#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:31:00 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179688 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001055.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001055
loop_
_publ_author_name
'Hoshino, Manabu'
'Uekusa, Hidehiro'
'Sonoda, Shintaro'
'Otsuka, Takuhiro'
'Kaizu, Youkoh'
_publ_section_title
;
 Photocrystallographic analysis of [AuCl(PPh3)2] for elucidation of the
 crystal packing effect on the photophysical properties
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              3085
_journal_page_last               3091
_journal_paper_doi               10.1039/b820066a
_journal_year                    2009
_chemical_formula_sum            'C36 H30 Au Cl P2'
_chemical_formula_weight         756.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.0546(10)
_cell_angle_beta                 95.5288(8)
_cell_angle_gamma                109.6372(9)
_cell_formula_units_Z            2
_cell_length_a                   10.8546(2)
_cell_length_b                   11.82870(10)
_cell_length_c                   14.1760(2)
_cell_measurement_temperature    137(2)
_cell_volume                     1521.82(4)
_computing_cell_refinement       'HKL Research, Inc. HKL-2000'
_computing_data_collection       'Rigaku RAPID AUTO'
_computing_data_reduction        'HKL Research, Inc. HKL-2000'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2002 (Giacovazzo, 2003)'
_diffrn_ambient_temperature      137(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode Ultrax18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_av_sigmaI/netI    0.0159
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            46909
_diffrn_reflns_theta_full        32.31
_diffrn_reflns_theta_max         32.31
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    5.051
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.741
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL SCALEPACK (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.652
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.841
_refine_diff_density_min         -0.523
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         10772
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0136
_refine_ls_R_factor_gt           0.0135
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0027P)²+1.3667P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0361
_refine_ls_wR_factor_ref         0.0362
_reflns_number_gt                10724
_reflns_number_total             10772
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b820066a.txt
_cod_data_source_block           137Koff
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7001055
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.210983(5) 0.246340(5) 0.275619(4) 0.01554(2) Uani 1 1 d . . .
P1 P 0.30567(3) 0.09708(3) 0.27603(3) 0.01466(5) Uani 1 1 d . . .
C111 C 0.25491(13) 0.00371(13) 0.35129(10) 0.0155(2) Uani 1 1 d . . .
C112 C 0.34063(14) -0.04279(15) 0.38964(12) 0.0207(2) Uani 1 1 d . . .
H112 H 0.430(2) -0.021(2) 0.3780(17) 0.025 Uiso 1 1 d . . .
C113 C 0.29948(16) -0.11498(16) 0.44655(13) 0.0233(3) Uani 1 1 d . . .
H113 H 0.357(2) -0.146(2) 0.4722(18) 0.028 Uiso 1 1 d . . .
C114 C 0.17253(16) -0.14045(15) 0.46610(12) 0.0222(3) Uani 1 1 d . . .
H114 H 0.142(2) -0.193(2) 0.5033(17) 0.027 Uiso 1 1 d . . .
C115 C 0.08684(15) -0.09389(14) 0.42850(12) 0.0215(2) Uani 1 1 d . . .
H115 H -0.001(2) -0.110(2) 0.4434(17) 0.026 Uiso 1 1 d . . .
C116 C 0.12770(13) -0.02148(14) 0.37172(11) 0.0180(2) Uani 1 1 d . . .
H116 H 0.070(2) 0.012(2) 0.3501(16) 0.022 Uiso 1 1 d . . .
C121 C 0.28860(13) -0.02675(14) 0.14311(10) 0.0181(2) Uani 1 1 d . . .
C122 C 0.2773(2) -0.15580(16) 0.11978(13) 0.0316(3) Uani 1 1 d . . .
H122 H 0.273(2) -0.183(2) 0.175(2) 0.038 Uiso 1 1 d . . .
C123 C 0.2712(3) -0.24357(18) 0.01739(15) 0.0406(5) Uani 1 1 d . . .
H123 H 0.260(3) -0.333(3) 0.004(2) 0.049 Uiso 1 1 d . . .
C124 C 0.2751(2) -0.20395(19) -0.06214(14) 0.0364(4) Uani 1 1 d . . .
H124 H 0.269(3) -0.264(3) -0.131(2) 0.044 Uiso 1 1 d . . .
C125 C 0.2856(3) -0.0762(2) -0.03942(15) 0.0400(4) Uani 1 1 d . . .
H125 H 0.291(3) -0.044(3) -0.092(2) 0.048 Uiso 1 1 d . . .
