#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:05:18 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179714 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/16/7001624.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001624
loop_
_publ_author_name
'Miller, Philip W.'
'Long, Nicholas J.'
'White, Andrew J. P.'
_publ_section_title
;
 Synthesis, characterisation and coordination chemistry of a new
 multidentate P2N4 ligand system
;
_journal_issue                   27
_journal_name_full               'Dalton Transactions'
_journal_page_first              5284
_journal_page_last               5286
_journal_paper_doi               10.1039/b905749h
_journal_year                    2009
_chemical_formula_moiety         'C34 H40 N8 P2 Pt, C3 H6 O, 2(Cl O4)'
_chemical_formula_sum            'C37 H46 Cl2 N8 O9 P2 Pt'
_chemical_formula_weight         1074.75
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 90.4399(8)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.35407(18)
_cell_length_b                   16.07748(18)
_cell_length_c                   14.12043(14)
_cell_measurement_reflns_used    39557
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.2740
_cell_measurement_theta_min      3.7952
_cell_volume                     4166.64(7)
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd'
_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 15.9863
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.886
_diffrn_measurement_device_type  'OD Xcalibur 3'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0281
_diffrn_reflns_av_sigmaI/netI    0.0203
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            52846
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         32.39
_diffrn_reflns_theta_min         3.84
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.636
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.68312
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May 8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.713
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             2152
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.976
_refine_diff_density_min         -1.024
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.120
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     590
_refine_ls_number_reflns         13229
_refine_ls_number_restraints     236
_refine_ls_restrained_S_all      1.126
_refine_ls_R_factor_all          0.0403
_refine_ls_R_factor_gt           0.0309
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0307P)²+8.4134P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0715
_refine_ls_wR_factor_ref         0.0800
_reflns_number_gt                11448
_reflns_number_total             13229
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b905749h.txt
_cod_data_source_block           Compound_4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7001624
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.288194(5) 0.586222(7) 0.488596(7) 0.02431(3) Uani 1 1 d . . .
P1 P 0.19235(4) 0.57842(5) 0.57934(5) 0.02585(14) Uani 1 1 d . . .
P2 P 0.29767(4) 0.45084(5) 0.49852(5) 0.02596(14) Uani 1 1 d . . .
C1 C 0.17043(17) 0.4699(2) 0.5972(2) 0.0318(6) Uani 1 1 d . . .
C2 C 0.1119(2) 0.4425(3) 0.6517(3) 0.0423(8) Uani 1 1 d . . .
H2A H 0.0784 0.4814 0.6775 0.051 Uiso 1 1 calc R . .
C3 C 0.1032(2) 0.3577(3) 0.6677(3) 0.0501(10) Uani 1 1 d . . .
H3A H 0.0638 0.3389 0.7055 0.060 Uiso 1 1 calc R . .
C4 C 0.1504(2) 0.3005(3) 0.6299(3) 0.0502(9) Uani 1 1 d . . .
H4A H 0.1435 0.2429 0.6419 0.060 Uiso 1 1 calc R . .
C5 C 0.2081(2) 0.3265(2) 0.5744(3) 0.0440(8) Uani 1 1 d . . .
H5A H 0.2401 0.2869 0.5470 0.053 Uiso 1 1 calc R . .
C6 C 0.21868(17) 0.4110(2) 0.5592(2) 0.0322(6) Uani 1 1 d . . .
C11 C 0.12178(16) 0.6236(2) 0.5048(2) 0.0343(6) Uani 1 1 d . . .
H11A H 0.1076 0.5819 0.4566 0.041 Uiso 1 1 calc R . .
H11B H 0.0786 0.6341 0.5446 0.041 Uiso 1 1 calc R . .
N12 N 0.14002(14) 0.7010(2) 0.45576(18) 0.0353(6) Uani 1 1 d . . .
C13 C 0.19982(17) 0.7498(2) 0.46738(19) 0.0315(6) Uani 1 1 d . . .
N14 N 0.26738(14) 0.71586(17) 0.48547(16) 0.0289(5) Uani 1 1 d . . .
C15 C 0.32435(18) 0.7675(2) 0.5042(2) 0.0320(6) Uani 1 1 d . . .
H15A H 0.3692 0.7429 0.5232 0.038 Uiso 1 1 calc R . .
