#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:58:42 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179873 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/69/7016911.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016911
loop_
_publ_author_name
'Khan, Muhammad S.'
'Al-Suti, Mohammed K'
'Shah, Hakkikulla H.'
'Al-Humaimi, Said'
'Al-Battashi, Fathiya R'
'Bjernemose, Jens K.'
'Male, Louise'
'Raithby, Paul R.'
'Zhang, Ning'
'Köhler, Anna'
'Warren, John E.'
_publ_section_title
;
 Synthesis and characterization of platinum(ii) di-ynes and poly-ynes
 incorporating ethylenedioxythiophene (EDOT) spacers in the backbone.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10174
_journal_page_last               10183
_journal_paper_doi               10.1039/c1dt11010a
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C52 H78 O4 P4 Pt2 S2'
_chemical_formula_sum            'C52 H78 O4 P4 Pt2 S2'
_chemical_formula_weight         1345.32
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2011-04-27T20:17:46-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 101.078(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   42.980(4)
_cell_length_b                   13.4875(13)
_cell_length_c                   9.8161(9)
_cell_measurement_reflns_used    8618
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.9
_cell_measurement_theta_min      2.64
_cell_measurement_wavelength     0.6775
_cell_volume                     5584.3(9)
_computing_cell_refinement       'SAINT (Bruker, 2003)'
_computing_data_collection       'APEX2 (Bruker, 2003)'
_computing_data_reduction        'SAINT (Bruker, 2003)'
_computing_molecular_graphics    'WinGX (Farrugia, 2005)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF (Buerskens, 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector                 APEXII
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device       'Burker APEX II Diffractometer'
_diffrn_measurement_device_type  'Bruker APEXII'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'silicon 111'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.6775
_diffrn_reflns_av_R_equivalents  0.0978
_diffrn_reflns_av_unetI/netI     0.0607
_diffrn_reflns_limit_h_max       61
_diffrn_reflns_limit_h_min       -61
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            31903
_diffrn_reflns_reduction_process "'Bruker APEX2 software'"
_diffrn_reflns_theta_full        28.95
_diffrn_reflns_theta_max         28.95
_diffrn_reflns_theta_min         1.51
_diffrn_source                   synchrotron
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.446
_exptl_absorpt_correction_T_max  0.8083
_exptl_absorpt_correction_T_min  0.4701
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.1 (Bruker, 2003)'
_exptl_crystal_colour            'Pale yellow'
_exptl_crystal_density_diffrn    1.6
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_F_000             2680
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.267
_refine_diff_density_min         -1.367
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.976
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     313
_refine_ls_number_reflns         8384
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.983
_refine_ls_R_factor_all          0.0325
_refine_ls_R_factor_gt           0.0283
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0336P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0722
_refine_ls_wR_factor_ref         0.0738
_reflns_number_gt                7251
_reflns_number_total             8384
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt11010a.txt
_cod_data_source_block           bath99
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7016911
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.15158(7) 0.2546(2) 1.0091(3) 0.0220(5) Uani 1 1 d . . .
C2 C 0.17103(7) 0.27189(19) 1.1109(3) 0.0222(5) Uani 1 1 d . . .
C3 C 0.19396(6) 0.2889(2) 1.2333(3) 0.0207(5) Uani 1 1 d . . .
C4 C 0.19984(6) 0.37289(19) 1.3128(3) 0.0194(5) Uani 1 1 d . A .
C5 C 0.22425(6) 0.3610(2) 1.4313(3) 0.0200(5) Uani 1 1 d . A .
C6 C 0.23738(6) 0.26806(18) 1.4462(3) 0.0186(5) Uani 1 1 d . . .
