#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:15:54 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179683 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/05/7000593.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000593
loop_
_publ_author_name
'Garon, Christian N.'
'McIsaac, Daniel I.'
'Vogels, Christopher M.'
'Decken, Andreas'
'Williams, Ian D.'
'Kleeberg, Christian'
'Marder, Todd B.'
'Westcott, Stephen A.'
_publ_section_title
;
 Synthesis and structure of indenyl rhodium(I) complexes containing
 unsaturated phosphines: catalyst precursors for alkene hydroboration
;
_journal_issue                   9
_journal_name_full               'Dalton Transactions'
_journal_page_first              1624
_journal_page_last               1631
_journal_paper_doi               10.1039/b812259h
_journal_year                    2009
_chemical_formula_moiety         'C70 H54 P4 Rh2'
_chemical_formula_sum            'C70 H54 P4 Rh2'
_chemical_formula_weight         1224.83
_chemical_name_systematic
;bis(μ₂-1,2-bis(Diphenylphosphino)ethyne)-
bis(η⁵-indenyl)-di-rodium
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.0975(5)
_cell_angle_beta                 92.9700(6)
_cell_angle_gamma                106.4690(5)
_cell_formula_units_Z            2
_cell_length_a                   11.6644(2)
_cell_length_b                   13.4814(2)
_cell_length_c                   19.1415(3)
_cell_measurement_reflns_used    9882
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      29.98
_cell_measurement_theta_min      2.19
_cell_volume                     2802.52(8)
_computing_cell_refinement       'SAINT version 7.46A (Bruker, 2007)'
_computing_data_collection       'SMART version 5.049 (Bruker, 1998)'
_computing_data_reduction        'SAINT version 7.46A (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL version 6.14 (Bruker, 2003)'
_computing_publication_material  'SHELXTL version 6.14 (Bruker, 2003)'
_computing_structure_refinement  'SHELXTL version 6.14 (Bruker, 2003)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 5.6
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART 6K CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_sigmaI/netI    0.0340
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            43145
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.10
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.746
_exptl_absorpt_correction_T_max  0.9618
_exptl_absorpt_correction_T_min  0.8926
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2006/1 (Bruker AXS)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.451
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1248
_exptl_crystal_recrystallization_method
'Diffusion of hexane into a solution in benzene at rt.'
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.261
_refine_diff_density_min         -0.654
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         12873
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0406
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0349P)²+2.0246P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0698
_refine_ls_wR_factor_ref         0.0757
_reflns_number_gt                10611
_reflns_number_total             12873
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b812259h.txt
_cod_data_source_block           08srv426
_cod_database_code               7000593
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.374958(15) 0.638171(13) 0.157536(9) 0.01510(5) Uani 1 1 d . . .
Rh1B Rh 0.043034(14) 0.243712(13) 0.300141(9) 0.01533(5) Uani 1 1 d . . .
P1 P 0.20032(5) 0.62729(4) 0.19822(3) 0.01511(11) Uani 1 1 d . . .
P1B P 0.22882(5) 0.33198(4) 0.35023(3) 0.01577(11) Uani 1 1 d . . .
P2 P 0.07792(5) 0.26468(4) 0.19191(3) 0.01507(11) Uani 1 1 d . . .
P2B P 0.46153(5) 0.61086(4) 0.25438(3) 0.01561(11) Uani 1 1 d . . .
C1 C 0.3313(2) 0.66025(19) 0.04935(12) 0.0231(5) Uani 1 1 d . . .
H1 H 0.2493 0.6542 0.0367 0.028 Uiso 1 1 calc R . .
C1B C -0.1500(2) 0.1510(2) 0.28004(13) 0.0247(5) Uani 1 1 d . . .
H1B H -0.1866 0.1395 0.2323 0.030 Uiso 1 1 calc R . .
C2 C 0.3822(2) 0.5751(2) 0.03978(12) 0.0249(5) Uani 1 1 d . . .
H2 H 0.3431 0.5039 0.0140 0.030 Uiso 1 1 calc R . .
C2B C -0.1361(2) 0.2422(2) 0.33670(13) 0.0248(5) Uani 1 1 d . . .
H2B H -0.1707 0.2977 0.3353 0.030 Uiso 1 1 calc R . .
C3 C 0.5009(2) 0.61445(19) 0.07515(12) 0.0234(5) Uani 1 1 d . . .
H3 H 0.5515 0.5727 0.0830 0.028 Uiso 1 1 calc R . .
C3A C 0.5324(2) 0.72899(19) 0.09731(12) 0.0208(5) Uani 1 1 d . . .
C3B C -0.0625(2) 0.2362(2) 0.39510(13) 0.0278(5) Uani 1 1 d . . .
H3B H -0.0300 0.2911 0.4373 0.033 Uiso 1 1 calc R . .
C3AB C -0.0444(2) 0.1320(2) 0.38012(13) 0.0258(5) Uani 1 1 d . . .
C4 C 0.6401(2) 0.8082(2) 0.12738(13) 0.0249(5) Uani 1 1 d . . .
H4 H 0.7113 0.7899 0.1370 0.030 Uiso 1 1 calc R . .
C4B C 0.0115(3) 0.0806(2) 0.42157(16) 0.0373(7) Uani 1 1 d . . .
H4B H 0.0471 0.1151 0.4695 0.045 Uiso 1 1 calc R . .
C5 C 0.6416(2) 0.9134(2) 0.14287(14) 0.0299(6) Uani 1 1 d . . .
H5 H 0.7150 0.9678 0.1619 0.036 Uiso 1 1 calc R . .
C5B C 0.0138(3) -0.0205(3) 0.39147(18) 0.0423(7) Uani 1 1 d . . .
H5B H 0.0495 -0.0566 0.4196 0.051 Uiso 1 1 calc R . .
C6 C 0.5365(2) 0.9411(2) 0.13092(15) 0.0320(6) Uani 1 1 d . . .
H6 H 0.5396 1.0139 0.1434 0.038 Uiso 1 1 calc R . .
C6B C -0.0350(3) -0.0715(2) 0.32043(19) 0.0421(7) Uani 1 1 d . . .
H6B H -0.0296 -0.1406 0.3009 0.050 Uiso 1 1 calc R . .
C7 C 0.4290(2) 0.8655(2) 0.10162(13) 0.0265(5) Uani 1 1 d . . .
H7 H 0.3579 0.8853 0.0949 0.032 Uiso 1 1 calc R . .
C7A C 0.4262(2) 0.75836(19) 0.08184(12) 0.0212(5) Uani 1 1 d . . .
C7B C -0.0908(2) -0.0235(2) 0.27796(16) 0.0326(6) Uani 1 1 d . . .
H7B H -0.1230 -0.0587 0.2296 0.039 Uiso 1 1 calc R . .
C7AB C -0.0988(2) 0.0788(2) 0.30784(14) 0.0251(5) Uani 1 1 d . . .
C8 C 0.0968(2) 0.67247(18) 0.14658(12) 0.0188(4) Uani 1 1 d . . .
C8B C 0.23872(19) 0.39774(18) 0.44482(12) 0.0191(4) Uani 1 1 d . . .
C9 C 0.1061(2) 0.7802(2) 0.16108(14) 0.0281(5) Uani 1 1 d . . .
H9 H 0.1608 0.8284 0.2002 0.034 Uiso 1 1 calc R . .
C9B C 0.2494(2) 0.3448(2) 0.49821(13) 0.0301(6) Uani 1 1 d . . .
H9B H 0.2601 0.2763 0.4859 0.036 Uiso 1 1 calc R . .
C10 C 0.0355(3) 0.8176(2) 0.11848(16) 0.0390(7) Uani 1 1 d . . .
H10 H 0.0423 0.8912 0.1289 0.047 Uiso 1 1 calc R . .
C10B C 0.2445(3) 0.3910(2) 0.56984(14) 0.0365(6) Uani 1 1 d . . .
