#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:16:45 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179888 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/84/7018469.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018469
loop_
_publ_author_name
'Humenny, Will J.'
'Mitzinger, Stefan'
'Khadka, Chhatra B.'
'Najafabadi, Bahareh Khalili'
'Vieira, Isabelle'
'Corrigan, John F.'
_publ_section_title
;
 N-heterocyclic carbene stabilized copper- and silver-phenylchalcogenolate
 ring complexes.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4413
_journal_page_last               4422
_journal_paper_doi               10.1039/c2dt11998f
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C76 H92 Ag4 N8 S4'
_chemical_formula_weight         1677.30
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                118.415(2)
_cell_angle_beta                 100.830(3)
_cell_angle_gamma                91.347(3)
_cell_formula_units_Z            1
_cell_length_a                   12.417(2)
_cell_length_b                   13.0539(12)
_cell_length_c                   13.0767(12)
_cell_measurement_reflns_used    4441
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      18.84
_cell_measurement_theta_min      2.18
_cell_volume                     1815.3(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1520
_diffrn_reflns_av_sigmaI/netI    0.0945
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            93571
_diffrn_reflns_theta_full        28.70
_diffrn_reflns_theta_max         28.70
_diffrn_reflns_theta_min         1.68
_exptl_absorpt_coefficient_mu    1.226
_exptl_absorpt_correction_T_max  0.9618
_exptl_absorpt_correction_T_min  0.9191
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.534
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             856
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.809
_refine_diff_density_min         -0.655
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.988
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     423
_refine_ls_number_reflns         9343
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.988
_refine_ls_R_factor_all          0.1000
_refine_ls_R_factor_gt           0.0459
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0275P)²+0.9794P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0726
_refine_ls_wR_factor_ref         0.0894
_reflns_number_gt                5856
_reflns_number_total             9343
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11998f.txt
_cod_data_source_block           b10126a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7018469
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.56798(3) -0.34023(3) 0.61937(3) 0.02364(9) Uani 1 1 d .
Ag2 Ag 0.36125(3) -0.24747(3) 0.53486(3) 0.02215(9) Uani 1 1 d .
S1 S 0.55709(8) -0.19923(8) 0.53314(9) 0.0186(2) Uani 1 1 d .
S2 S 0.36082(8) -0.45419(8) 0.52646(9) 0.0192(2) Uani 1 1 d .
N1 N 0.6625(3) -0.3699(3) 0.8482(3) 0.0172(7) Uani 1 1 d .
N2 N 0.7839(3) -0.2690(3) 0.8198(3) 0.0183(7) Uani 1 1 d .
N3 N 0.2064(3) -0.0575(3) 0.6445(3) 0.0196(7) Uani 1 1 d .
N4 N 0.1072(3) -0.2082(3) 0.4871(3) 0.0202(8) Uani 1 1 d .
C1 C 0.6750(3) -0.3149(3) 0.7846(3) 0.0171(8) Uani 1 1 d .
C2 C 0.8418(3) -0.2993(3) 0.9026(3) 0.0185(9) Uani 1 1 d .
C3 C 0.9532(3) -0.2791(4) 0.9588(4) 0.0231(9) Uani 1 1 d .
H3A H 1.0062 -0.2349 0.9465 0.028 Uiso 1 1 calc R
C4 C 0.9833(3) -0.3265(4) 1.0334(4) 0.0242(10) Uani 1 1 d .
H4A H 1.0589 -0.3164 1.0714 0.029 Uiso 1 1 calc R
C5 C 0.9047(3) -0.3885(3) 1.0538(3) 0.0223(9) Uani 1 1 d .
H5A H 0.9279 -0.4187 1.1066 0.027 Uiso 1 1 calc R
C6 C 0.7940(3) -0.4073(3) 0.9994(3) 0.0213(9) Uani 1 1 d .
H6A H 0.7408 -0.4489 1.0145 0.026 Uiso 1 1 calc R
C7 C 0.7630(3) -0.3631(3) 0.9217(3) 0.0171(8) Uani 1 1 d .
C8 C 0.5549(3) -0.4321(3) 0.8337(3) 0.0189(9) Uani 1 1 d .
