#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/10/7021035.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7021035
loop_
_publ_author_name
'Bojan, R. Vilma'
'Czerwieniec, Rafal'
'Laguna, Antonio'
'Lasanta, Tania'
'López-de-Luzuriaga, José M'
'Monge, Miguel'
'Olmos, M. Elena'
'Yersin, Harmut'
_publ_section_title
;
 Luminescent gold-silver complexes derived from neutral
 bis(perfluoroaryl)diphosphine gold(i) precursors.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4267
_journal_page_last               4277
_journal_paper_doi               10.1039/c2dt32973e
_journal_volume                  42
_journal_year                    2013
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C58.50 H25 Ag2 Au2 Br2 Cl F22 O4 P2'
_chemical_formula_sum            'C58.5 H25 Ag2 Au2 Br2 Cl F22 O4 P2'
_chemical_formula_weight         2076.67
_chemical_name_common            'TLC219 (CH2Cl2/hexano)'
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2009-07-06T18:02:45-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                102.6640(10)
_cell_angle_beta                 91.933(2)
_cell_angle_gamma                107.338(2)
_cell_formula_units_Z            2
_cell_length_a                   12.1335(3)
_cell_length_b                   15.0322(6)
_cell_length_c                   18.1077(7)
_cell_measurement_reflns_used    11376
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.1
_cell_measurement_theta_min      1.2
_cell_measurement_wavelength     0.71073
_cell_volume                     3058.51(19)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1986)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_orient_matrix_type       'by Bruker AXS Collect from scalepack cell'
_diffrn_orient_matrix_UB_11      0.113721E-1
_diffrn_orient_matrix_UB_12      0.690734E-1
_diffrn_orient_matrix_UB_13      0.14846E-2
_diffrn_orient_matrix_UB_21      0.607202E-1
_diffrn_orient_matrix_UB_22      -0.4517E-3
_diffrn_orient_matrix_UB_23      -0.359494E-1
_diffrn_orient_matrix_UB_31      -0.61021E-1
_diffrn_orient_matrix_UB_32      -0.195744E-1
_diffrn_orient_matrix_UB_33      -0.441125E-1
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_unetI/netI     0.0448
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            49615
_diffrn_reflns_theta_full        28.14
_diffrn_reflns_theta_max         28.14
_diffrn_reflns_theta_min         1.16
_diffrn_source                   'Enraf Nonius FR590'
_exptl_absorpt_coefficient_mu    6.929
_exptl_absorpt_correction_T_max  0.2149
_exptl_absorpt_correction_T_min  0.0421
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.255
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1950
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.15
_refine_diff_density_max         3.43
_refine_diff_density_min         -5.739
_refine_diff_density_rms         0.594
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.125
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     856
_refine_ls_number_reflns         14674
_refine_ls_number_restraints     190
_refine_ls_restrained_S_all      1.118
_refine_ls_R_factor_all          0.0977
_refine_ls_R_factor_gt           0.0675
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1514P)²+11.1527P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1952
_refine_ls_wR_factor_ref         0.2387
_reflns_number_gt                11256
_reflns_number_total             14674
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt32973e.txt
_cod_data_source_block           t2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C58.50 H25 Ag2 Au2 Br2 Cl F22 O4 P2'
_cod_database_code               7021035
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.45469(3) 0.17446(3) 0.17002(2) 0.04299(14) Uani 1 1 d .
Au2 Au 0.44944(3) 0.26576(3) 0.33346(2) 0.03756(14) Uani 1 1 d .
Ag1 Ag 0.54745(8) 0.43322(7) 0.45390(5) 0.0514(2) Uani 1 1 d .
Ag2 Ag 0.57392(9) 0.08930(8) 0.05113(6) 0.0641(3) Uani 1 1 d .
