#------------------------------------------------------------------------------
#$Date: 2016-03-21 01:21:50 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178377 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/10/4001040.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001040
loop_
_publ_author_name
'Goforth, Andrea M.'
'Hope, Håkon'
'Condron, Cathie L.'
'Kauzlarich, Susan M.'
'Jensen, Newell'
'Klavins, Peter'
'MaQuilon, Samuel'
'Fisk, Zachary'
_publ_section_title
;
 Magnetism and Negative Magnetoresistance of Two Magnetically Ordering,
 Rare-Earth-Containing Zintl phases with a New Structure Type: EuGa2Pn2(Pn
 = P, As)
;
_journal_issue                   19
_journal_name_full               'Chemistry of Materials'
_journal_page_first              4480
_journal_paper_doi               10.1021/cm901219u
_journal_volume                  21
_journal_year                    2009
_chemical_formula_sum            'Eu Ga2 P2'
_chemical_formula_weight         353.34
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           10
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2y'
_symmetry_space_group_name_H-M   'P 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.5220(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.2822(9)
_cell_length_b                   3.8967(4)
_cell_length_c                   12.0777(11)
_cell_measurement_temperature    100(1)
_cell_volume                     434.82(7)
_computing_cell_refinement       'Bruker Apex2'
_computing_data_collection       'Bruker Apex2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(1)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART APEX2'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0267
_diffrn_reflns_av_sigmaI/netI    0.0175
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            6586
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.65
_exptl_absorpt_coefficient_mu    27.064
_exptl_absorpt_correction_T_max  0.34
_exptl_absorpt_correction_T_min  0.09
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (multi-scan)'
_exptl_crystal_colour            'metallic silver'
_exptl_crystal_density_diffrn    5.398
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelpiped
_exptl_crystal_F_000             620
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.145
_refine_diff_density_min         -0.839
_refine_diff_density_rms         0.198
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.197
_refine_ls_matrix_type           full
_refine_ls_number_parameters     66
_refine_ls_number_reflns         1134
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.197
_refine_ls_R_factor_all          0.0159
_refine_ls_R_factor_gt           0.0148
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0130P)²+0.3900P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0325
_refine_ls_wR_factor_ref         0.0327
_reflns_number_gt                1096
_reflns_number_total             1134
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm901219u_si_001.cif
_cod_data_source_block           hh461p
_cod_database_code               4001040
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'-x, -y, -z'
'x, -y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.19443(2) 0.0000 0.279942(18) 0.00795(7) Uani 1 2 d S
Eu2 Eu 0.5000 0.5000 0.5000 0.00703(8) Uani 1 4 d S
Eu3 Eu 0.0000 0.5000 0.0000 0.00688(8) Uani 1 4 d S
Ga1 Ga -0.11199(5) 0.5000 0.43422(4) 0.00695(10) Uani 1 2 d S
Ga2 Ga 0.59696(5) 0.0000 0.27925(4) 0.00697(11) Uani 0.9820(6) 2 d SP
Ga3 Ga -0.19756(5) 0.0000 0.17222(4) 0.00710(11) Uani 0.9820(6) 2 d SP
Ga4 Ga 0.39558(5) 0.5000 0.05613(4) 0.00713(10) Uani 1 2 d S
P1 P -0.05576(12) 0.5000 0.23984(9) 0.0072(2) Uani 1 2 d S
P2 P 0.44202(12) 0.5000 0.25642(9) 0.0070(2) Uani 1 2 d S
P3 P 0.26386(12) 0.0000 0.53723(9) 0.0075(2) Uani 1 2 d S
P4 P 0.23966(12) 0.0000 0.02717(9) 0.0074(2) Uani 1 2 d S
Eu4P Eu -0.3050(12) 0.0000 0.2194(10) 0.008 Uiso 0.0180(6) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Eu1 P1 79.90(3) 1_545 .
P1 Eu1 P2 165.52(3) 1_545 .
P1 Eu1 P2 98.46(2) . .
P1 Eu1 P2 98.46(2) 1_545 1_545
P1 Eu1 P2 165.52(3) . 1_545
P2 Eu1 P2 79.50(3) . 1_545
P1 Eu1 P3 103.95(3) 1_545 .
