#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:05:58 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179879 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/75/7017528.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7017528
loop_
_publ_author_name
'Wu, Jing-Yun'
'Zhong, Ming-Shiou'
'Chiang, Ming-Hsi'
'Tsai, Meng-Rong'
'Lai, Long-Li'
_publ_section_title
;
 Synthesis, characterization and structural transformation of a discrete
 tetragonal metalloprism.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              156
_journal_page_last               164
_journal_paper_doi               10.1039/c1dt10949a
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C48 H56 Cu2 N20 O24'
_chemical_formula_weight         1424.21
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.808(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.1789(13)
_cell_length_b                   12.8654(9)
_cell_length_c                   23.3516(16)
_cell_measurement_reflns_used    4228
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      24.97
_cell_measurement_theta_min      2.37
_cell_volume                     5775.6(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Giacovazzo et al, 1993)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_sigmaI/netI    0.0644
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            18090
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         1.90
_exptl_absorpt_coefficient_mu    0.839
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6675
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS, 1996'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2936
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.405
_refine_diff_density_min         -0.422
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     456
_refine_ls_number_reflns         5036
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0803
_refine_ls_R_factor_gt           0.0423
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0279P)²+11.4180P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0826
_refine_ls_wR_factor_ref         0.0953
_reflns_number_gt                3422
_reflns_number_total             5036
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10949a.txt
_cod_data_source_block           cpd1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7017528
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.96813(18) 0.7254(3) 0.46613(16) 0.0315(9) Uani 1 1 d . . .
H1A H 0.9912 0.6591 0.4806 0.038 Uiso 1 1 calc R . .
H1B H 1.0014 0.7728 0.4617 0.038 Uiso 1 1 calc R . .
C2 C 1.00217(16) 0.8154(3) 0.56939(16) 0.0261(8) Uani 1 1 d . . .
H2A H 1.0312 0.8568 0.5553 0.031 Uiso 1 1 calc R . .
H2B H 1.0309 0.7610 0.5967 0.031 Uiso 1 1 calc R . .
C3 C 0.84436(18) 0.6735(3) 0.39849(17) 0.0261(8) Uani 1 1 d . . .
H3 H 0.8412 0.6514 0.4351 0.031 Uiso 1 1 calc R . .
C4 C 0.90766(17) 0.7110(2) 0.40318(16) 0.0241(8) Uani 1 1 d . . .
C5 C 0.91258(19) 0.7367(3) 0.34815(17) 0.0327(9) Uani 1 1 d . . .
H5 H 0.9549 0.7583 0.3491 0.039 Uiso 1 1 calc R . .
C6 C 0.8550(2) 0.7303(3) 0.29179(18) 0.0375(10) Uani 1 1 d . . .
H6 H 0.8578 0.7479 0.2543 0.045 Uiso 1 1 calc R . .
C7 C 0.79268(19) 0.6973(3) 0.29140(17) 0.0308(9) Uani 1 1 d . . .
H7 H 0.7532 0.6958 0.2534 0.037 Uiso 1 1 calc R . .
C8 C 0.91771(17) 0.8549(3) 0.61754(15) 0.0256(8) Uani 1 1 d . . .
H8 H 0.8973 0.7904 0.6034 0.031 Uiso 1 1 calc R . .
C9 C 0.97453(16) 0.8832(3) 0.60622(15) 0.0233(8) Uani 1 1 d . . .
C10 C 1.00555(18) 0.9784(3) 0.62900(16) 0.0297(9) Uani 1 1 d . . .
H10 H 1.0434 1.0004 0.6217 0.036 Uiso 1 1 calc R . .
C11 C 0.9799(2) 1.0399(3) 0.66245(18) 0.0374(10) Uani 1 1 d . . .
H11 H 1.0013 1.1027 0.6795 0.045 Uiso 1 1 calc R . .
C12 C 0.92210(19) 1.0076(3) 0.67049(17) 0.0315(9) Uani 1 1 d . . .
H12 H 0.9043 1.0505 0.6922 0.038 Uiso 1 1 calc R . .
