#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:55:11 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179870 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/66/7016615.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016615
loop_
_publ_author_name
'Flores, Jaime A.'
'Kobayashi, Yoshihiro'
'Dias, H. V. Rasika'
_publ_section_title
;
 Synthesis and characterization of silver(i) adducts supported solely
 by 1,3,5-triazapentadienyl ligands or by triazapentadienyl and other
 N-donors.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10351
_journal_page_last               10359
_journal_paper_doi               10.1039/c1dt10199d
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C22 H9 Ag Cl4 F14 N4'
_chemical_formula_weight         845.00
_chemical_name_common            {[N{(C3F7)C(2,6-Cl2C6H3)N}2]AgNCCH3}n
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.350(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   20.1753(12)
_cell_length_b                   16.8846(10)
_cell_length_c                   18.9949(11)
_cell_measurement_reflns_used    9848
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.24
_cell_measurement_theta_min      2.31
_cell_volume                     5798.3(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_av_sigmaI/netI    0.0359
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            40248
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.70
_exptl_absorpt_coefficient_mu    1.177
_exptl_absorpt_correction_T_max  0.9086
_exptl_absorpt_correction_T_min  0.7318
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             3280
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.755
_refine_diff_density_min         -0.700
_refine_diff_density_rms         0.117
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     813
_refine_ls_number_reflns         11119
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0572
_refine_ls_R_factor_gt           0.0451
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0650P)²+9.0254P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1113
_refine_ls_wR_factor_ref         0.1212
_reflns_number_gt                9010
_reflns_number_total             11119
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10199d.txt
_cod_data_source_block           dias345a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7016615
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.491087(17) 1.091638(17) 0.312387(18) 0.02580(10) Uani 1 1 d .
Ag2 Ag 0.022251(17) 0.571001(17) 0.200651(18) 0.02740(10) Uani 1 1 d .
Cl1 Cl 0.66959(6) 0.98916(6) 0.36877(6) 0.0317(2) Uani 1 1 d .
Cl2 Cl 0.43231(6) 1.00487(6) 0.08460(6) 0.0315(2) Uani 1 1 d .
Cl3 Cl 0.59596(9) 0.78722(9) 0.10114(10) 0.0641(4) Uani 1 1 d .
Cl4 Cl 0.34403(7) 0.70180(7) 0.11203(7) 0.0467(3) Uani 1 1 d .
Cl5 Cl 0.17293(6) 0.66560(6) 0.27177(7) 0.0384(3) Uani 1 1 d .
Cl6 Cl -0.06652(6) 0.78476(6) 0.02479(6) 0.0378(3) Uani 1 1 d .
Cl7 Cl 0.02508(7) 0.99709(7) 0.11784(7) 0.0426(3) Uani 1 1 d .
Cl8 Cl -0.18761(6) 0.93216(7) 0.20760(7) 0.0383(3) Uani 1 1 d .
N1 N 0.50691(17) 0.98371(18) 0.25884(18) 0.0204(7) Uani 1 1 d .
N2 N 0.50144(18) 0.85398(18) 0.21406(18) 0.0221(7) Uani 1 1 d .
N3 N 0.50618(19) 0.72315(19) 0.1782(2) 0.0264(7) Uani 1 1 d .
N4 N 0.4741(4) 1.0807(3) 0.4267(3) 0.0705(17) Uani 1 1 d .
N5 N 0.01251(17) 0.70094(19) 0.1820(2) 0.0270(7) Uani 1 1 d .
N6 N -0.00922(19) 0.83248(18) 0.20575(19) 0.0267(7) Uani 1 1 d .
N7 N -0.03210(18) 0.96002(18) 0.23573(18) 0.0242(7) Uani 1 1 d .
N8 N 0.0687(3) 0.5418(3) 0.0994(3) 0.0667(14) Uani 1 1 d .
C1 C 0.4850(2) 0.9101(2) 0.2524(2) 0.0191(8) Uani 1 1 d .
C2 C 0.5185(2) 0.7785(2) 0.2304(2) 0.0210(8) Uani 1 1 d .
C3 C 0.4262(2) 0.8932(2) 0.2820(2) 0.0227(8) Uani 1 1 d .
C4 C 0.3476(2) 0.9249(2) 0.2269(2) 0.0237(8) Uani 1 1 d .
