#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:26:03 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179721 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/23/7002306.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7002306
loop_
_publ_author_name
'Chai, Zuo-Yun'
'Wang, Zhong-Xia'
_publ_section_title
;
 Synthesis and characterization of Sn(II), Pb(II) and Yb(II) complexes
 supported by [C(Ph2PNSiMe3){6-(2-RC5H3N)}]2− or
 [CH(Ph2PNSiMe3){6-(2-RC5H3N)}]− (R =
 3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands
;
_journal_issue                   38
_journal_name_full               'Dalton Transactions'
_journal_page_first              8005
_journal_page_last               8012
_journal_paper_doi               10.1039/b906266a
_journal_year                    2009
_chemical_formula_sum            'C42 H60 N4 P2 Si4 Yb'
_chemical_formula_weight         968.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.018(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.9293(17)
_cell_length_b                   13.9411(15)
_cell_length_c                   23.677(2)
_cell_measurement_reflns_used    3235
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.214
_cell_measurement_theta_min      2.304
_cell_volume                     4759.6(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1532
_diffrn_reflns_av_sigmaI/netI    0.1744
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            24375
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.46
_exptl_absorpt_coefficient_mu    2.165
_exptl_absorpt_correction_T_max  0.8290
_exptl_absorpt_correction_T_min  0.6714
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.351
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1984
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.09
_refine_diff_density_max         3.544
_refine_diff_density_min         -1.386
_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.995
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     478
_refine_ls_number_reflns         8345
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.995
_refine_ls_R_factor_all          0.1679
_refine_ls_R_factor_gt           0.0681
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0481P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1337
_refine_ls_wR_factor_ref         0.1604
_reflns_number_gt                3701
_reflns_number_total             8345
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b906266a.txt
_cod_data_source_block           12
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        4759.6(9)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7002306
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Yb1 Yb -0.00641(3) 0.75229(5) 0.777000(19) 0.04598(17) Uani 1 1 d . . .
N1 N 0.1145(6) 0.6604(7) 0.7579(4) 0.046(2) Uani 1 1 d . . .
N2 N -0.0017(7) 0.5979(7) 0.8337(4) 0.054(3) Uani 1 1 d . . .
N3 N -0.0609(6) 0.7572(7) 0.6703(3) 0.051(2) Uani 1 1 d . . .
N4 N 0.0408(7) 0.8836(7) 0.8390(4) 0.058(3) Uani 1 1 d . . .
P1 P 0.0650(2) 0.5237(2) 0.81826(13) 0.0477(8) Uani 1 1 d . . .
P2 P 0.0220(2) 0.7887(2) 0.64664(12) 0.0444(8) Uani 1 1 d . . .
Si1 Si -0.0618(3) 0.6024(3) 0.88641(15) 0.0560(10) Uani 1 1 d . . .
Si2 Si -0.1594(2) 0.6921(3) 0.64181(14) 0.0533(9) Uani 1 1 d . . .
Si3 Si -0.0391(3) 0.9697(3) 0.83094(16) 0.0652(11) Uani 1 1 d . . .
Si4 Si 0.1498(3) 0.8902(3) 0.88070(14) 0.0584(10) Uani 1 1 d . . .
C1 C 0.1514(8) 0.5839(8) 0.7923(5) 0.049(3) Uani 1 1 d . . .
C2 C 0.2432(9) 0.5628(9) 0.8043(5) 0.053(3) Uani 1 1 d . . .
H2 H 0.2667 0.5092 0.8266 0.064 Uiso 1 1 calc R . .
C3 C 0.3011(9) 0.6213(9) 0.7833(5) 0.054(3) Uani 1 1 d . . .
H3 H 0.3644 0.6087 0.7924 0.065 Uiso 1 1 calc R . .
C4 C 0.2664(8) 0.6963(9) 0.7497(5) 0.052(3) Uani 1 1 d . . .
H4 H 0.3063 0.7370 0.7367 0.062 Uiso 1 1 calc R . .
C5 C 0.1707(9) 0.7150(8) 0.7336(5) 0.047(3) Uani 1 1 d . . .
C6 C 0.1306(8) 0.7917(9) 0.6965(4) 0.050(3) Uani 1 1 d . . .
H6 H 0.1649 0.8479 0.6989 0.060 Uiso 1 1 calc R . .
C7 C 0.0093(10) 0.4427(9) 0.7593(5) 0.057(3) Uani 1 1 d . . .
C8 C 0.0620(10) 0.4034(9) 0.7251(5) 0.061(3) Uani 1 1 d . . .
H8 H 0.1242 0.4196 0.7313 0.073 Uiso 1 1 calc R . .
C9 C 0.0203(11) 0.3384(10) 0.6809(6) 0.068(4) Uani 1 1 d . . .
H9 H 0.0539 0.3124 0.6566 0.081 Uiso 1 1 calc R . .
C10 C -0.0658(11) 0.3151(10) 0.6745(6) 0.070(4) Uani 1 1 d . . .
H10 H -0.0928 0.2720 0.6450 0.084 Uiso 1 1 calc R . .
C11 C -0.1172(10) 0.3491(10) 0.7075(6) 0.072(4) Uani 1 1 d . . .
