#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:07:06 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179913 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/08/7020874.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7020874
loop_
_publ_author_name
'Liu, Jinying'
'Ma, Chengbing'
'Chen, Hui'
'Hu, Mingqiang'
'Wen, Huimin'
'Cui, Honghua'
'Song, Xiaowei'
'Chen, Changneng'
_publ_section_title
;
 Syntheses, structures and magnetic properties of a family of
 heterometallic [Mn(II)(2)Mn(III)(2)Ln(III)(2)] clusters.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2423
_journal_page_last               2430
_journal_paper_doi               10.1039/c2dt32269b
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C62 H118 Eu2 Mn4 N2 O28'
_chemical_formula_sum            'C62 H118 Eu2 Mn4 N2 O28'
_chemical_formula_weight         1859.23
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method
;
SHELXL-97

The four tert-butyl groups were each disordered into two positions
with occupancies of 67/33,60/40,60/40,60/40, respectively,
and the temperature factors of all atoms were restrained by using
the command DELU/SIMU/ISOR. The subsequent refinement gave good ellipsoid plot.

The bond lengths and bond angles of those four tert-butyl groups
were restrained by using DFIX.

All the hydrogens were added geometrically. The singly-deprotonated
triethanolamine ligands (H2tea C) were confirmed by the charge
consideration and bond-valence-sum (BVS) calculations, but no
difference fourier peak was found to be suitable for the definition
of the proton of H2tea- anions, and these four hydrogens were
calculated in the reported formula.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 112.586(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   17.5106(4)
_cell_length_b                   11.4288(5)
_cell_length_c                   22.1104(7)
_cell_measurement_reflns_used    2876
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4856
_cell_measurement_theta_min      2.6746
_cell_volume                     4085.5(2)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 14.6306
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0221
_diffrn_reflns_av_sigmaI/netI    0.0216
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            30517
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.61
_exptl_absorpt_coefficient_mu    2.184
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8627
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Corp., 2000)'
_exptl_crystal_colour            BROWN
_exptl_crystal_density_diffrn    1.511
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       PRISM
_exptl_crystal_F_000             1900
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.996
_refine_diff_density_min         -1.049
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     554
_refine_ls_number_reflns         9336
_refine_ls_number_restraints     486
_refine_ls_restrained_S_all      1.439
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0370
_refine_ls_shift/su_max          0.025
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0707P)²+2.9882P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1034
_refine_ls_wR_factor_ref         0.1102
_reflns_number_gt                8321
_reflns_number_total             9336
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt32269b.txt
_cod_data_source_block           compound4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7020874
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.1700(2) 0.1780(4) -0.01347(18) 0.0393(8) Uani 1 1 d . . .
Eu1 Eu 0.279719(11) 0.01812(2) 0.058373(9) 0.03120(10) Uani 1 1 d . . .
Mn1 Mn 0.40292(4) 0.03567(5) -0.03269(3) 0.02791(15) Uani 1 1 d . . .
Mn2 Mn 0.51099(4) -0.02279(7) 0.13122(3) 0.03692(17) Uani 1 1 d . . .
C1 C 0.6261(3) 0.1946(4) -0.0142(2) 0.0367(9) Uani 1 1 d . . .
H1A H 0.6323 0.2337 -0.0510 0.044 Uiso 1 1 calc R . .
H1B H 0.6771 0.2060 0.0237 0.044 Uiso 1 1 calc R . .
C2 C 0.5819(3) 0.3812(4) 0.0171(3) 0.0531(13) Uani 1 1 d . . .
H2A H 0.6328 0.3831 0.0550 0.080 Uiso 1 1 calc R . .
H2B H 0.5397 0.4216 0.0266 0.080 Uiso 1 1 calc R . .
H2C H 0.5897 0.4187 -0.0189 0.080 Uiso 1 1 calc R . .
C3 C 0.5555(3) 0.2535(4) -0.0009(2) 0.0366(9) Uani 1 1 d . . .
C4 C 0.4745(3) 0.2540(4) -0.0617(2) 0.0414(10) Uani 1 1 d . . .
H4A H 0.4352 0.3037 -0.0526 0.050 Uiso 1 1 calc R . .
H4B H 0.4852 0.2895 -0.0975 0.050 Uiso 1 1 calc R . .
C5 C 0.5433(3) 0.1988(4) 0.0575(2) 0.0388(10) Uani 1 1 d . . .
H5A H 0.5933 0.2098 0.0962 0.047 Uiso 1 1 calc R . .
H5B H 0.4989 0.2398 0.0646 0.047 Uiso 1 1 calc R . .
C6 C 0.4343(4) 0.2756(7) 0.2053(3) 0.0783(18) Uani 1 1 d DU . .
