#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/30/7003048.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003048
loop_
_publ_author_name
'Ollagnier, Cecile M. A.'
'Perera, Sarath D.'
'Fitchett, Christopher M.'
'Draper, Sylvia M.'
_publ_section_title
;
 Rhodium and palladium complexes of a pyridyl-centred polyphenylene
 derivative
;
_journal_issue                   2
_journal_name_full               'Dalton Transactions'
_journal_page_first              283
_journal_page_last               290
_journal_paper_doi               10.1039/b709818a
_journal_year                    2008
_chemical_formula_moiety         'C68 H48 Cl2 N4 Rh, F6 P, C H2 Cl2'
_chemical_formula_sum            'C69 H50 Cl4 F6 N4 P Rh'
_chemical_formula_weight         1324.81
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.9429(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.1740(12)
_cell_length_b                   16.0642(8)
_cell_length_c                   31.4753(16)
_cell_measurement_temperature    153(2)
_cell_volume                     11809.6(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_av_sigmaI/netI    0.0383
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            50481
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    0.564
_exptl_absorpt_correction_T_max  0.9354
_exptl_absorpt_correction_T_min  0.8325
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'blessing Acta Cryst. 1995(A51) 33-38'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.490
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5392
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.566
_refine_diff_density_min         -0.521
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     767
_refine_ls_number_reflns         11586
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0804
_refine_ls_R_factor_gt           0.0537
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0792P)²+47.0434P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1374
_refine_ls_wR_factor_ref         0.1545
_reflns_number_gt                8309
_reflns_number_total             11586
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b709818a.txt
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_Hall     -C2yc
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7003048
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 1.0000 0.24833(3) 0.7500 0.01890(12) Uani 1 2 d S . .
Rh2 Rh 1.0000 0.74493(3) 0.7500 0.02408(13) Uani 1 2 d S . .
N1 N 0.96723(12) 0.33501(19) 0.70055(10) 0.0204(7) Uani 1 1 d . . .
C2 C 0.99252(16) 0.3277(3) 0.66641(12) 0.0241(8) Uani 1 1 d . . .
C3 C 0.96581(17) 0.3596(3) 0.62492(13) 0.0306(9) Uani 1 1 d . . .
C4 C 0.91266(18) 0.4000(3) 0.61883(14) 0.0337(10) Uani 1 1 d . . .
C5 C 0.88977(17) 0.4132(3) 0.65456(13) 0.0283(9) Uani 1 1 d . . .
C6 C 0.91912(16) 0.3807(2) 0.69593(13) 0.0244(8) Uani 1 1 d . . .
C7 C 1.04893(16) 0.2843(2) 0.67794(12) 0.0222(8) Uani 1 1 d . . .
N8 N 1.06115(13) 0.24418(19) 0.71681(10) 0.0216(7) Uani 1 1 d . . .
C9 C 1.10812(16) 0.1970(2) 0.72937(14) 0.0252(8) Uani 1 1 d . . .
H37A H 1.1155 0.1691 0.7569 0.030 Uiso 1 1 calc R . .
C10 C 1.14621(16) 0.1874(2) 0.70385(14) 0.0275(9) Uani 1 1 d . . .
H13A H 1.1777 0.1502 0.7123 0.033 Uiso 1 1 calc R . .
C11 C 1.13717(17) 0.2335(3) 0.66577(14) 0.0282(9) Uani 1 1 d . . .
H65A H 1.1640 0.2314 0.6485 0.034 Uiso 1 1 calc R . .
C12 C 1.08866(16) 0.2830(3) 0.65277(13) 0.0266(9) Uani 1 1 d . . .
H25A H 1.0826 0.3158 0.6269 0.032 Uiso 1 1 calc R . .
C13 C 0.99063(18) 0.3510(3) 0.58584(13) 0.0386(11) Uani 1 1 d . . .
C14 C 0.9885(2) 0.2762(4) 0.56449(15) 0.0482(13) Uani 1 1 d . . .
H70A H 0.9707 0.2295 0.5740 0.058 Uiso 1 1 calc R . .
C15 C 1.0123(2) 0.2686(5) 0.52887(18) 0.068(2) Uani 1 1 d . . .
H54A H 1.0106 0.2170 0.5138 0.081 Uiso 1 1 calc R . .
C16 C 1.0388(3) 0.3373(6) 0.51542(18) 0.075(2) Uani 1 1 d . . .
H62A H 1.0559 0.3321 0.4916 0.090 Uiso 1 1 calc R . .
C17 C 1.0401(3) 0.4110(5) 0.5361(2) 0.0672(19) Uani 1 1 d . . .
H53A H 1.0581 0.4575 0.5265 0.081 Uiso 1 1 calc R . .
C18 C 1.0157(2) 0.4195(4) 0.57097(17) 0.0529(14) Uani 1 1 d . . .
H60A H 1.0159 0.4721 0.5848 0.064 Uiso 1 1 calc R . .
C19 C 0.8803(2) 0.4290(4) 0.57379(17) 0.0594(17) Uani 1 1 d . . .
C20 C 0.8528(3) 0.3692(5) 0.54321(18) 0.076(2) Uani 1 1 d U . .
H20A H 0.8588 0.3120 0.5508 0.091 Uiso 1 1 calc R . .
C21 C 0.8169(3) 0.3893(7) 0.5022(2) 0.091(2) Uani 1 1 d U . .
H21A H 0.7963 0.3488 0.4823 0.109 Uiso 1 1 calc R . .
C22 C 0.8143(4) 0.4698(7) 0.4935(3) 0.096(3) Uani 1 1 d U . .
H22B H 0.7915 0.4846 0.4652 0.115 Uiso 1 1 calc R . .
C23 C 0.8394(3) 0.5347(6) 0.5191(3) 0.088(2) Uani 1 1 d U . .
H23A H 0.8344 0.5908 0.5093 0.106 Uiso 1 1 calc R . .
C24 C 0.8752(3) 0.5116(5) 0.5636(2) 0.083(2) Uani 1 1 d U . .
H24A H 0.8937 0.5528 0.5840 0.099 Uiso 1 1 calc R . .
C25 C 0.83307(17) 0.4557(3) 0.64832(13) 0.0266(9) Uani 1 1 d . . .
C26 C 0.78404(18) 0.4156(3) 0.62455(13) 0.0288(9) Uani 1 1 d . . .
