#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:25:44 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179919 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/14/7021412.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7021412
loop_
_publ_author_name
'Zhang, Bin'
'Zheng, Xiaodu'
'Su, Hao'
'Zhu, Yu'
'Du, Chenxia'
'Song, Maoping'
_publ_section_title
;
 Efficient fixation of atmospheric CO2 as carbonate by lanthanide-based
 complex via synergistic effect of zinc ion.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8571
_journal_page_last               8574
_journal_paper_doi               10.1039/c3dt50230a
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C41 H40 Eu2 N4 O17 Zn2, C2 H6 O'
_chemical_formula_sum            'C43 H46 Eu2 N4 O18 Zn2'
_chemical_formula_weight         1341.50
_chemical_name_systematic
;
?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2012-12-21
_audit_creation_method
;
Olex2 1.1
(compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;
_cell_angle_alpha                109.520(4)
_cell_angle_beta                 93.854(4)
_cell_angle_gamma                115.671(4)
_cell_formula_units_Z            2
_cell_length_a                   14.7702(5)
_cell_length_b                   14.9866(6)
_cell_length_c                   15.7271(8)
_cell_measurement_reflns_used    5005
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      26.3153
_cell_measurement_theta_min      3.0138
_cell_volume                     2863.8(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug 3 2011,13:03:54)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug 3 2011,13:03:54)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug 3 2011,13:03:54)
;
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
XS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      291.15
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_details
;
1 omega -18.00 22.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- -17.1323 -99.0000 -180.0000 40
2 omega -24.00 7.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 -99.0000 150.0000 31
3 omega -37.00 61.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 -19.0000 120.0000 98
4 omega 5.00 84.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 57.0000 90.0000 79
5 omega -1.00 56.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 57.0000 30.0000 57
6 omega 18.00 48.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 -99.0000 150.0000 30
7 omega -2.00 89.00 1.0000 64.9600
omega____ theta____ kappa____ phi______ frames
- 19.8666 57.0000 -60.0000 91
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0033319000
_diffrn_orient_matrix_UB_12      0.0036866000
_diffrn_orient_matrix_UB_13      0.0457642000
_diffrn_orient_matrix_UB_21      0.0187743000
_diffrn_orient_matrix_UB_22      -0.0373609000
_diffrn_orient_matrix_UB_23      -0.0052476000
_diffrn_orient_matrix_UB_31      0.0516561000
_diffrn_orient_matrix_UB_32      0.0434931000
_diffrn_orient_matrix_UB_33      0.0180154000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_unetI/netI     0.0781
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            22603
_diffrn_reflns_theta_full        26.35
_diffrn_reflns_theta_max         26.35
_diffrn_reflns_theta_min         3.02
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_source_current           n/a
_diffrn_source_voltage           n/a
_exptl_absorpt_coefficient_mu    3.052
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.50637
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.15 (release 03-08-2011 CrysAlis171 .NET)
(compiled Aug 3 2011,13:03:54)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1324
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.276
_refine_diff_density_min         -0.867
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     648
_refine_ls_number_reflns         11620
_refine_ls_number_restraints     89
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0951
_refine_ls_R_factor_gt           0.0524
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0515P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1213
_refine_ls_wR_factor_ref         0.1373
_reflns_number_gt                6762
_reflns_number_total             11620
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt50230a.txt
_cod_data_source_block           sha409
_cod_original_cell_volume        2863.8(2)
_cod_database_code               7021412
#BEGIN Tags that were not found in dictionaries:
_reflns_odcompleteness_completeness 99.73
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Eu1 Eu 0.278877(16) -0.126680(17) 0.396514(17) 0.06318(8) Uani 1 1 d U .
Eu2 Eu 0.522058(16) 0.178168(17) 0.451587(17) 0.06249(8) Uani 1 1 d U .
Zn1 Zn 0.08885(4) -0.37901(5) 0.36084(5) 0.0880(2) Uani 1 1 d . .
Zn2 Zn 0.35517(4) 0.21713(4) 0.32438(4) 0.07676(18) Uani 1 1 d . .
O1 O 0.1231(2) -0.2246(2) 0.4375(2) 0.0833(12) Uani 1 1 d . .
O2 O 0.1663(2) -0.3097(2) 0.2795(2) 0.0847(12) Uani 1 1 d . .
O3 O 0.1974(2) -0.0189(3) 0.5185(2) 0.0837(12) Uani 1 1 d . .
O4 O 0.3001(2) -0.1903(2) 0.2152(2) 0.0840(12) Uani 1 1 d . .
