#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:23:34 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179841 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/37/7013795.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013795
loop_
_publ_author_name
'Pechmann, Thomas'
'Brandt, Carsten D.'
'Werner, Helmut'
_publ_section_title
;
 Extending the coordination capabilities of tertiary phosphines and
 arsines: preparation, molecular structure, and reactivity of dinuclear
 rhodium complexes with PR3 and AsR3 in a doubly bridging coordination
 mode.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              959
_journal_page_last               966
_journal_paper_doi               10.1039/b314734g
_journal_year                    2004
_chemical_formula_sum            'C70 H70 As2 Cl4 Rh4'
_chemical_formula_weight         1614.54
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.535(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.4012(13)
_cell_length_b                   15.2521(9)
_cell_length_c                   19.4838(11)
_cell_measurement_reflns_used    8282
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.146
_cell_measurement_theta_min      2.292
_cell_volume                     6498.3(7)
_computing_cell_refinement       'SAINT-NT V6.0'
_computing_data_collection       'SMART-NT V5.6'
_computing_data_reduction        'SAINT-NT V6.0'
_computing_molecular_graphics    'XSHELL in SHELXTL-97'
_computing_publication_material  'XSHELL in SHELXTL-97'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.926
_diffrn_measured_fraction_theta_max 0.926
_diffrn_measurement_device_type  'Bruker Smart apex with D8-Goniometer'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0154
_diffrn_reflns_av_sigmaI/netI    0.0131
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            35365
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    2.214
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS2.0 (Sheldrick 2000)'
_exptl_crystal_colour            red-brown
_exptl_crystal_density_diffrn    1.650
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3216
_exptl_crystal_size_max          0.67
_exptl_crystal_size_mid          0.66
_exptl_crystal_size_min          0.63
_refine_diff_density_max         0.664
_refine_diff_density_min         -0.356
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     727
_refine_ls_number_reflns         10588
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0246
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0280P)²+3.5946P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0531
_refine_ls_wR_factor_ref         0.0540
_reflns_number_gt                9823
_reflns_number_total             10588
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b314734g.txt
_cod_data_source_block           tp5neu
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7013795
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.46517(11) 0.14734(14) 0.34690(11) 0.0308(5) Uani 1 1 d . . .
C2 C 0.45556(11) 0.23949(14) 0.37010(12) 0.0334(5) Uani 1 1 d . . .
C3 C 0.47346(14) 0.26685(17) 0.43915(14) 0.0490(7) Uani 1 1 d . . .
H3 H 0.4931 0.2268 0.4742 0.059 Uiso 1 1 calc R . .
C4 C 0.46292(16) 0.35297(19) 0.45770(17) 0.0633(9) Uani 1 1 d . . .
H4 H 0.4751 0.3706 0.5055 0.076 Uiso 1 1 calc R . .
C5 C 0.43563(15) 0.41190(17) 0.40867(18) 0.0593(9) Uani 1 1 d . . .
H5 H 0.4290 0.4704 0.4219 0.071 Uiso 1 1 calc R . .
C6 C 0.41762(14) 0.38616(17) 0.33950(17) 0.0539(8) Uani 1 1 d . . .
H6 H 0.3985 0.4271 0.3049 0.065 Uiso 1 1 calc R . .
C7 C 0.42726(12) 0.30086(16) 0.32028(14) 0.0426(6) Uani 1 1 d . . .
H7 H 0.4144 0.2837 0.2725 0.051 Uiso 1 1 calc R . .
C8 C 0.51732(12) 0.14024(14) 0.30865(13) 0.0373(6) Uani 1 1 d . . .
C9 C 0.57792(13) 0.14862(19) 0.34570(16) 0.0527(7) Uani 1 1 d . . .
H9 H 0.5866 0.1625 0.3944 0.063 Uiso 1 1 calc R . .
C10 C 0.62574(15) 0.1366(2) 0.3110(2) 0.0702(10) Uani 1 1 d . . .
H10 H 0.6669 0.1396 0.3369 0.084 Uiso 1 1 calc R . .
C11 C 0.61404(19) 0.1203(2) 0.2400(2) 0.0735(11) Uani 1 1 d . . .
H11 H 0.6469 0.1115 0.2171 0.088 Uiso 1 1 calc R . .
C12 C 0.55499(19) 0.11694(18) 0.20248(18) 0.0653(10) Uani 1 1 d . . .
H12 H 0.5469 0.1078 0.1531 0.078 Uiso 1 1 calc R . .
C13 C 0.50627(14) 0.12683(16) 0.23637(14) 0.0480(7) Uani 1 1 d . . .
H13 H 0.4654 0.1244 0.2098 0.058 Uiso 1 1 calc R . .
C14 C 0.36068(11) 0.07002(14) 0.38380(11) 0.0294(5) Uani 1 1 d . . .
C15 C 0.34646(10) 0.14936(14) 0.42348(12) 0.0306(5) Uani 1 1 d . . .
C16 C 0.31134(11) 0.21828(15) 0.38915(13) 0.0383(6) Uani 1 1 d . . .
H16 H 0.2969 0.2167 0.3396 0.046 Uiso 1 1 calc R . .
C17 C 0.29743(13) 0.28917(17) 0.42735(15) 0.0491(7) Uani 1 1 d . . .
H17 H 0.2734 0.3358 0.4036 0.059 Uiso 1 1 calc R . .
C18 C 0.31804(14) 0.29295(16) 0.49946(15) 0.0494(7) Uani 1 1 d . . .
H18 H 0.3083 0.3420 0.5250 0.059 Uiso 1 1 calc R . .
C19 C 0.35259(13) 0.22563(17) 0.53406(14) 0.0475(7) Uani 1 1 d . . .
H19 H 0.3671 0.2282 0.5836 0.057 Uiso 1 1 calc R . .
C20 C 0.36634(12) 0.15384(16) 0.49667(13) 0.0426(6) Uani 1 1 d . . .
H20 H 0.3896 0.1069 0.5211 0.051 Uiso 1 1 calc R . .
C21 C 0.31224(11) -0.00010(15) 0.37724(14) 0.0374(6) Uani 1 1 d . . .
C22 C 0.28178(13) -0.03089(18) 0.31142(16) 0.0517(7) Uani 1 1 d . . .
H22 H 0.2924 -0.0089 0.2700 0.062 Uiso 1 1 calc R . .
C23 C 0.23575(15) -0.0938(2) 0.3062(2) 0.0678(10) Uani 1 1 d . . .
H23 H 0.2152 -0.1140 0.2611 0.081 Uiso 1 1 calc R . .
C24 C 0.21987(15) -0.1267(2) 0.3649(2) 0.0721(10) Uani 1 1 d . . .
H24 H 0.1891 -0.1704 0.3608 0.087 Uiso 1 1 calc R . .
C25 C 0.24880(15) -0.0961(2) 0.4303(2) 0.0658(9) Uani 1 1 d . . .
H25 H 0.2375 -0.1185 0.4713 0.079 Uiso 1 1 calc R . .