C13 C 0.67141(19) 1.0392(3) 0.34599(17) 0.0344(9) Uani 1 1 d . . .
H13A H 0.7140 1.0602 0.3432 0.041 Uiso 1 1 calc R . .
H13B H 0.6374 1.0941 0.3279 0.041 Uiso 1 1 calc R . .
C14 C 0.69365(18) 1.1244(3) 0.44841(17) 0.0312(9) Uani 1 1 d . . .
H14A H 0.6524 1.1666 0.4271 0.037 Uiso 1 1 calc R . .
H14B H 0.7329 1.1621 0.4476 0.037 Uiso 1 1 calc R . .
C15 C 0.67745(18) 0.8465(3) 0.33123(17) 0.0282(9) Uani 1 1 d . . .
H15 H 0.7181 0.8462 0.3683 0.034 Uiso 1 1 calc R . .
C16 C 0.64472(19) 0.9405(3) 0.30903(17) 0.0308(9) Uani 1 1 d . . .
C17 C 0.5867(2) 0.9397(3) 0.25218(19) 0.0435(11) Uani 1 1 d . . .
H17 H 0.5638 1.0014 0.2349 0.052 Uiso 1 1 calc R . .
C18 C 0.5629(2) 0.8471(3) 0.22109(19) 0.0463(11) Uani 1 1 d . . .
H18 H 0.5243 0.8458 0.1824 0.056 Uiso 1 1 calc R . .
C19 C 0.5965(2) 0.7570(3) 0.24775(18) 0.0379(10) Uani 1 1 d . . .
H19 H 0.5790 0.6944 0.2274 0.046 Uiso 1 1 calc R . .
C20 C 0.74638(17) 1.0292(3) 0.55236(17) 0.0270(8) Uani 1 1 d . . .
H20 H 0.7687 0.9858 0.5348 0.032 Uiso 1 1 calc R . .
C21 C 0.70494(17) 1.1085(2) 0.51521(18) 0.0284(9) Uani 1 1 d . . .
C22 C 0.67426(18) 1.1745(3) 0.5434(2) 0.0349(10) Uani 1 1 d . . .
H22 H 0.6459 1.2287 0.5204 0.042 Uiso 1 1 calc R . .
C23 C 0.68593(19) 1.1597(3) 0.6053(2) 0.0400(10) Uani 1 1 d . . .
H23 H 0.6665 1.2048 0.6246 0.048 Uiso 1 1 calc R . .
C24 C 0.72640(19) 1.0777(3) 0.63854(19) 0.0350(9) Uani 1 1 d . . .
H24 H 0.7335 1.0675 0.6802 0.042 Uiso 1 1 calc R . .
Cu1 Cu 0.69689(2) 0.62049(3) 0.34275(2) 0.02741(14) Uani 1 1 d . . .
N1 N 0.94516(13) 0.7672(2) 0.51374(12) 0.0247(7) Uani 1 1 d . . .
H101 H 0.9118 0.8151 0.4951 0.030 Uiso 1 1 calc R . .
H102 H 0.9263 0.7152 0.5271 0.030 Uiso 1 1 calc R . .
N2 N 0.78779(15) 0.6674(2) 0.34417(13) 0.0260(7) Uani 1 1 d . . .
N3 N 0.89079(14) 0.9169(2) 0.64819(13) 0.0252(7) Uani 1 1 d . . .
N4 N 0.68525(14) 1.0245(2) 0.41369(13) 0.0277(7) Uani 1 1 d . . .
H103 H 0.6498 0.9886 0.4158 0.033 Uiso 1 1 calc R . .
H104 H 0.7242 0.9864 0.4328 0.033 Uiso 1 1 calc R . .
N5 N 0.65360(15) 0.7558(2) 0.30206(13) 0.0273(7) Uani 1 1 d . . .
N6 N 0.75608(14) 1.0117(2) 0.61192(14) 0.0278(7) Uani 1 1 d . . .
N7 N 0.67727(17) 0.5348(3) 0.20395(16) 0.0379(8) Uani 1 1 d . . .