C7 C 0.4381(8) 0.3903(10) 0.1642(6) 0.104(4) Uani 0.723(11) 1 d PDU A 1
H7A H 0.4288 0.3683 0.1200 0.156 Uiso 0.723(11) 1 calc PR A 1
H7B H 0.4915 0.4263 0.1841 0.156 Uiso 0.723(11) 1 calc PR A 1
H7C H 0.3962 0.4447 0.1639 0.156 Uiso 0.723(11) 1 calc PR A 1
C8 C 0.5230(7) 0.2379(14) 0.2439(7) 0.107(4) Uani 0.723(11) 1 d PDU A 1
H8A H 0.5581 0.2685 0.2233 0.160 Uiso 0.723(11) 1 calc PR A 1
H8B H 0.5262 0.1540 0.2449 0.160 Uiso 0.723(11) 1 calc PR A 1
H8C H 0.5409 0.2674 0.2878 0.160 Uiso 0.723(11) 1 calc PR A 1
C9 C 0.3893(8) 0.3081(13) 0.2463(6) 0.100(3) Uani 0.723(11) 1 d PDU A 1
H9A H 0.3578 0.3778 0.2292 0.150 Uiso 0.723(11) 1 calc PR A 1
H9B H 0.4279 0.3222 0.2902 0.150 Uiso 0.723(11) 1 calc PR A 1
H9C H 0.3527 0.2457 0.2464 0.150 Uiso 0.723(11) 1 calc PR A 1
C7' C 0.5231(14) 0.289(3) 0.2220(18) 0.091(5) Uani 0.277(11) 1 d PDU A 2
H7'A H 0.5321 0.3350 0.1892 0.137 Uiso 0.277(11) 1 calc PR A 2
H7'B H 0.5476 0.2128 0.2240 0.137 Uiso 0.277(11) 1 calc PR A 2
H7'C H 0.5479 0.3264 0.2638 0.137 Uiso 0.277(11) 1 calc PR A 2
C8' C 0.423(2) 0.217(3) 0.2680(12) 0.104(6) Uani 0.277(11) 1 d PDU A 2
H8'A H 0.4150 0.1339 0.2613 0.156 Uiso 0.277(11) 1 calc PR A 2
H8'B H 0.3755 0.2503 0.2732 0.156 Uiso 0.277(11) 1 calc PR A 2
H8'C H 0.4713 0.2312 0.3067 0.156 Uiso 0.277(11) 1 calc PR A 2
C9' C 0.381(2) 0.380(2) 0.1990(17) 0.108(5) Uani 0.277(11) 1 d PDU A 2
H9'A H 0.3773 0.4245 0.1610 0.162 Uiso 0.277(11) 1 calc PR A 2
H9'B H 0.4044 0.4282 0.2373 0.162 Uiso 0.277(11) 1 calc PR A 2
H9'C H 0.3266 0.3554 0.1944 0.162 Uiso 0.277(11) 1 calc PR A 2
C10 C 0.3897(3) 0.1870(5) 0.1525(2) 0.0427(10) Uani 1 1 d . A .
C11 C 0.2815(3) 0.2221(5) -0.0529(3) 0.0463(11) Uani 1 1 d . A .
H11A H 0.2512 0.1873 -0.0955 0.056 Uiso 1 1 calc R . .
H11B H 0.3158 0.2844 -0.0585 0.056 Uiso 1 1 calc R . .
C12 C 0.2212(3) 0.2717(5) -0.0252(3) 0.0473(11) Uani 1 1 d . . .
H12A H 0.2517 0.3117 0.0157 0.057 Uiso 1 1 calc R . .
H12B H 0.1855 0.3284 -0.0556 0.057 Uiso 1 1 calc R . .
C13 C 0.1291(3) 0.2227(5) 0.0295(3) 0.0485(12) Uani 1 1 d . . .
H13A H 0.0853 0.2765 0.0050 0.058 Uiso 1 1 calc R . .
H13B H 0.1691 0.2652 0.0660 0.058 Uiso 1 1 calc R . .
C14 C 0.0935(3) 0.1239(5) 0.0552(3) 0.0479(11) Uani 1 1 d . A .
H14A H 0.0736 0.1531 0.0877 0.058 Uiso 1 1 calc R . .
H14B H 0.0473 0.0891 0.0197 0.058 Uiso 1 1 calc R . .
C15 C 0.1096(3) 0.1308(6) -0.0758(3) 0.0533(13) Uani 1 1 d . . .
H15A H 0.1206 0.1641 -0.1120 0.064 Uiso 1 1 calc R . .
H15B H 0.0543 0.1541 -0.0806 0.064 Uiso 1 1 calc R . .
C16 C 0.1135(3) -0.0014(5) -0.0789(3) 0.0518(13) Uani 1 1 d . A .
H16A H 0.0890 -0.0357 -0.0504 0.062 Uiso 1 1 calc R . .
H16B H 0.0820 -0.0276 -0.1232 0.062 Uiso 1 1 calc R . .
C17 C 0.1595(3) -0.2212(5) 0.0578(3) 0.0508(12) Uani 1 1 d . A .
C18 C 0.1539(4) -0.3542(5) 0.0463(4) 0.0677(16) Uani 1 1 d DU . .
