#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:37:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179757 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/53/7005383.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7005383
loop_
_publ_author_name
'Jimenez-Rodriguez, Cristina'
'Pogorzelec, Peter J.'
'Eastham, Graham R.'
'Slawin, Alexandra M. Z.'
'Cole-Hamilton, David J.'
_publ_section_title
;
 Rhodium catalysed methanol carbonylation in the presence of
 bis(ditertiarybutylphosphinomethyl)benzene
;
_journal_issue                   37
_journal_name_full               'Dalton Transactions'
_journal_page_first              4160
_journal_paper_doi               10.1039/b701582h
_journal_year                    2007
_chemical_formula_sum            'C25 H44 I O P2 Rh'
_chemical_formula_weight         652.35
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.122(2)
_cell_angle_beta                 106.790(2)
_cell_angle_gamma                100.582(2)
_cell_formula_units_Z            4
_cell_length_a                   12.2158(12)
_cell_length_b                   12.7064(13)
_cell_length_c                   19.6855(19)
_cell_measurement_reflns_used    132
_cell_measurement_temperature    125(2)
_cell_measurement_theta_max      28
_cell_measurement_theta_min      12
_cell_volume                     2760.9(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      125(2)
_diffrn_detector_area_resol_mean 0.83
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0340
_diffrn_reflns_av_sigmaI/netI    0.0524
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            16256
_diffrn_reflns_theta_full        25.44
_diffrn_reflns_theta_max         25.44
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    1.867
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.746379
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.569
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          .1
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .01
_refine_diff_density_max         1.461
_refine_diff_density_min         -1.973
_refine_diff_density_rms         0.153
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.966
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         9905
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.966
_refine_ls_R_factor_all          0.0619
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0684P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0997
_refine_ls_wR_factor_ref         0.1070
_reflns_number_gt                7581
_reflns_number_total             9905
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b701582h.txt
_cod_data_source_block           Rh(DTBPMP)(CO)I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7005383
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 1.50513(4) 0.16237(3) 0.23804(2) 0.01376(10) Uani 1 1 d . . .
I1 I 1.73766(3) 0.26746(3) 0.313956(18) 0.02012(10) Uani 1 1 d . . .
P1 P 1.44231(12) 0.19512(11) 0.34600(7) 0.0142(3) Uani 1 1 d . . .
C1 C 1.3018(5) 0.1046(4) 0.3427(3) 0.0174(11) Uani 1 1 d . . .
H1A H 1.3150 0.0296 0.3404 0.021 Uiso 1 1 calc R . .
H1B H 1.2933 0.1322 0.3914 0.021 Uiso 1 1 calc R . .
C2 C 1.1820(5) 0.0870(4) 0.2856(3) 0.0169(11) Uani 1 1 d . . .
C3 C 1.1466(5) 0.0135(4) 0.2145(3) 0.0168(11) Uani 1 1 d . . .
C4 C 1.0270(5) -0.0144(5) 0.1696(3) 0.0246(12) Uani 1 1 d . . .
H4A H 1.0020 -0.0665 0.1223 0.029 Uiso 1 1 calc R . .
C5 C 0.9441(5) 0.0313(5) 0.1919(3) 0.0282(13) Uani 1 1 d . . .
H5A H 0.8639 0.0117 0.1602 0.034 Uiso 1 1 calc R . .
C6 C 0.9804(5) 0.1069(5) 0.2619(3) 0.0285(13) Uani 1 1 d . . .
H6A H 0.9256 0.1405 0.2781 0.034 Uiso 1 1 calc R . .
C7 C 1.0965(5) 0.1320(4) 0.3072(3) 0.0228(12) Uani 1 1 d . . .
H7A H 1.1199 0.1819 0.3552 0.027 Uiso 1 1 calc R . .
C8 C 1.2300(5) -0.0445(4) 0.1883(3) 0.0182(11) Uani 1 1 d . . .
H8A H 1.1800 -0.1114 0.1475 0.022 Uiso 1 1 calc R . .
H8B H 1.2721 -0.0718 0.2293 0.022 Uiso 1 1 calc R . .
P2 P 1.34461(12) 0.02451(11) 0.15569(7) 0.0158(3) Uani 1 1 d . . .
C9 C 1.5415(5) 0.1746(5) 0.4353(3) 0.0213(12) Uani 1 1 d . . .
C10 C 1.4776(5) 0.1498(5) 0.4896(3) 0.0278(13) Uani 1 1 d . . .
H10A H 1.5341 0.1403 0.5332 0.042 Uiso 1 1 calc R . .
H10B H 1.4133 0.0813 0.4653 0.042 Uiso 1 1 calc R . .
H10C H 1.4448 0.2120 0.5047 0.042 Uiso 1 1 calc R . .
C11 C 1.6479(5) 0.2766(5) 0.4794(3) 0.0244(12) Uani 1 1 d . . .
