#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:14:35 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179781 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/77/7007737.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007737
loop_
_publ_author_name
'Antonioli, Bianca'
'Bray, David J.'
'Clegg, Jack K.'
'Gloe, Kerstin'
'Gloe, Karsten'
'Kataeva, Olga'
'Lindoy, Leonard F.'
'McMurtrie, John C.'
'Steel, Peter J.'
'Sumby, Christopher J.'
'Wenzel, Marco'
_publ_section_title
;
 Silver(I) complexation of linked 2,2'-dipyridylamine derivatives.
 Synthetic, solvent extraction, membrane transport and X-ray structural
 studies.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4783
_journal_page_last               4794
_journal_paper_doi               10.1039/b609738c
_journal_year                    2006
_chemical_formula_sum            'C32 H30 Ag Cl N8 O4'
_chemical_formula_weight         733.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.41(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.522(1)
_cell_length_b                   22.118(1)
_cell_length_c                   17.633(1)
_cell_measurement_reflns_used    285
_cell_measurement_temperature    198(2)
_cell_measurement_theta_max      21.29
_cell_measurement_theta_min      3.12
_cell_volume                     3233.0(5)
_computing_cell_refinement
'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction        'EvalCCD (Duisenberg & Schreurs 1990-2000)'
_computing_molecular_graphics    'Schakal-99 (E.Keller 1999)'
_computing_publication_material  'XCIF 6.12 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0380
_diffrn_reflns_av_sigmaI/netI    0.0226
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            73465
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    0.756
_exptl_absorpt_correction_T_max  0.9282
_exptl_absorpt_correction_T_min  0.7885
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS 2.03.(Sheldrick,Bruker AXS Inc.,2002)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1496
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.363
_refine_diff_density_min         -0.377
_refine_diff_density_rms         0.056
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         7770
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0427
_refine_ls_R_factor_gt           0.0266
_refine_ls_shift/su_max          0.042
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0279P)²+1.7272P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0576
_refine_ls_wR_factor_ref         0.0626
_reflns_number_gt                6170
_reflns_number_total             7770
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b609738c.txt
_cod_data_source_block           ab5
_cod_original_cell_volume        3233.0(4)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7007737
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.975316(16) 0.761827(6) 0.053760(8) 0.02951(5) Uani 1 1 d . . .
N1 N 1.19141(17) 0.75460(6) 0.15310(9) 0.0248(3) Uani 1 1 d . . .
C2 C 1.2244(2) 0.69995(9) 0.18677(11) 0.0319(4) Uani 1 1 d . . .
H2 H 1.1714 0.6655 0.1604 0.038 Uiso 1 1 calc R . .
C3 C 1.3313(3) 0.69157(9) 0.25758(12) 0.0378(5) Uani 1 1 d . . .
H3 H 1.3512 0.6524 0.2798 0.045 Uiso 1 1 calc R . .
C4 C 1.4088(3) 0.74172(10) 0.29551(12) 0.0389(5) Uani 1 1 d . . .
H4 H 1.4823 0.7374 0.3447 0.047 Uiso 1 1 calc R . .
C5 C 1.3790(2) 0.79797(9) 0.26163(11) 0.0326(4) Uani 1 1 d . . .
H5 H 1.4323 0.8327 0.2870 0.039 Uiso 1 1 calc R . .
C6 C 1.2691(2) 0.80321(8) 0.18926(10) 0.0235(3) Uani 1 1 d . . .
N7 N 1.23285(16) 0.85963(6) 0.15456(8) 0.0223(3) Uani 1 1 d . . .
C8 C 1.2009(2) 0.86872(8) 0.07320(10) 0.0233(3) Uani 1 1 d . . .
N9 N 1.12204(18) 0.91951(7) 0.04679(9) 0.0285(3) Uani 1 1 d . . .
C10 C 1.0915(2) 0.93007(9) -0.03004(11) 0.0356(4) Uani 1 1 d . . .
H10 H 1.0351 0.9661 -0.0491 0.043 Uiso 1 1 calc R . .
C11 C 1.1366(3) 0.89221(10) -0.08304(11) 0.0414(5) Uani 1 1 d . . .
H11 H 1.1106 0.9013 -0.1372 0.050 Uiso 1 1 calc R . .
C12 C 1.2211(3) 0.84030(10) -0.05487(12) 0.0407(5) Uani 1 1 d . . .