C19 C 0.1089(10) -0.4058(13) 0.0898(8) 0.090(3) Uani 0.585(12) 1 d PDU B 1
H19A H 0.1373 -0.3809 0.1344 0.134 Uiso 0.585(12) 1 calc PR B 1
H19B H 0.1092 -0.4897 0.0878 0.134 Uiso 0.585(12) 1 calc PR B 1
H19C H 0.0528 -0.3783 0.0739 0.134 Uiso 0.585(12) 1 calc PR B 1
C20 C 0.0946(9) -0.3699(13) -0.0230(6) 0.089(3) Uani 0.585(12) 1 d PDU B 1
H20A H 0.0402 -0.3840 -0.0239 0.134 Uiso 0.585(12) 1 calc PR B 1
H20B H 0.1116 -0.4353 -0.0421 0.134 Uiso 0.585(12) 1 calc PR B 1
H20C H 0.0940 -0.3004 -0.0476 0.134 Uiso 0.585(12) 1 calc PR B 1
C21 C 0.2340(9) -0.4113(16) 0.0893(10) 0.101(4) Uani 0.585(12) 1 d PDU B 1
H21A H 0.2391 -0.4091 0.1341 0.151 Uiso 0.585(12) 1 calc PR B 1
H21B H 0.2795 -0.3701 0.0851 0.151 Uiso 0.585(12) 1 calc PR B 1
H21C H 0.2344 -0.4912 0.0760 0.151 Uiso 0.585(12) 1 calc PR B 1
C19' C 0.0765(11) -0.4108(18) 0.0440(13) 0.092(4) Uani 0.415(12) 1 d PDU B 2
H19D H 0.0755 -0.4117 0.0871 0.139 Uiso 0.415(12) 1 calc PR B 2
H19E H 0.0742 -0.4897 0.0284 0.139 Uiso 0.415(12) 1 calc PR B 2
H19F H 0.0297 -0.3678 0.0150 0.139 Uiso 0.415(12) 1 calc PR B 2
C20' C 0.1535(16) -0.367(2) -0.0270(9) 0.106(5) Uani 0.415(12) 1 d PDU B 2
H20D H 0.1025 -0.3364 -0.0583 0.159 Uiso 0.415(12) 1 calc PR B 2
H20E H 0.1589 -0.4476 -0.0363 0.159 Uiso 0.415(12) 1 calc PR B 2
H20F H 0.1990 -0.3232 -0.0298 0.159 Uiso 0.415(12) 1 calc PR B 2
C21' C 0.2348(11) -0.4111(19) 0.0521(12) 0.081(4) Uani 0.415(12) 1 d PDU B 2
H21D H 0.2674 -0.4273 0.0973 0.122 Uiso 0.415(12) 1 calc PR B 2
H21E H 0.2646 -0.3590 0.0350 0.122 Uiso 0.415(12) 1 calc PR B 2
H21F H 0.2234 -0.4828 0.0276 0.122 Uiso 0.415(12) 1 calc PR B 2
C22 C 0.4089(3) -0.1287(5) 0.1971(2) 0.0486(12) Uani 1 1 d . A .
C23 C 0.4057(4) -0.1902(7) 0.2569(3) 0.0698(16) Uani 1 1 d DU . .
C24 C 0.4741(8) -0.1356(13) 0.3176(5) 0.097(3) Uani 0.667(9) 1 d PDU C 1
H24A H 0.5139 -0.0969 0.3044 0.146 Uiso 0.667(9) 1 calc PR C 1
H24B H 0.5011 -0.1961 0.3485 0.146 Uiso 0.667(9) 1 calc PR C 1
H24C H 0.4499 -0.0799 0.3374 0.146 Uiso 0.667(9) 1 calc PR C 1
C25 C 0.4288(9) -0.3156(10) 0.2562(6) 0.089(3) Uani 0.667(9) 1 d PDU C 1
H25A H 0.4878 -0.3222 0.2708 0.134 Uiso 0.667(9) 1 calc PR C 1
H25B H 0.4034 -0.3457 0.2124 0.134 Uiso 0.667(9) 1 calc PR C 1
H25C H 0.4100 -0.3596 0.2848 0.134 Uiso 0.667(9) 1 calc PR C 1
C26 C 0.3242(7) -0.1722(13) 0.2630(6) 0.088(3) Uani 0.667(9) 1 d PDU C 1
H26A H 0.3259 -0.1012 0.2867 0.132 Uiso 0.667(9) 1 calc PR C 1
H26B H 0.3132 -0.2371 0.2860 0.132 Uiso 0.667(9) 1 calc PR C 1
H26C H 0.2812 -0.1668 0.2201 0.132 Uiso 0.667(9) 1 calc PR C 1
C24' C 0.4772(14) -0.269(2) 0.2913(11) 0.084(4) Uani 0.333(9) 1 d PDU C 2
H24D H 0.5274 -0.2240 0.3064 0.126 Uiso 0.333(9) 1 calc PR C 2
H24E H 0.4801 -0.3284 0.2617 0.126 Uiso 0.333(9) 1 calc PR C 2
H24F H 0.4701 -0.3047 0.3281 0.126 Uiso 0.333(9) 1 calc PR C 2
C25' C 0.3900(17) -0.098(2) 0.2994(11) 0.096(4) Uani 0.333(9) 1 d PDU C 2
H25D H 0.4373 -0.0480 0.3168 0.144 Uiso 0.333(9) 1 calc PR C 2
H25E H 0.3802 -0.1354 0.3347 0.144 Uiso 0.333(9) 1 calc PR C 2
H25F H 0.3424 -0.0531 0.2737 0.144 Uiso 0.333(9) 1 calc PR C 2
C26' C 0.3240(13) -0.268(2) 0.2323(11) 0.094(5) Uani 0.333(9) 1 d PDU C 2
H26D H 0.3058 -0.2805 0.1859 0.142 Uiso 0.333(9) 1 calc PR C 2
H26E H 0.2814 -0.2286 0.2417 0.142 Uiso 0.333(9) 1 calc PR C 2
H26F H 0.3355 -0.3422 0.2544 0.142 Uiso 0.333(9) 1 calc PR C 2
C27 C 0.6954(3) 0.0518(5) 0.1784(2) 0.0425(10) Uani 1 1 d . A .
C28 C 0.7707(3) 0.1071(6) 0.2318(3) 0.0646(15) Uani 1 1 d DU . .