C26 C 0.29420(12) -0.03308(17) 0.43675(16) 0.0475(7) Uani 1 1 d . . .
H26 H 0.3133 -0.0119 0.4821 0.057 Uiso 1 1 calc R . .
C27 C 0.53196(14) -0.0841(2) 0.33160(15) 0.0580(8) Uani 1 1 d . . .
H27A H 0.5504 -0.0821 0.3820 0.087 Uiso 1 1 calc R . .
H27B H 0.5521 -0.0411 0.3069 0.087 Uiso 1 1 calc R . .
H27C H 0.5370 -0.1429 0.3134 0.087 Uiso 1 1 calc R . .
C28 C 0.42329(15) -0.08007(18) 0.21503(14) 0.0536(8) Uani 1 1 d . . .
H28A H 0.4358 -0.1398 0.2059 0.080 Uiso 1 1 calc R . .
H28B H 0.4441 -0.0380 0.1903 0.080 Uiso 1 1 calc R . .
H28C H 0.3789 -0.0742 0.1983 0.080 Uiso 1 1 calc R . .
C29 C 0.41020(17) -0.16042(16) 0.34915(17) 0.0645(9) Uani 1 1 d . . .
H29A H 0.4051 -0.2058 0.3127 0.097 Uiso 1 1 calc R . .
H29B H 0.3703 -0.1459 0.3590 0.097 Uiso 1 1 calc R . .
H29C H 0.4374 -0.1821 0.3921 0.097 Uiso 1 1 calc R . .
C31 C 0.01569(10) 0.64287(14) 0.15320(11) 0.0289(5) Uani 1 1 d . . .
C32 C 0.02518(10) 0.73158(14) 0.12333(12) 0.0306(5) Uani 1 1 d . . .
C33 C -0.00595(12) 0.75510(17) 0.05613(14) 0.0430(6) Uani 1 1 d . . .
H33 H -0.0329 0.7142 0.0285 0.052 Uiso 1 1 calc R . .
C34 C 0.00179(14) 0.83743(19) 0.02883(17) 0.0583(8) Uani 1 1 d . . .
H34 H -0.0200 0.8527 -0.0171 0.070 Uiso 1 1 calc R . .
C35 C 0.04113(14) 0.89704(18) 0.06833(19) 0.0592(8) Uani 1 1 d . . .
H35 H 0.0466 0.9532 0.0496 0.071 Uiso 1 1 calc R . .
C36 C 0.07229(13) 0.87493(17) 0.13477(17) 0.0513(7) Uani 1 1 d . . .
H36 H 0.0994 0.9161 0.1619 0.062 Uiso 1 1 calc R . .
C37 C 0.06459(11) 0.79298(15) 0.16270(14) 0.0384(6) Uani 1 1 d . . .
H37 H 0.0862 0.7786 0.2088 0.046 Uiso 1 1 calc R . .
C38 C -0.04165(11) 0.63547(14) 0.18199(12) 0.0305(5) Uani 1 1 d . . .
C39 C -0.09991(11) 0.64423(16) 0.13874(13) 0.0385(6) Uani 1 1 d . . .
H39 H -0.1039 0.6560 0.0901 0.046 Uiso 1 1 calc R . .
C40 C -0.15198(12) 0.63604(18) 0.16591(15) 0.0485(7) Uani 1 1 d . . .
H40 H -0.1912 0.6403 0.1355 0.058 Uiso 1 1 calc R . .
C41 C -0.14713(13) 0.62162(18) 0.23710(16) 0.0505(7) Uani 1 1 d . . .
H41 H -0.1829 0.6166 0.2556 0.061 Uiso 1 1 calc R . .
C42 C -0.09003(13) 0.61456(17) 0.28086(14) 0.0458(7) Uani 1 1 d . . .
H42 H -0.0865 0.6048 0.3297 0.055 Uiso 1 1 calc R . .
C43 C -0.03761(12) 0.62165(16) 0.25404(13) 0.0386(6) Uani 1 1 d . . .
H43 H 0.0014 0.6171 0.2849 0.046 Uiso 1 1 calc R . .
C44 C 0.12951(10) 0.57324(14) 0.13608(11) 0.0280(5) Uani 1 1 d . . .
C45 C 0.15614(11) 0.65469(14) 0.11092(13) 0.0348(5) Uani 1 1 d . . .
C46 C 0.20457(13) 0.69729(17) 0.15617(18) 0.0540(7) Uani 1 1 d . . .
H46 H 0.2175 0.6771 0.2032 0.065 Uiso 1 1 calc R . .
C47 C 0.23374(15) 0.7676(2) 0.1341(2) 0.0725(10) Uani 1 1 d . . .
H47 H 0.2662 0.7958 0.1659 0.087 Uiso 1 1 calc R . .
C48 C 0.21625(17) 0.7973(2) 0.0665(3) 0.0769(12) Uani 1 1 d . . .
H48 H 0.2373 0.8450 0.0511 0.092 Uiso 1 1 calc R . .
C49 C 0.16806(17) 0.75814(19) 0.02047(19) 0.0653(10) Uani 1 1 d . . .
H49 H 0.1554 0.7797 -0.0262 0.078 Uiso 1 1 calc R . .
C50 C 0.13775(13) 0.68610(16) 0.04286(14) 0.0456(7) Uani 1 1 d . . .
H50 H 0.1046 0.6590 0.0112 0.055 Uiso 1 1 calc R . .
C51 C 0.17689(11) 0.50174(14) 0.15019(12) 0.0331(5) Uani 1 1 d . . .
C52 C 0.20054(13) 0.47096(19) 0.21778(15) 0.0501(7) Uani 1 1 d . . .
H52 H 0.1856 0.4939 0.2562 0.060 Uiso 1 1 calc R . .
C53 C 0.24591(16) 0.4069(2) 0.22978(19) 0.0709(10) Uani 1 1 d . . .
H53 H 0.2621 0.3870 0.2763 0.085 Uiso 1 1 calc R . .
C54 C 0.26746(15) 0.3722(2) 0.1747(2) 0.0691(10) Uani 1 1 d . . .
H54 H 0.2973 0.3270 0.1828 0.083 Uiso 1 1 calc R . .
C55 C 0.24556(13) 0.40335(19) 0.10771(18) 0.0563(8) Uani 1 1 d . . .
H55 H 0.2610 0.3802 0.0697 0.068 Uiso 1 1 calc R . .
C56 C 0.20129(12) 0.46808(17) 0.09527(14) 0.0417(6) Uani 1 1 d . . .
H56 H 0.1873 0.4900 0.0489 0.050 Uiso 1 1 calc R . .
C57 C -0.04991(13) 0.41203(18) 0.16942(15) 0.0504(7) Uani 1 1 d . . .
H57A H -0.0709 0.4209 0.1203 0.076 Uiso 1 1 calc R . .
H57B H -0.0673 0.4515 0.1996 0.076 Uiso 1 1 calc R . .
H57C H -0.0552 0.3511 0.1829 0.076 Uiso 1 1 calc R . .