H11 H -0.1780 0.3281 0.7022 0.086 Uiso 1 1 calc R . .
C12 C -0.0795(10) 0.4176(10) 0.7511(5) 0.064(4) Uani 1 1 d . . .
H12 H -0.1156 0.4446 0.7736 0.077 Uiso 1 1 calc R . .
C13 C 0.1266(9) 0.4475(10) 0.8776(5) 0.058(3) Uani 1 1 d . . .
C14 C 0.1834(9) 0.4905(10) 0.9250(5) 0.064(4) Uani 1 1 d . . .
H14 H 0.1889 0.5569 0.9258 0.076 Uiso 1 1 calc R . .
C15 C 0.2332(9) 0.4376(11) 0.9723(6) 0.069(4) Uani 1 1 d . . .
H15 H 0.2698 0.4676 1.0054 0.083 Uiso 1 1 calc R . .
C16 C 0.2268(10) 0.3400(11) 0.9689(6) 0.073(4) Uani 1 1 d . . .
H16 H 0.2626 0.3033 0.9992 0.088 Uiso 1 1 calc R . .
C17 C 0.1706(10) 0.2956(11) 0.9233(6) 0.077(4) Uani 1 1 d . . .
H17 H 0.1652 0.2291 0.9236 0.092 Uiso 1 1 calc R . .
C18 C 0.1199(9) 0.3477(10) 0.8753(6) 0.068(4) Uani 1 1 d . . .
H18 H 0.0828 0.3168 0.8427 0.082 Uiso 1 1 calc R . .
C19 C -0.1167(11) 0.4891(11) 0.8961(6) 0.095(5) Uani 1 1 d . . .
H19A H -0.0714 0.4386 0.9021 0.143 Uiso 1 1 calc R . .
H19B H -0.1656 0.4755 0.8618 0.143 Uiso 1 1 calc R . .
H19C H -0.1418 0.4934 0.9294 0.143 Uiso 1 1 calc R . .
C20 C 0.0075(11) 0.6420(12) 0.9572(6) 0.094(5) Uani 1 1 d . . .
H20A H 0.0408 0.5884 0.9780 0.141 Uiso 1 1 calc R . .
H20B H -0.0323 0.6686 0.9791 0.141 Uiso 1 1 calc R . .
H20C H 0.0507 0.6900 0.9519 0.141 Uiso 1 1 calc R . .
C21 C -0.1534(10) 0.6941(12) 0.8661(6) 0.098(5) Uani 1 1 d . . .
H21A H -0.1263 0.7541 0.8594 0.147 Uiso 1 1 calc R . .
H21B H -0.1833 0.7013 0.8972 0.147 Uiso 1 1 calc R . .
H21C H -0.1982 0.6746 0.8311 0.147 Uiso 1 1 calc R . .
C22 C 0.0301(9) 0.7229(8) 0.5823(5) 0.053(3) Uani 1 1 d . . .
C23 C -0.0338(8) 0.7349(9) 0.5302(5) 0.057(3) Uani 1 1 d . . .
H23 H -0.0793 0.7814 0.5273 0.068 Uiso 1 1 calc R . .
C24 C -0.0337(9) 0.6802(10) 0.4808(5) 0.061(3) Uani 1 1 d . . .
H24 H -0.0803 0.6873 0.4463 0.074 Uiso 1 1 calc R . .
C25 C 0.0345(10) 0.6179(9) 0.4844(6) 0.062(4) Uani 1 1 d . . .
H25 H 0.0382 0.5829 0.4516 0.075 Uiso 1 1 calc R . .
C26 C 0.0956(10) 0.6057(10) 0.5333(6) 0.071(4) Uani 1 1 d . . .
H26 H 0.1414 0.5598 0.5350 0.086 Uiso 1 1 calc R . .
C27 C 0.0975(9) 0.6582(9) 0.5850(5) 0.059(3) Uani 1 1 d . . .
H27 H 0.1437 0.6481 0.6193 0.071 Uiso 1 1 calc R . .
C28 C 0.0069(9) 0.9101(9) 0.6204(5) 0.050(3) Uani 1 1 d . . .
C29 C 0.0625(9) 0.9524(9) 0.5904(5) 0.054(3) Uani 1 1 d . . .
H29 H 0.1110 0.9175 0.5826 0.065 Uiso 1 1 calc R . .
C30 C 0.0484(9) 1.0463(10) 0.5713(5) 0.061(3) Uani 1 1 d . . .
H30 H 0.0867 1.0746 0.5507 0.073 Uiso 1 1 calc R . .
C31 C -0.0219(10) 1.0959(10) 0.5831(5) 0.061(4) Uani 1 1 d . . .
H31 H -0.0296 1.1599 0.5719 0.073 Uiso 1 1 calc R . .
C32 C -0.0802(10) 1.0579(9) 0.6099(5) 0.062(4) Uani 1 1 d . . .
H32 H -0.1301 1.0930 0.6156 0.074 Uiso 1 1 calc R . .
C33 C -0.0653(9) 0.9633(9) 0.6296(5) 0.056(3) Uani 1 1 d . . .
H33 H -0.1051 0.9358 0.6494 0.068 Uiso 1 1 calc R . .