C29 C 0.7548(7) 0.1446(16) 0.2896(6) 0.093(3) Uani 0.672(11) 1 d PDU D 1
H29A H 0.7334 0.2230 0.2831 0.140 Uiso 0.672(11) 1 calc PR D 1
H29B H 0.8054 0.1423 0.3277 0.140 Uiso 0.672(11) 1 calc PR D 1
H29C H 0.7151 0.0931 0.2958 0.140 Uiso 0.672(11) 1 calc PR D 1
C30 C 0.7895(8) 0.2216(11) 0.1989(6) 0.095(3) Uani 0.672(11) 1 d PDU D 1
H30A H 0.7704 0.2106 0.1524 0.142 Uiso 0.672(11) 1 calc PR D 1
H30B H 0.8480 0.2361 0.2164 0.142 Uiso 0.672(11) 1 calc PR D 1
H30C H 0.7614 0.2872 0.2081 0.142 Uiso 0.672(11) 1 calc PR D 1
C31 C 0.8431(7) 0.0243(11) 0.2474(6) 0.075(3) Uani 0.672(11) 1 d PDU D 1
H31A H 0.8651 0.0296 0.2138 0.113 Uiso 0.672(11) 1 calc PR D 1
H31B H 0.8250 -0.0544 0.2494 0.113 Uiso 0.672(11) 1 calc PR D 1
H31C H 0.8853 0.0450 0.2888 0.113 Uiso 0.672(11) 1 calc PR D 1
C29' C 0.7734(17) 0.054(3) 0.3022(9) 0.090(5) Uani 0.328(11) 1 d PDU D 2
H29D H 0.7497 -0.0231 0.2953 0.136 Uiso 0.328(11) 1 calc PR D 2
H29E H 0.7422 0.1039 0.3191 0.136 Uiso 0.328(11) 1 calc PR D 2
H29F H 0.8297 0.0501 0.3329 0.136 Uiso 0.328(11) 1 calc PR D 2
C30' C 0.7528(13) 0.2300(17) 0.2442(12) 0.091(4) Uani 0.328(11) 1 d PDU D 2
H30D H 0.7465 0.2772 0.2067 0.137 Uiso 0.328(11) 1 calc PR D 2
H30E H 0.7977 0.2598 0.2818 0.137 Uiso 0.328(11) 1 calc PR D 2
H30F H 0.7027 0.2324 0.2522 0.137 Uiso 0.328(11) 1 calc PR D 2
C31' C 0.8513(12) 0.081(3) 0.2292(14) 0.084(5) Uani 0.328(11) 1 d PDU D 2
H31D H 0.8538 0.1135 0.1900 0.125 Uiso 0.328(11) 1 calc PR D 2
H31E H 0.8586 -0.0024 0.2292 0.125 Uiso 0.328(11) 1 calc PR D 2
H31F H 0.8944 0.1141 0.2667 0.125 Uiso 0.328(11) 1 calc PR D 2
O1 O 0.61550(17) 0.0716(3) -0.02817(14) 0.0318(6) Uani 1 1 d . . .
O2 O 0.43695(17) 0.1442(3) -0.08286(14) 0.0357(6) Uani 1 1 d . . .
O3 O 0.52396(16) 0.0766(3) 0.05009(13) 0.0306(6) Uani 1 1 d . . .
O4 O 0.3121(2) 0.1894(4) 0.12700(18) 0.0540(9) Uani 1 1 d . . .
O5 O 0.4292(2) 0.1140(3) 0.13308(17) 0.0485(8) Uani 1 1 d . . .
O6 O 0.33182(17) 0.1365(3) -0.00987(14) 0.0333(6) Uani 1 1 d . . .
O7 O 0.1977(2) -0.0397(3) -0.05888(16) 0.0440(8) Uani 1 1 d . . .
O8 O 0.1562(2) 0.0382(3) 0.0841(2) 0.0492(8) Uani 1 1 d . . .
O9 O 0.1037(3) -0.1708(4) 0.0697(3) 0.0742(13) Uani 1 1 d . . .
O10 O 0.2194(2) -0.1701(3) 0.0517(2) 0.0540(9) Uani 1 1 d . . .
O11 O 0.3458(2) -0.0767(4) 0.15947(19) 0.0615(11) Uani 1 1 d . . .
O12 O 0.4753(3) -0.1362(4) 0.1882(2) 0.0649(11) Uani 1 1 d . . .
O13 O 0.6320(2) 0.0356(4) 0.19083(17) 0.0505(9) Uani 1 1 d . . .
O14 O 0.70014(19) 0.0254(3) 0.12432(16) 0.0405(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C15 N1 C12 111.4(4) . .
C15 N1 C13 112.0(4) . .
C12 N1 C13 109.6(4) . .
C15 N1 Eu1 113.3(3) . .
C12 N1 Eu1 104.6(2) . .
C13 N1 Eu1 105.5(3) . .
O11 Eu1 O10 71.72(15) . .
O11 Eu1 O4 82.22(15) . .
O10 Eu1 O4 140.08(14) . .
O11 Eu1 O1 85.30(13) . 3_655
O10 Eu1 O1 88.01(11) . 3_655
O4 Eu1 O1 120.02(11) . 3_655
O11 Eu1 O6 132.59(12) . .
O10 Eu1 O6 136.39(12) . .
O4 Eu1 O6 83.43(12) . .
O1 Eu1 O6 63.95(9) 3_655 .
O11 Eu1 O8 88.80(14) . .
O10 Eu1 O8 71.82(13) . .
O4 Eu1 O8 78.06(12) . .
O1 Eu1 O8 159.82(11) 3_655 .
O6 Eu1 O8 131.48(11) . .
O11 Eu1 O7 137.31(15) . .