C1 C 0.6132(10) 0.2616(9) 0.1493(7) 0.053(2) Uani 1 1 d U
C2 C 0.7171(9) 0.2616(9) 0.1900(6) 0.046(2) Uani 1 1 d U
C3 C 0.8204(10) 0.3284(9) 0.1926(7) 0.051(2) Uani 1 1 d U
C4 C 0.8304(12) 0.3987(10) 0.1590(9) 0.068(3) Uani 1 1 d U
C5 C 0.7296(13) 0.4034(10) 0.1187(9) 0.067(3) Uani 1 1 d U
C6 C 0.6260(10) 0.3321(9) 0.1146(7) 0.051(2) Uani 1 1 d U
F1 F 0.7137(6) 0.1918(5) 0.2275(4) 0.0542(16) Uani 1 1 d U
F2 F 0.9149(6) 0.3253(6) 0.2293(4) 0.0627(19) Uani 1 1 d U
F3 F 0.7340(9) 0.4734(7) 0.0838(8) 0.104(4) Uani 1 1 d U
F4 F 0.5339(7) 0.3350(6) 0.0731(5) 0.0648(19) Uani 1 1 d U
C11 C 0.9439(14) 0.4742(11) 0.1598(11) 0.075(3) Uani 1 1 d U
C12 C 1.0074(16) 0.4735(15) 0.0979(16) 0.116(7) Uani 1 1 d U
C13 C 1.1143(17) 0.5366(16) 0.0970(19) 0.121(6) Uani 1 1 d U
C14 C 1.1615(17) 0.6047(15) 0.1570(17) 0.110(5) Uani 1 1 d U
C15 C 1.1082(18) 0.6105(15) 0.2207(16) 0.113(5) Uani 1 1 d U
C16 C 0.9997(16) 0.5442(12) 0.2235(13) 0.092(4) Uani 1 1 d U
F5 F 0.9608(12) 0.4005(11) 0.0313(11) 0.173(8) Uani 1 1 d U
F6 F 1.1653(14) 0.5329(12) 0.0297(13) 0.196(9) Uani 1 1 d U
Br1 Br 1.30874(19) 0.69598(19) 0.1539(2) 0.1639(17) Uani 1 1 d .
F7 F 1.1558(14) 0.6783(11) 0.2891(9) 0.172(7) Uani 1 1 d U
F8 F 0.9441(14) 0.5467(10) 0.2869(7) 0.146(6) Uani 1 1 d U
C21 C 0.5884(8) 0.2449(8) 0.3859(6) 0.0392(19) Uani 1 1 d U
C22 C 0.7043(8) 0.2988(7) 0.3805(6) 0.0376(19) Uani 1 1 d U
C23 C 0.7972(8) 0.2738(8) 0.4067(6) 0.0394(19) Uani 1 1 d U
C24 C 0.7827(9) 0.1963(8) 0.4385(5) 0.0393(18) Uani 1 1 d U
C25 C 0.6686(9) 0.1446(9) 0.4462(6) 0.043(2) Uani 1 1 d U
C26 C 0.5770(8) 0.1710(8) 0.4216(6) 0.041(2) Uani 1 1 d U
F9 F 0.7262(5) 0.3742(5) 0.3491(4) 0.0458(14) Uani 1 1 d U
F10 F 0.9051(5) 0.3271(5) 0.3974(4) 0.0463(14) Uani 1 1 d U
F11 F 0.6499(5) 0.0684(5) 0.4761(4) 0.0500(15) Uani 1 1 d U
F12 F 0.4686(5) 0.1156(5) 0.4300(4) 0.0532(16) Uani 1 1 d U
C31 C 0.8838(8) 0.1669(8) 0.4581(5) 0.0367(19) Uani 1 1 d U
C32 C 0.8969(9) 0.0808(8) 0.4203(6) 0.040(2) Uani 1 1 d U
C33 C 0.9999(9) 0.0604(8) 0.4297(6) 0.041(2) Uani 1 1 d U
C34 C 1.0936(9) 0.1263(9) 0.4791(6) 0.041(2) Uani 1 1 d U
C35 C 1.0796(9) 0.2094(8) 0.5207(6) 0.040(2) Uani 1 1 d U
C36 C 0.9764(8) 0.2298(8) 0.5102(5) 0.038(2) Uani 1 1 d U
F13 F 0.8110(5) 0.0179(5) 0.3702(3) 0.0449(14) Uani 1 1 d U
F14 F 1.0086(6) -0.0221(5) 0.3889(4) 0.0481(15) Uani 1 1 d U
Br2 Br 1.23481(10) 0.10277(10) 0.48490(9) 0.0594(3) Uani 1 1 d .