C126 C 0.2916(2) 0.01217(19) 0.06232(13) 0.0314(3) Uani 1 1 d . . .
H126 H 0.300(2) 0.098(3) 0.077(2) 0.038 Uiso 1 1 d . . .
C131 C 0.48738(13) 0.19058(13) 0.33273(10) 0.0161(2) Uani 1 1 d . . .
C132 C 0.58234(14) 0.15044(16) 0.28568(12) 0.0221(3) Uani 1 1 d . . .
H132 H 0.553(2) 0.069(2) 0.2206(18) 0.026 Uiso 1 1 d . . .
C133 C 0.72054(15) 0.22858(18) 0.33283(13) 0.0263(3) Uani 1 1 d . . .
H133 H 0.787(2) 0.202(2) 0.3017(19) 0.032 Uiso 1 1 d . . .
C134 C 0.76428(15) 0.34731(17) 0.42607(13) 0.0252(3) Uani 1 1 d . . .
H134 H 0.860(2) 0.400(2) 0.4591(18) 0.030 Uiso 1 1 d . . .
C135 C 0.67015(16) 0.38778(16) 0.47364(12) 0.0249(3) Uani 1 1 d . . .
H135 H 0.696(2) 0.471(2) 0.5349(18) 0.030 Uiso 1 1 d . . .
C136 C 0.53228(15) 0.30988(15) 0.42727(11) 0.0215(2) Uani 1 1 d . . .
H136 H 0.468(2) 0.338(2) 0.4592(17) 0.026 Uiso 1 1 d . . .
P2 P 0.23056(3) 0.39141(3) 0.20064(3) 0.01599(6) Uani 1 1 d . . .
C211 C 0.39792(13) 0.52995(14) 0.26082(10) 0.0174(2) Uani 1 1 d . . .
C212 C 0.50580(16) 0.50535(18) 0.29687(15) 0.0271(3) Uani 1 1 d . . .
H212 H 0.491(2) 0.417(2) 0.2860(19) 0.033 Uiso 1 1 d . . .
C213 C 0.63387(16) 0.6089(2) 0.34835(15) 0.0316(3) Uani 1 1 d . . .
H213 H 0.708(2) 0.593(2) 0.375(2) 0.038 Uiso 1 1 d . . .
C214 C 0.65633(16) 0.73732(18) 0.36343(13) 0.0291(3) Uani 1 1 d . . .
H214 H 0.740(2) 0.805(2) 0.3973(19) 0.035 Uiso 1 1 d . . .
C215 C 0.55115(17) 0.76317(16) 0.32684(15) 0.0298(3) Uani 1 1 d . . .
H215 H 0.567(2) 0.850(3) 0.338(2) 0.036 Uiso 1 1 d . . .
C216 C 0.42167(15) 0.65999(15) 0.27621(13) 0.0246(3) Uani 1 1 d . . .
H216 H 0.349(2) 0.681(2) 0.2539(18) 0.029 Uiso 1 1 d . . .
C221 C 0.11061(13) 0.46865(13) 0.20695(11) 0.0173(2) Uani 1 1 d . . .
C222 C 0.09267(16) 0.52548(16) 0.13977(13) 0.0239(3) Uani 1 1 d . . .
H222 H 0.144(2) 0.520(2) 0.0869(18) 0.029 Uiso 1 1 d . . .
C223 C 0.00337(17) 0.58821(17) 0.14978(13) 0.0265(3) Uani 1 1 d . . .
H223 H -0.005(2) 0.627(2) 0.1046(19) 0.032 Uiso 1 1 d . . .
C224 C -0.06901(17) 0.59320(16) 0.22586(13) 0.0260(3) Uani 1 1 d . . .
H224 H -0.129(2) 0.636(2) 0.2320(18) 0.031 Uiso 1 1 d . . .
C225 C -0.05188(17) 0.53640(17) 0.29239(14) 0.0260(3) Uani 1 1 d . . .
H225 H -0.103(2) 0.543(2) 0.3464(18) 0.031 Uiso 1 1 d . . .
C226 C 0.03739(15) 0.47391(15) 0.28288(12) 0.0208(2) Uani 1 1 d . . .
H226 H 0.049(2) 0.434(2) 0.3266(17) 0.025 Uiso 1 1 d . . .
C231 C 0.22006(14) 0.30825(14) 0.05957(11) 0.0198(2) Uani 1 1 d . . .