H35A H 0.7868 0.3620 0.6125 0.035 Uiso 1 1 calc R . .
C27 C 0.73105(18) 0.4534(3) 0.61832(14) 0.0327(10) Uani 1 1 d . . .
H39A H 0.6976 0.4252 0.6023 0.039 Uiso 1 1 calc R . .
C28 C 0.72654(18) 0.5315(3) 0.63518(15) 0.0370(10) Uani 1 1 d . . .
H61A H 0.6902 0.5577 0.6305 0.044 Uiso 1 1 calc R . .
C29 C 0.77509(19) 0.5709(3) 0.65871(17) 0.0406(11) Uani 1 1 d . . .
H72A H 0.7722 0.6247 0.6705 0.049 Uiso 1 1 calc R . .
C30 C 0.82847(18) 0.5336(3) 0.66565(15) 0.0344(10) Uani 1 1 d . . .
H52A H 0.8617 0.5615 0.6822 0.041 Uiso 1 1 calc R . .
C31 C 0.89675(16) 0.4019(2) 0.73478(12) 0.0224(8) Uani 1 1 d . . .
C32 C 0.84337(17) 0.3746(2) 0.73778(13) 0.0264(9) Uani 1 1 d . . .
H26A H 0.8224 0.3359 0.7169 0.032 Uiso 1 1 calc R . .
C33 C 0.82063(18) 0.4038(3) 0.77116(14) 0.0311(10) Uani 1 1 d . . .
H57A H 0.7840 0.3851 0.7730 0.037 Uiso 1 1 calc R . .
C34 C 0.8507(2) 0.4595(3) 0.80154(14) 0.0349(10) Uani 1 1 d . . .
H45A H 0.8348 0.4793 0.8243 0.042 Uiso 1 1 calc R . .
C35 C 0.9041(2) 0.4870(2) 0.79915(14) 0.0320(10) Uani 1 1 d . . .
H66A H 0.9251 0.5250 0.8204 0.038 Uiso 1 1 calc R . .
C36 C 0.92663(17) 0.4587(2) 0.76560(13) 0.0257(8) Uani 1 1 d . . .
H48A H 0.9629 0.4783 0.7636 0.031 Uiso 1 1 calc R . .
N37 N 0.96690(13) 0.83163(19) 0.70100(10) 0.0219(7) Uani 1 1 d . . .
C38 C 0.90850(16) 0.8231(2) 0.68506(13) 0.0256(8) Uani 1 1 d . . .
C39 C 0.87968(17) 0.8553(3) 0.64417(13) 0.0277(9) Uani 1 1 d . . .
C40 C 0.91051(17) 0.9030(3) 0.62053(13) 0.0299(9) Uani 1 1 d . . .
C41 C 0.96958(17) 0.9148(3) 0.63817(13) 0.0271(9) Uani 1 1 d . . .
C42 C 0.99631(17) 0.8794(3) 0.67919(13) 0.0262(9) Uani 1 1 d . . .
C43 C 0.88050(16) 0.7793(2) 0.71572(13) 0.0249(8) Uani 1 1 d . . .
N44 N 0.91649(13) 0.74056(19) 0.74971(12) 0.0257(7) Uani 1 1 d . . .
C45 C 0.89645(18) 0.6961(3) 0.77847(15) 0.0323(10) Uani 1 1 d . . .
H84A H 0.9228 0.6676 0.8015 0.039 Uiso 1 1 calc R . .
C46 C 0.83861(18) 0.6904(3) 0.77572(16) 0.0340(10) Uani 1 1 d . . .
H63A H 0.8250 0.6568 0.7957 0.041 Uiso 1 1 calc R . .
C47 C 0.80158(18) 0.7346(3) 0.74335(15) 0.0313(10) Uani 1 1 d . . .
H64A H 0.7618 0.7346 0.7418 0.038 Uiso 1 1 calc R . .
C48 C 0.82193(17) 0.7794(3) 0.71287(14) 0.0300(9) Uani 1 1 d . . .
H49A H 0.7962 0.8098 0.6903 0.036 Uiso 1 1 calc R . .
C49 C 0.81801(17) 0.8366(3) 0.62288(14) 0.0316(9) Uani 1 1 d . . .
C50 C 0.8038(2) 0.7580(3) 0.60607(17) 0.0471(12) Uani 1 1 d . . .
H73A H 0.8323 0.7163 0.6089 0.057 Uiso 1 1 calc R . .
C51 C 0.7466(3) 0.7406(4) 0.5848(2) 0.0663(18) Uani 1 1 d . . .
H87A H 0.7367 0.6865 0.5731 0.080 Uiso 1 1 calc R . .
C52 C 0.7052(2) 0.7992(5) 0.58046(19) 0.0669(19) Uani 1 1 d . . .
H68A H 0.6667 0.7864 0.5657 0.080 Uiso 1 1 calc R . .
C53 C 0.7194(2) 0.8771(4) 0.59752(18) 0.0548(15) Uani 1 1 d . . .
H90A H 0.6903 0.9179 0.5950 0.066 Uiso 1 1 calc R . .
C54 C 0.77600(18) 0.8971(3) 0.61856(15) 0.0384(11) Uani 1 1 d . . .
H56A H 0.7856 0.9516 0.6298 0.046 Uiso 1 1 calc R . .
C55 C 0.88067(18) 0.9473(4) 0.57888(14) 0.0400(12) Uani 1 1 d . . .
C56 C 0.8550(2) 0.9053(4) 0.54055(17) 0.0596(16) Uani 1 1 d . . .
H82A H 0.8561 0.8462 0.5396 0.072 Uiso 1 1 calc R . .
C57 C 0.8270(2) 0.9515(5) 0.50252(17) 0.0624(18) Uani 1 1 d . . .
H89A H 0.8088 0.9234 0.4761 0.075 Uiso 1 1 calc R . .
C58 C 0.8262(3) 1.0370(5) 0.5042(2) 0.0731(19) Uani 1 1 d . . .
H91A H 0.8078 1.0676 0.4787 0.088 Uiso 1 1 calc R . .
C59 C 0.8512(2) 1.0780(4) 0.54155(19) 0.0615(16) Uani 1 1 d . . .
H59A H 0.8501 1.1371 0.5423 0.074 Uiso 1 1 calc R . .
C60 C 0.8787(2) 1.0338(4) 0.57892(17) 0.0466(12) Uani 1 1 d . . .
