#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:18:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179836 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/32/7013286.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013286
loop_
_publ_author_name
'Hong, Fung-E'
'Chang, Chin-Pei'
'Chang, Yu-Chang'
_publ_section_title
;
 Synthesis and structural characterization of novel palladium complexes
 chelated by bulky cobalt-containing phosphine ligands: unusual
 palladium?cobalt bond formation
;
_journal_issue                   20
_journal_name_full               'Dalton Transactions'
_journal_page_first              3892
_journal_paper_doi               10.1039/b306228g
_journal_year                    2003
_chemical_formula_sum            'C66 H57 Cl6 Co4 O12 P5 Pd'
_chemical_formula_weight         1751.74
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.1480(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.5696(12)
_cell_length_b                   19.5107(13)
_cell_length_c                   23.8716(17)
_cell_measurement_temperature    293(2)
_cell_volume                     7290.4(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0473
_diffrn_reflns_av_sigmaI/netI    0.0590
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            40766
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.38
_exptl_absorpt_coefficient_mu    1.520
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.597
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3502
_exptl_crystal_size_max          0.67
_exptl_crystal_size_mid          0.59
_exptl_crystal_size_min          0.40
_refine_diff_density_max         0.811
_refine_diff_density_min         -0.627
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.906
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     865
_refine_ls_number_reflns         14302
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.906
_refine_ls_R_factor_all          0.0955
_refine_ls_R_factor_gt           0.0494
_refine_ls_shift/su_max          0.394
_refine_ls_shift/su_mean         0.036
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1129P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1409
_refine_ls_wR_factor_ref         0.1732
_reflns_number_gt                8545
_reflns_number_total             14302
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b306228g.txt
_cod_data_source_block           hong140m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7013286
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd Pd 0.49092(3) 0.16797(3) 0.277585(19) 0.05761(15) Uani 1 1 d . . .
Co1 Co 0.88304(4) 0.23704(3) 0.24469(3) 0.04180(18) Uani 1 1 d . . .
Co2 Co 0.99237(4) 0.17655(4) 0.32791(3) 0.0480(2) Uani 1 1 d . . .
Co3 Co 0.67924(4) 0.09402(3) 0.20941(3) 0.04129(18) Uani 1 1 d . . .
Co4 Co 0.65716(4) 0.17333(3) 0.28788(3) 0.03949(17) Uani 1 1 d . . .
P1 P 0.82111(8) 0.06754(7) 0.23821(6) 0.0427(3) Uani 1 1 d . . .
P2 P 0.79156(8) 0.19817(7) 0.34674(6) 0.0419(3) Uani 1 1 d . . .
P3 P 0.74698(8) 0.25241(6) 0.18945(6) 0.0404(3) Uani 1 1 d . . .
P4 P 0.48941(9) 0.17314(7) 0.18533(6) 0.0469(3) Uani 1 1 d . . .
P5 P 1.09973(11) 0.16016(10) 0.29578(10) 0.0747(5) Uani 1 1 d . . .
Cl1 Cl 0.49837(12) 0.15773(10) 0.37875(7) 0.0813(5) Uani 1 1 d . . .
Cl2 Cl 0.34246(11) 0.16171(14) 0.24307(10) 0.1062(7) Uani 1 1 d . . .
O1 O 0.9545(3) 0.2460(3) 0.1477(2) 0.0904(15) Uani 1 1 d . . .
O2 O 0.9314(3) 0.3769(2) 0.2883(2) 0.0831(14) Uani 1 1 d . . .
O3 O 1.0636(4) 0.0760(4) 0.4212(3) 0.136(3) Uani 1 1 d . . .
O4 O 1.0673(4) 0.2944(3) 0.4037(3) 0.123(2) Uani 1 1 d . . .
O5 O 0.6339(4) 0.0572(3) 0.0847(2) 0.0957(16) Uani 1 1 d . . .
O6 O 0.5972(4) -0.0284(3) 0.2368(3) 0.1033(18) Uani 1 1 d . . .
O7 O 0.5937(3) 0.2950(2) 0.33320(19) 0.0663(11) Uani 1 1 d . . .
O8 O 0.6405(3) 0.0508(2) 0.3565(2) 0.0827(14) Uani 1 1 d . . .
O9 O 1.1846(4) 0.1559(6) 0.3475(5) 0.203(5) Uani 1 1 d . . .
