#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:12:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179235 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/55/4315528.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315528
loop_
_publ_author_name
'Keith Izod'
'John Stewart'
'Ewan R. Clark'
'William Clegg'
'Ross W. Harrington'
_publ_section_title
;
 Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide
 Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4698
_journal_page_last               4707
_journal_paper_doi               10.1021/ic1003534
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C52 H96 Ge2 P4 Si8, C4 H10 O'
_chemical_formula_sum            'C56 H106 Ge2 O P4 Si8'
_chemical_formula_weight         1289.19
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   21.4695(13)
_cell_length_b                   22.5652(13)
_cell_length_c                   29.9365(18)
_cell_measurement_reflns_used    9213
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.26
_cell_measurement_theta_min      2.60
_cell_volume                     14503.1(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL and local programs'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker SMART 1K CCD diffractometer'
_diffrn_measurement_method       'thin-slice ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0649
_diffrn_reflns_av_sigmaI/netI    0.0699
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            130441
_diffrn_reflns_theta_full        28.37
_diffrn_reflns_theta_max         28.37
_diffrn_reflns_theta_min         1.17
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.082
_exptl_absorpt_correction_T_max  0.671
_exptl_absorpt_correction_T_min  0.614
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.181
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5488
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.40
_refine_diff_density_max         1.425
_refine_diff_density_min         -0.590
_refine_diff_density_rms         0.116
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.513(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1332
_refine_ls_number_reflns         35168
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.140
_refine_ls_R_factor_all          0.0931
_refine_ls_R_factor_gt           0.0507
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0413P)²+13.8574P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1014
_refine_ls_wR_factor_ref         0.1208
_reflns_number_gt                26086
_reflns_number_total             35168
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic1003534_si_001_4.cif
_cod_data_source_block           ki282_compound_18.Et2O
_cod_database_code               4315528
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.77347(2) 0.44319(2) 0.465931(16) 0.01695(10) Uani 1 1 d . . .
Ge2 Ge 0.69078(2) 0.57554(2) 0.465718(16) 0.01776(10) Uani 1 1 d . . .
Ge3 Ge 0.20862(2) 0.44389(2) 0.216768(15) 0.01480(9) Uani 1 1 d . . .
Ge4 Ge 0.29092(2) 0.57650(2) 0.216839(15) 0.01513(10) Uani 1 1 d . . .
P1 P 0.79708(6) 0.38204(5) 0.52994(4) 0.0184(2) Uani 1 1 d . . .
P2 P 0.67005(6) 0.47404(5) 0.49004(4) 0.0161(2) Uani 1 1 d . . .
P3 P 0.66578(6) 0.63644(5) 0.52959(4) 0.0193(2) Uani 1 1 d . . .
P4 P 0.79604(5) 0.54555(5) 0.48611(4) 0.0162(2) Uani 1 1 d . . .
P5 P 0.32063(6) 0.63582(5) 0.28045(4) 0.0175(2) Uani 1 1 d . . .
P6 P 0.18824(5) 0.54507(5) 0.24207(4) 0.0155(2) Uani 1 1 d . . .
P7 P 0.31433(5) 0.47388(5) 0.23610(4) 0.0139(2) Uani 1 1 d . . .
P8 P 0.18828(5) 0.38237(5) 0.28114(4) 0.0159(2) Uani 1 1 d . . .
Si1 Si 0.88340(6) 0.28963(6) 0.47184(5) 0.0252(3) Uani 1 1 d . . .
Si2 Si 0.91969(7) 0.33530(6) 0.57006(5) 0.0242(3) Uani 1 1 d . . .
Si3 Si 0.52442(6) 0.46351(6) 0.47850(5) 0.0233(3) Uani 1 1 d . . .
Si4 Si 0.61115(7) 0.43495(6) 0.39490(5) 0.0270(3) Uani 1 1 d . . .
Si5 Si 0.53460(7) 0.66975(6) 0.56683(5) 0.0249(3) Uani 1 1 d . . .
Si6 Si 0.57368(7) 0.72432(7) 0.47243(5) 0.0299(3) Uani 1 1 d . . .
Si7 Si 0.84140(7) 0.58307(7) 0.38709(5) 0.0316(3) Uani 1 1 d . . .
Si8 Si 0.93613(6) 0.53643(6) 0.46152(5) 0.0275(3) Uani 1 1 d . . .
Si9 Si 0.40303(6) 0.72778(6) 0.21879(5) 0.0225(3) Uani 1 1 d . . .
Si10 Si 0.45151(6) 0.67738(6) 0.31221(4) 0.0210(3) Uani 1 1 d . . .
Si11 Si 0.12967(7) 0.58590(7) 0.14720(5) 0.0308(3) Uani 1 1 d . . .
Si12 Si 0.04392(6) 0.54451(6) 0.22819(5) 0.0241(3) Uani 1 1 d . . .
Si13 Si 0.45604(6) 0.47759(6) 0.21324(5) 0.0269(3) Uani 1 1 d . . .
Si14 Si 0.36084(7) 0.43859(7) 0.13644(5) 0.0306(3) Uani 1 1 d . . .
Si15 Si 0.09599(7) 0.29189(6) 0.22611(5) 0.0244(3) Uani 1 1 d . . .
Si16 Si 0.06573(6) 0.33861(6) 0.32467(5) 0.0222(3) Uani 1 1 d . . .
O1 O 0.7348(2) 0.5031(2) 0.74136(15) 0.0515(12) Uani 1 1 d . . .
O2 O 0.21418(18) 0.48732(18) 0.49073(13) 0.0404(10) Uani 1 1 d . . .
C1 C 0.8760(2) 0.34950(19) 0.51558(15) 0.0188(10) Uani 1 1 d . . .
H1A H 0.8989 0.3837 0.5021 0.023 Uiso 1 1 calc R . .
C2 C 0.9686(3) 0.2740(2) 0.4627(2) 0.0394(14) Uani 1 1 d . . .
H2A H 0.9734 0.2459 0.4380 0.059 Uiso 1 1 calc R . .
H2B H 0.9864 0.2570 0.4899 0.059 Uiso 1 1 calc R . .
H2C H 0.9902 0.3110 0.4554 0.059 Uiso 1 1 calc R . .
C3 C 0.8531(3) 0.3127(2) 0.41589(17) 0.0345(13) Uani 1 1 d . . .
H3A H 0.8669 0.2843 0.3932 0.052 Uiso 1 1 calc R . .
H3B H 0.8690 0.3522 0.4085 0.052 Uiso 1 1 calc R . .
H3C H 0.8074 0.3137 0.4167 0.052 Uiso 1 1 calc R . .
C4 C 0.8457(3) 0.2174(2) 0.48639(19) 0.0320(12) Uani 1 1 d . . .
H4A H 0.8663 0.1853 0.4700 0.048 Uiso 1 1 calc R . .
H4B H 0.8015 0.2188 0.4782 0.048 Uiso 1 1 calc R . .
H4C H 0.8496 0.2104 0.5186 0.048 Uiso 1 1 calc R . .
C5 C 0.8932(3) 0.3843(3) 0.61648(17) 0.0385(14) Uani 1 1 d . . .
H5A H 0.9180 0.3762 0.6433 0.058 Uiso 1 1 calc R . .
H5B H 0.8492 0.3767 0.6228 0.058 Uiso 1 1 calc R . .
H5C H 0.8987 0.4259 0.6078 0.058 Uiso 1 1 calc R . .
C6 C 1.0048(3) 0.3501(3) 0.5633(2) 0.0443(15) Uani 1 1 d . . .
H6A H 1.0261 0.3430 0.5918 0.067 Uiso 1 1 calc R . .
H6B H 1.0111 0.3914 0.5542 0.067 Uiso 1 1 calc R . .
H6C H 1.0220 0.3237 0.5404 0.067 Uiso 1 1 calc R . .
C7 C 0.9109(3) 0.2572(2) 0.59012(19) 0.0380(14) Uani 1 1 d . . .
H7A H 0.9288 0.2535 0.6201 0.057 Uiso 1 1 calc R . .
H7B H 0.9326 0.2303 0.5697 0.057 Uiso 1 1 calc R . .
H7C H 0.8666 0.2468 0.5911 0.057 Uiso 1 1 calc R . .
C8 C 0.7426(2) 0.3200(2) 0.52024(16) 0.0225(10) Uani 1 1 d . . .
C9 C 0.7099(2) 0.3108(2) 0.48071(18) 0.0280(11) Uani 1 1 d . . .
H9A H 0.7179 0.3355 0.4557 0.034 Uiso 1 1 calc R . .
C10 C 0.6655(3) 0.2657(2) 0.4772(2) 0.0400(14) Uani 1 1 d . . .
H10A H 0.6425 0.2609 0.4503 0.048 Uiso 1 1 calc R . .
C11 C 0.6552(3) 0.2286(3) 0.5126(3) 0.0519(18) Uani 1 1 d . . .
H11A H 0.6253 0.1977 0.5102 0.062 Uiso 1 1 calc R . .
C12 C 0.6884(3) 0.2362(2) 0.5520(2) 0.0426(15) Uani 1 1 d . . .
H12A H 0.6817 0.2100 0.5763 0.051 Uiso 1 1 calc R . .
C13 C 0.7311(3) 0.2819(2) 0.55582(19) 0.0315(12) Uani 1 1 d . . .
H13A H 0.7529 0.2873 0.5831 0.038 Uiso 1 1 calc R . .
C14 C 0.6053(2) 0.4395(2) 0.45842(14) 0.0196(10) Uani 1 1 d . . .
H14A H 0.6075 0.3970 0.4678 0.023 Uiso 1 1 calc R . .
C15 C 0.4747(2) 0.3958(2) 0.48173(19) 0.0370(14) Uani 1 1 d . . .
H15A H 0.4324 0.4070 0.4906 0.056 Uiso 1 1 calc R . .
H15B H 0.4921 0.3684 0.5038 0.056 Uiso 1 1 calc R . .