H12 H 1.2553 0.8133 -0.0897 0.049 Uiso 1 1 calc R . .
C13 C 1.2556(2) 0.82797(9) 0.02422(11) 0.0309(4) Uani 1 1 d . . .
H13 H 1.3147 0.7929 0.0447 0.037 Uiso 1 1 calc R . .
C14 C 1.2446(2) 0.91299(8) 0.20467(10) 0.0246(4) Uani 1 1 d . . .
H14A H 1.2237 0.9006 0.2554 0.030 Uiso 1 1 calc R . .
H14B H 1.1591 0.9419 0.1804 0.030 Uiso 1 1 calc R . .
C15 C 1.40605(19) 0.94507(7) 0.21957(9) 0.0206(3) Uani 1 1 d . . .
C16 C 1.53214(19) 0.92484(7) 0.18806(9) 0.0198(3) Uani 1 1 d . . .
H16 H 1.5191 0.8889 0.1578 0.024 Uiso 1 1 calc R . .
C17 C 1.67672(19) 0.95647(7) 0.20024(9) 0.0197(3) Uani 1 1 d . . .
C18 C 1.6945(2) 1.00952(8) 0.24411(10) 0.0241(3) Uani 1 1 d . . .
H18 H 1.7916 1.0322 0.2516 0.029 Uiso 1 1 calc R . .
C19 C 1.5707(2) 1.02916(8) 0.27674(10) 0.0275(4) Uani 1 1 d . . .
H19 H 1.5842 1.0648 0.3076 0.033 Uiso 1 1 calc R . .
C20 C 1.4272(2) 0.99723(8) 0.26468(10) 0.0262(4) Uani 1 1 d . . .
H20 H 1.3429 1.0111 0.2873 0.031 Uiso 1 1 calc R . .
N21 N 0.79111(17) 0.83561(7) 0.00377(8) 0.0248(3) Uani 1 1 d . . .
C22 C 0.7530(2) 0.83908(9) -0.07458(11) 0.0323(4) Uani 1 1 d . . .
H22 H 0.7821 0.8062 -0.1033 0.039 Uiso 1 1 calc R . .
C23 C 0.6747(2) 0.88734(10) -0.11525(11) 0.0378(5) Uani 1 1 d . . .
H23 H 0.6524 0.8885 -0.1706 0.045 Uiso 1 1 calc R . .
C24 C 0.6292(2) 0.93445(10) -0.07318(12) 0.0374(5) Uani 1 1 d . . .
H24 H 0.5750 0.9687 -0.0994 0.045 Uiso 1 1 calc R . .
C25 C 0.6629(2) 0.93122(9) 0.00673(11) 0.0320(4) Uani 1 1 d . . .
H25 H 0.6302 0.9628 0.0362 0.038 Uiso 1 1 calc R . .
C26 C 0.74587(19) 0.88098(8) 0.04434(10) 0.0230(3) Uani 1 1 d . . .
N27 N 0.78952(17) 0.87795(6) 0.12551(8) 0.0226(3) Uani 1 1 d . . .
C28 C 0.8112(2) 0.82257(8) 0.16687(10) 0.0251(4) Uani 1 1 d . . .
N29 N 0.9114(2) 0.82450(7) 0.23703(9) 0.0332(4) Uani 1 1 d . . .
C30 C 0.9380(3) 0.77249(10) 0.27739(12) 0.0428(5) Uani 1 1 d . . .
H30 H 1.0087 0.7733 0.3277 0.051 Uiso 1 1 calc R . .
C31 C 0.8691(3) 0.71834(10) 0.25026(13) 0.0466(6) Uani 1 1 d . . .
H31 H 0.8953 0.6824 0.2799 0.056 Uiso 1 1 calc R . .
C32 C 0.7606(3) 0.71736(10) 0.17878(13) 0.0418(5) Uani 1 1 d . . .
H32 H 0.7084 0.6807 0.1591 0.050 Uiso 1 1 calc R . .
C33 C 0.7286(2) 0.77019(8) 0.13606(12) 0.0321(4) Uani 1 1 d . . .
H33 H 0.6526 0.7709 0.0872 0.039 Uiso 1 1 calc R . .
C34 C 0.8188(2) 0.93415(8) 0.16991(10) 0.0241(3) Uani 1 1 d . . .