C16 C 0.3218(2) 0.8515(2) 0.4977(2) 0.0431(8) Uani 1 1 d . . .
H16A H 0.3634 0.8849 0.5104 0.052 Uiso 1 1 calc R . .
C17 C 0.2552(3) 0.8864(3) 0.4715(3) 0.0519(10) Uani 1 1 d . . .
H17A H 0.2514 0.9449 0.4633 0.062 Uiso 1 1 calc R . .
C18 C 0.1950(2) 0.8373(2) 0.4576(2) 0.0430(8) Uani 1 1 d . . .
H18A H 0.1496 0.8622 0.4412 0.052 Uiso 1 1 calc R . .
C19 C 0.0741(2) 0.7383(3) 0.4148(3) 0.0508(10) Uani 1 1 d . . .
H19A H 0.0491 0.7710 0.4633 0.076 Uiso 1 1 calc R . .
H19B H 0.0416 0.6942 0.3917 0.076 Uiso 1 1 calc R . .
H19C H 0.0875 0.7746 0.3620 0.076 Uiso 1 1 calc R . .
C21 C 0.18972(17) 0.6245(2) 0.6986(2) 0.0316(6) Uani 1 1 d . . .
H21A H 0.1385 0.6263 0.7199 0.038 Uiso 1 1 calc R . .
H21B H 0.2169 0.5878 0.7428 0.038 Uiso 1 1 calc R . .
N22 N 0.21995(14) 0.70725(17) 0.70454(19) 0.0320(5) Uani 1 1 d . . .
C23 C 0.17399(16) 0.7749(2) 0.70221(19) 0.0281(5) Uani 1 1 d . . .
N24 N 0.10777(14) 0.76161(19) 0.66472(18) 0.0337(5) Uani 1 1 d . . .
C25 C 0.06083(19) 0.8252(3) 0.6629(2) 0.0411(8) Uani 1 1 d . . .
H25A H 0.0137 0.8158 0.6366 0.049 Uiso 1 1 calc R . .
C26 C 0.0769(2) 0.9035(2) 0.6971(3) 0.0469(9) Uani 1 1 d . . .
H26A H 0.0421 0.9472 0.6939 0.056 Uiso 1 1 calc R . .
C27 C 0.1452(2) 0.9163(2) 0.7361(3) 0.0456(9) Uani 1 1 d . . .
H27A H 0.1577 0.9694 0.7610 0.055 Uiso 1 1 calc R . .
C28 C 0.19513(19) 0.8528(2) 0.7390(2) 0.0361(7) Uani 1 1 d . . .
H28A H 0.2425 0.8610 0.7650 0.043 Uiso 1 1 calc R . .
C29 C 0.29614(18) 0.7148(3) 0.7320(2) 0.0388(7) Uani 1 1 d . . .
H29A H 0.3153 0.7681 0.7095 0.058 Uiso 1 1 calc R . .
H29B H 0.3240 0.6692 0.7039 0.058 Uiso 1 1 calc R . .
H29C H 0.3005 0.7122 0.8012 0.058 Uiso 1 1 calc R . .
C31 C 0.30555(19) 0.4078(2) 0.3792(2) 0.0345(6) Uani 1 1 d . . .
H31A H 0.3524 0.3777 0.3744 0.041 Uiso 1 1 calc R . .
H31B H 0.2659 0.3669 0.3689 0.041 Uiso 1 1 calc R . .
N32 N 0.30190(15) 0.4708(2) 0.30403(18) 0.0367(6) Uani 1 1 d . . .
C33 C 0.35631(17) 0.5304(2) 0.3012(2) 0.0343(7) Uani 1 1 d . . .
N34 N 0.36751(14) 0.57995(16) 0.37938(19) 0.0316(5) Uani 1 1 d . . .
C35 C 0.42310(18) 0.6338(2) 0.3795(3) 0.0393(7) Uani 1 1 d . . .
H35A H 0.4329 0.6642 0.4358 0.047 Uiso 1 1 calc R . .
C36 C 0.4666(2) 0.6475(3) 0.3027(3) 0.0543(11) Uani 1 1 d . . .
H36A H 0.5056 0.6863 0.3056 0.065 Uiso 1 1 calc R . .