H10B H 0.2521 0.3538 0.6060 0.044 Uiso 1 1 calc R . .
C11 C -0.0443(3) 0.7487(2) 0.06130(15) 0.0358(6) Uani 1 1 d . . .
H11 H -0.0918 0.7749 0.0322 0.043 Uiso 1 1 calc R . .
C11B C 0.2290(3) 0.4895(2) 0.58817(14) 0.0386(7) Uani 1 1 d . . .
H11B H 0.2255 0.5210 0.6370 0.046 Uiso 1 1 calc R . .
C12 C -0.0546(2) 0.6415(2) 0.04668(14) 0.0323(6) Uani 1 1 d . . .
H12 H -0.1096 0.5938 0.0075 0.039 Uiso 1 1 calc R . .
C12B C 0.2184(3) 0.5433(3) 0.53492(16) 0.0458(8) Uani 1 1 d . . .
H12B H 0.2078 0.6119 0.5475 0.055 Uiso 1 1 calc R . .
C13 C 0.0153(2) 0.6030(2) 0.08921(13) 0.0253(5) Uani 1 1 d . . .
H13 H 0.0074 0.5291 0.0790 0.030 Uiso 1 1 calc R . .
C13B C 0.2231(3) 0.4976(2) 0.46357(14) 0.0344(6) Uani 1 1 d . . .
H13B H 0.2156 0.5348 0.4274 0.041 Uiso 1 1 calc R . .
C14 C 0.18679(19) 0.68594(17) 0.29148(12) 0.0177(4) Uani 1 1 d . . .
C14B C 0.3342(2) 0.25349(18) 0.34869(12) 0.0200(4) Uani 1 1 d . . .
C15 C 0.0962(2) 0.6393(2) 0.32962(13) 0.0235(5) Uani 1 1 d . . .
H15 H 0.0372 0.5739 0.3072 0.028 Uiso 1 1 calc R . .
C15B C 0.4587(2) 0.2986(2) 0.35546(16) 0.0315(6) Uani 1 1 d . . .
H15B H 0.4928 0.3737 0.3651 0.038 Uiso 1 1 calc R . .
C16 C 0.0922(2) 0.6886(2) 0.40052(14) 0.0297(6) Uani 1 1 d . . .
H16 H 0.0301 0.6569 0.4264 0.036 Uiso 1 1 calc R . .
C16B C 0.5328(3) 0.2334(3) 0.34800(18) 0.0426(7) Uani 1 1 d . . .
H16B H 0.6175 0.2643 0.3516 0.051 Uiso 1 1 calc R . .
C17 C 0.1781(2) 0.7835(2) 0.43359(13) 0.0295(5) Uani 1 1 d . . .
H17 H 0.1753 0.8167 0.4821 0.035 Uiso 1 1 calc R . .
C17B C 0.4850(3) 0.1245(3) 0.33543(17) 0.0421(7) Uani 1 1 d . . .
H17B H 0.5363 0.0805 0.3301 0.051 Uiso 1 1 calc R . .
C18 C 0.2682(2) 0.83003(19) 0.39597(13) 0.0266(5) Uani 1 1 d . . .
H18 H 0.3273 0.8953 0.4187 0.032 Uiso 1 1 calc R . .
C18B C 0.3619(3) 0.0798(2) 0.33064(15) 0.0352(6) Uani 1 1 d . . .
H18B H 0.3285 0.0049 0.3230 0.042 Uiso 1 1 calc R . .
C19 C 0.2726(2) 0.78171(18) 0.32502(13) 0.0215(5) Uani 1 1 d . . .
H19 H 0.3344 0.8142 0.2993 0.026 Uiso 1 1 calc R . .
C19B C 0.2867(2) 0.14383(19) 0.33699(13) 0.0249(5) Uani 1 1 d . . .
H19B H 0.2021 0.1124 0.3333 0.030 Uiso 1 1 calc R . .
C20 C 0.12135(19) 0.49125(18) 0.18948(12) 0.0181(4) Uani 1 1 d . . .
C20B C 0.31499(19) 0.43950(17) 0.31693(12) 0.0174(4) Uani 1 1 d . . .
C21 C 0.09288(19) 0.39690(17) 0.18566(11) 0.0178(4) Uani 1 1 d . . .
C21B C 0.37464(19) 0.51150(18) 0.29406(12) 0.0184(4) Uani 1 1 d . . .
C22 C 0.21022(19) 0.24358(17) 0.15131(11) 0.0173(4) Uani 1 1 d . . .
C22B C 0.5221(2) 0.72257(18) 0.33268(12) 0.0195(4) Uani 1 1 d . . .
C23 C 0.2495(2) 0.16090(19) 0.16557(13) 0.0228(5) Uani 1 1 d . . .
H23 H 0.2090 0.1189 0.1962 0.027 Uiso 1 1 calc R . .
C23B C 0.5811(2) 0.82144(19) 0.31959(14) 0.0252(5) Uani 1 1 d . . .
H23B H 0.5845 0.8293 0.2715 0.030 Uiso 1 1 calc R . .
C24 C 0.3484(2) 0.1396(2) 0.13503(14) 0.0305(6) Uani 1 1 d . . .
H24 H 0.3757 0.0836 0.1453 0.037 Uiso 1 1 calc R . .
C24B C 0.6346(3) 0.9082(2) 0.37640(16) 0.0349(6) Uani 1 1 d . . .
H24B H 0.6780 0.9745 0.3673 0.042 Uiso 1 1 calc R . .
C25 C 0.4066(2) 0.1997(2) 0.08994(15) 0.0337(6) Uani 1 1 d . . .
H25 H 0.4730 0.1842 0.0684 0.040 Uiso 1 1 calc R . .
C25B C 0.6246(3) 0.8975(2) 0.44640(16) 0.0395(7) Uani 1 1 d . . .
H25B H 0.6609 0.9570 0.4853 0.047 Uiso 1 1 calc R . .
C26 C 0.3683(2) 0.2826(2) 0.07606(14) 0.0321(6) Uani 1 1 d . . .
H26 H 0.4090 0.3241 0.0453 0.038 Uiso 1 1 calc R . .
C26B C 0.5623(3) 0.8011(2) 0.46031(14) 0.0355(6) Uani 1 1 d . . .
H26B H 0.5533 0.7949 0.5084 0.043 Uiso 1 1 calc R . .
C27 C 0.2708(2) 0.3054(2) 0.10681(12) 0.0243(5) Uani 1 1 d . . .
H27 H 0.2454 0.3629 0.0976 0.029 Uiso 1 1 calc R . .
C27B C 0.5130(2) 0.7135(2) 0.40319(13) 0.0265(5) Uani 1 1 d . . .
H27B H 0.4725 0.6467 0.4125 0.032 Uiso 1 1 calc R . .
C28 C -0.04541(19) 0.18878(17) 0.12064(11) 0.0175(4) Uani 1 1 d . . .
C28B C 0.5925(2) 0.56257(18) 0.23832(11) 0.0183(4) Uani 1 1 d . . .
C29 C -0.0526(2) 0.08601(18) 0.08453(12) 0.0221(5) Uani 1 1 d . . .
H29 H 0.0116 0.0579 0.0927 0.027 Uiso 1 1 calc R . .
C29B C 0.5792(2) 0.45429(19) 0.21920(13) 0.0237(5) Uani 1 1 d . . .
H29B H 0.5029 0.4041 0.2182 0.028 Uiso 1 1 calc R . .
C30 C -0.1535(2) 0.02418(19) 0.03645(13) 0.0269(5) Uani 1 1 d . . .
H30 H -0.1574 -0.0458 0.0116 0.032 Uiso 1 1 calc R . .
C30B C 0.6775(2) 0.4193(2) 0.20161(15) 0.0320(6) Uani 1 1 d . . .
H30B H 0.6680 0.3452 0.1887 0.038 Uiso 1 1 calc R . .
C31 C -0.2483(2) 0.0638(2) 0.02451(13) 0.0267(5) Uani 1 1 d . . .