H11A H 1.6955 0.2620 0.5241 0.037 Uiso 1 1 calc R . .
H11B H 1.6191 0.3422 0.4933 0.037 Uiso 1 1 calc R . .
H11C H 1.6966 0.2904 0.4489 0.037 Uiso 1 1 calc R . .
C12 C 1.5866(5) 0.0741(5) 0.4099(3) 0.0242(12) Uani 1 1 d . . .
H12A H 1.6382 0.0589 0.4531 0.036 Uiso 1 1 calc R . .
H12B H 1.6315 0.0901 0.3776 0.036 Uiso 1 1 calc R . .
H12C H 1.5192 0.0088 0.3827 0.036 Uiso 1 1 calc R . .
C13 C 1.4181(5) 0.3400(4) 0.3615(3) 0.0193(11) Uani 1 1 d . . .
C14 C 1.3317(5) 0.3427(5) 0.2877(3) 0.0242(12) Uani 1 1 d . . .
H14A H 1.3164 0.4165 0.2928 0.036 Uiso 1 1 calc R . .
H14B H 1.2572 0.2860 0.2744 0.036 Uiso 1 1 calc R . .
H14C H 1.3668 0.3274 0.2489 0.036 Uiso 1 1 calc R . .
C15 C 1.3680(6) 0.3701(5) 0.4238(3) 0.0280(13) Uani 1 1 d . . .
H15A H 1.3581 0.4459 0.4294 0.042 Uiso 1 1 calc R . .
H15B H 1.4228 0.3663 0.4701 0.042 Uiso 1 1 calc R . .
H15C H 1.2911 0.3174 0.4117 0.042 Uiso 1 1 calc R . .
C16 C 1.5327(5) 0.4297(4) 0.3778(3) 0.0228(12) Uani 1 1 d . . .
H16A H 1.5170 0.5035 0.3857 0.034 Uiso 1 1 calc R . .
H16B H 1.5609 0.4158 0.3357 0.034 Uiso 1 1 calc R . .
H16C H 1.5933 0.4271 0.4222 0.034 Uiso 1 1 calc R . .
C17 C 1.2538(5) 0.0559(5) 0.0694(3) 0.0260(13) Uani 1 1 d . . .
C18 C 1.2057(7) 0.1559(5) 0.0958(3) 0.0421(18) Uani 1 1 d . . .
H18A H 1.1582 0.1746 0.0529 0.063 Uiso 1 1 calc R . .
H18B H 1.2722 0.2204 0.1265 0.063 Uiso 1 1 calc R . .
H18C H 1.1563 0.1360 0.1249 0.063 Uiso 1 1 calc R . .
C19 C 1.1493(6) -0.0416(5) 0.0182(3) 0.0372(16) Uani 1 1 d . . .
H19A H 1.1068 -0.0201 -0.0250 0.056 Uiso 1 1 calc R . .
H19B H 1.0955 -0.0614 0.0447 0.056 Uiso 1 1 calc R . .
H19C H 1.1784 -0.1059 0.0019 0.056 Uiso 1 1 calc R . .
C20 C 1.3289(7) 0.0940(10) 0.0240(4) 0.084(4) Uani 1 1 d . . .
H20A H 1.2780 0.1086 -0.0197 0.127 Uiso 1 1 calc R . .
H20B H 1.3659 0.0355 0.0084 0.127 Uiso 1 1 calc R . .
H20C H 1.3905 0.1624 0.0543 0.127 Uiso 1 1 calc R . .
C21 C 1.4035(5) -0.1018(5) 0.1291(3) 0.0257(13) Uani 1 1 d . . .
C22 C 1.3101(7) -0.2111(6) 0.0869(4) 0.064(3) Uani 1 1 d . . .
H22A H 1.3489 -0.2703 0.0757 0.096 Uiso 1 1 calc R . .
H22B H 1.2588 -0.2034 0.0407 0.096 Uiso 1 1 calc R . .
H22C H 1.2624 -0.2302 0.1171 0.096 Uiso 1 1 calc R . .
C23 C 1.4819(12) -0.0822(8) 0.0838(7) 0.129(6) Uani 1 1 d . . .
H23A H 1.5108 -0.1482 0.0714 0.193 Uiso 1 1 calc R . .
H23B H 1.5494 -0.0175 0.1124 0.193 Uiso 1 1 calc R . .
H23C H 1.4366 -0.0681 0.0383 0.193 Uiso 1 1 calc R . .
C24 C 1.4762(7) -0.1182(6) 0.2005(4) 0.054(2) Uani 1 1 d . . .
H24A H 1.5088 -0.1822 0.1896 0.082 Uiso 1 1 calc R . .
H24B H 1.4259 -0.1321 0.2301 0.082 Uiso 1 1 calc R . .