O1 O 0.65563(12) 0.53262(19) 0.24778(11) 0.0342(6) Uani 1 1 d . . .
O2 O 0.7143(2) 0.4635(2) 0.20165(18) 0.0793(12) Uani 1 1 d . . .
O3 O 0.66138(14) 0.6088(2) 0.16655(12) 0.0482(8) Uani 1 1 d . . .
N8 N 0.63656(15) 0.4952(2) 0.03157(13) 0.0276(7) Uani 1 1 d . . .
O4 O 0.65495(13) 0.58458(18) 0.02671(12) 0.0387(7) Uani 1 1 d . . .
O5 O 0.67746(12) 0.41927(18) 0.03702(11) 0.0302(6) Uani 1 1 d . . .
O6 O 0.57867(12) 0.47690(18) 0.03107(11) 0.0328(6) Uani 1 1 d . . .
N9 N 0.52999(17) 0.0202(3) 0.92033(15) 0.0362(8) Uani 1 1 d . . .
O7 O 0.57776(13) 0.08742(19) 0.92850(12) 0.0394(7) Uani 1 1 d . . .
O8 O 0.53932(14) -0.0690(2) 0.90715(15) 0.0582(9) Uani 1 1 d . . .
O9 O 0.47641(14) 0.0470(2) 0.92504(13) 0.0507(8) Uani 1 1 d . . .
N10 N 1.0000 0.7159(5) 0.2500 0.0539(17) Uani 1 2 d SD . .
O10 O 1.0000 0.6194(10) 0.2500 0.094(7) Uani 0.50 2 d SP A 1
O10' O 0.9877(12) 0.6371(12) 0.2104(9) 0.092(9) Uani 0.25 1 d PD . 2
O11 O 0.9405(8) 0.7454(11) 0.2013(6) 0.075(4) Uani 0.50 1 d P A 1
O11' O 0.9502(7) 0.7703(8) 0.2282(5) 0.052(3) Uani 0.50 1 d P A 2
N11 N 0.7438(5) 0.2376(8) 1.0007(6) 0.0213(17) Uiso 0.50 1 d P B -1
O12 O 0.6897(2) 0.1805(3) 0.9752(2) 0.0247(11) Uani 0.50 1 d P B -1
O13 O 0.7531(3) 0.3027(4) 0.9619(3) 0.0262(13) Uani 0.50 1 d P B -1
O14 O 0.7818(3) 0.2336(5) 1.0545(3) 0.0271(14) Uani 0.50 1 d P B -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C4 111.3(3) . .
N1 C1 H1A 109.4 . .
C4 C1 H1A 109.4 . .
N1 C1 H1B 109.4 . .
C4 C1 H1B 109.4 . .
H1A C1 H1B 108.0 . .
N1 C2 C9 111.9(3) . .
N1 C2 H2A 109.2 . .
C9 C2 H2A 109.2 . .
N1 C2 H2B 109.2 . .
C9 C2 H2B 109.2 . .
H2A C2 H2B 107.9 . .
N2 C3 C4 123.3(3) . .
N2 C3 H3 118.3 . .
C4 C3 H3 118.3 . .
C5 C4 C3 117.5(3) . .
C5 C4 C1 121.2(3) . .
C3 C4 C1 121.3(3) . .
C6 C5 C4 119.9(3) . .
C6 C5 H5 120.1 . .
C4 C5 H5 120.1 . .
C5 C6 C7 119.1(3) . .
C5 C6 H6 120.4 . .
C7 C6 H6 120.4 . .
N2 C7 C6 121.7(3) . .
N2 C7 H7 119.1 . .
C6 C7 H7 119.1 . .
N3 C8 C9 122.8(3) . .
N3 C8 H8 118.6 . .
C9 C8 H8 118.6 . .
C8 C9 C10 117.9(3) . .
C8 C9 C2 122.3(3) . .
C10 C9 C2 119.7(3) . .
C11 C10 C9 119.4(3) . .
C11 C10 H10 120.3 . .
C9 C10 H10 120.3 . .
C10 C11 C12 119.3(3) . .