H8A H 0.5001 -0.4219 0.7737 0.023 Uiso 1 1 calc R
C9 C 0.5597(4) -0.5638(3) 0.7821(4) 0.0282(10) Uani 1 1 d .
H9A H 0.5846 -0.5943 0.7072 0.042 Uiso 1 1 calc R
H9B H 0.4860 -0.6039 0.7667 0.042 Uiso 1 1 calc R
H9C H 0.6117 -0.5776 0.8393 0.042 Uiso 1 1 calc R
C10 C 0.5149(3) -0.3773(4) 0.9483(4) 0.0276(10) Uani 1 1 d .
H10A H 0.5142 -0.2930 0.9771 0.041 Uiso 1 1 calc R
H10B H 0.5645 -0.3890 1.0085 0.041 Uiso 1 1 calc R
H10C H 0.4399 -0.4143 0.9336 0.041 Uiso 1 1 calc R
C11 C 0.8307(3) -0.2011(3) 0.7719(4) 0.0234(9) Uani 1 1 d .
H11A H 0.7679 -0.1906 0.7189 0.028 Uiso 1 1 calc R
C12 C 0.8829(4) -0.0788(4) 0.8725(4) 0.0364(12) Uani 1 1 d .
H12A H 0.8294 -0.0416 0.9212 0.055 Uiso 1 1 calc R
H12B H 0.9038 -0.0308 0.8384 0.055 Uiso 1 1 calc R
H12C H 0.9488 -0.0853 0.9225 0.055 Uiso 1 1 calc R
C13 C 0.9091(4) -0.2689(4) 0.6949(4) 0.0364(12) Uani 1 1 d .
H13A H 0.8699 -0.3451 0.6306 0.055 Uiso 1 1 calc R
H13B H 0.9717 -0.2813 0.7440 0.055 Uiso 1 1 calc R
H13C H 0.9363 -0.2241 0.6603 0.055 Uiso 1 1 calc R
C14 C 0.5900(3) -0.0536(3) 0.6560(3) 0.0184(9) Uani 1 1 d .
C15 C 0.6086(3) 0.0400(3) 0.6345(4) 0.0222(9) Uani 1 1 d .
H15A H 0.6005 0.0249 0.5547 0.027 Uiso 1 1 calc R
C16 C 0.6387(3) 0.1545(4) 0.7280(4) 0.0304(11) Uani 1 1 d .
H16A H 0.6509 0.2167 0.7115 0.036 Uiso 1 1 calc R
C17 C 0.6510(4) 0.1784(4) 0.8442(4) 0.0339(11) Uani 1 1 d .
H17A H 0.6732 0.2565 0.9080 0.041 Uiso 1 1 calc R
C18 C 0.6304(4) 0.0870(4) 0.8674(4) 0.0320(11) Uani 1 1 d .
H18A H 0.6371 0.1029 0.9474 0.038 Uiso 1 1 calc R
C19 C 0.6003(3) -0.0272(4) 0.7741(4) 0.0242(10) Uani 1 1 d .
H19A H 0.5863 -0.0887 0.7912 0.029 Uiso 1 1 calc R
C20 C 0.2125(3) -0.1656(3) 0.5518(4) 0.0200(9) Uani 1 1 d .
C21 C 0.0339(3) -0.1303(3) 0.5388(4) 0.0193(9) Uani 1 1 d .
C22 C -0.0810(3) -0.1385(4) 0.5054(4) 0.0240(10) Uani 1 1 d .
H22A H -0.1236 -0.2044 0.4357 0.029 Uiso 1 1 calc R
C23 C -0.1294(4) -0.0442(4) 0.5804(4) 0.0296(11) Uani 1 1 d .
H23A H -0.2074 -0.0460 0.5620 0.035 Uiso 1 1 calc R
C24 C -0.0658(4) 0.0525(4) 0.6817(4) 0.0285(10) Uani 1 1 d .
H24A H -0.1018 0.1152 0.7304 0.034 Uiso 1 1 calc R
C25 C 0.0477(3) 0.0603(4) 0.7133(4) 0.0257(10) Uani 1 1 d .
H25A H 0.0903 0.1271 0.7821 0.031 Uiso 1 1 calc R
C26 C 0.0974(3) -0.0335(3) 0.6407(3) 0.0193(9) Uani 1 1 d .
