#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:18:03 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179889 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/85/7018565.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018565
loop_
_publ_author_name
'Burrows, Andrew D.'
'Mahon, Mary F.'
'Renouf, Catherine L.'
'Richardson, Christopher'
'Warren, Anna J.'
'Warren, John E.'
_publ_section_title
;
 Dipyridyl β-diketonate complexes and their use as metalloligands in the
 formation of mixed-metal coordination networks.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4153
_journal_page_last               4163
_journal_paper_doi               10.1039/c2dt12115h
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C42 H32 Ag2 Cl2 Fe N9 O12'
_chemical_formula_weight         1197.26
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.969(2)
_cell_angle_beta                 109.712(2)
_cell_angle_gamma                103.542(2)
_cell_formula_units_Z            2
_cell_length_a                   11.7140(3)
_cell_length_b                   14.0930(5)
_cell_length_c                   15.5890(6)
_cell_measurement_reflns_used    151495
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      2.910
_cell_volume                     2251.12(14)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction
'Denzo & Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  '95mm CCD camera on κ-goniostat'
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1069
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            32276
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         3.56
_exptl_absorpt_coefficient_mu    1.371
_exptl_absorpt_correction_T_max  0.93
_exptl_absorpt_correction_T_min  0.74
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
?
;
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.766
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1194
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.928
_refine_diff_density_min         -2.073
_refine_diff_density_rms         0.208
_refine_ls_extinction_coef       0.0118(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.116
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         32276
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.116
_refine_ls_R_factor_all          0.1329
_refine_ls_R_factor_gt           0.1066
_refine_ls_shift/su_max          0.025
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0507P)²+37.8924P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2402
_refine_ls_wR_factor_ref         0.2594
_reflns_number_gt                25177
_reflns_number_total             32276
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12115h.txt
_cod_data_source_block           compound12_k07adb11
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-Scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2251.11(13)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7018565
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.91434(5) 0.50038(5) 0.27677(4) 0.0432(2) Uani 1 1 d .
Ag2 Ag 0.84249(5) 0.82285(5) 0.25576(4) 0.0444(2) Uani 1 1 d .
Fe1 Fe 0.55878(9) 0.78887(8) 0.58869(7) 0.0317(2) Uani 1 1 d .
Cl1 Cl 0.5158(3) 0.4890(3) 0.1568(2) 0.0897(9) Uani 1 1 d .
Cl2 Cl 0.3697(3) 0.6306(2) 0.1557(2) 0.0795(7) Uani 1 1 d .
O1 O 0.6885(4) 0.7222(4) 0.5794(3) 0.0358(11) Uani 1 1 d .
O2 O 0.4291(4) 0.6602(4) 0.4933(3) 0.0352(11) Uani 1 1 d .
O3 O 0.5813(4) 0.8487(4) 0.4870(3) 0.0363(11) Uani 1 1 d .
O4 O 0.4194(4) 0.8504(4) 0.5763(3) 0.0348(11) Uani 1 1 d .
O5 O 0.5197(4) 0.7436(4) 0.6913(3) 0.0368(11) Uani 1 1 d .
O6 O 0.7037(4) 0.9004(4) 0.6910(3) 0.0313(10) Uani 1 1 d .
O7 O 0.8446(7) 0.6440(5) 0.2240(5) 0.0677(17) Uani 1 1 d .
O8 O 0.8216(7) 0.5309(5) 0.0982(5) 0.0738(18) Uani 1 1 d .
O9 O 0.7326(7) 0.6491(5) 0.0853(5) 0.081(2) Uani 1 1 d .
O10 O 0.7325(7) 1.0254(5) 1.0657(4) 0.0740(19) Uani 1 1 d .
O11 O 0.7861(8) 1.1182(6) 1.2087(5) 0.085(2) Uani 1 1 d .
O12 O 0.9003(9) 1.1597(6) 1.1340(7) 0.127(4) Uani 1 1 d .
N1 N 0.9246(5) 0.5863(5) 0.4227(4) 0.0390(14) Uani 1 1 d .
N2 N 0.0981(5) 0.4787(4) 0.2721(4) 0.0350(13) Uani 1 1 d .