H31 H -0.3181 0.0207 -0.0073 0.032 Uiso 1 1 calc R . .
C31B C 0.7895(2) 0.4920(2) 0.20270(15) 0.0336(6) Uani 1 1 d . . .
H31B H 0.8565 0.4678 0.1907 0.040 Uiso 1 1 calc R . .
C32 C -0.2399(2) 0.1679(2) 0.05981(13) 0.0264(5) Uani 1 1 d . . .
H32 H -0.3034 0.1965 0.0510 0.032 Uiso 1 1 calc R . .
C32B C 0.8027(2) 0.5995(2) 0.22136(14) 0.0290(5) Uani 1 1 d . . .
H32B H 0.8789 0.6494 0.2217 0.035 Uiso 1 1 calc R . .
C33 C -0.1397(2) 0.22930(19) 0.10752(13) 0.0240(5) Uani 1 1 d . . .
H33 H -0.1351 0.2998 0.1316 0.029 Uiso 1 1 calc R . .
C33B C 0.7055(2) 0.63529(19) 0.23966(13) 0.0234(5) Uani 1 1 d . . .
H33B H 0.7158 0.7095 0.2532 0.028 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 C1 99.23(7) . . ?
P1 Rh1 P2B 95.41(2) . . ?
C1 Rh1 P2B 165.13(7) . . ?
P1 Rh1 C3 156.45(7) . . ?
C1 Rh1 C3 62.00(9) . . ?
P2B Rh1 C3 103.18(7) . . ?
P1 Rh1 C2 119.87(7) . . ?
C1 Rh1 C2 37.11(9) . . ?
P2B Rh1 C2 130.91(7) . . ?
C3 Rh1 C2 36.60(9) . . ?
P1 Rh1 C7A 113.94(6) . . ?
C1 Rh1 C7A 36.87(8) . . ?
P2B Rh1 C7A 136.55(6) . . ?
C3 Rh1 C7A 60.46(8) . . ?
C2 Rh1 C7A 60.47(8) . . ?
P1 Rh1 C3A 148.12(6) . . ?
C1 Rh1 C3A 60.44(8) . . ?
P2B Rh1 C3A 107.28(6) . . ?
C3 Rh1 C3A 36.10(8) . . ?
C2 Rh1 C3A 59.73(8) . . ?
C7A Rh1 C3A 35.13(8) . . ?
P2 Rh1B P1B 94.82(2) . . ?
P2 Rh1B C1B 100.71(7) . . ?
P1B Rh1B C1B 164.46(7) . . ?
P2 Rh1B C2B 119.70(7) . . ?
P1B Rh1B C2B 132.14(7) . . ?
C1B Rh1B C2B 37.31(9) . . ?
P2 Rh1B C3B 155.97(7) . . ?
P1B Rh1B C3B 103.30(7) . . ?
C1B Rh1B C3B 61.79(9) . . ?
C2B Rh1B C3B 36.48(9) . . ?
P2 Rh1B C7AB 116.76(6) . . ?
P1B Rh1B C7AB 134.04(6) . . ?
C1B Rh1B C7AB 36.31(9) . . ?
C2B Rh1B C7AB 60.03(9) . . ?
C3B Rh1B C7AB 59.80(9) . . ?
P2 Rh1B C3AB 150.63(6) . . ?
P1B Rh1B C3AB 105.85(6) . . ?
C1B Rh1B C3AB 59.79(9) . . ?
C2B Rh1B C3AB 59.36(9) . . ?
C3B Rh1B C3AB 35.82(9) . . ?
C7AB Rh1B C3AB 34.59(8) . . ?
C20 P1 C14 102.14(10) . . ?
C20 P1 C8 102.91(10) . . ?
C14 P1 C8 103.03(10) . . ?
C20 P1 Rh1 108.46(7) . . ?
C14 P1 Rh1 122.65(7) . . ?
C8 P1 Rh1 115.29(7) . . ?
C20B P1B C8B 100.24(10) . . ?
C20B P1B C14B 100.16(10) . . ?
C8B P1B C14B 104.42(10) . . ?
C20B P1B Rh1B 119.89(7) . . ?
C8B P1B Rh1B 113.71(7) . . ?
C14B P1B Rh1B 116.00(8) . . ?
C21 P2 C22 100.86(10) . . ?
C21 P2 C28 101.50(10) . . ?
C22 P2 C28 102.65(10) . . ?
C21 P2 Rh1B 111.22(7) . . ?
C22 P2 Rh1B 122.79(7) . . ?
C28 P2 Rh1B 114.98(7) . . ?
C21B P2B C22B 101.78(10) . . ?
C21B P2B C28B 100.18(10) . . ?
C22B P2B C28B 101.81(10) . . ?
C21B P2B Rh1 117.23(7) . . ?
C22B P2B Rh1 119.00(8) . . ?
C28B P2B Rh1 114.03(7) . . ?
C2 C1 C7A 108.2(2) . . ?
C2 C1 Rh1 73.13(13) . . ?
C7A C1 Rh1 77.58(13) . . ?
C2 C1 H1 125.9 . . ?
C7A C1 H1 125.9 . . ?
Rh1 C1 H1 115.5 . . ?
C2B C1B C7AB 108.1(2) . . ?
C2B C1B Rh1B 72.15(13) . . ?
C7AB C1B Rh1B 79.06(13) . . ?
C2B C1B H1B 126.0 . . ?
C7AB C1B H1B 126.0 . . ?
Rh1B C1B H1B 115.0 . . ?
C3 C2 C1 108.2(2) . . ?
C3 C2 Rh1 71.49(13) . . ?
C1 C2 Rh1 69.76(13) . . ?
C3 C2 H2 125.9 . . ?
C1 C2 H2 125.9 . . ?
Rh1 C2 H2 124.5 . . ?
C3B C2B C1B 108.4(2) . . ?
C3B C2B Rh1B 72.44(13) . . ?
C1B C2B Rh1B 70.54(13) . . ?
C3B C2B H2B 125.8 . . ?
C1B C2B H2B 125.8 . . ?
Rh1B C2B H2B 122.9 . . ?
C2 C3 C3A 108.4(2) . . ?
C2 C3 Rh1 71.91(13) . . ?
C3A C3 Rh1 77.58(13) . . ?
C2 C3 H3 125.8 . . ?
C3A C3 H3 125.8 . . ?
Rh1 C3 H3 116.7 . . ?
C4 C3A C7A 119.7(2) . . ?
C4 C3A C3 132.8(2) . . ?
C7A C3A C3 107.5(2) . . ?
C4 C3A Rh1 128.59(16) . . ?
C7A C3A Rh1 71.41(12) . . ?
C3 C3A Rh1 66.32(12) . . ?
C2B C3B C3AB 108.5(2) . . ?
C2B C3B Rh1B 71.08(13) . . ?
C3AB C3B Rh1B 78.86(13) . . ?
C2B C3B H3B 125.8 . . ?
C3AB C3B H3B 125.8 . . ?
Rh1B C3B H3B 116.3 . . ?
C4B C3AB C7AB 120.2(3) . . ?
C4B C3AB C3B 132.6(3) . . ?
C7AB C3AB C3B 107.2(2) . . ?
C4B C3AB Rh1B 128.71(17) . . ?
C7AB C3AB Rh1B 71.69(13) . . ?
C3B C3AB Rh1B 65.32(13) . . ?
C5 C4 C3A 119.1(2) . . ?
C5 C4 H4 120.5 . . ?
C3A C4 H4 120.5 . . ?
C5B C4B C3AB 118.7(3) . . ?
C5B C4B H4B 120.7 . . ?
C3AB C4B H4B 120.7 . . ?
C4 C5 C6 121.0(2) . . ?
C4 C5 H5 119.5 . . ?
C6 C5 H5 119.5 . . ?
C4B C5B C6B 121.6(3) . . ?
C4B C5B H5B 119.2 . . ?
C6B C5B H5B 119.2 . . ?