C7 C 0.18834(13) 0.5299(3) 1.3971(5) 0.0296(14) Uani 0.713(12) 1 d P A 1
H7A H 0.1755 0.5101 1.4664 0.035 Uiso 0.713(12) 1 calc PR A 1
H7B H 0.1814 0.5968 1.3626 0.035 Uiso 0.713(12) 1 calc PR A 1
C8 C 0.22292(16) 0.5322(4) 1.4642(7) 0.0315(13) Uani 0.713(12) 1 d P A 1
H8A H 0.2355 0.5519 1.3943 0.038 Uiso 0.713(12) 1 calc PR A 1
H8B H 0.2263 0.5826 1.5389 0.038 Uiso 0.713(12) 1 calc PR A 1
C7' C 0.2020(3) 0.5431(6) 1.3476(12) 0.021(3) Uani 0.287(12) 1 d P A 2
H7'1 H 0.189 0.6043 1.3368 0.025 Uiso 0.287(12) 1 calc PR A 2
H7'2 H 0.2206 0.5538 1.3035 0.025 Uiso 0.287(12) 1 calc PR A 2
C8' C 0.2129(4) 0.5186(10) 1.5022(15) 0.026(3) Uani 0.287(12) 1 d P A 2
H8'1 H 0.2236 0.5773 1.5509 0.031 Uiso 0.287(12) 1 calc PR A 2
H8'2 H 0.1942 0.5031 1.5433 0.031 Uiso 0.287(12) 1 calc PR A 2
C9 C 0.07872(6) 0.2014(2) 0.6805(3) 0.0260(6) Uani 1 1 d . . .
C10 C 0.07026(8) 0.2661(3) 0.5672(4) 0.0376(8) Uani 1 1 d . . .
H10 H 0.0821 0.3251 0.5632 0.045 Uiso 1 1 calc R . .
C11 C 0.04469(10) 0.2447(4) 0.4607(4) 0.0539(11) Uani 1 1 d . . .
H11 H 0.0395 0.2892 0.3847 0.065 Uiso 1 1 calc R . .
C12 C 0.02669(9) 0.1604(4) 0.4633(5) 0.0646(14) Uani 1 1 d . . .
H12 H 0.0092 0.1468 0.3904 0.078 Uiso 1 1 calc R . .
C13 C 0.03446(9) 0.0966(4) 0.5729(5) 0.0613(12) Uani 1 1 d . . .
H13 H 0.0223 0.0381 0.5762 0.074 Uiso 1 1 calc R . .
C14 C 0.06015(8) 0.1166(3) 0.6802(4) 0.0424(8) Uani 1 1 d . . .
H14 H 0.0651 0.0711 0.7552 0.051 Uiso 1 1 calc R . .
C15 C 0.04220(7) 0.3288(3) 0.8790(4) 0.0391(8) Uani 1 1 d . . .
H15A H 0.0412 0.3539 0.7835 0.047 Uiso 1 1 calc R . .
H15B H 0.0323 0.2622 0.8715 0.047 Uiso 1 1 calc R . .
C16 C 0.02252(8) 0.3969(3) 0.9525(5) 0.0540(11) Uani 1 1 d . . .
H16A H 0.0221 0.3707 1.0452 0.081 Uiso 1 1 calc R . .
H16B H 0.0008 0.4006 0.8987 0.081 Uiso 1 1 calc R . .
H16C H 0.0319 0.4633 0.9608 0.081 Uiso 1 1 calc R . .
C17 C 0.09795(7) 0.4430(2) 0.9933(3) 0.0268(6) Uani 1 1 d . . .
H17A H 0.0842 0.4782 1.0475 0.032 Uiso 1 1 calc R . .
H17B H 0.1198 0.4423 1.0489 0.032 Uiso 1 1 calc R . .
C18 C 0.09777(9) 0.4986(3) 0.8571(4) 0.0389(7) Uani 1 1 d . . .
H18A H 0.1127 0.4669 0.8067 0.058 Uiso 1 1 calc R . .
H18B H 0.1041 0.5676 0.8774 0.058 Uiso 1 1 calc R . .
H18C H 0.0764 0.4968 0.8001 0.058 Uiso 1 1 calc R . .
C19 C 0.08306(8) 0.2663(2) 1.1344(4) 0.0310(7) Uani 1 1 d . . .
H19A H 0.1049 0.2642 1.1893 0.037 Uiso 1 1 calc R . .
H19B H 0.0704 0.3112 1.1823 0.037 Uiso 1 1 calc R . .