C232 C 0.3237(2) 0.3510(2) 0.01540(15) 0.0401(5) Uani 1 1 d . . .
H232 H 0.401(3) 0.428(3) 0.055(2) 0.048 Uiso 1 1 d . . .
C233 C 0.3126(2) 0.2779(3) -0.09186(17) 0.0535(7) Uani 1 1 d . . .
H233 H 0.383(3) 0.303(3) -0.121(3) 0.064 Uiso 1 1 d . . .
C234 C 0.1991(2) 0.1611(2) -0.15521(14) 0.0391(4) Uani 1 1 d . . .
H234 H 0.194(3) 0.109(3) -0.230(2) 0.047 Uiso 1 1 d . . .
C235 C 0.0949(2) 0.1188(2) -0.11163(14) 0.0350(4) Uani 1 1 d . . .
H235 H 0.018(3) 0.036(3) -0.153(2) 0.042 Uiso 1 1 d . . .
C236 C 0.10485(17) 0.19165(18) -0.00487(13) 0.0297(3) Uani 1 1 d . . .
H236 H 0.032(2) 0.161(2) 0.0248(19) 0.036 Uiso 1 1 d . . .
Cl1 Cl 0.06797(4) 0.26640(4) 0.40846(3) 0.02475(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Au1 P1 136.814(12) . . ?
P2 Au1 Cl1 114.185(12) . . ?
P1 Au1 Cl1 108.649(12) . . ?
P2 Au1 Au1 80.288(9) . 2 ?
P1 Au1 Au1 89.278(8) . 2 ?
Cl1 Au1 Au1 111.599(10) . 2 ?
C111 P1 C131 103.86(6) . . ?
C111 P1 C121 106.07(6) . . ?
C131 P1 C121 104.20(6) . . ?
C111 P1 Au1 119.56(4) . . ?
C131 P1 Au1 108.53(4) . . ?
C121 P1 Au1 113.20(5) . . ?
C112 C111 C116 119.33(12) . . ?
C112 C111 P1 121.37(10) . . ?
C116 C111 P1 119.29(10) . . ?
C113 C112 C111 120.50(13) . . ?
C113 C112 H112 120.7(13) . . ?
C111 C112 H112 118.8(13) . . ?
C114 C113 C112 119.93(14) . . ?
C114 C113 H113 119.6(14) . . ?
C112 C113 H113 120.5(14) . . ?
C113 C114 C115 119.87(13) . . ?
C113 C114 H114 120.5(13) . . ?
C115 C114 H114 119.6(13) . . ?
C114 C115 C116 120.38(13) . . ?
C114 C115 H115 119.9(13) . . ?
C116 C115 H115 119.7(13) . . ?
C115 C116 C111 119.99(13) . . ?
C115 C116 H116 118.5(13) . . ?
C111 C116 H116 121.5(13) . . ?
C122 C121 C126 118.80(14) . . ?
C122 C121 P1 123.14(11) . . ?
C126 C121 P1 118.03(11) . . ?
C121 C122 C123 120.25(16) . . ?
C121 C122 H122 118.4(15) . . ?
C123 C122 H122 121.3(15) . . ?
C124 C123 C122 120.61(18) . . ?
C124 C123 H123 121.7(17) . . ?
C122 C123 H123 117.6(17) . . ?
C125 C124 C123 119.31(16) . . ?
C125 C124 H124 121.1(17) . . ?
C123 C124 H124 119.6(17) . . ?
C124 C125 C126 120.63(17) . . ?
C124 C125 H125 122.0(16) . . ?
C126 C125 H125 117.4(16) . . ?
C125 C126 C121 120.40(16) . . ?
C125 C126 H126 119.8(16) . . ?
C121 C126 H126 119.8(16) . . ?
C132 C131 C136 119.36(13) . . ?
C132 C131 P1 123.28(10) . . ?
C136 C131 P1 117.35(10) . . ?
C133 C132 C131 120.16(14) . . ?
C133 C132 H132 119.8(13) . . ?
C131 C132 H132 120.0(13) . . ?
C134 C133 C132 120.15(14) . . ?
C134 C133 H133 118.8(14) . . ?
C132 C133 H133 121.0(14) . . ?
C133 C134 C135 120.02(14) . . ?
C133 C134 H134 119.8(14) . . ?
C135 C134 H134 120.2(14) . . ?
C136 C135 C134 120.05(14) . . ?
C136 C135 H135 117.5(14) . . ?