C7 C6 C5 121.6(2) . . ?
C7 C6 H6 119.2 . . ?
C5 C6 H6 119.2 . . ?
C7B C6B C5B 121.4(3) . . ?
C7B C6B H6B 119.3 . . ?
C5B C6B H6B 119.3 . . ?
C6 C7 C7A 118.6(2) . . ?
C6 C7 H7 120.7 . . ?
C7A C7 H7 120.7 . . ?
C7 C7A C3A 119.9(2) . . ?
C7 C7A C1 133.2(2) . . ?
C3A C7A C1 106.8(2) . . ?
C7 C7A Rh1 123.83(16) . . ?
C3A C7A Rh1 73.46(13) . . ?
C1 C7A Rh1 65.55(12) . . ?
C6B C7B C7AB 118.6(3) . . ?
C6B C7B H7B 120.7 . . ?
C7AB C7B H7B 120.7 . . ?
C7B C7AB C3AB 119.4(2) . . ?
C7B C7AB C1B 133.5(2) . . ?
C3AB C7AB C1B 107.1(2) . . ?
C7B C7AB Rh1B 125.45(17) . . ?
C3AB C7AB Rh1B 73.72(13) . . ?
C1B C7AB Rh1B 64.63(12) . . ?
C9 C8 C13 119.0(2) . . ?
C9 C8 P1 119.28(18) . . ?
C13 C8 P1 121.54(17) . . ?
C9B C8B C13B 119.0(2) . . ?
C9B C8B P1B 120.71(19) . . ?
C13B C8B P1B 119.98(18) . . ?
C10 C9 C8 120.3(2) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C8B C9B C10B 120.7(3) . . ?
C8B C9B H9B 119.6 . . ?
C10B C9B H9B 119.6 . . ?
C11 C10 C9 120.6(3) . . ?
C11 C10 H10 119.7 . . ?
C9 C10 H10 119.7 . . ?
C11B C10B C9B 120.2(3) . . ?
C11B C10B H10B 119.9 . . ?
C9B C10B H10B 119.9 . . ?
C10 C11 C12 119.5(2) . . ?
C10 C11 H11 120.2 . . ?
C12 C11 H11 120.2 . . ?
C10B C11B C12B 119.5(3) . . ?
C10B C11B H11B 120.2 . . ?
C12B C11B H11B 120.2 . . ?
C11 C12 C13 120.4(2) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C13B C12B C11B 120.4(3) . . ?
C13B C12B H12B 119.8 . . ?
C11B C12B H12B 119.8 . . ?
C8 C13 C12 120.2(2) . . ?
C8 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C8B C13B C12B 120.2(3) . . ?
C8B C13B H13B 119.9 . . ?
C12B C13B H13B 119.9 . . ?
C19 C14 C15 119.4(2) . . ?
C19 C14 P1 117.27(17) . . ?
C15 C14 P1 123.32(17) . . ?
C19B C14B C15B 119.0(2) . . ?
C19B C14B P1B 117.97(18) . . ?
C15B C14B P1B 122.92(18) . . ?
C16 C15 C14 119.9(2) . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C16B C15B C14B 119.8(3) . . ?
C16B C15B H15B 120.1 . . ?
C14B C15B H15B 120.1 . . ?
C17 C16 C15 120.3(2) . . ?
C17 C16 H16 119.8 . . ?
C15 C16 H16 119.8 . . ?
C17B C16B C15B 120.9(3) . . ?
C17B C16B H16B 119.6 . . ?
C15B C16B H16B 119.6 . . ?
C16 C17 C18 119.9(2) . . ?
C16 C17 H17 120.0 . . ?
C18 C17 H17 120.0 . . ?
C16B C17B C18B 119.5(3) . . ?
C16B C17B H17B 120.3 . . ?
C18B C17B H17B 120.3 . . ?
C17 C18 C19 120.2(2) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 H18 119.9 . . ?
C17B C18B C19B 120.3(3) . . ?
C17B C18B H18B 119.9 . . ?
C19B C18B H18B 119.9 . . ?
C18 C19 C14 120.2(2) . . ?
C18 C19 H19 119.9 . . ?
C14 C19 H19 119.9 . . ?
C18B C19B C14B 120.5(2) . . ?
C18B C19B H19B 119.7 . . ?
C14B C19B H19B 119.7 . . ?
C21 C20 P1 165.5(2) . . ?
C21B C20B P1B 179.0(2) . . ?
C20 C21 P2 168.5(2) . . ?
C20B C21B P2B 175.9(2) . . ?
C23 C22 C27 119.6(2) . . ?
C23 C22 P2 117.36(17) . . ?
C27 C22 P2 123.00(18) . . ?
C27B C22B C23B 119.1(2) . . ?
C27B C22B P2B 123.58(18) . . ?
C23B C22B P2B 117.30(17) . . ?
C22 C23 C24 120.0(2) . . ?
C22 C23 H23 120.0 . . ?
C24 C23 H23 120.0 . . ?
C24B C23B C22B 120.4(2) . . ?
C24B C23B H23B 119.8 . . ?
C22B C23B H23B 119.8 . . ?
C25 C24 C23 120.1(2) . . ?
C25 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
C25B C24B C23B 119.6(3) . . ?
C25B C24B H24B 120.2 . . ?
C23B C24B H24B 120.2 . . ?
C24 C25 C26 120.0(2) . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C24B C25B C26B 120.8(3) . . ?
C24B C25B H25B 119.6 . . ?
C26B C25B H25B 119.6 . . ?
C25 C26 C27 120.4(2) . . ?
C25 C26 H26 119.8 . . ?
C27 C26 H26 119.8 . . ?
C25B C26B C27B 119.3(3) . . ?
C25B C26B H26B 120.4 . . ?
C27B C26B H26B 120.4 . . ?
C26 C27 C22 119.8(2) . . ?
C26 C27 H27 120.1 . . ?
C22 C27 H27 120.1 . . ?
C22B C27B C26B 120.8(2) . . ?
C22B C27B H27B 119.6 . . ?
C26B C27B H27B 119.6 . . ?
C29 C28 C33 119.2(2) . . ?
C29 C28 P2 120.46(17) . . ?
C33 C28 P2 120.00(17) . . ?
C29B C28B C33B 119.2(2) . . ?
C29B C28B P2B 120.94(17) . . ?
C33B C28B P2B 119.68(17) . . ?
C28 C29 C30 120.2(2) . . ?
C28 C29 H29 119.9 . . ?
C30 C29 H29 119.9 . . ?
C30B C29B C28B 120.1(2) . . ?
C30B C29B H29B 119.9 . . ?
C28B C29B H29B 119.9 . . ?
C31 C30 C29 120.5(2) . . ?
C31 C30 H30 119.7 . . ?
C29 C30 H30 119.7 . . ?
C29B C30B C31B 120.5(2) . . ?
C29B C30B H30B 119.8 . . ?
C31B C30B H30B 119.8 . . ?
C30 C31 C32 119.2(2) . . ?
C30 C31 H31 120.4 . . ?
C32 C31 H31 120.4 . . ?
C32B C31B C30B 119.5(2) . . ?
C32B C31B H31B 120.2 . . ?
C30B C31B H31B 120.2 . . ?
C33 C32 C31 120.3(2) . . ?
C33 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?
C31B C32B C33B 120.5(2) . . ?
C31B C32B H32B 119.7 . . ?
C33B C32B H32B 119.7 . . ?
C32 C33 C28 120.6(2) . . ?
C32 C33 H33 119.7 . . ?
C28 C33 H33 119.7 . . ?
C32B C33B C28B 120.2(2) . . ?
C32B C33B H33B 119.9 . . ?
C28B C33B H33B 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.1956(6) . ?
Rh1 C1 2.207(2) . ?
Rh1 P2B 2.2124(6) . ?
Rh1 C3 2.246(2) . ?
Rh1 C2 2.251(2) . ?
Rh1 C7A 2.368(2) . ?