C10 C11 H11 120.3 . .
C12 C11 H11 120.3 . .
N3 C12 C11 122.3(3) . .
N3 C12 H12 118.9 . .
C11 C12 H12 118.9 . .
N4 C13 C16 111.1(3) . .
N4 C13 H13A 109.4 . .
C16 C13 H13A 109.4 . .
N4 C13 H13B 109.4 . .
C16 C13 H13B 109.4 . .
H13A C13 H13B 108.0 . .
N4 C14 C21 112.4(3) . .
N4 C14 H14A 109.1 . .
C21 C14 H14A 109.1 . .
N4 C14 H14B 109.1 . .
C21 C14 H14B 109.1 . .
H14A C14 H14B 107.9 . .
N5 C15 C16 123.3(3) . .
N5 C15 H15 118.3 . .
C16 C15 H15 118.3 . .
C17 C16 C15 117.2(4) . .
C17 C16 C13 121.8(3) . .
C15 C16 C13 121.0(3) . .
C18 C17 C16 119.7(4) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
C19 C18 C17 119.2(4) . .
C19 C18 H18 120.4 . .
C17 C18 H18 120.4 . .
N5 C19 C18 122.3(4) . .
N5 C19 H19 118.9 . .
C18 C19 H19 118.9 . .
N6 C20 C21 123.7(3) . .
N6 C20 H20 118.1 . .
C21 C20 H20 118.1 . .
C20 C21 C22 116.8(4) . .
C20 C21 C14 122.5(3) . .
C22 C21 C14 120.7(3) . .
C23 C22 C21 119.9(4) . .
C23 C22 H22 120.0 . .
C21 C22 H22 120.0 . .
C22 C23 C24 119.7(3) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
N6 C24 C23 121.4(4) . .
N6 C24 H24 119.3 . .
C23 C24 H24 119.3 . .
N2 Cu1 N5 89.51(11) . .
N2 Cu1 N3 172.70(11) . 7_666
N5 Cu1 N3 89.92(11) . 7_666
N2 Cu1 N6 89.20(11) . 7_666
N5 Cu1 N6 176.89(12) . 7_666
N3 Cu1 N6 91.00(11) 7_666 7_666
N2 Cu1 O1 97.88(10) . .
N5 Cu1 O1 93.22(10) . .
N3 Cu1 O1 89.42(10) 7_666 .
N6 Cu1 O1 89.76(10) 7_666 .
C2 N1 C1 113.8(2) . .
C2 N1 H101 108.8 . .
C1 N1 H101 108.8 . .
C2 N1 H102 108.8 . .
C1 N1 H102 108.8 . .
H101 N1 H102 107.7 . .
C3 N2 C7 118.3(3) . .
C3 N2 Cu1 120.5(2) . .
C7 N2 Cu1 121.1(2) . .
C12 N3 C8 118.2(3) . .
C12 N3 Cu1 119.8(2) . 7_666
C8 N3 Cu1 121.9(2) . 7_666
C14 N4 C13 113.1(3) . .
C14 N4 H103 109.0 . .
C13 N4 H103 109.0 . .
C14 N4 H104 109.0 . .
C13 N4 H104 109.0 . .
H103 N4 H104 107.8 . .
C19 N5 C15 118.1(3) . .
C19 N5 Cu1 120.7(3) . .
C15 N5 Cu1 120.9(2) . .
C20 N6 C24 118.3(3) . .
C20 N6 Cu1 120.7(2) . 7_666
C24 N6 Cu1 120.5(3) . 7_666
O2 N7 O3 122.3(3) . .
O2 N7 O1 117.9(4) . .
O3 N7 O1 119.7(3) . .
N7 O1 Cu1 129.5(2) . .
O4 N8 O6 121.5(3) . .
O4 N8 O5 119.7(3) . .
O6 N8 O5 118.8(3) . .
O8 N9 O9 122.4(3) . .
O8 N9 O7 117.9(3) . .
O9 N9 O7 119.7(3) . .
O11' N10 O11' 107.8(12) 2_755 .