F15 F 1.1659(5) 0.2714(5) 0.5705(4) 0.0514(16) Uani 1 1 d U
F16 F 0.9685(6) 0.3143(5) 0.5504(4) 0.0528(17) Uani 1 1 d U
P1 P 0.2898(2) 0.0640(2) 0.18719(14) 0.0368(6) Uani 1 1 d .
P2 P 0.2902(2) 0.2930(2) 0.28393(15) 0.0372(6) Uani 1 1 d .
C51 C 0.1599(8) 0.0939(8) 0.2199(5) 0.036(2) Uani 1 1 d U
C52 C 0.1599(9) 0.1869(8) 0.2588(6) 0.040(2) Uani 1 1 d U
C53 C 0.0544(9) 0.2004(8) 0.2756(6) 0.044(2) Uani 1 1 d U
H53 H 0.0526 0.2611 0.3 0.053 Uiso 1 1 calc R
C54 C -0.0478(9) 0.1250(9) 0.2566(6) 0.047(3) Uani 1 1 d U
H54 H -0.1181 0.1353 0.2675 0.057 Uiso 1 1 calc R
C55 C -0.0456(9) 0.0349(9) 0.2217(6) 0.042(2) Uani 1 1 d U
H55 H -0.1141 -0.0164 0.2109 0.05 Uiso 1 1 calc R
C56 C 0.0556(9) 0.0201(8) 0.2026(5) 0.040(2) Uani 1 1 d U
H56 H 0.055 -0.0411 0.1774 0.048 Uiso 1 1 calc R
C61 C 0.2317(9) -0.0196(8) 0.0956(5) 0.040(2) Uani 1 1 d U
C62 C 0.1753(11) 0.0117(10) 0.0418(6) 0.053(3) Uani 1 1 d U
H62 H 0.1684 0.0731 0.054 0.064 Uiso 1 1 calc R
C63 C 0.1313(12) -0.0468(11) -0.0275(7) 0.061(3) Uani 1 1 d U
H63 H 0.0973 -0.0246 -0.0634 0.073 Uiso 1 1 calc R
C64 C 0.1367(12) -0.1411(12) -0.0455(7) 0.065(3) Uani 1 1 d U
H64 H 0.0998 -0.1833 -0.0913 0.079 Uiso 1 1 calc R
C65 C 0.1964(12) -0.1704(10) 0.0044(7) 0.059(3) Uani 1 1 d U
H65 H 0.208 -0.23 -0.0092 0.071 Uiso 1 1 calc R
C66 C 0.2407(11) -0.1088(9) 0.0774(7) 0.053(3) Uani 1 1 d U
H66 H 0.2763 -0.1303 0.1131 0.063 Uiso 1 1 calc R
C71 C 0.3235(10) -0.0062(9) 0.2502(6) 0.046(2) Uani 1 1 d U
C72 C 0.4370(11) -0.0121(10) 0.2520(7) 0.054(3) Uani 1 1 d U
H72 H 0.4907 0.0191 0.2232 0.065 Uiso 1 1 calc R
C73 C 0.4675(13) -0.0676(11) 0.2995(7) 0.062(3) Uani 1 1 d U
H73 H 0.5416 -0.0737 0.3004 0.074 Uiso 1 1 calc R
C74 C 0.3902(15) -0.1118(13) 0.3437(9) 0.072(4) Uani 1 1 d U
H74 H 0.411 -0.1474 0.3746 0.087 Uiso 1 1 calc R
C75 C 0.2782(13) -0.1022(12) 0.3411(8) 0.065(3) Uani 1 1 d U
H75 H 0.2247 -0.1313 0.3711 0.077 Uiso 1 1 calc R
C76 C 0.2470(11) -0.0506(10) 0.2951(7) 0.055(3) Uani 1 1 d U
H76 H 0.1725 -0.0455 0.2943 0.065 Uiso 1 1 calc R
C81 C 0.3053(11) 0.3418(9) 0.1993(6) 0.047(2) Uani 1 1 d U
C82 C 0.4015(13) 0.4178(9) 0.1999(7) 0.057(3) Uani 1 1 d U
H82 H 0.4594 0.4407 0.2405 0.068 Uiso 1 1 calc R