H34A H 0.8489 0.9659 0.1363 0.029 Uiso 1 1 calc R . .
H34B H 0.9118 0.9281 0.2147 0.029 Uiso 1 1 calc R . .
N35 N 0.9021(3) 0.68606(9) -0.03056(11) 0.0530(5) Uani 1 1 d . . .
C36 C 0.8517(3) 0.64190(10) -0.05783(11) 0.0387(5) Uani 1 1 d . . .
C37 C 0.7880(3) 0.58549(10) -0.09375(14) 0.0522(6) Uani 1 1 d . . .
H37A H 0.7144 0.5937 -0.1443 0.078 Uiso 1 1 calc R . .
H37B H 0.7293 0.5645 -0.0598 0.078 Uiso 1 1 calc R . .
H37C H 0.8770 0.5600 -0.1015 0.078 Uiso 1 1 calc R . .
Cl1 Cl 1.09854(5) 0.45042(2) -0.13452(3) 0.03319(10) Uani 1 1 d . . .
O1 O 1.0930(2) 0.51425(7) -0.14834(10) 0.0493(4) Uani 1 1 d . . .
O2 O 0.9766(2) 0.43403(9) -0.09493(11) 0.0618(5) Uani 1 1 d . . .
O3 O 1.0690(2) 0.42050(8) -0.20864(10) 0.0597(5) Uani 1 1 d . . .
O4 O 1.25517(18) 0.43383(9) -0.08967(10) 0.0567(5) Uani 1 1 d . . .
N38 N 1.4350(5) 0.69583(15) -0.0188(2) 0.1046(10) Uani 1 1 d . . .
C39 C 1.3929(4) 0.64789(15) -0.01080(17) 0.0656(7) Uani 1 1 d . . .
C40 C 1.3451(4) 0.58623(15) 0.00169(19) 0.0756(9) Uani 1 1 d . . .
H40A H 1.4364 0.5647 0.0346 0.113 Uiso 1 1 calc R . .
H40B H 1.3117 0.5655 -0.0486 0.113 Uiso 1 1 calc R . .
H40C H 1.2549 0.5869 0.0275 0.113 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N35 Ag1 N1 121.40(7) . . ?
N35 Ag1 N21 102.57(7) . . ?
N1 Ag1 N21 135.93(5) . . ?
C6 N1 C2 118.64(16) . . ?
C6 N1 Ag1 122.74(11) . . ?
C2 N1 Ag1 117.37(12) . . ?
N1 C2 C3 123.17(18) . . ?
C2 C3 C4 118.18(19) . . ?
C5 C4 C3 119.71(19) . . ?
C4 C5 C6 119.09(18) . . ?
N1 C6 N7 118.30(15) . . ?
N1 C6 C5 121.17(16) . . ?
N7 C6 C5 120.48(16) . . ?
C6 N7 C8 123.04(14) . . ?
C6 N7 C14 118.69(14) . . ?
C8 N7 C14 117.96(14) . . ?
N9 C8 C13 122.59(16) . . ?
N9 C8 N7 115.90(15) . . ?
C13 C8 N7 121.46(16) . . ?
C8 N9 C10 117.58(17) . . ?
N9 C10 C11 124.22(19) . . ?
C10 C11 C12 117.73(18) . . ?
C13 C12 C11 119.74(19) . . ?
C12 C13 C8 118.10(18) . . ?
N7 C14 C15 114.49(13) . . ?
C20 C15 C16 119.06(15) . . ?
C20 C15 C14 118.67(14) . . ?
C16 C15 C14 122.25(15) . . ?
C17 C16 C15 121.00(15) . . ?
C16 C17 C18 119.19(15) . . ?
C16 C17 C34 122.27(15) . 1_655 ?
C18 C17 C34 118.51(15) . 1_655 ?
C19 C18 C17 120.00(16) . . ?
C18 C19 C20 120.48(16) . . ?
C19 C20 C15 120.25(16) . . ?
C26 N21 C22 118.34(15) . . ?
C26 N21 Ag1 125.71(11) . . ?
C22 N21 Ag1 114.55(12) . . ?
N21 C22 C23 123.63(18) . . ?
C22 C23 C24 117.94(18) . . ?
C25 C24 C23 119.50(18) . . ?
C24 C25 C26 119.35(18) . . ?