N3 N 0.6656(5) 0.8568(5) 0.2566(4) 0.0368(13) Uani 1 1 d .
N4 N 0.0018(5) 0.8555(5) 0.4086(4) 0.0410(14) Uani 1 1 d .
N5 N 0.2689(6) 0.6429(5) 0.8049(5) 0.0436(15) Uani 1 1 d .
N6 N 1.0580(6) 1.1109(5) 0.8335(4) 0.0497(16) Uani 1 1 d .
N7 N 0.7996(7) 0.6086(5) 0.1367(6) 0.0564(18) Uani 1 1 d .
N8 N 0.1465(10) 0.7420(9) 0.2047(7) 0.093(3) Uani 1 1 d .
N9 N 0.8117(8) 1.1047(6) 1.1379(6) 0.066(2) Uani 1 1 d .
C1 C 1.0264(6) 0.6217(6) 0.5064(5) 0.0399(17) Uani 1 1 d .
H1 H 1.1030 0.6092 0.5072 0.048 Uiso 1 1 calc R
C2 C 1.0288(7) 0.6748(6) 0.5911(5) 0.0386(16) Uani 1 1 d .
H2 H 1.1055 0.7020 0.6474 0.046 Uiso 1 1 calc R
C3 C 0.9160(6) 0.6868(6) 0.5911(5) 0.0365(16) Uani 1 1 d .
H3 H 0.9139 0.7231 0.6482 0.044 Uiso 1 1 calc R
C4 C 0.8042(6) 0.6463(5) 0.5080(4) 0.0301(14) Uani 1 1 d .
C5 C 0.8153(6) 0.5992(6) 0.4240(5) 0.0372(16) Uani 1 1 d .
H5 H 0.7417 0.5754 0.3656 0.045 Uiso 1 1 calc R
C6 C 0.6803(6) 0.6571(5) 0.5055(5) 0.0336(15) Uani 1 1 d .
C7 C 0.5652(7) 0.5972(6) 0.4317(5) 0.0409(17) Uani 1 1 d .
H7 H 0.5680 0.5538 0.3783 0.049 Uiso 1 1 calc R
C8 C 0.4432(6) 0.5958(5) 0.4299(5) 0.0326(15) Uani 1 1 d .
C9 C 0.3268(6) 0.5202(5) 0.3528(5) 0.0323(15) Uani 1 1 d .
C10 C 0.3230(7) 0.4317(5) 0.2986(5) 0.0371(17) Uani 1 1 d .
H10 H 0.3994 0.4151 0.3069 0.045 Uiso 1 1 calc R
C11 C 0.2060(7) 0.3654(6) 0.2306(6) 0.0482(19) Uani 1 1 d .
H11 H 0.2023 0.3029 0.1919 0.058 Uiso 1 1 calc R
C12 C 0.0951(8) 0.3888(6) 0.2186(6) 0.0467(19) Uani 1 1 d .
H12 H 0.0155 0.3418 0.1725 0.056 Uiso 1 1 calc R
C13 C 0.2095(6) 0.5422(6) 0.3357(5) 0.0366(16) Uani 1 1 d .
H13 H 0.2120 0.6056 0.3719 0.044 Uiso 1 1 calc R
C14 C 0.4952(6) 0.8627(5) 0.4190(5) 0.0290(14) Uani 1 1 d .
C15 C 0.5273(6) 0.8768(5) 0.3380(5) 0.0330(15) Uani 1 1 d .
C16 C 0.6235(7) 0.8453(6) 0.3261(5) 0.0380(16) Uani 1 1 d .
H16 H 0.6643 0.8128 0.3698 0.046 Uiso 1 1 calc R
C17 C 0.6065(6) 0.9034(6) 0.1964(5) 0.0410(17) Uani 1 1 d .
H17 H 0.6343 0.9137 0.1473 0.049 Uiso 1 1 calc R
C18 C 0.5080(7) 0.9369(6) 0.2025(5) 0.0363(16) Uani 1 1 d .
H18 H 0.4679 0.9678 0.1570 0.044 Uiso 1 1 calc R
C19 C 0.4673(7) 0.9262(6) 0.2732(6) 0.0445(18) Uani 1 1 d .