O10 Eu1 O7 68.60(14) . .
O4 Eu1 O7 139.84(13) . .
O1 Eu1 O7 78.32(10) 3_655 .
O6 Eu1 O7 73.22(11) . .
O8 Eu1 O7 93.30(13) . .
O11 Eu1 N1 148.83(14) . .
O10 Eu1 N1 112.30(13) . .
O4 Eu1 N1 76.21(12) . .
O1 Eu1 N1 125.01(10) 3_655 .
O6 Eu1 N1 67.09(10) . .
O8 Eu1 N1 65.06(12) . .
O7 Eu1 N1 64.80(12) . .
O11 Eu1 O5 66.56(13) . .
O10 Eu1 O5 134.48(12) . .
O4 Eu1 O5 49.70(11) . .
O1 Eu1 O5 71.54(10) 3_655 .
O6 Eu1 O5 69.74(10) . .
O8 Eu1 O5 123.29(12) . .
O7 Eu1 O5 139.65(11) . .
N1 Eu1 O5 112.75(12) . .
O11 Eu1 C10 71.37(16) . .
O10 Eu1 C10 142.27(14) . .
O4 Eu1 C10 24.53(12) . .
O1 Eu1 C10 96.56(11) 3_655 .
O6 Eu1 C10 77.09(12) . .
O8 Eu1 C10 99.80(13) . .
O7 Eu1 C10 149.01(14) . .
N1 Eu1 C10 95.57(14) . .
O5 Eu1 C10 25.29(11) . .
O11 Eu1 Mn1 112.89(10) . .
O10 Eu1 Mn1 112.11(9) . .
O4 Eu1 Mn1 105.64(9) . .
O1 Eu1 Mn1 32.43(7) 3_655 .
O6 Eu1 Mn1 31.83(7) . .
O8 Eu1 Mn1 158.24(9) . .
O7 Eu1 Mn1 69.82(8) . .
N1 Eu1 Mn1 94.61(8) . .
O5 Eu1 Mn1 70.33(7) . .
C10 Eu1 Mn1 89.38(9) . .
O11 Eu1 Mn2 58.69(10) . .
O10 Eu1 Mn2 107.05(9) . .
O4 Eu1 Mn2 82.93(8) . .
O1 Eu1 Mn2 42.09(7) 3_655 .
O6 Eu1 Mn2 74.84(6) . .
O8 Eu1 Mn2 144.33(9) . .
O7 Eu1 Mn2 120.09(8) . .
N1 Eu1 Mn2 138.13(9) . .
O5 Eu1 Mn2 33.73(7) . .
C10 Eu1 Mn2 58.42(9) . .
Mn1 Eu1 Mn2 56.680(15) . .
O6 Mn1 O2 98.21(14) . .
O6 Mn1 O1 84.18(12) . 3_655
O2 Mn1 O1 171.54(12) . 3_655
O6 Mn1 O3 175.13(13) . 3_655
O2 Mn1 O3 86.43(13) . 3_655
O1 Mn1 O3 91.02(12) 3_655 3_655
O6 Mn1 O14 92.67(12) . 3_655
O2 Mn1 O14 89.98(13) . 3_655
O1 Mn1 O14 98.03(13) 3_655 3_655
O3 Mn1 O14 88.78(12) 3_655 3_655
O6 Mn1 O3 99.56(11) . .
O2 Mn1 O3 86.03(12) . .
O1 Mn1 O3 85.57(11) 3_655 .
O3 Mn1 O3 79.23(12) 3_655 .
O14 Mn1 O3 167.56(11) 3_655 .
O6 Mn1 Mn2 139.62(9) . 3_655
O2 Mn1 Mn2 43.52(10) . 3_655
O1 Mn1 Mn2 135.70(9) 3_655 3_655
O3 Mn1 Mn2 45.24(8) 3_655 3_655
O14 Mn1 Mn2 77.87(9) 3_655 3_655
O3 Mn1 Mn2 91.21(7) . 3_655
O6 Mn1 Eu1 42.78(9) . .
O2 Mn1 Eu1 140.99(9) . .
O1 Mn1 Eu1 41.85(8) 3_655 .
O3 Mn1 Eu1 132.53(9) 3_655 .
O14 Mn1 Eu1 92.42(9) 3_655 .
O3 Mn1 Eu1 98.10(7) . .
Mn2 Mn1 Eu1 169.79(3) 3_655 .
O12 Mn2 O13 106.35(17) . .
O12 Mn2 O5 94.90(16) . .
O13 Mn2 O5 105.94(15) . .
O12 Mn2 O2 100.57(15) . 3_655
O13 Mn2 O2 89.95(13) . 3_655
O5 Mn2 O2 153.76(13) . 3_655
O12 Mn2 O3 165.63(16) . .
O13 Mn2 O3 87.32(13) . .
O5 Mn2 O3 85.29(12) . .
O2 Mn2 O3 74.52(11) 3_655 .
O12 Mn2 Mn1 138.06(13) . 3_655
O13 Mn2 Mn1 79.19(10) . 3_655
O5 Mn2 Mn1 124.16(10) . 3_655
O2 Mn2 Mn1 37.50(8) 3_655 3_655
O3 Mn2 Mn1 38.91(7) . 3_655
O12 Mn2 Eu1 79.12(11) . .
O13 Mn2 Eu1 151.26(11) . .
O5 Mn2 Eu1 45.37(10) . .
O2 Mn2 Eu1 117.23(8) 3_655 .
O3 Mn2 Eu1 91.03(7) . .