C34 C -0.2453(9) 0.7627(10) 0.5869(6) 0.080(4) Uani 1 1 d . . .
H34A H -0.2757 0.8074 0.6066 0.120 Uiso 1 1 calc R . .
H34B H -0.2905 0.7202 0.5634 0.120 Uiso 1 1 calc R . .
H34C H -0.2142 0.7970 0.5624 0.120 Uiso 1 1 calc R . .
C35 C -0.1394(9) 0.5757(9) 0.6102(5) 0.069(4) Uani 1 1 d . . .
H35A H -0.1284 0.5858 0.5724 0.103 Uiso 1 1 calc R . .
H35B H -0.1929 0.5356 0.6062 0.103 Uiso 1 1 calc R . .
H35C H -0.0864 0.5450 0.6355 0.103 Uiso 1 1 calc R . .
C36 C -0.2118(10) 0.6716(11) 0.7039(5) 0.080(4) Uani 1 1 d . . .
H36A H -0.1750 0.6261 0.7304 0.120 Uiso 1 1 calc R . .
H36B H -0.2736 0.6470 0.6893 0.120 Uiso 1 1 calc R . .
H36C H -0.2140 0.7310 0.7239 0.120 Uiso 1 1 calc R . .
C37 C -0.1446(9) 0.9332(11) 0.7736(5) 0.079(4) Uani 1 1 d . . .
H37A H -0.1341 0.9424 0.7356 0.118 Uiso 1 1 calc R . .
H37B H -0.1963 0.9717 0.7769 0.118 Uiso 1 1 calc R . .
H37C H -0.1577 0.8668 0.7786 0.118 Uiso 1 1 calc R . .
C38 C -0.0814(10) 0.9920(11) 0.8964(6) 0.095(5) Uani 1 1 d . . .
H38A H -0.0743 0.9348 0.9198 0.142 Uiso 1 1 calc R . .
H38B H -0.1457 1.0096 0.8847 0.142 Uiso 1 1 calc R . .
H38C H -0.0462 1.0431 0.9189 0.142 Uiso 1 1 calc R . .
C39 C -0.0021(11) 1.0863(11) 0.8077(7) 0.101(5) Uani 1 1 d . . .
H39A H 0.0353 1.1195 0.8411 0.151 Uiso 1 1 calc R . .
H39B H -0.0558 1.1242 0.7901 0.151 Uiso 1 1 calc R . .
H39C H 0.0335 1.0759 0.7798 0.151 Uiso 1 1 calc R . .
C40 C 0.2302(9) 0.9489(10) 0.8443(5) 0.080(4) Uani 1 1 d . . .
H40A H 0.2215 0.9227 0.8057 0.120 Uiso 1 1 calc R . .
H40B H 0.2929 0.9379 0.8665 0.120 Uiso 1 1 calc R . .
H40C H 0.2181 1.0165 0.8416 0.120 Uiso 1 1 calc R . .
C41 C 0.1997(9) 0.7682(9) 0.9007(6) 0.075(4) Uani 1 1 d . . .
H41A H 0.1585 0.7316 0.9174 0.112 Uiso 1 1 calc R . .
H41B H 0.2588 0.7740 0.9287 0.112 Uiso 1 1 calc R . .
H41C H 0.2074 0.7364 0.8663 0.112 Uiso 1 1 calc R . .
C42 C 0.1651(9) 0.9535(10) 0.9522(5) 0.081(4) Uani 1 1 d . . .
H42A H 0.1441 1.0186 0.9453 0.122 Uiso 1 1 calc R . .
H42B H 0.2295 0.9530 0.9731 0.122 Uiso 1 1 calc R . .
H42C H 0.1295 0.9214 0.9750 0.122 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Yb1 N1 115.2(3) . . ?
N4 Yb1 N3 126.3(4) . . ?
N1 Yb1 N3 83.3(3) . . ?
N4 Yb1 N2 111.8(3) . . ?
N1 Yb1 N2 73.8(3) . . ?
N3 Yb1 N2 121.9(3) . . ?
N4 Yb1 C5 101.2(3) . . ?
N1 Yb1 C5 24.0(3) . . ?
N3 Yb1 C5 75.4(3) . . ?
N2 Yb1 C5 97.1(3) . . ?
N4 Yb1 C6 96.0(3) . . ?
N1 Yb1 C6 48.3(3) . . ?
N3 Yb1 C6 58.0(3) . . ?
N2 Yb1 C6 122.1(3) . . ?
C5 Yb1 C6 25.9(3) . . ?
N4 Yb1 P2 112.4(2) . . ?
N1 Yb1 P2 66.9(2) . . ?
N3 Yb1 P2 26.9(2) . . ?
N2 Yb1 P2 130.0(2) . . ?
C5 Yb1 P2 52.0(2) . . ?
C6 Yb1 P2 31.3(2) . . ?
C5 N1 C1 119.3(10) . . ?
C5 N1 Yb1 111.3(7) . . ?
C1 N1 Yb1 121.3(7) . . ?
P1 N2 Si1 133.4(6) . . ?
P1 N2 Yb1 112.1(5) . . ?
Si1 N2 Yb1 114.0(5) . . ?