H24C H 1.5412 -0.0511 0.2281 0.082 Uiso 1 1 calc R . .
C25 C 1.5609(5) 0.1789(5) 0.1621(3) 0.0266(13) Uani 1 1 d . . .
O25 O 1.6023(4) 0.1997(4) 0.1208(2) 0.0492(13) Uani 1 1 d . . .
Rh31 Rh 2.02312(4) 0.70226(3) 0.29843(2) 0.01585(11) Uani 1 1 d . . .
I31 I 2.24627(3) 0.71979(3) 0.29153(2) 0.03025(11) Uani 1 1 d . . .
P31 P 1.92167(12) 0.54202(11) 0.18921(7) 0.0143(3) Uani 1 1 d . . .
C31 C 1.7730(4) 0.4558(4) 0.1742(3) 0.0158(11) Uani 1 1 d . . .
H31A H 1.7514 0.3968 0.1273 0.019 Uiso 1 1 calc R . .
H31B H 1.7834 0.4177 0.2138 0.019 Uiso 1 1 calc R . .
C32 C 1.6649(5) 0.4981(4) 0.1707(3) 0.0184(11) Uani 1 1 d . . .
C33 C 1.6493(4) 0.5564(4) 0.2346(3) 0.0172(11) Uani 1 1 d . . .
C34 C 1.5382(5) 0.5784(5) 0.2277(3) 0.0239(12) Uani 1 1 d . . .
H34A H 1.5246 0.6146 0.2707 0.029 Uiso 1 1 calc R . .
C35 C 1.4479(5) 0.5486(5) 0.1597(3) 0.0287(14) Uani 1 1 d . . .
H35A H 1.3749 0.5669 0.1564 0.034 Uiso 1 1 calc R . .
C36 C 1.4645(5) 0.4928(5) 0.0977(3) 0.0311(14) Uani 1 1 d . . .
H36A H 1.4029 0.4718 0.0511 0.037 Uiso 1 1 calc R . .
C37 C 1.5713(5) 0.4669(5) 0.1030(3) 0.0240(12) Uani 1 1 d . . .
H37A H 1.5816 0.4270 0.0597 0.029 Uiso 1 1 calc R . .
C38 C 1.7411(5) 0.5820(4) 0.3107(3) 0.0170(11) Uani 1 1 d . . .
H38A H 1.7690 0.5139 0.3126 0.020 Uiso 1 1 calc R . .
H38B H 1.6983 0.5910 0.3463 0.020 Uiso 1 1 calc R . .
P32 P 1.87500(12) 0.70015(11) 0.34803(7) 0.0152(3) Uani 1 1 d . . .
C39 C 1.9982(5) 0.4224(4) 0.1850(3) 0.0192(11) Uani 1 1 d . . .
C40 C 1.9165(5) 0.3068(5) 0.1387(3) 0.0278(13) Uani 1 1 d . . .
H40A H 1.9628 0.2514 0.1395 0.042 Uiso 1 1 calc R . .
H40B H 1.8804 0.3082 0.0876 0.042 Uiso 1 1 calc R . .
H40C H 1.8542 0.2869 0.1594 0.042 Uiso 1 1 calc R . .
C41 C 2.1026(5) 0.4427(5) 0.1557(3) 0.0260(13) Uani 1 1 d . . .
H41A H 2.1378 0.3793 0.1546 0.039 Uiso 1 1 calc R . .
H41B H 2.1625 0.5109 0.1883 0.039 Uiso 1 1 calc R . .
H41C H 2.0736 0.4508 0.1057 0.039 Uiso 1 1 calc R . .
C42 C 2.0452(5) 0.4188(5) 0.2657(3) 0.0215(12) Uani 1 1 d . . .
H42A H 2.0858 0.3593 0.2683 0.032 Uiso 1 1 calc R . .
H42B H 1.9789 0.4042 0.2839 0.032 Uiso 1 1 calc R . .
H42C H 2.1009 0.4905 0.2962 0.032 Uiso 1 1 calc R . .
C43 C 1.8986(5) 0.5919(4) 0.1031(3) 0.0183(11) Uani 1 1 d . . .
C44 C 1.8219(5) 0.6746(5) 0.1075(3) 0.0246(13) Uani 1 1 d . . .
H44A H 1.8080 0.7022 0.0636 0.037 Uiso 1 1 calc R . .
H44B H 1.8630 0.7374 0.1519 0.037 Uiso 1 1 calc R . .
H44C H 1.7460 0.6370 0.1096 0.037 Uiso 1 1 calc R . .
C45 C 1.8390(5) 0.4950(4) 0.0318(3) 0.0229(12) Uani 1 1 d . . .
H45A H 1.8288 0.5243 -0.0112 0.034 Uiso 1 1 calc R . .
H45B H 1.7614 0.4560 0.0311 0.034 Uiso 1 1 calc R . .