O10 O 1.1212(5) 0.2082(5) 0.2533(5) 0.202(5) Uani 1 1 d . . .
O11 O 1.0951(4) 0.0914(4) 0.2613(4) 0.156(3) Uani 1 1 d . . .
C1 C 0.9272(4) 0.2407(3) 0.1858(3) 0.0565(14) Uani 1 1 d . . .
C2 C 0.9099(4) 0.3232(3) 0.2722(3) 0.0546(14) Uani 1 1 d . . .
C3 C 1.0326(4) 0.1135(4) 0.3834(3) 0.083(2) Uani 1 1 d . . .
C4 C 1.0374(4) 0.2485(4) 0.3739(3) 0.0743(19) Uani 1 1 d . . .
C5 C 0.6556(4) 0.0722(3) 0.1325(3) 0.0561(14) Uani 1 1 d . . .
C6 C 0.6310(4) 0.0185(3) 0.2264(3) 0.0608(15) Uani 1 1 d . . .
C7 C 0.6106(3) 0.2446(3) 0.3147(2) 0.0500(13) Uani 1 1 d . . .
C8 C 0.6441(4) 0.0992(3) 0.3310(3) 0.0602(15) Uani 1 1 d . . .
C9 C 0.8831(3) 0.1415(3) 0.2708(2) 0.0424(11) Uani 1 1 d . . .
C10 C 0.8695(3) 0.1851(2) 0.3113(2) 0.0399(11) Uani 1 1 d . . .
C11 C 0.6782(3) 0.1958(2) 0.2123(2) 0.0378(11) Uani 1 1 d . . .
C12 C 0.5997(3) 0.1684(2) 0.1974(2) 0.0396(11) Uani 1 1 d . . .
C13 C 1.2552(9) 0.1497(7) 0.3730(6) 0.209(8) Uani 1 1 d . . .
H13A H 1.2646 0.1549 0.4147 0.313 Uiso 1 1 calc R . .
H13B H 1.2871 0.1839 0.3604 0.313 Uiso 1 1 calc R . .
H13C H 1.2737 0.1050 0.3657 0.313 Uiso 1 1 calc R . .
C14 C 1.1408(8) 0.2755(6) 0.2576(7) 0.217(9) Uani 1 1 d . . .
H14A H 1.1503 0.2905 0.2220 0.325 Uiso 1 1 calc R . .
H14B H 1.1916 0.2829 0.2909 0.325 Uiso 1 1 calc R . .
H14C H 1.0945 0.3011 0.2631 0.325 Uiso 1 1 calc R . .
C15 C 1.1449(6) 0.0701(6) 0.2259(4) 0.130(4) Uani 1 1 d . . .
H15A H 1.1273 0.0250 0.2105 0.195 Uiso 1 1 calc R . .
H15B H 1.2042 0.0692 0.2497 0.195 Uiso 1 1 calc R . .
H15C H 1.1368 0.1016 0.1936 0.195 Uiso 1 1 calc R . .
C16 C 0.8546(3) 0.0359(3) 0.1774(2) 0.0516(13) Uani 1 1 d . . .
C17 C 0.8151(5) -0.0230(3) 0.1484(3) 0.078(2) Uani 1 1 d . . .
H17A H 0.7734 -0.0442 0.1606 0.093 Uiso 1 1 calc R . .
C18 C 0.8364(6) -0.0504(4) 0.1022(4) 0.100(3) Uani 1 1 d . . .
H18A H 0.8092 -0.0899 0.0834 0.120 Uiso 1 1 calc R . .
C19 C 0.8978(6) -0.0197(5) 0.0838(4) 0.101(3) Uani 1 1 d . . .
H19A H 0.9119 -0.0378 0.0522 0.121 Uiso 1 1 calc R . .
C20 C 0.9382(5) 0.0383(5) 0.1126(3) 0.094(2) Uani 1 1 d . . .
H20A H 0.9804 0.0592 0.1008 0.113 Uiso 1 1 calc R . .
C21 C 0.9159(4) 0.0656(3) 0.1596(3) 0.0648(16) Uani 1 1 d . . .
H21A H 0.9435 0.1047 0.1789 0.078 Uiso 1 1 calc R . .
C22 C 0.8647(4) -0.0013(3) 0.2917(2) 0.0500(13) Uani 1 1 d . . .
C23 C 0.8207(4) -0.0300(4) 0.3252(3) 0.0766(19) Uani 1 1 d . . .