C37 C 0.4521(2) 0.6032(3) 0.2210(3) 0.0600(13) Uani 1 1 d . . .
H37A H 0.4792 0.6141 0.1653 0.072 Uiso 1 1 calc R . .
C38 C 0.3989(2) 0.5438(3) 0.2202(3) 0.0497(10) Uani 1 1 d . . .
H38A H 0.3907 0.5115 0.1648 0.060 Uiso 1 1 calc R . .
C39 C 0.2808(3) 0.4325(3) 0.2132(3) 0.0551(11) Uani 1 1 d . . .
H39A H 0.2724 0.4762 0.1659 0.083 Uiso 1 1 calc R . .
H39B H 0.2360 0.4002 0.2214 0.083 Uiso 1 1 calc R . .
H39C H 0.3199 0.3957 0.1917 0.083 Uiso 1 1 calc R . .
C41 C 0.37660(16) 0.41152(19) 0.5653(2) 0.0291(5) Uani 1 1 d . . .
H41A H 0.3759 0.3500 0.5647 0.035 Uiso 1 1 calc R . .
H41B H 0.4219 0.4301 0.5342 0.035 Uiso 1 1 calc R . .
N42 N 0.37649(16) 0.44053(19) 0.66216(18) 0.0341(5) Uani 1 1 d . . .
C43 C 0.41261(17) 0.5123(2) 0.6853(2) 0.0316(6) Uani 1 1 d . . .
N44 N 0.44251(15) 0.55437(18) 0.61340(19) 0.0338(5) Uani 1 1 d . . .
C45 C 0.4842(2) 0.6205(2) 0.6349(3) 0.0419(8) Uani 1 1 d . . .
H45A H 0.5059 0.6502 0.5843 0.050 Uiso 1 1 calc R . .
C46 C 0.4972(2) 0.6477(3) 0.7255(3) 0.0517(10) Uani 1 1 d . . .
H46A H 0.5290 0.6932 0.7374 0.062 Uiso 1 1 calc R . .
C47 C 0.4627(2) 0.6073(3) 0.7987(3) 0.0524(11) Uani 1 1 d . . .
H47A H 0.4689 0.6264 0.8619 0.063 Uiso 1 1 calc R . .
C48 C 0.4195(2) 0.5393(3) 0.7799(2) 0.0414(8) Uani 1 1 d . . .
H48A H 0.3948 0.5112 0.8295 0.050 Uiso 1 1 calc R . .
C49 C 0.3442(2) 0.3889(3) 0.7343(3) 0.0512(10) Uani 1 1 d . . .
H49A H 0.3798 0.3795 0.7854 0.077 Uiso 1 1 calc R . .
H49B H 0.3299 0.3354 0.7066 0.077 Uiso 1 1 calc R . .
H49C H 0.3012 0.4168 0.7599 0.077 Uiso 1 1 calc R . .
Cl1 Cl 0.40786(5) 0.17834(5) 0.50001(5) 0.04146(18) Uani 1 1 d . . .
O11 O 0.39195(18) 0.20518(19) 0.59375(19) 0.0534(7) Uani 1 1 d . . .
O12 O 0.3920(3) 0.0926(2) 0.4912(3) 0.0909(15) Uani 1 1 d . . .
O13 O 0.3672(2) 0.2260(2) 0.4337(2) 0.0765(12) Uani 1 1 d . . .
O14 O 0.4836(2) 0.1921(3) 0.4843(3) 0.0976(16) Uani 1 1 d . . .
