#------------------------------------------------------------------------------
#$Date: 2020-11-05 10:56:28 +0200 (Thu, 05 Nov 2020) $
#$Revision: 258736 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/38/4313876.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313876
loop_
_publ_author_name
'Indrani Pal'
'Swati Dutta'
'Falguni Basuli'
'Savitha Goverdhan'
'Shie-Ming Peng'
'Gene-Hsiang Lee'
'Samaresh Bhattacharya'
_publ_section_title
;
 Unprecedented Chemical Transformation of Semicarbazones Mediated by
 Wilkinson's Catalyst
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4338
_journal_page_last               4345
_journal_paper_doi               10.1021/ic034247j
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C50 H47 Cl N5 O3 P2 Rh'
_chemical_formula_weight         966.22
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.000(5)
_cell_angle_beta                 114.370(5)
_cell_angle_gamma                90.000(5)
_cell_formula_units_Z            8
_cell_length_a                   24.288(5)
_cell_length_b                   17.010(5)
_cell_length_c                   25.114(5)
_cell_measurement_temperature    293(2)
_cell_volume                     9451(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.473
_diffrn_measured_fraction_theta_max 0.473
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.1796
_diffrn_reflns_av_sigmaI/netI    0.1738
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            12442
_diffrn_reflns_theta_full        22.50
_diffrn_reflns_theta_max         22.50
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    0.532
_exptl_crystal_density_diffrn    1.358
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3984
_refine_diff_density_max         0.794
_refine_diff_density_min         -0.978
_refine_diff_density_rms         0.104
_refine_ls_extinction_coef       0.000018(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     563
_refine_ls_number_reflns         6097
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.1825
_refine_ls_R_factor_gt           0.0860
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0370P)²+105.3325P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1666
_refine_ls_wR_factor_ref         0.2001
_reflns_number_gt                3071
_reflns_number_total             6097
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034247jsi20030307_080141.cif
_cod_data_source_block           rh1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0370P)^2^+105.3325P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0370P)^2^+105.3325P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 

2020-10-30
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C100 H94 Cl2 N10 O6 P4 Rh2'
_cod_original_formula_weight         1932.45
_cod_original_formula_units_Z            4
_cod_database_code               4313876
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5245(5) 0.1103(7) 0.3020(5) 0.031(3) Uani 1 d . . .
C2 C 0.5478(5) 0.0905(8) 0.3614(5) 0.038(3) Uani 1 d . . .
H2 H 0.5533 0.0383 0.3736 0.046 Uiso 1 calc R . .
C3 C 0.5625(6) 0.1526(9) 0.4020(5) 0.050(4) Uani 1 d . . .
C4 C 0.5579(7) 0.2307(10) 0.3871(6) 0.060(4) Uani 1 d . . .
H4 H 0.5698 0.2700 0.4154 0.072 Uiso 1 calc R . .
C5 C 0.5355(6) 0.2481(9) 0.3295(7) 0.058(4) Uani 1 d . . .
H5 H 0.5311 0.3008 0.3186 0.069 Uiso 1 calc R . .
C6 C 0.5188(5) 0.1925(8) 0.2864(5) 0.035(3) Uani 1 d . . .
C7 C 0.4930(6) 0.2096(8) 0.2242(6) 0.041(3) Uani 1 d . . .
H7 H 0.4866 0.2604 0.2093 0.049 Uiso 1 calc R . .
C8 C 0.4447(7) 0.0763(14) 0.1098(7) 0.064(5) Uani 1 d . . .
C9 C 0.4097(9) -0.0020(16) 0.0199(8) 0.128(9) Uani 1 d . . .
H9A H 0.4369 -0.0400 0.0467 0.154 Uiso 1 calc R . .
H9B H 0.4199 0.0025 -0.0135 0.154 Uiso 1 calc R . .
C10 C 0.3445(11) -0.0316(18) -0.0008(10) 0.191(14) Uani 1 d . . .
H10A H 0.3173 0.0124 -0.0111 0.287 Uiso 1 calc R . .
H10B H 0.3404 -0.0610 0.0299 0.287 Uiso 1 calc R . .
H10C H 0.3349 -0.0648 -0.0344 0.287 Uiso 1 calc R . .
C11 C 0.4001(9) 0.1430(14) 0.0127(7) 0.111(8) Uani 1 d . . .
H11A H 0.3836 0.1815 0.0306 0.133 Uiso 1 calc R . .