H74A H 0.8965 1.0632 0.6051 0.056 Uiso 1 1 calc R . .
C61 C 1.00368(16) 0.9589(3) 0.61167(13) 0.0274(9) Uani 1 1 d . . .
C62 C 1.01214(18) 0.9201(3) 0.57451(14) 0.0350(10) Uani 1 1 d . . .
H58A H 0.9968 0.8661 0.5668 0.042 Uiso 1 1 calc R . .
C63 C 1.0427(2) 0.9593(3) 0.54847(15) 0.0426(12) Uani 1 1 d . . .
H22A H 1.0482 0.9323 0.5230 0.051 Uiso 1 1 calc R . .
C64 C 1.0650(2) 1.0375(3) 0.55981(16) 0.0425(11) Uani 1 1 d . . .
H36A H 1.0861 1.0647 0.5422 0.051 Uiso 1 1 calc R . .
C65 C 1.0566(2) 1.0759(3) 0.59645(16) 0.0421(11) Uani 1 1 d . . .
H86A H 1.0718 1.1301 0.6040 0.051 Uiso 1 1 calc R . .
C66 C 1.02649(18) 1.0374(3) 0.62274(14) 0.0350(10) Uani 1 1 d . . .
H43A H 1.0215 1.0646 0.6483 0.042 Uiso 1 1 calc R . .
C67 C 1.05763(16) 0.9005(2) 0.69894(13) 0.0253(8) Uani 1 1 d . . .
C68 C 1.10059(18) 0.8743(3) 0.68035(15) 0.0325(10) Uani 1 1 d . . .
H33A H 1.0920 0.8359 0.6566 0.039 Uiso 1 1 calc R . .
C69 C 1.15633(19) 0.9035(3) 0.69615(17) 0.0405(12) Uani 1 1 d . . .
H75A H 1.1857 0.8844 0.6835 0.049 Uiso 1 1 calc R . .
C70 C 1.16879(18) 0.9601(3) 0.73017(17) 0.0421(12) Uani 1 1 d . . .
H67A H 1.2067 0.9810 0.7404 0.050 Uiso 1 1 calc R . .
C71 C 1.12709(19) 0.9867(3) 0.74947(16) 0.0366(11) Uani 1 1 d . . .
H38A H 1.1362 1.0247 0.7734 0.044 Uiso 1 1 calc R . .
C72 C 1.07105(17) 0.9575(3) 0.73363(14) 0.0289(9) Uani 1 1 d . . .
H27A H 1.0419 0.9765 0.7465 0.035 Uiso 1 1 calc R . .
Cl1 Cl 0.95876(4) 0.14569(6) 0.69949(3) 0.0279(2) Uani 1 1 d . . .
Cl2 Cl 1.02797(4) 0.64275(7) 0.80449(4) 0.0363(3) Uani 1 1 d . . .
P1 P 0.76967(5) 0.15865(8) 0.64857(4) 0.0360(3) Uani 1 1 d . . .
F1 F 0.82056(13) 0.2249(2) 0.65944(13) 0.0664(9) Uani 1 1 d . . .
F2 F 0.76273(16) 0.1737(3) 0.59801(10) 0.0818(12) Uani 1 1 d . . .
F3 F 0.72388(14) 0.2297(2) 0.64814(12) 0.0676(10) Uani 1 1 d . . .
F4 F 0.71925(14) 0.0929(2) 0.63842(14) 0.0794(11) Uani 1 1 d . . .
F5 F 0.77714(14) 0.1451(3) 0.69977(10) 0.0742(11) Uani 1 1 d . . .
F6 F 0.81578(12) 0.08731(19) 0.64996(11) 0.0548(8) Uani 1 1 d . . .
C80 C 0.6027(3) 0.1704(4) 0.5679(2) 0.0693(18) Uani 1 1 d . . .
H55A H 0.6388 0.1438 0.5843 0.083 Uiso 1 1 calc R . .
H55B H 0.5879 0.1388 0.5403 0.083 Uiso 1 1 calc R . .
Cl81 Cl 0.61656(8) 0.27310(12) 0.55532(7) 0.0814(5) Uani 1 1 d . . .
Cl82 Cl 0.55188(9) 0.16542(13) 0.59984(6) 0.0859(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Rh1 N8 176.21(17) . 2_756 ?
N8 Rh1 N1 102.72(12) . 2_756 ?
N8 Rh1 N1 79.86(12) 2_756 2_756 ?
N8 Rh1 N1 79.86(12) . . ?
N8 Rh1 N1 102.72(12) 2_756 . ?
N1 Rh1 N1 96.27(17) 2_756 . ?
N8 Rh1 Cl1 82.24(9) . . ?
N8 Rh1 Cl1 95.06(9) 2_756 . ?
N1 Rh1 Cl1 174.39(9) 2_756 . ?
N1 Rh1 Cl1 87.13(9) . . ?
N8 Rh1 Cl1 95.06(9) . 2_756 ?
N8 Rh1 Cl1 82.24(9) 2_756 2_756 ?
N1 Rh1 Cl1 87.13(9) 2_756 2_756 ?
N1 Rh1 Cl1 174.39(9) . 2_756 ?
Cl1 Rh1 Cl1 89.85(5) . 2_756 ?
N44 Rh2 N44 176.01(18) . 2_756 ?
N44 Rh2 N37 102.70(12) . 2_756 ?
N44 Rh2 N37 80.02(13) 2_756 2_756 ?
N44 Rh2 N37 80.02(13) . . ?
N44 Rh2 N37 102.70(12) 2_756 . ?
N37 Rh2 N37 95.88(17) 2_756 . ?
N44 Rh2 Cl2 82.70(10) . 2_756 ?
N44 Rh2 Cl2 94.50(10) 2_756 2_756 ?
N37 Rh2 Cl2 174.32(9) 2_756 2_756 ?
N37 Rh2 Cl2 86.74(9) . 2_756 ?
N44 Rh2 Cl2 94.50(10) . . ?
N44 Rh2 Cl2 82.69(10) 2_756 . ?
N37 Rh2 Cl2 86.74(9) 2_756 . ?
N37 Rh2 Cl2 174.32(9) . . ?
Cl2 Rh2 Cl2 91.11(6) 2_756 . ?
C6 N1 C2 120.5(3) . . ?
C6 N1 Rh1 126.4(3) . . ?