C134 C135 H135 122.2(14) . . ?
C135 C136 C131 120.26(14) . . ?
C135 C136 H136 120.0(13) . . ?
C131 C136 H136 119.7(13) . . ?
C221 P2 C211 105.86(6) . . ?
C221 P2 C231 104.43(6) . . ?
C211 P2 C231 105.55(6) . . ?
C221 P2 Au1 119.50(5) . . ?
C211 P2 Au1 109.47(5) . . ?
C231 P2 Au1 111.05(5) . . ?
C216 C211 C212 118.74(13) . . ?
C216 C211 P2 122.97(11) . . ?
C212 C211 P2 118.23(11) . . ?
C213 C212 C211 120.61(16) . . ?
C213 C212 H212 120.2(14) . . ?
C211 C212 H212 119.2(14) . . ?
C214 C213 C212 120.23(16) . . ?
C214 C213 H213 119.1(15) . . ?
C212 C213 H213 120.7(15) . . ?
C213 C214 C215 119.97(15) . . ?
C213 C214 H214 120.2(16) . . ?
C215 C214 H214 119.8(16) . . ?
C214 C215 C216 120.16(16) . . ?
C214 C215 H215 119.5(15) . . ?
C216 C215 H215 120.3(15) . . ?
C211 C216 C215 120.28(15) . . ?
C211 C216 H216 120.7(14) . . ?
C215 C216 H216 119.0(14) . . ?
C226 C221 C222 119.50(13) . . ?
C226 C221 P2 118.69(10) . . ?
C222 C221 P2 121.80(11) . . ?
C223 C222 C221 120.03(14) . . ?
C223 C222 H222 121.5(14) . . ?
C221 C222 H222 118.5(14) . . ?
C224 C223 C222 120.06(14) . . ?
C224 C223 H223 121.8(14) . . ?
C222 C223 H223 118.1(15) . . ?
C225 C224 C223 120.06(14) . . ?
C225 C224 H224 120.5(14) . . ?
C223 C224 H224 119.5(14) . . ?
C224 C225 C226 120.11(15) . . ?
C224 C225 H225 118.3(14) . . ?
C226 C225 H225 121.6(14) . . ?
C225 C226 C221 120.24(13) . . ?
C225 C226 H226 121.0(13) . . ?
C221 C226 H226 118.8(13) . . ?
C232 C231 C236 118.96(14) . . ?
C232 C231 P2 123.26(12) . . ?
C236 C231 P2 117.67(11) . . ?
C231 C232 C233 120.36(17) . . ?
C231 C232 H232 121.5(17) . . ?
C233 C232 H232 118.1(17) . . ?
C234 C233 C232 120.54(18) . . ?
C234 C233 H233 118(2) . . ?
C232 C233 H233 121(2) . . ?
C233 C234 C235 119.26(17) . . ?
C233 C234 H234 119.7(16) . . ?
C235 C234 H234 121.1(16) . . ?
C234 C235 C236 120.52(17) . . ?
C234 C235 H235 120.6(16) . . ?
C236 C235 H235 118.8(16) . . ?
C235 C236 C231 120.35(16) . . ?
C235 C236 H236 119.9(15) . . ?
C231 C236 H236 119.7(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P2 2.3122(3) . ?
Au1 P1 2.3238(3) . ?
Au1 Cl1 2.5443(3) . ?
Au1 Au1 7.44986(18) 2 ?
P1 C111 1.8135(13) . ?
P1 C131 1.8142(13) . ?
P1 C121 1.8218(14) . ?
C111 C112 1.3944(19) . ?
C111 C116 1.3955(18) . ?
C112 C113 1.390(2) . ?
C112 H112 0.97(2) . ?
C113 C114 1.388(2) . ?
C113 H113 0.93(2) . ?
C114 C115 1.390(2) . ?
C114 H114 0.96(2) . ?
C115 C116 1.3898(19) . ?
C115 H115 0.97(2) . ?
C116 H116 0.93(2) . ?
C121 C122 1.388(2) . ?
C121 C126 1.391(2) . ?
C122 C123 1.394(2) . ?
C122 H122 0.96(3) . ?
C123 C124 1.379(3) . ?
C123 H123 0.96(3) . ?
C124 C125 1.377(3) . ?
C124 H124 0.93(3) . ?
C125 C126 1.390(2) . ?
C125 H125 0.96(3) . ?
C126 H126 0.93(3) . ?
C131 C132 1.3950(19) . ?