N21 C26 N27 118.08(15) . . ?
N21 C26 C25 121.21(16) . . ?
N27 C26 C25 120.67(16) . . ?
C26 N27 C28 122.84(14) . . ?
C26 N27 C34 118.77(14) . . ?
C28 N27 C34 118.36(14) . . ?
N29 C28 C33 122.99(17) . . ?
N29 C28 N27 115.47(16) . . ?
C33 C28 N27 121.52(16) . . ?
C28 N29 C30 117.23(18) . . ?
N29 C30 C31 123.9(2) . . ?
C30 C31 C32 118.3(2) . . ?
C31 C32 C33 119.3(2) . . ?
C32 C33 C28 118.1(2) . . ?
N27 C34 C17 114.57(14) . 1_455 ?
C36 N35 Ag1 162.51(19) . . ?
N35 C36 C37 179.2(2) . . ?
O2 Cl1 O1 109.59(11) . . ?
O2 Cl1 O4 110.86(10) . . ?
O1 Cl1 O4 109.64(10) . . ?
O2 Cl1 O3 109.56(12) . . ?
O1 Cl1 O3 107.93(11) . . ?
O4 Cl1 O3 109.21(11) . . ?
N38 C39 C40 177.7(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N35 2.2311(19) . ?
Ag1 N1 2.2336(15) . ?
Ag1 N21 2.2941(14) . ?
N1 C6 1.343(2) . ?
N1 C2 1.347(2) . ?
C2 C3 1.377(3) . ?
C3 C4 1.382(3) . ?
C4 C5 1.378(3) . ?
C5 C6 1.402(2) . ?
C6 N7 1.393(2) . ?
N7 C8 1.411(2) . ?
N7 C14 1.464(2) . ?
C8 N9 1.336(2) . ?
C8 C13 1.401(3) . ?
N9 C10 1.339(2) . ?
C10 C11 1.374(3) . ?
C11 C12 1.385(3) . ?
C12 C13 1.384(3) . ?
C14 C15 1.516(2) . ?
C15 C20 1.389(2) . ?
C15 C16 1.393(2) . ?
C16 C17 1.390(2) . ?
C17 C18 1.394(2) . ?
C17 C34 1.515(2) 1_655 ?
C18 C19 1.383(2) . ?
C19 C20 1.385(3) . ?
N21 C26 1.340(2) . ?
N21 C22 1.346(2) . ?
C22 C23 1.370(3) . ?
C23 C24 1.386(3) . ?
C24 C25 1.373(3) . ?
C25 C26 1.399(2) . ?
C26 N27 1.394(2) . ?
N27 C28 1.416(2) . ?
N27 C34 1.460(2) . ?
C28 N29 1.331(2) . ?
C28 C33 1.398(3) . ?
N29 C30 1.344(3) . ?
C30 C31 1.370(3) . ?
C31 C32 1.380(3) . ?
C32 C33 1.383(3) . ?
C34 C17 1.515(2) 1_455 ?
N35 C36 1.129(3) . ?
C36 C37 1.447(3) . ?
Cl1 O2 1.4266(16) . ?
Cl1 O1 1.4315(16) . ?
Cl1 O4 1.4326(15) . ?
Cl1 O3 1.4342(17) . ?
N38 C39 1.139(4) . ?
C39 C40 1.455(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N35 Ag1 N1 C6 158.16(13) . . . . ?
N21 Ag1 N1 C6 -17.63(16) . . . . ?
N35 Ag1 N1 C2 -34.83(15) . . . . ?
N21 Ag1 N1 C2 149.39(12) . . . . ?
C6 N1 C2 C3 1.6(3) . . . . ?
Ag1 N1 C2 C3 -165.93(15) . . . . ?
N1 C2 C3 C4 -0.4(3) . . . . ?
C2 C3 C4 C5 -0.7(3) . . . . ?
C3 C4 C5 C6 0.5(3) . . . . ?
C2 N1 C6 N7 -179.23(15) . . . . ?
Ag1 N1 C6 N7 -12.4(2) . . . . ?
C2 N1 C6 C5 -1.8(2) . . . . ?
Ag1 N1 C6 C5 165.04(13) . . . . ?
C4 C5 C6 N1 0.8(3) . . . . ?
C4 C5 C6 N7 178.13(17) . . . . ?