C27 C 0.3044(3) 0.0192(4) 0.7351(4) 0.0279(10) Uani 1 1 d .
H27A H 0.3696 -0.0231 0.7130 0.033 Uiso 1 1 calc R
C28 C 0.3241(4) 0.1346(4) 0.7345(4) 0.0342(11) Uani 1 1 d .
H28A H 0.3295 0.1182 0.6545 0.051 Uiso 1 1 calc R
H28B H 0.3931 0.1802 0.7919 0.051 Uiso 1 1 calc R
H28C H 0.2624 0.1797 0.7569 0.051 Uiso 1 1 calc R
C29 C 0.3003(4) 0.0377(4) 0.8582(4) 0.0398(13) Uani 1 1 d .
H29A H 0.2865 -0.0387 0.8539 0.060 Uiso 1 1 calc R
H29B H 0.2407 0.0841 0.8861 0.060 Uiso 1 1 calc R
H29C H 0.3711 0.0795 0.9141 0.060 Uiso 1 1 calc R
C30 C 0.0681(3) -0.3275(3) 0.3832(4) 0.0230(9) Uani 1 1 d .
H30A H -0.0039 -0.3231 0.3371 0.028 Uiso 1 1 calc R
C31 C 0.0452(4) -0.4138(3) 0.4258(4) 0.0291(10) Uani 1 1 d .
H31A H -0.0079 -0.3856 0.4769 0.044 Uiso 1 1 calc R
H31B H 0.1143 -0.4207 0.4713 0.044 Uiso 1 1 calc R
H31C H 0.0145 -0.4908 0.3568 0.044 Uiso 1 1 calc R
C32 C 0.1468(3) -0.3680(4) 0.2992(4) 0.0299(11) Uani 1 1 d .
H32A H 0.1646 -0.3064 0.2802 0.045 Uiso 1 1 calc R
H32B H 0.1116 -0.4398 0.2256 0.045 Uiso 1 1 calc R
H32C H 0.2149 -0.3839 0.3378 0.045 Uiso 1 1 calc R
C33 C 0.2983(3) -0.4449(3) 0.6409(3) 0.0172(8) Uani 1 1 d .
C34 C 0.2675(3) -0.3397(4) 0.7226(4) 0.0237(9) Uani 1 1 d .
H34A H 0.2798 -0.2711 0.7161 0.028 Uiso 1 1 calc R
C35 C 0.2197(3) -0.3331(4) 0.8123(4) 0.0273(10) Uani 1 1 d .
H35A H 0.1985 -0.2607 0.8657 0.033 Uiso 1 1 calc R
C36 C 0.2024(3) -0.4307(4) 0.8249(4) 0.0281(10) Uani 1 1 d .
H36A H 0.1702 -0.4260 0.8872 0.034 Uiso 1 1 calc R
C37 C 0.2328(3) -0.5357(4) 0.7455(4) 0.0248(10) Uani 1 1 d .
H37A H 0.2219 -0.6032 0.7542 0.030 Uiso 1 1 calc R
C38 C 0.2786(3) -0.5439(4) 0.6538(4) 0.0215(9) Uani 1 1 d .
H38A H 0.2970 -0.6173 0.5989 0.026 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 S1 127.83(10) . .
C1 Ag1 S2 125.42(11) . .
S1 Ag1 S2 100.20(3) . .
C1 Ag1 S2 95.56(9) . 2_646
S1 Ag1 S2 111.56(3) . 2_646
S2 Ag1 S2 87.80(3) . 2_646
C1 Ag1 Ag2 139.75(9) . .
S1 Ag1 Ag2 51.34(2) . .
S2 Ag1 Ag2 53.83(2) . .
S2 Ag1 Ag2 123.16(2) 2_646 .
C20 Ag2 S1 138.30(11) . .
C20 Ag2 S2 118.47(11) . .
S1 Ag2 S2 103.08(3) . .
C20 Ag2 Ag1 155.36(11) . .
S1 Ag2 Ag1 53.27(3) . .
S2 Ag2 Ag1 55.07(2) . .
C14 S1 Ag2 100.93(13) . .