Mn1 Mn2 Eu1 116.06(2) 3_655 .
O1 C1 C3 115.1(3) . .
O1 C1 H1A 108.5 . .
C3 C1 H1A 108.5 . .
O1 C1 H1B 108.5 . .
C3 C1 H1B 108.5 . .
H1A C1 H1B 107.5 . .
C3 C2 H2A 109.5 . .
C3 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C3 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C5 C3 C1 111.7(4) . .
C5 C3 C4 111.1(4) . .
C1 C3 C4 112.1(4) . .
C5 C3 C2 107.3(4) . .
C1 C3 C2 106.4(4) . .
C4 C3 C2 107.9(4) . .
O2 C4 C3 116.3(3) . .
O2 C4 H4A 108.2 . .
C3 C4 H4A 108.2 . .
O2 C4 H4B 108.2 . .
C3 C4 H4B 108.2 . .
H4A C4 H4B 107.4 . .
O3 C5 C3 114.1(4) . .
O3 C5 H5A 108.7 . .
C3 C5 H5A 108.7 . .
O3 C5 H5B 108.7 . .
C3 C5 H5B 108.7 . .
H5A C5 H5B 107.6 . .
C7' C6 C9 126.4(16) . .
C7' C6 C9' 121(2) . .
C9 C6 C9' 52.1(15) . .
C7' C6 C10 116.6(15) . .
C9 C6 C10 114.0(7) . .
C9' C6 C10 110.1(13) . .
C7' C6 C8 29.2(16) . .
C9 C6 C8 113.8(9) . .
C9' C6 C8 138.5(14) . .
C10 C6 C8 110.9(7) . .
C7' C6 C7 77.9(17) . .
C9 C6 C7 107.0(9) . .
C9' C6 C7 56.9(16) . .
C10 C6 C7 103.2(6) . .
C8 C6 C7 107.0(9) . .
C7' C6 C8' 107.2(19) . .
C9 C6 C8' 45.6(13) . .
C9' C6 C8' 97.7(18) . .
C10 C6 C8' 100.7(12) . .
C8 C6 C8' 80.7(14) . .
C7 C6 C8' 149.9(14) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C6 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C6 C7' H7'A 109.5 . .
C6 C7' H7'B 109.5 . .
H7'A C7' H7'B 109.5 . .
C6 C7' H7'C 109.5 . .
H7'A C7' H7'C 109.5 . .
H7'B C7' H7'C 109.5 . .
C6 C8' H8'A 109.5 . .
C6 C8' H8'B 109.5 . .
H8'A C8' H8'B 109.5 . .
C6 C8' H8'C 109.5 . .
H8'A C8' H8'C 109.5 . .
H8'B C8' H8'C 109.5 . .
C6 C9' H9'A 109.5 . .
C6 C9' H9'B 109.5 . .
H9'A C9' H9'B 109.5 . .
C6 C9' H9'C 109.4 . .
H9'A C9' H9'C 109.5 . .
H9'B C9' H9'C 109.5 . .
O4 C10 O5 120.1(4) . .
O4 C10 C6 118.8(4) . .
O5 C10 C6 121.1(4) . .
O4 C10 Eu1 52.8(2) . .
O5 C10 Eu1 67.7(3) . .
C6 C10 Eu1 170.1(4) . .
O6 C11 C12 109.7(4) . .
O6 C11 H11A 109.7 . .
C12 C11 H11A 109.7 . .
O6 C11 H11B 109.7 . .
C12 C11 H11B 109.7 . .
H11A C11 H11B 108.2 . .
N1 C12 C11 111.2(4) . .
N1 C12 H12A 109.4 . .
C11 C12 H12A 109.4 . .
N1 C12 H12B 109.4 . .
C11 C12 H12B 109.4 . .
H12A C12 H12B 108.0 . .
N1 C13 C14 110.8(4) . .
N1 C13 H13A 109.5 . .
C14 C13 H13A 109.5 . .
N1 C13 H13B 109.5 . .
C14 C13 H13B 109.5 . .
H13A C13 H13B 108.1 . .
O8 C14 C13 109.0(4) . .
O8 C14 H14A 109.9 . .
C13 C14 H14A 109.9 . .
O8 C14 H14B 109.9 . .
C13 C14 H14B 109.9 . .
H14A C14 H14B 108.3 . .
N1 C15 C16 112.2(4) . .
N1 C15 H15A 109.2 . .
C16 C15 H15A 109.2 . .
N1 C15 H15B 109.2 . .
C16 C15 H15B 109.2 . .
H15A C15 H15B 107.9 . .
O7 C16 C15 110.3(4) . .
O7 C16 H16A 109.6 . .
C15 C16 H16A 109.6 . .
O7 C16 H16B 109.6 . .
C15 C16 H16B 109.6 . .
H16A C16 H16B 108.1 . .
O9 C17 O10 124.3(5) . .
O9 C17 C18 119.1(5) . .
O10 C17 C18 116.6(5) . .
C20 C18 C21 134.8(11) . .
C20 C18 C19' 69.4(11) . .
C21 C18 C19' 116.7(13) . .
C20 C18 C17 105.2(7) . .
C21 C18 C17 109.8(8) . .
C19' C18 C17 115.9(10) . .
C20 C18 C19 105.6(9) . .
C21 C18 C19 90.9(11) . .
C19' C18 C19 36.2(10) . .
C17 C18 C19 106.6(7) . .
C20 C18 C21' 107.0(12) . .
C21 C18 C21' 31.7(10) . .
C19' C18 C21' 128.7(13) . .