C5 C 0.2896(2) 0.9174(3) 0.2583(3) 0.0322(10) Uani 1 1 d .
C6 C 0.5664(2) 0.7529(2) 0.3158(2) 0.0276(9) Uani 1 1 d .
C7 C 0.6478(2) 0.7374(2) 0.3343(3) 0.0349(10) Uani 1 1 d .
C8 C 0.7028(3) 0.7312(3) 0.4224(3) 0.0488(13) Uani 1 1 d .
C9 C 0.5554(2) 1.0002(2) 0.2237(2) 0.0214(8) Uani 1 1 d .
C10 C 0.6315(2) 1.0083(2) 0.2686(2) 0.0257(8) Uani 1 1 d .
C11 C 0.6777(2) 1.0310(2) 0.2357(3) 0.0324(10) Uani 1 1 d .
H11 H 0.7292 1.0379 0.2678 0.039 Uiso 1 1 calc R
C12 C 0.6481(3) 1.0435(3) 0.1563(3) 0.0361(10) Uani 1 1 d .
H12 H 0.6796 1.0585 0.1335 0.043 Uiso 1 1 calc R
C13 C 0.5726(2) 1.0345(2) 0.1085(3) 0.0314(9) Uani 1 1 d .
H13 H 0.5527 1.0424 0.0534 0.038 Uiso 1 1 calc R
C14 C 0.5274(2) 1.0140(2) 0.1425(2) 0.0258(8) Uani 1 1 d .
C15 C 0.4661(3) 0.7462(2) 0.0986(2) 0.0321(10) Uani 1 1 d .
C16 C 0.5016(3) 0.7729(3) 0.0546(3) 0.0473(13) Uani 1 1 d .
C17 C 0.4606(4) 0.7854(3) -0.0268(3) 0.0612(18) Uani 1 1 d .
H17 H 0.4854 0.8022 -0.0566 0.073 Uiso 1 1 calc R
C18 C 0.3864(4) 0.7736(3) -0.0633(3) 0.0652(19) Uani 1 1 d .
H18 H 0.3598 0.7824 -0.1183 0.078 Uiso 1 1 calc R
C19 C 0.3493(4) 0.7493(3) -0.0217(3) 0.0589(17) Uani 1 1 d .
H19 H 0.2973 0.7414 -0.0472 0.071 Uiso 1 1 calc R
C20 C 0.3897(3) 0.7363(2) 0.0589(3) 0.0390(11) Uani 1 1 d .
C21 C 0.4362(4) 1.0726(3) 0.4573(3) 0.0564(15) Uani 1 1 d .
C22 C 0.3910(3) 1.0617(4) 0.4937(3) 0.0684(18) Uani 1 1 d .
H22A H 0.3394 1.0578 0.4539 0.103 Uiso 1 1 calc R
H22B H 0.3964 1.1067 0.5284 0.103 Uiso 1 1 calc R
H22C H 0.4051 1.0128 0.5247 0.103 Uiso 1 1 calc R
C23 C -0.0146(2) 0.7546(2) 0.2112(2) 0.0258(9) Uani 1 1 d .
C24 C -0.0012(2) 0.8911(2) 0.2549(2) 0.0235(8) Uani 1 1 d .
C25 C -0.0657(2) 0.7232(2) 0.2457(3) 0.0298(9) Uani 1 1 d .
C26 C -0.1432(2) 0.6989(2) 0.1824(3) 0.0363(11) Uani 1 1 d .
C27 C -0.2001(3) 0.6759(3) 0.2124(4) 0.0504(13) Uani 1 1 d .
C28 C 0.0585(2) 0.8821(2) 0.3401(2) 0.0265(9) Uani 1 1 d .
C29 C 0.1360(2) 0.9091(2) 0.3528(2) 0.0273(9) Uani 1 1 d .
C30 C 0.1920(3) 0.9232(3) 0.4380(3) 0.0481(13) Uani 1 1 d .
C31 C 0.0572(2) 0.7293(2) 0.1467(3) 0.0291(9) Uani 1 1 d .
C32 C 0.1329(2) 0.7139(2) 0.1813(3) 0.0327(10) Uani 1 1 d .
C33 C 0.1778(3) 0.7336(3) 0.1454(3) 0.0414(11) Uani 1 1 d .
H33 H 0.2290 0.7206 0.1697 0.050 Uiso 1 1 calc R
C34 C 0.1468(3) 0.7724(3) 0.0741(3) 0.0473(13) Uani 1 1 d .