C14 S1 Ag1 107.29(13) . .
Ag2 S1 Ag1 75.38(3) . .
C33 S2 Ag2 107.09(13) . .
C33 S2 Ag1 110.35(13) . .
Ag2 S2 Ag1 71.10(3) . .
C33 S2 Ag1 120.05(13) . 2_646
Ag2 S2 Ag1 132.85(4) . 2_646
Ag1 S2 Ag1 92.20(3) . 2_646
C1 N1 C7 111.3(3) . .
C1 N1 C8 122.1(3) . .
C7 N1 C8 126.6(3) . .
C1 N2 C2 110.7(3) . .
C1 N2 C11 122.7(3) . .
C2 N2 C11 126.6(3) . .
C20 N3 C26 111.2(3) . .
C20 N3 C27 122.5(3) . .
C26 N3 C27 126.3(3) . .
C20 N4 C21 111.2(3) . .
C20 N4 C30 126.5(3) . .
C21 N4 C30 121.9(3) . .
N1 C1 N2 105.9(3) . .
N1 C1 Ag1 128.4(3) . .
N2 C1 Ag1 122.7(3) . .
C3 C2 C7 121.7(4) . .
C3 C2 N2 132.3(4) . .
C7 C2 N2 106.0(3) . .
C4 C3 C2 117.1(4) . .
C4 C3 H3A 121.5 . .
C2 C3 H3A 121.5 . .
C3 C4 C5 121.3(4) . .
C3 C4 H4A 119.4 . .
C5 C4 H4A 119.4 . .
C6 C5 C4 121.7(4) . .
C6 C5 H5A 119.1 . .
C4 C5 H5A 119.1 . .
C5 C6 C7 117.6(4) . .
C5 C6 H6A 121.2 . .
C7 C6 H6A 121.2 . .
C6 C7 N1 133.3(4) . .
C6 C7 C2 120.6(4) . .
N1 C7 C2 106.0(3) . .
N1 C8 C10 111.4(3) . .
N1 C8 C9 110.9(3) . .
C10 C8 C9 113.4(3) . .
N1 C8 H8A 106.9 . .
C10 C8 H8A 106.9 . .
C9 C8 H8A 106.9 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C8 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C8 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N2 C11 C13 110.7(3) . .
N2 C11 C12 110.5(3) . .
C13 C11 C12 113.6(4) . .
N2 C11 H11A 107.2 . .
C13 C11 H11A 107.2 . .
C12 C11 H11A 107.2 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C13 H13A 109.5 . .
C11 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C11 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C19 C14 C15 117.5(4) . .
C19 C14 S1 123.3(3) . .
C15 C14 S1 119.1(3) . .
C16 C15 C14 121.1(4) . .
C16 C15 H15A 119.5 . .
C14 C15 H15A 119.5 . .
C17 C16 C15 120.5(4) . .
C17 C16 H16A 119.7 . .
C15 C16 H16A 119.7 . .
C16 C17 C18 119.3(4) . .
C16 C17 H17A 120.3 . .
C18 C17 H17A 120.3 . .
C19 C18 C17 120.1(4) . .
C19 C18 H18A 119.9 . .
C17 C18 H18A 119.9 . .
C18 C19 C14 121.4(4) . .
C18 C19 H19A 119.3 . .
C14 C19 H19A 119.3 . .
N4 C20 N3 105.4(3) . .
N4 C20 Ag2 130.5(3) . .
N3 C20 Ag2 123.8(3) . .
N4 C21 C26 106.5(3) . .
N4 C21 C22 131.1(4) . .
C26 C21 C22 122.4(4) . .
C23 C22 C21 116.1(4) . .
C23 C22 H22A 122.0 . .
C21 C22 H22A 122.0 . .
C24 C23 C22 121.4(4) . .
C24 C23 H23A 119.3 . .
C22 C23 H23A 119.3 . .
C25 C24 C23 122.0(4) . .
C25 C24 H24A 119.0 . .
C23 C24 H24A 119.0 . .
C24 C25 C26 117.4(4) . .
C24 C25 H25A 121.3 . .
C26 C25 H25A 121.3 . .
C25 C26 N3 133.7(4) . .