C58 C 0.06494(14) 0.40094(19) 0.27873(14) 0.0520(7) Uani 1 1 d . . .
H58A H 0.0507 0.3413 0.2847 0.078 Uiso 1 1 calc R . .
H58B H 0.0484 0.4411 0.3092 0.078 Uiso 1 1 calc R . .
H58C H 0.1097 0.4024 0.2914 0.078 Uiso 1 1 calc R . .
C59 C 0.06695(17) 0.33675(16) 0.13644(16) 0.0630(9) Uani 1 1 d . . .
H59A H 0.0613 0.2833 0.1622 0.094 Uiso 1 1 calc R . .
H59B H 0.1105 0.3447 0.1374 0.094 Uiso 1 1 calc R . .
H59C H 0.0443 0.3316 0.0876 0.094 Uiso 1 1 calc R . .
C60 C 0.18277(14) 0.3391(2) 0.58011(16) 0.0571(8) Uani 1 1 d . . .
H60 H 0.1949 0.3044 0.6212 0.069 Uiso 1 1 calc R . .
C61 C 0.18199(17) 0.4295(2) 0.58469(19) 0.0714(10) Uani 1 1 d . . .
H61 H 0.1941 0.4573 0.6292 0.086 Uiso 1 1 calc R . .
C62 C 0.16378(16) 0.4790(2) 0.5250(2) 0.0724(10) Uani 1 1 d . . .
H62 H 0.1627 0.5411 0.5285 0.087 Uiso 1 1 calc R . .
C63 C 0.14715(16) 0.4401(2) 0.4603(2) 0.0672(9) Uani 1 1 d . . .
H63 H 0.1349 0.4747 0.4191 0.081 Uiso 1 1 calc R . .
C64 C 0.14839(15) 0.3499(2) 0.45592(17) 0.0623(8) Uani 1 1 d . . .
H64 H 0.1372 0.3220 0.4114 0.075 Uiso 1 1 calc R . .
C65 C 0.16582(13) 0.3006(2) 0.51572(16) 0.0557(8) Uani 1 1 d . . .
H65 H 0.1661 0.2384 0.5122 0.067 Uiso 1 1 calc R . .
C70 C 0.31333(18) 0.6740(2) 0.42072(18) 0.0744(10) Uani 1 1 d . . .
H70 H 0.3011 0.7166 0.3849 0.089 Uiso 1 1 calc R . .
C71 C 0.3576(2) 0.6925(3) 0.47864(19) 0.0978(15) Uani 1 1 d . . .
H71 H 0.3766 0.7485 0.4832 0.117 Uiso 1 1 calc R . .
C72 C 0.37504(19) 0.6313(3) 0.53019(19) 0.0931(14) Uani 1 1 d . . .
H72 H 0.4065 0.6450 0.5700 0.112 Uiso 1 1 calc R . .
C73 C 0.34807(17) 0.5513(2) 0.52534(19) 0.0698(9) Uani 1 1 d . . .
H73 H 0.3599 0.5090 0.5615 0.084 Uiso 1 1 calc R . .
C74 C 0.30366(18) 0.5331(2) 0.4675(2) 0.0779(11) Uani 1 1 d . . .
H74 H 0.2841 0.4775 0.4636 0.094 Uiso 1 1 calc R . .
C75 C 0.28681(16) 0.5932(2) 0.4152(2) 0.0713(10) Uani 1 1 d . . .
H75 H 0.2564 0.5787 0.3746 0.086 Uiso 1 1 calc R . .
Cl1 Cl 0.33211(4) 0.14009(5) 0.19059(4) 0.0600(2) Uani 1 1 d . . .
Cl2 Cl 0.55617(3) 0.05699(4) 0.49138(3) 0.03587(13) Uani 1 1 d . . .
Cl3 Cl 0.13027(3) 0.64675(5) 0.32378(3) 0.04972(17) Uani 1 1 d . . .
Cl4 Cl -0.06374(3) 0.52967(4) 0.01265(3) 0.03405(13) Uani 1 1 d . . .
As1 As 0.445430(13) -0.056562(15) 0.316699(12) 0.03462(7) Uani 1 1 d . . .
As2 As 0.036837(12) 0.437056(15) 0.180168(12) 0.03278(6) Uani 1 1 d . . .
Rh1 Rh 0.389241(9) 0.088692(11) 0.295462(9) 0.03112(5) Uani 1 1 d . . .
Rh2 Rh 0.452924(8) 0.050059(10) 0.414977(8) 0.02472(5) Uani 1 1 d . . .
Rh3 Rh 0.086958(8) 0.587263(11) 0.215323(9) 0.02865(5) Uani 1 1 d . . .
Rh4 Rh 0.040138(8) 0.548841(10) 0.088936(8) 0.02375(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C8 112.88(18) . . ?
C2 C1 Rh1 114.11(16) . . ?
C8 C1 Rh1 112.65(16) . . ?
C2 C1 Rh2 115.70(15) . . ?
C8 C1 Rh2 119.42(15) . . ?
Rh1 C1 Rh2 77.32(8) . . ?
C3 C2 C7 117.8(2) . . ?
C3 C2 C1 122.9(2) . . ?
C7 C2 C1 119.3(2) . . ?
C2 C3 C4 120.4(3) . . ?
C5 C4 C3 121.1(3) . . ?
C4 C5 C6 119.5(3) . . ?
C5 C6 C7 120.2(3) . . ?
C6 C7 C2 121.0(3) . . ?
C13 C8 C9 118.4(2) . . ?
C13 C8 C1 121.3(2) . . ?
C9 C8 C1 120.3(2) . . ?
C10 C9 C8 119.9(3) . . ?
C11 C10 C9 120.8(3) . . ?
C12 C11 C10 119.8(3) . . ?
C11 C12 C13 120.4(3) . . ?
C8 C13 C12 120.5(3) . . ?
C15 C14 C21 112.60(19) . . ?
C15 C14 Rh1 118.30(15) . . ?
C21 C14 Rh1 112.95(16) . . ?
C15 C14 Rh2 106.23(15) . . ?
C21 C14 Rh2 125.52(15) . . ?
Rh1 C14 Rh2 77.51(8) . . ?
C16 C15 C20 118.3(2) . . ?
C16 C15 C14 121.3(2) . . ?
C20 C15 C14 120.4(2) . . ?
C17 C16 C15 120.0(2) . . ?
C18 C17 C16 121.0(2) . . ?
C19 C18 C17 119.8(2) . . ?
C18 C19 C20 119.9(3) . . ?
C19 C20 C15 121.0(2) . . ?
C22 C21 C26 117.9(2) . . ?
C22 C21 C14 121.0(2) . . ?
C26 C21 C14 121.0(2) . . ?
C23 C22 C21 120.3(3) . . ?
C24 C23 C22 120.9(3) . . ?
C23 C24 C25 119.6(3) . . ?
C24 C25 C26 120.4(3) . . ?
C25 C26 C21 120.8(3) . . ?
C32 C31 C38 114.36(18) . . ?
C32 C31 Rh3 117.39(16) . . ?