H19 H 0.4007 0.9510 0.2791 0.053 Uiso 1 1 calc R
C20 C 0.3774(7) 0.8670(6) 0.4224(5) 0.0418(17) Uani 1 1 d .
H20 H 0.3158 0.8741 0.3680 0.050 Uiso 1 1 calc R
C21 C 0.3449(6) 0.8615(5) 0.5013(5) 0.0366(16) Uani 1 1 d .
C22 C 0.2191(6) 0.8705(5) 0.4967(5) 0.0326(15) Uani 1 1 d .
C23 C 0.1160(6) 0.8486(5) 0.4131(5) 0.0377(16) Uani 1 1 d .
H23 H 0.1255 0.8275 0.3550 0.045 Uiso 1 1 calc R
C24 C -0.0126(7) 0.8834(5) 0.4902(5) 0.0361(16) Uani 1 1 d .
H24 H -0.0927 0.8888 0.4883 0.043 Uiso 1 1 calc R
C25 C 0.0874(6) 0.9047(5) 0.5776(5) 0.0370(16) Uani 1 1 d .
H25 H 0.0751 0.9241 0.6348 0.044 Uiso 1 1 calc R
C26 C 0.2041(7) 0.8977(5) 0.5820(5) 0.0339(15) Uani 1 1 d .
H26 H 0.2727 0.9111 0.6415 0.041 Uiso 1 1 calc R
C27 C 0.5577(7) 0.7949(6) 0.7789(5) 0.0376(16) Uani 1 1 d .
C28 C 0.4694(6) 0.7595(5) 0.8252(5) 0.0364(16) Uani 1 1 d .
C29 C 0.3540(6) 0.6799(5) 0.7693(5) 0.0350(16) Uani 1 1 d .
H29 H 0.3352 0.6511 0.7039 0.042 Uiso 1 1 calc R
C30 C 0.2928(8) 0.6858(7) 0.8947(6) 0.057(2) Uani 1 1 d .
H30 H 0.2332 0.6593 0.9200 0.068 Uiso 1 1 calc R
C31 C 0.3994(9) 0.7666(8) 0.9527(7) 0.074(3) Uani 1 1 d .
H31 H 0.4113 0.7965 1.0164 0.089 Uiso 1 1 calc R
C32 C 0.4911(8) 0.8057(8) 0.9191(6) 0.063(3) Uani 1 1 d .
H32 H 0.5660 0.8619 0.9589 0.076 Uiso 1 1 calc R
C33 C 0.6644(6) 0.8806(5) 0.8251(5) 0.0323(15) Uani 1 1 d .
H33 H 0.6893 0.9108 0.8913 0.039 Uiso 1 1 calc R
C34 C 0.7389(6) 0.9261(5) 0.7805(5) 0.0334(15) Uani 1 1 d .
C35 C 0.8643(7) 1.0097(6) 0.8376(5) 0.0388(16) Uani 1 1 d .
C36 C 0.9419(6) 1.0380(6) 0.7902(5) 0.0397(17) Uani 1 1 d .
H36 H 0.9119 1.0045 0.7240 0.048 Uiso 1 1 calc R
C37 C 1.0998(8) 1.1554(7) 0.9274(6) 0.066(3) Uani 1 1 d .
H37 H 1.1830 1.2046 0.9592 0.080 Uiso 1 1 calc R
C38 C 1.0274(9) 1.1334(8) 0.9813(6) 0.071(3) Uani 1 1 d .
H38 H 1.0592 1.1673 1.0475 0.085 Uiso 1 1 calc R
C39 C 0.9070(8) 1.0596(7) 0.9331(6) 0.060(2) Uani 1 1 d .
H39 H 0.8538 1.0435 0.9663 0.072 Uiso 1 1 calc R
C40 C 0.0429(14) 0.6443(11) 0.0238(8) 0.099(4) Uani 1 1 d .
H40A H 0.0415 0.5732 0.0146 0.148 Uiso 1 1 calc R
H40B H 0.0939 0.6775 -0.0072 0.148 Uiso 1 1 calc R
H40C H -0.0449 0.6459 -0.0044 0.148 Uiso 1 1 calc R
C41 C 0.1021(13) 0.7006(14) 0.1302(12) 0.112(5) Uani 1 1 d .