C20 C 0.06869(9) 0.1620(3) 1.1274(5) 0.0469(9) Uani 1 1 d . . .
H20A H 0.0465 0.1648 1.0798 0.07 Uiso 1 1 calc R . .
H20B H 0.0699 0.1365 1.2217 0.07 Uiso 1 1 calc R . .
H20C H 0.0805 0.118 1.0763 0.07 Uiso 1 1 calc R . .
C21 C 0.14870(7) 0.2176(2) 0.5516(3) 0.0254(6) Uani 1 1 d . . .
H21A H 0.1644 0.1858 0.5039 0.03 Uiso 1 1 calc R . .
H21B H 0.1275 0.2102 0.4915 0.03 Uiso 1 1 calc R . .
C22 C 0.15643(8) 0.3276(2) 0.5695(4) 0.0364(7) Uani 1 1 d . . .
H22A H 0.1412 0.3596 0.6179 0.055 Uiso 1 1 calc R . .
H22B H 0.1552 0.3583 0.4781 0.055 Uiso 1 1 calc R . .
H22C H 0.1779 0.3357 0.624 0.055 Uiso 1 1 calc R . .
C23 C 0.13804(7) 0.0269(2) 0.6604(3) 0.0259(6) Uani 1 1 d . . .
H23A H 0.1162 0.0263 0.6051 0.031 Uiso 1 1 calc R . .
H23B H 0.1525 0.0029 0.6 0.031 Uiso 1 1 calc R . .
C24 C 0.13988(8) -0.0431(2) 0.7832(3) 0.0353(7) Uani 1 1 d . . .
H24A H 0.1609 -0.0385 0.8426 0.053 Uiso 1 1 calc R . .
H24B H 0.1361 -0.1113 0.7494 0.053 Uiso 1 1 calc R . .
H24C H 0.1237 -0.0247 0.8368 0.053 Uiso 1 1 calc R . .
C25 C 0.19079(7) 0.1455(3) 0.7980(3) 0.0323(7) Uani 1 1 d . . .
H25A H 0.1992 0.2137 0.8143 0.039 Uiso 1 1 calc R . .
H25B H 0.1923 0.1134 0.8897 0.039 Uiso 1 1 calc R . .
C26 C 0.21174(7) 0.0884(3) 0.7156(4) 0.0379(8) Uani 1 1 d . . .
H26A H 0.2337 0.0882 0.7672 0.057 Uiso 1 1 calc R . .
H26B H 0.2109 0.1204 0.6253 0.057 Uiso 1 1 calc R . .
H26C H 0.2041 0.02 0.7015 0.057 Uiso 1 1 calc R . .
O1 O 0.18321(5) 0.45960(15) 1.2819(2) 0.0265(4) Uani 1 1 d . . .
O2 O 0.23402(5) 0.43720(15) 1.5222(2) 0.0276(4) Uani 1 1 d . . .
P1 P 0.083927(16) 0.31542(6) 0.96151(7) 0.02276(14) Uani 1 1 d . . .
P2 P 0.148818(16) 0.15340(5) 0.71485(7) 0.02025(13) Uani 1 1 d . . .
S1 S 0.219456(15) 0.19394(5) 1.30780(7) 0.02164(13) Uani 1 1 d . . .
Pt1 Pt 0.116162(2) 0.229165(7) 0.842724(9) 0.01790(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0027 0.0015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0097 0.0055 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0946 0.0859 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1156 0.1126 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.275 7.788 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 Pt1 176.0(3) . .
C1 C2 C3 177.9(3) . .
C4 C3 C2 129.6(3) . .
C4 C3 S1 109.5(2) . .
C2 C3 S1 120.8(2) . .
C3 C4 O1 123.1(2) . .
C3 C4 C5 113.6(2) . .
O1 C4 C5 123.3(2) . .
C6 C5 O2 123.2(2) . .
C6 C5 C4 114.5(2) . .
O2 C5 C4 122.3(2) . .
C5 C6 C6 128.4(3) . 7_558
C5 C6 S1 109.30(19) . .
C6 C6 S1 122.3(3) 7_558 .
