiso calc R 1 1
C C19 -0.02015(13) 0.5068(2) 0.20580(9) 0.0600(4) Uani d . 1 1
H H19 -0.0200 0.4815 0.2492 0.072 Uiso calc R 1 1
C C31 0.32246(11) 1.08677(18) -0.05113(6) 0.0436(3) Uani d . 1 1
C C32 0.25500(13) 1.0445(2) -0.09802(7) 0.0615(4) Uani d . 1 1
H H32 0.2198 0.9503 -0.0943 0.074 Uiso calc R 1 1
C C33 0.23919(18) 1.1419(3) -0.15091(9) 0.0826(7) Uani d . 1 1
H H33 0.1942 1.1119 -0.1826 0.099 Uiso calc R 1 1
C C34 0.2896(2) 1.2812(3) -0.15630(9) 0.0873(7) Uani d . 1 1
H H34 0.2787 1.3462 -0.1916 0.105 Uiso calc R 1 1
C C35 0.35562(18) 1.3253(3) -0.11021(10) 0.0787(6) Uani d . 1 1
H H35 0.3894 1.4209 -0.1138 0.094 Uiso calc R 1 1
C C36 0.37261(13) 1.2288(2) -0.05827(8) 0.0594(4) Uani d . 1 1
H H36 0.4187 1.2594 -0.0273 0.071 Uiso calc R 1 1
C C41 0.17892(10) 1.04422(16) 0.05398(6) 0.0379(3) Uani d . 1 1
H H41A 0.1758 1.1387 0.0277 0.045 Uiso calc R 1 1
H H41B 0.1490 0.9583 0.0299 0.045 Uiso calc R 1 1
C C42 0.01616(12) 1.0763(2) 0.09830(9) 0.0662(5) Uani d . 1 1
H H42A -0.0039 0.9799 0.0777 0.099 Uiso calc R 1 1
H H42B 0.0028 1.1641 0.0704 0.099 Uiso calc R 1 1
H H42C -0.0203 1.0891 0.1375 0.099 Uiso calc R 1 1
C C43 0.15684(14) 1.21341(18) 0.14362(8) 0.0576(4) Uani d U 1 1
H H43A 0.1172 1.2339 0.1815 0.069 Uiso calc R 1 1
H H43B 0.1493 1.3024 0.1147 0.069 Uiso calc R 1 1
C C44 0.26476(14) 1.19575(19) 0.16236(7) 0.0571(4) Uani d . 1 1
H H44A 0.2894 1.2966 0.1779 0.069 Uiso calc R 1 1
H H44B 0.2700 1.1201 0.1972 0.069 Uiso calc R 1 1
C C45 0.32857(11) 1.14165(16) 0.10784(6) 0.0419(3) Uani d . 1 1
N N1 0.36204(9) 0.74661(13) 0.05769(6) 0.0422(3) Uani d . 1 1
N N2 0.12222(9) 1.07001(14) 0.11253(5) 0.0457(3) Uani d U 1 1
N N3 0.13447(9) 0.71125(13) 0.08434(5) 0.0408(3) Uani d . 1 1
N N4 0.13632(9) 0.63976(14) 0.21868(6) 0.0469(3) Uani d . 1 1
O O1 0.40639(9) 1.20595(13) 0.09512(5) 0.0567(3) Uani d . 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 C1 H1A 109.5
N1 C1 H1B 109.5
H1A C1 H1B 109.5
N1 C1 H1C 109.5
H1A C1 H1C 109.5
H1B C1 H1C 109.5
N1 C2 C3 100.96(11)
N1 C2 H2A 111.6
C3 C2 H2A 111.6
N1 C2 H2B 111.6
C3 C2 H2B 111.6
H2A C2 H2B 109.4
C31 C3 C2 116.76(11)
C31 C3 C4 117.63(11)
C2 C3 C4 102.87(10)
C31 C3 H3 106.2
C2 C3 H3 106.2
C4 C3 H3 106.2
C45 C4 C41 105.97(10)
C45 C4 C3 111.52(11)
C41 C4 C3 111.71(10)
C45 C4 C5 111.80(10)
C41 C4 C5 113.06(10)
C3 C4 C5 102.93(9)
N1 C5 C6 108.76(10)
N1 C5 C12 113.57(11)
C6 C5 C12 100.41(10)
N1 C5 C4 102.92(10)
C6 C5 C4 116.47(10)
C12 C5 C4 115.03(10)
C11 C6 C7 119.99(13)
C11 C6 C5 127.61(13)
C7 C6 C5 112.30(12)
C8 C7 C6 121.10(14)
C8 C7 C13 130.31(14)
C6 C7 C13 108.49(11)
C9 C8 C7 118.38(16)
C9 C8 H8 120.8
C7 C8 H8 120.8
C8 C9 C10 120.94(14)
C8 C9 H9 119.5
C10 C9 H9 119.5
C11 C10 C9 121.03(16)
C11 C10 H10 119.5
C9 C10 H10 119.5