C131 C136 1.3984(19) . ?
C132 C133 1.394(2) . ?
C132 H132 0.96(2) . ?
C133 C134 1.386(2) . ?
C133 H133 0.96(2) . ?
C134 C135 1.392(2) . ?
C134 H134 0.97(2) . ?
C135 C136 1.389(2) . ?
C135 H135 0.95(2) . ?
C136 H136 0.95(2) . ?
P2 C221 1.8154(14) . ?
P2 C211 1.8218(14) . ?
P2 C231 1.8221(14) . ?
C211 C216 1.393(2) . ?
C211 C212 1.395(2) . ?
C212 C213 1.388(2) . ?
C212 H212 0.94(2) . ?
C213 C214 1.378(3) . ?
C213 H213 0.96(3) . ?
C214 C215 1.382(3) . ?
C214 H214 0.91(2) . ?
C215 C216 1.395(2) . ?
C215 H215 0.93(3) . ?
C216 H216 0.96(2) . ?
C221 C226 1.3928(19) . ?
C221 C222 1.3966(19) . ?
C222 C223 1.392(2) . ?
C222 H222 0.97(2) . ?
C223 C224 1.389(2) . ?
C223 H223 0.94(2) . ?
C224 C225 1.386(2) . ?
C224 H224 0.94(2) . ?
C225 C226 1.390(2) . ?
C225 H225 0.98(2) . ?
C226 H226 0.94(2) . ?
C231 C232 1.384(2) . ?
C231 C236 1.391(2) . ?
C232 C233 1.392(3) . ?
C232 H232 0.92(3) . ?
C233 C234 1.380(3) . ?
C233 H233 0.91(3) . ?
C234 C235 1.381(3) . ?
C234 H234 0.98(3) . ?
C235 C236 1.389(2) . ?
C235 H235 0.95(3) . ?
C236 H236 0.96(2) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C114 H114 Cl1 0.96(2) 2.76(2) 3.5428(15) 139.9(17) 2_556
C116 H116 Cl1 0.93(2) 2.80(2) 3.5281(14) 135.6(16) .
C226 H226 Cl1 0.94(2) 2.71(2) 3.6278(15) 166.4(17) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Au1 P1 C111 179.62(5) . . . . ?
Cl1 Au1 P1 C111 7.16(5) . . . . ?
Au1 Au1 P1 C111 -105.44(5) 2 . . . ?
P2 Au1 P1 C131 60.89(5) . . . . ?
Cl1 Au1 P1 C131 -111.57(5) . . . . ?
Au1 Au1 P1 C131 135.83(4) 2 . . . ?
P2 Au1 P1 C121 -54.26(5) . . . . ?
Cl1 Au1 P1 C121 133.27(5) . . . . ?
Au1 Au1 P1 C121 20.67(5) 2 . . . ?
C131 P1 C111 C112 -32.92(13) . . . . ?
C121 P1 C111 C112 76.60(13) . . . . ?
Au1 P1 C111 C112 -154.00(10) . . . . ?
C131 P1 C111 C116 146.73(11) . . . . ?
C121 P1 C111 C116 -103.76(11) . . . . ?
Au1 P1 C111 C116 25.64(12) . . . . ?
C116 C111 C112 C113 0.8(2) . . . . ?
P1 C111 C112 C113 -179.56(12) . . . . ?
C111 C112 C113 C114 -0.4(2) . . . . ?
C112 C113 C114 C115 0.1(2) . . . . ?
C113 C114 C115 C116 -0.2(2) . . . . ?
C114 C115 C116 C111 0.6(2) . . . . ?
C112 C111 C116 C115 -0.9(2) . . . . ?
P1 C111 C116 C115 179.45(11) . . . . ?
C111 P1 C121 C122 -16.32(15) . . . . ?
C131 P1 C121 C122 92.95(15) . . . . ?
Au1 P1 C121 C122 -149.33(13) . . . . ?
C111 P1 C121 C126 165.84(13) . . . . ?
C131 P1 C121 C126 -84.88(14) . . . . ?
Au1 P1 C121 C126 32.84(14) . . . . ?
C126 C121 C122 C123 1.0(3) . . . . ?
P1 C121 C122 C123 -176.86(16) . . . . ?
C121 C122 C123 C124 -0.6(3) . . . . ?
C122 C123 C124 C125 0.2(4) . . . . ?
C123 C124 C125 C126 -0.3(4) . . . . ?
