#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:29:40 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179847 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/43/7014378.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014378
loop_
_publ_author_name
'Meinholz, Margret M.'
'Pandey, Sushil K.'
'Deuerlein, Stephan M.'
'Stalke, Dietmar'
_publ_section_title
;
 Access to new Janus head ligands: linking sulfur diimides and
 phosphanes for hemilabile tripodal scorpionates.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1662
_journal_page_last               1671
_journal_paper_doi               10.1039/c0dt00665c
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C24 H64 Li2 N4 P2 S2 Si4'
_chemical_formula_weight         661.09
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.7850(10)
_cell_angle_beta                 117.3660(10)
_cell_angle_gamma                103.4460(10)
_cell_formula_units_Z            1
_cell_length_a                   10.6002(6)
_cell_length_b                   10.6350(10)
_cell_length_c                   10.7744(6)
_cell_measurement_reflns_used    9920
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.125
_cell_measurement_theta_min      2.5065
_cell_volume                     986.48(12)
_computing_cell_refinement       'SAINT V7.46A'
_computing_data_collection       'APEX2 v2.2-0'
_computing_data_reduction        'SAINT V7.46A'
_computing_molecular_graphics    'XSHELL v4.01'
_computing_publication_material  'XSHELL v4.01'
_computing_structure_refinement  'SHELXL in SHELXTL v2008/4'
_computing_structure_solution    'SHELXS in SHELXTL v2008/4'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker TXS-Mo rotating anode'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'INCOATEC Helios mirror optics'
_diffrn_radiation_source         'Bruker TXS-Mo rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0146
_diffrn_reflns_av_sigmaI/netI    0.0074
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            39887
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_diffrn_reflns_theta_min         2.50
_exptl_absorpt_coefficient_mu    0.357
_exptl_absorpt_correction_T_max  0.9893
_exptl_absorpt_correction_T_min  0.8587
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS-2008/2
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.113
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             360
_exptl_crystal_size_max          0.75
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.686
_refine_diff_density_min         -0.453
_refine_diff_density_rms         0.049
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     181
_refine_ls_number_reflns         4676
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0277
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0396P)²+0.4560P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0747
_refine_ls_wR_factor_ref         0.0768
_reflns_number_gt                4365
_reflns_number_total             4676
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT00665C.TXT
_cod_data_source_block           p-1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7014378
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.03063(16) 0.53036(15) 0.25222(17) 0.0340(3) Uani 1 1 d . . .
H1A H 0.0014 0.5787 0.1805 0.051 Uiso 1 1 calc R . .
H1B H -0.0577 0.4858 0.2578 0.051 Uiso 1 1 calc R . .
H1C H 0.0660 0.4606 0.2203 0.051 Uiso 1 1 calc R . .
C2 C 0.10781(17) 0.77313(16) 0.50719(18) 0.0344(3) Uani 1 1 d . . .
H2A H 0.1870 0.8373 0.6074 0.052 Uiso 1 1 calc R . .
H2B H 0.0213 0.7183 0.5096 0.052 Uiso 1 1 calc R . .
H2C H 0.0734 0.8249 0.4400 0.052 Uiso 1 1 calc R . .
C3 C 0.25392(18) 0.55830(15) 0.56846(18) 0.0343(3) Uani 1 1 d . . .
H3A H 0.2921 0.4945 0.5312 0.051 Uiso 1 1 calc R . .
H3B H 0.1686 0.5064 0.5743 0.051 Uiso 1 1 calc R . .
H3C H 0.3359 0.6227 0.6676 0.051 Uiso 1 1 calc R . .
C4 C 0.89791(17) 0.84578(17) 0.72055(17) 0.0362(3) Uani 1 1 d . . .
H4A H 0.8420 0.7462 0.6787 0.054 Uiso 1 1 calc R . .
H4B H 0.9907 0.8686 0.8169 0.054 Uiso 1 1 calc R . .
H4C H 0.9256 0.8756 0.6527 0.054 Uiso 1 1 calc R . .
C5 C 0.71900(17) 0.87026(15) 0.87042(15) 0.0316(3) Uani 1 1 d . . .
H5A H 0.6386 0.9012 0.8697 0.047 Uiso 1 1 calc R . .
H5B H 0.8080 0.9059 0.9719 0.047 Uiso 1 1 calc R . .
H5C H 0.6812 0.7695 0.8347 0.047 Uiso 1 1 calc R . .
C6 C 0.88623(15) 1.12360(14) 0.83362(15) 0.0282(3) Uani 1 1 d . . .