C17 C18 C21' 114.2(9) . .
C19 C18 C21' 117.3(12) . .
C20 C18 C20' 39.8(9) . .
C21 C18 C20' 103.7(13) . .
C19' C18 C20' 105.9(13) . .
C17 C18 C20' 103.0(9) . .
C19 C18 C20' 140.0(10) . .
C21' C18 C20' 72.1(13) . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C18 C20 H20A 109.5 . .
C18 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C18 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C18 C21 H21A 109.5 . .
C18 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C18 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C18 C19' H19D 109.5 . .
C18 C19' H19E 109.5 . .
H19D C19' H19E 109.5 . .
C18 C19' H19F 109.5 . .
H19D C19' H19F 109.5 . .
H19E C19' H19F 109.5 . .
C18 C20' H20D 109.5 . .
C18 C20' H20E 109.5 . .
H20D C20' H20E 109.5 . .
C18 C20' H20F 109.5 . .
H20D C20' H20F 109.5 . .
H20E C20' H20F 109.5 . .
C18 C21' H21D 109.5 . .
C18 C21' H21E 109.5 . .
H21D C21' H21E 109.5 . .
C18 C21' H21F 109.5 . .
H21D C21' H21F 109.5 . .
H21E C21' H21F 109.5 . .
O11 C22 O12 124.4(5) . .
O11 C22 C23 118.8(5) . .
O12 C22 C23 116.8(5) . .
C24' C23 C25' 114.9(14) . .
C24' C23 C25 41.3(11) . .
C25' C23 C25 142.6(12) . .
C24' C23 C26 132.8(10) . .
C25' C23 C26 55.9(11) . .
C25 C23 C26 113.9(9) . .
C24' C23 C22 114.8(9) . .
C25' C23 C22 107.3(11) . .
C25 C23 C22 109.6(7) . .
C26 C23 C22 111.7(6) . .
C24' C23 C24 65.2(12) . .
C25' C23 C24 56.1(11) . .
C25 C23 C24 106.0(8) . .
C26 C23 C24 108.3(8) . .
C22 C23 C24 107.0(7) . .
C24' C23 C26' 107.8(15) . .
C25' C23 C26' 104.3(14) . .
C25 C23 C26' 70.8(12) . .
C26 C23 C26' 49.1(11) . .
C22 C23 C26' 106.9(9) . .
C24 C23 C26' 144.8(10) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C23 C25 H25A 109.5 . .
C23 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C23 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C23 C26 H26A 109.5 . .
C23 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C23 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C23 C24' H24D 109.5 . .
C23 C24' H24E 109.5 . .
H24D C24' H24E 109.5 . .
C23 C24' H24F 109.5 . .
H24D C24' H24F 109.5 . .
H24E C24' H24F 109.5 . .
C23 C25' H25D 109.5 . .
C23 C25' H25E 109.5 . .
H25D C25' H25E 109.5 . .
C23 C25' H25F 109.5 . .
H25D C25' H25F 109.5 . .
H25E C25' H25F 109.5 . .
C23 C26' H26D 109.5 . .
C23 C26' H26E 109.5 . .
H26D C26' H26E 109.5 . .
C23 C26' H26F 109.5 . .
H26D C26' H26F 109.5 . .
H26E C26' H26F 109.5 . .
O13 C27 O14 123.8(4) . .
O13 C27 C28 117.6(4) . .
O14 C27 C28 118.6(4) . .
C31' C28 C29 126.8(12) . .
C31' C28 C30' 118.4(15) . .
C29 C28 C30' 56.0(11) . .
C31' C28 C31 31.2(12) . .
C29 C28 C31 114.0(9) . .
C30' C28 C31 140.1(10) . .
C31' C28 C27 116.3(11) . .
C29 C28 C27 113.4(6) . .
C30' C28 C27 110.7(9) . .
C31 C28 C27 108.4(6) . .
C31' C28 C30 77.3(14) . .
C29 C28 C30 107.3(9) . .
C30' C28 C30 53.3(11) . .
C31 C28 C30 108.5(8) . .
C27 C28 C30 104.8(6) . .
C31' C28 C29' 106.4(15) . .
C29 C28 C29' 40.3(10) . .
C30' C28 C29' 96.0(14) . .
C31 C28 C29' 80.6(13) . .
C27 C28 C29' 106.2(9) . .
C30 C28 C29' 142.7(11) . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C28 C30 H30A 109.5 . .
C28 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C28 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C28 C31 H31A 109.5 . .
C28 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C28 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C28 C29' H29D 109.5 . .
C28 C29' H29E 109.5 . .
H29D C29' H29E 109.5 . .
C28 C29' H29F 109.5 . .
H29D C29' H29F 109.5 . .
H29E C29' H29F 109.5 . .
C28 C30' H30D 109.5 . .
C28 C30' H30E 109.5 . .
H30D C30' H30E 109.5 . .
C28 C30' H30F 109.5 . .
H30D C30' H30F 109.5 . .
H30E C30' H30F 109.5 . .
C28 C31' H31D 109.5 . .
C28 C31' H31E 109.5 . .
H31D C31' H31E 109.5 . .
C28 C31' H31F 109.5 . .
H31D C31' H31F 109.5 . .
H31E C31' H31F 109.5 . .
C1 O1 Mn1 120.8(3) . 3_655
C1 O1 Eu1 115.2(2) . 3_655
Mn1 O1 Eu1 105.72(12) 3_655 3_655
C4 O2 Mn1 126.5(3) . .