O1 C7 C8 110.0(5) . .
O1 C7 H7A 109.7 . .
C8 C7 H7A 109.7 . .
O1 C7 H7B 109.7 . .
C8 C7 H7B 109.7 . .
H7A C7 H7B 108.2 . .
O2 C8 C7 112.2(5) . .
O2 C8 H8A 109.2 . .
C7 C8 H8A 109.2 . .
O2 C8 H8B 109.2 . .
C7 C8 H8B 109.2 . .
H8A C8 H8B 107.9 . .
O1 C7' C8' 107.9(10) . .
O1 C7' H7'1 110.1 . .
C8' C7' H7'1 110.1 . .
O1 C7' H7'2 110.1 . .
C8' C7' H7'2 110.1 . .
H7'1 C7' H7'2 108.4 . .
O2 C8' C7' 111.7(10) . .
O2 C8' H8'1 109.3 . .
C7' C8' H8'1 109.3 . .
O2 C8' H8'2 109.3 . .
C7' C8' H8'2 109.3 . .
H8'1 C8' H8'2 107.9 . .
C14 C9 C10 116.6(3) . .
C14 C9 Pt1 120.7(2) . .
C10 C9 Pt1 122.8(3) . .
C11 C10 C9 120.8(4) . .
C11 C10 H10 119.6 . .
C9 C10 H10 119.6 . .
C12 C11 C10 121.4(4) . .
C12 C11 H11 119.3 . .
C10 C11 H11 119.3 . .
C13 C12 C11 118.7(3) . .
C13 C12 H12 120.6 . .
C11 C12 H12 120.6 . .
C12 C13 C14 120.6(4) . .
C12 C13 H13 119.7 . .
C14 C13 H13 119.7 . .
C9 C14 C13 121.9(4) . .
C9 C14 H14 119 . .
C13 C14 H14 119 . .
C16 C15 P1 115.9(3) . .
C16 C15 H15A 108.3 . .
P1 C15 H15A 108.3 . .
C16 C15 H15B 108.3 . .
P1 C15 H15B 108.3 . .
H15A C15 H15B 107.4 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 P1 111.4(2) . .
C18 C17 H17A 109.3 . .
P1 C17 H17A 109.3 . .
C18 C17 H17B 109.3 . .
P1 C17 H17B 109.3 . .
H17A C17 H17B 108 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 P1 111.8(3) . .
C20 C19 H19A 109.3 . .
P1 C19 H19A 109.3 . .
C20 C19 H19B 109.3 . .
P1 C19 H19B 109.3 . .
H19A C19 H19B 107.9 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 P2 113.5(2) . .
C22 C21 H21A 108.9 . .
P2 C21 H21A 108.9 . .
C22 C21 H21B 108.9 . .
P2 C21 H21B 108.9 . .
H21A C21 H21B 107.7 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 P2 112.1(2) . .
C24 C23 H23A 109.2 . .
P2 C23 H23A 109.2 . .
C24 C23 H23B 109.2 . .
P2 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26 C25 P2 115.0(2) . .
C26 C25 H25A 108.5 . .
P2 C25 H25A 108.5 . .
C26 C25 H25B 108.5 . .
P2 C25 H25B 108.5 . .
H25A C25 H25B 107.5 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C4 O1 C7 112.8(2) . .
C4 O1 C7' 109.8(4) . .
C7 O1 C7' 33.8(4) . .
C5 O2 C8' 112.6(6) . .
C5 O2 C8 111.8(3) . .
C8' O2 C8 26.1(5) . .
C19 P1 C15 104.68(17) . .
C19 P1 C17 104.31(14) . .
C15 P1 C17 104.23(15) . .
C19 P1 Pt1 114.22(11) . .
C15 P1 Pt1 117.51(11) . .
C17 P1 Pt1 110.64(10) . .
C21 P2 C23 103.29(13) . .
C21 P2 C25 104.80(15) . .
C23 P2 C25 104.44(15) . .
C21 P2 Pt1 111.76(10) . .
C23 P2 Pt1 115.47(10) . .
C25 P2 Pt1 115.77(11) . .