H6A H 0.9523 1.1491 0.7949 0.042 Uiso 1 1 calc R . .
H6B H 0.9490 1.1472 0.9416 0.042 Uiso 1 1 calc R . .
H6C H 0.8161 1.1736 0.8106 0.042 Uiso 1 1 calc R . .
C7 C 0.51522(15) 0.68832(12) 0.33825(14) 0.0227(2) Uani 1 1 d . . .
H7 H 0.6175 0.6796 0.3799 0.027 Uiso 1 1 calc R . .
C8 C 0.39809(18) 0.54279(14) 0.24487(17) 0.0331(3) Uani 1 1 d . . .
H8A H 0.4050 0.4875 0.3093 0.050 Uiso 1 1 calc R . .
H8B H 0.4185 0.5014 0.1702 0.050 Uiso 1 1 calc R . .
H8C H 0.2954 0.5460 0.1951 0.050 Uiso 1 1 calc R . .
C9 C 0.35850(15) 0.72585(14) 0.05206(14) 0.0277(3) Uani 1 1 d . . .
H9A H 0.3677 0.6388 0.0127 0.033 Uiso 1 1 calc R . .
H9B H 0.2623 0.7025 0.0517 0.033 Uiso 1 1 calc R . .
C10 C 0.3517(2) 0.81040(17) -0.04908(16) 0.0391(3) Uani 1 1 d . . .
H10A H 0.3497 0.8994 -0.0068 0.059 Uiso 1 1 calc R . .
H10B H 0.2592 0.7610 -0.1477 0.059 Uiso 1 1 calc R . .
H10C H 0.4417 0.8252 -0.0577 0.059 Uiso 1 1 calc R . .
C11 C 0.68650(15) 0.82307(14) 0.22816(16) 0.0283(3) Uani 1 1 d . . .
H11A H 0.6980 0.8878 0.1756 0.034 Uiso 1 1 calc R . .
H11B H 0.7782 0.8619 0.3298 0.034 Uiso 1 1 calc R . .
C12 C 0.68595(18) 0.68781(16) 0.14904(18) 0.0356(3) Uani 1 1 d . . .
H12A H 0.6778 0.6227 0.2009 0.053 Uiso 1 1 calc R . .
H12B H 0.7809 0.7045 0.1491 0.053 Uiso 1 1 calc R . .
H12C H 0.5988 0.6494 0.0463 0.053 Uiso 1 1 calc R . .
Li1 Li 0.4151(2) 0.9641(2) 0.5438(2) 0.0213(4) Uani 1 1 d . . .
N1 N 0.33293(11) 0.75951(10) 0.43262(11) 0.01938(19) Uani 1 1 d . . .
N2 N 0.61443(11) 0.90764(10) 0.57732(11) 0.01837(19) Uani 1 1 d . . .
P1 P 0.52025(4) 0.81858(3) 0.24417(3) 0.02007(8) Uani 1 1 d . . .
S1 S 0.49701(3) 0.74885(3) 0.49762(3) 0.01809(8) Uani 1 1 d . . .
Si1 Si 0.18756(4) 0.65625(3) 0.43937(4) 0.02178(8) Uani 1 1 d . . .
Si2 Si 0.77471(4) 0.93548(3) 0.74601(4) 0.01909(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 C1 H1A 109.5 . . ?
Si1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Si1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Si1 C2 H2A 109.5 . . ?
Si1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Si1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si2 C4 H4A 109.5 . . ?
Si2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si2 C5 H5A 109.5 . . ?
Si2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
Si2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
Si2 C6 H6A 109.5 . . ?
Si2 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si2 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 S1 107.92(9) . . ?
C8 C7 P1 118.47(9) . . ?
S1 C7 P1 111.63(6) . . ?
C8 C7 H7 106.0 . . ?
S1 C7 H7 106.0 . . ?
P1 C7 H7 106.0 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C10 C9 P1 112.08(10) . . ?
C10 C9 H9A 109.2 . . ?
P1 C9 H9A 109.2 . . ?
C10 C9 H9B 109.2 . . ?
P1 C9 H9B 109.2 . . ?
H9A C9 H9B 107.9 . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 P1 117.80(10) . . ?
C12 C11 H11A 107.9 . . ?
P1 C11 H11A 107.9 . . ?
C12 C11 H11B 107.9 . . ?
P1 C11 H11B 107.9 . . ?
H11A C11 H11B 107.2 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N1 Li1 N2 117.92(11) . 2_676 ?
N1 Li1 N2 73.19(8) . . ?
N2 Li1 N2 110.54(10) 2_676 . ?