P1 Eu1 P3 103.95(3) . .
P2 Eu1 P3 90.43(3) . .
P2 Eu1 P3 90.43(3) 1_545 .
P1 Eu1 P4 90.96(3) 1_545 .
P1 Eu1 P4 90.96(3) . .
P2 Eu1 P4 74.64(3) . .
P2 Eu1 P4 74.64(3) 1_545 .
P3 Eu1 P4 160.41(3) . .
P1 Eu1 Ga2 138.558(14) 1_545 .
P1 Eu1 Ga2 138.559(15) . .
P2 Eu1 Ga2 40.232(14) . .
P2 Eu1 Ga2 40.232(14) 1_545 .
P3 Eu1 Ga2 83.75(2) . .
P4 Eu1 Ga2 76.66(2) . .
P1 Eu1 Ga3 40.654(15) 1_545 .
P1 Eu1 Ga3 40.654(15) . .
P2 Eu1 Ga3 133.159(18) . .
P2 Eu1 Ga3 133.160(18) 1_545 .
P3 Eu1 Ga3 116.61(2) . .
P4 Eu1 Ga3 82.98(2) . .
Ga2 Eu1 Ga3 159.638(12) . .
P1 Eu1 Eu1 129.948(14) 1_545 1_565
P1 Eu1 Eu1 50.053(14) . 1_565
P2 Eu1 Eu1 50.250(14) . 1_565
P2 Eu1 Eu1 129.749(14) 1_545 1_565
P3 Eu1 Eu1 90.0 . 1_565
P4 Eu1 Eu1 90.0 . 1_565
Ga2 Eu1 Eu1 90.0 . 1_565
Ga3 Eu1 Eu1 90.0 . 1_565
P1 Eu1 Eu1 50.053(14) 1_545 1_545
P1 Eu1 Eu1 129.948(14) . 1_545
P2 Eu1 Eu1 129.750(13) . 1_545
P2 Eu1 Eu1 50.251(14) 1_545 1_545
P3 Eu1 Eu1 90.0 . 1_545
P4 Eu1 Eu1 90.0 . 1_545
Ga2 Eu1 Eu1 90.0 . 1_545
Ga3 Eu1 Eu1 90.0 . 1_545
Eu1 Eu1 Eu1 180.0 1_565 1_545
P1 Eu1 Eu3 45.90(2) 1_545 1_545
P1 Eu1 Eu3 84.577(19) . 1_545
P2 Eu1 Eu3 119.72(2) . 1_545
P2 Eu1 Eu3 84.08(2) 1_545 1_545
P3 Eu1 Eu3 147.495(11) . 1_545
P4 Eu1 Eu3 45.077(16) . 1_545
Ga2 Eu1 Eu3 110.718(8) . 1_545
Ga3 Eu1 Eu3 52.165(6) . 1_545
Eu1 Eu1 Eu3 117.924(3) 1_565 1_545
Eu1 Eu1 Eu3 62.078(3) 1_545 1_545
P1 Eu1 Eu3 84.576(19) 1_545 .
P1 Eu1 Eu3 45.90(2) . .
P2 Eu1 Eu3 84.08(2) . .
P2 Eu1 Eu3 119.72(2) 1_545 .
P3 Eu1 Eu3 147.495(10) . .
P4 Eu1 Eu3 45.077(16) . .
Ga2 Eu1 Eu3 110.718(8) . .
Ga3 Eu1 Eu3 52.165(6) . .
Eu1 Eu1 Eu3 62.078(3) 1_565 .
Eu1 Eu1 Eu3 117.924(3) 1_545 .
Eu3 Eu1 Eu3 55.846(7) 1_545 .
P2 Eu2 P2 180.0 3_666 .
P2 Eu2 P3 94.82(3) 3_666 3_666
P2 Eu2 P3 85.18(3) . 3_666
P2 Eu2 P3 94.82(3) 3_666 3_656
P2 Eu2 P3 85.18(3) . 3_656
P3 Eu2 P3 81.04(3) 3_666 3_656
P2 Eu2 P3 85.18(3) 3_666 1_565
P2 Eu2 P3 94.82(3) . 1_565
P3 Eu2 P3 98.96(3) 3_666 1_565
P3 Eu2 P3 180.0 3_656 1_565
P2 Eu2 P3 85.18(3) 3_666 .