H15C H 0.4735 0.3764 0.4524 0.056 Uiso 1 1 calc R . .
C16 C 0.4893(2) 0.5199(2) 0.44024(19) 0.0361(13) Uani 1 1 d . . .
H16A H 0.4488 0.5324 0.4520 0.054 Uiso 1 1 calc R . .
H16B H 0.4837 0.5025 0.4105 0.054 Uiso 1 1 calc R . .
H16C H 0.5170 0.5543 0.4382 0.054 Uiso 1 1 calc R . .
C17 C 0.5209(2) 0.4983(2) 0.53517(19) 0.0311(12) Uani 1 1 d . . .
H17A H 0.4790 0.5141 0.5404 0.047 Uiso 1 1 calc R . .
H17B H 0.5513 0.5307 0.5369 0.047 Uiso 1 1 calc R . .
H17C H 0.5306 0.4685 0.5579 0.047 Uiso 1 1 calc R . .
C18 C 0.5418(3) 0.3925(3) 0.37354(19) 0.0414(15) Uani 1 1 d . . .
H18A H 0.5444 0.3890 0.3410 0.062 Uiso 1 1 calc R . .
H18B H 0.5035 0.4135 0.3817 0.062 Uiso 1 1 calc R . .
H18C H 0.5415 0.3528 0.3869 0.062 Uiso 1 1 calc R . .
C19 C 0.6139(3) 0.5081(2) 0.36613(18) 0.0388(14) Uani 1 1 d . . .
H19A H 0.6065 0.5026 0.3341 0.058 Uiso 1 1 calc R . .
H19B H 0.6549 0.5262 0.3706 0.058 Uiso 1 1 calc R . .
H19C H 0.5817 0.5341 0.3785 0.058 Uiso 1 1 calc R . .
C20 C 0.6789(3) 0.3899(2) 0.37468(17) 0.0344(13) Uani 1 1 d . . .
H20A H 0.6781 0.3878 0.3420 0.052 Uiso 1 1 calc R . .
H20B H 0.6762 0.3497 0.3870 0.052 Uiso 1 1 calc R . .
H20C H 0.7179 0.4085 0.3844 0.052 Uiso 1 1 calc R . .
C21 C 0.6564(2) 0.4538(2) 0.54823(15) 0.0205(10) Uani 1 1 d . . .
C22 C 0.6724(2) 0.4927(2) 0.58212(16) 0.0276(12) Uani 1 1 d . . .
H22A H 0.6868 0.5312 0.5746 0.033 Uiso 1 1 calc R . .
C23 C 0.6681(3) 0.4767(3) 0.62666(18) 0.0427(15) Uani 1 1 d . . .
H23A H 0.6816 0.5033 0.6493 0.051 Uiso 1 1 calc R . .
C24 C 0.6439(3) 0.4220(3) 0.6382(2) 0.0492(17) Uani 1 1 d . . .
H24A H 0.6399 0.4110 0.6687 0.059 Uiso 1 1 calc R . .
C25 C 0.6257(3) 0.3834(3) 0.6048(2) 0.0396(15) Uani 1 1 d . . .
H25A H 0.6083 0.3461 0.6125 0.048 Uiso 1 1 calc R . .
C26 C 0.6323(2) 0.3983(2) 0.56031(18) 0.0272(11) Uani 1 1 d . . .
H26A H 0.6206 0.3708 0.5378 0.033 Uiso 1 1 calc R . .
C27 C 0.5845(2) 0.6626(2) 0.51451(15) 0.0209(10) Uani 1 1 d . . .
H27A H 0.5661 0.6274 0.4990 0.025 Uiso 1 1 calc R . .
C28 C 0.4525(3) 0.6468(3) 0.5535(2) 0.0415(15) Uani 1 1 d . . .
H28A H 0.4391 0.6162 0.5746 0.062 Uiso 1 1 calc R . .
H28B H 0.4508 0.6311 0.5230 0.062 Uiso 1 1 calc R . .
H28C H 0.4249 0.6813 0.5559 0.062 Uiso 1 1 calc R . .
C29 C 0.5337(3) 0.7481(2) 0.5881(2) 0.0444(16) Uani 1 1 d . . .
H29A H 0.5074 0.7504 0.6148 0.067 Uiso 1 1 calc R . .
H29B H 0.5170 0.7744 0.5650 0.067 Uiso 1 1 calc R . .
H29C H 0.5762 0.7603 0.5957 0.067 Uiso 1 1 calc R . .
C30 C 0.5641(3) 0.6242(3) 0.61467(18) 0.0390(14) Uani 1 1 d . . .
H30A H 0.5347 0.6270 0.6397 0.059 Uiso 1 1 calc R . .
H30B H 0.6049 0.6392 0.6241 0.059 Uiso 1 1 calc R . .
H30C H 0.5680 0.5828 0.6053 0.059 Uiso 1 1 calc R . .
C31 C 0.6036(3) 0.7022(3) 0.41584(18) 0.0419(15) Uani 1 1 d . . .
H31A H 0.5924 0.7327 0.3939 0.063 Uiso 1 1 calc R . .
H31B H 0.5850 0.6643 0.4071 0.063 Uiso 1 1 calc R . .
H31C H 0.6490 0.6982 0.4170 0.063 Uiso 1 1 calc R . .
C32 C 0.4880(3) 0.7397(3) 0.4653(2) 0.0494(17) Uani 1 1 d . . .
H32A H 0.4822 0.7705 0.4426 0.074 Uiso 1 1 calc R . .
H32B H 0.4705 0.7533 0.4937 0.074 Uiso 1 1 calc R . .
H32C H 0.4668 0.7034 0.4558 0.074 Uiso 1 1 calc R . .
C33 C 0.6108(3) 0.7965(2) 0.4883(2) 0.0409(15) Uani 1 1 d . . .
H33A H 0.5897 0.8290 0.4727 0.061 Uiso 1 1 calc R . .
H33B H 0.6549 0.7960 0.4797 0.061 Uiso 1 1 calc R . .
H33C H 0.6074 0.8023 0.5206 0.061 Uiso 1 1 calc R . .
C34 C 0.7172(2) 0.7011(2) 0.51952(17) 0.0255(11) Uani 1 1 d . . .
C35 C 0.7499(2) 0.7116(2) 0.4808(2) 0.0352(13) Uani 1 1 d . . .
H35A H 0.7442 0.6860 0.4559 0.042 Uiso 1 1 calc R . .
C36 C 0.7912(3) 0.7591(3) 0.4772(2) 0.0514(18) Uani 1 1 d . . .
H36A H 0.8135 0.7657 0.4503 0.062 Uiso 1 1 calc R . .
C37 C 0.7991(3) 0.7962(3) 0.5132(3) 0.059(2) Uani 1 1 d . . .
H37A H 0.8274 0.8284 0.5110 0.071 Uiso 1 1 calc R . .
C38 C 0.7664(3) 0.7873(3) 0.5526(3) 0.0560(19) Uani 1 1 d . . .
H38A H 0.7717 0.8135 0.5771 0.067 Uiso 1 1 calc R . .
C39 C 0.7259(3) 0.7397(2) 0.5556(2) 0.0377(14) Uani 1 1 d . . .
H39A H 0.7036 0.7332 0.5826 0.045 Uiso 1 1 calc R . .
C40 C 0.8585(2) 0.5742(2) 0.44931(15) 0.0212(10) Uani 1 1 d . . .
H40A H 0.8650 0.6158 0.4599 0.025 Uiso 1 1 calc R . .
C41 C 0.8090(3) 0.5155(3) 0.36031(18) 0.0480(16) Uani 1 1 d . . .
H41A H 0.8038 0.5225 0.3282 0.072 Uiso 1 1 calc R . .
H41B H 0.7685 0.5062 0.3737 0.072 Uiso 1 1 calc R . .
H41C H 0.8376 0.4822 0.3649 0.072 Uiso 1 1 calc R . .
C42 C 0.9158(3) 0.6036(3) 0.3576(2) 0.0557(19) Uani 1 1 d . . .
H42A H 0.9073 0.6094 0.3257 0.084 Uiso 1 1 calc R . .
H42B H 0.9463 0.5717 0.3613 0.084 Uiso 1 1 calc R . .
H42C H 0.9324 0.6403 0.3703 0.084 Uiso 1 1 calc R . .
C43 C 0.7870(3) 0.6454(3) 0.37473(19) 0.0452(16) Uani 1 1 d . . .
H43A H 0.7848 0.6515 0.3424 0.068 Uiso 1 1 calc R . .
H43B H 0.8022 0.6816 0.3892 0.068 Uiso 1 1 calc R . .
H43C H 0.7455 0.6357 0.3862 0.068 Uiso 1 1 calc R . .
C44 C 0.9470(3) 0.4707(2) 0.42438(19) 0.0365(13) Uani 1 1 d . . .
H44A H 0.9867 0.4513 0.4315 0.055 Uiso 1 1 calc R . .
H44B H 0.9473 0.4836 0.3931 0.055 Uiso 1 1 calc R . .
H44C H 0.9128 0.4426 0.4291 0.055 Uiso 1 1 calc R . .
C45 C 1.0007(3) 0.5912(3) 0.4551(2) 0.0479(17) Uani 1 1 d . . .
H45A H 1.0401 0.5730 0.4644 0.072 Uiso 1 1 calc R . .
H45B H 0.9923 0.6259 0.4738 0.072 Uiso 1 1 calc R . .
H45C H 1.0037 0.6034 0.4238 0.072 Uiso 1 1 calc R . .
C46 C 0.9446(2) 0.5089(2) 0.52010(18) 0.0351(13) Uani 1 1 d . . .
H46A H 0.9838 0.4870 0.5230 0.053 Uiso 1 1 calc R . .
H46B H 0.9097 0.4826 0.5273 0.053 Uiso 1 1 calc R . .
H46C H 0.9446 0.5426 0.5407 0.053 Uiso 1 1 calc R . .