N1 Li1 Li1 97.38(12) . 2_676 ?
N2 Li1 Li1 58.80(9) 2_676 2_676 ?
N2 Li1 Li1 51.74(8) . 2_676 ?
N1 Li1 P1 154.66(11) . 2_676 ?
N2 Li1 P1 83.25(7) 2_676 2_676 ?
N2 Li1 P1 114.22(9) . 2_676 ?
Li1 Li1 P1 106.03(12) 2_676 2_676 ?
N1 Li1 S1 36.41(4) . . ?
N2 Li1 S1 125.63(10) 2_676 . ?
N2 Li1 S1 37.35(4) . . ?
Li1 Li1 S1 76.24(10) 2_676 . ?
P1 Li1 S1 141.66(9) 2_676 . ?
S1 N1 Si1 123.87(6) . . ?
S1 N1 Li1 94.40(8) . . ?
Si1 N1 Li1 117.57(8) . . ?
S1 N2 Si2 112.80(6) . . ?
S1 N2 Li1 118.62(8) . 2_676 ?
Si2 N2 Li1 127.08(8) . 2_676 ?
S1 N2 Li1 86.64(7) . . ?
Si2 N2 Li1 126.67(8) . . ?
Li1 N2 Li1 69.46(10) 2_676 . ?
C11 P1 C9 103.00(6) . . ?
C11 P1 C7 100.84(6) . . ?
C9 P1 C7 103.57(6) . . ?
C11 P1 Li1 111.58(6) . 2_676 ?
C9 P1 Li1 133.73(7) . 2_676 ?
C7 P1 Li1 99.18(6) . 2_676 ?
N1 S1 N2 104.22(5) . . ?
N1 S1 C7 106.57(6) . . ?
N2 S1 C7 102.80(6) . . ?
N1 S1 Li1 49.19(6) . . ?
N2 S1 Li1 56.02(6) . . ?
C7 S1 Li1 122.99(6) . . ?
N1 Si1 C1 112.28(6) . . ?
N1 Si1 C3 112.57(6) . . ?
C1 Si1 C3 108.21(7) . . ?
N1 Si1 C2 106.28(6) . . ?
C1 Si1 C2 108.07(7) . . ?
C3 Si1 C2 109.30(7) . . ?
N2 Si2 C6 107.83(5) . . ?
N2 Si2 C4 111.48(6) . . ?
C6 Si2 C4 108.69(7) . . ?
N2 Si2 C5 110.75(6) . . ?
C6 Si2 C5 110.25(7) . . ?
C4 Si2 C5 107.82(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 Si1 1.8698(14) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 Si1 1.8736(14) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 Si1 1.8703(15) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 Si2 1.8712(14) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 Si2 1.8741(14) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 Si2 1.8597(14) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.5246(18) . ?
C7 S1 1.8300(12) . ?
C7 P1 1.8682(13) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.525(2) . ?
C9 P1 1.8395(13) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.5259(19) . ?
C11 P1 1.8389(13) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
Li1 N1 2.028(2) . ?
Li1 N2 2.219(2) . ?
Li1 P1 2.622(2) 2_676 ?
N1 S1 1.5906(10) . ?
N1 Si1 1.7122(11) . ?
N2 S1 1.6235(10) . ?
N2 Si2 1.7330(10) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Li1 N1 S1 113.09(11) 2_676 . . . ?
N2 Li1 N1 S1 8.33(6) . . . . ?
Li1 Li1 N1 S1 54.59(12) 2_676 . . . ?
P1 Li1 N1 S1 -103.0(2) 2_676 . . . ?
N2 Li1 N1 Si1 -114.79(11) 2_676 . . . ?
N2 Li1 N1 Si1 140.46(7) . . . . ?
Li1 Li1 N1 Si1 -173.29(9) 2_676 . . . ?
P1 Li1 N1 Si1 29.2(3) 2_676 . . . ?
S1 Li1 N1 Si1 132.12(9) . . . . ?
N1 Li1 N2 S1 -8.15(6) . . . . ?
N2 Li1 N2 S1 -122.30(10) 2_676 . . . ?
Li1 Li1 N2 S1 -122.30(10) 2_676 . . . ?
P1 Li1 N2 S1 145.92(8) 2_676 . . . ?
N1 Li1 N2 Si2 -124.27(8) . . . . ?
N2 Li1 N2 Si2 121.58(10) 2_676 . . . ?
Li1 Li1 N2 Si2 121.58(10) 2_676 . . . ?
P1 Li1 N2 Si2 29.81(13) 2_676 . . . ?