P2 Eu2 P3 94.82(3) . .
P3 Eu2 P3 180.0 3_666 .
P3 Eu2 P3 98.96(3) 3_656 .
P3 Eu2 P3 81.04(3) 1_565 .
P2 Eu2 Ga2 136.793(14) 3_666 .
P2 Eu2 Ga2 43.207(14) . .
P3 Eu2 Ga2 90.127(19) 3_666 .
P3 Eu2 Ga2 43.67(2) 3_656 .
P3 Eu2 Ga2 136.33(2) 1_565 .
P3 Eu2 Ga2 89.873(19) . .
P2 Eu2 Ga2 43.207(14) 3_666 3_666
P2 Eu2 Ga2 136.793(14) . 3_666
P3 Eu2 Ga2 89.873(19) 3_666 3_666
P3 Eu2 Ga2 136.33(2) 3_656 3_666
P3 Eu2 Ga2 43.67(2) 1_565 3_666
P3 Eu2 Ga2 90.127(19) . 3_666
Ga2 Eu2 Ga2 180.0 . 3_666
P2 Eu2 Ga2 43.207(14) 3_666 3_656
P2 Eu2 Ga2 136.793(14) . 3_656
P3 Eu2 Ga2 136.33(2) 3_666 3_656
P3 Eu2 Ga2 89.873(19) 3_656 3_656
P3 Eu2 Ga2 90.127(19) 1_565 3_656
P3 Eu2 Ga2 43.67(2) . 3_656
Ga2 Eu2 Ga2 112.117(11) . 3_656
Ga2 Eu2 Ga2 67.883(11) 3_666 3_656
P2 Eu2 Ga2 136.793(14) 3_666 1_565
P2 Eu2 Ga2 43.207(14) . 1_565
P3 Eu2 Ga2 43.67(2) 3_666 1_565
P3 Eu2 Ga2 90.127(19) 3_656 1_565
P3 Eu2 Ga2 89.873(19) 1_565 1_565
P3 Eu2 Ga2 136.33(2) . 1_565
Ga2 Eu2 Ga2 67.883(11) . 1_565
Ga2 Eu2 Ga2 112.117(11) 3_666 1_565
Ga2 Eu2 Ga2 180.0 3_656 1_565
P2 Eu2 Eu2 90.0 3_666 1_545
P2 Eu2 Eu2 90.0 . 1_545
P3 Eu2 Eu2 130.521(14) 3_666 1_545
P3 Eu2 Eu2 49.479(14) 3_656 1_545
P3 Eu2 Eu2 130.521(14) 1_565 1_545
P3 Eu2 Eu2 49.479(14) . 1_545
Ga2 Eu2 Eu2 56.058(5) . 1_545
Ga2 Eu2 Eu2 123.942(5) 3_666 1_545
Ga2 Eu2 Eu2 56.059(5) 3_656 1_545
Ga2 Eu2 Eu2 123.941(5) 1_565 1_545
P2 Eu2 Eu2 90.0 3_666 1_565
P2 Eu2 Eu2 90.0 . 1_565
P3 Eu2 Eu2 49.479(14) 3_666 1_565
P3 Eu2 Eu2 130.521(14) 3_656 1_565
P3 Eu2 Eu2 49.479(14) 1_565 1_565
P3 Eu2 Eu2 130.521(14) . 1_565
Ga2 Eu2 Eu2 123.942(5) . 1_565
Ga2 Eu2 Eu2 56.058(5) 3_666 1_565
Ga2 Eu2 Eu2 123.941(5) 3_656 1_565
Ga2 Eu2 Eu2 56.059(5) 1_565 1_565
Eu2 Eu2 Eu2 180.0 1_545 1_565
P4 Eu3 P4 180.0 3 1_565
P4 Eu3 P4 82.61(3) 3 3_565
P4 Eu3 P4 97.39(3) 1_565 3_565
P4 Eu3 P4 97.39(3) 3 .
P4 Eu3 P4 82.61(3) 1_565 .