C38 C31 Rh3 112.30(15) . . ?
C32 C31 Rh4 108.24(14) . . ?
C38 C31 Rh4 122.25(15) . . ?
Rh3 C31 Rh4 77.68(8) . . ?
C33 C32 C37 118.2(2) . . ?
C33 C32 C31 120.8(2) . . ?
C37 C32 C31 121.0(2) . . ?
C34 C33 C32 121.0(3) . . ?
C35 C34 C33 120.0(3) . . ?
C36 C35 C34 119.8(3) . . ?
C35 C36 C37 120.6(3) . . ?
C36 C37 C32 120.4(3) . . ?
C39 C38 C43 117.8(2) . . ?
C39 C38 C31 121.7(2) . . ?
C43 C38 C31 120.4(2) . . ?
C40 C39 C38 120.9(2) . . ?
C41 C40 C39 120.4(3) . . ?
C42 C41 C40 119.5(3) . . ?
C41 C42 C43 120.5(3) . . ?
C42 C43 C38 120.8(2) . . ?
C51 C44 C45 110.11(19) . . ?
C51 C44 Rh3 111.90(15) . . ?
C45 C44 Rh3 116.96(15) . . ?
C51 C44 Rh4 122.17(15) . . ?
C45 C44 Rh4 114.96(15) . . ?
Rh3 C44 Rh4 77.39(8) . . ?
C50 C45 C46 118.1(2) . . ?
C50 C45 C44 122.7(2) . . ?
C46 C45 C44 119.0(2) . . ?
C47 C46 C45 121.4(3) . . ?
C48 C47 C46 120.3(3) . . ?
C47 C48 C49 120.1(3) . . ?
C48 C49 C50 119.9(3) . . ?
C45 C50 C49 120.2(3) . . ?
C52 C51 C56 117.9(2) . . ?
C52 C51 C44 121.8(2) . . ?
C56 C51 C44 120.2(2) . . ?
C51 C52 C53 120.7(3) . . ?
C54 C53 C52 120.4(3) . . ?
C55 C54 C53 119.7(3) . . ?
C54 C55 C56 120.5(3) . . ?
C55 C56 C51 120.8(3) . . ?
C65 C60 C61 119.0(3) . . ?
C62 C61 C60 120.0(3) . . ?
C63 C62 C61 120.9(3) . . ?
C62 C63 C64 118.9(3) . . ?
C65 C64 C63 120.1(3) . . ?
C60 C65 C64 121.1(3) . . ?
C71 C70 C75 118.7(3) . . ?
C70 C71 C72 120.7(3) . . ?
C73 C72 C71 120.8(4) . . ?
C72 C73 C74 118.4(3) . . ?
C73 C74 C75 121.1(3) . . ?
C74 C75 C70 120.3(3) . . ?
Rh2 Cl2 Rh2 101.48(2) . 3_656 ?
Rh4 Cl4 Rh4 101.57(2) 3_565 . ?
C29 As1 C27 103.80(15) . . ?
C29 As1 C28 98.52(13) . . ?
C27 As1 C28 97.84(13) . . ?
C29 As1 Rh2 104.32(9) . . ?
C27 As1 Rh2 97.33(8) . . ?
C28 As1 Rh2 148.58(8) . . ?
C29 As1 Rh1 123.00(10) . . ?
C27 As1 Rh1 131.05(10) . . ?
C28 As1 Rh1 89.27(8) . . ?
Rh2 As1 Rh1 60.225(9) . . ?
C59 As2 C57 103.42(14) . . ?
C59 As2 C58 98.04(13) . . ?
C57 As2 C58 98.67(12) . . ?
C59 As2 Rh4 99.22(8) . . ?
C57 As2 Rh4 104.03(8) . . ?
C58 As2 Rh4 147.29(8) . . ?
C59 As2 Rh3 130.09(10) . . ?
C57 As2 Rh3 124.75(9) . . ?
C58 As2 Rh3 87.75(8) . . ?
Rh4 As2 Rh3 59.970(9) . . ?
C14 Rh1 C1 91.66(9) . . ?
C14 Rh1 Cl1 126.72(7) . . ?
C1 Rh1 Cl1 122.97(6) . . ?
C14 Rh1 Rh2 52.37(7) . . ?
C1 Rh1 Rh2 52.38(6) . . ?
Cl1 Rh1 Rh2 173.55(2) . . ?
C14 Rh1 As1 88.58(6) . . ?
C1 Rh1 As1 88.33(6) . . ?
Cl1 Rh1 As1 127.09(2) . . ?
Rh2 Rh1 As1 58.958(8) . . ?
C14 Rh2 C1 88.19(9) . . ?
C14 Rh2 Cl2 158.01(6) . . ?
C1 Rh2 Cl2 96.89(7) . . ?
C14 Rh2 Cl2 94.43(6) . 3_656 ?
C1 Rh2 Cl2 173.52(6) . 3_656 ?
Cl2 Rh2 Cl2 78.52(2) . 3_656 ?
C14 Rh2 As1 88.49(6) . . ?
C1 Rh2 As1 88.35(6) . . ?
Cl2 Rh2 As1 112.956(18) . . ?
Cl2 Rh2 As1 97.628(17) 3_656 . ?
C14 Rh2 Rh1 50.12(6) . . ?
C1 Rh2 Rh1 50.30(6) . . ?
Cl2 Rh2 Rh1 144.647(17) . . ?
Cl2 Rh2 Rh1 135.230(16) 3_656 . ?
As1 Rh2 Rh1 60.817(9) . . ?
C31 Rh3 C44 91.73(9) . . ?
C31 Rh3 Cl3 121.02(6) . . ?
C44 Rh3 Cl3 125.01(7) . . ?
C31 Rh3 Rh4 52.60(6) . . ?
C44 Rh3 Rh4 52.25(6) . . ?
Cl3 Rh3 Rh4 170.13(2) . . ?
C31 Rh3 As2 88.36(6) . . ?
C44 Rh3 As2 87.29(6) . . ?
Cl3 Rh3 As2 131.62(2) . . ?
Rh4 Rh3 As2 58.011(8) . . ?
C44 Rh4 C31 87.92(9) . . ?
C44 Rh4 Cl4 95.11(6) . 3_565 ?
C31 Rh4 Cl4 163.66(6) . 3_565 ?
C44 Rh4 As2 88.95(6) . . ?
C31 Rh4 As2 89.41(6) . . ?
Cl4 Rh4 As2 106.665(17) 3_565 . ?
C44 Rh4 Cl4 169.94(6) . . ?
C31 Rh4 Cl4 96.17(6) . . ?
Cl4 Rh4 Cl4 78.43(2) 3_565 . ?
As2 Rh4 Cl4 100.250(17) . . ?
C44 Rh4 Rh3 50.37(6) . . ?
C31 Rh4 Rh3 49.72(6) . . ?
Cl4 Rh4 Rh3 141.124(16) 3_565 . ?
As2 Rh4 Rh3 62.018(8) . . ?