Rh1 C3A 2.395(2) . ?
Rh1B P2 2.1920(6) . ?
Rh1B P1B 2.2081(6) . ?
Rh1B C1B 2.212(2) . ?
Rh1B C2B 2.234(2) . ?
Rh1B C3B 2.251(2) . ?
Rh1B C7AB 2.404(2) . ?
Rh1B C3AB 2.431(2) . ?
P1 C20 1.771(2) . ?
P1 C14 1.829(2) . ?
P1 C8 1.831(2) . ?
P1B C20B 1.773(2) . ?
P1B C8B 1.823(2) . ?
P1B C14B 1.833(2) . ?
P2 C21 1.771(2) . ?
P2 C22 1.829(2) . ?
P2 C28 1.832(2) . ?
P2B C21B 1.771(2) . ?
P2B C22B 1.832(2) . ?
P2B C28B 1.838(2) . ?
C1 C2 1.419(3) . ?
C1 C7A 1.455(3) . ?
C1 H1 0.9500 . ?
C1B C2B 1.422(3) . ?
C1B C7AB 1.450(3) . ?
C1B H1B 0.9500 . ?
C2 C3 1.412(3) . ?
C2 H2 0.9500 . ?
C2B C3B 1.404(4) . ?
C2B H2B 0.9500 . ?
C3 C3A 1.445(3) . ?
C3 H3 0.9500 . ?
C3A C4 1.399(3) . ?
C3A C7A 1.438(3) . ?
C3B C3AB 1.450(4) . ?
C3B H3B 0.9500 . ?
C3AB C4B 1.404(4) . ?
C3AB C7AB 1.438(3) . ?
C4 C5 1.382(4) . ?
C4 H4 0.9500 . ?
C4B C5B 1.372(4) . ?
C4B H4B 0.9500 . ?
C5 C6 1.400(4) . ?
C5 H5 0.9500 . ?
C5B C6B 1.397(5) . ?
C5B H5B 0.9500 . ?
C6 C7 1.375(4) . ?
C6 H6 0.9500 . ?
C6B C7B 1.381(4) . ?
C6B H6B 0.9500 . ?
C7 C7A 1.405(3) . ?
C7 H7 0.9500 . ?
C7B C7AB 1.409(4) . ?
C7B H7B 0.9500 . ?
C8 C9 1.391(3) . ?
C8 C13 1.394(3) . ?
C8B C9B 1.382(3) . ?
C8B C13B 1.384(3) . ?
C9 C10 1.391(4) . ?
C9 H9 0.9500 . ?
C9B C10B 1.393(4) . ?
C9B H9B 0.9500 . ?
C10 C11 1.380(4) . ?
C10 H10 0.9500 . ?
C10B C11B 1.367(4) . ?
C10B H10B 0.9500 . ?
C11 C12 1.382(4) . ?
C11 H11 0.9500 . ?
C11B C12B 1.389(4) . ?
C11B H11B 0.9500 . ?
C12 C13 1.395(3) . ?
C12 H12 0.9500 . ?
C12B C13B 1.387(4) . ?
C12B H12B 0.9500 . ?
C13 H13 0.9500 . ?
C13B H13B 0.9500 . ?
C14 C19 1.391(3) . ?
C14 C15 1.393(3) . ?
C14B C19B 1.388(3) . ?
C14B C15B 1.393(3) . ?
C15 C16 1.390(3) . ?
C15 H15 0.9500 . ?
C15B C16B 1.389(4) . ?
C15B H15B 0.9500 . ?
C16 C17 1.382(4) . ?
C16 H16 0.9500 . ?
C16B C17B 1.377(4) . ?
C16B H16B 0.9500 . ?
C17 C18 1.382(4) . ?
C17 H17 0.9500 . ?
C17B C18B 1.381(4) . ?
C17B H17B 0.9500 . ?
C18 C19 1.388(3) . ?
C18 H18 0.9500 . ?
C18B C19B 1.387(4) . ?
C18B H18B 0.9500 . ?
C19 H19 0.9500 . ?
C19B H19B 0.9500 . ?
C20 C21 1.205(3) . ?
C20B C21B 1.202(3) . ?
C22 C23 1.390(3) . ?
C22 C27 1.395(3) . ?
C22B C27B 1.387(3) . ?
C22B C23B 1.397(3) . ?
C23 C24 1.393(3) . ?
C23 H23 0.9500 . ?
C23B C24B 1.387(4) . ?
C23B H23B 0.9500 . ?
C24 C25 1.380(4) . ?
C24 H24 0.9500 . ?
C24B C25B 1.385(4) . ?
C24B H24B 0.9500 . ?
C25 C26 1.383(4) . ?
C25 H25 0.9500 . ?
C25B C26B 1.385(4) . ?
C25B H25B 0.9500 . ?
C26 C27 1.388(3) . ?
C26 H26 0.9500 . ?
C26B C27B 1.389(4) . ?
C26B H26B 0.9500 . ?
C27 H27 0.9500 . ?
C27B H27B 0.9500 . ?
C28 C29 1.390(3) . ?
C28 C33 1.394(3) . ?
C28B C29B 1.390(3) . ?
C28B C33B 1.398(3) . ?
C29 C30 1.392(3) . ?
C29 H29 0.9500 . ?
C29B C30B 1.389(3) . ?
C29B H29B 0.9500 . ?
C30 C31 1.385(4) . ?
C30 H30 0.9500 . ?
C30B C31B 1.389(4) . ?
C30B H30B 0.9500 . ?
C31 C32 1.398(3) . ?
C31 H31 0.9500 . ?
C31B C32B 1.379(4) . ?
C31B H31B 0.9500 . ?
C32 C33 1.382(3) . ?
C32 H32 0.9500 . ?
C32B C33B 1.386(3) . ?
C32B H32B 0.9500 . ?
C33 H33 0.9500 . ?
C33B H33B 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Rh1 P1 C20 99.55(10) . . . . ?
P2B Rh1 P1 C20 -77.87(8) . . . . ?
C3 Rh1 P1 C20 64.38(18) . . . . ?
C2 Rh1 P1 C20 66.52(11) . . . . ?
C7A Rh1 P1 C20 135.00(10) . . . . ?
C3A Rh1 P1 C20 146.31(13) . . . . ?
C1 Rh1 P1 C14 -141.95(11) . . . . ?
P2B Rh1 P1 C14 40.63(9) . . . . ?
C3 Rh1 P1 C14 -177.13(17) . . . . ?
C2 Rh1 P1 C14 -174.98(11) . . . . ?
C7A Rh1 P1 C14 -106.51(11) . . . . ?
C3A Rh1 P1 C14 -95.19(14) . . . . ?
C1 Rh1 P1 C8 -15.17(11) . . . . ?
P2B Rh1 P1 C8 167.42(8) . . . . ?
C3 Rh1 P1 C8 -50.34(18) . . . . ?
C2 Rh1 P1 C8 -48.19(11) . . . . ?
C7A Rh1 P1 C8 20.28(11) . . . . ?
C3A Rh1 P1 C8 31.60(14) . . . . ?
P2 Rh1B P1B C20B 32.17(9) . . . . ?
C1B Rh1B P1B C20B -147.6(3) . . . . ?
C2B Rh1B P1B C20B -106.14(12) . . . . ?
C3B Rh1B P1B C20B -131.94(11) . . . . ?
C7AB Rh1B P1B C20B 167.42(12) . . . . ?
C3AB Rh1B P1B C20B -168.91(11) . . . . ?
P2 Rh1B P1B C8B 150.62(8) . . . . ?
C1B Rh1B P1B C8B -29.1(3) . . . . ?
C2B Rh1B P1B C8B 12.31(13) . . . . ?
C3B Rh1B P1B C8B -13.49(11) . . . . ?
C7AB Rh1B P1B C8B -74.13(12) . . . . ?
C3AB Rh1B P1B C8B -50.46(11) . . . . ?
P2 Rh1B P1B C14B -88.27(8) . . . . ?