P4 Eu3 P4 180.0 3_565 .
P4 Eu3 P1 95.23(3) 3 3_565
P4 Eu3 P1 84.77(3) 1_565 3_565
P4 Eu3 P1 95.23(3) 3_565 3_565
P4 Eu3 P1 84.77(3) . 3_565
P4 Eu3 P1 84.77(3) 3 .
P4 Eu3 P1 95.23(3) 1_565 .
P4 Eu3 P1 84.77(3) 3_565 .
P4 Eu3 P1 95.23(3) . .
P1 Eu3 P1 180.0 3_565 .
P4 Eu3 Ga3 137.28(2) 3 3_565
P4 Eu3 Ga3 42.72(2) 1_565 3_565
P4 Eu3 Ga3 89.934(19) 3_565 3_565
P4 Eu3 Ga3 90.065(19) . 3_565
P1 Eu3 Ga3 43.464(14) 3_565 3_565
P1 Eu3 Ga3 136.536(14) . 3_565
P4 Eu3 Ga3 89.934(19) 3 3
P4 Eu3 Ga3 90.066(19) 1_565 3
P4 Eu3 Ga3 137.28(2) 3_565 3
P4 Eu3 Ga3 42.72(2) . 3
P1 Eu3 Ga3 43.464(14) 3_565 3
P1 Eu3 Ga3 136.536(14) . 3
Ga3 Eu3 Ga3 67.747(10) 3_565 3
P4 Eu3 Ga3 90.066(19) 3 1_565
P4 Eu3 Ga3 89.934(19) 1_565 1_565
P4 Eu3 Ga3 42.72(2) 3_565 1_565
P4 Eu3 Ga3 137.28(2) . 1_565
P1 Eu3 Ga3 136.536(14) 3_565 1_565
P1 Eu3 Ga3 43.464(14) . 1_565
Ga3 Eu3 Ga3 112.253(10) 3_565 1_565
Ga3 Eu3 Ga3 180.000(12) 3 1_565
P4 Eu3 Ga3 42.72(2) 3 .
P4 Eu3 Ga3 137.28(2) 1_565 .
P4 Eu3 Ga3 90.066(19) 3_565 .
P4 Eu3 Ga3 89.935(19) . .
P1 Eu3 Ga3 136.536(14) 3_565 .
P1 Eu3 Ga3 43.464(14) . .
Ga3 Eu3 Ga3 180.000(12) 3_565 .
Ga3 Eu3 Ga3 112.253(10) 3 .
Ga3 Eu3 Ga3 67.747(10) 1_565 .
P4 Eu3 Ga4 41.352(15) 3 3_565
P4 Eu3 Ga4 138.648(15) 1_565 3_565
P4 Eu3 Ga4 41.352(15) 3_565 3_565
P4 Eu3 Ga4 138.648(15) . 3_565
P1 Eu3 Ga4 94.84(2) 3_565 3_565
P1 Eu3 Ga4 85.16(2) . 3_565
Ga3 Eu3 Ga4 117.581(10) 3_565 3_565
Ga3 Eu3 Ga4 117.581(10) 3 3_565
Ga3 Eu3 Ga4 62.419(10) 1_565 3_565
Ga3 Eu3 Ga4 62.418(10) . 3_565
P4 Eu3 Ga4 138.648(15) 3 .
P4 Eu3 Ga4 41.352(15) 1_565 .
P4 Eu3 Ga4 138.648(15) 3_565 .
P4 Eu3 Ga4 41.352(15) . .
P1 Eu3 Ga4 85.16(2) 3_565 .
P1 Eu3 Ga4 94.84(2) . .
Ga3 Eu3 Ga4 62.418(10) 3_565 .
Ga3 Eu3 Ga4 62.418(10) 3 .
Ga3 Eu3 Ga4 117.582(10) 1_565 .
Ga3 Eu3 Ga4 117.582(10) . .
Ga4 Eu3 Ga4 180.0 3_565 .
P3 Ga1 P3 105.44(4) 3_556 3_566
P3 Ga1 P1 108.25(3) 3_556 .
P3 Ga1 P1 108.25(3) 3_566 .