C2 N1 Rh1 111.6(2) . . ?
N1 C2 C3 120.6(3) . . ?
N1 C2 C7 114.4(3) . . ?
C3 C2 C7 124.9(3) . . ?
C2 C3 C4 118.8(4) . . ?
C2 C3 C13 123.0(4) . . ?
C4 C3 C13 118.2(4) . . ?
C5 C4 C3 120.0(4) . . ?
C5 C4 C19 119.7(4) . . ?
C3 C4 C19 120.3(4) . . ?
C4 C5 C6 118.6(4) . . ?
C4 C5 C25 120.3(4) . . ?
C6 C5 C25 121.0(4) . . ?
N1 C6 C5 120.9(4) . . ?
N1 C6 C31 121.2(3) . . ?
C5 C6 C31 117.9(3) . . ?
N8 C7 C12 119.1(3) . . ?
N8 C7 C2 114.7(3) . . ?
C12 C7 C2 126.1(4) . . ?
C9 N8 C7 120.7(3) . . ?
C9 N8 Rh1 123.0(3) . . ?
C7 N8 Rh1 115.8(2) . . ?
N8 C9 C10 122.3(4) . . ?
N8 C9 H37A 118.8 . . ?
C10 C9 H37A 118.8 . . ?
C11 C10 C9 117.9(4) . . ?
C11 C10 H13A 121.1 . . ?
C9 C10 H13A 121.1 . . ?
C10 C11 C12 119.8(4) . . ?
C10 C11 H65A 120.1 . . ?
C12 C11 H65A 120.1 . . ?
C11 C12 C7 119.6(4) . . ?
C11 C12 H25A 120.2 . . ?
C7 C12 H25A 120.2 . . ?
C14 C13 C18 119.5(5) . . ?
C14 C13 C3 120.5(5) . . ?
C18 C13 C3 120.1(5) . . ?
C13 C14 C15 120.0(6) . . ?
C13 C14 H70A 120.0 . . ?
C15 C14 H70A 120.0 . . ?
C14 C15 C16 119.5(6) . . ?
C14 C15 H54A 120.2 . . ?
C16 C15 H54A 120.3 . . ?
C17 C16 C15 120.3(5) . . ?
C17 C16 H62A 119.8 . . ?
C15 C16 H62A 119.8 . . ?
C16 C17 C18 120.5(6) . . ?
C16 C17 H53A 119.7 . . ?
C18 C17 H53A 119.7 . . ?
C17 C18 C13 120.1(6) . . ?
C17 C18 H60A 120.0 . . ?
C13 C18 H60A 120.0 . . ?
C24 C19 C20 120.5(6) . . ?
C24 C19 C4 121.2(6) . . ?
C20 C19 C4 118.2(6) . . ?
C21 C20 C19 123.2(8) . . ?
C21 C20 H20A 118.4 . . ?
C19 C20 H20A 118.4 . . ?
C22 C21 C20 113.8(9) . . ?
C22 C21 H21A 123.1 . . ?
C20 C21 H21A 123.1 . . ?
C21 C22 C23 129.8(9) . . ?
C21 C22 H22B 115.1 . . ?
C23 C22 H22B 115.1 . . ?
C22 C23 C24 115.2(8) . . ?
C22 C23 H23A 122.4 . . ?
C24 C23 H23A 122.4 . . ?
C19 C24 C23 117.3(8) . . ?
C19 C24 H24A 121.3 . . ?
C23 C24 H24A 121.3 . . ?
C30 C25 C26 119.3(4) . . ?
C30 C25 C5 121.7(4) . . ?
C26 C25 C5 119.0(4) . . ?
C27 C26 C25 120.2(4) . . ?
C27 C26 H35A 119.9 . . ?
C25 C26 H35A 119.9 . . ?
C28 C27 C26 120.5(4) . . ?
C28 C27 H39A 119.8 . . ?
C26 C27 H39A 119.8 . . ?
C29 C28 C27 119.2(4) . . ?
C29 C28 H61A 120.4 . . ?
C27 C28 H61A 120.4 . . ?
C28 C29 C30 121.2(4) . . ?
C28 C29 H72A 119.4 . . ?
C30 C29 H72A 119.4 . . ?
C25 C30 C29 119.7(4) . . ?
C25 C30 H52A 120.2 . . ?
C29 C30 H52A 120.2 . . ?
C32 C31 C36 119.0(4) . . ?
C32 C31 C6 121.4(3) . . ?
C36 C31 C6 119.1(3) . . ?
C33 C32 C31 120.1(4) . . ?
C33 C32 H26A 119.9 . . ?
C31 C32 H26A 119.9 . . ?
C34 C33 C32 120.4(4) . . ?
C34 C33 H57A 119.8 . . ?
C32 C33 H57A 119.8 . . ?
C33 C34 C35 120.2(4) . . ?
C33 C34 H45A 119.9 . . ?
C35 C34 H45A 119.9 . . ?
C36 C35 C34 119.5(4) . . ?
C36 C35 H66A 120.2 . . ?
C34 C35 H66A 120.2 . . ?
C35 C36 C31 120.8(4) . . ?
C35 C36 H48A 119.6 . . ?
C31 C36 H48A 119.6 . . ?
C42 N37 C38 119.8(3) . . ?
C42 N37 Rh2 127.3(3) . . ?
C38 N37 Rh2 111.4(3) . . ?
N37 C38 C39 121.3(4) . . ?
N37 C38 C43 113.9(3) . . ?
C39 C38 C43 124.8(3) . . ?
C38 C39 C40 118.9(4) . . ?
C38 C39 C49 122.8(4) . . ?
C40 C39 C49 118.3(4) . . ?
C41 C40 C39 119.2(4) . . ?
C41 C40 C55 119.4(4) . . ?
C39 C40 C55 121.2(4) . . ?
C40 C41 C42 119.2(4) . . ?
C40 C41 C61 119.6(4) . . ?
C42 C41 C61 121.0(4) . . ?
N37 C42 C41 121.3(4) . . ?
N37 C42 C67 121.0(4) . . ?
C41 C42 C67 117.6(4) . . ?
N44 C43 C48 119.3(4) . . ?
N44 C43 C38 115.1(3) . . ?
C48 C43 C38 125.5(4) . . ?
C45 N44 C43 120.8(3) . . ?
C45 N44 Rh2 123.5(3) . . ?
C43 N44 Rh2 115.4(3) . . ?