C42 C 0.4517(10) 0.5724(9) 0.0987(7) 0.072(3) Uani 1 1 d .
H42A H 0.5222 0.6258 0.0970 0.087 Uiso 1 1 calc R
H42B H 0.3924 0.5335 0.0321 0.087 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 117.0(2) 1_655 .
N2 Ag1 N5 115.5(2) 1_655 2_666
N1 Ag1 N5 112.5(2) . 2_666
N2 Ag1 O7 119.7(2) 1_655 .
N1 Ag1 O7 83.8(2) . .
N5 Ag1 O7 104.0(2) 2_666 .
N3 Ag2 N6 119.4(2) . 2_776
N3 Ag2 N4 114.22(19) . 1_655
N6 Ag2 N4 107.3(2) 2_776 1_655
N3 Ag2 O7 120.1(2) . .
N6 Ag2 O7 103.5(2) 2_776 .
N4 Ag2 O7 87.2(2) 1_655 .
O6 Fe1 O5 86.50(19) . .
O6 Fe1 O2 170.04(18) . .
O5 Fe1 O2 89.78(19) . .
O6 Fe1 O4 99.95(19) . .
O5 Fe1 O4 85.65(18) . .
O2 Fe1 O4 88.96(19) . .
O6 Fe1 O1 85.91(19) . .
O5 Fe1 O1 101.33(19) . .
O2 Fe1 O1 85.77(19) . .
O4 Fe1 O1 171.22(19) . .
O6 Fe1 O3 92.94(19) . .
O5 Fe1 O3 170.89(18) . .
O2 Fe1 O3 92.18(19) . .
O4 Fe1 O3 85.50(18) . .
O1 Fe1 O3 87.69(18) . .
C6 O1 Fe1 126.9(4) . .
C8 O2 Fe1 128.2(4) . .
C14 O3 Fe1 127.5(4) . .
C21 O4 Fe1 127.2(4) . .
C27 O5 Fe1 128.4(5) . .
C34 O6 Fe1 131.6(4) . .
N7 O7 Ag2 105.8(5) . .
N7 O7 Ag1 101.5(5) . .
Ag2 O7 Ag1 152.0(3) . .
C1 N1 C5 116.6(6) . .
C1 N1 Ag1 127.2(4) . .
C5 N1 Ag1 116.1(5) . .
C13 N2 C12 118.4(6) . .
C13 N2 Ag1 120.0(4) . 1_455
C12 N2 Ag1 120.0(5) . 1_455
C17 N3 C16 116.1(6) . .
C17 N3 Ag2 121.4(4) . .
C16 N3 Ag2 121.8(5) . .
C24 N4 C23 118.4(6) . .
C24 N4 Ag2 124.6(4) . 1_455
C23 N4 Ag2 117.0(5) . 1_455
C30 N5 C29 118.6(7) . .
C30 N5 Ag1 116.0(5) . 2_666
C29 N5 Ag1 125.3(5) . 2_666
C37 N6 C36 117.4(6) . .
C37 N6 Ag2 121.3(5) . 2_776
C36 N6 Ag2 120.1(5) . 2_776
O7 N7 O9 120.2(7) . .
O7 N7 O8 120.5(7) . .
O9 N7 O8 119.4(8) . .
O12 N9 O11 122.7(9) . .
O12 N9 O10 121.3(8) . .
O11 N9 O10 116.0(8) . .
N1 C1 C2 125.1(6) . .
N1 C1 H1 117.4 . .
C2 C1 H1 117.4 . .
C3 C2 C1 117.3(7) . .
C3 C2 H2 121.3 . .
C1 C2 H2 121.3 . .
C2 C3 C4 120.6(6) . .
C2 C3 H3 119.7 . .
C4 C3 H3 119.7 . .
C3 C4 C5 116.9(6) . .
C3 C4 C6 122.1(6) . .
C5 C4 C6 120.9(6) . .
N1 C5 C4 123.1(7) . .
N1 C5 H5 118.4 . .
C4 C5 H5 118.4 . .
O1 C6 C7 123.2(6) . .
O1 C6 C4 114.9(6) . .