C1B Rh1B P1B C14B 92.0(3) . . . . ?
C2B Rh1B P1B C14B 133.42(12) . . . . ?
C3B Rh1B P1B C14B 107.62(11) . . . . ?
C7AB Rh1B P1B C14B 46.98(12) . . . . ?
C3AB Rh1B P1B C14B 70.65(10) . . . . ?
P1B Rh1B P2 C21 -73.60(8) . . . . ?
C1B Rh1B P2 C21 106.33(10) . . . . ?
C2B Rh1B P2 C21 71.82(11) . . . . ?
C3B Rh1B P2 C21 65.55(19) . . . . ?
C7AB Rh1B P2 C21 140.93(10) . . . . ?
C3AB Rh1B P2 C21 151.27(14) . . . . ?
P1B Rh1B P2 C22 45.78(9) . . . . ?
C1B Rh1B P2 C22 -134.29(11) . . . . ?
C2B Rh1B P2 C22 -168.81(11) . . . . ?
C3B Rh1B P2 C22 -175.08(18) . . . . ?
C7AB Rh1B P2 C22 -99.69(11) . . . . ?
C3AB Rh1B P2 C22 -89.35(15) . . . . ?
P1B Rh1B P2 C28 171.77(8) . . . . ?
C1B Rh1B P2 C28 -8.31(11) . . . . ?
C2B Rh1B P2 C28 -42.82(11) . . . . ?
C3B Rh1B P2 C28 -49.09(19) . . . . ?
C7AB Rh1B P2 C28 26.30(11) . . . . ?
C3AB Rh1B P2 C28 36.64(15) . . . . ?
P1 Rh1 P2B C21B 41.75(9) . . . . ?
C1 Rh1 P2B C21B -128.3(3) . . . . ?
C3 Rh1 P2B C21B -123.70(10) . . . . ?
C2 Rh1 P2B C21B -96.33(12) . . . . ?
C7A Rh1 P2B C21B 175.59(12) . . . . ?
C3A Rh1 P2B C21B -160.93(10) . . . . ?
P1 Rh1 P2B C22B -81.47(9) . . . . ?
C1 Rh1 P2B C22B 108.5(3) . . . . ?
C3 Rh1 P2B C22B 113.09(11) . . . . ?
C2 Rh1 P2B C22B 140.45(12) . . . . ?
C7A Rh1 P2B C22B 52.37(12) . . . . ?
C3A Rh1 P2B C22B 75.86(10) . . . . ?
P1 Rh1 P2B C28B 158.30(8) . . . . ?
C1 Rh1 P2B C28B -11.7(3) . . . . ?
C3 Rh1 P2B C28B -7.14(10) . . . . ?
C2 Rh1 P2B C28B 20.22(12) . . . . ?
C7A Rh1 P2B C28B -67.86(12) . . . . ?
C3A Rh1 P2B C28B -44.37(10) . . . . ?
P1 Rh1 C1 C2 -128.43(13) . . . . ?
P2B Rh1 C1 C2 41.5(3) . . . . ?
C3 Rh1 C1 C2 36.46(14) . . . . ?
C7A Rh1 C1 C2 113.6(2) . . . . ?
C3A Rh1 C1 C2 77.83(15) . . . . ?
P1 Rh1 C1 C7A 117.93(13) . . . . ?
P2B Rh1 C1 C7A -72.1(3) . . . . ?
C3 Rh1 C1 C7A -77.18(15) . . . . ?
C2 Rh1 C1 C7A -113.6(2) . . . . ?
C3A Rh1 C1 C7A -35.82(13) . . . . ?
P2 Rh1B C1B C2B -125.70(14) . . . . ?
P1B Rh1B C1B C2B 54.0(3) . . . . ?
C3B Rh1B C1B C2B 36.73(15) . . . . ?
C7AB Rh1B C1B C2B 113.2(2) . . . . ?
C3AB Rh1B C1B C2B 77.94(16) . . . . ?
P2 Rh1B C1B C7AB 121.09(13) . . . . ?
P1B Rh1B C1B C7AB -59.2(3) . . . . ?
C2B Rh1B C1B C7AB -113.2(2) . . . . ?
C3B Rh1B C1B C7AB -76.48(16) . . . . ?
C3AB Rh1B C1B C7AB -35.27(14) . . . . ?
C7A C1 C2 C3 8.9(3) . . . . ?
Rh1 C1 C2 C3 -61.47(16) . . . . ?
C7A C1 C2 Rh1 70.35(15) . . . . ?
P1 Rh1 C2 C3 -178.56(12) . . . . ?
C1 Rh1 C2 C3 118.3(2) . . . . ?
P2B Rh1 C2 C3 -48.65(17) . . . . ?
C7A Rh1 C2 C3 79.18(15) . . . . ?
C3A Rh1 C2 C3 38.44(13) . . . . ?
P1 Rh1 C2 C1 63.09(15) . . . . ?
P2B Rh1 C2 C1 -167.00(11) . . . . ?
C3 Rh1 C2 C1 -118.3(2) . . . . ?
C7A Rh1 C2 C1 -39.17(13) . . . . ?
C3A Rh1 C2 C1 -79.91(15) . . . . ?
C7AB C1B C2B C3B 8.7(3) . . . . ?
Rh1B C1B C2B C3B -62.95(16) . . . . ?
C7AB C1B C2B Rh1B 71.65(16) . . . . ?
P2 Rh1B C2B C3B -175.71(13) . . . . ?
P1B Rh1B C2B C3B -45.43(18) . . . . ?
C1B Rh1B C2B C3B 117.6(2) . . . . ?
C7AB Rh1B C2B C3B 78.65(16) . . . . ?
C3AB Rh1B C2B C3B 38.38(15) . . . . ?
P2 Rh1B C2B C1B 66.72(15) . . . . ?
P1B Rh1B C2B C1B -163.00(12) . . . . ?
C3B Rh1B C2B C1B -117.6(2) . . . . ?
C7AB Rh1B C2B C1B -38.92(14) . . . . ?
C3AB Rh1B C2B C1B -79.20(16) . . . . ?
C1 C2 C3 C3A -9.3(3) . . . . ?
Rh1 C2 C3 C3A -69.70(16) . . . . ?
C1 C2 C3 Rh1 60.38(16) . . . . ?
P1 Rh1 C3 C2 3.1(3) . . . . ?
C1 Rh1 C3 C2 -36.97(14) . . . . ?
P2B Rh1 C3 C2 144.36(13) . . . . ?
C7A Rh1 C3 C2 -79.22(15) . . . . ?
C3A Rh1 C3 C2 -114.3(2) . . . . ?
P1 Rh1 C3 C3A 117.43(16) . . . . ?
C1 Rh1 C3 C3A 77.34(14) . . . . ?
P2B Rh1 C3 C3A -101.33(13) . . . . ?
C2 Rh1 C3 C3A 114.3(2) . . . . ?
C7A Rh1 C3 C3A 35.08(13) . . . . ?
C2 C3 C3A C4 -172.6(2) . . . . ?
Rh1 C3 C3A C4 121.5(3) . . . . ?
C2 C3 C3A C7A 6.2(3) . . . . ?
Rh1 C3 C3A C7A -59.75(16) . . . . ?
C2 C3 C3A Rh1 65.91(16) . . . . ?
P1 Rh1 C3A C4 95.4(2) . . . . ?
C1 Rh1 C3A C4 151.1(2) . . . . ?
P2B Rh1 C3A C4 -38.0(2) . . . . ?
C3 Rh1 C3A C4 -126.8(3) . . . . ?
C2 Rh1 C3A C4 -165.8(3) . . . . ?
C7A Rh1 C3A C4 113.5(3) . . . . ?
P1 Rh1 C3A C7A -18.2(2) . . . . ?
C1 Rh1 C3A C7A 37.60(14) . . . . ?
P2B Rh1 C3A C7A -151.55(12) . . . . ?