H23A H 0.7659 -0.0146 0.3208 0.092 Uiso 1 1 calc R . .
C24 C 0.8566(6) -0.0820(4) 0.3660(4) 0.100(3) Uani 1 1 d . . .
H24A H 0.8252 -0.1013 0.3880 0.120 Uiso 1 1 calc R . .
C25 C 0.9364(5) -0.1043(4) 0.3737(4) 0.089(2) Uani 1 1 d . . .
H25A H 0.9606 -0.1384 0.4013 0.107 Uiso 1 1 calc R . .
C26 C 0.9818(5) -0.0765(4) 0.3407(4) 0.090(2) Uani 1 1 d . . .
H26A H 1.0365 -0.0924 0.3452 0.108 Uiso 1 1 calc R . .
C27 C 0.9467(4) -0.0252(3) 0.3007(3) 0.0688(17) Uani 1 1 d . . .
H27A H 0.9787 -0.0061 0.2792 0.083 Uiso 1 1 calc R . .
C28 C 0.8148(4) 0.1451(3) 0.4139(2) 0.0519(13) Uani 1 1 d . . .
C29 C 0.7699(5) 0.1602(4) 0.4524(3) 0.083(2) Uani 1 1 d . . .
H29A H 0.7332 0.1976 0.4450 0.099 Uiso 1 1 calc R . .
C30 C 0.7798(6) 0.1198(5) 0.5014(3) 0.104(3) Uani 1 1 d . . .
H30A H 0.7488 0.1299 0.5266 0.124 Uiso 1 1 calc R . .
C31 C 0.8325(6) 0.0668(5) 0.5133(3) 0.100(3) Uani 1 1 d . . .
H31A H 0.8401 0.0406 0.5471 0.120 Uiso 1 1 calc R . .
C32 C 0.8757(5) 0.0511(4) 0.4752(4) 0.103(3) Uani 1 1 d . . .
H32A H 0.9121 0.0134 0.4832 0.124 Uiso 1 1 calc R . .
C33 C 0.8667(4) 0.0899(3) 0.4251(3) 0.0679(17) Uani 1 1 d . . .
H33A H 0.8961 0.0781 0.3994 0.081 Uiso 1 1 calc R . .
C34 C 0.8181(3) 0.2839(3) 0.3786(2) 0.0524(14) Uani 1 1 d . . .
C35 C 0.7808(4) 0.3419(3) 0.3477(3) 0.0629(16) Uani 1 1 d . . .
H35A H 0.7375 0.3371 0.3114 0.076 Uiso 1 1 calc R . .
C36 C 0.8061(5) 0.4061(3) 0.3692(4) 0.083(2) Uani 1 1 d . . .
H36A H 0.7807 0.4445 0.3475 0.100 Uiso 1 1 calc R . .
C37 C 0.8695(6) 0.4135(5) 0.4235(5) 0.107(3) Uani 1 1 d . . .
H37A H 0.8862 0.4570 0.4389 0.129 Uiso 1 1 calc R . .
C38 C 0.9087(6) 0.3552(5) 0.4553(4) 0.108(3) Uani 1 1 d . . .
H38A H 0.9524 0.3601 0.4913 0.130 Uiso 1 1 calc R . .
C39 C 0.8827(4) 0.2907(4) 0.4334(3) 0.081(2) Uani 1 1 d . . .
H39A H 0.9079 0.2520 0.4548 0.097 Uiso 1 1 calc R . .
C40 C 0.7155(3) 0.2336(3) 0.1095(2) 0.0494(13) Uani 1 1 d . . .
C41 C 0.6452(4) 0.2666(4) 0.0696(3) 0.0734(18) Uani 1 1 d . . .
H41A H 0.6164 0.3004 0.0829 0.088 Uiso 1 1 calc R . .
C42 C 0.6183(6) 0.2490(5) 0.0099(3) 0.100(3) Uani 1 1 d . . .
H42A H 0.5712 0.2704 -0.0168 0.119 Uiso 1 1 calc R . .
C43 C 0.6625(6) 0.1994(4) -0.0089(3) 0.089(3) Uani 1 1 d . . .
H43A H 0.6444 0.1870 -0.0488 0.106 Uiso 1 1 calc R . .
C44 C 0.7319(5) 0.1682(4) 0.0293(3) 0.081(2) Uani 1 1 d . . .