P3 Ga1 Ga1 111.50(3) 3_556 3_566
P3 Ga1 Ga1 111.50(3) 3_566 3_566
P1 Ga1 Ga1 111.64(4) . 3_566
P3 Ga1 Eu4P 54.19(15) 3_556 .
P3 Ga1 Eu4P 106.27(14) 3_566 .
P1 Ga1 Eu4P 56.27(17) . .
Ga1 Ga1 Eu4P 142.17(13) 3_566 .
P3 Ga1 Eu4P 106.27(14) 3_556 1_565
P3 Ga1 Eu4P 54.19(15) 3_566 1_565
P1 Ga1 Eu4P 56.27(17) . 1_565
Ga1 Ga1 Eu4P 142.17(13) 3_566 1_565
Eu4P Ga1 Eu4P 65.9(2) . 1_565
Ga3 Ga2 P2 115.58(3) 1_655 1_545
Ga3 Ga2 P2 115.59(3) 1_655 .
P2 Ga2 P2 107.14(5) 1_545 .
Ga3 Ga2 P3 96.30(3) 1_655 3_656
P2 Ga2 P3 110.97(3) 1_545 3_656
P2 Ga2 P3 110.97(3) . 3_656
Ga3 Ga2 Eu2 133.388(14) 1_655 .
P2 Ga2 Eu2 110.01(3) 1_545 .
P2 Ga2 Eu2 56.20(3) . .
P3 Ga2 Eu2 57.47(2) 3_656 .
Ga3 Ga2 Eu2 133.388(14) 1_655 1_545
P2 Ga2 Eu2 56.20(3) 1_545 1_545
P2 Ga2 Eu2 110.01(3) . 1_545
P3 Ga2 Eu2 57.47(2) 3_656 1_545
Eu2 Ga2 Eu2 67.883(11) . 1_545
Ga3 Ga2 Eu1 147.78(2) 1_655 .
P2 Ga2 Eu1 54.36(2) 1_545 .
P2 Ga2 Eu1 54.36(2) . .
P3 Ga2 Eu1 115.92(3) 3_656 .
Eu2 Ga2 Eu1 70.540(8) . .
Eu2 Ga2 Eu1 70.540(8) 1_545 .
P4 Ga3 Ga2 118.55(3) 3 1_455
P4 Ga3 P1 111.40(3) 3 1_545
Ga2 Ga3 P1 104.45(3) 1_455 1_545
P4 Ga3 P1 111.40(3) 3 .
Ga2 Ga3 P1 104.45(3) 1_455 .
P1 Ga3 P1 105.53(5) 1_545 .
P4 Ga3 Eu3 56.46(2) 3 .
Ga2 Ga3 Eu3 143.946(9) 1_455 .
P1 Ga3 Eu3 110.26(3) 1_545 .
P1 Ga3 Eu3 57.23(3) . .
P4 Ga3 Eu3 56.46(2) 3 1_545
Ga2 Ga3 Eu3 143.946(8) 1_455 1_545
P1 Ga3 Eu3 57.23(3) 1_545 1_545
P1 Ga3 Eu3 110.26(3) . 1_545
Eu3 Ga3 Eu3 67.747(10) . 1_545
P4 Ga3 Eu1 114.03(3) 3 .
Ga2 Ga3 Eu1 127.42(2) 1_455 .
P1 Ga3 Eu1 53.88(2) 1_545 .
P1 Ga3 Eu1 53.88(2) . .
Eu3 Ga3 Eu1 70.055(10) . .
Eu3 Ga3 Eu1 70.055(10) 1_545 .
P2 Ga4 P4 100.97(3) . .
P2 Ga4 P4 100.97(3) . 1_565
P4 Ga4 P4 106.46(5) . 1_565
P2 Ga4 Ga4 118.41(4) . 3_665
P4 Ga4 Ga4 114.12(3) . 3_665
P4 Ga4 Ga4 114.12(3) 1_565 3_665
P2 Ga4 Eu3 105.31(3) . .
P4 Ga4 Eu3 53.30(2) . .
P4 Ga4 Eu3 53.30(2) 1_565 .
Ga4 Ga4 Eu3 136.29(3) 3_665 .