N44 C45 C46 122.0(4) . . ?
N44 C45 H84A 119.0 . . ?
C46 C45 H84A 119.0 . . ?
C47 C46 C45 118.0(4) . . ?
C47 C46 H63A 121.0 . . ?
C45 C46 H63A 121.0 . . ?
C46 C47 C48 120.2(4) . . ?
C46 C47 H64A 119.9 . . ?
C48 C47 H64A 119.9 . . ?
C47 C48 C43 119.3(4) . . ?
C47 C48 H49A 120.3 . . ?
C43 C48 H49A 120.3 . . ?
C50 C49 C54 120.0(4) . . ?
C50 C49 C39 118.4(4) . . ?
C54 C49 C39 121.5(4) . . ?
C49 C50 C51 119.0(5) . . ?
C49 C50 H73A 120.5 . . ?
C51 C50 H73A 120.5 . . ?
C52 C51 C50 121.5(6) . . ?
C52 C51 H87A 119.3 . . ?
C50 C51 H87A 119.3 . . ?
C51 C52 C53 119.4(5) . . ?
C51 C52 H68A 120.3 . . ?
C53 C52 H68A 120.3 . . ?
C52 C53 C54 120.8(5) . . ?
C52 C53 H90A 119.6 . . ?
C54 C53 H90A 119.6 . . ?
C49 C54 C53 119.2(5) . . ?
C49 C54 H56A 120.4 . . ?
C53 C54 H56A 120.4 . . ?
C56 C55 C60 118.8(5) . . ?
C56 C55 C40 122.5(5) . . ?
C60 C55 C40 118.8(4) . . ?
C55 C56 C57 119.2(6) . . ?
C55 C56 H82A 120.4 . . ?
C57 C56 H82A 120.4 . . ?
C58 C57 C56 119.8(6) . . ?
C58 C57 H89A 120.1 . . ?
C56 C57 H89A 120.1 . . ?
C59 C58 C57 121.0(6) . . ?
C59 C58 H91A 119.5 . . ?
C57 C58 H91A 119.5 . . ?
C58 C59 C60 119.8(7) . . ?
C58 C59 H59A 120.1 . . ?
C60 C59 H59A 120.1 . . ?
C59 C60 C55 121.3(6) . . ?
C59 C60 H74A 119.3 . . ?
C55 C60 H74A 119.3 . . ?
C66 C61 C62 119.1(4) . . ?
C66 C61 C41 122.2(4) . . ?
C62 C61 C41 118.7(4) . . ?
C61 C62 C63 120.8(4) . . ?
C61 C62 H58A 119.6 . . ?
C63 C62 H58A 119.6 . . ?
C64 C63 C62 119.5(4) . . ?
C64 C63 H22A 120.2 . . ?
C62 C63 H22A 120.2 . . ?
C65 C64 C63 119.8(4) . . ?
C65 C64 H36A 120.1 . . ?
C63 C64 H36A 120.1 . . ?
C64 C65 C66 121.2(5) . . ?
C64 C65 H86A 119.4 . . ?
C66 C65 H86A 119.4 . . ?
C65 C66 C61 119.7(4) . . ?
C65 C66 H43A 120.2 . . ?
C61 C66 H43A 120.2 . . ?
C68 C67 C72 118.8(4) . . ?
C68 C67 C42 121.9(4) . . ?
C72 C67 C42 118.7(4) . . ?
C67 C68 C69 120.6(4) . . ?
C67 C68 H33A 119.7 . . ?
C69 C68 H33A 119.7 . . ?
C70 C69 C68 119.9(4) . . ?
C70 C69 H75A 120.1 . . ?
C68 C69 H75A 120.1 . . ?
C71 C70 C69 120.7(4) . . ?
C71 C70 H67A 119.6 . . ?
C69 C70 H67A 119.6 . . ?
C70 C71 C72 119.5(4) . . ?
C70 C71 H38A 120.3 . . ?
C72 C71 H38A 120.3 . . ?
C67 C72 C71 120.5(4) . . ?
C67 C72 H27A 119.8 . . ?
C71 C72 H27A 119.8 . . ?
F2 P1 F4 91.3(2) . . ?
F2 P1 F3 89.4(2) . . ?
F4 P1 F3 88.8(2) . . ?
F2 P1 F5 179.0(3) . . ?
F4 P1 F5 89.6(2) . . ?
F3 P1 F5 90.22(19) . . ?
F2 P1 F6 91.7(2) . . ?
F4 P1 F6 91.29(19) . . ?
F3 P1 F6 178.94(19) . . ?
F5 P1 F6 88.73(18) . . ?
F2 P1 F1 89.4(2) . . ?
F4 P1 F1 179.3(2) . . ?
F3 P1 F1 91.14(19) . . ?
F5 P1 F1 89.7(2) . . ?
F6 P1 F1 88.76(17) . . ?
Cl81 C80 Cl82 111.8(4) . . ?
Cl81 C80 H55A 109.3 . . ?
Cl82 C80 H55A 109.3 . . ?
Cl81 C80 H55B 109.3 . . ?
Cl82 C80 H55B 109.3 . . ?
H55A C80 H55B 107.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N8 2.019(3) . ?
Rh1 N8 2.019(3) 2_756 ?
Rh1 N1 2.086(3) 2_756 ?
Rh1 N1 2.086(3) . ?
Rh1 Cl1 2.3287(10) . ?
Rh1 Cl1 2.3287(10) 2_756 ?
Rh2 N44 2.018(3) . ?
Rh2 N44 2.018(3) 2_756 ?
Rh2 N37 2.079(3) 2_756 ?
Rh2 N37 2.079(3) . ?
Rh2 Cl2 2.3441(11) 2_756 ?
Rh2 Cl2 2.3442(11) . ?
N1 C6 1.351(5) . ?
N1 C2 1.372(5) . ?
C2 C3 1.396(5) . ?
C2 C7 1.491(5) . ?
C3 C4 1.407(6) . ?
C3 C13 1.507(6) . ?
C4 C5 1.392(6) . ?
C4 C19 1.506(6) . ?
C5 C6 1.413(5) . ?
C5 C25 1.498(5) . ?
C6 C31 1.498(5) . ?
C7 N8 1.347(5) . ?
C7 C12 1.394(5) . ?
N8 C9 1.337(5) . ?
C9 C10 1.378(6) . ?