H44A H 0.7616 0.1353 0.0156 0.098 Uiso 1 1 calc R . .
C45 C 0.7585(4) 0.1853(3) 0.0889(3) 0.0624(16) Uani 1 1 d . . .
H45A H 0.8060 0.1637 0.1151 0.075 Uiso 1 1 calc R . .
C46 C 0.7052(4) 0.3396(3) 0.1874(2) 0.0517(14) Uani 1 1 d . . .
C47 C 0.6319(4) 0.3552(3) 0.2002(3) 0.0603(15) Uani 1 1 d . . .
H47A H 0.6017 0.3205 0.2112 0.072 Uiso 1 1 calc R . .
C48 C 0.6029(5) 0.4221(4) 0.1968(3) 0.080(2) Uani 1 1 d . . .
H48A H 0.5536 0.4326 0.2056 0.096 Uiso 1 1 calc R . .
C49 C 0.6474(6) 0.4722(4) 0.1803(4) 0.103(3) Uani 1 1 d . . .
H49A H 0.6282 0.5172 0.1781 0.124 Uiso 1 1 calc R . .
C50 C 0.7192(6) 0.4579(4) 0.1668(4) 0.099(3) Uani 1 1 d . . .
H50A H 0.7480 0.4930 0.1550 0.119 Uiso 1 1 calc R . .
C51 C 0.7498(5) 0.3915(3) 0.1707(3) 0.0728(18) Uani 1 1 d . . .
H51A H 0.7996 0.3818 0.1623 0.087 Uiso 1 1 calc R . .
C52 C 0.4422(4) 0.0998(3) 0.1396(3) 0.0654(17) Uani 1 1 d . . .
C53 C 0.4180(5) 0.0437(4) 0.1651(4) 0.103(3) Uani 1 1 d . . .
H53A H 0.4204 0.0458 0.2046 0.123 Uiso 1 1 calc R . .
C54 C 0.3904(7) -0.0154(5) 0.1332(7) 0.147(5) Uani 1 1 d . . .
H54A H 0.3788 -0.0545 0.1515 0.176 Uiso 1 1 calc R . .
C55 C 0.3805(8) -0.0153(7) 0.0739(7) 0.164(6) Uani 1 1 d . . .
H55A H 0.3579 -0.0537 0.0511 0.197 Uiso 1 1 calc R . .
C56 C 0.4026(10) 0.0387(6) 0.0488(5) 0.182(7) Uani 1 1 d . . .
H56A H 0.3966 0.0374 0.0087 0.218 Uiso 1 1 calc R . .
C57 C 0.4347(7) 0.0974(4) 0.0815(4) 0.126(4) Uani 1 1 d . . .
H57A H 0.4509 0.1348 0.0635 0.152 Uiso 1 1 calc R . .
C58 C 0.4448(3) 0.2514(3) 0.1464(3) 0.0567(15) Uani 1 1 d . . .
C59 C 0.4063(5) 0.2983(4) 0.1735(4) 0.088(2) Uani 1 1 d . . .
H59A H 0.4028 0.2892 0.2109 0.106 Uiso 1 1 calc R . .
C60 C 0.3732(6) 0.3589(5) 0.1441(6) 0.128(4) Uani 1 1 d . . .
H60A H 0.3479 0.3904 0.1625 0.154 Uiso 1 1 calc R . .
C61 C 0.3767(7) 0.3733(6) 0.0900(6) 0.133(4) Uani 1 1 d . . .
H61A H 0.3522 0.4134 0.0708 0.159 Uiso 1 1 calc R . .
C62 C 0.4160(8) 0.3290(5) 0.0630(5) 0.129(4) Uani 1 1 d . . .
H62A H 0.4202 0.3394 0.0261 0.155 Uiso 1 1 calc R . .
C63 C 0.4505(5) 0.2669(4) 0.0921(3) 0.086(2) Uani 1 1 d . . .
H63A H 0.4773 0.2365 0.0739 0.104 Uiso 1 1 calc R . .
C100 C 0.598(2) -0.1891(17) 0.1152(11) 0.481(7) Uani 1 1 d . . .
Cl3 Cl 0.6381(7) -0.1521(4) 0.1766(4) 0.198(3) Uani 0.60 1 d P . .
Cl3' Cl 0.5649(10) -0.1172(7) 0.1061(11) 0.252(8) Uani 0.40 1 d P . .