C124 C125 C126 C121 0.7(3) . . . . ?
C122 C121 C126 C125 -1.1(3) . . . . ?
P1 C121 C126 C125 176.88(16) . . . . ?
C111 P1 C131 C132 100.08(13) . . . . ?
C121 P1 C131 C132 -10.81(14) . . . . ?
Au1 P1 C131 C132 -131.70(11) . . . . ?
C111 P1 C131 C136 -81.19(12) . . . . ?
C121 P1 C131 C136 167.93(11) . . . . ?
Au1 P1 C131 C136 47.04(11) . . . . ?
C136 C131 C132 C133 0.2(2) . . . . ?
P1 C131 C132 C133 178.88(12) . . . . ?
C131 C132 C133 C134 -0.7(2) . . . . ?
C132 C133 C134 C135 0.9(2) . . . . ?
C133 C134 C135 C136 -0.6(2) . . . . ?
C134 C135 C136 C131 0.0(2) . . . . ?
C132 C131 C136 C135 0.2(2) . . . . ?
P1 C131 C136 C135 -178.61(12) . . . . ?
P1 Au1 P2 C221 169.72(5) . . . . ?
Cl1 Au1 P2 C221 -18.10(5) . . . . ?
Au1 Au1 P2 C221 91.32(5) 2 . . . ?
P1 Au1 P2 C211 -68.07(5) . . . . ?
Cl1 Au1 P2 C211 104.11(5) . . . . ?
Au1 Au1 P2 C211 -146.47(5) 2 . . . ?
P1 Au1 P2 C231 48.09(5) . . . . ?
Cl1 Au1 P2 C231 -139.74(5) . . . . ?
Au1 Au1 P2 C231 -30.32(5) 2 . . . ?
C221 P2 C211 C216 -16.91(14) . . . . ?
C231 P2 C211 C216 93.46(13) . . . . ?
Au1 P2 C211 C216 -146.95(11) . . . . ?
C221 P2 C211 C212 160.42(12) . . . . ?
C231 P2 C211 C212 -89.22(13) . . . . ?
Au1 P2 C211 C212 30.37(13) . . . . ?
C216 C211 C212 C213 0.9(2) . . . . ?
P2 C211 C212 C213 -176.58(13) . . . . ?
C211 C212 C213 C214 -0.7(3) . . . . ?
C212 C213 C214 C215 -0.2(3) . . . . ?
C213 C214 C215 C216 1.1(3) . . . . ?
C212 C211 C216 C215 0.0(2) . . . . ?
P2 C211 C216 C215 177.28(13) . . . . ?
C214 C215 C216 C211 -0.9(3) . . . . ?
C211 P2 C221 C226 -104.22(12) . . . . ?
C231 P2 C221 C226 144.63(11) . . . . ?
Au1 P2 C221 C226 19.76(13) . . . . ?
C211 P2 C221 C222 74.15(13) . . . . ?
C231 P2 C221 C222 -37.00(14) . . . . ?
Au1 P2 C221 C222 -161.87(10) . . . . ?
C226 C221 C222 C223 0.8(2) . . . . ?
P2 C221 C222 C223 -177.59(12) . . . . ?
C221 C222 C223 C224 -0.6(2) . . . . ?
C222 C223 C224 C225 0.4(3) . . . . ?
C223 C224 C225 C226 -0.2(3) . . . . ?
C224 C225 C226 C221 0.3(2) . . . . ?
C222 C221 C226 C225 -0.6(2) . . . . ?
P2 C221 C226 C225 177.79(12) . . . . ?
C221 P2 C231 C232 110.79(17) . . . . ?
C211 P2 C231 C232 -0.59(18) . . . . ?
Au1 P2 C231 C232 -119.13(16) . . . . ?
C221 P2 C231 C236 -73.07(14) . . . . ?
C211 P2 C231 C236 175.55(13) . . . . ?
Au1 P2 C231 C236 57.01(14) . . . . ?
C236 C231 C232 C233 -0.1(3) . . . . ?
P2 C231 C232 C233 175.9(2) . . . . ?
C231 C232 C233 C234 -0.9(4) . . . . ?
C232 C233 C234 C235 1.4(4) . . . . ?
C233 C234 C235 C236 -1.0(4) . . . . ?
C234 C235 C236 C231 0.0(3) . . . . ?
C232 C231 C236 C235 0.6(3) . . . . ?
P2 C231 C236 C235 -175.70(15) . . . . ?