P2 N3 Si2 133.9(5) . . ?
P2 N3 Yb1 107.4(4) . . ?
Si2 N3 Yb1 114.5(4) . . ?
Si3 N4 Si4 125.8(6) . . ?
Si3 N4 Yb1 113.7(5) . . ?
Si4 N4 Yb1 120.1(5) . . ?
N2 P1 C1 109.6(5) . . ?
N2 P1 C13 116.0(5) . . ?
C1 P1 C13 106.1(6) . . ?
N2 P1 C7 113.7(6) . . ?
C1 P1 C7 104.8(6) . . ?
C13 P1 C7 105.7(6) . . ?
N3 P2 C6 116.9(5) . . ?
N3 P2 C28 110.6(6) . . ?
C6 P2 C28 102.9(6) . . ?
N3 P2 C22 113.3(5) . . ?
C6 P2 C22 109.2(5) . . ?
C28 P2 C22 102.5(5) . . ?
N3 P2 Yb1 45.7(3) . . ?
C6 P2 Yb1 71.9(4) . . ?
C28 P2 Yb1 116.0(4) . . ?
C22 P2 Yb1 140.5(4) . . ?
N2 Si1 C20 113.7(6) . . ?
N2 Si1 C19 113.3(6) . . ?
C20 Si1 C19 108.4(7) . . ?
N2 Si1 C21 109.2(6) . . ?
C20 Si1 C21 103.7(7) . . ?
C19 Si1 C21 107.9(8) . . ?
N3 Si2 C35 114.5(5) . . ?
N3 Si2 C34 111.3(6) . . ?
C35 Si2 C34 109.8(6) . . ?
N3 Si2 C36 105.4(5) . . ?
C35 Si2 C36 109.3(6) . . ?
C34 Si2 C36 106.2(6) . . ?
N4 Si3 C38 114.5(6) . . ?
N4 Si3 C39 114.1(6) . . ?
C38 Si3 C39 107.2(7) . . ?
N4 Si3 C37 109.3(6) . . ?
C38 Si3 C37 104.4(6) . . ?
C39 Si3 C37 106.5(7) . . ?
N4 Si4 C40 113.6(6) . . ?
N4 Si4 C41 111.3(6) . . ?
C40 Si4 C41 105.0(6) . . ?
N4 Si4 C42 115.6(6) . . ?
C40 Si4 C42 105.8(6) . . ?
C41 Si4 C42 104.7(6) . . ?
C2 C1 N1 121.4(11) . . ?
C2 C1 P1 127.5(10) . . ?
N1 C1 P1 111.0(9) . . ?
C1 C2 C3 119.5(12) . . ?
C1 C2 H2 120.3 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 119.9(12) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C3 C4 C5 121.1(12) . . ?
C3 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
N1 C5 C4 118.4(11) . . ?
N1 C5 C6 118.4(11) . . ?
C4 C5 C6 123.0(11) . . ?
N1 C5 Yb1 44.6(5) . . ?
C4 C5 Yb1 146.3(8) . . ?
C6 C5 Yb1 79.7(7) . . ?
C5 C6 P2 124.9(10) . . ?
C5 C6 Yb1 74.4(6) . . ?
P2 C6 Yb1 76.8(4) . . ?
C5 C6 H6 117.5 . . ?
P2 C6 H6 117.5 . . ?
Yb1 C6 H6 122.5 . . ?
C12 C7 C8 120.3(13) . . ?
C12 C7 P1 120.8(10) . . ?
C8 C7 P1 118.7(10) . . ?
C7 C8 C9 119.0(13) . . ?
C7 C8 H8 120.5 . . ?
C9 C8 H8 120.5 . . ?
C10 C9 C8 119.0(13) . . ?
C10 C9 H9 120.5 . . ?
C8 C9 H9 120.5 . . ?
C9 C10 C11 123.6(15) . . ?
C9 C10 H10 118.2 . . ?
C11 C10 H10 118.2 . . ?
C10 C11 C12 119.6(14) . . ?
C10 C11 H11 120.2 . . ?
C12 C11 H11 120.2 . . ?
C7 C12 C11 118.5(13) . . ?
C7 C12 H12 120.8 . . ?
C11 C12 H12 120.8 . . ?
C14 C13 C18 119.7(12) . . ?
C14 C13 P1 117.8(11) . . ?
C18 C13 P1 122.5(10) . . ?
C13 C14 C15 121.5(14) . . ?
C13 C14 H14 119.2 . . ?
C15 C14 H14 119.2 . . ?
C16 C15 C14 117.9(14) . . ?
C16 C15 H15 121.1 . . ?
C14 C15 H15 121.1 . . ?
C17 C16 C15 122.0(14) . . ?
C17 C16 H16 119.0 . . ?
C15 C16 H16 119.0 . . ?
C16 C17 C18 120.8(15) . . ?
C16 C17 H17 119.6 . . ?
C18 C17 H17 119.6 . . ?
C13 C18 C17 118.0(14) . . ?
C13 C18 H18 121.0 . . ?
C17 C18 H18 121.0 . . ?
Si1 C19 H19A 109.5 . . ?
Si1 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si1 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si1 C20 H20A 109.5 . . ?