C83 C 0.4112(17) 0.4600(12) 0.1388(9) 0.074(4) Uani 1 1 d U
H83 H 0.4736 0.5146 0.1403 0.089 Uiso 1 1 calc R
C84 C 0.3308(18) 0.4231(14) 0.0761(9) 0.081(4) Uani 1 1 d U
H84 H 0.3403 0.4494 0.0338 0.097 Uiso 1 1 calc R
C85 C 0.2384(17) 0.3484(14) 0.0772(9) 0.080(4) Uani 1 1 d U
H85 H 0.1811 0.3257 0.0362 0.096 Uiso 1 1 calc R
C86 C 0.2240(14) 0.3041(11) 0.1352(7) 0.063(3) Uani 1 1 d U
H86 H 0.1611 0.2495 0.1324 0.076 Uiso 1 1 calc R
C91 C 0.2469(9) 0.3805(8) 0.3522(6) 0.040(2) Uani 1 1 d U
C92 C 0.2509(9) 0.3762(8) 0.4302(6) 0.041(2) Uani 1 1 d U
H92 H 0.28 0.3311 0.4444 0.049 Uiso 1 1 calc R
C93 C 0.2128(9) 0.4373(8) 0.4861(7) 0.048(2) Uani 1 1 d U
H93 H 0.2154 0.4334 0.5367 0.058 Uiso 1 1 calc R
C94 C 0.1712(10) 0.5036(9) 0.4625(7) 0.054(3) Uani 1 1 d U
H94 H 0.1424 0.5434 0.4981 0.065 Uiso 1 1 calc R
C95 C 0.1700(12) 0.5139(10) 0.3882(8) 0.061(3) Uani 1 1 d U
H95 H 0.1466 0.5624 0.3749 0.073 Uiso 1 1 calc R
C96 C 0.2055(10) 0.4484(9) 0.3335(7) 0.050(3) Uani 1 1 d U
H96 H 0.2005 0.4517 0.2829 0.06 Uiso 1 1 calc R
O1 O 0.5106(8) 0.3624(6) 0.5490(5) 0.057(2) Uani 1 1 d U
O2 O 0.5626(7) 0.5328(6) 0.3791(5) 0.054(2) Uani 1 1 d .
C7 C 0.4694(11) 0.3942(9) 0.6050(7) 0.051(2) Uani 1 1 d U
C8 C 0.4570(14) 0.3370(10) 0.6656(8) 0.066(3) Uani 1 1 d U
F17 F 0.4139(10) 0.2440(7) 0.6363(6) 0.090(3) Uani 1 1 d U
F18 F 0.5634(9) 0.3547(8) 0.7016(6) 0.093(3) Uani 1 1 d U
F19 F 0.3922(10) 0.3602(8) 0.7193(6) 0.091(3) Uani 1 1 d U
O3 O 0.6302(9) -0.0137(7) 0.1014(6) 0.072(3) Uani 1 1 d U
O4 O 0.5080(9) 0.1445(7) -0.0399(6) 0.074(3) Uani 1 1 d .
C9 C 0.5788(11) -0.1010(11) 0.0828(8) 0.065(3) Uani 1 1 d U
C10 C 0.6327(14) -0.1599(13) 0.1199(10) 0.078(3) Uani 1 1 d U
F20 F 0.5669(12) -0.2522(10) 0.1112(11) 0.157(6) Uani 1 1 d U
F21 F 0.7314(9) -0.1659(8) 0.0891(6) 0.096(3) Uani 1 1 d U
F22 F 0.6723(10) -0.1218(11) 0.1944(6) 0.110(4) Uani 1 1 d U
C20 C 0.146(2) 0.2926(18) 0.8204(16) 0.057(6) Uani 0.5 1 d P
H20A H 0.2175 0.2851 0.839 0.068 Uiso 0.5 1 calc PR
H20B H 0.1622 0.3578 0.8148 0.068 Uiso 0.5 1 calc PR
Cl1 Cl 0.0477(6) 0.2726(5) 0.8835(3) 0.0604(17) Uani 0.5 1 d P
Cl2 Cl 0.0915(11) 0.2109(7) 0.7312(4) 0.126(5) Uani 0.5 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Au1 P1 173.0(3) . .