Cl2 Cl 0.0741(5) 0.1256(6) 0.8515(6) 0.0352(19) Uani 0.399(4) 1 d PD A 1
O21 O 0.0509(5) 0.1725(5) 0.9323(5) 0.049(2) Uiso 0.399(4) 1 d PD A 1
O22 O 0.1295(4) 0.0677(5) 0.8792(5) 0.0486(17) Uiso 0.399(4) 1 d PD A 1
O23 O 0.0110(5) 0.0825(6) 0.8148(8) 0.075(3) Uiso 0.399(4) 1 d PD A 1
O24 O 0.1013(7) 0.1779(7) 0.7788(7) 0.094(3) Uiso 0.399(4) 1 d PD A 1
Cl2' Cl 0.0723(6) 0.1312(7) 0.8401(8) 0.053(4) Uani 0.325(9) 1 d PD B 2
O21' O 0.0616(8) 0.2026(7) 0.8975(10) 0.077(6) Uiso 0.325(9) 1 d PD B 2
O22' O 0.0694(8) 0.0554(7) 0.8956(9) 0.087(4) Uiso 0.325(9) 1 d PD B 2
O23' O 0.0160(6) 0.1246(8) 0.7699(8) 0.072(4) Uiso 0.325(9) 1 d PD B 2
O24' O 0.1410(5) 0.1367(8) 0.7980(9) 0.080(4) Uiso 0.325(9) 1 d PD B 2
Cl2" Cl 0.0693(5) 0.1305(7) 0.8449(8) 0.034(3) Uani 0.276(9) 1 d PD C 3
O21" O 0.0568(7) 0.1917(8) 0.9166(10) 0.040(3) Uiso 0.276(9) 1 d PD C 3
O22" O 0.0244(7) 0.0600(7) 0.8647(9) 0.064(4) Uiso 0.276(9) 1 d PD C 3
O23" O 0.0528(9) 0.1633(9) 0.7541(8) 0.081(5) Uiso 0.276(9) 1 d PD C 3
O24" O 0.1443(5) 0.1043(9) 0.8483(10) 0.071(4) Uiso 0.276(9) 1 d PD C 3
O50 O 0.1102(4) 0.0106(3) 0.3970(4) 0.086(3) Uani 0.801(14) 1 d PD D 1
C50 C 0.1221(4) 0.0702(4) 0.4443(5) 0.0556(17) Uani 0.801(14) 1 d PD D 1
C51 C 0.1826(5) 0.1286(6) 0.4250(8) 0.095(3) Uani 0.801(14) 1 d PD D 1
H51A H 0.2106 0.1085 0.3707 0.142 Uiso 0.801(14) 1 calc PR D 1
H51B H 0.2146 0.1321 0.4807 0.142 Uiso 0.801(14) 1 calc PR D 1
H51C H 0.1628 0.1838 0.4106 0.142 Uiso 0.801(14) 1 calc PR D 1
C52 C 0.0775(5) 0.0926(5) 0.5282(6) 0.074(2) Uani 0.801(14) 1 d PD D 1
H52A H 0.0363 0.0542 0.5330 0.111 Uiso 0.801(14) 1 calc PR D 1
H52B H 0.0594 0.1496 0.5211 0.111 Uiso 0.801(14) 1 calc PR D 1
H52C H 0.1076 0.0887 0.5857 0.111 Uiso 0.801(14) 1 calc PR D 1
O50' O 0.1594(14) 0.0223(12) 0.3654(15) 0.073(7) Uiso 0.199(14) 1 d PD D 2
C50' C 0.1513(14) 0.0794(13) 0.4179(16) 0.059(7) Uiso 0.199(14) 1 d PD D 2
C51' C 0.1822(18) 0.1628(14) 0.399(2) 0.067(8) Uiso 0.199(14) 1 d PD D 2
H51D H 0.1681 0.1808 0.3353 0.100 Uiso 0.199(14) 1 calc PR D 2
H51E H 0.2354 0.1603 0.4042 0.100 Uiso 0.199(14) 1 calc PR D 2
H51F H 0.1635 0.2025 0.4457 0.100 Uiso 0.199(14) 1 calc PR D 2
C52' C 0.111(3) 0.072(2) 0.508(2) 0.114(17) Uiso 0.199(14) 1 d PD D 2
H52D H 0.0947 0.0144 0.5164 0.171 Uiso 0.199(14) 1 calc PR D 2
H52E H 0.0680 0.1087 0.5057 0.171 Uiso 0.199(14) 1 calc PR D 2
H52F H 0.1424 0.0883 0.5608 0.171 Uiso 0.199(14) 1 calc PR D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N14 Pt N34 98.95(10) . . ?
N14 Pt P1 85.58(7) . . ?
N34 Pt P1 167.91(8) . . ?
N14 Pt P2 173.66(7) . . ?
N34 Pt P2 86.84(7) . . ?
P1 Pt P2 88.24(3) . . ?
C1 P1 C11 107.97(16) . . ?