Ga3 P1 Ga3 105.53(5) . 1_565
Ga3 P1 Ga1 99.34(3) . .
Ga3 P1 Ga1 99.34(3) 1_565 .
Ga3 P1 Eu3 79.31(3) . .
Ga3 P1 Eu3 79.31(3) 1_565 .
Ga1 P1 Eu3 177.69(5) . .
Ga1 P1 Eu4P 81.2(2) . 1_565
Eu3 P1 Eu4P 97.1(2) . 1_565
Ga1 P1 Eu4P 81.2(2) . .
Eu3 P1 Eu4P 97.1(2) . .
Eu4P P1 Eu4P 80.5(3) 1_565 .
Ga3 P1 Eu1 85.461(15) . .
Ga3 P1 Eu1 160.61(4) 1_565 .
Ga1 P1 Eu1 94.43(3) . .
Eu3 P1 Eu1 87.33(2) . .
Eu4P P1 Eu1 175.5(2) 1_565 .
Eu4P P1 Eu1 99.64(14) . .
Ga3 P1 Eu1 160.61(4) . 1_565
Ga3 P1 Eu1 85.462(15) 1_565 1_565
Ga1 P1 Eu1 94.43(3) . 1_565
Eu3 P1 Eu1 87.33(2) . 1_565
Eu4P P1 Eu1 99.64(14) 1_565 1_565
Eu4P P1 Eu1 175.5(2) . 1_565
Eu1 P1 Eu1 79.89(3) . 1_565
Ga4 P2 Ga2 99.25(3) . 1_565
Ga4 P2 Ga2 99.25(3) . .
Ga2 P2 Ga2 107.14(5) 1_565 .
Ga4 P2 Eu2 179.73(5) . .
Ga2 P2 Eu2 80.59(3) 1_565 .
Ga2 P2 Eu2 80.59(3) . .
Ga4 P2 Eu1 91.71(3) . 1_565
Ga2 P2 Eu1 85.408(15) 1_565 1_565
Ga2 P2 Eu1 161.60(4) . 1_565
Eu2 P2 Eu1 88.50(3) . 1_565
Ga4 P2 Eu1 91.71(3) . .
Ga2 P2 Eu1 161.60(4) 1_565 .
Ga2 P2 Eu1 85.408(15) . .
Eu2 P2 Eu1 88.50(3) . .
Eu1 P2 Eu1 79.50(3) 1_565 .
Ga4 P2 Eu4P 85.5(2) . 1_665
Eu2 P2 Eu4P 94.3(2) . 1_665
Eu1 P2 Eu4P 101.49(13) 1_565 1_665
Eu1 P2 Eu4P 177.0(2) . 1_665
Ga4 P2 Eu4P 85.5(2) . 1_655
Eu2 P2 Eu4P 94.3(2) . 1_655
Eu1 P2 Eu4P 177.0(2) 1_565 1_655
Eu1 P2 Eu4P 101.49(13) . 1_655
Eu4P P2 Eu4P 77.4(3) 1_665 1_655
Ga1 P3 Ga1 105.44(4) 3_556 3_566
Ga1 P3 Ga2 97.64(3) 3_556 3_656
Ga1 P3 Ga2 97.64(3) 3_566 3_656
Ga1 P3 Eu4P 83.10(14) 3_556 3_556
Ga1 P3 Eu4P 83.10(14) 3_566 3_556
Ga1 P3 Eu2 167.72(3) 3_556 .
Ga1 P3 Eu2 86.742(13) 3_566 .
Ga2 P3 Eu2 78.86(3) 3_656 .
Eu4P P3 Eu2 97.12(17) 3_556 .
Ga1 P3 Eu2 86.742(13) 3_556 1_545
Ga1 P3 Eu2 167.72(3) 3_566 1_545
Ga2 P3 Eu2 78.86(3) 3_656 1_545
Eu4P P3 Eu2 97.12(17) 3_556 1_545
Eu2 P3 Eu2 81.04(3) . 1_545
Ga1 P3 Eu1 94.24(3) 3_556 .
Ga1 P3 Eu1 94.24(3) 3_566 .
Ga2 P3 Eu1 160.32(4) 3_656 .