C6 S1 C3 93.05(13) . .
C1 Pt1 C9 177.13(11) . .
C1 Pt1 P1 86.46(9) . .
C9 Pt1 P1 91.52(8) . .
C1 Pt1 P2 94.14(9) . .
C9 Pt1 P2 88.02(8) . .
P1 Pt1 P2 175.75(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.195(4) .
C1 Pt1 2.037(3) .
C2 C3 1.419(4) .
C3 C4 1.371(4) .
C3 S1 1.752(3) .
C4 O1 1.374(3) .
C4 C5 1.418(4) .
C5 C6 1.371(4) .
C5 O2 1.373(3) .
C6 C6 1.446(5) 7_558
C6 S1 1.742(3) .
C7 O1 1.459(5) .
C7 C8 1.506(9) .
C7 H7A 0.99 .
C7 H7B 0.99 .
C8 O2 1.445(6) .
C8 H8A 0.99 .
C8 H8B 0.99 .
C7' O1 1.461(9) .
C7' C8' 1.536(19) .
C7' H7'1 0.99 .
C7' H7'2 0.99 .
C8' O2 1.413(13) .
C8' H8'1 0.99 .
C8' H8'2 0.99 .
C9 C14 1.394(5) .
C9 C10 1.405(5) .
C9 Pt1 2.069(3) .
C10 C11 1.394(5) .
C10 H10 0.95 .
C11 C12 1.378(7) .
C11 H11 0.95 .
C12 C13 1.368(7) .
C12 H12 0.95 .
C13 C14 1.398(5) .
C13 H13 0.95 .
C14 H14 0.95 .
C15 C16 1.521(5) .
C15 P1 1.829(3) .
C15 H15A 0.99 .
C15 H15B 0.99 .
C16 H16A 0.98 .
C16 H16B 0.98 .
C16 H16C 0.98 .
C17 C18 1.532(4) .
C17 P1 1.830(3) .
C17 H17A 0.99 .
C17 H17B 0.99 .
C18 H18A 0.98 .
C18 H18B 0.98 .
C18 H18C 0.98 .
C19 C20 1.533(5) .
C19 P1 1.828(3) .
C19 H19A 0.99 .
C19 H19B 0.99 .
C20 H20A 0.98 .
C20 H20B 0.98 .
C20 H20C 0.98 .
C21 C22 1.522(4) .
C21 P2 1.820(3) .
C21 H21A 0.99 .
C21 H21B 0.99 .
C22 H22A 0.98 .
C22 H22B 0.98 .
C22 H22C 0.98 .
C23 C24 1.522(4) .
C23 P2 1.821(3) .
C23 H23A 0.99 .
C23 H23B 0.99 .
C24 H24A 0.98 .
C24 H24B 0.98 .
C24 H24C 0.98 .
C25 C26 1.529(4) .
C25 P2 1.834(3) .
C25 H25A 0.99 .
C25 H25B 0.99 .
C26 H26A 0.98 .
C26 H26B 0.98 .
C26 H26C 0.98 .
P1 Pt1 2.2920(7) .
P2 Pt1 2.2950(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Pt1 C1 C2 C3 93(10) . .
C1 C2 C3 C4 -142(9) . .
C1 C2 C3 S1 36(9) . .
C2 C3 C4 O1 -0.7(5) . .
S1 C3 C4 O1 -179.0(2) . .
C2 C3 C4 C5 178.1(3) . .
S1 C3 C4 C5 -0.2(3) . .
C3 C4 C5 C6 -0.6(4) . .
O1 C4 C5 C6 178.2(2) . .
C3 C4 C5 O2 178.7(2) . .
O1 C4 C5 O2 -2.6(4) . .
O2 C5 C6 C6 0.3(5) . 7_558
C4 C5 C6 C6 179.5(3) . 7_558
O2 C5 C6 S1 -178.2(2) . .
C4 C5 C6 S1 1.1(3) . .
O1 C7 C8 O2 -61.9(8) . .
O1 C7' C8' O2 65.5(15) . .
C14 C9 C10 C11 -0.5(5) . .