H11B H 0.3683 0.1285 -0.0247 0.133 Uiso 1 calc R . .
C12 C 0.4509(9) 0.179(2) 0.0028(8) 0.184(16) Uani 1 d . . .
H12A H 0.4783 0.2042 0.0381 0.276 Uiso 1 calc R . .
H12B H 0.4352 0.2180 -0.0277 0.276 Uiso 1 calc R . .
H12C H 0.4719 0.1395 -0.0085 0.276 Uiso 1 calc R . .
C13 C 0.3937(6) 0.0479(9) 0.3008(6) 0.045(3) Uani 1 d . . .
C14 C 0.4260(6) -0.0062(9) 0.3431(6) 0.063(4) Uani 1 d . . .
H14 H 0.4497 -0.0430 0.3349 0.075 Uiso 1 calc R . .
C15 C 0.4239(8) -0.0072(12) 0.3972(7) 0.085(6) Uani 1 d . . .
H15 H 0.4458 -0.0444 0.4250 0.102 Uiso 1 calc R . .
C16 C 0.3890(9) 0.0478(12) 0.4095(7) 0.089(5) Uani 1 d . . .
H16 H 0.3885 0.0505 0.4463 0.107 Uiso 1 calc R . .
C17 C 0.3546(9) 0.0990(12) 0.3651(9) 0.105(7) Uani 1 d . . .
H17 H 0.3285 0.1332 0.3722 0.126 Uiso 1 calc R . .
C18 C 0.3569(7) 0.1020(10) 0.3129(7) 0.071(5) Uani 1 d . . .
H18 H 0.3346 0.1391 0.2852 0.086 Uiso 1 calc R . .
C19 C 0.3514(5) -0.0423(9) 0.1973(6) 0.050(4) Uani 1 d . . .
C20 C 0.3601(7) -0.0916(10) 0.1588(8) 0.089(6) Uani 1 d . . .
H20 H 0.3937 -0.0829 0.1506 0.107 Uiso 1 calc R . .
C21 C 0.3232(8) -0.1523(11) 0.1315(9) 0.097(7) Uani 1 d . . .
H21 H 0.3304 -0.1825 0.1041 0.116 Uiso 1 calc R . .
C22 C 0.2759(7) -0.1683(10) 0.1448(9) 0.089(6) Uani 1 d . . .
H22 H 0.2498 -0.2091 0.1257 0.106 Uiso 1 calc R . .
C23 C 0.2659(8) -0.1243(11) 0.1866(8) 0.085(6) Uani 1 d . . .
H23 H 0.2342 -0.1368 0.1968 0.102 Uiso 1 calc R . .
C24 C 0.3038(6) -0.0618(8) 0.2129(7) 0.060(4) Uani 1 d . . .
H24 H 0.2978 -0.0324 0.2412 0.072 Uiso 1 calc R . .
C25 C 0.3515(6) 0.1265(9) 0.1866(6) 0.046(4) Uani 1 d . . .
C26 C 0.3621(6) 0.2012(9) 0.2093(6) 0.053(4) Uani 1 d . . .
H26 H 0.3897 0.2105 0.2475 0.063 Uiso 1 calc R . .
C27 C 0.3307(8) 0.2613(11) 0.1738(9) 0.085(6) Uani 1 d . . .
H27 H 0.3378 0.3118 0.1894 0.102 Uiso 1 calc R . .
C28 C 0.2894(9) 0.2534(13) 0.1169(10) 0.095(7) Uani 1 d . . .
H28 H 0.2689 0.2962 0.0944 0.114 Uiso 1 calc R . .
C29 C 0.2806(8) 0.1794(15) 0.0958(8) 0.089(6) Uani 1 d . . .
H29 H 0.2529 0.1716 0.0574 0.107 Uiso 1 calc R . .
C30 C 0.3112(6) 0.1122(10) 0.1288(6) 0.056(4) Uani 1 d . . .
H30 H 0.3047 0.0619 0.1128 0.067 Uiso 1 calc R . .
C31 C 0.6566(5) 0.0473(9) 0.3088(5) 0.040(3) Uani 1 d . . .
C32 C 0.6583(6) -0.0042(9) 0.3505(5) 0.050(4) Uani 1 d . . .
H32 H 0.6259 -0.0386 0.3417 0.060 Uiso 1 calc R . .