Cl4 Cl 0.5952(19) -0.1483(16) 0.0626(10) 0.191(9) Uani 0.20 1 d P . .
Cl4' Cl 0.6578(5) -0.1919(3) 0.0634(3) 0.208(3) Uani 0.80 1 d P . .
C101 C 1.2143(9) 0.2986(10) 0.5685(12) 0.367(19) Uani 1 1 d . . .
H10A H 1.2361 0.2913 0.5359 0.441 Uiso 1 1 calc R . .
H10B H 1.2593 0.2893 0.6057 0.441 Uiso 1 1 calc R . .
Cl5 Cl 1.1707(4) 0.3882(3) 0.5672(2) 0.267(3) Uani 1 1 d . . .
Cl6 Cl 1.1396(7) 0.2568(4) 0.5622(4) 0.498(9) Uani 1 1 d . . .
C102 C 0.531(3) 0.0242(13) 0.4872(14) 0.321(17) Uani 1 1 d . . .
O101 O 0.5919(8) 0.0135(8) 0.5168(4) 0.189(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P4 Pd Cl2 89.10(7) . . ?
P4 Pd Cl1 176.92(7) . . ?
Cl2 Pd Cl1 92.97(7) . . ?
P4 Pd C7 94.46(13) . . ?
Cl2 Pd C7 144.11(15) . . ?
Cl1 Pd C7 85.20(13) . . ?
P4 Pd Co4 76.35(4) . . ?
Cl2 Pd Co4 165.39(6) . . ?
Cl1 Pd Co4 101.52(5) . . ?
C7 Pd Co4 41.08(14) . . ?
C1 Co1 C2 97.6(3) . . ?
C1 Co1 C10 147.6(2) . . ?
C2 Co1 C10 105.5(2) . . ?
C1 Co1 C9 109.2(2) . . ?
C2 Co1 C9 142.5(2) . . ?
C10 Co1 C9 40.6(2) . . ?
C1 Co1 P3 97.19(19) . . ?
C2 Co1 P3 99.84(19) . . ?
C10 Co1 P3 100.76(15) . . ?
C9 Co1 P3 102.17(14) . . ?
C1 Co1 Co2 105.46(19) . . ?
C2 Co1 Co2 97.03(18) . . ?
C10 Co1 Co2 50.05(14) . . ?
C9 Co1 Co2 51.38(14) . . ?
P3 Co1 Co2 149.57(5) . . ?
C3 Co2 C4 96.2(4) . . ?
C3 Co2 C10 108.8(3) . . ?
C4 Co2 C10 104.8(3) . . ?
C3 Co2 C9 107.9(3) . . ?
C4 Co2 C9 142.3(3) . . ?
C10 Co2 C9 40.4(2) . . ?
C3 Co2 P5 90.6(2) . . ?
C4 Co2 P5 96.1(2) . . ?
C10 Co2 P5 149.29(16) . . ?
C9 Co2 P5 111.79(16) . . ?
C3 Co2 Co1 156.8(2) . . ?
C4 Co2 Co1 99.5(2) . . ?
C10 Co2 Co1 50.41(14) . . ?
C9 Co2 Co1 50.30(14) . . ?
P5 Co2 Co1 104.59(6) . . ?
C6 Co3 C5 94.2(3) . . ?
C6 Co3 C12 108.7(2) . . ?
C5 Co3 C12 96.7(2) . . ?
C6 Co3 C11 143.8(2) . . ?
C5 Co3 C11 105.7(2) . . ?
C12 Co3 C11 40.1(2) . . ?
C6 Co3 P1 103.8(2) . . ?
C5 Co3 P1 96.40(19) . . ?
C12 Co3 P1 143.70(15) . . ?
C11 Co3 P1 103.62(14) . . ?
C6 Co3 Co4 98.7(2) . . ?
C5 Co3 Co4 149.20(19) . . ?
C12 Co3 Co4 52.61(14) . . ?
C11 Co3 Co4 50.37(14) . . ?
P1 Co3 Co4 107.36(4) . . ?
C7 Co4 C8 105.4(3) . . ?
C7 Co4 C11 111.9(2) . . ?
C8 Co4 C11 140.4(2) . . ?
C7 Co4 C12 107.7(2) . . ?
C8 Co4 C12 117.0(2) . . ?
C11 Co4 C12 38.63(19) . . ?
C7 Co4 P2 93.58(18) . . ?
C8 Co4 P2 95.40(19) . . ?