Eu4P P3 Eu1 175.6(2) 3_556 .
Eu2 P3 Eu1 86.24(2) . .
Eu2 P3 Eu1 86.24(3) 1_545 .
Ga3 P4 Ga4 100.45(3) 3 1_545
Ga3 P4 Ga4 100.45(3) 3 .
Ga4 P4 Ga4 106.46(5) 1_545 .
Ga3 P4 Eu3 80.82(3) 3 1_545
Ga4 P4 Eu3 85.348(13) 1_545 1_545
Ga4 P4 Eu3 167.54(4) . 1_545
Ga3 P4 Eu3 80.82(3) 3 .
Ga4 P4 Eu3 167.54(4) 1_545 .
Ga4 P4 Eu3 85.348(13) . .
Eu3 P4 Eu3 82.61(3) 1_545 .
Ga4 P4 Eu4P 88.25(13) 1_545 3
Ga4 P4 Eu4P 88.25(13) . 3
Eu3 P4 Eu4P 96.22(16) 1_545 3
Eu3 P4 Eu4P 96.22(16) . 3
Ga3 P4 Eu1 162.99(5) 3 .
Ga4 P4 Eu1 89.63(3) 1_545 .
Ga4 P4 Eu1 89.63(3) . .
Eu3 P4 Eu1 86.44(2) 1_545 .
Eu3 P4 Eu1 86.44(2) . .
Eu4P P4 Eu1 176.5(2) 3 .
P3 Eu4P P1 83.9(3) 3_556 .
P3 Eu4P P1 83.9(3) 3_556 1_545
P1 Eu4P P1 80.5(3) . 1_545
P3 Eu4P P4 161.3(4) 3_556 3
P1 Eu4P P4 81.9(3) . 3
P1 Eu4P P4 81.9(3) 1_545 3
P3 Eu4P P2 83.3(3) 3_556 1_445
P1 Eu4P P2 167.1(4) . 1_445
P1 Eu4P P2 99.61(6) 1_545 1_445
P4 Eu4P P2 111.0(3) 3 1_445
P3 Eu4P P2 83.3(3) 3_556 1_455
P1 Eu4P P2 99.61(6) . 1_455
P1 Eu4P P2 167.1(4) 1_545 1_455
P4 Eu4P P2 111.0(3) 3 1_455
P2 Eu4P P2 77.4(3) 1_445 1_455
P3 Eu4P Ga1 42.71(15) 3_556 .
P1 Eu4P Ga1 42.57(13) . .
P1 Eu4P Ga1 88.1(3) 1_545 .
P4 Eu4P Ga1 124.5(3) 3 .
P2 Eu4P Ga1 124.5(4) 1_445 .
P2 Eu4P Ga1 83.53(17) 1_455 .
P3 Eu4P Ga1 42.71(15) 3_556 1_545
P1 Eu4P Ga1 88.1(3) . 1_545
P1 Eu4P Ga1 42.57(13) 1_545 1_545
P4 Eu4P Ga1 124.5(3) 3 1_545
P2 Eu4P Ga1 83.53(17) 1_445 1_545
P2 Eu4P Ga1 124.5(4) 1_455 1_545
Ga1 Eu4P Ga1 65.9(2) . 1_545
P3 Eu4P Eu4P 90.0 3_556 1_565
P1 Eu4P Eu4P 49.76(14) . 1_565
P1 Eu4P Eu4P 130.24(14) 1_545 1_565
P4 Eu4P Eu4P 90.0 3 1_565
P2 Eu4P Eu4P 128.69(13) 1_445 1_565
P2 Eu4P Eu4P 51.31(13) 1_455 1_565
Ga1 Eu4P Eu4P 57.06(11) . 1_565
Ga1 Eu4P Eu4P 122.94(11) 1_545 1_565
P3 Eu4P Eu4P 90.0 3_556 1_545
P1 Eu4P Eu4P 130.24(14) . 1_545
P1 Eu4P Eu4P 49.76(14) 1_545 1_545
P4 Eu4P Eu4P 90.0 3 1_545
P2 Eu4P Eu4P 51.31(13) 1_445 1_545
P2 Eu4P Eu4P 128.69(13) 1_455 1_545
Ga1 Eu4P Eu4P 122.94(11) . 1_545
Ga1 Eu4P Eu4P 57.06(11) 1_545 1_545
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 P1 3.0344(9) 1_545
Eu1 P1 3.0344(9) .