H34 H 0.1772 0.7878 0.0499 0.057 Uiso 1 1 calc R
C35 C 0.0718(3) 0.7891(3) 0.0373(3) 0.0409(11) Uani 1 1 d .
H35 H 0.0506 0.8157 -0.0119 0.049 Uiso 1 1 calc R
C36 C 0.0275(2) 0.7665(2) 0.0732(3) 0.0316(9) Uani 1 1 d .
C37 C -0.0862(2) 0.9684(2) 0.1552(2) 0.0275(9) Uani 1 1 d .
C38 C -0.0679(3) 0.9887(2) 0.0956(3) 0.0353(10) Uani 1 1 d .
C39 C -0.1215(3) 1.0017(3) 0.0198(3) 0.0473(13) Uani 1 1 d .
H39 H -0.1074 1.0168 -0.0198 0.057 Uiso 1 1 calc R
C40 C -0.1945(3) 0.9931(3) 0.0014(3) 0.0555(15) Uani 1 1 d .
H40 H -0.2309 1.0019 -0.0510 0.067 Uiso 1 1 calc R
C41 C -0.2159(3) 0.9715(3) 0.0591(3) 0.0469(13) Uani 1 1 d .
H41 H -0.2667 0.9649 0.0466 0.056 Uiso 1 1 calc R
C42 C -0.1613(2) 0.9596(2) 0.1354(3) 0.0336(10) Uani 1 1 d .
C43 C 0.0882(4) 0.4843(4) 0.0812(4) 0.0618(16) Uani 1 1 d .
C44 C 0.1084(5) 0.4096(4) 0.0607(5) 0.087(2) Uani 1 1 d .
H44A H 0.1025 0.3679 0.0934 0.131 Uiso 1 1 calc R
H44B H 0.1600 0.4115 0.0695 0.131 Uiso 1 1 calc R
H44C H 0.0764 0.3983 0.0052 0.131 Uiso 1 1 calc R
F1 F 0.44703(12) 0.92458(13) 0.35441(13) 0.0264(5) Uani 1 1 d .
F2 F 0.41867(12) 0.81382(12) 0.28768(13) 0.0254(5) Uani 1 1 d .
F3 F 0.32319(13) 0.88539(14) 0.15876(13) 0.0319(5) Uani 1 1 d .
F4 F 0.35141(13) 1.00245(13) 0.21175(15) 0.0340(6) Uani 1 1 d .
F5 F 0.30448(14) 0.96740(18) 0.31746(17) 0.0498(7) Uani 1 1 d .
F6 F 0.22372(13) 0.93631(16) 0.20160(16) 0.0412(6) Uani 1 1 d .
F7 F 0.28651(14) 0.84517(16) 0.28240(17) 0.0434(7) Uani 1 1 d .
F8 F 0.56744(12) 0.80961(13) 0.36692(13) 0.0277(5) Uani 1 1 d .
F9 F 0.53928(12) 0.68592(13) 0.33315(13) 0.0294(5) Uani 1 1 d .
F10 F 0.65319(14) 0.66943(15) 0.29983(19) 0.0497(7) Uani 1 1 d .
F11 F 0.67112(13) 0.79730(15) 0.30354(17) 0.0412(6) Uani 1 1 d .
F12 F 0.71461(16) 0.80190(18) 0.45731(18) 0.0585(8) Uani 1 1 d .
F13 F 0.67758(17) 0.6830(2) 0.45943(19) 0.0676(10) Uani 1 1 d .
F14 F 0.76693(16) 0.7044(2) 0.4291(2) 0.0741(11) Uani 1 1 d .
F15 F -0.07735(12) 0.77944(14) 0.29010(14) 0.0316(5) Uani 1 1 d .
F16 F -0.03503(13) 0.66047(14) 0.29313(15) 0.0371(6) Uani 1 1 d .
F17 F -0.17167(13) 0.75964(15) 0.13197(16) 0.0419(6) Uani 1 1 d .
F18 F -0.13666(14) 0.63653(15) 0.14152(18) 0.0487(7) Uani 1 1 d .
F19 F -0.17461(18) 0.6189(2) 0.2648(2) 0.0730(10) Uani 1 1 d .
F20 F -0.26157(16) 0.6500(2) 0.1522(2) 0.0704(10) Uani 1 1 d .