C11 Co4 P2 94.94(14) . . ?
C12 Co4 P2 133.19(14) . . ?
C7 Co4 Co3 155.47(17) . . ?
C8 Co4 Co3 90.29(19) . . ?
C11 Co4 Co3 50.09(14) . . ?
C12 Co4 Co3 47.79(13) . . ?
P2 Co4 Co3 103.74(4) . . ?
C7 Co4 Pd 61.20(18) . . ?
C8 Co4 Pd 73.36(19) . . ?
C11 Co4 Pd 113.84(14) . . ?
C12 Co4 Pd 78.16(14) . . ?
P2 Co4 Pd 146.76(5) . . ?
Co3 Co4 Pd 107.42(3) . . ?
C9 P1 C22 104.4(2) . . ?
C9 P1 C16 109.7(3) . . ?
C22 P1 C16 98.8(3) . . ?
C9 P1 Co3 109.62(17) . . ?
C22 P1 Co3 120.55(19) . . ?
C16 P1 Co3 112.92(18) . . ?
C10 P2 C34 102.5(2) . . ?
C10 P2 C28 110.9(2) . . ?
C34 P2 C28 101.5(3) . . ?
C10 P2 Co4 113.22(17) . . ?
C34 P2 Co4 120.48(18) . . ?
C28 P2 Co4 107.62(19) . . ?
C11 P3 C46 107.9(2) . . ?
C11 P3 C40 101.5(2) . . ?
C46 P3 C40 100.4(2) . . ?
C11 P3 Co1 110.91(16) . . ?
C46 P3 Co1 116.17(18) . . ?
C40 P3 Co1 118.32(19) . . ?
C12 P4 C52 106.1(3) . . ?
C12 P4 C58 110.8(3) . . ?
C52 P4 C58 109.5(3) . . ?
C12 P4 Pd 99.45(16) . . ?
C52 P4 Pd 115.3(2) . . ?
C58 P4 Pd 114.9(2) . . ?
O10 P5 O11 99.3(6) . . ?
O10 P5 O9 102.6(6) . . ?
O11 P5 O9 104.5(5) . . ?
O10 P5 Co2 123.1(3) . . ?
O11 P5 Co2 114.0(2) . . ?
O9 P5 Co2 111.3(4) . . ?
C13 O9 P5 161.2(14) . . ?
C14 O10 P5 131.1(12) . . ?
C15 O11 P5 128.8(7) . . ?
O1 C1 Co1 176.9(6) . . ?
O2 C2 Co1 175.4(6) . . ?
O3 C3 Co2 174.8(7) . . ?
O4 C4 Co2 179.3(8) . . ?
O5 C5 Co3 173.8(6) . . ?
O6 C6 Co3 177.4(6) . . ?
O7 C7 Co4 168.8(5) . . ?
O7 C7 Pd 113.4(4) . . ?
Co4 C7 Pd 77.7(2) . . ?
O8 C8 Co4 174.9(6) . . ?
C10 C9 P1 127.2(4) . . ?
C10 C9 Co1 69.5(3) . . ?
P1 C9 Co1 133.2(3) . . ?
C10 C9 Co2 68.0(3) . . ?
P1 C9 Co2 146.5(3) . . ?
Co1 C9 Co2 78.32(18) . . ?
C9 C10 P2 138.0(4) . . ?
C9 C10 Co2 71.6(3) . . ?
P2 C10 Co2 142.0(3) . . ?
C9 C10 Co1 69.9(3) . . ?
P2 C10 Co1 127.3(3) . . ?
Co2 C10 Co1 79.55(19) . . ?
C12 C11 P3 145.1(4) . . ?
C12 C11 Co3 67.2(3) . . ?
P3 C11 Co3 126.2(3) . . ?
C12 C11 Co4 73.2(3) . . ?
P3 C11 Co4 136.6(3) . . ?
Co3 C11 Co4 79.53(17) . . ?
C11 C12 P4 152.7(4) . . ?
C11 C12 Co3 72.7(3) . . ?
P4 C12 Co3 133.7(3) . . ?
C11 C12 Co4 68.2(3) . . ?
P4 C12 Co4 105.5(2) . . ?
Co3 C12 Co4 79.60(17) . . ?
C21 C16 C17 118.6(6) . . ?
C21 C16 P1 124.1(4) . . ?
C17 C16 P1 117.3(5) . . ?