C47 C 0.8188(2) 0.57027(19) 0.54212(15) 0.0215(10) Uani 1 1 d . . .
C48 C 0.8415(2) 0.6276(2) 0.54932(17) 0.0273(11) Uani 1 1 d . . .
H48A H 0.8471 0.6537 0.5247 0.033 Uiso 1 1 calc R . .
C49 C 0.8556(2) 0.6465(2) 0.59197(18) 0.0329(13) Uani 1 1 d . . .
H49A H 0.8709 0.6856 0.5965 0.039 Uiso 1 1 calc R . .
C50 C 0.8477(3) 0.6092(3) 0.6280(2) 0.0462(16) Uani 1 1 d . . .
H50A H 0.8569 0.6225 0.6574 0.055 Uiso 1 1 calc R . .
C51 C 0.8262(3) 0.5518(3) 0.62086(18) 0.0374(13) Uani 1 1 d . . .
H51A H 0.8208 0.5256 0.6454 0.045 Uiso 1 1 calc R . .
C52 C 0.8128(2) 0.5327(2) 0.57811(17) 0.0291(12) Uani 1 1 d . . .
H52A H 0.7991 0.4931 0.5735 0.035 Uiso 1 1 calc R . .
C53 C 0.39846(19) 0.66623(18) 0.26173(14) 0.0146(9) Uani 1 1 d . . .
H53A H 0.4179 0.6318 0.2460 0.018 Uiso 1 1 calc R . .
C54 C 0.3669(3) 0.7062(3) 0.16410(17) 0.0369(14) Uani 1 1 d . . .
H54A H 0.3766 0.7363 0.1415 0.055 Uiso 1 1 calc R . .
H54B H 0.3216 0.7033 0.1677 0.055 Uiso 1 1 calc R . .
H54C H 0.3835 0.6678 0.1545 0.055 Uiso 1 1 calc R . .
C55 C 0.4868(2) 0.7433(3) 0.20610(19) 0.0374(14) Uani 1 1 d . . .
H55A H 0.4896 0.7719 0.1815 0.056 Uiso 1 1 calc R . .
H55B H 0.5077 0.7064 0.1975 0.056 Uiso 1 1 calc R . .
H55C H 0.5071 0.7598 0.2327 0.056 Uiso 1 1 calc R . .
C56 C 0.3669(3) 0.7997(2) 0.23658(18) 0.0304(12) Uani 1 1 d . . .
H56A H 0.3789 0.8310 0.2156 0.046 Uiso 1 1 calc R . .
H56B H 0.3814 0.8100 0.2666 0.046 Uiso 1 1 calc R . .
H56C H 0.3214 0.7956 0.2368 0.046 Uiso 1 1 calc R . .
C57 C 0.4278(3) 0.6309(2) 0.36007(17) 0.0349(13) Uani 1 1 d . . .
H57A H 0.4582 0.6352 0.3843 0.052 Uiso 1 1 calc R . .
H57B H 0.4259 0.5893 0.3507 0.052 Uiso 1 1 calc R . .
H57C H 0.3867 0.6435 0.3706 0.052 Uiso 1 1 calc R . .
C58 C 0.4514(3) 0.7560(2) 0.33196(18) 0.0377(14) Uani 1 1 d . . .
H58A H 0.4778 0.7596 0.3585 0.057 Uiso 1 1 calc R . .
H58B H 0.4088 0.7680 0.3394 0.057 Uiso 1 1 calc R . .
H58C H 0.4676 0.7818 0.3083 0.057 Uiso 1 1 calc R . .
C59 C 0.5334(2) 0.6565(2) 0.29709(19) 0.0344(13) Uani 1 1 d . . .
H59A H 0.5551 0.6418 0.3237 0.052 Uiso 1 1 calc R . .
H59B H 0.5553 0.6914 0.2855 0.052 Uiso 1 1 calc R . .
H59C H 0.5327 0.6254 0.2742 0.052 Uiso 1 1 calc R . .
C60 C 0.2664(2) 0.69856(19) 0.27464(17) 0.0240(11) Uani 1 1 d . . .
C61 C 0.2596(3) 0.7351(2) 0.3119(2) 0.0386(14) Uani 1 1 d . . .
H61A H 0.2850 0.7291 0.3375 0.046 Uiso 1 1 calc R . .
C62 C 0.2153(3) 0.7805(3) 0.3116(3) 0.061(2) Uani 1 1 d . . .
H62A H 0.2118 0.8060 0.3368 0.073 Uiso 1 1 calc R . .
C63 C 0.1771(3) 0.7887(3) 0.2760(3) 0.062(2) Uani 1 1 d . . .
H63A H 0.1464 0.8190 0.2768 0.074 Uiso 1 1 calc R . .
C64 C 0.1829(3) 0.7531(3) 0.2387(3) 0.056(2) Uani 1 1 d . . .
H64A H 0.1565 0.7589 0.2135 0.067 Uiso 1 1 calc R . .
C65 C 0.2277(3) 0.7087(2) 0.2383(2) 0.0377(14) Uani 1 1 d . . .
H65A H 0.2319 0.6845 0.2125 0.045 Uiso 1 1 calc R . .
C66 C 0.1223(2) 0.5773(2) 0.21048(16) 0.0222(10) Uani 1 1 d . . .
H66A H 0.1203 0.6191 0.2215 0.027 Uiso 1 1 calc R . .
C67 C 0.1926(3) 0.6388(3) 0.1302(2) 0.0506(18) Uani 1 1 d . . .
H67A H 0.1938 0.6417 0.0976 0.076 Uiso 1 1 calc R . .
H67B H 0.2328 0.6245 0.1412 0.076 Uiso 1 1 calc R . .
H67C H 0.1839 0.6780 0.1430 0.076 Uiso 1 1 calc R . .
C68 C 0.0559(3) 0.6208(3) 0.1256(2) 0.0418(15) Uani 1 1 d . . .
H68A H 0.0594 0.6270 0.0933 0.063 Uiso 1 1 calc R . .
H68B H 0.0493 0.6590 0.1404 0.063 Uiso 1 1 calc R . .
H68C H 0.0205 0.5946 0.1318 0.063 Uiso 1 1 calc R . .
C69 C 0.1420(3) 0.5154(3) 0.11642(18) 0.0461(16) Uani 1 1 d . . .
H69A H 0.1360 0.5222 0.0844 0.069 Uiso 1 1 calc R . .
H69B H 0.1120 0.4857 0.1269 0.069 Uiso 1 1 calc R . .
H69C H 0.1845 0.5011 0.1218 0.069 Uiso 1 1 calc R . .
C70 C -0.0154(3) 0.6055(3) 0.2294(2) 0.0402(15) Uani 1 1 d . . .
H70A H -0.0558 0.5893 0.2386 0.060 Uiso 1 1 calc R . .
H70B H -0.0191 0.6229 0.1995 0.060 Uiso 1 1 calc R . .
H70C H -0.0022 0.6360 0.2506 0.060 Uiso 1 1 calc R . .
C71 C 0.0418(2) 0.5124(2) 0.28550(18) 0.0315(12) Uani 1 1 d . . .
H71A H 0.0023 0.4916 0.2900 0.047 Uiso 1 1 calc R . .
H71B H 0.0457 0.5442 0.3076 0.047 Uiso 1 1 calc R . .
H71C H 0.0764 0.4844 0.2891 0.047 Uiso 1 1 calc R . .
C72 C 0.0208(3) 0.4828(2) 0.1900(2) 0.0408(14) Uani 1 1 d . . .
H72A H -0.0157 0.4624 0.2022 0.061 Uiso 1 1 calc R . .
H72B H 0.0554 0.4546 0.1873 0.061 Uiso 1 1 calc R . .
H72C H 0.0107 0.4989 0.1605 0.061 Uiso 1 1 calc R . .
C73 C 0.1733(2) 0.5653(2) 0.30061(15) 0.0202(10) Uani 1 1 d . . .
C74 C 0.1497(2) 0.6207(2) 0.31216(18) 0.0302(12) Uani 1 1 d . . .
H74A H 0.1395 0.6485 0.2895 0.036 Uiso 1 1 calc R . .
C75 C 0.1411(3) 0.6354(3) 0.3569(2) 0.0475(17) Uani 1 1 d . . .
H75A H 0.1239 0.6729 0.3645 0.057 Uiso 1 1 calc R . .
C76 C 0.1571(3) 0.5963(3) 0.3901(2) 0.0461(17) Uani 1 1 d . . .
H76A H 0.1520 0.6073 0.4205 0.055 Uiso 1 1 calc R . .
C77 C 0.1803(3) 0.5416(3) 0.37945(17) 0.0365(14) Uani 1 1 d . . .
H77A H 0.1911 0.5143 0.4024 0.044 Uiso 1 1 calc R . .
C78 C 0.1880(2) 0.5262(2) 0.33435(16) 0.0266(11) Uani 1 1 d . . .
H78A H 0.2037 0.4881 0.3270 0.032 Uiso 1 1 calc R . .
C79 C 0.3763(2) 0.4442(2) 0.19898(15) 0.0192(9) Uani 1 1 d . . .
H79A H 0.3803 0.4019 0.2086 0.023 Uiso 1 1 calc R . .
C80 C 0.5167(3) 0.4192(3) 0.2058(3) 0.068(2) Uani 1 1 d . . .
H80A H 0.5579 0.4378 0.2040 0.101 Uiso 1 1 calc R . .
H80B H 0.5085 0.3971 0.1782 0.101 Uiso 1 1 calc R . .
H80C H 0.5156 0.3919 0.2313 0.101 Uiso 1 1 calc R . .
C81 C 0.4715(3) 0.5433(3) 0.1769(2) 0.0496(17) Uani 1 1 d . . .
H81A H 0.5074 0.5652 0.1886 0.074 Uiso 1 1 calc R . .
H81B H 0.4348 0.5692 0.1768 0.074 Uiso 1 1 calc R . .