O11' N10 O10 126.1(6) 2_755 .
O11' N10 O10 126.1(6) . .
O11' N10 O10' 105.9(11) 2_755 2_755
O11' N10 O10' 129.1(12) . 2_755
O10 N10 O10' 39.9(7) . 2_755
O11' N10 O10' 129.1(12) 2_755 .
O11' N10 O10' 105.9(11) . .
O10 N10 O10' 39.9(7) . .
O10' N10 O10' 79.9(14) 2_755 .
O11' N10 O11 29.1(5) 2_755 2_755
O11' N10 O11 122.8(8) . 2_755
O10 N10 O11 106.4(6) . 2_755
O10' N10 O11 77.7(11) 2_755 2_755
O10' N10 O11 130.2(12) . 2_755
O11' N10 O11 122.8(8) 2_755 .
O11' N10 O11 29.1(5) . .
O10 N10 O11 106.4(6) . .
O10' N10 O11 130.2(12) 2_755 .
O10' N10 O11 77.7(11) . .
O11 N10 O11 147.3(12) 2_755 .
N10 O10' O10' 50.1(7) . 2_755
O14 N11 O12 123.3(13) . .
O14 N11 O13 122.3(7) . .
O12 N11 O13 114.3(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.489(4) .
C1 C4 1.502(5) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 N1 1.488(4) .
C2 C9 1.505(4) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 N2 1.332(4) .
C3 C4 1.385(5) .
C3 H3 0.9300 .
C4 C5 1.372(5) .
C5 C6 1.371(5) .
C5 H5 0.9300 .
C6 C7 1.383(5) .
C6 H6 0.9300 .
C7 N2 1.336(4) .
C7 H7 0.9300 .
C8 N3 1.348(4) .
C8 C9 1.385(4) .
C8 H8 0.9300 .
C9 C10 1.386(5) .
C10 C11 1.374(5) .
C10 H10 0.9300 .
C11 C12 1.378(5) .
C11 H11 0.9300 .
C12 N3 1.336(4) .
C12 H12 0.9300 .
C13 N4 1.494(4) .
C13 C16 1.505(5) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 N4 1.490(4) .
C14 C21 1.490(5) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 N5 1.338(4) .
C15 C16 1.383(5) .
C15 H15 0.9300 .
C16 C17 1.379(5) .
C17 C18 1.376(5) .
C17 H17 0.9300 .
C18 C19 1.365(5) .
C18 H18 0.9300 .
C19 N5 1.336(4) .
C19 H19 0.9300 .
C20 N6 1.337(4) .
C20 C21 1.387(5) .
C20 H20 0.9300 .
C21 C22 1.392(5) .
C22 C23 1.372(5) .
C22 H22 0.9300 .
C23 C24 1.375(5) .
C23 H23 0.9300 .
C24 N6 1.353(4) .
C24 H24 0.9300 .
Cu1 N2 2.004(3) .
Cu1 N5 2.011(3) .
Cu1 N3 2.013(3) 7_666
Cu1 N6 2.030(3) 7_666
Cu1 O1 2.309(2) .
N1 H101 0.9000 .
N1 H102 0.9000 .
N3 Cu1 2.013(3) 7_666
N4 H103 0.9000 .
N4 H104 0.9000 .
N6 Cu1 2.030(3) 7_666
N7 O2 1.223(4) .
N7 O3 1.239(4) .
N7 O1 1.285(4) .
N8 O4 1.235(3) .
N8 O6 1.244(3) .
N8 O5 1.276(3) .
N9 O8 1.225(4) .
N9 O9 1.234(4) .
N9 O7 1.283(4) .
N10 O11' 1.188(12) 2_755
N10 O11' 1.188(12) .
N10 O10 1.241(15) .
N10 O10' 1.323(18) 2_755
N10 O10' 1.323(18) .
N10 O11 1.349(17) 2_755
N10 O11 1.349(17) .
O10' O10' 1.70(4) 2_755
N11 O14 1.176(15) .
N11 O12 1.279(9) .
N11 O13 1.307(17) .