C3 Rh1 C3A C7A 119.7(2) . . . . ?
C2 Rh1 C3A C7A 80.67(15) . . . . ?
P1 Rh1 C3A C3 -137.82(13) . . . . ?
C1 Rh1 C3A C3 -82.06(15) . . . . ?
P2B Rh1 C3A C3 88.78(13) . . . . ?
C2 Rh1 C3A C3 -38.99(14) . . . . ?
C7A Rh1 C3A C3 -119.7(2) . . . . ?
C1B C2B C3B C3AB -9.0(3) . . . . ?
Rh1B C2B C3B C3AB -70.74(16) . . . . ?
C1B C2B C3B Rh1B 61.74(16) . . . . ?
P2 Rh1B C3B C2B 9.2(3) . . . . ?
P1B Rh1B C3B C2B 147.13(14) . . . . ?
C1B Rh1B C3B C2B -37.57(15) . . . . ?
C7AB Rh1B C3B C2B -79.33(16) . . . . ?
C3AB Rh1B C3B C2B -114.1(2) . . . . ?
P2 Rh1B C3B C3AB 123.31(17) . . . . ?
P1B Rh1B C3B C3AB -98.74(14) . . . . ?
C1B Rh1B C3B C3AB 76.56(15) . . . . ?
C2B Rh1B C3B C3AB 114.1(2) . . . . ?
C7AB Rh1B C3B C3AB 34.80(14) . . . . ?
C2B C3B C3AB C4B -173.6(3) . . . . ?
Rh1B C3B C3AB C4B 120.8(3) . . . . ?
C2B C3B C3AB C7AB 5.8(3) . . . . ?
Rh1B C3B C3AB C7AB -59.71(16) . . . . ?
C2B C3B C3AB Rh1B 65.53(16) . . . . ?
P2 Rh1B C3AB C4B 98.0(3) . . . . ?
P1B Rh1B C3AB C4B -35.0(3) . . . . ?
C1B Rh1B C3AB C4B 151.5(3) . . . . ?
C2B Rh1B C3AB C4B -165.0(3) . . . . ?
C3B Rh1B C3AB C4B -125.9(3) . . . . ?
C7AB Rh1B C3AB C4B 114.4(3) . . . . ?
P2 Rh1B C3AB C7AB -16.4(2) . . . . ?
P1B Rh1B C3AB C7AB -149.44(13) . . . . ?
C1B Rh1B C3AB C7AB 37.04(14) . . . . ?
C2B Rh1B C3AB C7AB 80.58(16) . . . . ?
C3B Rh1B C3AB C7AB 119.7(2) . . . . ?
P2 Rh1B C3AB C3B -136.08(14) . . . . ?
P1B Rh1B C3AB C3B 90.88(14) . . . . ?
C1B Rh1B C3AB C3B -82.64(16) . . . . ?
C2B Rh1B C3AB C3B -39.10(14) . . . . ?
C7AB Rh1B C3AB C3B -119.7(2) . . . . ?
C7A C3A C4 C5 1.2(3) . . . . ?
C3 C3A C4 C5 179.9(2) . . . . ?
Rh1 C3A C4 C5 -87.9(3) . . . . ?
C7AB C3AB C4B C5B 0.5(4) . . . . ?
C3B C3AB C4B C5B 179.9(3) . . . . ?
Rh1B C3AB C4B C5B -89.5(3) . . . . ?
C3A C4 C5 C6 1.9(4) . . . . ?
C3AB C4B C5B C6B 1.8(4) . . . . ?
C4 C5 C6 C7 -1.8(4) . . . . ?
C4B C5B C6B C7B -1.8(4) . . . . ?
C5 C6 C7 C7A -1.5(4) . . . . ?
C6 C7 C7A C3A 4.6(3) . . . . ?
C6 C7 C7A C1 -179.0(2) . . . . ?
C6 C7 C7A Rh1 94.0(3) . . . . ?
C4 C3A C7A C7 -4.5(3) . . . . ?
C3 C3A C7A C7 176.5(2) . . . . ?
Rh1 C3A C7A C7 119.9(2) . . . . ?
C4 C3A C7A C1 178.3(2) . . . . ?
C3 C3A C7A C1 -0.7(2) . . . . ?
Rh1 C3A C7A C1 -57.27(15) . . . . ?
C4 C3A C7A Rh1 -124.5(2) . . . . ?
C3 C3A C7A Rh1 56.58(15) . . . . ?
C2 C1 C7A C7 178.3(2) . . . . ?
Rh1 C1 C7A C7 -114.3(3) . . . . ?
C2 C1 C7A C3A -5.0(2) . . . . ?
Rh1 C1 C7A C3A 62.36(16) . . . . ?
C2 C1 C7A Rh1 -67.34(15) . . . . ?
P1 Rh1 C7A C7 54.4(2) . . . . ?
C1 Rh1 C7A C7 126.9(3) . . . . ?
P2B Rh1 C7A C7 -73.9(2) . . . . ?
C3 Rh1 C7A C7 -151.3(2) . . . . ?
C2 Rh1 C7A C7 166.4(2) . . . . ?
C3A Rh1 C7A C7 -115.3(3) . . . . ?
P1 Rh1 C7A C3A 169.63(11) . . . . ?
C1 Rh1 C7A C3A -117.8(2) . . . . ?
P2B Rh1 C7A C3A 41.41(17) . . . . ?
C3 Rh1 C7A C3A -36.05(13) . . . . ?
C2 Rh1 C7A C3A -78.36(15) . . . . ?
P1 Rh1 C7A C1 -72.58(14) . . . . ?
P2B Rh1 C7A C1 159.20(11) . . . . ?
C3 Rh1 C7A C1 81.75(15) . . . . ?
C2 Rh1 C7A C1 39.43(14) . . . . ?
C3A Rh1 C7A C1 117.8(2) . . . . ?
C5B C6B C7B C7AB -0.5(4) . . . . ?
C6B C7B C7AB C3AB 2.7(4) . . . . ?
C6B C7B C7AB C1B -179.7(3) . . . . ?
C6B C7B C7AB Rh1B 93.1(3) . . . . ?
C4B C3AB C7AB C7B -2.8(3) . . . . ?
C3B C3AB C7AB C7B 177.7(2) . . . . ?
Rh1B C3AB C7AB C7B 121.9(2) . . . . ?
C4B C3AB C7AB C1B 179.1(2) . . . . ?
C3B C3AB C7AB C1B -0.5(3) . . . . ?
Rh1B C3AB C7AB C1B -56.19(15) . . . . ?
C4B C3AB C7AB Rh1B -124.7(2) . . . . ?
C3B C3AB C7AB Rh1B 55.74(15) . . . . ?
C2B C1B C7AB C7B 177.3(3) . . . . ?
Rh1B C1B C7AB C7B -115.8(3) . . . . ?
C2B C1B C7AB C3AB -5.0(3) . . . . ?
Rh1B C1B C7AB C3AB 61.97(16) . . . . ?
C2B C1B C7AB Rh1B -66.96(15) . . . . ?
P2 Rh1B C7AB C7B 56.2(2) . . . . ?
P1B Rh1B C7AB C7B -72.0(2) . . . . ?
C1B Rh1B C7AB C7B 126.7(3) . . . . ?
C2B Rh1B C7AB C7B 166.7(3) . . . . ?
C3B Rh1B C7AB C7B -150.9(3) . . . . ?
C3AB Rh1B C7AB C7B -114.8(3) . . . . ?
P2 Rh1B C7AB C3AB 171.08(12) . . . . ?
P1B Rh1B C7AB C3AB 42.87(17) . . . . ?
C1B Rh1B C7AB C3AB -118.5(2) . . . . ?
C2B Rh1B C7AB C3AB -78.45(16) . . . . ?
C3B Rh1B C7AB C3AB -36.04(15) . . . . ?
P2 Rh1B C7AB C1B -70.45(15) . . . . ?
P1B Rh1B C7AB C1B 161.34(12) . . . . ?