C10 C11 C6 118.53(15)
C10 C11 H11 120.7
C6 C11 H11 120.7
N3 C12 C13 122.84(13)
N3 C12 C5 126.36(12)
C13 C12 C5 110.50(11)
N4 C13 C12 124.08(13)
N4 C13 C7 127.56(13)
C12 C13 C7 108.29(12)
N4 C14 C19 119.42(15)
N4 C14 C15 121.63(13)
C19 C14 C15 118.90(15)
N3 C15 C16 118.66(14)
N3 C15 C14 122.10(13)
C16 C15 C14 119.24(14)
C17 C16 C15 120.08(17)
C17 C16 H16 120.0
C15 C16 H16 120.0
C16 C17 C18 120.53(17)
C16 C17 H17 119.7
C18 C17 H17 119.7
C19 C18 C17 120.90(17)
C19 C18 H18 119.5
C17 C18 H18 119.5
C18 C19 C14 120.29(17)
C18 C19 H19 119.9
C14 C19 H19 119.9
C32 C31 C36 117.89(15)
C32 C31 C3 123.14(14)
C36 C31 C3 118.87(13)
C31 C32 C33 120.5(2)
C31 C32 H32 119.8
C33 C32 H32 119.8
C34 C33 C32 120.1(2)
C34 C33 H33 119.9
C32 C33 H33 119.9
C35 C34 C33 120.16(18)
C35 C34 H34 119.9
C33 C34 H34 119.9
C34 C35 C36 120.1(2)
C34 C35 H35 120.0
C36 C35 H35 120.0
C35 C36 C31 121.31(19)
C35 C36 H36 119.3
C31 C36 H36 119.3
N2 C41 C4 112.24(10)
N2 C41 H41A 109.2
C4 C41 H41A 109.2
N2 C41 H41B 109.2
C4 C41 H41B 109.2
H41A C41 H41B 107.9
N2 C42 H42A 109.5
N2 C42 H42B 109.5
H42A C42 H42B 109.5
N2 C42 H42C 109.5
H42A C42 H42C 109.5
H42B C42 H42C 109.5
N2 C43 C44 109.87(12)
N2 C43 H43A 109.7
C44 C43 H43A 109.7
N2 C43 H43B 109.7
C44 C43 H43B 109.7
H43A C43 H43B 108.2
C45 C44 C43 112.72(12)
C45 C44 H44A 109.0
C43 C44 H44A 109.0
C45 C44 H44B 109.0
C43 C44 H44B 109.0
H44A C44 H44B 107.8
O1 C45 C44 121.83(13)
O1 C45 C4 121.92(13)
C44 C45 C4 116.22(13)
C2 N1 C1 116.35(12)
C2 N1 C5 108.49(10)
C1 N1 C5 116.94(12)
C43 N2 C42 111.90(13)
C43 N2 C41 109.35(12)
C42 N2 C41 110.44(12)
C12 N3 C15 114.77(12)
C13 N4 C14 114.51(12)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 N1 1.4499(18)
C1 H1A 0.9600
C1 H1B 0.9600
C1 H1C 0.9600
C2 N1 1.4423(18)
C2 C3 1.5117(19)
C2 H2A 0.9700
C2 H2B 0.9700
C3 C31 1.5091(18)
C3 C4 1.5531(17)
C3 H3 0.9800
C4 C45 1.5301(18)
C4 C41 1.5312(18)
C4 C5 1.6003(17)
C5 N1 1.4731(17)
C5 C6 1.5252(18)
C5 C12 1.5284(19)
C6 C11 1.386(2)
C6 C7 1.3908(19)
C7 C8 1.389(2)
C7 C13 1.456(2)
C8 C9 1.369(2)
C8 H8 0.9300
C9 C10 1.384(3)
C9 H9 0.9300
C10 C11 1.383(2)
C10 H10 0.9300
C11 H11 0.9300
C12 N3 1.2986(17)
C12 C13 1.4302(19)
C13 N4 1.3058(18)
C14 N4 1.371(2)
C14 C19 1.408(2)
C14 C15 1.414(2)
C15 N3 1.3807(18)
C15 C16 1.400(2)
C16 C17 1.365(2)
C16 H16 0.9300
C17 C18 1.392(3)
C17 H17 0.9300
C18 C19 1.351(3)
C18 H18 0.9300
C19 H19 0.9300
C31 C32 1.379(2)
C31 C36 1.385(2)
C32 C33 1.393(3)
C32 H32 0.9300
C33 C34 1.364(3)
C33 H33 0.9300
C34 C35 1.359(3)
C34 H34 0.9300
C35 C36 1.375(2)
C35 H35 0.9300
C36 H36 0.9300
C41 N2 1.4582(17)
C41 H41A 0.9700
C41 H41B 0.9700
C42 N2 1.457(2)
C42 H42A 0.9600
C42 H42B 0.9600
C42 H42C 0.9600
C43 N2 1.451(2)
C43 C44 1.509(2)
C43 H43A 0.9700
C43 H43B 0.9700
C44 C45 1.498(2)