H45C H 1.8889 0.4429 0.0302 0.034 Uiso 1 1 calc R . .
C46 C 2.0164(5) 0.6569(5) 0.1014(3) 0.0240(12) Uani 1 1 d . . .
H46A H 2.0021 0.6815 0.0564 0.036 Uiso 1 1 calc R . .
H46B H 2.0705 0.6086 0.1020 0.036 Uiso 1 1 calc R . .
H46C H 2.0519 0.7221 0.1448 0.036 Uiso 1 1 calc R . .
C47 C 1.8120(5) 0.8265(4) 0.3529(3) 0.0218(12) Uani 1 1 d . . .
C48 C 1.7575(5) 0.8279(5) 0.2726(3) 0.0287(14) Uani 1 1 d . . .
H48A H 1.7233 0.8917 0.2715 0.043 Uiso 1 1 calc R . .
H48B H 1.6954 0.7587 0.2451 0.043 Uiso 1 1 calc R . .
H48C H 1.8192 0.8341 0.2499 0.043 Uiso 1 1 calc R . .
C49 C 1.7211(6) 0.8235(6) 0.3922(4) 0.0420(17) Uani 1 1 d . . .
H49A H 1.6920 0.8906 0.3933 0.063 Uiso 1 1 calc R . .
H49B H 1.7582 0.8209 0.4429 0.063 Uiso 1 1 calc R . .
H49C H 1.6546 0.7573 0.3657 0.063 Uiso 1 1 calc R . .
C50 C 1.9073(6) 0.9381(5) 0.3905(3) 0.0329(15) Uani 1 1 d . . .
H50A H 1.8693 0.9997 0.3916 0.049 Uiso 1 1 calc R . .
H50B H 1.9618 0.9457 0.3627 0.049 Uiso 1 1 calc R . .
H50C H 1.9515 0.9400 0.4411 0.049 Uiso 1 1 calc R . .
C51 C 1.9364(5) 0.6775(4) 0.4439(3) 0.0193(11) Uani 1 1 d . . .
C52 C 1.8414(5) 0.6275(5) 0.4735(3) 0.0274(13) Uani 1 1 d . . .
H52A H 1.8797 0.6187 0.5223 0.041 Uiso 1 1 calc R . .
H52B H 1.7940 0.5546 0.4395 0.041 Uiso 1 1 calc R . .
H52C H 1.7898 0.6774 0.4775 0.041 Uiso 1 1 calc R . .
C53 C 2.0142(6) 0.7860(5) 0.5027(3) 0.0296(14) Uani 1 1 d . . .
H53A H 2.0433 0.7708 0.5505 0.044 Uiso 1 1 calc R . .
H53B H 1.9673 0.8405 0.5064 0.044 Uiso 1 1 calc R . .
H53C H 2.0815 0.8160 0.4886 0.044 Uiso 1 1 calc R . .
C54 C 2.0113(5) 0.5953(5) 0.4361(3) 0.0234(12) Uani 1 1 d . . .
H54A H 2.0446 0.5808 0.4838 0.035 Uiso 1 1 calc R . .
H54B H 2.0757 0.6267 0.4200 0.035 Uiso 1 1 calc R . .
H54C H 1.9616 0.5253 0.3993 0.035 Uiso 1 1 calc R . .
C55 C 2.1146(7) 0.8395(5) 0.3684(3) 0.0289(14) Uani 1 1 d . . .
O55 O 2.1697(4) 0.9175(4) 0.4050(2) 0.0370(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C25 Rh1 P2 89.87(17) . . ?
C25 Rh1 P1 164.52(19) . . ?
P2 Rh1 P1 100.28(5) . . ?
C25 Rh1 I1 78.65(17) . . ?
P2 Rh1 I1 157.42(4) . . ?
P1 Rh1 I1 95.32(3) . . ?
C1 P1 C13 104.3(2) . . ?
C1 P1 C9 96.5(2) . . ?
C13 P1 C9 111.6(2) . . ?
C1 P1 Rh1 119.42(17) . . ?
C13 P1 Rh1 106.63(16) . . ?
C9 P1 Rh1 117.62(18) . . ?
C2 C1 P1 124.8(4) . . ?
C2 C1 H1A 106.1 . . ?
P1 C1 H1A 106.1 . . ?
C2 C1 H1B 106.1 . . ?
P1 C1 H1B 106.1 . . ?
H1A C1 H1B 106.3 . . ?
C3 C2 C7 118.1(5) . . ?
C3 C2 C1 122.2(5) . . ?
C7 C2 C1 119.0(5) . . ?
C2 C3 C4 118.5(5) . . ?
C2 C3 C8 121.9(5) . . ?
C4 C3 C8 119.3(5) . . ?
C5 C4 C3 122.4(5) . . ?
C5 C4 H4A 118.8 . . ?
C3 C4 H4A 118.8 . . ?