H81C H 0.4803 0.5300 0.1464 0.074 Uiso 1 1 calc R . .
C82 C 0.4653(2) 0.5041(2) 0.27160(17) 0.0289(12) Uani 1 1 d . . .
H82A H 0.5055 0.5243 0.2747 0.043 Uiso 1 1 calc R . .
H82B H 0.4636 0.4703 0.2921 0.043 Uiso 1 1 calc R . .
H82C H 0.4316 0.5318 0.2788 0.043 Uiso 1 1 calc R . .
C83 C 0.4336(3) 0.4134(3) 0.1071(2) 0.056(2) Uani 1 1 d . . .
H83A H 0.4264 0.4130 0.0748 0.084 Uiso 1 1 calc R . .
H83B H 0.4445 0.3735 0.1172 0.084 Uiso 1 1 calc R . .
H83C H 0.4678 0.4407 0.1140 0.084 Uiso 1 1 calc R . .
C84 C 0.3021(3) 0.3801(3) 0.12272(19) 0.0461(16) Uani 1 1 d . . .
H84A H 0.2980 0.3768 0.0902 0.069 Uiso 1 1 calc R . .
H84B H 0.2618 0.3909 0.1357 0.069 Uiso 1 1 calc R . .
H84C H 0.3158 0.3421 0.1350 0.069 Uiso 1 1 calc R . .
C85 C 0.3336(4) 0.5091(3) 0.10984(19) 0.0577(19) Uani 1 1 d . . .
H85A H 0.3270 0.5026 0.0778 0.087 Uiso 1 1 calc R . .
H85B H 0.3651 0.5400 0.1141 0.087 Uiso 1 1 calc R . .
H85C H 0.2944 0.5216 0.1237 0.087 Uiso 1 1 calc R . .
C86 C 0.3365(2) 0.44961(19) 0.29241(14) 0.0172(9) Uani 1 1 d . . .
C87 C 0.3279(2) 0.4873(2) 0.32818(16) 0.0234(11) Uani 1 1 d . . .
H87A H 0.3128 0.5263 0.3231 0.028 Uiso 1 1 calc R . .
C88 C 0.3409(2) 0.4690(3) 0.37161(18) 0.0340(13) Uani 1 1 d . . .
H88A H 0.3346 0.4950 0.3961 0.041 Uiso 1 1 calc R . .
C89 C 0.3634(3) 0.4115(3) 0.37846(19) 0.0376(14) Uani 1 1 d . . .
H89A H 0.3715 0.3981 0.4080 0.045 Uiso 1 1 calc R . .
C90 C 0.3736(2) 0.3747(2) 0.3432(2) 0.0349(14) Uani 1 1 d . . .
H90A H 0.3906 0.3364 0.3480 0.042 Uiso 1 1 calc R . .
C91 C 0.3596(2) 0.3932(2) 0.30062(18) 0.0273(12) Uani 1 1 d . . .
H91A H 0.3657 0.3667 0.2763 0.033 Uiso 1 1 calc R . .
C92 C 0.1073(2) 0.35186(19) 0.26954(15) 0.0177(9) Uani 1 1 d . . .
H92A H 0.0847 0.3866 0.2566 0.021 Uiso 1 1 calc R . .
C93 C 0.1355(3) 0.2197(2) 0.23869(18) 0.0302(12) Uani 1 1 d . . .
H93A H 0.1205 0.1893 0.2180 0.045 Uiso 1 1 calc R . .
H93B H 0.1260 0.2078 0.2694 0.045 Uiso 1 1 calc R . .
H93C H 0.1806 0.2244 0.2353 0.045 Uiso 1 1 calc R . .
C94 C 0.1212(3) 0.3160(3) 0.16942(17) 0.0388(14) Uani 1 1 d . . .
H94A H 0.1099 0.2856 0.1475 0.058 Uiso 1 1 calc R . .
H94B H 0.1665 0.3217 0.1692 0.058 Uiso 1 1 calc R . .
H94C H 0.1006 0.3534 0.1618 0.058 Uiso 1 1 calc R . .
C95 C 0.0105(2) 0.2755(3) 0.22158(19) 0.0399(14) Uani 1 1 d . . .
H95A H 0.0038 0.2443 0.1993 0.060 Uiso 1 1 calc R . .
H95B H -0.0118 0.3114 0.2124 0.060 Uiso 1 1 calc R . .
H95C H -0.0053 0.2621 0.2506 0.060 Uiso 1 1 calc R . .
C96 C -0.0199(2) 0.3537(3) 0.3193(2) 0.0412(15) Uani 1 1 d . . .
H96A H -0.0395 0.3514 0.3488 0.062 Uiso 1 1 calc R . .
H96B H -0.0388 0.3242 0.2994 0.062 Uiso 1 1 calc R . .
H96C H -0.0262 0.3934 0.3068 0.062 Uiso 1 1 calc R . .
C97 C 0.0950(3) 0.3872(2) 0.37066(16) 0.0310(12) Uani 1 1 d . . .
H97A H 0.0714 0.3793 0.3980 0.046 Uiso 1 1 calc R . .
H97B H 0.0899 0.4289 0.3621 0.046 Uiso 1 1 calc R . .
H97C H 0.1392 0.3790 0.3759 0.046 Uiso 1 1 calc R . .
C98 C 0.0753(3) 0.2600(2) 0.34432(18) 0.0342(13) Uani 1 1 d . . .
H98A H 0.0575 0.2559 0.3743 0.051 Uiso 1 1 calc R . .
H98B H 0.1197 0.2499 0.3451 0.051 Uiso 1 1 calc R . .
H98C H 0.0537 0.2332 0.3237 0.051 Uiso 1 1 calc R . .
C99 C 0.2401(2) 0.3189(2) 0.26986(17) 0.0213(10) Uani 1 1 d . . .
C100 C 0.2530(2) 0.2817(2) 0.30614(19) 0.0311(12) Uani 1 1 d . . .
H10B H 0.2345 0.2896 0.3344 0.037 Uiso 1 1 calc R . .
C101 C 0.2926(3) 0.2332(3) 0.3013(2) 0.0499(17) Uani 1 1 d . . .
H10C H 0.2983 0.2066 0.3256 0.060 Uiso 1 1 calc R . .
C102 C 0.3232(3) 0.2237(3) 0.2618(3) 0.0545(19) Uani 1 1 d . . .
H10D H 0.3521 0.1921 0.2593 0.065 Uiso 1 1 calc R . .
C103 C 0.3121(3) 0.2602(3) 0.2257(2) 0.0453(16) Uani 1 1 d . . .
H10E H 0.3323 0.2531 0.1980 0.054 Uiso 1 1 calc R . .
C104 C 0.2707(2) 0.3078(2) 0.23018(19) 0.0314(12) Uani 1 1 d . . .
H10F H 0.2634 0.3330 0.2053 0.038 Uiso 1 1 calc R . .
C105 C 0.6382(3) 0.5508(4) 0.7458(3) 0.085(3) Uani 1 1 d . . .
H10G H 0.6181 0.5878 0.7550 0.127 Uiso 1 1 calc R . .
H10H H 0.6245 0.5184 0.7653 0.127 Uiso 1 1 calc R . .
H10I H 0.6268 0.5417 0.7148 0.127 Uiso 1 1 calc R . .
C106 C 0.7052(3) 0.5572(3) 0.7490(3) 0.0603(19) Uani 1 1 d . . .
H10J H 0.7197 0.5866 0.7268 0.072 Uiso 1 1 calc R . .
H10K H 0.7163 0.5719 0.7791 0.072 Uiso 1 1 calc R . .
C107 C 0.7993(3) 0.5048(4) 0.7472(2) 0.061(2) Uani 1 1 d . . .
H10L H 0.8091 0.5178 0.7780 0.073 Uiso 1 1 calc R . .
H10M H 0.8178 0.5338 0.7262 0.073 Uiso 1 1 calc R . .
C108 C 0.8264(4) 0.4452(4) 0.7392(3) 0.101(3) Uani 1 1 d . . .
H10N H 0.8719 0.4481 0.7385 0.152 Uiso 1 1 calc R . .
H10O H 0.8114 0.4299 0.7105 0.152 Uiso 1 1 calc R . .
H10P H 0.8137 0.4182 0.7632 0.152 Uiso 1 1 calc R . .
C109 C 0.1121(3) 0.4489(3) 0.4851(2) 0.0496(16) Uani 1 1 d . . .
H10Q H 0.0881 0.4122 0.4818 0.074 Uiso 1 1 calc R . .
H10R H 0.1052 0.4742 0.4590 0.074 Uiso 1 1 calc R . .
H10S H 0.0988 0.4697 0.5121 0.074 Uiso 1 1 calc R . .
C110 C 0.1805(3) 0.4341(3) 0.4887(2) 0.0431(15) Uani 1 1 d . . .
H11B H 0.1883 0.4102 0.5158 0.052 Uiso 1 1 calc R . .
H11C H 0.1938 0.4107 0.4623 0.052 Uiso 1 1 calc R . .
C111 C 0.2796(3) 0.4780(3) 0.4963(2) 0.0501(17) Uani 1 1 d . . .
H11D H 0.2963 0.4549 0.4709 0.060 Uiso 1 1 calc R . .
H11F H 0.2876 0.4555 0.5242 0.060 Uiso 1 1 calc R . .
C112 C 0.3103(3) 0.5368(3) 0.4985(3) 0.069(2) Uani 1 1 d . . .
H11E H 0.3549 0.5316 0.5044 0.103 Uiso 1 1 calc R . .
H11I H 0.2915 0.5603 0.5225 0.103 Uiso 1 1 calc R . .
H11G H 0.3048 0.5575 0.4700 0.103 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ge1 P2 96.86(4) . . ?
P1 Ge1 P4 107.65(4) . . ?
P2 Ge1 P4 80.62(4) . . ?
P2 Ge2 P3 104.89(4) . . ?
P2 Ge2 P4 80.44(4) . . ?