C1 P1 C21 104.67(15) . . ?
C11 P1 C21 110.25(15) . . ?
C1 P1 Pt 108.51(10) . . ?
C11 P1 Pt 102.18(11) . . ?
C21 P1 Pt 122.65(11) . . ?
C6 P2 C31 111.83(15) . . ?
C6 P2 C41 105.50(15) . . ?
C31 P2 C41 105.99(14) . . ?
C6 P2 Pt 108.64(11) . . ?
C31 P2 Pt 108.94(12) . . ?
C41 P2 Pt 115.95(10) . . ?
C2 C1 C6 119.2(3) . . ?
C2 C1 P1 123.5(3) . . ?
C6 C1 P1 117.1(2) . . ?
C3 C2 C1 119.2(3) . . ?
C4 C3 C2 121.2(3) . . ?
C3 C4 C5 120.3(4) . . ?
C6 C5 C4 119.3(4) . . ?
C5 C6 C1 120.7(3) . . ?
C5 C6 P2 122.2(3) . . ?
C1 C6 P2 116.9(2) . . ?
N12 C11 P1 116.7(2) . . ?
C13 N12 C11 128.4(3) . . ?
C13 N12 C19 118.4(3) . . ?
C11 N12 C19 110.1(3) . . ?
N12 C13 N14 121.3(3) . . ?
N12 C13 C18 120.8(3) . . ?
N14 C13 C18 117.9(3) . . ?
C15 N14 C13 119.0(3) . . ?
C15 N14 Pt 117.3(2) . . ?
C13 N14 Pt 123.7(2) . . ?
C16 C15 N14 124.7(3) . . ?
C15 C16 C17 116.7(4) . . ?
C18 C17 C16 120.7(4) . . ?
C17 C18 C13 120.5(3) . . ?
N22 C21 P1 114.2(2) . . ?
C23 N22 C21 119.5(3) . . ?
C23 N22 C29 121.9(3) . . ?
C21 N22 C29 117.4(3) . . ?
N24 C23 N22 115.9(3) . . ?
N24 C23 C28 122.3(3) . . ?
N22 C23 C28 121.8(3) . . ?
C25 N24 C23 117.9(3) . . ?
N24 C25 C26 123.7(4) . . ?
C25 C26 C27 117.8(4) . . ?
C28 C27 C26 120.3(3) . . ?
C27 C28 C23 117.9(3) . . ?
N32 C31 P2 113.6(2) . . ?
C33 N32 C31 118.0(3) . . ?
C33 N32 C39 116.7(3) . . ?
C31 N32 C39 110.6(3) . . ?
N34 C33 N32 118.8(3) . . ?
N34 C33 C38 118.9(4) . . ?
N32 C33 C38 122.3(3) . . ?
C35 N34 C33 119.0(3) . . ?
C35 N34 Pt 119.6(2) . . ?
C33 N34 Pt 120.6(2) . . ?
N34 C35 C36 123.5(4) . . ?
C35 C36 C37 118.0(4) . . ?
C38 C37 C36 120.0(4) . . ?
C37 C38 C33 120.1(4) . . ?
N42 C41 P2 111.6(2) . . ?
C43 N42 C49 121.1(3) . . ?
C43 N42 C41 119.6(3) . . ?
C49 N42 C41 119.1(3) . . ?
N44 C43 N42 116.4(3) . . ?
N44 C43 C48 121.9(3) . . ?
N42 C43 C48 121.7(3) . . ?
C43 N44 C45 117.6(3) . . ?
N44 C45 C46 124.0(4) . . ?
C45 C46 C47 118.2(4) . . ?
C48 C47 C46 119.8(4) . . ?
C47 C48 C43 118.3(4) . . ?
O12 Cl1 O13 111.2(2) . . ?
O12 Cl1 O11 109.5(2) . . ?
O13 Cl1 O11 109.8(2) . . ?
O12 Cl1 O14 109.8(3) . . ?
O13 Cl1 O14 108.8(3) . . ?
O11 Cl1 O14 107.7(3) . . ?
O24 Cl2 O22 109.2(8) . . ?
O24 Cl2 O21 111.8(8) . . ?
O22 Cl2 O21 109.8(7) . . ?