C4 C5 C6 118.8(5) . . ?
C4 C5 H5A 120.6 . . ?
C6 C5 H5A 120.6 . . ?
C7 C6 C5 119.2(6) . . ?
C7 C6 H6A 120.4 . . ?
C5 C6 H6A 120.4 . . ?
C6 C7 C2 122.8(5) . . ?
C6 C7 H7A 118.6 . . ?
C2 C7 H7A 118.6 . . ?
C3 C8 P2 123.2(4) . . ?
C3 C8 H8A 106.5 . . ?
P2 C8 H8A 106.5 . . ?
C3 C8 H8B 106.5 . . ?
P2 C8 H8B 106.5 . . ?
H8A C8 H8B 106.5 . . ?
C8 P2 C17 103.3(3) . . ?
C8 P2 C21 97.4(2) . . ?
C17 P2 C21 110.4(3) . . ?
C8 P2 Rh1 119.90(17) . . ?
C17 P2 Rh1 117.94(19) . . ?
C21 P2 Rh1 105.95(19) . . ?
C12 C9 C11 109.3(5) . . ?
C12 C9 C10 108.4(4) . . ?
C11 C9 C10 106.4(4) . . ?
C12 C9 P1 105.2(3) . . ?
C11 C9 P1 112.6(3) . . ?
C10 C9 P1 114.8(4) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C15 C13 C16 108.8(4) . . ?
C15 C13 C14 110.3(5) . . ?
C16 C13 C14 106.2(4) . . ?
C15 C13 P1 113.3(4) . . ?
C16 C13 P1 111.7(4) . . ?
C14 C13 P1 106.3(4) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C19 C17 C20 108.4(6) . . ?
C19 C17 C18 108.7(5) . . ?
C20 C17 C18 105.9(6) . . ?
C19 C17 P2 113.7(4) . . ?
C20 C17 P2 112.9(4) . . ?
C18 C17 P2 107.0(4) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C23 C21 C24 108.7(7) . . ?
C23 C21 C22 107.3(7) . . ?
C24 C21 C22 106.7(6) . . ?
C23 C21 P2 111.6(4) . . ?
C24 C21 P2 106.5(4) . . ?
C22 C21 P2 115.7(4) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
O25 C25 Rh1 172.6(5) . . ?
C55 Rh31 P32 91.1(2) . . ?
C55 Rh31 P31 167.41(17) . . ?
P32 Rh31 P31 98.76(5) . . ?
C55 Rh31 I31 75.8(2) . . ?
P32 Rh31 I31 159.39(4) . . ?
P31 Rh31 I31 96.70(4) . . ?
C31 P31 C43 103.1(2) . . ?
C31 P31 C39 96.5(2) . . ?
C43 P31 C39 111.7(2) . . ?
C31 P31 Rh31 121.05(16) . . ?
C43 P31 Rh31 109.13(17) . . ?
C39 P31 Rh31 114.38(17) . . ?
C32 C31 P31 125.5(4) . . ?
C32 C31 H31A 106.0 . . ?
P31 C31 H31A 106.0 . . ?
C32 C31 H31B 106.0 . . ?
P31 C31 H31B 106.0 . . ?
H31A C31 H31B 106.3 . . ?
C37 C32 C33 119.0(5) . . ?
C37 C32 C31 118.9(5) . . ?
C33 C32 C31 121.6(4) . . ?
C32 C33 C34 117.8(5) . . ?
C32 C33 C38 122.0(5) . . ?
C34 C33 C38 119.7(5) . . ?
C35 C34 C33 121.9(5) . . ?
C35 C34 H34A 119.1 . . ?
C33 C34 H34A 119.1 . . ?
C36 C35 C34 119.8(5) . . ?
C36 C35 H35A 120.1 . . ?
C34 C35 H35A 120.1 . . ?
C35 C36 C37 119.7(5) . . ?
C35 C36 H36A 120.1 . . ?
C37 C36 H36A 120.1 . . ?
C36 C37 C32 121.7(5) . . ?
C36 C37 H37A 119.1 . . ?
C32 C37 H37A 119.1 . . ?
C33 C38 P32 123.6(4) . . ?
C33 C38 H38A 106.4 . . ?
P32 C38 H38A 106.4 . . ?
C33 C38 H38B 106.4 . . ?
P32 C38 H38B 106.4 . . ?
H38A C38 H38B 106.5 . . ?
C38 P32 C47 103.1(2) . . ?
C38 P32 C51 97.5(2) . . ?
C47 P32 C51 111.7(2) . . ?
C38 P32 Rh31 120.65(17) . . ?
C47 P32 Rh31 116.06(18) . . ?
C51 P32 Rh31 106.44(17) . . ?
C40 C39 C42 107.6(4) . . ?
C40 C39 C41 106.9(4) . . ?
C42 C39 C41 109.5(4) . . ?