Pt1 C9 C10 C11 -179.5(3) . .
C9 C10 C11 C12 0.7(6) . .
C10 C11 C12 C13 -0.4(7) . .
C11 C12 C13 C14 0.0(7) . .
C10 C9 C14 C13 0.1(5) . .
Pt1 C9 C14 C13 179.2(3) . .
C12 C13 C14 C9 0.1(6) . .
C3 C4 O1 C7 166.2(4) . .
C5 C4 O1 C7 -12.5(4) . .
C3 C4 O1 C7' -157.6(6) . .
C5 C4 O1 C7' 23.8(7) . .
C8 C7 O1 C4 42.4(6) . .
C8 C7 O1 C7' -49.5(8) . .
C8' C7' O1 C4 -51.8(11) . .
C8' C7' O1 C7 49.8(10) . .
C6 C5 O2 C8' -167.7(7) . .
C4 C5 O2 C8' 13.2(8) . .
C6 C5 O2 C8 164.1(4) . .
C4 C5 O2 C8 -15.1(5) . .
C7' C8' O2 C5 -43.7(14) . .
C7' C8' O2 C8 50.1(13) . .
C7 C8 O2 C5 46.4(7) . .
C7 C8 O2 C8' -50.6(15) . .
C20 C19 P1 C15 65.3(3) . .
C20 C19 P1 C17 174.5(2) . .
C20 C19 P1 Pt1 -64.6(3) . .
C16 C15 P1 C19 59.4(4) . .
C16 C15 P1 C17 -49.9(4) . .
C16 C15 P1 Pt1 -172.7(3) . .
C18 C17 P1 C19 -175.7(2) . .
C18 C17 P1 C15 -66.2(3) . .
C18 C17 P1 Pt1 61.0(2) . .
C22 C21 P2 C23 178.7(2) . .
C22 C21 P2 C25 -72.2(3) . .
C22 C21 P2 Pt1 53.9(2) . .
C24 C23 P2 C21 174.4(2) . .
C24 C23 P2 C25 65.0(2) . .
C24 C23 P2 Pt1 -63.3(2) . .
C26 C25 P2 C21 -60.5(3) . .
C26 C25 P2 C23 47.7(3) . .
C26 C25 P2 Pt1 175.9(2) . .
C5 C6 S1 C3 -1.0(2) . .
C6 C6 S1 C3 -179.5(3) 7_558 .
C4 C3 S1 C6 0.7(2) . .
C2 C3 S1 C6 -177.8(2) . .
C2 C1 Pt1 C9 -39(5) . .
C2 C1 Pt1 P1 7(4) . .
C2 C1 Pt1 P2 -18E1(10) . .
C14 C9 Pt1 C1 -45(2) . .
C10 C9 Pt1 C1 134(2) . .
C14 C9 Pt1 P1 -90.1(3) . .
C10 C9 Pt1 P1 88.8(3) . .
C14 C9 Pt1 P2 94.1(3) . .
C10 C9 Pt1 P2 -86.9(3) . .
C19 P1 Pt1 C1 -55.72(15) . .
C15 P1 Pt1 C1 -178.91(17) . .
C17 P1 Pt1 C1 61.60(13) . .
C19 P1 Pt1 C9 122.23(16) . .
C15 P1 Pt1 C9 -0.96(18) . .
C17 P1 Pt1 C9 -120.45(14) . .
C19 P1 Pt1 P2 -154.0(3) . .
C15 P1 Pt1 P2 82.8(4) . .
C17 P1 Pt1 P2 -36.7(4) . .
C21 P2 Pt1 C1 -120.79(14) . .
C23 P2 Pt1 C1 121.53(13) . .
C25 P2 Pt1 C1 -0.92(15) . .
C21 P2 Pt1 C9 61.10(15) . .
C23 P2 Pt1 C9 -56.58(14) . .
C25 P2 Pt1 C9 -179.03(16) . .
C21 P2 Pt1 P1 -22.8(4) . .
C23 P2 Pt1 P1 -140.5(3) . .
C25 P2 Pt1 P1 97.1(3) . .