Si1 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si1 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si1 C21 H21A 109.5 . . ?
Si1 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si1 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C27 C22 C23 117.8(11) . . ?
C27 C22 P2 121.0(10) . . ?
C23 C22 P2 121.2(9) . . ?
C22 C23 C24 122.7(12) . . ?
C22 C23 H23 118.6 . . ?
C24 C23 H23 118.6 . . ?
C25 C24 C23 118.2(13) . . ?
C25 C24 H24 120.9 . . ?
C23 C24 H24 120.9 . . ?
C26 C25 C24 119.8(13) . . ?
C26 C25 H25 120.1 . . ?
C24 C25 H25 120.1 . . ?
C25 C26 C27 124.0(14) . . ?
C25 C26 H26 118.0 . . ?
C27 C26 H26 118.0 . . ?
C22 C27 C26 117.3(12) . . ?
C22 C27 H27 121.3 . . ?
C26 C27 H27 121.3 . . ?
C29 C28 C33 117.4(12) . . ?
C29 C28 P2 123.4(10) . . ?
C33 C28 P2 119.2(9) . . ?
C28 C29 C30 121.4(12) . . ?
C28 C29 H29 119.3 . . ?
C30 C29 H29 119.3 . . ?
C31 C30 C29 118.5(12) . . ?
C31 C30 H30 120.7 . . ?
C29 C30 H30 120.7 . . ?
C32 C31 C30 122.9(13) . . ?
C32 C31 H31 118.5 . . ?
C30 C31 H31 118.5 . . ?
C31 C32 C33 118.3(13) . . ?
C31 C32 H32 120.9 . . ?
C33 C32 H32 120.9 . . ?
C28 C33 C32 121.4(12) . . ?
C28 C33 H33 119.3 . . ?
C32 C33 H33 119.3 . . ?
Si2 C34 H34A 109.5 . . ?
Si2 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
Si2 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Si2 C35 H35A 109.5 . . ?
Si2 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
Si2 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
Si2 C36 H36A 109.5 . . ?
Si2 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
Si2 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Si3 C37 H37A 109.5 . . ?
Si3 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
Si3 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
Si3 C38 H38A 109.5 . . ?
Si3 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
Si3 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
Si3 C39 H39A 109.5 . . ?
Si3 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
Si3 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
Si4 C40 H40A 109.5 . . ?
Si4 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
Si4 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
Si4 C41 H41A 109.5 . . ?
Si4 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
Si4 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si4 C42 H42A 109.5 . . ?
Si4 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
Si4 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Yb1 N4 2.338(10) . ?
Yb1 N1 2.352(9) . ?
Yb1 N3 2.446(8) . ?
Yb1 N2 2.529(9) . ?
Yb1 C5 3.119(12) . ?
Yb1 C6 3.185(11) . ?
Yb1 P2 3.263(3) . ?
N1 C5 1.364(13) . ?
N1 C1 1.368(13) . ?
N2 P1 1.544(10) . ?
N2 Si1 1.717(9) . ?
N3 P2 1.549(9) . ?
N3 Si2 1.711(10) . ?
N4 Si3 1.668(11) . ?
N4 Si4 1.674(11) . ?
P1 C1 1.777(12) . ?
P1 C13 1.810(12) . ?
P1 C7 1.819(13) . ?
P2 C6 1.741(12) . ?
P2 C28 1.797(12) . ?
P2 C22 1.808(11) . ?
Si1 C20 1.812(14) . ?
Si1 C19 1.821(15) . ?
Si1 C21 1.841(15) . ?
Si2 C35 1.844(12) . ?
Si2 C34 1.854(13) . ?
Si2 C36 1.857(12) . ?
Si3 C38 1.846(13) . ?
Si3 C39 1.847(16) . ?
Si3 C37 1.864(14) . ?
Si4 C40 1.841(13) . ?
Si4 C41 1.867(13) . ?
Si4 C42 1.870(12) . ?
C1 C2 1.359(15) . ?
C2 C3 1.371(15) . ?
C2 H2 0.9300 . ?
C3 C4 1.335(15) . ?
C3 H3 0.9300 . ?
C4 C5 1.404(15) . ?
C4 H4 0.9300 . ?
C5 C6 1.415(15) . ?
C6 H6 0.9300 . ?
C7 C12 1.336(16) . ?
C7 C8 1.380(15) . ?
C8 C9 1.402(17) . ?
C8 H8 0.9300 . ?
C9 C10 1.296(17) . ?
C9 H9 0.9300 . ?
C10 C11 1.318(16) . ?
C10 H10 0.9300 . ?
C11 C12 1.412(17) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.358(17) . ?
C13 C18 1.395(17) . ?
C14 C15 1.385(16) . ?
C14 H14 0.9300 . ?
C15 C16 1.365(18) . ?
C15 H15 0.9300 . ?
C16 C17 1.334(18) . ?
C16 H16 0.9300 . ?
C17 C18 1.395(16) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C27 1.341(15) . ?
C22 C23 1.361(15) . ?
C23 C24 1.396(15) . ?
C23 H23 0.9300 . ?
C24 C25 1.324(16) . ?
C24 H24 0.9300 . ?
C25 C26 1.288(17) . ?