C40 C39 P31 115.1(4) . . ?
C42 C39 P31 104.4(3) . . ?
C41 C39 P31 113.1(4) . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C39 C41 H41A 109.5 . . ?
C39 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C39 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C39 C42 H42A 109.5 . . ?
C39 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C39 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C46 C43 C44 106.5(4) . . ?
C46 C43 C45 109.1(4) . . ?
C44 C43 C45 110.7(4) . . ?
C46 C43 P31 111.1(4) . . ?
C44 C43 P31 107.1(3) . . ?
C45 C43 P31 112.2(4) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C43 C46 H46A 109.5 . . ?
C43 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C43 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C49 C47 C48 111.6(5) . . ?
C49 C47 C50 108.0(5) . . ?
C48 C47 C50 104.9(4) . . ?
C49 C47 P32 113.0(4) . . ?
C48 C47 P32 105.7(4) . . ?
C50 C47 P32 113.4(4) . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C47 C49 H49A 109.5 . . ?
C47 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C47 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C47 C50 H50A 109.5 . . ?
C47 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C47 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C54 C51 C53 109.1(5) . . ?
C54 C51 C52 107.5(4) . . ?
C53 C51 C52 106.9(4) . . ?
C54 C51 P32 106.4(3) . . ?
C53 C51 P32 112.2(4) . . ?
C52 C51 P32 114.6(4) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C51 C54 H54A 109.5 . . ?
C51 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C51 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
O55 C55 Rh31 175.7(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C25 1.847(5) . ?
Rh1 P2 2.2915(14) . ?
Rh1 P1 2.4426(13) . ?
Rh1 I1 2.7205(6) . ?
P1 C1 1.859(5) . ?
P1 C13 1.894(5) . ?
P1 C9 1.925(5) . ?
C1 C2 1.510(7) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.403(7) . ?
C2 C7 1.404(7) . ?
C3 C4 1.405(8) . ?
C3 C8 1.506(7) . ?
C4 C5 1.387(8) . ?
C4 H4A 0.9500 . ?
C5 C6 1.397(8) . ?
C5 H5A 0.9500 . ?
C6 C7 1.375(8) . ?
C6 H6A 0.9500 . ?
C7 H7A 0.9500 . ?
C8 P2 1.856(5) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
P2 C17 1.906(5) . ?
P2 C21 1.912(6) . ?
C9 C12 1.529(8) . ?
C9 C11 1.542(8) . ?
C9 C10 1.543(7) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C15 1.532(7) . ?
C13 C16 1.537(8) . ?
C13 C14 1.541(7) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C19 1.527(8) . ?
C17 C20 1.539(9) . ?
C17 C18 1.551(8) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C23 1.508(9) . ?
C21 C24 1.509(8) . ?
C21 C22 1.519(9) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 O25 1.125(7) . ?
Rh31 C55 1.890(7) . ?
Rh31 P32 2.2896(14) . ?
Rh31 P31 2.4493(14) . ?
Rh31 I31 2.7390(6) . ?
P31 C31 1.847(5) . ?
P31 C43 1.897(5) . ?
P31 C39 1.924(5) . ?
C31 C32 1.503(7) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C37 1.404(7) . ?
C32 C33 1.404(7) . ?
C33 C34 1.410(7) . ?
C33 C38 1.515(7) . ?
C34 C35 1.390(8) . ?
C34 H34A 0.9500 . ?
C35 C36 1.366(8) . ?
C35 H35A 0.9500 . ?
C36 C37 1.384(8) . ?
C36 H36A 0.9500 . ?
C37 H37A 0.9500 . ?
C38 P32 1.847(5) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
P32 C47 1.900(5) . ?
P32 C51 1.924(5) . ?
C39 C40 1.536(8) . ?
C39 C42 1.539(7) . ?
C39 C41 1.547(7) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 C46 1.535(8) . ?
C43 C44 1.536(7) . ?
C43 C45 1.539(7) . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 C49 1.526(8) . ?
C47 C48 1.532(7) . ?
C47 C50 1.539(8) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 C54 1.522(7) . ?
C51 C53 1.535(7) . ?
C51 C52 1.538(8) . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 O55 1.063(7) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C25 Rh1 P1 C1 135.2(7) . . . . ?
P2 Rh1 P1 C1 4.94(19) . . . . ?
I1 Rh1 P1 C1 -158.66(19) . . . . ?
C25 Rh1 P1 C13 17.6(7) . . . . ?
P2 Rh1 P1 C13 -112.68(19) . . . . ?
I1 Rh1 P1 C13 83.71(18) . . . . ?
C25 Rh1 P1 C9 -108.6(7) . . . . ?
P2 Rh1 P1 C9 121.1(2) . . . . ?
I1 Rh1 P1 C9 -42.5(2) . . . . ?