C1 Au1 Ag2 62.9(3) . .
P1 Au1 Ag2 110.77(6) . .
C1 Au1 Au2 100.5(3) . .
P1 Au1 Au2 83.74(6) . .
Ag2 Au1 Au2 149.66(3) . .
C21 Au2 P2 175.6(3) . .
C21 Au2 Ag1 74.1(3) . .
P2 Au2 Ag1 102.76(7) . .
C21 Au2 Au1 102.6(3) . .
P2 Au2 Au1 81.78(6) . .
Ag1 Au2 Au1 145.08(3) . .
O2 Ag1 O1 163.6(3) . .
O2 Ag1 Au2 94.0(2) . .
O1 Ag1 Au2 97.1(2) . .
O2 Ag1 Ag1 81.6(2) . 2_666
O1 Ag1 Ag1 82.0(2) . 2_666
Au2 Ag1 Ag1 133.47(5) . 2_666
O3 Ag2 O4 157.0(4) . .
O3 Ag2 C1 113.1(4) . .
O4 Ag2 C1 89.8(4) . .
O3 Ag2 Au1 103.2(3) . .
O4 Ag2 Au1 95.5(3) . .
C1 Ag2 Au1 43.3(3) . .
O3 Ag2 Ag2 81.4(2) . 2_655
O4 Ag2 Ag2 78.7(3) . 2_655
C1 Ag2 Ag2 153.9(3) . 2_655
Au1 Ag2 Ag2 114.05(5) . 2_655
C6 C1 C2 115.4(12) . .
C6 C1 Au1 124.8(9) . .
C2 C1 Au1 118.2(10) . .
C6 C1 Ag2 112.8(9) . .
C2 C1 Ag2 96.4(7) . .
Au1 C1 Ag2 73.8(4) . .
C3 C2 F1 117.2(10) . .
C3 C2 C1 122.6(13) . .
F1 C2 C1 120.2(11) . .
C4 C3 F2 118.0(12) . .
C4 C3 C2 120.8(12) . .
F2 C3 C2 121.1(13) . .
C3 C4 C5 119.1(13) . .
C3 C4 C11 122.7(13) . .
C5 C4 C11 118.2(14) . .
F3 C5 C6 119.3(12) . .
F3 C5 C4 121.9(13) . .
C6 C5 C4 118.7(13) . .
C1 C6 F4 118.9(11) . .
C1 C6 C5 123.2(12) . .
F4 C6 C5 117.9(12) . .
C16 C11 C12 113.8(18) . .
C16 C11 C4 123.6(19) . .
C12 C11 C4 122.3(16) . .
C13 C12 C11 125(2) . .
C13 C12 F5 117(2) . .
C11 C12 F5 118.1(16) . .
C14 C13 C12 119(3) . .
C14 C13 F6 121(2) . .
C12 C13 F6 119(3) . .
C13 C14 C15 120(2) . .
C13 C14 Br1 119(2) . .
C15 C14 Br1 120.5(19) . .
C14 C15 F7 124.0(19) . .
C14 C15 C16 121(2) . .
F7 C15 C16 115(3) . .
F8 C16 C11 116.8(16) . .
F8 C16 C15 123(2) . .
C11 C16 C15 120(2) . .
C26 C21 C22 115.1(9) . .
C26 C21 Au2 122.6(8) . .
C22 C21 Au2 122.0(8) . .
F9 C22 C23 118.8(9) . .
F9 C22 C21 120.4(9) . .
C23 C22 C21 120.8(11) . .
F10 C23 C24 120.1(8) . .
F10 C23 C22 117.2(10) . .
C24 C23 C22 122.7(10) . .
C23 C24 C25 116.8(9) . .
C23 C24 C31 120.4(9) . .
C25 C24 C31 122.7(10) . .
F11 C25 C26 120.6(10) . .
F11 C25 C24 119.1(9) . .
C26 C25 C24 120.3(11) . .
F12 C26 C21 119.3(9) . .
F12 C26 C25 116.3(10) . .
C21 C26 C25 124.2(10) . .
C32 C31 C36 116.8(9) . .