F21 F -0.21855(16) 0.73680(19) 0.2430(2) 0.0620(9) Uani 1 1 d .
F22 F 0.04034(14) 0.92429(16) 0.38985(14) 0.0391(6) Uani 1 1 d .
F23 F 0.06542(13) 0.80567(14) 0.36367(15) 0.0365(6) Uani 1 1 d .
F24 F 0.16394(15) 0.85412(18) 0.32264(19) 0.0547(8) Uani 1 1 d .
F25 F 0.13169(15) 0.97613(17) 0.31274(18) 0.0532(8) Uani 1 1 d .
F26 F 0.17716(19) 0.9955(2) 0.46170(19) 0.0679(10) Uani 1 1 d .
F27 F 0.18901(16) 0.8726(2) 0.48608(17) 0.0612(9) Uani 1 1 d .
F28 F 0.25982(14) 0.92799(18) 0.44430(17) 0.0497(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N3 150.28(12) . 2_655
N1 Ag1 N4 118.52(14) . .
N3 Ag1 N4 90.69(14) 2_655 .
N7 Ag2 N5 156.17(13) 2_545 .
N7 Ag2 N8 106.18(15) 2_545 .
N5 Ag2 N8 96.17(15) . .
C1 N1 C9 114.4(3) . .
C1 N1 Ag1 136.5(3) . .
C9 N1 Ag1 109.0(2) . .
C2 N2 C1 131.6(3) . .
C2 N3 C15 116.2(3) . .
C2 N3 Ag1 131.6(3) . 2_645
C15 N3 Ag1 110.0(2) . 2_645
C21 N4 Ag1 150.9(6) . .
C23 N5 C31 116.1(3) . .
C23 N5 Ag2 130.1(3) . .
C31 N5 Ag2 112.3(2) . .
C24 N6 C23 132.5(4) . .
C24 N7 C37 115.5(3) . .
C24 N7 Ag2 134.4(3) . 2
C37 N7 Ag2 110.1(2) . 2
C43 N8 Ag2 132.9(5) . .
N1 C1 N2 125.1(3) . .
N1 C1 C3 115.1(3) . .
N2 C1 C3 119.2(3) . .
N3 C2 N2 124.8(4) . .
N3 C2 C6 114.8(3) . .
N2 C2 C6 119.7(3) . .
F1 C3 F2 107.5(3) . .
F1 C3 C1 110.7(3) . .
F2 C3 C1 109.9(3) . .
F1 C3 C4 108.3(3) . .
F2 C3 C4 106.0(3) . .
C1 C3 C4 114.1(3) . .
F3 C4 F4 107.9(3) . .
F3 C4 C5 108.5(3) . .
F4 C4 C5 106.7(3) . .
F3 C4 C3 107.9(3) . .
F4 C4 C3 109.9(3) . .
C5 C4 C3 115.8(3) . .
F7 C5 F6 108.7(3) . .
F7 C5 F5 108.9(4) . .
F6 C5 F5 107.6(3) . .
F7 C5 C4 111.9(3) . .
F6 C5 C4 109.1(4) . .
F5 C5 C4 110.5(3) . .
F8 C6 F9 107.1(3) . .
F8 C6 C2 111.1(3) . .
F9 C6 C2 111.0(3) . .
F8 C6 C7 106.2(3) . .
F9 C6 C7 107.9(3) . .
C2 C6 C7 113.3(3) . .
F10 C7 F11 108.0(4) . .
F10 C7 C6 109.9(3) . .
F11 C7 C6 108.3(3) . .
F10 C7 C8 107.1(4) . .
F11 C7 C8 107.4(4) . .
C6 C7 C8 115.9(4) . .
F13 C8 F14 109.4(4) . .
F13 C8 F12 108.3(5) . .
F14 C8 F12 107.9(4) . .
F13 C8 C7 111.0(4) . .
F14 C8 C7 109.1(5) . .
F12 C8 C7 111.1(4) . .
C10 C9 C14 116.9(4) . .
C10 C9 N1 121.8(3) . .
C14 C9 N1 121.2(3) . .
C11 C10 C9 122.0(4) . .
C11 C10 Cl1 119.1(3) . .
C9 C10 Cl1 118.9(3) . .
C12 C11 C10 119.1(4) . .
C12 C11 H11 120.4 . .