C33 C 0.7052(7) -0.0085(11) 0.4051(7) 0.081(6) Uani 1 d . . .
H33 H 0.7041 -0.0447 0.4324 0.098 Uiso 1 calc R . .
C34 C 0.7533(7) 0.0409(13) 0.4187(7) 0.081(5) Uani 1 d . . .
H34 H 0.7848 0.0396 0.4558 0.098 Uiso 1 calc R . .
C35 C 0.7550(6) 0.0919(11) 0.3781(7) 0.074(5) Uani 1 d . . .
H35 H 0.7885 0.1245 0.3875 0.088 Uiso 1 calc R . .
C36 C 0.7077(6) 0.0969(9) 0.3223(6) 0.061(4) Uani 1 d . . .
H36 H 0.7097 0.1319 0.2946 0.074 Uiso 1 calc R . .
C37 C 0.6156(6) -0.0449(9) 0.2056(5) 0.044(3) Uani 1 d . . .
C38 C 0.6748(6) -0.0557(10) 0.2153(7) 0.070(5) Uani 1 d . . .
H38 H 0.7042 -0.0208 0.2389 0.084 Uiso 1 calc R . .
C39 C 0.6905(7) -0.1183(10) 0.1901(7) 0.075(5) Uani 1 d . . .
H39 H 0.7302 -0.1231 0.1941 0.090 Uiso 1 calc R . .
C40 C 0.6489(8) -0.1737(9) 0.1590(7) 0.073(5) Uani 1 d . . .
H40 H 0.6610 -0.2178 0.1446 0.088 Uiso 1 calc R . .
C41 C 0.5893(8) -0.1642(9) 0.1490(7) 0.066(5) Uani 1 d . . .
H41 H 0.5605 -0.2013 0.1275 0.080 Uiso 1 calc R . .
C42 C 0.5727(7) -0.0993(9) 0.1714(6) 0.062(4) Uani 1 d . . .
H42 H 0.5322 -0.0914 0.1636 0.074 Uiso 1 calc R . .
C43 C 0.6067(5) 0.1247(9) 0.1946(6) 0.043(4) Uani 1 d . . .
C44 C 0.6154(5) 0.2014(8) 0.2174(6) 0.047(4) Uani 1 d . . .
H44 H 0.6191 0.2098 0.2554 0.057 Uiso 1 calc R . .
C45 C 0.6184(6) 0.2627(10) 0.1848(7) 0.067(5) Uani 1 d . . .
H45 H 0.6242 0.3133 0.2002 0.081 Uiso 1 calc R . .
C46 C 0.6127(7) 0.2502(14) 0.1286(8) 0.091(7) Uani 1 d . . .
H46 H 0.6143 0.2926 0.1059 0.109 Uiso 1 calc R . .
C47 C 0.6047(7) 0.1739(12) 0.1053(7) 0.070(5) Uani 1 d . . .
H47 H 0.6017 0.1653 0.0676 0.084 Uiso 1 calc R . .
C48 C 0.6015(6) 0.1127(9) 0.1388(6) 0.058(4) Uani 1 d . . .
H48 H 0.5956 0.0620 0.1236 0.070 Uiso 1 calc R . .
N1 N 0.5883(10) 0.1315(13) 0.4639(7) 0.113(7) Uani 1 d . . .
N2 N 0.4793(5) 0.1461(6) 0.1904(4) 0.035(3) Uani 1 d . . .
N3 N 0.4548(5) 0.1499(9) 0.1314(5) 0.063(4) Uani 1 d . . .
O1 O 0.4584(4) 0.0123(7) 0.1378(4) 0.063(3) Uani 1 d . . .
N4 N 0.4184(7) 0.0747(11) 0.0493(6) 0.090(5) Uani 1 d . . .
O2 O 0.6000(10) 0.1822(11) 0.4993(6) 0.205(11) Uani 1 d . . .
O3 O 0.5922(7) 0.0656(10) 0.4778(5) 0.109(5) Uani 1 d . . .
P1 P 0.39729(14) 0.0439(2) 0.22959(14) 0.0383(8) Uani 1 d . . .
P2 P 0.59458(14) 0.0431(2) 0.23577(13) 0.0368(8) Uani 1 d . . .
Cl Cl 0.51217(15) -0.08312(19) 0.27451(16) 0.0474(9) Uani 1 d . . .