Cl4 Rh4 Rh3 138.145(16) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.506(3) . ?
C1 C8 1.520(3) . ?
C1 Rh1 1.989(2) . ?
C1 Rh2 2.048(2) . ?
C2 C3 1.382(4) . ?
C2 C7 1.398(3) . ?
C3 C4 1.396(4) . ?
C4 C5 1.357(5) . ?
C5 C6 1.377(4) . ?
C6 C7 1.384(4) . ?
C8 C13 1.391(4) . ?
C8 C9 1.398(4) . ?
C9 C10 1.397(4) . ?
C10 C11 1.373(5) . ?
C11 C12 1.367(5) . ?
C12 C13 1.401(4) . ?
C14 C15 1.507(3) . ?
C14 C21 1.509(3) . ?
C14 Rh1 1.983(2) . ?
C14 Rh2 2.046(2) . ?
C15 C16 1.394(3) . ?
C15 C20 1.400(3) . ?
C16 C17 1.386(3) . ?
C17 C18 1.382(4) . ?
C18 C19 1.372(4) . ?
C19 C20 1.386(3) . ?
C21 C22 1.397(4) . ?
C21 C26 1.402(4) . ?
C22 C23 1.396(4) . ?
C23 C24 1.366(5) . ?
C24 C25 1.379(5) . ?
C25 C26 1.385(4) . ?
C27 As1 1.943(3) . ?
C28 As1 1.968(3) . ?
C29 As1 1.936(3) . ?
C31 C32 1.506(3) . ?
C31 C38 1.513(3) . ?
C31 Rh3 1.973(2) . ?
C31 Rh4 2.055(2) . ?
C32 C33 1.390(3) . ?
C32 C37 1.397(3) . ?
C33 C34 1.389(4) . ?
C34 C35 1.379(4) . ?
C35 C36 1.373(4) . ?
C36 C37 1.389(4) . ?
C38 C39 1.398(3) . ?
C38 C43 1.403(3) . ?
C39 C40 1.387(4) . ?
C40 C41 1.385(4) . ?
C41 C42 1.379(4) . ?
C42 C43 1.389(4) . ?
C44 C51 1.505(3) . ?
C44 C45 1.506(3) . ?
C44 Rh3 1.994(2) . ?
C44 Rh4 2.047(2) . ?
C45 C50 1.386(3) . ?
C45 C46 1.400(4) . ?
C46 C47 1.373(4) . ?
C47 C48 1.367(5) . ?
C48 C49 1.380(5) . ?
C49 C50 1.410(4) . ?
C51 C52 1.390(3) . ?
C51 C56 1.400(3) . ?
C52 C53 1.393(4) . ?
C53 C54 1.375(5) . ?
C54 C55 1.375(5) . ?
C55 C56 1.383(4) . ?
C57 As2 1.946(3) . ?
C58 As2 1.965(3) . ?
C59 As2 1.942(3) . ?
C60 C65 1.363(4) . ?
C60 C61 1.382(5) . ?
C61 C62 1.373(5) . ?
C62 C63 1.370(5) . ?
C63 C64 1.379(4) . ?
C64 C65 1.371(4) . ?
C70 C71 1.361(5) . ?
C70 C75 1.363(5) . ?
C71 C72 1.364(5) . ?
C72 C73 1.356(5) . ?
C73 C74 1.360(5) . ?
C74 C75 1.362(5) . ?
Cl1 Rh1 2.3006(7) . ?
Cl2 Rh2 2.4662(7) . ?
Cl2 Rh2 2.4895(6) 3_656 ?
Cl3 Rh3 2.3108(6) . ?
Cl4 Rh4 2.4669(6) 3_565 ?
Cl4 Rh4 2.4917(6) . ?
As1 Rh2 2.4899(3) . ?
As1 Rh1 2.5372(3) . ?
As2 Rh4 2.4757(3) . ?
As2 Rh3 2.5777(3) . ?
Rh1 Rh2 2.5225(3) . ?
Rh2 Cl2 2.4895(6) 3_656 ?
Rh3 Rh4 2.5271(3) . ?
Rh4 Cl4 2.4669(6) 3_565 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C1 C2 C3 -104.7(3) . . . . ?
Rh1 C1 C2 C3 125.0(2) . . . . ?
Rh2 C1 C2 C3 38.0(3) . . . . ?
C8 C1 C2 C7 75.4(3) . . . . ?
Rh1 C1 C2 C7 -54.9(3) . . . . ?
Rh2 C1 C2 C7 -141.92(19) . . . . ?
C7 C2 C3 C4 0.4(4) . . . . ?
C1 C2 C3 C4 -179.5(3) . . . . ?
C2 C3 C4 C5 -0.7(5) . . . . ?
C3 C4 C5 C6 0.5(5) . . . . ?
C4 C5 C6 C7 0.1(5) . . . . ?
C5 C6 C7 C2 -0.4(4) . . . . ?
C3 C2 C7 C6 0.1(4) . . . . ?
C1 C2 C7 C6 -180.0(2) . . . . ?
C2 C1 C8 C13 -107.2(3) . . . . ?
Rh1 C1 C8 C13 23.8(3) . . . . ?
Rh2 C1 C8 C13 111.6(2) . . . . ?
C2 C1 C8 C9 71.7(3) . . . . ?
Rh1 C1 C8 C9 -157.28(19) . . . . ?
Rh2 C1 C8 C9 -69.4(3) . . . . ?
C13 C8 C9 C10 -5.1(4) . . . . ?
C1 C8 C9 C10 176.0(2) . . . . ?
C8 C9 C10 C11 2.9(4) . . . . ?
C9 C10 C11 C12 0.8(5) . . . . ?
C10 C11 C12 C13 -2.3(5) . . . . ?
C9 C8 C13 C12 3.6(4) . . . . ?
C1 C8 C13 C12 -177.4(2) . . . . ?
C11 C12 C13 C8 0.0(4) . . . . ?
C21 C14 C15 C16 -88.1(3) . . . . ?
Rh1 C14 C15 C16 46.7(3) . . . . ?
Rh2 C14 C15 C16 131.0(2) . . . . ?
C21 C14 C15 C20 89.3(3) . . . . ?
Rh1 C14 C15 C20 -136.0(2) . . . . ?
Rh2 C14 C15 C20 -51.6(2) . . . . ?
C20 C15 C16 C17 0.6(4) . . . . ?
C14 C15 C16 C17 178.0(2) . . . . ?
C15 C16 C17 C18 0.2(4) . . . . ?
C16 C17 C18 C19 -0.2(4) . . . . ?
C17 C18 C19 C20 -0.4(4) . . . . ?
C18 C19 C20 C15 1.2(4) . . . . ?
C16 C15 C20 C19 -1.3(4) . . . . ?
C14 C15 C20 C19 -178.7(2) . . . . ?
C15 C14 C21 C22 122.7(3) . . . . ?
Rh1 C14 C21 C22 -14.5(3) . . . . ?
Rh2 C14 C21 C22 -105.3(2) . . . . ?