C7 C6 C4 121.9(6) . .
C6 C7 C8 124.6(6) . .
C6 C7 H7 117.7 . .
C8 C7 H7 117.7 . .
O2 C8 C7 122.4(7) . .
O2 C8 C9 117.7(5) . .
C7 C8 C9 119.9(5) . .
C10 C9 C13 118.1(7) . .
C10 C9 C8 124.8(6) . .
C13 C9 C8 117.1(6) . .
C9 C10 C11 118.9(6) . .
C9 C10 H10 120.5 . .
C11 C10 H10 120.5 . .
C12 C11 C10 120.8(7) . .
C12 C11 H11 119.6 . .
C10 C11 H11 119.6 . .
N2 C12 C11 120.8(8) . .
N2 C12 H12 119.6 . .
C11 C12 H12 119.6 . .
N2 C13 C9 123.0(6) . .
N2 C13 H13 118.5 . .
C9 C13 H13 118.5 . .
O3 C14 C20 122.1(6) . .
O3 C14 C15 115.9(5) . .
C20 C14 C15 121.9(6) . .
C16 C15 C19 117.5(6) . .
C16 C15 C14 118.8(6) . .
C19 C15 C14 123.6(5) . .
N3 C16 C15 124.8(7) . .
N3 C16 H16 117.6 . .
C15 C16 H16 117.6 . .
N3 C17 C18 123.1(6) . .
N3 C17 H17 118.5 . .
C18 C17 H17 118.5 . .
C19 C18 C17 120.4(7) . .
C19 C18 H18 119.8 . .
C17 C18 H18 119.8 . .
C18 C19 C15 118.0(6) . .
C18 C19 H19 121.0 . .
C15 C19 H19 121.0 . .
C14 C20 C21 124.5(7) . .
C14 C20 H20 117.8 . .
C21 C20 H20 117.8 . .
O4 C21 C20 122.5(6) . .
O4 C21 C22 118.6(6) . .
C20 C21 C22 118.9(6) . .
C23 C22 C26 118.4(6) . .
C23 C22 C21 123.3(6) . .
C26 C22 C21 118.2(6) . .
N4 C23 C22 123.5(6) . .
N4 C23 H23 118.2 . .
C22 C23 H23 118.2 . .
N4 C24 C25 121.1(6) . .
N4 C24 H24 119.4 . .
C25 C24 H24 119.4 . .
C26 C25 C24 120.4(6) . .
C26 C25 H25 119.8 . .
C24 C25 H25 119.8 . .
C25 C26 C22 118.2(7) . .
C25 C26 H26 120.9 . .
C22 C26 H26 120.9 . .
O5 C27 C33 123.6(6) . .
O5 C27 C28 114.3(6) . .
C33 C27 C28 121.9(6) . .
C32 C28 C29 117.9(6) . .
C32 C28 C27 123.6(7) . .
C29 C28 C27 118.4(6) . .
N5 C29 C28 122.5(6) . .
N5 C29 H29 118.7 . .
C28 C29 H29 118.7 . .
N5 C30 C31 122.7(7) . .
N5 C30 H30 118.6 . .
C31 C30 H30 118.6 . .
C30 C31 C32 120.3(8) . .
C30 C31 H31 119.8 . .
C32 C31 H31 119.8 . .
C28 C32 C31 117.8(8) . .
C28 C32 H32 121.1 . .
C31 C32 H32 121.1 . .
C27 C33 C34 124.1(6) . .
C27 C33 H33 117.9 . .
C34 C33 H33 117.9 . .
O6 C34 C33 122.4(6) . .
O6 C34 C35 116.6(6) . .
C33 C34 C35 121.1(6) . .
C39 C35 C36 118.3(7) . .
C39 C35 C34 124.5(6) . .
C36 C35 C34 117.2(6) . .
N6 C36 C35 123.2(7) . .
N6 C36 H36 118.4 . .
C35 C36 H36 118.4 . .
N6 C37 C38 123.7(7) . .
N6 C37 H37 118.2 . .
C38 C37 H37 118.2 . .
C39 C38 C37 116.9(8) . .
C39 C38 H38 121.6 . .
C37 C38 H38 121.6 . .