C18 C17 C16 121.3(7) . . ?
C17 C18 C19 120.1(8) . . ?
C18 C19 C20 119.2(7) . . ?
C19 C20 C21 120.0(8) . . ?
C16 C21 C20 120.8(7) . . ?
C23 C22 C27 117.0(5) . . ?
C23 C22 P1 123.0(5) . . ?
C27 C22 P1 119.9(4) . . ?
C22 C23 C24 121.3(7) . . ?
C25 C24 C23 120.2(7) . . ?
C24 C25 C26 119.7(7) . . ?
C25 C26 C27 120.1(7) . . ?
C22 C27 C26 121.7(6) . . ?
C33 C28 C29 118.9(5) . . ?
C33 C28 P2 124.0(5) . . ?
C29 C28 P2 116.9(4) . . ?
C30 C29 C28 120.1(6) . . ?
C31 C30 C29 121.0(7) . . ?
C30 C31 C32 119.1(7) . . ?
C33 C32 C31 121.6(7) . . ?
C28 C33 C32 119.3(6) . . ?
C35 C34 C39 119.6(6) . . ?
C35 C34 P2 121.4(4) . . ?
C39 C34 P2 118.7(5) . . ?
C34 C35 C36 121.4(6) . . ?
C37 C36 C35 119.6(8) . . ?
C36 C37 C38 119.8(7) . . ?
C37 C38 C39 120.3(7) . . ?
C34 C39 C38 119.3(7) . . ?
C45 C40 C41 119.2(5) . . ?
C45 C40 P3 120.4(4) . . ?
C41 C40 P3 120.3(5) . . ?
C40 C41 C42 120.1(7) . . ?
C43 C42 C41 118.9(7) . . ?
C44 C43 C42 121.3(7) . . ?
C43 C44 C45 119.9(7) . . ?
C40 C45 C44 120.5(6) . . ?
C47 C46 C51 119.5(6) . . ?
C47 C46 P3 123.5(4) . . ?
C51 C46 P3 117.0(5) . . ?
C46 C47 C48 120.7(6) . . ?
C49 C48 C47 119.0(8) . . ?
C50 C49 C48 121.5(7) . . ?
C49 C50 C51 120.4(8) . . ?
C50 C51 C46 119.0(7) . . ?
C57 C52 C53 119.0(7) . . ?
C57 C52 P4 121.4(6) . . ?
C53 C52 P4 119.5(6) . . ?
C54 C53 C52 121.0(10) . . ?
C53 C54 C55 118.4(11) . . ?
C56 C55 C54 120.8(11) . . ?
C55 C56 C57 120.9(12) . . ?
C52 C57 C56 119.6(10) . . ?
C63 C58 C59 118.8(7) . . ?
C63 C58 P4 122.0(5) . . ?
C59 C58 P4 119.2(5) . . ?
C60 C59 C58 119.3(8) . . ?
C59 C60 C61 121.8(9) . . ?
C60 C61 C62 120.1(10) . . ?
C61 C62 C63 119.3(10) . . ?
C58 C63 C62 120.7(8) . . ?
Cl4 C100 Cl3 115.4(19) . . ?
Cl4 C100 Cl3' 58(2) . . ?
Cl3 C100 Cl3' 74.2(16) . . ?
Cl4 C100 Cl4' 46.3(15) . . ?
Cl3 C100 Cl4' 118.9(14) . . ?
Cl3' C100 Cl4' 100.5(16) . . ?
C100 Cl3 Cl3' 50.9(17) . . ?
Cl4 Cl3' C100 60.7(14) . . ?
Cl4 Cl3' Cl3 102.9(16) . . ?
C100 Cl3' Cl3 54.9(13) . . ?
Cl4' Cl4 Cl3' 136(2) . . ?
Cl4' Cl4 C100 81(3) . . ?
Cl3' Cl4 C100 61.8(19) . . ?
Cl4 Cl4' C100 52.9(17) . . ?
Cl6 C101 Cl5 102.1(12) . . ?
O101 C102 C102 102(3) . 3_656 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd P4 2.1966(15) . ?
Pd Cl2 2.3270(18) . ?
Pd Cl1 2.3857(17) . ?
Pd C7 2.409(6) . ?
Pd Co4 2.6861(8) . ?
Co1 C1 1.786(6) . ?
Co1 C2 1.806(6) . ?
Co1 C10 1.961(5) . ?
Co1 C9 1.966(5) . ?