C10 C11 H11 120.4 . .
C11 C12 C13 121.2(4) . .
C11 C12 H12 119.4 . .
C13 C12 H12 119.4 . .
C14 C13 C12 118.8(4) . .
C14 C13 H13 120.6 . .
C12 C13 H13 120.6 . .
C13 C14 C9 121.9(4) . .
C13 C14 Cl2 120.0(3) . .
C9 C14 Cl2 118.1(3) . .
C20 C15 C16 117.0(4) . .
C20 C15 N3 121.0(4) . .
C16 C15 N3 121.8(4) . .
C15 C16 C17 119.9(6) . .
C15 C16 Cl3 118.9(4) . .
C17 C16 Cl3 121.2(4) . .
C18 C17 C16 121.0(5) . .
C18 C17 H17 119.5 . .
C16 C17 H17 119.5 . .
C17 C18 C19 120.7(5) . .
C17 C18 H18 119.7 . .
C19 C18 H18 119.7 . .
C18 C19 C20 118.5(6) . .
C18 C19 H19 120.7 . .
C20 C19 H19 120.7 . .
C15 C20 C19 122.8(5) . .
C15 C20 Cl4 118.0(3) . .
C19 C20 Cl4 119.1(4) . .
N4 C21 C22 179.2(6) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N5 C23 N6 126.3(4) . .
N5 C23 C25 115.4(3) . .
N6 C23 C25 117.9(3) . .
N7 C24 N6 125.6(4) . .
N7 C24 C28 116.1(3) . .
N6 C24 C28 117.6(3) . .
F16 C25 F15 106.8(3) . .
F16 C25 C23 111.0(3) . .
F15 C25 C23 110.8(3) . .
F16 C25 C26 108.5(3) . .
F15 C25 C26 106.0(3) . .
C23 C25 C26 113.4(4) . .
F17 C26 F18 107.7(4) . .
F17 C26 C27 107.7(4) . .
F18 C26 C27 107.2(4) . .
F17 C26 C25 108.4(3) . .
F18 C26 C25 109.3(3) . .
C27 C26 C25 116.2(4) . .
F19 C27 F21 109.3(5) . .
F19 C27 F20 108.2(4) . .
F21 C27 F20 107.3(4) . .
F19 C27 C26 111.1(4) . .
F21 C27 C26 111.7(4) . .
F20 C27 C26 109.1(5) . .
F23 C28 F22 106.9(3) . .
F23 C28 C24 111.2(3) . .
F22 C28 C24 110.7(3) . .
F23 C28 C29 106.3(3) . .
F22 C28 C29 107.7(3) . .
C24 C28 C29 113.7(3) . .
F24 C29 F25 106.0(4) . .
F24 C29 C30 107.9(4) . .
F25 C29 C30 107.4(4) . .
F24 C29 C28 108.5(3) . .
F25 C29 C28 110.7(3) . .
C30 C29 C28 115.8(4) . .
F27 C30 F28 110.7(4) . .
F27 C30 F26 105.8(5) . .
F28 C30 F26 106.5(4) . .
F27 C30 C29 114.0(4) . .
F28 C30 C29 110.8(4) . .
F26 C30 C29 108.6(4) . .
C32 C31 C36 116.7(4) . .
C32 C31 N5 120.3(4) . .
C36 C31 N5 122.6(4) . .
C31 C32 C33 122.6(4) . .
C31 C32 Cl5 119.0(3) . .
C33 C32 Cl5 118.4(4) . .
C34 C33 C32 118.9(4) . .
C34 C33 H33 120.6 . .
C32 C33 H33 120.6 . .
C33 C34 C35 120.7(4) . .
C33 C34 H34 119.7 . .
C35 C34 H34 119.7 . .
C34 C35 C36 119.3(5) . .
C34 C35 H35 120.3 . .
C36 C35 H35 120.3 . .
C35 C36 C31 121.7(4) . .
C35 C36 Cl6 118.6(4) . .
C31 C36 Cl6 119.6(3) . .
C38 C37 C42 117.3(4) . .
C38 C37 N7 122.9(4) . .
C42 C37 N7 119.8(4) . .
C37 C38 C39 121.6(5) . .
C37 C38 Cl7 118.3(3) . .
C39 C38 Cl7 120.1(4) . .
C40 C39 C38 120.5(5) . .
C40 C39 H39 119.7 . .