P3 Ge2 P4 99.54(4) . . ?
P6 Ge3 P7 80.44(4) . . ?
P6 Ge3 P8 104.91(4) . . ?
P7 Ge3 P8 97.96(4) . . ?
P5 Ge4 P6 98.97(4) . . ?
P5 Ge4 P7 106.60(4) . . ?
P6 Ge4 P7 80.60(4) . . ?
Ge1 P1 C1 103.24(14) . . ?
Ge1 P1 C8 100.09(16) . . ?
C1 P1 C8 103.7(2) . . ?
Ge1 P2 Ge2 90.78(4) . . ?
Ge1 P2 C14 114.32(15) . . ?
Ge1 P2 C21 111.00(15) . . ?
Ge2 P2 C14 112.22(15) . . ?
Ge2 P2 C21 123.23(16) . . ?
C14 P2 C21 105.2(2) . . ?
Ge2 P3 C27 101.11(15) . . ?
Ge2 P3 C34 100.75(16) . . ?
C27 P3 C34 105.4(2) . . ?
Ge1 P4 Ge2 90.95(4) . . ?
Ge1 P4 C40 109.14(16) . . ?
Ge1 P4 C47 124.63(15) . . ?
Ge2 P4 C40 115.20(15) . . ?
Ge2 P4 C47 113.07(15) . . ?
C40 P4 C47 104.1(2) . . ?
Ge4 P5 C53 101.59(14) . . ?
Ge4 P5 C60 100.66(17) . . ?
C53 P5 C60 104.6(2) . . ?
Ge3 P6 Ge4 90.80(4) . . ?
Ge3 P6 C66 110.20(16) . . ?
Ge3 P6 C73 123.91(15) . . ?
Ge4 P6 C66 114.78(15) . . ?
Ge4 P6 C73 112.42(15) . . ?
C66 P6 C73 104.8(2) . . ?
Ge3 P7 Ge4 90.89(4) . . ?
Ge3 P7 C79 115.13(15) . . ?
Ge3 P7 C86 112.15(14) . . ?
Ge4 P7 C79 110.37(15) . . ?
Ge4 P7 C86 123.64(15) . . ?
C79 P7 C86 104.8(2) . . ?
Ge3 P8 C92 103.16(15) . . ?
Ge3 P8 C99 101.01(16) . . ?
C92 P8 C99 103.7(2) . . ?
C1 Si1 C2 108.4(2) . . ?
C1 Si1 C3 113.1(2) . . ?
C1 Si1 C4 115.2(2) . . ?
C2 Si1 C3 105.1(3) . . ?
C2 Si1 C4 106.9(3) . . ?
C3 Si1 C4 107.5(3) . . ?
C1 Si2 C5 112.8(2) . . ?
C1 Si2 C6 111.0(2) . . ?
C1 Si2 C7 112.5(2) . . ?
C5 Si2 C6 105.8(3) . . ?
C5 Si2 C7 106.8(3) . . ?
C6 Si2 C7 107.6(3) . . ?
C14 Si3 C15 107.7(2) . . ?
C14 Si3 C16 111.4(2) . . ?
C14 Si3 C17 116.1(2) . . ?
C15 Si3 C16 111.0(3) . . ?
C15 Si3 C17 105.9(3) . . ?
C16 Si3 C17 104.7(2) . . ?
C14 Si4 C18 108.3(2) . . ?
C14 Si4 C19 114.5(2) . . ?
C14 Si4 C20 113.7(2) . . ?
C18 Si4 C19 108.6(3) . . ?
C18 Si4 C20 103.2(2) . . ?
C19 Si4 C20 107.9(3) . . ?
C27 Si5 C28 109.2(2) . . ?
C27 Si5 C29 111.4(2) . . ?
C27 Si5 C30 113.1(2) . . ?
C28 Si5 C29 108.7(3) . . ?
C28 Si5 C30 109.2(3) . . ?
C29 Si5 C30 105.0(3) . . ?
C27 Si6 C31 111.2(2) . . ?
C27 Si6 C32 109.4(3) . . ?
C27 Si6 C33 114.8(2) . . ?
C31 Si6 C32 106.3(3) . . ?
C31 Si6 C33 108.2(3) . . ?
C32 Si6 C33 106.5(3) . . ?
C40 Si7 C41 114.0(2) . . ?
C40 Si7 C42 108.7(3) . . ?
C40 Si7 C43 113.1(2) . . ?
C41 Si7 C42 108.5(3) . . ?
C41 Si7 C43 107.4(3) . . ?
C42 Si7 C43 104.6(3) . . ?
C40 Si8 C44 110.5(2) . . ?
C40 Si8 C45 109.4(2) . . ?
C40 Si8 C46 114.4(2) . . ?
C44 Si8 C45 111.8(3) . . ?
C44 Si8 C46 106.4(3) . . ?
C45 Si8 C46 104.1(3) . . ?
C53 Si9 C54 112.4(2) . . ?
C53 Si9 C55 109.0(2) . . ?
C53 Si9 C56 114.8(2) . . ?
C54 Si9 C55 105.6(3) . . ?
C54 Si9 C56 107.5(3) . . ?
C55 Si9 C56 107.1(3) . . ?
C53 Si10 C57 112.0(2) . . ?
C53 Si10 C58 112.0(2) . . ?
C53 Si10 C59 109.6(2) . . ?
C57 Si10 C58 107.1(3) . . ?
C57 Si10 C59 107.6(3) . . ?
C58 Si10 C59 108.4(3) . . ?
C66 Si11 C67 113.2(2) . . ?
C66 Si11 C68 108.3(2) . . ?
C66 Si11 C69 114.6(2) . . ?
C67 Si11 C68 104.3(3) . . ?
C67 Si11 C69 108.0(3) . . ?
C68 Si11 C69 107.9(3) . . ?
C66 Si12 C70 108.6(2) . . ?
C66 Si12 C71 115.3(2) . . ?
C66 Si12 C72 110.6(2) . . ?
C70 Si12 C71 104.6(3) . . ?
C70 Si12 C72 112.3(3) . . ?
C71 Si12 C72 105.5(3) . . ?
C79 Si13 C80 108.6(3) . . ?
C79 Si13 C81 109.9(3) . . ?
C79 Si13 C82 115.5(2) . . ?
C80 Si13 C81 111.6(3) . . ?
C80 Si13 C82 105.4(3) . . ?
C81 Si13 C82 105.8(3) . . ?
C79 Si14 C83 109.5(3) . . ?
C79 Si14 C84 112.4(2) . . ?
C79 Si14 C85 114.6(2) . . ?
C83 Si14 C84 104.2(3) . . ?
C83 Si14 C85 108.5(3) . . ?
C84 Si14 C85 107.2(3) . . ?
C92 Si15 C93 115.2(2) . . ?
C92 Si15 C94 112.3(2) . . ?
C92 Si15 C95 108.4(2) . . ?
C93 Si15 C94 107.8(3) . . ?
C93 Si15 C95 106.6(3) . . ?
C94 Si15 C95 106.0(3) . . ?
C92 Si16 C96 110.9(2) . . ?
C92 Si16 C97 112.9(2) . . ?
C92 Si16 C98 111.6(2) . . ?
C96 Si16 C97 106.7(3) . . ?
C96 Si16 C98 107.8(3) . . ?
C97 Si16 C98 106.7(3) . . ?
C106 O1 C107 113.9(6) . . ?
C110 O2 C111 112.6(5) . . ?
P1 C1 Si1 120.6(2) . . ?
P1 C1 Si2 108.1(2) . . ?
P1 C1 H1A 103.4 . . ?
Si1 C1 Si2 115.6(2) . . ?
Si1 C1 H1A 103.4 . . ?
Si2 C1 H1A 103.4 . . ?
Si1 C2 H2A 109.5 . . ?
Si1 C2 H2B 109.5 . . ?
Si1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si1 C4 H4A 109.5 . . ?
Si1 C4 H4B 109.5 . . ?
Si1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si2 C5 H5A 109.5 . . ?
Si2 C5 H5B 109.5 . . ?
Si2 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si2 C6 H6A 109.5 . . ?
Si2 C6 H6B 109.5 . . ?
Si2 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si2 C7 H7A 109.5 . . ?
Si2 C7 H7B 109.5 . . ?
Si2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
P1 C8 C9 124.5(4) . . ?
P1 C8 C13 117.4(4) . . ?
C9 C8 C13 118.0(5) . . ?
C8 C9 H9A 119.4 . . ?
C8 C9 C10 121.2(5) . . ?
H9A C9 C10 119.4 . . ?
C9 C10 H10A 120.1 . . ?
C9 C10 C11 119.8(6) . . ?
H10A C10 C11 120.1 . . ?
C10 C11 H11A 120.0 . . ?
C10 C11 C12 119.9(5) . . ?
H11A C11 C12 120.0 . . ?
C11 C12 H12A 119.9 . . ?
C11 C12 C13 120.2(5) . . ?
H12A C12 C13 119.9 . . ?
C8 C13 C12 120.9(5) . . ?
C8 C13 H13A 119.6 . . ?
C12 C13 H13A 119.6 . . ?
P2 C14 Si3 113.6(2) . . ?
P2 C14 Si4 118.9(2) . . ?
P2 C14 H14A 103.0 . . ?
Si3 C14 Si4 112.8(2) . . ?
Si3 C14 H14A 103.0 . . ?
Si4 C14 H14A 103.0 . . ?
Si3 C15 H15A 109.5 . . ?
Si3 C15 H15B 109.5 . . ?
Si3 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Si3 C16 H16A 109.5 . . ?
Si3 C16 H16B 109.5 . . ?
Si3 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si3 C17 H17A 109.5 . . ?
Si3 C17 H17B 109.5 . . ?
Si3 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si4 C18 H18A 109.5 . . ?
Si4 C18 H18B 109.5 . . ?
Si4 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si4 C19 H19A 109.5 . . ?
Si4 C19 H19B 109.5 . . ?