C13 P1 C1 C2 62.7(5) . . . . ?
C9 P1 C1 C2 177.0(4) . . . . ?
Rh1 P1 C1 C2 -56.2(5) . . . . ?
P1 C1 C2 C3 79.7(6) . . . . ?
P1 C1 C2 C7 -110.2(5) . . . . ?
C7 C2 C3 C4 -2.2(7) . . . . ?
C1 C2 C3 C4 168.0(5) . . . . ?
C7 C2 C3 C8 -176.0(5) . . . . ?
C1 C2 C3 C8 -5.8(7) . . . . ?
C2 C3 C4 C5 2.6(8) . . . . ?
C8 C3 C4 C5 176.6(5) . . . . ?
C3 C4 C5 C6 -0.8(8) . . . . ?
C4 C5 C6 C7 -1.3(8) . . . . ?
C5 C6 C7 C2 1.6(8) . . . . ?
C3 C2 C7 C6 0.1(8) . . . . ?
C1 C2 C7 C6 -170.4(5) . . . . ?
C2 C3 C8 P2 -79.0(6) . . . . ?
C4 C3 C8 P2 107.2(5) . . . . ?
C3 C8 P2 C17 -64.2(5) . . . . ?
C3 C8 P2 C21 -177.3(4) . . . . ?
C3 C8 P2 Rh1 69.4(5) . . . . ?
C25 Rh1 P2 C8 -179.2(3) . . . . ?
P1 Rh1 P2 C8 -11.0(2) . . . . ?
I1 Rh1 P2 C8 122.0(2) . . . . ?
C25 Rh1 P2 C17 -52.0(3) . . . . ?
P1 Rh1 P2 C17 116.2(2) . . . . ?
I1 Rh1 P2 C17 -110.8(2) . . . . ?
C25 Rh1 P2 C21 72.2(3) . . . . ?
P1 Rh1 P2 C21 -119.56(18) . . . . ?
I1 Rh1 P2 C21 13.4(2) . . . . ?
C1 P1 C9 C12 90.5(4) . . . . ?
C13 P1 C9 C12 -161.3(4) . . . . ?
Rh1 P1 C9 C12 -37.6(4) . . . . ?
C1 P1 C9 C11 -150.5(4) . . . . ?
C13 P1 C9 C11 -42.3(5) . . . . ?
Rh1 P1 C9 C11 81.4(4) . . . . ?
C1 P1 C9 C10 -28.5(4) . . . . ?
C13 P1 C9 C10 79.7(4) . . . . ?
Rh1 P1 C9 C10 -156.6(3) . . . . ?
C1 P1 C13 C15 47.9(4) . . . . ?
C9 P1 C13 C15 -55.2(5) . . . . ?
Rh1 P1 C13 C15 175.1(4) . . . . ?
C1 P1 C13 C16 171.2(4) . . . . ?
C9 P1 C13 C16 68.1(4) . . . . ?
Rh1 P1 C13 C16 -61.6(4) . . . . ?
C1 P1 C13 C14 -73.4(4) . . . . ?
C9 P1 C13 C14 -176.5(4) . . . . ?
Rh1 P1 C13 C14 53.8(4) . . . . ?
C8 P2 C17 C19 -45.4(5) . . . . ?
C21 P2 C17 C19 57.8(5) . . . . ?
Rh1 P2 C17 C19 179.8(4) . . . . ?
C8 P2 C17 C20 -169.3(6) . . . . ?
C21 P2 C17 C20 -66.1(6) . . . . ?
Rh1 P2 C17 C20 55.9(6) . . . . ?
C8 P2 C17 C18 74.6(5) . . . . ?
C21 P2 C17 C18 177.8(4) . . . . ?
Rh1 P2 C17 C18 -60.2(5) . . . . ?
C8 P2 C21 C23 167.2(7) . . . . ?
C17 P2 C21 C23 60.1(8) . . . . ?
Rh1 P2 C21 C23 -68.7(7) . . . . ?
C8 P2 C21 C24 -74.2(5) . . . . ?
C17 P2 C21 C24 178.6(5) . . . . ?
Rh1 P2 C21 C24 49.8(5) . . . . ?
C8 P2 C21 C22 44.1(5) . . . . ?
C17 P2 C21 C22 -63.1(6) . . . . ?
Rh1 P2 C21 C22 168.2(5) . . . . ?
P2 Rh1 C25 O25 162(5) . . . . ?
P1 Rh1 C25 O25 31(5) . . . . ?
I1 Rh1 C25 O25 -37(5) . . . . ?
C55 Rh31 P31 C31 -146.0(9) . . . . ?
P32 Rh31 P31 C31 -4.7(2) . . . . ?
I31 Rh31 P31 C31 161.60(19) . . . . ?
C55 Rh31 P31 C43 -26.7(9) . . . . ?
P32 Rh31 P31 C43 114.54(18) . . . . ?