C38 C39 H39 119.7 . .
C39 C40 C41 120.2(5) . .
C39 C40 H40 119.9 . .
C41 C40 H40 119.9 . .
C42 C41 C40 118.6(5) . .
C42 C41 H41 120.7 . .
C40 C41 H41 120.7 . .
C41 C42 C37 121.8(5) . .
C41 C42 Cl8 118.9(4) . .
C37 C42 Cl8 119.3(3) . .
N8 C43 C44 175.2(7) . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.178(3) .
Ag1 N3 2.227(3) 2_655
Ag1 N4 2.350(5) .
Ag2 N7 2.190(3) 2_545
Ag2 N5 2.217(3) .
Ag2 N8 2.535(5) .
Cl1 C10 1.737(4) .
Cl2 C14 1.743(4) .
Cl3 C16 1.724(6) .
Cl4 C20 1.742(5) .
Cl5 C32 1.743(5) .
Cl6 C36 1.729(4) .
Cl7 C38 1.737(5) .
Cl8 C42 1.738(5) .
N1 C1 1.307(5) .
N1 C9 1.435(5) .
N2 C2 1.321(5) .
N2 C1 1.324(5) .
N3 C2 1.304(5) .
N3 C15 1.416(5) .
N3 Ag1 2.226(3) 2_645
N4 C21 1.158(8) .
N5 C23 1.303(5) .
N5 C31 1.424(5) .
N6 C24 1.320(5) .
N6 C23 1.327(5) .
N7 C24 1.294(5) .
N7 C37 1.438(5) .
N7 Ag2 2.190(3) 2
N8 C43 1.156(7) .
C1 C3 1.548(5) .
C2 C6 1.536(5) .
C3 F1 1.354(4) .
C3 F2 1.358(4) .
C3 C4 1.556(5) .
C4 F3 1.341(4) .
C4 F4 1.351(4) .
C4 C5 1.537(6) .
C5 F7 1.314(5) .
C5 F6 1.326(5) .
C5 F5 1.328(5) .
C6 F8 1.358(5) .
C6 F9 1.359(4) .
C6 C7 1.543(6) .
C7 F10 1.349(5) .
C7 F11 1.352(5) .
C7 C8 1.548(7) .
C8 F13 1.316(6) .
C8 F14 1.321(6) .
C8 F12 1.335(6) .
C9 C10 1.394(6) .
C9 C14 1.406(6) .
C10 C11 1.386(6) .
C11 C12 1.369(6) .
C11 H11 0.9500 .
C12 C13 1.392(6) .
C12 H12 0.9500 .
C13 C14 1.376(6) .
C13 H13 0.9500 .
C15 C20 1.393(7) .
C15 C16 1.394(7) .
C16 C17 1.409(8) .
C17 C18 1.357(9) .
C17 H17 0.9500 .
C18 C19 1.370(9) .
C18 H18 0.9500 .
C19 C20 1.396(7) .
C19 H19 0.9500 .
C21 C22 1.379(8) .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C25 1.542(6) .
C24 C28 1.536(5) .
C25 F16 1.349(5) .
C25 F15 1.358(5) .
C25 C26 1.546(6) .
C26 F17 1.346(5) .
C26 F18 1.349(5) .
C26 C27 1.540(7) .
C27 F19 1.314(6) .
C27 F21 1.314(6) .
C27 F20 1.333(6) .
C28 F23 1.352(5) .
C28 F22 1.358(5) .
C28 C29 1.543(6) .
C29 F24 1.339(5) .
C29 F25 1.345(5) .
C29 C30 1.526(6) .
C30 F27 1.272(6) .
C30 F28 1.321(5) .
C30 F26 1.378(6) .
C31 C32 1.392(6) .
C31 C36 1.399(6) .
C32 C33 1.396(6) .
C33 C34 1.380(7) .
C33 H33 0.9500 .
C34 C35 1.386(7) .
C34 H34 0.9500 .
C35 C36 1.397(6) .
C35 H35 0.9500 .
C37 C38 1.381(6) .
C37 C42 1.397(6) .
C38 C39 1.382(6) .
C39 C40 1.361(8) .
C39 H39 0.9500 .
C40 C41 1.393(8) .
C40 H40 0.9500 .
C41 C42 1.392(6) .
C41 H41 0.9500 .
C43 C44 1.431(8) .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