C15 C14 C21 C26 -54.0(3) . . . . ?
Rh1 C14 C21 C26 168.82(19) . . . . ?
Rh2 C14 C21 C26 78.0(3) . . . . ?
C26 C21 C22 C23 -1.2(4) . . . . ?
C14 C21 C22 C23 -178.0(3) . . . . ?
C21 C22 C23 C24 -0.4(5) . . . . ?
C22 C23 C24 C25 1.4(5) . . . . ?
C23 C24 C25 C26 -0.7(5) . . . . ?
C24 C25 C26 C21 -0.9(5) . . . . ?
C22 C21 C26 C25 1.9(4) . . . . ?
C14 C21 C26 C25 178.6(2) . . . . ?
C38 C31 C32 C33 -80.0(3) . . . . ?
Rh3 C31 C32 C33 145.24(19) . . . . ?
Rh4 C31 C32 C33 60.0(2) . . . . ?
C38 C31 C32 C37 98.8(3) . . . . ?
Rh3 C31 C32 C37 -35.9(3) . . . . ?
Rh4 C31 C32 C37 -121.15(19) . . . . ?
C37 C32 C33 C34 -0.1(4) . . . . ?
C31 C32 C33 C34 178.8(2) . . . . ?
C32 C33 C34 C35 0.4(4) . . . . ?
C33 C34 C35 C36 -0.4(5) . . . . ?
C34 C35 C36 C37 0.0(5) . . . . ?
C35 C36 C37 C32 0.4(4) . . . . ?
C33 C32 C37 C36 -0.3(4) . . . . ?
C31 C32 C37 C36 -179.2(2) . . . . ?
C32 C31 C38 C39 63.6(3) . . . . ?
Rh3 C31 C38 C39 -159.38(18) . . . . ?
Rh4 C31 C38 C39 -70.2(3) . . . . ?
C32 C31 C38 C43 -114.8(2) . . . . ?
Rh3 C31 C38 C43 22.3(3) . . . . ?
Rh4 C31 C38 C43 111.5(2) . . . . ?
C43 C38 C39 C40 -2.5(3) . . . . ?
C31 C38 C39 C40 179.1(2) . . . . ?
C38 C39 C40 C41 2.0(4) . . . . ?
C39 C40 C41 C42 -0.6(4) . . . . ?
C40 C41 C42 C43 -0.1(4) . . . . ?
C41 C42 C43 C38 -0.5(4) . . . . ?
C39 C38 C43 C42 1.7(3) . . . . ?
C31 C38 C43 C42 -179.8(2) . . . . ?
C51 C44 C45 C50 111.6(2) . . . . ?
Rh3 C44 C45 C50 -119.2(2) . . . . ?
Rh4 C44 C45 C50 -31.1(3) . . . . ?
C51 C44 C45 C46 -63.6(3) . . . . ?
Rh3 C44 C45 C46 65.6(3) . . . . ?
Rh4 C44 C45 C46 153.66(19) . . . . ?
C50 C45 C46 C47 -0.7(4) . . . . ?
C44 C45 C46 C47 174.7(2) . . . . ?
C45 C46 C47 C48 -0.6(5) . . . . ?
C46 C47 C48 C49 1.7(5) . . . . ?
C47 C48 C49 C50 -1.4(5) . . . . ?
C46 C45 C50 C49 0.9(4) . . . . ?
C44 C45 C50 C49 -174.3(2) . . . . ?
C48 C49 C50 C45 0.1(4) . . . . ?
C45 C44 C51 C52 112.8(3) . . . . ?
Rh3 C44 C51 C52 -19.1(3) . . . . ?
Rh4 C44 C51 C52 -107.6(2) . . . . ?
C45 C44 C51 C56 -63.1(3) . . . . ?
Rh3 C44 C51 C56 165.01(18) . . . . ?
Rh4 C44 C51 C56 76.5(3) . . . . ?
C56 C51 C52 C53 -1.7(4) . . . . ?
C44 C51 C52 C53 -177.7(3) . . . . ?
C51 C52 C53 C54 -0.9(5) . . . . ?
C52 C53 C54 C55 2.3(5) . . . . ?
C53 C54 C55 C56 -1.2(5) . . . . ?
C54 C55 C56 C51 -1.5(4) . . . . ?
C52 C51 C56 C55 2.9(4) . . . . ?
C44 C51 C56 C55 179.0(2) . . . . ?
C65 C60 C61 C62 0.6(5) . . . . ?
C60 C61 C62 C63 -1.0(5) . . . . ?
C61 C62 C63 C64 0.6(6) . . . . ?
C62 C63 C64 C65 0.3(5) . . . . ?
C61 C60 C65 C64 0.3(5) . . . . ?
C63 C64 C65 C60 -0.7(5) . . . . ?
C75 C70 C71 C72 -0.1(7) . . . . ?
C70 C71 C72 C73 -0.9(7) . . . . ?
C71 C72 C73 C74 0.7(7) . . . . ?
C72 C73 C74 C75 0.6(6) . . . . ?
C73 C74 C75 C70 -1.6(6) . . . . ?
C71 C70 C75 C74 1.4(6) . . . . ?
C15 C14 Rh1 C1 64.39(18) . . . . ?
C21 C14 Rh1 C1 -161.03(16) . . . . ?
Rh2 C14 Rh1 C1 -37.50(8) . . . . ?
C15 C14 Rh1 Cl1 -70.10(19) . . . . ?
C21 C14 Rh1 Cl1 64.48(17) . . . . ?
Rh2 C14 Rh1 Cl1 -171.99(3) . . . . ?
C15 C14 Rh1 Rh2 101.88(18) . . . . ?
C21 C14 Rh1 Rh2 -123.53(18) . . . . ?
C15 C14 Rh1 As1 152.67(17) . . . . ?
C21 C14 Rh1 As1 -72.74(15) . . . . ?
Rh2 C14 Rh1 As1 50.79(5) . . . . ?
C2 C1 Rh1 C14 -75.24(16) . . . . ?
C8 C1 Rh1 C14 154.34(16) . . . . ?
Rh2 C1 Rh1 C14 37.49(8) . . . . ?
C2 C1 Rh1 Cl1 61.80(17) . . . . ?
C8 C1 Rh1 Cl1 -68.63(16) . . . . ?
Rh2 C1 Rh1 Cl1 174.52(3) . . . . ?
C2 C1 Rh1 Rh2 -112.72(17) . . . . ?
C8 C1 Rh1 Rh2 116.85(17) . . . . ?
C2 C1 Rh1 As1 -163.76(15) . . . . ?
C8 C1 Rh1 As1 65.81(14) . . . . ?
Rh2 C1 Rh1 As1 -51.04(5) . . . . ?
C29 As1 Rh1 C14 42.44(13) . . . . ?
C27 As1 Rh1 C14 -118.10(13) . . . . ?
C28 As1 Rh1 C14 142.13(12) . . . . ?
Rh2 As1 Rh1 C14 -45.74(7) . . . . ?
C29 As1 Rh1 C1 134.14(13) . . . . ?