I31 Rh31 P31 C43 -79.13(18) . . . . ?
C55 Rh31 P31 C39 99.3(9) . . . . ?
P32 Rh31 P31 C39 -119.45(18) . . . . ?
I31 Rh31 P31 C39 46.87(18) . . . . ?
C43 P31 C31 C32 -65.5(5) . . . . ?
C39 P31 C31 C32 -179.7(4) . . . . ?
Rh31 P31 C31 C32 56.7(5) . . . . ?
P31 C31 C32 C37 111.8(5) . . . . ?
P31 C31 C32 C33 -76.0(6) . . . . ?
C37 C32 C33 C34 1.6(7) . . . . ?
C31 C32 C33 C34 -170.7(5) . . . . ?
C37 C32 C33 C38 173.4(5) . . . . ?
C31 C32 C33 C38 1.1(8) . . . . ?
C32 C33 C34 C35 -3.0(8) . . . . ?
C38 C33 C34 C35 -175.0(5) . . . . ?
C33 C34 C35 C36 2.4(9) . . . . ?
C34 C35 C36 C37 -0.4(9) . . . . ?
C35 C36 C37 C32 -1.0(9) . . . . ?
C33 C32 C37 C36 0.3(8) . . . . ?
C31 C32 C37 C36 172.8(5) . . . . ?
C32 C33 C38 P32 81.6(6) . . . . ?
C34 C33 C38 P32 -106.8(5) . . . . ?
C33 C38 P32 C47 63.2(5) . . . . ?
C33 C38 P32 C51 177.7(4) . . . . ?
C33 C38 P32 Rh31 -68.2(5) . . . . ?
C55 Rh31 P32 C38 -178.2(2) . . . . ?
P31 Rh31 P32 C38 9.62(19) . . . . ?
I31 Rh31 P32 C38 -128.6(2) . . . . ?
C55 Rh31 P32 C47 56.2(3) . . . . ?
P31 Rh31 P32 C47 -116.0(2) . . . . ?
I31 Rh31 P32 C47 105.9(2) . . . . ?
C55 Rh31 P32 C51 -68.8(2) . . . . ?
P31 Rh31 P32 C51 119.01(18) . . . . ?
I31 Rh31 P32 C51 -19.2(2) . . . . ?
C31 P31 C39 C40 27.0(4) . . . . ?
C43 P31 C39 C40 -79.9(4) . . . . ?
Rh31 P31 C39 C40 155.5(3) . . . . ?
C31 P31 C39 C42 -90.7(4) . . . . ?
C43 P31 C39 C42 162.3(3) . . . . ?
Rh31 P31 C39 C42 37.7(4) . . . . ?
C31 P31 C39 C41 150.4(4) . . . . ?
C43 P31 C39 C41 43.4(5) . . . . ?
Rh31 P31 C39 C41 -81.2(4) . . . . ?
C31 P31 C43 C46 -174.5(4) . . . . ?
C39 P31 C43 C46 -71.9(4) . . . . ?
Rh31 P31 C43 C46 55.6(4) . . . . ?
C31 P31 C43 C44 69.5(4) . . . . ?
C39 P31 C43 C44 172.1(4) . . . . ?
Rh31 P31 C43 C44 -60.4(4) . . . . ?
C31 P31 C43 C45 -52.1(4) . . . . ?
C39 P31 C43 C45 50.5(5) . . . . ?
Rh31 P31 C43 C45 178.0(3) . . . . ?
C38 P32 C47 C49 50.6(5) . . . . ?
C51 P32 C47 C49 -53.0(5) . . . . ?
Rh31 P32 C47 C49 -175.3(4) . . . . ?
C38 P32 C47 C48 -71.7(4) . . . . ?
C51 P32 C47 C48 -175.3(4) . . . . ?
Rh31 P32 C47 C48 62.4(4) . . . . ?
C38 P32 C47 C50 173.9(4) . . . . ?
C51 P32 C47 C50 70.3(5) . . . . ?
Rh31 P32 C47 C50 -52.0(4) . . . . ?
C38 P32 C51 C54 87.0(4) . . . . ?
C47 P32 C51 C54 -165.7(4) . . . . ?
Rh31 P32 C51 C54 -38.1(4) . . . . ?
C38 P32 C51 C53 -153.8(4) . . . . ?
C47 P32 C51 C53 -46.5(5) . . . . ?
Rh31 P32 C51 C53 81.2(4) . . . . ?
C38 P32 C51 C52 -31.6(4) . . . . ?
C47 P32 C51 C52 75.7(4) . . . . ?
Rh31 P32 C51 C52 -156.7(4) . . . . ?
P32 Rh31 C55 O55 -161(8) . . . . ?
P31 Rh31 C55 O55 -20(8) . . . . ?
I31 Rh31 C55 O55 35(8) . . . . ?