C2B Rh1B C7AB C1B 40.02(14) . . . . ?
C3B Rh1B C7AB C1B 82.43(16) . . . . ?
C3AB Rh1B C7AB C1B 118.5(2) . . . . ?
C20 P1 C8 C9 157.27(19) . . . . ?
C14 P1 C8 C9 51.3(2) . . . . ?
Rh1 P1 C8 C9 -84.86(19) . . . . ?
C20 P1 C8 C13 -28.0(2) . . . . ?
C14 P1 C8 C13 -133.9(2) . . . . ?
Rh1 P1 C8 C13 89.89(19) . . . . ?
C20B P1B C8B C9B -142.3(2) . . . . ?
C14B P1B C8B C9B -38.9(2) . . . . ?
Rh1B P1B C8B C9B 88.5(2) . . . . ?
C20B P1B C8B C13B 44.4(2) . . . . ?
C14B P1B C8B C13B 147.8(2) . . . . ?
Rh1B P1B C8B C13B -84.8(2) . . . . ?
C13 C8 C9 C10 -0.4(4) . . . . ?
P1 C8 C9 C10 174.4(2) . . . . ?
C13B C8B C9B C10B 0.0(4) . . . . ?
P1B C8B C9B C10B -173.4(2) . . . . ?
C8 C9 C10 C11 -0.2(4) . . . . ?
C8B C9B C10B C11B 0.1(4) . . . . ?
C9 C10 C11 C12 0.5(5) . . . . ?
C9B C10B C11B C12B -0.1(5) . . . . ?
C10 C11 C12 C13 -0.2(4) . . . . ?
C10B C11B C12B C13B 0.2(5) . . . . ?
C9 C8 C13 C12 0.7(4) . . . . ?
P1 C8 C13 C12 -174.05(19) . . . . ?
C11 C12 C13 C8 -0.4(4) . . . . ?
C9B C8B C13B C12B 0.0(4) . . . . ?
P1B C8B C13B C12B 173.5(2) . . . . ?
C11B C12B C13B C8B -0.1(5) . . . . ?
C20 P1 C14 C19 157.03(18) . . . . ?
C8 P1 C14 C19 -96.45(19) . . . . ?
Rh1 P1 C14 C19 35.5(2) . . . . ?
C20 P1 C14 C15 -22.7(2) . . . . ?
C8 P1 C14 C15 83.8(2) . . . . ?
Rh1 P1 C14 C15 -144.17(17) . . . . ?
C20B P1B C14B C19B -149.32(19) . . . . ?
C8B P1B C14B C19B 107.23(19) . . . . ?
Rh1B P1B C14B C19B -18.7(2) . . . . ?
C20B P1B C14B C15B 27.7(2) . . . . ?
C8B P1B C14B C15B -75.8(2) . . . . ?
Rh1B P1B C14B C15B 158.29(19) . . . . ?
C19 C14 C15 C16 0.0(3) . . . . ?
P1 C14 C15 C16 179.76(19) . . . . ?
C19B C14B C15B C16B 2.2(4) . . . . ?
P1B C14B C15B C16B -174.8(2) . . . . ?
C14 C15 C16 C17 -0.4(4) . . . . ?
C14B C15B C16B C17B -1.4(5) . . . . ?
C15 C16 C17 C18 0.3(4) . . . . ?
C15B C16B C17B C18B -0.4(5) . . . . ?
C16 C17 C18 C19 0.0(4) . . . . ?
C16B C17B C18B C19B 1.3(5) . . . . ?
C17 C18 C19 C14 -0.3(4) . . . . ?
C15 C14 C19 C18 0.3(3) . . . . ?
P1 C14 C19 C18 -179.43(18) . . . . ?
C17B C18B C19B C14B -0.4(4) . . . . ?
C15B C14B C19B C18B -1.3(4) . . . . ?
P1B C14B C19B C18B 175.82(19) . . . . ?
C14 P1 C20 C21 -100.6(8) . . . . ?
C8 P1 C20 C21 152.8(8) . . . . ?
Rh1 P1 C20 C21 30.2(8) . . . . ?
P1 C20 C21 P2 30.2(17) . . . . ?
C22 P2 C21 C20 -63.9(10) . . . . ?
C28 P2 C21 C20 -169.3(10) . . . . ?
Rh1B P2 C21 C20 67.9(11) . . . . ?
C21 P2 C22 C23 161.19(18) . . . . ?
C28 P2 C22 C23 -94.27(18) . . . . ?
Rh1B P2 C22 C23 37.0(2) . . . . ?
C21 P2 C22 C27 -19.6(2) . . . . ?
C28 P2 C22 C27 84.9(2) . . . . ?
Rh1B P2 C22 C27 -143.80(16) . . . . ?
C21B P2B C22B C27B 10.2(2) . . . . ?
C28B P2B C22B C27B -93.0(2) . . . . ?
Rh1 P2B C22B C27B 140.72(18) . . . . ?
C21B P2B C22B C23B -170.23(18) . . . . ?
C28B P2B C22B C23B 86.59(19) . . . . ?
Rh1 P2B C22B C23B -39.7(2) . . . . ?
C27 C22 C23 C24 -0.5(3) . . . . ?
P2 C22 C23 C24 178.74(18) . . . . ?
C27B C22B C23B C24B 3.0(4) . . . . ?
P2B C22B C23B C24B -176.6(2) . . . . ?
C22 C23 C24 C25 -0.7(4) . . . . ?
C22B C23B C24B C25B -3.0(4) . . . . ?
C23 C24 C25 C26 1.2(4) . . . . ?
C23B C24B C25B C26B 0.4(4) . . . . ?
C24 C25 C26 C27 -0.5(4) . . . . ?
C24B C25B C26B C27B 2.2(4) . . . . ?
C25 C26 C27 C22 -0.8(4) . . . . ?
C23 C22 C27 C26 1.2(3) . . . . ?
P2 C22 C27 C26 -177.96(18) . . . . ?
C23B C22B C27B C26B -0.4(4) . . . . ?
P2B C22B C27B C26B 179.1(2) . . . . ?
C25B C26B C27B C22B -2.1(4) . . . . ?
C21 P2 C28 C29 150.67(19) . . . . ?
C22 P2 C28 C29 46.6(2) . . . . ?
Rh1B P2 C28 C29 -89.18(19) . . . . ?
C21 P2 C28 C33 -36.2(2) . . . . ?
C22 P2 C28 C33 -140.27(19) . . . . ?
Rh1B P2 C28 C33 83.93(19) . . . . ?
C21B P2B C28B C29B 35.3(2) . . . . ?
C22B P2B C28B C29B 139.72(19) . . . . ?
Rh1 P2B C28B C29B -90.82(19) . . . . ?
C21B P2B C28B C33B -149.88(19) . . . . ?
C22B P2B C28B C33B -45.4(2) . . . . ?
Rh1 P2B C28B C33B 84.03(19) . . . . ?
C33 C28 C29 C30 -0.7(3) . . . . ?
P2 C28 C29 C30 172.49(18) . . . . ?
C33B C28B C29B C30B -0.1(4) . . . . ?
P2B C28B C29B C30B 174.8(2) . . . . ?
C28 C29 C30 C31 -0.6(4) . . . . ?
C28B C29B C30B C31B -0.2(4) . . . . ?
C29 C30 C31 C32 1.8(4) . . . . ?
C29B C30B C31B C32B -0.1(4) . . . . ?
C30 C31 C32 C33 -1.8(4) . . . . ?
C30B C31B C32B C33B 0.7(4) . . . . ?
C31 C32 C33 C28 0.5(4) . . . . ?
C29 C28 C33 C32 0.7(4) . . . . ?
P2 C28 C33 C32 -172.48(19) . . . . ?
C31B C32B C33B C28B -1.0(4) . . . . ?
C29B C28B C33B C32B 0.7(4) . . . . ?
P2B C28B C33B C32B -174.24(19) . . . . ?