C9 H37A 0.9500 . ?
C10 C11 1.377(6) . ?
C10 H13A 0.9500 . ?
C11 C12 1.388(6) . ?
C11 H65A 0.9500 . ?
C12 H25A 0.9500 . ?
C13 C14 1.372(7) . ?
C13 C18 1.393(7) . ?
C14 C15 1.392(7) . ?
C14 H70A 0.9500 . ?
C15 C16 1.396(10) . ?
C15 H54A 0.9500 . ?
C16 C17 1.346(10) . ?
C16 H62A 0.9500 . ?
C17 C18 1.383(7) . ?
C17 H53A 0.9500 . ?
C18 H60A 0.9500 . ?
C19 C24 1.363(9) . ?
C19 C20 1.402(10) . ?
C20 C21 1.396(8) . ?
C20 H20A 0.9500 . ?
C21 C22 1.319(12) . ?
C21 H21A 0.9500 . ?
C22 C23 1.361(12) . ?
C22 H22B 0.9500 . ?
C23 C24 1.491(10) . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9500 . ?
C25 C30 1.381(6) . ?
C25 C26 1.387(6) . ?
C26 C27 1.385(6) . ?
C26 H35A 0.9500 . ?
C27 C28 1.378(7) . ?
C27 H39A 0.9500 . ?
C28 C29 1.371(6) . ?
C28 H61A 0.9500 . ?
C29 C30 1.388(6) . ?
C29 H72A 0.9500 . ?
C30 H52A 0.9500 . ?
C31 C32 1.389(5) . ?
C31 C36 1.391(5) . ?
C32 C33 1.387(6) . ?
C32 H26A 0.9500 . ?
C33 C34 1.373(6) . ?
C33 H57A 0.9500 . ?
C34 C35 1.385(6) . ?
C34 H45A 0.9500 . ?
C35 C36 1.384(6) . ?
C35 H66A 0.9500 . ?
C36 H48A 0.9500 . ?
N37 C42 1.348(5) . ?
N37 C38 1.378(5) . ?
C38 C39 1.395(6) . ?
C38 C43 1.490(5) . ?
C39 C40 1.408(6) . ?
C39 C49 1.499(5) . ?
C40 C41 1.405(6) . ?
C40 C55 1.503(6) . ?
C41 C42 1.407(6) . ?
C41 C61 1.494(6) . ?
C42 C67 1.491(5) . ?
C43 N44 1.345(5) . ?
C43 C48 1.395(5) . ?
N44 C45 1.338(5) . ?
C45 C46 1.382(6) . ?
C45 H84A 0.9500 . ?
C46 C47 1.368(6) . ?
C46 H63A 0.9500 . ?
C47 C48 1.387(6) . ?
C47 H64A 0.9500 . ?
C48 H49A 0.9500 . ?
C49 C50 1.378(7) . ?
C49 C54 1.386(6) . ?
C50 C51 1.399(7) . ?
C50 H73A 0.9500 . ?
C51 C52 1.356(9) . ?
C51 H87A 0.9500 . ?
C52 C53 1.369(9) . ?
C52 H68A 0.9500 . ?
C53 C54 1.396(7) . ?
C53 H90A 0.9500 . ?
C54 H56A 0.9500 . ?
C55 C56 1.382(7) . ?
C55 C60 1.390(8) . ?
C56 C57 1.423(8) . ?
C56 H82A 0.9500 . ?
C57 C58 1.375(10) . ?
C57 H89A 0.9500 . ?
C58 C59 1.347(9) . ?
C58 H91A 0.9500 . ?
C59 C60 1.389(7) . ?
C59 H59A 0.9500 . ?
C60 H74A 0.9500 . ?
C61 C66 1.384(6) . ?
C61 C62 1.386(6) . ?
C62 C63 1.388(6) . ?
C62 H58A 0.9500 . ?
C63 C64 1.377(7) . ?
C63 H22A 0.9500 . ?
C64 C65 1.369(7) . ?
C64 H36A 0.9500 . ?
C65 C66 1.382(6) . ?
C65 H86A 0.9500 . ?
C66 H43A 0.9500 . ?
C67 C68 1.383(6) . ?
C67 C72 1.397(6) . ?
C68 C69 1.392(6) . ?
C68 H33A 0.9500 . ?
C69 C70 1.378(7) . ?
C69 H75A 0.9500 . ?
C70 C71 1.372(7) . ?
C70 H67A 0.9500 . ?
C71 C72 1.398(6) . ?
C71 H38A 0.9500 . ?
C72 H27A 0.9500 . ?
P1 F2 1.575(3) . ?
P1 F4 1.582(3) . ?
P1 F3 1.587(3) . ?
P1 F5 1.590(3) . ?
P1 F6 1.591(3) . ?
P1 F1 1.595(3) . ?
C80 Cl81 1.750(7) . ?
C80 Cl82 1.778(7) . ?
C80 H55A 0.9900 . ?
C80 H55B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N8 Rh1 N1 C6 -177.6(3) . . . . ?
N8 Rh1 N1 C6 5.2(3) 2_756 . . . ?
N1 Rh1 N1 C6 -75.8(3) 2_756 . . . ?
Cl1 Rh1 N1 C6 99.7(3) . . . . ?
Cl1 Rh1 N1 C6 157.1(7) 2_756 . . . ?
N8 Rh1 N1 C2 16.6(2) . . . . ?
N8 Rh1 N1 C2 -160.5(2) 2_756 . . . ?
N1 Rh1 N1 C2 118.5(3) 2_756 . . . ?
Cl1 Rh1 N1 C2 -66.0(2) . . . . ?
Cl1 Rh1 N1 C2 -8.6(11) 2_756 . . . ?
C6 N1 C2 C3 -7.1(6) . . . . ?
Rh1 N1 C2 C3 159.6(3) . . . . ?
C6 N1 C2 C7 172.9(3) . . . . ?
Rh1 N1 C2 C7 -20.4(4) . . . . ?
N1 C2 C3 C4 0.5(6) . . . . ?
C7 C2 C3 C4 -179.4(4) . . . . ?
N1 C2 C3 C13 -178.0(4) . . . . ?
C7 C2 C3 C13 2.1(7) . . . . ?
C2 C3 C4 C5 5.0(7) . . . . ?
C13 C3 C4 C5 -176.5(4) . . . . ?
C2 C3 C4 C19 -175.1(5) . . . . ?