C32 C31 C24 121.8(9) . .
C36 C31 C24 121.0(9) . .
F13 C32 C31 119.3(9) . .
F13 C32 C33 118.9(9) . .
C31 C32 C33 121.7(10) . .
F14 C33 C32 118.6(10) . .
F14 C33 C34 120.8(9) . .
C32 C33 C34 120.6(10) . .
C35 C34 C33 118.5(9) . .
C35 C34 Br2 121.4(8) . .
C33 C34 Br2 120.1(8) . .
F15 C35 C34 119.6(9) . .
F15 C35 C36 119.9(9) . .
C34 C35 C36 120.5(10) . .
F16 C36 C35 118.2(9) . .
F16 C36 C31 120.0(9) . .
C35 C36 C31 121.8(9) . .
C61 P1 C71 106.5(5) . .
C61 P1 C51 101.6(4) . .
C71 P1 C51 105.8(5) . .
C61 P1 Au1 107.8(4) . .
C71 P1 Au1 110.1(4) . .
C51 P1 Au1 123.6(4) . .
C91 P2 C81 103.6(5) . .
C91 P2 C52 104.6(5) . .
C81 P2 C52 105.0(5) . .
C91 P2 Au2 110.9(3) . .
C81 P2 Au2 117.1(4) . .
C52 P2 Au2 114.4(3) . .
C56 C51 C52 118.8(9) . .
C56 C51 P1 116.6(7) . .
C52 C51 P1 124.6(8) . .
C53 C52 C51 118.4(10) . .
C53 C52 P2 117.3(8) . .
C51 C52 P2 124.2(7) . .
C54 C53 C52 120.9(10) . .
C55 C54 C53 119.8(10) . .
C56 C55 C54 120.5(10) . .
C55 C56 C51 121.5(10) . .
C66 C61 C62 119.3(10) . .
C66 C61 P1 123.0(9) . .
C62 C61 P1 117.7(8) . .
C63 C62 C61 120.4(12) . .
C62 C63 C64 120.4(13) . .
C65 C64 C63 119.6(12) . .
C64 C65 C66 119.2(12) . .
C61 C66 C65 120.7(12) . .
C76 C71 C72 119.7(11) . .
C76 C71 P1 124.6(9) . .
C72 C71 P1 115.7(10) . .
C71 C72 C73 118.1(12) . .
C74 C73 C72 121.5(13) . .
C73 C74 C75 118.4(14) . .
C76 C75 C74 120.9(14) . .
C75 C76 C71 121.4(12) . .
C82 C81 C86 119.6(12) . .
C82 C81 P2 117.6(9) . .
C86 C81 P2 122.8(11) . .
C81 C82 C83 118.8(13) . .
C84 C83 C82 121.3(17) . .
C85 C84 C83 118.1(15) . .
C84 C85 C86 123.2(16) . .
C85 C86 C81 118.7(16) . .
C96 C91 C92 117.2(10) . .
C96 C91 P2 124.0(9) . .
C92 C91 P2 118.7(8) . .
C93 C92 C91 122.6(11) . .
C94 C93 C92 116.7(11) . .
C93 C94 C95 123.3(10) . .
C94 C95 C96 117.8(12) . .
C91 C96 C95 122.3(12) . .
C7 O1 Ag1 123.2(9) . .
C7 O2 Ag1 123.2(8) 2_666 .
O1 C7 O2 129.9(13) . 2_666
O1 C7 C8 114.7(11) . .
O2 C7 C8 115.4(11) 2_666 .
F17 C8 F19 107.5(14) . .
F17 C8 F18 107.9(12) . .
F19 C8 F18 105.9(12) . .
F17 C8 C7 112.2(11) . .
F19 C8 C7 114.5(11) . .
F18 C8 C7 108.4(13) . .
C9 O3 Ag2 122.1(11) . .
C9 O4 Ag2 124.3(11) 2_655 .
O4 C9 O3 129.3(17) 2_655 .
O4 C9 C10 116.2(14) 2_655 .
O3 C9 C10 114.6(13) . .
F20 C10 F22 108.8(16) . .
F20 C10 F21 104.3(16) . .
F22 C10 F21 101.6(13) . .