C25 H25 0.9300 . ?
C26 C27 1.419(16) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C28 C29 1.358(15) . ?
C28 C33 1.371(15) . ?
C29 C30 1.384(16) . ?
C29 H29 0.9300 . ?
C30 C31 1.346(16) . ?
C30 H30 0.9300 . ?
C31 C32 1.314(15) . ?
C31 H31 0.9300 . ?
C32 C33 1.398(16) . ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 Yb1 N1 C5 -58.1(8) . . . . ?
N3 Yb1 N1 C5 69.0(7) . . . . ?
N2 Yb1 N1 C5 -165.0(8) . . . . ?
C6 Yb1 N1 C5 16.6(6) . . . . ?
P2 Yb1 N1 C5 46.8(7) . . . . ?
N4 Yb1 N1 C1 90.4(9) . . . . ?
N3 Yb1 N1 C1 -142.5(9) . . . . ?
N2 Yb1 N1 C1 -16.5(9) . . . . ?
C5 Yb1 N1 C1 148.5(13) . . . . ?
C6 Yb1 N1 C1 165.1(11) . . . . ?
P2 Yb1 N1 C1 -164.7(9) . . . . ?
N4 Yb1 N2 P1 -119.7(5) . . . . ?
N1 Yb1 N2 P1 -8.5(5) . . . . ?
N3 Yb1 N2 P1 62.6(6) . . . . ?
C5 Yb1 N2 P1 -14.6(6) . . . . ?
C6 Yb1 N2 P1 -7.1(7) . . . . ?
P2 Yb1 N2 P1 30.7(7) . . . . ?
N4 Yb1 N2 Si1 53.3(6) . . . . ?
N1 Yb1 N2 Si1 164.5(6) . . . . ?
N3 Yb1 N2 Si1 -124.4(5) . . . . ?
C5 Yb1 N2 Si1 158.4(5) . . . . ?
C6 Yb1 N2 Si1 165.9(4) . . . . ?
P2 Yb1 N2 Si1 -156.4(3) . . . . ?
N4 Yb1 N3 P2 66.2(6) . . . . ?
N1 Yb1 N3 P2 -50.2(5) . . . . ?
N2 Yb1 N3 P2 -116.4(5) . . . . ?
C5 Yb1 N3 P2 -27.1(5) . . . . ?
C6 Yb1 N3 P2 -6.0(4) . . . . ?
N4 Yb1 N3 Si2 -133.7(5) . . . . ?
N1 Yb1 N3 Si2 109.9(5) . . . . ?
N2 Yb1 N3 Si2 43.7(6) . . . . ?
C5 Yb1 N3 Si2 133.0(6) . . . . ?
C6 Yb1 N3 Si2 154.1(7) . . . . ?
P2 Yb1 N3 Si2 160.1(9) . . . . ?
N1 Yb1 N4 Si3 156.7(4) . . . . ?
N3 Yb1 N4 Si3 56.0(6) . . . . ?
N2 Yb1 N4 Si3 -121.6(5) . . . . ?
C5 Yb1 N4 Si3 136.0(5) . . . . ?
C6 Yb1 N4 Si3 110.3(5) . . . . ?
P2 Yb1 N4 Si3 82.6(5) . . . . ?
N1 Yb1 N4 Si4 -16.9(7) . . . . ?
N3 Yb1 N4 Si4 -117.6(6) . . . . ?
N2 Yb1 N4 Si4 64.8(6) . . . . ?
C5 Yb1 N4 Si4 -37.6(6) . . . . ?
C6 Yb1 N4 Si4 -63.3(6) . . . . ?
P2 Yb1 N4 Si4 -91.0(5) . . . . ?
Si1 N2 P1 C1 -145.9(8) . . . . ?
Yb1 N2 P1 C1 25.2(7) . . . . ?
Si1 N2 P1 C13 -25.8(12) . . . . ?
Yb1 N2 P1 C13 145.4(6) . . . . ?
Si1 N2 P1 C7 97.2(9) . . . . ?
Yb1 N2 P1 C7 -91.7(6) . . . . ?
Si2 N3 P2 C6 -144.1(8) . . . . ?
Yb1 N3 P2 C6 10.5(7) . . . . ?
Si2 N3 P2 C28 98.7(9) . . . . ?
Yb1 N3 P2 C28 -106.7(5) . . . . ?
Si2 N3 P2 C22 -15.7(11) . . . . ?
Yb1 N3 P2 C22 138.9(5) . . . . ?
Si2 N3 P2 Yb1 -154.6(12) . . . . ?
N4 Yb1 P2 N3 -127.1(6) . . . . ?
N1 Yb1 P2 N3 123.9(6) . . . . ?
N2 Yb1 P2 N3 82.7(6) . . . . ?
C5 Yb1 P2 N3 146.0(6) . . . . ?
C6 Yb1 P2 N3 170.1(7) . . . . ?
N4 Yb1 P2 C6 62.8(5) . . . . ?
N1 Yb1 P2 C6 -46.2(5) . . . . ?
N3 Yb1 P2 C6 -170.1(7) . . . . ?
N2 Yb1 P2 C6 -87.4(5) . . . . ?