Rh Rh 0.49529(4) 0.04374(7) 0.23054(4) 0.0338(3) Uani 1 d . . .
C1S C 0.3747(17) 0.348(2) 0.0306(15) 0.141(12) Uani 1 d . . .
C2S C 0.4373(13) 0.3470(18) 0.0773(13) 0.224(18) Uani 1 d . . .
H2S1 H 0.4462 0.2960 0.0952 0.336 Uiso 1 calc R . .
H2S2 H 0.4408 0.3858 0.1063 0.336 Uiso 1 calc R . .
H2S3 H 0.4654 0.3589 0.0605 0.336 Uiso 1 calc R . .
N1S N 0.3277(12) 0.344(2) -0.0036(13) 0.165(11) Uani 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 118.3(12) . . ?
C2 C1 Rh 131.4(10) . . ?
C6 C1 Rh 110.3(8) . . ?
C1 C2 C3 117.4(12) . . ?
C4 C3 C2 124.1(12) . . ?
C4 C3 N1 118.6(16) . . ?
C2 C3 N1 117.1(15) . . ?
C5 C4 C3 117.1(15) . . ?
C4 C5 C6 123.6(14) . . ?
C5 C6 C1 119.4(11) . . ?
C5 C6 C7 124.6(13) . . ?
C1 C6 C7 115.9(11) . . ?
N2 C7 C6 114.1(11) . . ?
O1 C8 N3 127.9(15) . . ?
O1 C8 N4 119.3(18) . . ?
N3 C8 N4 112.7(19) . . ?
N4 C9 C10 112.1(19) . . ?
N4 C11 C12 112.6(19) . . ?
C14 C13 C18 118.8(13) . . ?
C14 C13 P1 119.2(11) . . ?
C18 C13 P1 121.9(11) . . ?
C13 C14 C15 121.8(15) . . ?
C16 C15 C14 119.1(16) . . ?
C15 C16 C17 117.8(16) . . ?
C18 C17 C16 123.8(18) . . ?
C17 C18 C13 118.5(16) . . ?
C20 C19 C24 116.1(15) . . ?
C20 C19 P1 124.6(12) . . ?
C24 C19 P1 119.3(12) . . ?
C21 C20 C19 124.3(17) . . ?
C22 C21 C20 118.9(17) . . ?
C21 C22 C23 120.7(16) . . ?
C24 C23 C22 119.0(16) . . ?
C23 C24 C19 120.7(16) . . ?
C26 C25 C30 121.6(14) . . ?
C26 C25 P1 119.9(11) . . ?
C30 C25 P1 118.1(13) . . ?
C27 C26 C25 117.7(15) . . ?
C26 C27 C28 125(2) . . ?
C29 C28 C27 115.5(19) . . ?
C28 C29 C30 124.0(18) . . ?
C25 C30 C29 115.9(16) . . ?
C32 C31 C36 117.1(12) . . ?
C32 C31 P2 119.9(11) . . ?
C36 C31 P2 122.5(11) . . ?
C31 C32 C33 123.6(15) . . ?
C34 C33 C32 119.3(16) . . ?
C35 C34 C33 119.7(14) . . ?
C34 C35 C36 121.7(15) . . ?
C35 C36 C31 118.5(15) . . ?
C38 C37 C42 118.9(14) . . ?
C38 C37 P2 119.1(11) . . ?
C42 C37 P2 121.9(10) . . ?
C37 C38 C39 119.7(15) . . ?
C40 C39 C38 121.2(15) . . ?
C39 C40 C41 119.9(15) . . ?
C42 C41 C40 119.0(15) . . ?
C41 C42 C37 121.1(14) . . ?
C48 C43 C44 119.5(14) . . ?
C48 C43 P2 119.8(12) . . ?
C44 C43 P2 120.3(10) . . ?
C45 C44 C43 120.4(15) . . ?
C44 C45 C46 119.7(17) . . ?
C45 C46 C47 120.6(17) . . ?
C48 C47 C46 118.7(16) . . ?
C47 C48 C43 121.0(16) . . ?
O3 N1 O2 120.7(18) . . ?
O3 N1 C3 120(2) . . ?
O2 N1 C3 119(2) . . ?
C7 N2 N3 122.9(11) . . ?
C7 N2 Rh 116.6(8) . . ?
N3 N2 Rh 120.6(10) . . ?
C8 N3 N2 108.8(13) . . ?
C8 O1 Rh 106.3(10) . . ?