Si4 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si4 C20 H20A 109.5 . . ?
Si4 C20 H20B 109.5 . . ?
Si4 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
P2 C21 C22 120.1(4) . . ?
P2 C21 C26 121.9(4) . . ?
C22 C21 C26 117.9(4) . . ?
C21 C22 H22A 119.2 . . ?
C21 C22 C23 121.6(5) . . ?
H22A C22 C23 119.2 . . ?
C22 C23 H23A 120.1 . . ?
C22 C23 C24 119.9(6) . . ?
H23A C23 C24 120.1 . . ?
C23 C24 H24A 120.4 . . ?
C23 C24 C25 119.1(5) . . ?
H24A C24 C25 120.4 . . ?
C24 C25 H25A 119.5 . . ?
C24 C25 C26 121.1(5) . . ?
H25A C25 C26 119.5 . . ?
C21 C26 C25 120.3(5) . . ?
C21 C26 H26A 119.9 . . ?
C25 C26 H26A 119.9 . . ?
P3 C27 Si5 110.4(2) . . ?
P3 C27 Si6 120.0(3) . . ?
P3 C27 H27A 103.1 . . ?
Si5 C27 Si6 114.5(2) . . ?
Si5 C27 H27A 103.1 . . ?
Si6 C27 H27A 103.1 . . ?
Si5 C28 H28A 109.5 . . ?
Si5 C28 H28B 109.5 . . ?
Si5 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Si5 C29 H29A 109.5 . . ?
Si5 C29 H29B 109.5 . . ?
Si5 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
Si5 C30 H30A 109.5 . . ?
Si5 C30 H30B 109.5 . . ?
Si5 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
Si6 C31 H31A 109.5 . . ?
Si6 C31 H31B 109.5 . . ?
Si6 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
Si6 C32 H32A 109.5 . . ?
Si6 C32 H32B 109.5 . . ?
Si6 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
Si6 C33 H33A 109.5 . . ?
Si6 C33 H33B 109.5 . . ?
Si6 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
P3 C34 C35 125.2(4) . . ?
P3 C34 C39 116.3(4) . . ?
C35 C34 C39 118.4(5) . . ?
C34 C35 H35A 119.3 . . ?
C34 C35 C36 121.4(6) . . ?
H35A C35 C36 119.3 . . ?
C35 C36 H36A 120.5 . . ?
C35 C36 C37 119.1(6) . . ?
H36A C36 C37 120.5 . . ?
C36 C37 H37A 119.5 . . ?
C36 C37 C38 121.0(6) . . ?
H37A C37 C38 119.5 . . ?
C37 C38 H38A 120.4 . . ?
C37 C38 C39 119.1(6) . . ?
H38A C38 C39 120.4 . . ?
C34 C39 C38 121.0(6) . . ?
C34 C39 H39A 119.5 . . ?
C38 C39 H39A 119.5 . . ?
P4 C40 Si7 118.5(2) . . ?
P4 C40 Si8 111.3(2) . . ?
P4 C40 H40A 103.8 . . ?
Si7 C40 Si8 113.7(2) . . ?
Si7 C40 H40A 103.8 . . ?
Si8 C40 H40A 103.8 . . ?
Si7 C41 H41A 109.5 . . ?
Si7 C41 H41B 109.5 . . ?
Si7 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si7 C42 H42A 109.5 . . ?
Si7 C42 H42B 109.5 . . ?
Si7 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Si7 C43 H43A 109.5 . . ?
Si7 C43 H43B 109.5 . . ?
Si7 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
Si8 C44 H44A 109.5 . . ?
Si8 C44 H44B 109.5 . . ?
Si8 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
Si8 C45 H45A 109.5 . . ?
Si8 C45 H45B 109.5 . . ?
Si8 C45 H45C 109.5 . . ?
H45A C45 H45B 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
Si8 C46 H46A 109.5 . . ?
Si8 C46 H46B 109.5 . . ?
Si8 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
P4 C47 C48 121.0(4) . . ?
P4 C47 C52 120.2(4) . . ?
C48 C47 C52 118.8(4) . . ?
C47 C48 H48A 119.8 . . ?
C47 C48 C49 120.3(5) . . ?
H48A C48 C49 119.8 . . ?
C48 C49 H49A 119.7 . . ?
C48 C49 C50 120.6(5) . . ?
H49A C49 C50 119.7 . . ?
C49 C50 H50A 120.4 . . ?
C49 C50 C51 119.2(5) . . ?
H50A C50 C51 120.4 . . ?
C50 C51 H51A 119.9 . . ?
C50 C51 C52 120.2(5) . . ?
H51A C51 C52 119.9 . . ?
C47 C52 C51 120.9(5) . . ?
C47 C52 H52A 119.6 . . ?
C51 C52 H52A 119.6 . . ?
P5 C53 Si9 120.8(2) . . ?
P5 C53 Si10 109.9(2) . . ?
P5 C53 H53A 103.1 . . ?
Si9 C53 Si10 114.2(2) . . ?
Si9 C53 H53A 103.1 . . ?
Si10 C53 H53A 103.1 . . ?
Si9 C54 H54A 109.5 . . ?
Si9 C54 H54B 109.5 . . ?
Si9 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
Si9 C55 H55A 109.5 . . ?
Si9 C55 H55B 109.5 . . ?
Si9 C55 H55C 109.5 . . ?
H55A C55 H55B 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
Si9 C56 H56A 109.5 . . ?
Si9 C56 H56B 109.5 . . ?
Si9 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
Si10 C57 H57A 109.5 . . ?
Si10 C57 H57B 109.5 . . ?
Si10 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
Si10 C58 H58A 109.5 . . ?
Si10 C58 H58B 109.5 . . ?
Si10 C58 H58C 109.5 . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
Si10 C59 H59A 109.5 . . ?
Si10 C59 H59B 109.5 . . ?
Si10 C59 H59C 109.5 . . ?
H59A C59 H59B 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
P5 C60 C61 116.4(4) . . ?
P5 C60 C65 125.4(4) . . ?
C61 C60 C65 117.8(5) . . ?
C60 C61 H61A 120.0 . . ?
C60 C61 C62 120.0(6) . . ?
H61A C61 C62 120.0 . . ?
C61 C62 H62A 119.5 . . ?
C61 C62 C63 121.0(7) . . ?
H62A C62 C63 119.5 . . ?
C62 C63 H63A 119.9 . . ?
C62 C63 C64 120.2(6) . . ?
H63A C63 C64 119.9 . . ?
C63 C64 H64A 120.4 . . ?
C63 C64 C65 119.1(6) . . ?
H64A C64 C65 120.4 . . ?
C60 C65 C64 121.9(6) . . ?
C60 C65 H65A 119.1 . . ?
C64 C65 H65A 119.1 . . ?
P6 C66 Si11 118.9(2) . . ?
P6 C66 Si12 112.3(2) . . ?
P6 C66 H66A 103.6 . . ?
Si11 C66 Si12 112.7(2) . . ?
Si11 C66 H66A 103.6 . . ?
Si12 C66 H66A 103.6 . . ?
Si11 C67 H67A 109.5 . . ?
Si11 C67 H67B 109.5 . . ?
Si11 C67 H67C 109.5 . . ?
H67A C67 H67B 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
Si11 C68 H68A 109.5 . . ?
Si11 C68 H68B 109.5 . . ?
Si11 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
Si11 C69 H69A 109.5 . . ?
Si11 C69 H69B 109.5 . . ?
Si11 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
Si12 C70 H70A 109.5 . . ?
Si12 C70 H70B 109.5 . . ?
Si12 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
Si12 C71 H71A 109.5 . . ?
Si12 C71 H71B 109.5 . . ?
Si12 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
Si12 C72 H72A 109.5 . . ?
Si12 C72 H72B 109.5 . . ?
Si12 C72 H72C 109.5 . . ?
H72A C72 H72B 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
P6 C73 C74 121.5(4) . . ?
P6 C73 C78 120.0(4) . . ?
C74 C73 C78 118.4(5) . . ?
C73 C74 H74A 119.9 . . ?
C73 C74 C75 120.2(5) . . ?
H74A C74 C75 119.9 . . ?
C74 C75 H75A 119.7 . . ?
C74 C75 C76 120.6(5) . . ?
H75A C75 C76 119.7 . . ?
C75 C76 H76A 119.9 . . ?
C75 C76 C77 120.2(5) . . ?
H76A C76 C77 119.9 . . ?
C76 C77 H77A 120.4 . . ?
C76 C77 C78 119.3(6) . . ?
H77A C77 C78 120.4 . . ?
C73 C78 C77 121.3(5) . . ?
C73 C78 H78A 119.3 . . ?
C77 C78 H78A 119.3 . . ?
P7 C79 Si13 111.4(2) . . ?
P7 C79 Si14 119.1(2) . . ?
P7 C79 H79A 103.5 . . ?
Si13 C79 Si14 113.6(2) . . ?
Si13 C79 H79A 103.5 . . ?
Si14 C79 H79A 103.5 . . ?
Si13 C80 H80A 109.5 . . ?
Si13 C80 H80B 109.5 . . ?
Si13 C80 H80C 109.5 . . ?
H80A C80 H80B 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
Si13 C81 H81A 109.5 . . ?
Si13 C81 H81B 109.5 . . ?
Si13 C81 H81C 109.5 . . ?
H81A C81 H81B 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
Si13 C82 H82A 109.5 . . ?
Si13 C82 H82B 109.5 . . ?
Si13 C82 H82C 109.5 . . ?
H82A C82 H82B 109.5 . . ?
H82A C82 H82C 109.5 . . ?
H82B C82 H82C 109.5 . . ?
Si14 C83 H83A 109.5 . . ?
Si14 C83 H83B 109.5 . . ?
Si14 C83 H83C 109.5 . . ?
H83A C83 H83B 109.5 . . ?
H83A C83 H83C 109.5 . . ?
H83B C83 H83C 109.5 . . ?
Si14 C84 H84A 109.5 . . ?