Co1 P3 2.2274(14) . ?
Co1 Co2 2.5020(10) . ?
Co2 C3 1.769(7) . ?
Co2 C4 1.787(7) . ?
Co2 C10 1.950(5) . ?
Co2 C9 1.996(5) . ?
Co2 P5 2.1794(19) . ?
Co3 C6 1.785(6) . ?
Co3 C5 1.798(6) . ?
Co3 C12 1.918(5) . ?
Co3 C11 1.987(5) . ?
Co3 P1 2.2816(15) . ?
Co3 Co4 2.5468(9) . ?
Co4 C7 1.806(6) . ?
Co4 C8 1.828(7) . ?
Co4 C11 1.995(5) . ?
Co4 C12 2.057(5) . ?
Co4 P2 2.2618(15) . ?
P1 C9 1.794(5) . ?
P1 C22 1.830(5) . ?
P1 C16 1.824(5) . ?
P2 C10 1.778(5) . ?
P2 C34 1.831(6) . ?
P2 C28 1.841(5) . ?
P3 C11 1.796(5) . ?
P3 C46 1.830(5) . ?
P3 C40 1.843(5) . ?
P4 C12 1.757(5) . ?
P4 C52 1.813(6) . ?
P4 C58 1.813(6) . ?
P5 O10 1.507(8) . ?
P5 O11 1.562(7) . ?
P5 O9 1.540(9) . ?
O1 C1 1.146(7) . ?
O2 C2 1.131(6) . ?
O3 C3 1.145(7) . ?
O4 C4 1.150(8) . ?
O5 C5 1.117(6) . ?
O6 C6 1.141(7) . ?
O7 C7 1.149(6) . ?
O8 C8 1.136(7) . ?
O9 C13 1.134(13) . ?
O10 C14 1.349(14) . ?
O11 C15 1.423(9) . ?
C9 C10 1.362(7) . ?
C11 C12 1.341(7) . ?
C16 C21 1.352(8) . ?
C16 C17 1.390(8) . ?
C17 C18 1.371(10) . ?
C18 C19 1.372(12) . ?
C19 C20 1.379(11) . ?
C20 C21 1.397(9) . ?
C22 C23 1.367(8) . ?
C22 C27 1.384(8) . ?
C23 C24 1.397(9) . ?
C24 C25 1.347(11) . ?
C25 C26 1.367(10) . ?
C26 C27 1.373(9) . ?
C28 C33 1.349(8) . ?
C28 C29 1.390(8) . ?
C29 C30 1.375(9) . ?
C30 C31 1.324(10) . ?
C31 C32 1.362(10) . ?
C32 C33 1.381(9) . ?
C34 C35 1.381(8) . ?
C34 C39 1.399(8) . ?
C35 C36 1.367(8) . ?
C36 C37 1.383(11) . ?
C37 C38 1.403(12) . ?
C38 C39 1.377(10) . ?
C40 C45 1.368(8) . ?
C40 C41 1.396(8) . ?
C41 C42 1.388(9) . ?
C42 C43 1.375(12) . ?
C43 C44 1.357(11) . ?
C44 C45 1.383(8) . ?
C46 C47 1.380(8) . ?
C46 C51 1.387(8) . ?
C47 C48 1.384(8) . ?
C48 C49 1.359(11) . ?
C49 C50 1.359(12) . ?
C50 C51 1.384(10) . ?
C52 C57 1.352(10) . ?
C52 C53 1.374(10) . ?
C53 C54 1.375(13) . ?
C54 C55 1.370(17) . ?
C55 C56 1.322(18) . ?
C56 C57 1.389(12) . ?
C58 C63 1.366(9) . ?
C58 C59 1.391(9) . ?
C59 C60 1.394(12) . ?
C60 C61 1.342(14) . ?
C61 C62 1.363(14) . ?
C62 C63 1.420(11) . ?
C100 Cl4 1.48(3) . ?
C100 Cl3 1.57(2) . ?
C100 Cl3' 1.49(4) . ?
C100 Cl4' 1.83(3) . ?
Cl3 Cl3' 1.85(2) . ?
Cl3' Cl4 1.43(3) . ?
Cl4 Cl4' 1.34(3) . ?
C101 Cl6 1.449(16) . ?
C101 Cl5 1.89(2) . ?
C102 O101 1.05(4) . ?
C102 C102 1.65(5) 3_656 ?