C8 N4 C11 124.6(18) . . ?
C8 N4 C9 118.3(18) . . ?
C11 N4 C9 117.0(13) . . ?
C19 P1 C13 101.5(7) . . ?
C19 P1 C25 104.1(6) . . ?
C13 P1 C25 106.6(7) . . ?
C19 P1 Rh 115.6(5) . . ?
C13 P1 Rh 116.3(4) . . ?
C25 P1 Rh 111.6(4) . . ?
C43 P2 C31 106.2(6) . . ?
C43 P2 C37 104.3(6) . . ?
C31 P2 C37 101.0(6) . . ?
C43 P2 Rh 111.4(4) . . ?
C31 P2 Rh 117.0(4) . . ?
C37 P2 Rh 115.6(4) . . ?
N2 Rh C1 83.1(5) . . ?
N2 Rh O1 76.3(5) . . ?
C1 Rh O1 159.4(5) . . ?
N2 Rh P2 90.8(3) . . ?
C1 Rh P2 88.7(3) . . ?
O1 Rh P2 91.0(3) . . ?
N2 Rh P1 90.5(3) . . ?
C1 Rh P1 89.5(3) . . ?
O1 Rh P1 91.2(3) . . ?
P2 Rh P1 177.61(14) . . ?
N2 Rh Cl 177.2(3) . . ?
C1 Rh Cl 99.7(3) . . ?
O1 Rh Cl 100.9(4) . . ?
P2 Rh Cl 89.62(13) . . ?
P1 Rh Cl 89.19(14) . . ?
N1S C1S C2S 177(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.401(15) . ?
C1 C6 1.442(18) . ?
C1 Rh 1.989(12) . ?
C2 C3 1.409(17) . ?
C3 C4 1.37(2) . ?
C3 N1 1.460(18) . ?
C4 C5 1.351(18) . ?
C5 C6 1.368(18) . ?
C6 C7 1.452(16) . ?
C7 N2 1.328(15) . ?
C8 O1 1.26(2) . ?
C8 N3 1.35(2) . ?
C8 N4 1.384(19) . ?
C9 N4 1.47(2) . ?
C9 C10 1.53(3) . ?
C11 N4 1.43(2) . ?
C11 C12 1.49(2) . ?
C13 C14 1.377(18) . ?
C13 C18 1.401(19) . ?
C13 P1 1.828(12) . ?
C14 C15 1.382(19) . ?
C15 C16 1.38(2) . ?
C16 C17 1.39(2) . ?
C17 C18 1.34(2) . ?
C19 C20 1.360(19) . ?
C19 C24 1.404(18) . ?
C19 P1 1.819(16) . ?
C20 C21 1.35(2) . ?
C21 C22 1.35(2) . ?
C22 C23 1.39(2) . ?
C23 C24 1.38(2) . ?
C25 C26 1.373(19) . ?
C25 C30 1.396(18) . ?
C25 P1 1.840(14) . ?
C26 C27 1.36(2) . ?
C27 C28 1.37(2) . ?
C28 C29 1.35(3) . ?
C29 C30 1.43(2) . ?
C31 C32 1.352(18) . ?
C31 C36 1.421(17) . ?
C31 P2 1.833(11) . ?
C32 C33 1.377(17) . ?
C33 C34 1.36(2) . ?
C34 C35 1.35(2) . ?
C35 C36 1.403(18) . ?
C37 C38 1.367(16) . ?
C37 C42 1.393(17) . ?
C37 P2 1.842(15) . ?
C38 C39 1.37(2) . ?
C39 C40 1.37(2) . ?
C40 C41 1.375(19) . ?
C41 C42 1.373(19) . ?
C43 C48 1.367(17) . ?
C43 C44 1.405(18) . ?
C43 P2 1.828(15) . ?
C44 C45 1.347(18) . ?
C45 C46 1.38(2) . ?
C46 C47 1.40(2) . ?
C47 C48 1.36(2) . ?
N1 O3 1.17(2) . ?
N1 O2 1.19(2) . ?
N2 N3 1.351(14) . ?
N2 Rh 1.968(10) . ?
O1 Rh 2.189(9) . ?
P1 Rh 2.371(3) . ?
P2 Rh 2.361(3) . ?
Cl Rh 2.381(4) . ?
C1S N1S 1.11(3) . ?
C1S C2S 1.49(3) . ?