S1 Li1 N2 Si2 -116.11(9) . . . . ?
N1 Li1 N2 Li1 114.15(11) . . . 2_676 ?
N2 Li1 N2 Li1 0.0 2_676 . . 2_676 ?
P1 Li1 N2 Li1 -91.77(11) 2_676 . . 2_676 ?
S1 Li1 N2 Li1 122.30(10) . . . 2_676 ?
C12 C11 P1 C9 -51.05(13) . . . . ?
C12 C11 P1 C7 55.78(12) . . . . ?
C12 C11 P1 Li1 160.28(11) . . . 2_676 ?
C10 C9 P1 C11 -69.46(12) . . . . ?
C10 C9 P1 C7 -174.19(10) . . . . ?
C10 C9 P1 Li1 68.54(14) . . . 2_676 ?
C8 C7 P1 C11 -102.25(11) . . . . ?
S1 C7 P1 C11 131.48(7) . . . . ?
C8 C7 P1 C9 4.13(11) . . . . ?
S1 C7 P1 C9 -122.15(7) . . . . ?
C8 C7 P1 Li1 143.53(10) . . . 2_676 ?
S1 C7 P1 Li1 17.26(8) . . . 2_676 ?
Si1 N1 S1 N2 -138.92(7) . . . . ?
Li1 N1 S1 N2 -11.28(8) . . . . ?
Si1 N1 S1 C7 112.78(8) . . . . ?
Li1 N1 S1 C7 -119.57(8) . . . . ?
Si1 N1 S1 Li1 -127.64(11) . . . . ?
Si2 N2 S1 N1 138.91(6) . . . . ?
Li1 N2 S1 N1 -54.09(10) 2_676 . . . ?
Li1 N2 S1 N1 10.28(8) . . . . ?
Si2 N2 S1 C7 -110.03(7) . . . . ?
Li1 N2 S1 C7 56.96(10) 2_676 . . . ?
Li1 N2 S1 C7 121.34(7) . . . . ?
Si2 N2 S1 Li1 128.63(9) . . . . ?
Li1 N2 S1 Li1 -64.38(11) 2_676 . . . ?
C8 C7 S1 N1 -65.34(10) . . . . ?
P1 C7 S1 N1 66.51(8) . . . . ?
C8 C7 S1 N2 -174.64(9) . . . . ?
P1 C7 S1 N2 -42.78(8) . . . . ?
C8 C7 S1 Li1 -117.04(10) . . . . ?
P1 C7 S1 Li1 14.81(10) . . . . ?
N2 Li1 S1 N1 -89.94(13) 2_676 . . . ?
N2 Li1 S1 N1 -166.78(10) . . . . ?
Li1 Li1 S1 N1 -123.68(13) 2_676 . . . ?
P1 Li1 S1 N1 137.75(17) 2_676 . . . ?
N1 Li1 S1 N2 166.78(10) . . . . ?
N2 Li1 S1 N2 76.84(12) 2_676 . . . ?
Li1 Li1 S1 N2 43.10(8) 2_676 . . . ?
P1 Li1 S1 N2 -55.47(13) 2_676 . . . ?
N1 Li1 S1 C7 83.61(9) . . . . ?
N2 Li1 S1 C7 -6.33(15) 2_676 . . . ?
N2 Li1 S1 C7 -83.17(8) . . . . ?
Li1 Li1 S1 C7 -40.07(12) 2_676 . . . ?
P1 Li1 S1 C7 -138.63(12) 2_676 . . . ?
S1 N1 Si1 C1 -109.09(8) . . . . ?
Li1 N1 Si1 C1 133.86(9) . . . . ?
S1 N1 Si1 C3 13.33(10) . . . . ?
Li1 N1 Si1 C3 -103.72(10) . . . . ?
S1 N1 Si1 C2 132.95(8) . . . . ?
Li1 N1 Si1 C2 15.91(10) . . . . ?
S1 N2 Si2 C6 -173.50(6) . . . . ?
Li1 N2 Si2 C6 20.84(11) 2_676 . . . ?
Li1 N2 Si2 C6 -69.99(10) . . . . ?
S1 N2 Si2 C4 67.26(9) . . . . ?
Li1 N2 Si2 C4 -98.40(11) 2_676 . . . ?
Li1 N2 Si2 C4 170.77(10) . . . . ?
S1 N2 Si2 C5 -52.79(8) . . . . ?
Li1 N2 Si2 C5 141.55(10) 2_676 . . . ?
Li1 N2 Si2 C5 50.73(11) . . . . ?