Si14 C84 H84B 109.5 . . ?
Si14 C84 H84C 109.5 . . ?
H84A C84 H84B 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
Si14 C85 H85A 109.5 . . ?
Si14 C85 H85B 109.5 . . ?
Si14 C85 H85C 109.5 . . ?
H85A C85 H85B 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
P7 C86 C87 119.6(3) . . ?
P7 C86 C91 121.9(4) . . ?
C87 C86 C91 118.4(4) . . ?
C86 C87 H87A 119.5 . . ?
C86 C87 C88 121.0(5) . . ?
H87A C87 C88 119.5 . . ?
C87 C88 H88A 120.6 . . ?
C87 C88 C89 118.8(5) . . ?
H88A C88 C89 120.6 . . ?
C88 C89 H89A 119.8 . . ?
C88 C89 C90 120.5(5) . . ?
H89A C89 C90 119.8 . . ?
C89 C90 H90A 120.0 . . ?
C89 C90 C91 119.9(5) . . ?
H90A C90 C91 120.0 . . ?
C86 C91 C90 121.4(5) . . ?
C86 C91 H91A 119.3 . . ?
C90 C91 H91A 119.3 . . ?
P8 C92 Si15 120.1(2) . . ?
P8 C92 Si16 109.1(2) . . ?
P8 C92 H92A 103.4 . . ?
Si15 C92 Si16 115.1(2) . . ?
Si15 C92 H92A 103.4 . . ?
Si16 C92 H92A 103.4 . . ?
Si15 C93 H93A 109.5 . . ?
Si15 C93 H93B 109.5 . . ?
Si15 C93 H93C 109.5 . . ?
H93A C93 H93B 109.5 . . ?
H93A C93 H93C 109.5 . . ?
H93B C93 H93C 109.5 . . ?
Si15 C94 H94A 109.5 . . ?
Si15 C94 H94B 109.5 . . ?
Si15 C94 H94C 109.5 . . ?
H94A C94 H94B 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
Si15 C95 H95A 109.5 . . ?
Si15 C95 H95B 109.5 . . ?
Si15 C95 H95C 109.5 . . ?
H95A C95 H95B 109.5 . . ?
H95A C95 H95C 109.5 . . ?
H95B C95 H95C 109.5 . . ?
Si16 C96 H96A 109.5 . . ?
Si16 C96 H96B 109.5 . . ?
Si16 C96 H96C 109.5 . . ?
H96A C96 H96B 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
Si16 C97 H97A 109.5 . . ?
Si16 C97 H97B 109.5 . . ?
Si16 C97 H97C 109.5 . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
Si16 C98 H98A 109.5 . . ?
Si16 C98 H98B 109.5 . . ?
Si16 C98 H98C 109.5 . . ?
H98A C98 H98B 109.5 . . ?
H98A C98 H98C 109.5 . . ?
H98B C98 H98C 109.5 . . ?
P8 C99 C100 116.3(4) . . ?
P8 C99 C104 125.9(4) . . ?
C100 C99 C104 117.7(5) . . ?
C99 C100 H10B 119.6 . . ?
C99 C100 C101 120.8(5) . . ?
H10B C100 C101 119.6 . . ?
C100 C101 H10C 119.9 . . ?
C100 C101 C102 120.3(6) . . ?
H10C C101 C102 119.9 . . ?
C101 C102 H10D 120.0 . . ?
C101 C102 C103 120.1(5) . . ?
H10D C102 C103 120.0 . . ?
C102 C103 H10E 120.3 . . ?
C102 C103 C104 119.4(6) . . ?
H10E C103 C104 120.3 . . ?
C99 C104 C103 121.6(5) . . ?
C99 C104 H10F 119.2 . . ?
C103 C104 H10F 119.2 . . ?
H10G C105 H10H 109.5 . . ?
H10G C105 H10I 109.5 . . ?
H10G C105 C106 109.5 . . ?
H10H C105 H10I 109.5 . . ?
H10H C105 C106 109.5 . . ?
H10I C105 C106 109.5 . . ?
O1 C106 C105 110.7(7) . . ?
O1 C106 H10J 109.5 . . ?
O1 C106 H10K 109.5 . . ?
C105 C106 H10J 109.5 . . ?
C105 C106 H10K 109.5 . . ?
H10J C106 H10K 108.1 . . ?
O1 C107 H10L 109.7 . . ?
O1 C107 H10M 109.7 . . ?
O1 C107 C108 110.0(7) . . ?
H10L C107 H10M 108.2 . . ?
H10L C107 C108 109.7 . . ?
H10M C107 C108 109.7 . . ?
C107 C108 H10N 109.5 . . ?
C107 C108 H10O 109.5 . . ?
C107 C108 H10P 109.5 . . ?
H10N C108 H10O 109.5 . . ?
H10N C108 H10P 109.5 . . ?
H10O C108 H10P 109.5 . . ?
H10Q C109 H10R 109.5 . . ?
H10Q C109 H10S 109.5 . . ?
H10Q C109 C110 109.5 . . ?
H10R C109 H10S 109.5 . . ?
H10R C109 C110 109.5 . . ?
H10S C109 C110 109.5 . . ?
O2 C110 C109 108.3(5) . . ?
O2 C110 H11B 110.0 . . ?
O2 C110 H11C 110.0 . . ?
C109 C110 H11B 110.0 . . ?
C109 C110 H11C 110.0 . . ?
H11B C110 H11C 108.4 . . ?
O2 C111 H11D 110.1 . . ?
O2 C111 H11F 110.1 . . ?
O2 C111 C112 108.0(6) . . ?
H11D C111 H11F 108.4 . . ?
H11D C111 C112 110.1 . . ?
H11F C111 C112 110.1 . . ?
C111 C112 H11E 109.5 . . ?
C111 C112 H11I 109.5 . . ?
C111 C112 H11G 109.5 . . ?
H11E C112 H11I 109.5 . . ?
H11E C112 H11G 109.5 . . ?
H11I C112 H11G 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 P1 2.4151(13) . ?
Ge1 P2 2.4362(13) . ?
Ge1 P4 2.4361(12) . ?
Ge2 P2 2.4442(12) . ?
Ge2 P3 2.4153(13) . ?
Ge2 P4 2.4369(13) . ?
Ge3 P6 2.4450(12) . ?
Ge3 P7 2.4379(12) . ?
Ge3 P8 2.4149(12) . ?
Ge4 P5 2.4135(13) . ?
Ge4 P6 2.4359(12) . ?
Ge4 P7 2.4389(12) . ?
P1 C1 1.897(5) . ?
P1 C8 1.847(5) . ?
P2 C14 1.853(4) . ?
P2 C21 1.824(5) . ?
P3 C27 1.896(5) . ?
P3 C34 1.854(5) . ?
P4 C40 1.853(5) . ?
P4 C47 1.833(5) . ?
P5 C53 1.891(4) . ?
P5 C60 1.841(5) . ?
P6 C66 1.850(5) . ?
P6 C73 1.839(5) . ?
P7 C79 1.858(4) . ?
P7 C86 1.835(4) . ?
P8 C92 1.902(4) . ?
P8 C99 1.845(5) . ?
Si1 C1 1.888(5) . ?
Si1 C2 1.882(5) . ?
Si1 C3 1.871(5) . ?
Si1 C4 1.870(5) . ?
Si2 C1 1.908(5) . ?
Si2 C5 1.865(6) . ?
Si2 C6 1.869(6) . ?
Si2 C7 1.872(5) . ?
Si3 C14 1.917(5) . ?
Si3 C15 1.867(5) . ?
Si3 C16 1.871(5) . ?
Si3 C17 1.871(6) . ?
Si4 C14 1.909(5) . ?
Si4 C18 1.882(5) . ?
Si4 C19 1.863(6) . ?
Si4 C20 1.876(5) . ?
Si5 C27 1.904(5) . ?
Si5 C28 1.879(6) . ?
Si5 C29 1.879(6) . ?
Si5 C30 1.872(6) . ?
Si6 C27 1.893(5) . ?
Si6 C31 1.880(6) . ?
Si6 C32 1.884(6) . ?
Si6 C33 1.875(6) . ?
Si7 C40 1.909(5) . ?
Si7 C41 1.858(6) . ?
Si7 C42 1.882(6) . ?
Si7 C43 1.864(6) . ?
Si8 C40 1.907(5) . ?
Si8 C44 1.869(5) . ?
Si8 C45 1.867(5) . ?
Si8 C46 1.869(6) . ?
Si9 C53 1.895(4) . ?
Si9 C54 1.876(5) . ?
Si9 C55 1.872(5) . ?
Si9 C56 1.876(5) . ?
Si10 C53 1.909(4) . ?
Si10 C57 1.848(5) . ?
Si10 C58 1.870(5) . ?
Si10 C59 1.877(5) . ?
Si11 C66 1.911(5) . ?
Si11 C67 1.873(6) . ?
Si11 C68 1.884(5) . ?
Si11 C69 1.857(6) . ?
Si12 C66 1.914(5) . ?
Si12 C70 1.875(5) . ?
Si12 C71 1.863(5) . ?
Si12 C72 1.869(5) . ?
Si13 C79 1.918(4) . ?
Si13 C80 1.867(6) . ?
Si13 C81 1.868(6) . ?
Si13 C82 1.857(5) . ?
Si14 C79 1.905(5) . ?
Si14 C83 1.880(6) . ?
Si14 C84 1.871(6) . ?
Si14 C85 1.873(7) . ?
Si15 C92 1.892(5) . ?
Si15 C93 1.874(5) . ?
Si15 C94 1.863(6) . ?
Si15 C95 1.878(5) . ?
Si16 C92 1.900(5) . ?
Si16 C96 1.877(5) . ?
Si16 C97 1.869(5) . ?
Si16 C98 1.880(5) . ?
O1 C106 1.395(8) . ?
O1 C107 1.397(8) . ?
O2 C110 1.404(7) . ?
O2 C111 1.430(7) . ?