C13 C3 C4 C19 3.5(7) . . . . ?
C3 C4 C5 C6 -4.0(7) . . . . ?
C19 C4 C5 C6 176.0(5) . . . . ?
C3 C4 C5 C25 -179.7(4) . . . . ?
C19 C4 C5 C25 0.4(7) . . . . ?
C2 N1 C6 C5 8.1(6) . . . . ?
Rh1 N1 C6 C5 -156.5(3) . . . . ?
C2 N1 C6 C31 -169.0(3) . . . . ?
Rh1 N1 C6 C31 26.4(5) . . . . ?
C4 C5 C6 N1 -2.5(6) . . . . ?
C25 C5 C6 N1 173.2(4) . . . . ?
C4 C5 C6 C31 174.7(4) . . . . ?
C25 C5 C6 C31 -9.7(6) . . . . ?
N1 C2 C7 N8 12.9(5) . . . . ?
C3 C2 C7 N8 -167.2(4) . . . . ?
N1 C2 C7 C12 -166.3(4) . . . . ?
C3 C2 C7 C12 13.6(7) . . . . ?
C12 C7 N8 C9 -6.3(5) . . . . ?
C2 C7 N8 C9 174.3(3) . . . . ?
C12 C7 N8 Rh1 -178.9(3) . . . . ?
C2 C7 N8 Rh1 1.8(4) . . . . ?
N8 Rh1 N8 C9 -49.1(3) 2_756 . . . ?
N1 Rh1 N8 C9 83.5(3) 2_756 . . . ?
N1 Rh1 N8 C9 177.7(3) . . . . ?
Cl1 Rh1 N8 C9 -93.8(3) . . . . ?
Cl1 Rh1 N8 C9 -4.7(3) 2_756 . . . ?
N8 Rh1 N8 C7 123.3(3) 2_756 . . . ?
N1 Rh1 N8 C7 -104.1(3) 2_756 . . . ?
N1 Rh1 N8 C7 -9.9(3) . . . . ?
Cl1 Rh1 N8 C7 78.5(3) . . . . ?
Cl1 Rh1 N8 C7 167.7(3) 2_756 . . . ?
C7 N8 C9 C10 0.5(6) . . . . ?
Rh1 N8 C9 C10 172.5(3) . . . . ?
N8 C9 C10 C11 5.0(6) . . . . ?
C9 C10 C11 C12 -4.4(6) . . . . ?
C10 C11 C12 C7 -1.3(6) . . . . ?
N8 C7 C12 C11 6.7(6) . . . . ?
C2 C7 C12 C11 -174.0(4) . . . . ?
C2 C3 C13 C14 74.8(6) . . . . ?
C4 C3 C13 C14 -103.7(5) . . . . ?
C2 C3 C13 C18 -105.6(5) . . . . ?
C4 C3 C13 C18 75.9(6) . . . . ?
C18 C13 C14 C15 1.4(7) . . . . ?
C3 C13 C14 C15 -179.0(4) . . . . ?
C13 C14 C15 C16 0.6(8) . . . . ?
C14 C15 C16 C17 -1.5(9) . . . . ?
C15 C16 C17 C18 0.4(9) . . . . ?
C16 C17 C18 C13 1.7(8) . . . . ?
C14 C13 C18 C17 -2.5(7) . . . . ?
C3 C13 C18 C17 177.8(4) . . . . ?
C5 C4 C19 C24 70.7(7) . . . . ?
C3 C4 C19 C24 -109.3(6) . . . . ?
C5 C4 C19 C20 -105.8(6) . . . . ?
C3 C4 C19 C20 74.3(6) . . . . ?
C24 C19 C20 C21 -3.1(9) . . . . ?
C4 C19 C20 C21 173.3(5) . . . . ?
C19 C20 C21 C22 4.3(10) . . . . ?
C20 C21 C22 C23 -2.7(12) . . . . ?
C21 C22 C23 C24 0.0(12) . . . . ?
C20 C19 C24 C23 0.1(8) . . . . ?
C4 C19 C24 C23 -176.3(5) . . . . ?
C22 C23 C24 C19 1.4(9) . . . . ?
C4 C5 C25 C30 -112.6(5) . . . . ?
C6 C5 C25 C30 71.9(5) . . . . ?
C4 C5 C25 C26 67.5(5) . . . . ?
C6 C5 C25 C26 -108.0(5) . . . . ?
C30 C25 C26 C27 0.0(6) . . . . ?
C5 C25 C26 C27 179.9(4) . . . . ?
C25 C26 C27 C28 0.8(6) . . . . ?
C26 C27 C28 C29 -0.9(7) . . . . ?
C27 C28 C29 C30 0.2(7) . . . . ?
C26 C25 C30 C29 -0.6(6) . . . . ?
C5 C25 C30 C29 179.5(4) . . . . ?
C28 C29 C30 C25 0.5(7) . . . . ?
N1 C6 C31 C32 -117.8(4) . . . . ?
C5 C6 C31 C32 65.0(5) . . . . ?
N1 C6 C31 C36 70.6(5) . . . . ?
C5 C6 C31 C36 -106.6(4) . . . . ?
C36 C31 C32 C33 -0.1(6) . . . . ?
C6 C31 C32 C33 -171.7(4) . . . . ?
C31 C32 C33 C34 -0.2(6) . . . . ?
C32 C33 C34 C35 -0.1(6) . . . . ?
C33 C34 C35 C36 0.8(6) . . . . ?
C34 C35 C36 C31 -1.2(6) . . . . ?
C32 C31 C36 C35 0.9(6) . . . . ?
C6 C31 C36 C35 172.6(4) . . . . ?
N44 Rh2 N37 C42 175.9(3) . . . . ?
N44 Rh2 N37 C42 -7.1(3) 2_756 . . . ?
N37 Rh2 N37 C42 74.0(3) 2_756 . . . ?
Cl2 Rh2 N37 C42 -101.0(3) 2_756 . . . ?
Cl2 Rh2 N37 C42 -168.8(7) . . . . ?
N44 Rh2 N37 C38 -18.0(3) . . . . ?
N44 Rh2 N37 C38 159.0(3) 2_756 . . . ?
N37 Rh2 N37 C38 -119.9(3) 2_756 . . . ?
Cl2 Rh2 N37 C38 65.1(2) 2_756 . . . ?
Cl2 Rh2 N37 C38 -2.7(11) . . . . ?