C35 C39 C38 120.5(7) . .
C35 C39 H39 119.8 . .
C38 C39 H39 119.8 . .
C41 C40 H40A 109.5 . .
C41 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C41 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
N8 C41 C40 177.9(17) . .
Cl2 C42 Cl1 112.1(5) . .
Cl2 C42 H42A 109.2 . .
Cl1 C42 H42A 109.2 . .
Cl2 C42 H42B 109.2 . .
Cl1 C42 H42B 109.2 . .
H42A C42 H42B 107.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.267(5) 1_655
Ag1 N1 2.315(6) .
Ag1 N5 2.335(6) 2_666
Ag1 O7 2.528(6) .
Ag2 N3 2.237(5) .
Ag2 N6 2.291(6) 2_776
Ag2 N4 2.356(6) 1_655
Ag2 O7 2.483(6) .
Fe1 O6 1.966(5) .
Fe1 O5 1.979(5) .
Fe1 O2 1.992(5) .
Fe1 O4 1.992(4) .
Fe1 O1 1.994(4) .
Fe1 O3 1.996(5) .
Cl1 C42 1.768(10) .
Cl2 C42 1.748(9) .
O1 C6 1.289(8) .
O2 C8 1.291(7) .
O3 C14 1.278(7) .
O4 C21 1.264(8) .
O5 C27 1.285(8) .
O6 C34 1.264(8) .
O7 N7 1.231(9) .
O8 N7 1.269(9) .
O9 N7 1.243(9) .
O10 N9 1.307(10) .
O11 N9 1.231(9) .
O12 N9 1.168(10) .
N1 C1 1.340(9) .
N1 C5 1.340(8) .
N2 C13 1.314(9) .
N2 C12 1.364(9) .
N2 Ag1 2.267(5) 1_455
N3 C17 1.342(9) .
N3 C16 1.353(8) .
N4 C24 1.337(9) .
N4 C23 1.343(8) .
N4 Ag2 2.356(6) 1_455
N5 C30 1.320(10) .
N5 C29 1.346(8) .
N5 Ag1 2.335(6) 2_666
N6 C37 1.341(11) .
N6 C36 1.350(10) .
N6 Ag2 2.291(6) 2_776
N8 C41 1.073(17) .
C1 C2 1.377(10) .
C1 H1 0.9500 .
C2 C3 1.371(9) .
C2 H2 0.9500 .
C3 C4 1.394(10) .
C3 H3 0.9500 .
C4 C5 1.413(9) .
C4 C6 1.482(9) .
C5 H5 0.9500 .
C6 C7 1.381(10) .
C7 C8 1.415(9) .
C7 H7 0.9500 .
C8 C9 1.472(10) .
C9 C10 1.350(10) .
C9 C13 1.428(9) .
C10 C11 1.385(11) .
C10 H10 0.9500 .
C11 C12 1.375(10) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 C20 1.414(9) .
C14 C15 1.468(9) .
C15 C16 1.359(9) .
C15 C19 1.420(10) .
C16 H16 0.9500 .
C17 C18 1.369(9) .
C17 H17 0.9500 .
C18 C19 1.360(10) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.416(10) .
C20 H20 0.9500 .
C21 C22 1.488(9) .
C22 C23 1.364(10) .
C22 C26 1.394(9) .
C23 H23 0.9500 .
C24 C25 1.387(10) .
C24 H24 0.9500 .
C25 C26 1.373(9) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C33 1.376(10) .
C27 C28 1.496(9) .
C28 C32 1.393(10) .
C28 C29 1.402(10) .
C29 H29 0.9500 .
C30 C31 1.361(12) .
C30 H30 0.9500 .
C31 C32 1.395(11) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 C34 1.405(9) .
C33 H33 0.9500 .
C34 C35 1.499(10) .
C35 C39 1.376(11) .
C35 C36 1.389(9) .
C36 H36 0.9500 .
C37 C38 1.407(11) .
C37 H37 0.9500 .
C38 C39 1.392(12) .
C38 H38 0.9500 .
C39 H39 0.9500 .
C40 C41 1.53(2) .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C42 H42A 0.9900 .
C42 H42B 0.9900 .