C27 As1 Rh1 C1 -26.39(13) . . . . ?
C28 As1 Rh1 C1 -126.17(12) . . . . ?
Rh2 As1 Rh1 C1 45.96(6) . . . . ?
C29 As1 Rh1 Cl1 -94.52(12) . . . . ?
C27 As1 Rh1 Cl1 104.94(12) . . . . ?
C28 As1 Rh1 Cl1 5.17(10) . . . . ?
Rh2 As1 Rh1 Cl1 177.29(3) . . . . ?
C29 As1 Rh1 Rh2 88.18(12) . . . . ?
C27 As1 Rh1 Rh2 -72.35(12) . . . . ?
C28 As1 Rh1 Rh2 -172.13(10) . . . . ?
C15 C14 Rh2 C1 -79.93(15) . . . . ?
C21 C14 Rh2 C1 145.7(2) . . . . ?
Rh1 C14 Rh2 C1 36.25(8) . . . . ?
C15 C14 Rh2 Cl2 24.1(3) . . . . ?
C21 C14 Rh2 Cl2 -110.3(2) . . . . ?
Rh1 C14 Rh2 Cl2 140.28(12) . . . . ?
C15 C14 Rh2 Cl2 94.13(14) . . . 3_656 ?
C21 C14 Rh2 Cl2 -40.3(2) . . . 3_656 ?
Rh1 C14 Rh2 Cl2 -149.68(5) . . . 3_656 ?
C15 C14 Rh2 As1 -168.33(14) . . . . ?
C21 C14 Rh2 As1 57.28(19) . . . . ?
Rh1 C14 Rh2 As1 -52.15(5) . . . . ?
C15 C14 Rh2 Rh1 -116.18(16) . . . . ?
C21 C14 Rh2 Rh1 109.4(2) . . . . ?
C2 C1 Rh2 C14 74.74(18) . . . . ?
C8 C1 Rh2 C14 -145.18(19) . . . . ?
Rh1 C1 Rh2 C14 -36.14(8) . . . . ?
C2 C1 Rh2 Cl2 -83.79(17) . . . . ?
C8 C1 Rh2 Cl2 56.28(18) . . . . ?
Rh1 C1 Rh2 Cl2 165.33(5) . . . . ?
C2 C1 Rh2 Cl2 -39.3(7) . . . 3_656 ?
C8 C1 Rh2 Cl2 100.8(6) . . . 3_656 ?
Rh1 C1 Rh2 Cl2 -150.1(6) . . . 3_656 ?
C2 C1 Rh2 As1 163.29(17) . . . . ?
C8 C1 Rh2 As1 -56.64(18) . . . . ?
Rh1 C1 Rh2 As1 52.40(5) . . . . ?
C2 C1 Rh2 Rh1 110.88(19) . . . . ?
C8 C1 Rh2 Rh1 -109.0(2) . . . . ?
Rh2 Cl2 Rh2 C14 72.99(17) 3_656 . . . ?
Rh2 Cl2 Rh2 C1 175.37(7) 3_656 . . . ?
Rh2 Cl2 Rh2 Cl2 0.0 3_656 . . 3_656 ?
Rh2 Cl2 Rh2 As1 -93.50(2) 3_656 . . . ?
Rh2 Cl2 Rh2 Rh1 -164.951(17) 3_656 . . . ?
C29 As1 Rh2 C14 -76.16(13) . . . . ?
C27 As1 Rh2 C14 177.51(12) . . . . ?
C28 As1 Rh2 C14 59.2(2) . . . . ?
Rh1 As1 Rh2 C14 43.95(6) . . . . ?
C29 As1 Rh2 C1 -164.39(13) . . . . ?
C27 As1 Rh2 C1 89.28(12) . . . . ?
C28 As1 Rh2 C1 -29.1(2) . . . . ?
Rh1 As1 Rh2 C1 -44.29(7) . . . . ?
C29 As1 Rh2 Cl2 98.82(11) . . . . ?
C27 As1 Rh2 Cl2 -7.51(10) . . . . ?
C28 As1 Rh2 Cl2 -125.84(19) . . . . ?
Rh1 As1 Rh2 Cl2 -141.075(17) . . . . ?
C29 As1 Rh2 Cl2 18.11(11) . . . 3_656 ?
C27 As1 Rh2 Cl2 -88.22(10) . . . 3_656 ?
C28 As1 Rh2 Cl2 153.44(19) . . . 3_656 ?
Rh1 As1 Rh2 Cl2 138.212(16) . . . 3_656 ?
C29 As1 Rh2 Rh1 -120.11(11) . . . . ?
C27 As1 Rh2 Rh1 133.56(10) . . . . ?
C28 As1 Rh2 Rh1 15.23(19) . . . . ?
C1 Rh1 Rh2 C14 129.81(11) . . . . ?
Cl1 Rh1 Rh2 C14 84.3(2) . . . . ?
As1 Rh1 Rh2 C14 -115.30(8) . . . . ?
C14 Rh1 Rh2 C1 -129.81(11) . . . . ?
Cl1 Rh1 Rh2 C1 -45.5(2) . . . . ?
As1 Rh1 Rh2 C1 114.89(8) . . . . ?
C14 Rh1 Rh2 Cl2 -155.57(8) . . . . ?
C1 Rh1 Rh2 Cl2 -25.75(9) . . . . ?
Cl1 Rh1 Rh2 Cl2 -71.3(2) . . . . ?
As1 Rh1 Rh2 Cl2 89.13(3) . . . . ?
C14 Rh1 Rh2 Cl2 45.61(8) . . . 3_656 ?
C1 Rh1 Rh2 Cl2 175.43(9) . . . 3_656 ?
Cl1 Rh1 Rh2 Cl2 129.9(2) . . . 3_656 ?
As1 Rh1 Rh2 Cl2 -69.69(2) . . . 3_656 ?
C14 Rh1 Rh2 As1 115.30(8) . . . . ?
C1 Rh1 Rh2 As1 -114.89(8) . . . . ?
Cl1 Rh1 Rh2 As1 -160.4(2) . . . . ?
C32 C31 Rh3 C44 -66.92(16) . . . . ?
C38 C31 Rh3 C44 157.47(15) . . . . ?
Rh4 C31 Rh3 C44 37.42(8) . . . . ?
C32 C31 Rh3 Cl3 66.55(17) . . . . ?
C38 C31 Rh3 Cl3 -69.06(16) . . . . ?
Rh4 C31 Rh3 Cl3 170.89(3) . . . . ?
C32 C31 Rh3 Rh4 -104.34(17) . . . . ?
C38 C31 Rh3 Rh4 120.05(17) . . . . ?
C32 C31 Rh3 As2 -154.16(15) . . . . ?
C38 C31 Rh3 As2 70.23(14) . . . . ?
Rh4 C31 Rh3 As2 -49.82(5) . . . . ?
C51 C44 Rh3 C31 -157.51(16) . . . . ?
C45 C44 Rh3 C31 74.17(18) . . . . ?
Rh4 C44 Rh3 C31 -37.63(8) . . . . ?