C42 N37 C38 C39 7.2(6) . . . . ?
Rh2 N37 C38 C39 -160.1(3) . . . . ?
C42 N37 C38 C43 -171.3(3) . . . . ?
Rh2 N37 C38 C43 21.4(4) . . . . ?
N37 C38 C39 C40 -5.1(6) . . . . ?
C43 C38 C39 C40 173.3(4) . . . . ?
N37 C38 C39 C49 170.8(4) . . . . ?
C43 C38 C39 C49 -10.9(6) . . . . ?
C38 C39 C40 C41 1.8(6) . . . . ?
C49 C39 C40 C41 -174.3(4) . . . . ?
C38 C39 C40 C55 -173.0(4) . . . . ?
C49 C39 C40 C55 11.0(6) . . . . ?
C39 C40 C41 C42 -0.7(6) . . . . ?
C55 C40 C41 C42 174.2(4) . . . . ?
C39 C40 C41 C61 174.7(4) . . . . ?
C55 C40 C41 C61 -10.5(6) . . . . ?
C38 N37 C42 C41 -6.0(6) . . . . ?
Rh2 N37 C42 C41 159.1(3) . . . . ?
C38 N37 C42 C67 170.5(3) . . . . ?
Rh2 N37 C42 C67 -24.4(5) . . . . ?
C40 C41 C42 N37 2.8(6) . . . . ?
C61 C41 C42 N37 -172.5(4) . . . . ?
C40 C41 C42 C67 -173.8(4) . . . . ?
C61 C41 C42 C67 10.9(6) . . . . ?
N37 C38 C43 N44 -12.7(5) . . . . ?
C39 C38 C43 N44 168.9(4) . . . . ?
N37 C38 C43 C48 164.0(4) . . . . ?
C39 C38 C43 C48 -14.5(6) . . . . ?
C48 C43 N44 C45 6.0(6) . . . . ?
C38 C43 N44 C45 -177.1(4) . . . . ?
C48 C43 N44 Rh2 180.0(3) . . . . ?
C38 C43 N44 Rh2 -3.2(4) . . . . ?
N44 Rh2 N44 C45 51.9(3) 2_756 . . . ?
N37 Rh2 N44 C45 -80.9(3) 2_756 . . . ?
N37 Rh2 N44 C45 -174.8(4) . . . . ?
Cl2 Rh2 N44 C45 97.3(3) 2_756 . . . ?
Cl2 Rh2 N44 C45 6.7(3) . . . . ?
N44 Rh2 N44 C43 -121.9(3) 2_756 . . . ?
N37 Rh2 N44 C43 105.3(3) 2_756 . . . ?
N37 Rh2 N44 C43 11.4(3) . . . . ?
Cl2 Rh2 N44 C43 -76.5(3) 2_756 . . . ?
Cl2 Rh2 N44 C43 -167.1(3) . . . . ?
C43 N44 C45 C46 -2.5(6) . . . . ?
Rh2 N44 C45 C46 -176.0(3) . . . . ?
N44 C45 C46 C47 -2.5(7) . . . . ?
C45 C46 C47 C48 3.8(7) . . . . ?
C46 C47 C48 C43 -0.4(6) . . . . ?
N44 C43 C48 C47 -4.6(6) . . . . ?
C38 C43 C48 C47 178.9(4) . . . . ?
C38 C39 C49 C50 -72.1(6) . . . . ?
C40 C39 C49 C50 103.8(5) . . . . ?
C38 C39 C49 C54 110.1(5) . . . . ?
C40 C39 C49 C54 -74.0(6) . . . . ?
C54 C49 C50 C51 -0.1(7) . . . . ?
C39 C49 C50 C51 -177.9(5) . . . . ?
C49 C50 C51 C52 -0.1(9) . . . . ?
C50 C51 C52 C53 -0.5(9) . . . . ?
C51 C52 C53 C54 1.2(9) . . . . ?
C50 C49 C54 C53 0.7(7) . . . . ?
C39 C49 C54 C53 178.5(4) . . . . ?
C52 C53 C54 C49 -1.3(7) . . . . ?
C41 C40 C55 C56 116.6(5) . . . . ?
C39 C40 C55 C56 -68.7(6) . . . . ?
C41 C40 C55 C60 -63.6(6) . . . . ?
C39 C40 C55 C60 111.2(5) . . . . ?
C60 C55 C56 C57 -0.6(7) . . . . ?
C40 C55 C56 C57 179.3(4) . . . . ?
C55 C56 C57 C58 0.7(8) . . . . ?
C56 C57 C58 C59 -0.7(9) . . . . ?
C57 C58 C59 C60 0.6(9) . . . . ?
C58 C59 C60 C55 -0.5(8) . . . . ?
C56 C55 C60 C59 0.6(7) . . . . ?
C40 C55 C60 C59 -179.3(4) . . . . ?
C40 C41 C61 C66 110.5(5) . . . . ?
C42 C41 C61 C66 -74.3(5) . . . . ?
C40 C41 C61 C62 -68.8(5) . . . . ?
C42 C41 C61 C62 106.4(5) . . . . ?
C66 C61 C62 C63 -0.4(7) . . . . ?
C41 C61 C62 C63 178.9(4) . . . . ?
C61 C62 C63 C64 0.2(7) . . . . ?
C62 C63 C64 C65 -0.3(8) . . . . ?
C63 C64 C65 C66 0.6(8) . . . . ?
C64 C65 C66 C61 -0.8(7) . . . . ?
C62 C61 C66 C65 0.7(7) . . . . ?
C41 C61 C66 C65 -178.6(4) . . . . ?
N37 C42 C67 C68 116.2(4) . . . . ?
C41 C42 C67 C68 -67.2(5) . . . . ?
N37 C42 C67 C72 -72.5(5) . . . . ?
C41 C42 C67 C72 104.1(4) . . . . ?
C72 C67 C68 C69 0.6(6) . . . . ?
C42 C67 C68 C69 171.8(4) . . . . ?
C67 C68 C69 C70 -1.0(7) . . . . ?
C68 C69 C70 C71 1.6(7) . . . . ?
C69 C70 C71 C72 -1.6(7) . . . . ?
C68 C67 C72 C71 -0.6(6) . . . . ?
C42 C67 C72 C71 -172.1(4) . . . . ?
C70 C71 C72 C67 1.1(6) . . . . ?