F20 C10 C9 115.0(14) . .
F22 C10 C9 115.2(15) . .
F21 C10 C9 110.6(14) . .
Cl1 C20 Cl2 110.2(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C1 2.079(13) .
Au1 P1 2.268(3) .
Au1 Ag2 2.9106(10) .
Au1 Au2 2.9884(5) .
Au2 C21 2.044(9) .
Au2 P2 2.285(2) .
Au2 Ag1 2.8532(9) .
Ag1 O2 2.202(9) .
Ag1 O1 2.207(10) .
Ag1 Ag1 2.8605(16) 2_666
Ag2 O3 2.213(12) .
Ag2 O4 2.226(12) .
Ag2 C1 2.698(12) .
Ag2 Ag2 2.9293(19) 2_655
C1 C6 1.320(19) .
C1 C2 1.438(16) .
C2 C3 1.345(17) .
C2 F1 1.361(15) .
C3 C4 1.31(2) .
C3 F2 1.324(14) .
C4 C5 1.432(19) .
C4 C11 1.50(2) .
C5 F3 1.329(17) .
C5 C6 1.375(19) .
C6 F4 1.342(14) .
C11 C16 1.37(2) .
C11 C12 1.38(3) .
C12 C13 1.36(3) .
C12 F5 1.41(3) .
C13 C14 1.30(4) .
C13 F6 1.38(3) .
C14 C15 1.34(4) .
C14 Br1 1.912(19) .
C15 F7 1.40(3) .
C15 C16 1.40(3) .
C16 F8 1.35(3) .
C21 C26 1.378(16) .
C21 C22 1.418(14) .
C22 F9 1.339(13) .
C22 C23 1.389(14) .
C23 F10 1.354(12) .
C23 C24 1.378(16) .
C24 C25 1.399(15) .
C24 C31 1.479(14) .
C25 F11 1.335(14) .
C25 C26 1.378(14) .
C26 F12 1.365(12) .
C31 C32 1.383(14) .
C31 C36 1.397(13) .
C32 F13 1.332(12) .
C32 C33 1.386(14) .
C33 F14 1.332(12) .
C33 C34 1.395(15) .
C34 C35 1.371(15) .
C34 Br2 1.854(10) .
C35 F15 1.328(12) .
C35 C36 1.391(14) .
C36 F16 1.350(11) .
P1 C61 1.818(10) .
P1 C71 1.826(12) .
P1 C51 1.845(9) .
P2 C91 1.810(10) .
P2 C81 1.831(12) .
P2 C52 1.839(11) .
C51 C56 1.384(15) .
C51 C52 1.421(13) .
C52 C53 1.388(14) .
C53 C54 1.379(16) .
C54 C55 1.373(16) .
C55 C56 1.354(14) .
C61 C66 1.347(16) .
C61 C62 1.410(16) .
C62 C63 1.350(17) .
C63 C64 1.40(2) .
C64 C65 1.36(2) .
C65 C66 1.418(17) .
C71 C76 1.374(18) .
C71 C72 1.407(16) .
C72 C73 1.431(19) .
C73 C74 1.37(2) .
C74 C75 1.41(2) .
C75 C76 1.370(19) .
C81 C82 1.366(19) .
C81 C86 1.393(17) .
C82 C83 1.38(2) .
C83 C84 1.37(2) .
C84 C85 1.33(3) .
C85 C86 1.35(2) .
C91 C96 1.362(16) .
C91 C92 1.427(15) .
C92 C93 1.399(14) .
C93 C94 1.381(19) .
C94 C95 1.39(2) .
C95 C96 1.411(16) .
O1 C7 1.214(14) .
O2 C7 1.249(14) 2_666
C7 O2 1.249(14) 2_666
C7 C8 1.52(2) .
C8 F17 1.316(16) .
C8 F19 1.323(18) .
C8 F18 1.351(17) .
O3 C9 1.238(17) .
O4 C9 1.204(16) 2_655
C9 O4 1.204(16) 2_655
C9 C10 1.50(2) .
C10 F20 1.35(2) .
C10 F22 1.35(2) .
C10 F21 1.358(18) .
C20 Cl1 1.68(3) .
C20 Cl2 1.77(3) .