C25 C26 C21 120.6(4) . .
N3 C26 C21 105.7(3) . .
N3 C27 C29 111.6(4) . .
N3 C27 C28 112.2(3) . .
C29 C27 C28 112.5(4) . .
N3 C27 H27A 106.7 . .
C29 C27 H27A 106.7 . .
C28 C27 H27A 106.7 . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N4 C30 C31 110.1(3) . .
N4 C30 C32 112.5(3) . .
C31 C30 C32 112.4(3) . .
N4 C30 H30A 107.2 . .
C31 C30 H30A 107.2 . .
C32 C30 H30A 107.2 . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C30 C32 H32A 109.5 . .
C30 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C30 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C34 C33 C38 117.3(4) . .
C34 C33 S2 122.1(3) . .
C38 C33 S2 120.7(3) . .
C35 C34 C33 121.6(4) . .
C35 C34 H34A 119.2 . .
C33 C34 H34A 119.2 . .
C36 C35 C34 120.5(4) . .
C36 C35 H35A 119.8 . .
C34 C35 H35A 119.8 . .
C35 C36 C37 118.9(4) . .
C35 C36 H36A 120.5 . .
C37 C36 H36A 120.5 . .
C38 C37 C36 121.1(4) . .
C38 C37 H37A 119.5 . .
C36 C37 H37A 119.5 . .
C37 C38 C33 120.6(4) . .
C37 C38 H38A 119.7 . .
C33 C38 H38A 119.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.182(4) .
Ag1 S1 2.5705(10) .
Ag1 S2 2.6890(12) .
Ag1 S2 2.7376(10) 2_646
Ag1 Ag2 3.1033(6) .
Ag2 C20 2.150(4) .
Ag2 S1 2.5045(11) .
Ag2 S2 2.6479(10) .
S1 C14 1.781(4) .
S2 C33 1.768(4) .
S2 Ag1 2.7376(10) 2_646
N1 C1 1.359(5) .
N1 C7 1.396(5) .
N1 C8 1.479(5) .
N2 C1 1.365(5) .
N2 C2 1.404(5) .
N2 C11 1.468(5) .
N3 C20 1.371(5) .
N3 C26 1.393(5) .
N3 C27 1.470(5) .
N4 C20 1.356(5) .
N4 C21 1.392(5) .
N4 C30 1.486(5) .
C2 C3 1.393(5) .
C2 C7 1.401(5) .
C3 C4 1.386(5) .
C3 H3A 0.9500 .
C4 C5 1.396(6) .
C4 H4A 0.9500 .
C5 C6 1.381(5) .
C5 H5A 0.9500 .
C6 C7 1.391(5) .
C6 H6A 0.9500 .
C8 C10 1.510(5) .
C8 C9 1.526(5) .
C8 H8A 1.0000 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C13 1.519(5) .
C11 C12 1.528(6) .
C11 H11A 1.0000 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C19 1.392(5) .
C14 C15 1.402(5) .
C15 C16 1.390(6) .
C15 H15A 0.9500 .
C16 C17 1.374(6) .
C16 H16A 0.9500 .
C17 C18 1.394(6) .
C17 H17A 0.9500 .
C18 C19 1.386(6) .
C18 H18A 0.9500 .
C19 H19A 0.9500 .
C21 C26 1.396(5) .
C21 C22 1.396(5) .
C22 C23 1.394(5) .
C22 H22A 0.9500 .
C23 C24 1.393(6) .
C23 H23A 0.9500 .
C24 C25 1.380(6) .
C24 H24A 0.9500 .
C25 C26 1.389(5) .
C25 H25A 0.9500 .
C27 C29 1.521(6) .
C27 C28 1.525(6) .
C27 H27A 1.0000 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 C31 1.517(6) .
C30 C32 1.521(5) .
C30 H30A 1.0000 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 C34 1.397(5) .
C33 C38 1.402(5) .
C34 C35 1.380(6) .
C34 H34A 0.9500 .
C35 C36 1.377(6) .
C35 H35A 0.9500 .
C36 C37 1.384(6) .
C36 H36A 0.9500 .
C37 C38 1.383(5) .
C37 H37A 0.9500 .
C38 H38A 0.9500 .