N1 C6 N7 C8 -37.7(2) . . . . ?
C5 C6 N7 C8 144.91(17) . . . . ?
N1 C6 N7 C14 148.92(15) . . . . ?
C5 C6 N7 C14 -28.5(2) . . . . ?
C6 N7 C8 N9 160.44(15) . . . . ?
C14 N7 C8 N9 -26.1(2) . . . . ?
C6 N7 C8 C13 -22.3(2) . . . . ?
C14 N7 C8 C13 151.21(16) . . . . ?
C13 C8 N9 C10 1.9(3) . . . . ?
N7 C8 N9 C10 179.12(15) . . . . ?
C8 N9 C10 C11 -0.2(3) . . . . ?
N9 C10 C11 C12 -1.1(3) . . . . ?
C10 C11 C12 C13 0.7(3) . . . . ?
C11 C12 C13 C8 0.8(3) . . . . ?
N9 C8 C13 C12 -2.2(3) . . . . ?
N7 C8 C13 C12 -179.29(17) . . . . ?
C6 N7 C14 C15 93.20(18) . . . . ?
C8 N7 C14 C15 -80.57(18) . . . . ?
N7 C14 C15 C20 178.18(15) . . . . ?
N7 C14 C15 C16 -0.2(2) . . . . ?
C20 C15 C16 C17 -0.9(2) . . . . ?
C14 C15 C16 C17 177.50(15) . . . . ?
C15 C16 C17 C18 -0.6(2) . . . . ?
C15 C16 C17 C34 177.13(15) . . . 1_655 ?
C16 C17 C18 C19 1.8(2) . . . . ?
C34 C17 C18 C19 -176.01(15) 1_655 . . . ?
C17 C18 C19 C20 -1.5(3) . . . . ?
C18 C19 C20 C15 0.0(3) . . . . ?
C16 C15 C20 C19 1.2(3) . . . . ?
C14 C15 C20 C19 -177.23(16) . . . . ?
N35 Ag1 N21 C26 155.42(14) . . . . ?
N1 Ag1 N21 C26 -28.26(17) . . . . ?
N35 Ag1 N21 C22 -38.45(14) . . . . ?
N1 Ag1 N21 C22 137.86(12) . . . . ?
C26 N21 C22 C23 2.1(3) . . . . ?
Ag1 N21 C22 C23 -165.16(16) . . . . ?
N21 C22 C23 C24 -1.5(3) . . . . ?
C22 C23 C24 C25 -0.2(3) . . . . ?
C23 C24 C25 C26 1.4(3) . . . . ?
C22 N21 C26 N27 -178.26(15) . . . . ?
Ag1 N21 C26 N27 -12.6(2) . . . . ?
C22 N21 C26 C25 -0.8(2) . . . . ?
Ag1 N21 C26 C25 164.86(13) . . . . ?
C24 C25 C26 N21 -0.9(3) . . . . ?
C24 C25 C26 N27 176.50(17) . . . . ?
N21 C26 N27 C28 -29.1(2) . . . . ?
C25 C26 N27 C28 153.40(16) . . . . ?
N21 C26 N27 C34 149.05(15) . . . . ?
C25 C26 N27 C34 -28.4(2) . . . . ?
C26 N27 C28 N29 153.74(15) . . . . ?
C34 N27 C28 N29 -24.4(2) . . . . ?
C26 N27 C28 C33 -27.9(2) . . . . ?
C34 N27 C28 C33 153.90(16) . . . . ?
C33 C28 N29 C30 3.2(3) . . . . ?
N27 C28 N29 C30 -178.53(16) . . . . ?
C28 N29 C30 C31 0.4(3) . . . . ?
N29 C30 C31 C32 -2.9(3) . . . . ?
C30 C31 C32 C33 1.9(3) . . . . ?
C31 C32 C33 C28 1.4(3) . . . . ?
N29 C28 C33 C32 -4.1(3) . . . . ?
N27 C28 C33 C32 177.73(16) . . . . ?
C26 N27 C34 C17 97.33(17) . . . 1_455 ?
C28 N27 C34 C17 -84.42(18) . . . 1_455 ?
N1 Ag1 N35 C36 76.1(7) . . . . ?
N21 Ag1 N35 C36 -106.9(7) . . . . ?
Ag1 N35 C36 C37 -174(100) . . . . ?