C4 O2 Mn2 120.4(3) . 3_655
Mn1 O2 Mn2 98.97(14) . 3_655
C5 O3 Mn1 121.3(2) . 3_655
C5 O3 Mn2 120.1(3) . .
Mn1 O3 Mn2 95.85(12) 3_655 .
C5 O3 Mn1 113.7(2) . .
Mn1 O3 Mn1 100.77(12) 3_655 .
Mn2 O3 Mn1 101.24(11) . .
C10 O4 Eu1 102.6(3) . .
C10 O5 Mn2 162.4(3) . .
C10 O5 Eu1 87.0(3) . .
Mn2 O5 Eu1 100.89(14) . .
C11 O6 Mn1 122.9(3) . .
C11 O6 Eu1 120.9(3) . .
Mn1 O6 Eu1 105.39(13) . .
C16 O7 Eu1 110.4(3) . .
C14 O8 Eu1 123.9(3) . .
C17 O10 Eu1 141.9(4) . .
C22 O11 Eu1 147.1(4) . .
C22 O12 Mn2 124.6(4) . .
C27 O13 Mn2 131.6(3) . .
C27 O14 Mn1 127.2(3) . 3_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N1 C15 1.479(6) .
N1 C12 1.482(6) .
N1 C13 1.483(6) .
N1 Eu1 2.685(4) .
Eu1 O11 2.350(4) .
Eu1 O10 2.376(4) .
Eu1 O4 2.407(4) .
Eu1 O1 2.409(3) 3_655
Eu1 O6 2.449(3) .
Eu1 O8 2.449(3) .
Eu1 O7 2.522(3) .
Eu1 O5 2.731(4) .
Eu1 C10 2.948(5) .
Eu1 Mn1 3.4763(6) .
Eu1 Mn2 3.7686(7) .
Mn1 O6 1.901(3) .
Mn1 O2 1.906(3) .
Mn1 O1 1.937(3) 3_655
Mn1 O3 1.952(3) 3_655
Mn1 O14 2.245(3) 3_655
Mn1 O3 2.254(3) .
Mn1 Mn2 3.0925(9) 3_655
Mn2 O12 2.065(4) .
Mn2 O13 2.127(4) .
Mn2 O5 2.131(4) .
Mn2 O2 2.156(3) 3_655
Mn2 O3 2.207(3) .
Mn2 Mn1 3.0925(9) 3_655
C1 O1 1.436(5) .
C1 C3 1.533(6) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 C3 1.536(7) .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C3 C5 1.522(7) .
C3 C4 1.535(6) .
C4 O2 1.411(6) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 O3 1.432(5) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C7' 1.46(2) .
C6 C9 1.459(11) .
C6 C9' 1.49(2) .
C6 C10 1.515(7) .
C6 C8 1.519(12) .
C6 C7 1.612(14) .
C6 C8' 1.62(2) .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C7' H7'A 0.9600 .
C7' H7'B 0.9600 .
C7' H7'C 0.9600 .
C8' H8'A 0.9600 .
C8' H8'B 0.9600 .
C8' H8'C 0.9600 .
C9' H9'A 0.9600 .
C9' H9'B 0.9600 .
C9' H9'C 0.9600 .
C10 O4 1.254(6) .
C10 O5 1.261(6) .
C11 O6 1.412(5) .
C11 C12 1.520(6) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C14 1.503(8) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 O8 1.426(6) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.515(8) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 O7 1.435(6) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 O9 1.246(7) .
C17 O10 1.252(6) .
C17 C18 1.537(8) .
C18 C20 1.496(13) .
C18 C21 1.508(14) .
C18 C19' 1.485(16) .
C18 C19 1.573(13) .
C18 C21' 1.519(16) .
C18 C20' 1.626(18) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C19' H19D 0.9600 .
C19' H19E 0.9600 .
C19' H19F 0.9600 .
C20' H20D 0.9600 .
C20' H20E 0.9600 .
C20' H20F 0.9600 .
C21' H21D 0.9600 .
C21' H21E 0.9600 .
C21' H21F 0.9600 .
C22 O11 1.249(6) .
C22 O12 1.253(6) .
C22 C23 1.518(7) .
C23 C24' 1.490(17) .
C23 C25' 1.502(19) .
C23 C25 1.490(13) .
C23 C26 1.499(11) .
C23 C24 1.546(13) .
C23 C26' 1.593(18) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C24' H24D 0.9600 .
C24' H24E 0.9600 .
C24' H24F 0.9600 .
C25' H25D 0.9600 .
C25' H25E 0.9600 .
C25' H25F 0.9600 .
C26' H26D 0.9600 .
C26' H26E 0.9600 .
C26' H26F 0.9600 .
C27 O13 1.257(6) .
C27 O14 1.265(6) .
C27 C28 1.529(7) .
C28 C31' 1.466(18) .
C28 C29 1.474(11) .
C28 C30' 1.488(18) .
C28 C31 1.513(11) .
C28 C30 1.591(13) .
C28 C29' 1.655(18) .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C29' H29D 0.9600 .
C29' H29E 0.9600 .
C29' H29F 0.9600 .
C30' H30D 0.9600 .
C30' H30E 0.9600 .
C30' H30F 0.9600 .
C31' H31D 0.9600 .
C31' H31E 0.9600 .
C31' H31F 0.9600 .
O1 Mn1 1.937(3) 3_655
O1 Eu1 2.409(3) 3_655
O2 Mn2 2.156(3) 3_655
O3 Mn1 1.952(3) 3_655
O14 Mn1 2.245(3) 3_655