C5 Yb1 P2 C6 -24.1(5) . . . . ?
N4 Yb1 P2 C28 -33.1(6) . . . . ?
N1 Yb1 P2 C28 -142.1(5) . . . . ?
N3 Yb1 P2 C28 94.0(7) . . . . ?
N2 Yb1 P2 C28 176.7(5) . . . . ?
C5 Yb1 P2 C28 -120.0(5) . . . . ?
C6 Yb1 P2 C28 -95.9(6) . . . . ?
N4 Yb1 P2 C22 161.3(7) . . . . ?
N1 Yb1 P2 C22 52.3(7) . . . . ?
N3 Yb1 P2 C22 -71.6(8) . . . . ?
N2 Yb1 P2 C22 11.1(8) . . . . ?
C5 Yb1 P2 C22 74.4(7) . . . . ?
C6 Yb1 P2 C22 98.5(8) . . . . ?
P1 N2 Si1 C20 81.1(11) . . . . ?
Yb1 N2 Si1 C20 -89.9(7) . . . . ?
P1 N2 Si1 C19 -43.3(11) . . . . ?
Yb1 N2 Si1 C19 145.7(6) . . . . ?
P1 N2 Si1 C21 -163.6(9) . . . . ?
Yb1 N2 Si1 C21 25.4(8) . . . . ?
P2 N3 Si2 C35 50.9(11) . . . . ?
Yb1 N3 Si2 C35 -102.4(6) . . . . ?
P2 N3 Si2 C34 -74.3(10) . . . . ?
Yb1 N3 Si2 C34 132.5(6) . . . . ?
P2 N3 Si2 C36 171.1(9) . . . . ?
Yb1 N3 Si2 C36 17.8(7) . . . . ?
Si4 N4 Si3 C38 -69.7(10) . . . . ?
Yb1 N4 Si3 C38 117.1(7) . . . . ?
Si4 N4 Si3 C39 54.4(9) . . . . ?
Yb1 N4 Si3 C39 -118.8(7) . . . . ?
Si4 N4 Si3 C37 173.5(7) . . . . ?
Yb1 N4 Si3 C37 0.3(7) . . . . ?
Si3 N4 Si4 C40 -84.2(8) . . . . ?
Yb1 N4 Si4 C40 88.5(7) . . . . ?
Si3 N4 Si4 C41 157.6(7) . . . . ?
Yb1 N4 Si4 C41 -29.6(7) . . . . ?
Si3 N4 Si4 C42 38.4(10) . . . . ?
Yb1 N4 Si4 C42 -148.8(6) . . . . ?
C5 N1 C1 C2 2.0(16) . . . . ?
Yb1 N1 C1 C2 -144.0(9) . . . . ?
C5 N1 C1 P1 -179.6(7) . . . . ?
Yb1 N1 C1 P1 34.4(11) . . . . ?
N2 P1 C1 C2 139.6(11) . . . . ?
C13 P1 C1 C2 13.6(13) . . . . ?
C7 P1 C1 C2 -98.0(12) . . . . ?
N2 P1 C1 N1 -38.7(10) . . . . ?
C13 P1 C1 N1 -164.7(8) . . . . ?
C7 P1 C1 N1 83.7(9) . . . . ?
N1 C1 C2 C3 2.4(17) . . . . ?
P1 C1 C2 C3 -175.7(9) . . . . ?
C1 C2 C3 C4 -2.2(17) . . . . ?
C2 C3 C4 C5 -2.2(18) . . . . ?
C1 N1 C5 C4 -6.3(15) . . . . ?
Yb1 N1 C5 C4 142.9(9) . . . . ?
C1 N1 C5 C6 177.8(10) . . . . ?
Yb1 N1 C5 C6 -33.0(12) . . . . ?
C1 N1 C5 Yb1 -149.2(12) . . . . ?
C3 C4 C5 N1 6.5(17) . . . . ?
C3 C4 C5 C6 -177.8(11) . . . . ?
C3 C4 C5 Yb1 56(2) . . . . ?
N4 Yb1 C5 N1 128.5(7) . . . . ?
N3 Yb1 C5 N1 -106.6(8) . . . . ?
N2 Yb1 C5 N1 14.5(8) . . . . ?
C6 Yb1 C5 N1 -150.9(11) . . . . ?
P2 Yb1 C5 N1 -121.8(8) . . . . ?
N4 Yb1 C5 C4 55.7(16) . . . . ?
N1 Yb1 C5 C4 -72.7(16) . . . . ?
N3 Yb1 C5 C4 -179.4(16) . . . . ?
N2 Yb1 C5 C4 -58.2(16) . . . . ?
C6 Yb1 C5 C4 136.4(19) . . . . ?
P2 Yb1 C5 C4 165.4(17) . . . . ?
N4 Yb1 C5 C6 -80.7(7) . . . . ?
N1 Yb1 C5 C6 150.9(11) . . . . ?
N3 Yb1 C5 C6 44.2(7) . . . . ?
N2 Yb1 C5 C6 165.4(7) . . . . ?
P2 Yb1 C5 C6 29.1(6) . . . . ?
N1 C5 C6 P2 -38.2(14) . . . . ?
C4 C5 C6 P2 146.1(10) . . . . ?