C51 C44 Rh3 Cl3 71.90(17) . . . . ?
C45 C44 Rh3 Cl3 -56.43(19) . . . . ?
Rh4 C44 Rh3 Cl3 -168.22(3) . . . . ?
C51 C44 Rh3 Rh4 -119.88(17) . . . . ?
C45 C44 Rh3 Rh4 111.79(19) . . . . ?
C51 C44 Rh3 As2 -69.23(15) . . . . ?
C45 C44 Rh3 As2 162.44(17) . . . . ?
Rh4 C44 Rh3 As2 50.64(5) . . . . ?
C59 As2 Rh3 C31 121.52(14) . . . . ?
C57 As2 Rh3 C31 -40.86(12) . . . . ?
C58 As2 Rh3 C31 -139.86(11) . . . . ?
Rh4 As2 Rh3 C31 45.69(6) . . . . ?
C59 As2 Rh3 C44 29.71(14) . . . . ?
C57 As2 Rh3 C44 -132.67(12) . . . . ?
C58 As2 Rh3 C44 128.33(11) . . . . ?
Rh4 As2 Rh3 C44 -46.12(6) . . . . ?
C59 As2 Rh3 Cl3 -106.86(12) . . . . ?
C57 As2 Rh3 Cl3 90.75(10) . . . . ?
C58 As2 Rh3 Cl3 -8.24(10) . . . . ?
Rh4 As2 Rh3 Cl3 177.30(3) . . . . ?
C59 As2 Rh3 Rh4 75.83(12) . . . . ?
C57 As2 Rh3 Rh4 -86.55(10) . . . . ?
C58 As2 Rh3 Rh4 174.45(9) . . . . ?
C51 C44 Rh4 C31 144.01(18) . . . . ?
C45 C44 Rh4 C31 -78.19(16) . . . . ?
Rh3 C44 Rh4 C31 35.90(8) . . . . ?
C51 C44 Rh4 Cl4 -52.08(18) . . . 3_565 ?
C45 C44 Rh4 Cl4 85.72(15) . . . 3_565 ?
Rh3 C44 Rh4 Cl4 -160.18(5) . . . 3_565 ?
C51 C44 Rh4 As2 54.56(17) . . . . ?
C45 C44 Rh4 As2 -167.64(15) . . . . ?
Rh3 C44 Rh4 As2 -53.54(5) . . . . ?
C51 C44 Rh4 Cl4 -101.7(4) . . . . ?
C45 C44 Rh4 Cl4 36.1(5) . . . . ?
Rh3 C44 Rh4 Cl4 150.2(3) . . . . ?
C51 C44 Rh4 Rh3 108.11(19) . . . . ?
C45 C44 Rh4 Rh3 -114.09(17) . . . . ?
C32 C31 Rh4 C44 78.78(16) . . . . ?
C38 C31 Rh4 C44 -145.04(18) . . . . ?
Rh3 C31 Rh4 C44 -36.30(8) . . . . ?
C32 C31 Rh4 Cl4 -22.4(3) . . . 3_565 ?
C38 C31 Rh4 Cl4 113.8(2) . . . 3_565 ?
Rh3 C31 Rh4 Cl4 -137.45(19) . . . 3_565 ?
C32 C31 Rh4 As2 167.75(15) . . . . ?
C38 C31 Rh4 As2 -56.07(17) . . . . ?
Rh3 C31 Rh4 As2 52.68(5) . . . . ?
C32 C31 Rh4 Cl4 -92.00(15) . . . . ?
C38 C31 Rh4 Cl4 44.18(18) . . . . ?
Rh3 C31 Rh4 Cl4 152.92(5) . . . . ?
C32 C31 Rh4 Rh3 115.07(17) . . . . ?
C38 C31 Rh4 Rh3 -108.75(19) . . . . ?
C59 As2 Rh4 C44 -86.74(13) . . . . ?
C57 As2 Rh4 C44 166.82(11) . . . . ?
C58 As2 Rh4 C44 34.24(19) . . . . ?
Rh3 As2 Rh4 C44 44.54(6) . . . . ?
C59 As2 Rh4 C31 -174.68(13) . . . . ?
C57 As2 Rh4 C31 78.89(11) . . . . ?
C58 As2 Rh4 C31 -53.69(19) . . . . ?
Rh3 As2 Rh4 C31 -43.39(6) . . . . ?
C59 As2 Rh4 Cl4 8.28(11) . . . 3_565 ?
C57 As2 Rh4 Cl4 -98.15(9) . . . 3_565 ?
C58 As2 Rh4 Cl4 129.27(18) . . . 3_565 ?
Rh3 As2 Rh4 Cl4 139.567(17) . . . 3_565 ?
C59 As2 Rh4 Cl4 89.16(11) . . . . ?
C57 As2 Rh4 Cl4 -17.27(9) . . . . ?
C58 As2 Rh4 Cl4 -149.86(18) . . . . ?
Rh3 As2 Rh4 Cl4 -139.556(16) . . . . ?
C59 As2 Rh4 Rh3 -131.28(11) . . . . ?
C57 As2 Rh4 Rh3 122.28(9) . . . . ?
C58 As2 Rh4 Rh3 -10.30(18) . . . . ?
Rh4 Cl4 Rh4 C44 50.8(4) 3_565 . . . ?
Rh4 Cl4 Rh4 C31 164.39(6) 3_565 . . . ?
Rh4 Cl4 Rh4 Cl4 0.0 3_565 . . 3_565 ?
Rh4 Cl4 Rh4 As2 -105.098(19) 3_565 . . . ?
Rh4 Cl4 Rh4 Rh3 -164.252(14) 3_565 . . . ?
C31 Rh3 Rh4 C44 129.81(11) . . . . ?
Cl3 Rh3 Rh4 C44 77.43(14) . . . . ?
As2 Rh3 Rh4 C44 -114.41(8) . . . . ?
C44 Rh3 Rh4 C31 -129.81(11) . . . . ?
Cl3 Rh3 Rh4 C31 -52.38(14) . . . . ?
As2 Rh3 Rh4 C31 115.78(8) . . . . ?
C31 Rh3 Rh4 Cl4 162.36(9) . . . 3_565 ?
C44 Rh3 Rh4 Cl4 32.55(8) . . . 3_565 ?
Cl3 Rh3 Rh4 Cl4 109.98(12) . . . 3_565 ?
As2 Rh3 Rh4 Cl4 -81.86(3) . . . 3_565 ?
C31 Rh3 Rh4 As2 -115.78(8) . . . . ?
C44 Rh3 Rh4 As2 114.41(8) . . . . ?
Cl3 Rh3 Rh4 As2 -168.16(12) . . . . ?
C31 Rh3 Rh4 Cl4 -42.71(8) . . . . ?
C44 Rh3 Rh4 Cl4 -172.52(8) . . . . ?
Cl3 Rh3 Rh4 Cl4 -95.08(12) . . . . ?
As2 Rh3 Rh4 Cl4 73.08(2) . . . . ?