C44 H44A 0.9700
C44 H44B 0.9700
C45 O1 1.2095(18)
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C41 H41B N3 . 0.97 2.39 2.9475(18) 116.3
C9 H9 O1 2_645 0.93 2.53 3.3564(18) 148.4
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C2 C3 C31 -174.91(11)
N1 C2 C3 C4 -44.52(13)
C31 C3 C4 C45 -82.17(14)
C2 C3 C4 C45 147.97(11)
C31 C3 C4 C41 36.21(16)
C2 C3 C4 C41 -93.65(12)
C31 C3 C4 C5 157.82(11)
C2 C3 C4 C5 27.95(12)
C45 C4 C5 N1 -121.60(11)
C41 C4 C5 N1 118.90(11)
C3 C4 C5 N1 -1.78(12)
C45 C4 C5 C6 -2.74(15)
C41 C4 C5 C6 -122.24(12)
C3 C4 C5 C6 117.08(12)
C45 C4 C5 C12 114.35(13)
C41 C4 C5 C12 -5.15(14)
C3 C4 C5 C12 -125.83(11)
N1 C5 C6 C11 56.97(17)
C12 C5 C6 C11 176.43(13)
C4 C5 C6 C11 -58.68(18)
N1 C5 C6 C7 -119.49(12)
C12 C5 C6 C7 -0.03(13)
C4 C5 C6 C7 124.86(12)
C11 C6 C7 C8 0.6(2)
C5 C6 C7 C8 177.34(12)
C11 C6 C7 C13 -176.19(12)
C5 C6 C7 C13 0.57(15)
C6 C7 C8 C9 0.6(2)
C13 C7 C8 C9 176.60(14)
C7 C8 C9 C10 -0.7(2)
C8 C9 C10 C11 -0.5(3)
C9 C10 C11 C6 1.7(2)
C7 C6 C11 C10 -1.7(2)
C5 C6 C11 C10 -177.93(13)
N1 C5 C12 N3 -58.40(17)
C6 C5 C12 N3 -174.31(12)
C4 C5 C12 N3 59.83(17)
N1 C5 C12 C13 115.36(12)
C6 C5 C12 C13 -0.54(13)
C4 C5 C12 C13 -126.41(11)
N3 C12 C13 N4 -2.3(2)
C5 C12 C13 N4 -176.31(12)
N3 C12 C13 C7 174.93(12)
C5 C12 C13 C7 0.91(14)
C8 C7 C13 N4 -0.2(2)
C6 C7 C13 N4 176.18(13)
C8 C7 C13 C12 -177.28(14)
C6 C7 C13 C12 -0.91(15)
N4 C14 C15 N3 0.5(2)
C19 C14 C15 N3 -176.95(13)
N4 C14 C15 C16 179.83(13)
C19 C14 C15 C16 2.4(2)
N3 C15 C16 C17 177.03(14)
C14 C15 C16 C17 -2.4(2)
C15 C16 C17 C18 0.5(3)
C16 C17 C18 C19 1.3(3)
C17 C18 C19 C14 -1.2(3)
N4 C14 C19 C18 -178.14(15)
C15 C14 C19 C18 -0.7(2)
C2 C3 C31 C32 30.6(2)
C4 C3 C31 C32 -92.51(16)
C2 C3 C31 C36 -145.75(14)
C4 C3 C31 C36 91.18(16)
C36 C31 C32 C33 0.6(2)
C3 C31 C32 C33 -175.77(15)
C31 C32 C33 C34 -0.9(3)
C32 C33 C34 C35 0.2(3)
C33 C34 C35 C36 0.6(3)
C34 C35 C36 C31 -0.9(3)
C32 C31 C36 C35 0.3(2)
C3 C31 C36 C35 176.80(15)
C45 C4 C41 N2 -56.74(14)
C3 C4 C41 N2 -178.38(11)
C5 C4 C41 N2 66.07(13)
N2 C43 C44 C45 51.34(18)
C43 C44 C45 O1 132.24(15)
C43 C44 C45 C4 -45.70(17)
C41 C4 C45 O1 -131.69(13)
C3 C4 C45 O1 -9.93(17)
C5 C4 C45 O1 104.71(14)
C41 C4 C45 C44 46.25(14)
C3 C4 C45 C44 168.01(11)
C5 C4 C45 C44 -77.35(14)
C3 C2 N1 C1 -179.96(13)
C3 C2 N1 C5 45.72(14)
C6 C5 N1 C2 -151.26(11)
C12 C5 N1 C2 97.86(13)
C4 C5 N1 C2 -27.15(13)
C6 C5 N1 C1 74.73(16)
C12 C5 N1 C1 -36.15(17)
C4 C5 N1 C1 -161.16(13)
C44 C43 N2 C42 175.24(13)
C44 C43 N2 C41 -62.07(16)
C4 C41 N2 C43 67.73(14)
C4 C41 N2 C42 -168.72(12)
C13 C12 N3 C15 3.36(18)
C5 C12 N3 C15 176.41(12)
C16 C15 N3 C12 178.09(13)
C14 C15 N3 C12 -2.53(19)
C12 C13 N4 C14 -0.02(19)
C7 C13 N4 C14 -176.69(13)
C19 C14 N4 C13 178.22(13)
C15 C14 N4 C13 0.82(19)