Yb1 C5 C6 P2 -61.1(8) . . . . ?
N1 C5 C6 Yb1 22.9(8) . . . . ?
C4 C5 C6 Yb1 -152.8(11) . . . . ?
N3 P2 C6 C5 52.1(11) . . . . ?
C28 P2 C6 C5 173.4(9) . . . . ?
C22 P2 C6 C5 -78.2(10) . . . . ?
Yb1 P2 C6 C5 60.0(9) . . . . ?
N3 P2 C6 Yb1 -7.9(5) . . . . ?
C28 P2 C6 Yb1 113.4(4) . . . . ?
C22 P2 C6 Yb1 -138.2(4) . . . . ?
N4 Yb1 C6 C5 103.3(7) . . . . ?
N1 Yb1 C6 C5 -15.4(6) . . . . ?
N3 Yb1 C6 C5 -127.3(8) . . . . ?
N2 Yb1 C6 C5 -17.2(8) . . . . ?
P2 Yb1 C6 C5 -132.5(9) . . . . ?
N4 Yb1 C6 P2 -124.2(4) . . . . ?
N1 Yb1 C6 P2 117.1(6) . . . . ?
N3 Yb1 C6 P2 5.3(4) . . . . ?
N2 Yb1 C6 P2 115.4(4) . . . . ?
C5 Yb1 C6 P2 132.5(9) . . . . ?
N2 P1 C7 C12 -31.1(13) . . . . ?
C1 P1 C7 C12 -150.8(11) . . . . ?
C13 P1 C7 C12 97.3(11) . . . . ?
N2 P1 C7 C8 152.5(9) . . . . ?
C1 P1 C7 C8 32.8(11) . . . . ?
C13 P1 C7 C8 -79.1(11) . . . . ?
C12 C7 C8 C9 1.5(19) . . . . ?
P1 C7 C8 C9 177.8(10) . . . . ?
C7 C8 C9 C10 -2(2) . . . . ?
C8 C9 C10 C11 0(2) . . . . ?
C9 C10 C11 C12 3(2) . . . . ?
C8 C7 C12 C11 1.0(19) . . . . ?
P1 C7 C12 C11 -175.4(10) . . . . ?
C10 C11 C12 C7 -3(2) . . . . ?
N2 P1 C13 C14 -60.4(12) . . . . ?
C1 P1 C13 C14 61.6(11) . . . . ?
C7 P1 C13 C14 172.5(10) . . . . ?
N2 P1 C13 C18 121.7(11) . . . . ?
C1 P1 C13 C18 -116.3(11) . . . . ?
C7 P1 C13 C18 -5.4(12) . . . . ?
C18 C13 C14 C15 -1.9(19) . . . . ?
P1 C13 C14 C15 -179.9(9) . . . . ?
C13 C14 C15 C16 2.8(19) . . . . ?
C14 C15 C16 C17 -4(2) . . . . ?
C15 C16 C17 C18 4(2) . . . . ?
C14 C13 C18 C17 1.8(19) . . . . ?
P1 C13 C18 C17 179.7(9) . . . . ?
C16 C17 C18 C13 -3(2) . . . . ?
N3 P2 C22 C27 -108.5(11) . . . . ?
C6 P2 C22 C27 23.7(12) . . . . ?
C28 P2 C22 C27 132.4(11) . . . . ?
Yb1 P2 C22 C27 -60.9(13) . . . . ?
N3 P2 C22 C23 69.2(11) . . . . ?
C6 P2 C22 C23 -158.6(10) . . . . ?
C28 P2 C22 C23 -50.0(11) . . . . ?
Yb1 P2 C22 C23 116.8(9) . . . . ?
C27 C22 C23 C24 2.7(18) . . . . ?
P2 C22 C23 C24 -175.1(10) . . . . ?
C22 C23 C24 C25 -3.7(19) . . . . ?
C23 C24 C25 C26 3(2) . . . . ?
C24 C25 C26 C27 -2(2) . . . . ?
C23 C22 C27 C26 -1.4(18) . . . . ?
P2 C22 C27 C26 176.4(9) . . . . ?
C25 C26 C27 C22 1(2) . . . . ?
N3 P2 C28 C29 -171.2(9) . . . . ?
C6 P2 C28 C29 63.2(11) . . . . ?
C22 P2 C28 C29 -50.2(11) . . . . ?
Yb1 P2 C28 C29 139.1(9) . . . . ?
N3 P2 C28 C33 7.4(11) . . . . ?
C6 P2 C28 C33 -118.2(10) . . . . ?
C22 P2 C28 C33 128.4(10) . . . . ?
Yb1 P2 C28 C33 -42.3(11) . . . . ?
C33 C28 C29 C30 1.6(17) . . . . ?
P2 C28 C29 C30 -179.7(9) . . . . ?
C28 C29 C30 C31 0.3(18) . . . . ?
C29 C30 C31 C32 -3.0(19) . . . . ?
C30 C31 C32 C33 3.5(19) . . . . ?
C29 C28 C33 C32 -1.1(18) . . . . ?
P2 C28 C33 C32 -179.8(9) . . . . ?
C31 C32 C33 C28 -1.4(18) . . . . ?