O24 Cl2 O23 108.1(8) . . ?
O22 Cl2 O23 110.7(8) . . ?
O21 Cl2 O23 107.2(7) . . ?
O24' Cl2' O21' 108.7(9) . . ?
O24' Cl2' O23' 111.0(9) . . ?
O21' Cl2' O23' 110.7(9) . . ?
O24' Cl2' O22' 108.6(9) . . ?
O21' Cl2' O22' 111.4(9) . . ?
O23' Cl2' O22' 106.3(8) . . ?
O23" Cl2" O22" 110.6(9) . . ?
O23" Cl2" O21" 110.5(9) . . ?
O22" Cl2" O21" 108.1(9) . . ?
O23" Cl2" O24" 109.6(9) . . ?
O22" Cl2" O24" 108.2(9) . . ?
O21" Cl2" O24" 109.7(9) . . ?
O50 C50 C51 122.8(7) . . ?
O50 C50 C52 122.9(7) . . ?
C51 C50 C52 114.3(6) . . ?
O50' C50' C51' 122.5(14) . . ?
O50' C50' C52' 122.6(14) . . ?
C51' C50' C52' 114.9(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt N14 2.119(3) . ?
Pt N34 2.131(2) . ?
Pt P1 2.1879(7) . ?
Pt P2 2.1880(8) . ?
P1 C1 1.809(3) . ?
P1 C11 1.814(3) . ?
P1 C21 1.841(3) . ?
P2 C6 1.807(3) . ?
P2 C31 1.828(3) . ?
P2 C41 1.835(3) . ?
C1 C2 1.398(4) . ?
C1 C6 1.406(4) . ?
C2 C3 1.393(6) . ?
C3 C4 1.374(6) . ?
C4 C5 1.388(5) . ?
C5 C6 1.388(5) . ?
C11 N12 1.464(5) . ?
N12 C13 1.358(5) . ?
N12 C19 1.466(4) . ?
C13 N14 1.377(4) . ?
C13 C18 1.417(5) . ?
N14 C15 1.360(4) . ?
C15 C16 1.354(5) . ?
C16 C17 1.393(6) . ?
C17 C18 1.371(7) . ?
C21 N22 1.444(4) . ?
N22 C23 1.377(4) . ?
N22 C29 1.453(4) . ?
C23 N24 1.339(4) . ?
C23 C28 1.409(4) . ?
N24 C25 1.337(5) . ?
C25 C26 1.380(6) . ?
C26 C27 1.381(6) . ?
C27 C28 1.374(5) . ?
C31 N32 1.469(5) . ?
N32 C33 1.384(5) . ?
N32 C39 1.472(4) . ?
C33 N34 1.375(4) . ?
C33 C38 1.408(4) . ?
N34 C35 1.338(4) . ?
C35 C36 1.368(5) . ?
C36 C37 1.380(7) . ?
C37 C38 1.367(7) . ?
C41 N42 1.445(4) . ?
N42 C43 1.369(4) . ?
N42 C49 1.444(5) . ?
C43 N44 1.341(4) . ?
C43 C48 1.410(4) . ?
N44 C45 1.343(5) . ?
C45 C46 1.370(6) . ?
C46 C47 1.379(7) . ?
C47 C48 1.376(6) . ?
Cl1 O12 1.414(4) . ?
Cl1 O13 1.417(3) . ?
Cl1 O11 1.425(3) . ?
Cl1 O14 1.426(4) . ?
Cl2 O24 1.421(10) . ?
Cl2 O22 1.430(10) . ?
Cl2 O21 1.434(9) . ?
Cl2 O23 1.442(10) . ?
Cl2' O24' 1.402(11) . ?
Cl2' O21' 1.419(10) . ?
Cl2' O23' 1.431(11) . ?
Cl2' O22' 1.450(11) . ?
Cl2" O23" 1.417(12) . ?
Cl2" O22" 1.430(11) . ?
Cl2" O21" 1.431(10) . ?
Cl2" O24" 1.440(10) . ?
O50 C50 1.188(7) . ?
C50 C51 1.480(9) . ?
C50 C52 1.489(9) . ?
O50' C50' 1.190(16) . ?
C50' C51' 1.481(15) . ?
C50' C52' 1.482(15) . ?