Eu1 P2 3.0470(9) .
Eu1 P2 3.0470(9) 1_545
Eu1 P3 3.1122(12) .
Eu1 P4 3.1214(11) .
Eu1 Ga2 3.7372(6) .
Eu1 Ga3 3.7444(6) .
Eu1 Eu1 3.8967(4) 1_565
Eu1 Eu1 3.8967(4) 1_545
Eu1 Eu3 4.1606(3) 1_545
Eu1 Eu3 4.1606(3) .
Eu2 P2 2.9393(11) 3_666
Eu2 P2 2.9393(11) .
Eu2 P3 2.9987(8) 3_666
Eu2 P3 2.9987(8) 3_656
Eu2 P3 2.9987(8) 1_565
Eu2 P3 2.9987(8) .
Eu2 Ga2 3.4895(4) .
Eu2 Ga2 3.4895(4) 3_666
Eu2 Ga2 3.4895(4) 3_656
Eu2 Ga2 3.4895(4) 1_565
Eu2 Eu2 3.8967(4) 1_545
Eu2 Eu2 3.8967(4) 1_565
Eu3 P4 2.9516(8) 3
Eu3 P4 2.9516(8) 1_565
Eu3 P4 2.9516(8) 3_565
Eu3 P4 2.9516(8) .
Eu3 P1 2.9912(11) 3_565
Eu3 P1 2.9912(11) .
Eu3 Ga3 3.4956(4) 3_565
Eu3 Ga3 3.4956(4) 3
Eu3 Ga3 3.4956(4) 1_565
Eu3 Ga3 3.4956(4) .
Eu3 Ga4 3.6692(6) 3_565
Eu3 Ga4 3.6692(6) .
Ga1 P3 2.4486(7) 3_556
Ga1 P3 2.4486(7) 3_566
Ga1 P1 2.4535(12) .
Ga1 Ga1 2.4922(9) 3_566
Ga1 Eu4P 3.583(10) .
Ga1 Eu4P 3.583(10) 1_565
Ga2 Ga3 2.4048(6) 1_655
Ga2 P2 2.4216(7) 1_545
Ga2 P2 2.4216(7) .
Ga2 P3 2.4558(13) 3_656
Ga2 Eu2 3.4895(4) 1_545
Ga3 P4 2.4023(12) 3
Ga3 Ga2 2.4048(6) 1_455
Ga3 P1 2.4471(8) 1_545
Ga3 P1 2.4471(8) .
Ga3 Eu3 3.4956(4) 1_545
Ga4 P2 2.4159(12) .
Ga4 P4 2.4322(7) .
Ga4 P4 2.4322(7) 1_565
Ga4 Ga4 2.4703(9) 3_665
P1 Ga3 2.4471(8) 1_565
P1 Eu4P 3.016(9) 1_565
P1 Eu4P 3.016(9) .
P1 Eu1 3.0344(9) 1_565
P2 Ga2 2.4216(7) 1_565
P2 Eu1 3.0470(9) 1_565
P2 Eu4P 3.117(9) 1_665
P2 Eu4P 3.117(9) 1_655
P3 Ga1 2.4486(7) 3_556
P3 Ga1 2.4486(7) 3_566
P3 Ga2 2.4558(12) 3_656
P3 Eu4P 2.927(12) 3_556
P3 Eu2 2.9987(8) 1_545
P4 Ga3 2.4022(12) 3
P4 Ga4 2.4322(7) 1_545
P4 Eu3 2.9516(8) 1_545
P4 Eu4P 3.096(12) 3
Eu4P P3 2.927(12) 3_556
Eu4P P1 3.016(9) 1_545
Eu4P P4 3.096(12) 3
Eu4P P2 3.117(9) 1_445
Eu4P P2 3.117(9) 1_455
Eu4P Ga1 3.584(10) 1_545
Eu4P Eu4P 3.8967(4) 1_565
Eu4P Eu4P 3.8967(4) 1_545