C1 H1A 1.000 . ?
C2 H2A 0.980 . ?
C2 H2B 0.980 . ?
C2 H2C 0.980 . ?
C3 H3A 0.980 . ?
C3 H3B 0.980 . ?
C3 H3C 0.980 . ?
C4 H4A 0.980 . ?
C4 H4B 0.980 . ?
C4 H4C 0.980 . ?
C5 H5A 0.980 . ?
C5 H5B 0.980 . ?
C5 H5C 0.980 . ?
C6 H6A 0.980 . ?
C6 H6B 0.980 . ?
C6 H6C 0.980 . ?
C7 H7A 0.980 . ?
C7 H7B 0.980 . ?
C7 H7C 0.980 . ?
C8 C9 1.392(7) . ?
C8 C13 1.391(7) . ?
C9 H9A 0.950 . ?
C9 C10 1.397(7) . ?
C10 H10A 0.950 . ?
C10 C11 1.368(9) . ?
C11 H11A 0.950 . ?
C11 C12 1.388(9) . ?
C12 H12A 0.950 . ?
C12 C13 1.385(8) . ?
C13 H13A 0.950 . ?
C14 H14A 1.000 . ?
C15 H15A 0.980 . ?
C15 H15B 0.980 . ?
C15 H15C 0.980 . ?
C16 H16A 0.980 . ?
C16 H16B 0.980 . ?
C16 H16C 0.980 . ?
C17 H17A 0.980 . ?
C17 H17B 0.980 . ?
C17 H17C 0.980 . ?
C18 H18A 0.980 . ?
C18 H18B 0.980 . ?
C18 H18C 0.980 . ?
C19 H19A 0.980 . ?
C19 H19B 0.980 . ?
C19 H19C 0.980 . ?
C20 H20A 0.980 . ?
C20 H20B 0.980 . ?
C20 H20C 0.980 . ?
C21 C22 1.384(7) . ?
C21 C26 1.403(6) . ?
C22 H22A 0.950 . ?
C22 C23 1.385(7) . ?
C23 H23A 0.950 . ?
C23 C24 1.383(9) . ?
C24 H24A 0.950 . ?
C24 C25 1.382(9) . ?
C25 H25A 0.950 . ?
C25 C26 1.380(7) . ?
C26 H26A 0.950 . ?
C27 H27A 1.000 . ?
C28 H28A 0.980 . ?
C28 H28B 0.980 . ?
C28 H28C 0.980 . ?
C29 H29A 0.980 . ?
C29 H29B 0.980 . ?
C29 H29C 0.980 . ?
C30 H30A 0.980 . ?
C30 H30B 0.980 . ?
C30 H30C 0.980 . ?
C31 H31A 0.980 . ?
C31 H31B 0.980 . ?
C31 H31C 0.980 . ?
C32 H32A 0.980 . ?
C32 H32B 0.980 . ?
C32 H32C 0.980 . ?
C33 H33A 0.980 . ?
C33 H33B 0.980 . ?
C33 H33C 0.980 . ?
C34 C35 1.377(7) . ?
C34 C39 1.402(7) . ?
C35 H35A 0.950 . ?
C35 C36 1.394(8) . ?
C36 H36A 0.950 . ?
C36 C37 1.376(9) . ?
C37 H37A 0.950 . ?
C37 C38 1.386(10) . ?
C38 H38A 0.950 . ?
C38 C39 1.384(8) . ?
C39 H39A 0.950 . ?
C40 H40A 1.000 . ?
C41 H41A 0.980 . ?
C41 H41B 0.980 . ?
C41 H41C 0.980 . ?
C42 H42A 0.980 . ?
C42 H42B 0.980 . ?
C42 H42C 0.980 . ?
C43 H43A 0.980 . ?
C43 H43B 0.980 . ?
C43 H43C 0.980 . ?
C44 H44A 0.980 . ?
C44 H44B 0.980 . ?
C44 H44C 0.980 . ?
C45 H45A 0.980 . ?
C45 H45B 0.980 . ?
C45 H45C 0.980 . ?
C46 H46A 0.980 . ?
C46 H46B 0.980 . ?
C46 H46C 0.980 . ?
C47 C48 1.400(6) . ?
C47 C52 1.377(7) . ?
C48 H48A 0.950 . ?
C48 C49 1.380(7) . ?
C49 H49A 0.950 . ?
C49 C50 1.380(8) . ?
C50 H50A 0.950 . ?
C50 C51 1.393(8) . ?
C51 H51A 0.950 . ?
C51 C52 1.381(7) . ?
C52 H52A 0.950 . ?
C53 H53A 1.000 . ?
C54 H54A 0.980 . ?
C54 H54B 0.980 . ?
C54 H54C 0.980 . ?
C55 H55A 0.980 . ?
C55 H55B 0.980 . ?
C55 H55C 0.980 . ?
C56 H56A 0.980 . ?
C56 H56B 0.980 . ?
C56 H56C 0.980 . ?
C57 H57A 0.980 . ?
C57 H57B 0.980 . ?
C57 H57C 0.980 . ?
C58 H58A 0.980 . ?
C58 H58B 0.980 . ?
C58 H58C 0.980 . ?
C59 H59A 0.980 . ?
C59 H59B 0.980 . ?
C59 H59C 0.980 . ?
C60 C61 1.395(7) . ?
C60 C65 1.388(7) . ?
C61 H61A 0.950 . ?
C61 C62 1.400(8) . ?
C62 H62A 0.950 . ?
C62 C63 1.357(11) . ?
C63 H63A 0.950 . ?
C63 C64 1.384(10) . ?
C64 H64A 0.950 . ?
C64 C65 1.389(8) . ?
C65 H65A 0.950 . ?
C66 H66A 1.000 . ?
C67 H67A 0.980 . ?
C67 H67B 0.980 . ?
C67 H67C 0.980 . ?
C68 H68A 0.980 . ?
C68 H68B 0.980 . ?
C68 H68C 0.980 . ?
C69 H69A 0.980 . ?
C69 H69B 0.980 . ?
C69 H69C 0.980 . ?
C70 H70A 0.980 . ?
C70 H70B 0.980 . ?
C70 H70C 0.980 . ?
C71 H71A 0.980 . ?
C71 H71B 0.980 . ?
C71 H71C 0.980 . ?
C72 H72A 0.980 . ?
C72 H72B 0.980 . ?
C72 H72C 0.980 . ?
C73 C74 1.392(6) . ?
C73 C78 1.378(7) . ?
C74 H74A 0.950 . ?
C74 C75 1.392(8) . ?
C75 H75A 0.950 . ?
C75 C76 1.373(9) . ?
C76 H76A 0.950 . ?
C76 C77 1.369(8) . ?
C77 H77A 0.950 . ?
C77 C78 1.404(7) . ?
C78 H78A 0.950 . ?
C79 H79A 1.000 . ?
C80 H80A 0.980 . ?
C80 H80B 0.980 . ?
C80 H80C 0.980 . ?
C81 H81A 0.980 . ?
C81 H81B 0.980 . ?
C81 H81C 0.980 . ?
C82 H82A 0.980 . ?
C82 H82B 0.980 . ?
C82 H82C 0.980 . ?
C83 H83A 0.980 . ?
C83 H83B 0.980 . ?
C83 H83C 0.980 . ?
C84 H84A 0.980 . ?
C84 H84B 0.980 . ?
C84 H84C 0.980 . ?
C85 H85A 0.980 . ?
C85 H85B 0.980 . ?
C85 H85C 0.980 . ?
C86 C87 1.380(7) . ?
C86 C91 1.388(6) . ?
C87 H87A 0.950 . ?
C87 C88 1.393(7) . ?
C88 H88A 0.950 . ?
C88 C89 1.398(8) . ?
C89 H89A 0.950 . ?
C89 C90 1.362(8) . ?
C90 H90A 0.950 . ?
C90 C91 1.373(7) . ?
C91 H91A 0.950 . ?
C92 H92A 1.000 . ?
C93 H93A 0.980 . ?
C93 H93B 0.980 . ?
C93 H93C 0.980 . ?
C94 H94A 0.980 . ?
C94 H94B 0.980 . ?
C94 H94C 0.980 . ?
C95 H95A 0.980 . ?
C95 H95B 0.980 . ?
C95 H95C 0.980 . ?
C96 H96A 0.980 . ?
C96 H96B 0.980 . ?
C96 H96C 0.980 . ?
C97 H97A 0.980 . ?
C97 H97B 0.980 . ?
C97 H97C 0.980 . ?
C98 H98A 0.980 . ?
C98 H98B 0.980 . ?
C98 H98C 0.980 . ?
C99 C100 1.401(7) . ?
C99 C104 1.380(7) . ?
C100 H10B 0.9500 . ?
C100 C101 1.392(8) . ?
C101 H10C 0.950 . ?
C101 C102 1.369(9) . ?
C102 H10D 0.950 . ?
C102 C103 1.380(9) . ?
C103 H10E 0.950 . ?
C103 C104 1.400(7) . ?
C104 H10F 0.950 . ?
C105 H10G 0.980 . ?
C105 H10H 0.980 . ?
C105 H10I 0.980 . ?
C105 C106 1.449(10) . ?
C106 H10J 0.990 . ?
C106 H10K 0.990 . ?
C107 H10L 0.990 . ?
C107 H10M 0.990 . ?
C107 C108 1.487(10) . ?
C108 H10N 0.980 . ?
C108 H10O 0.980 . ?
C108 H10P 0.980 . ?
C109 H10Q 0.980 . ?
C109 H10R 0.980 . ?
C109 H10S 0.980 . ?
C109 C110 1.509(8) . ?
C110 H11B 0.990 . ?
C110 H11C 0.990 . ?
C111 H11D 0.990 . ?
C111 H11F 0.990 . ?
C111 C112 1.484(9) . ?
C112 H11E 0.980 . ?
C112 H11I 0.980 . ?
C112 H11G 0.980 . ?