O5 O 0.4286(2) 0.2783(2) 0.4604(2) 0.0755(10) Uani 1 1 d . .
O6 O 0.4778(2) 0.1903(2) 0.3059(2) 0.0755(10) Uani 1 1 d . .
O7 O 0.5193(2) 0.3142(2) 0.6225(2) 0.0821(11) Uani 1 1 d . .
O8 O 0.6292(2) 0.1509(2) 0.3144(2) 0.0842(11) Uani 1 1 d . .
O9 O 0.1746(2) -0.0835(2) 0.3107(2) 0.0826(11) Uani 1 1 d . .
O10 O 0.3360(2) 0.0414(2) 0.3773(2) 0.0832(11) Uani 1 1 d . .
O11 O 0.2338(2) 0.0763(2) 0.2984(2) 0.0804(10) Uani 1 1 d . .
O12 O 0.6932(2) 0.2530(2) 0.5495(3) 0.1129(14) Uani 1 1 d . .
O13 O 0.6667(2) 0.3496(2) 0.4866(3) 0.0844(11) Uani 1 1 d U .
O14 O 0.8239(2) 0.4146(2) 0.5732(3) 0.0966(13) Uani 1 1 d . .
O15 O 0.5473(4) 0.0554(6) 0.6277(4) 0.101(3) Uani 0.572(3) 1 d PU 1
O16 O 0.3954(4) -0.0598(4) 0.5480(4) 0.0720(18) Uani 0.572(3) 1 d PU 1
O17 O 0.4602(5) 0.1040(4) 0.5564(5) 0.099(2) Uani 0.572(3) 1 d PU 1
O18 O 0.4867(8) -0.0079(6) 0.6178(6) 0.108(3) Uani 0.428(3) 1 d PU 2
O19 O 0.4024(6) 0.0379(8) 0.5330(7) 0.107(4) Uani 0.428(3) 1 d PU 2
O20 O 0.5593(5) 0.1314(5) 0.5887(5) 0.068(2) Uani 0.428(3) 1 d PU 2
O21 O -0.0196(6) -0.1744(6) 0.2227(5) 0.262(4) Uiso 1 1 d . .
H21 H -0.0107 -0.1183 0.2639 0.394 Uiso 1 1 calc R .
N1 N -0.0493(3) -0.4345(3) 0.3983(4) 0.117(2) Uani 1 1 d D .
N2 N -0.0031(4) -0.5171(4) 0.2464(4) 0.150(3) Uani 1 1 d D .
N3 N 0.3124(3) 0.3344(3) 0.3516(3) 0.0855(13) Uani 1 1 d U .
N4 N 0.3429(3) 0.2263(3) 0.1981(3) 0.0926(15) Uani 1 1 d . .
C1 C 0.0685(3) -0.1917(4) 0.4910(4) 0.0778(18) Uani 1 1 d . .
C2 C 0.1058(3) -0.0819(4) 0.5370(4) 0.0778(18) Uani 1 1 d . .
C3 C 0.0555(4) -0.0404(5) 0.5918(4) 0.114(3) Uani 1 1 d . .
H3 H 0.0822 0.0341 0.6210 0.137 Uiso 1 1 calc R .
C4 C -0.0368(5) -0.1103(7) 0.6042(5) 0.158(4) Uani 1 1 d . .
H4 H -0.0727 -0.0829 0.6416 0.189 Uiso 1 1 calc R .
C5 C -0.0741(5) -0.2174(6) 0.5620(5) 0.139(3) Uani 1 1 d . .
H5 H -0.1346 -0.2636 0.5725 0.166 Uiso 1 1 calc R .
C6 C -0.0253(4) -0.2605(5) 0.5039(4) 0.101(2) Uani 1 1 d . .
C7 C -0.0758(4) -0.3720(6) 0.4575(5) 0.128(3) Uani 1 1 d . .
H7 H -0.1387 -0.4078 0.4708 0.154 Uiso 1 1 calc R .
C8 C -0.1076(7) -0.5545(5) 0.3576(4) 0.140(4) Uani 0.687(6) 1 d PDU 1
H8A H -0.1772 -0.5809 0.3668 0.167 Uiso 0.687(6) 1 calc PR 1
H8B H -0.0722 -0.5839 0.3845 0.167 Uiso 0.687(6) 1 calc PR 1
C8A C -0.1234(7) -0.5406(7) 0.3222(10) 0.140(4) Uani 0.313(6) 1 d PDU 2
H8AA H -0.1593 -0.5290 0.2764 0.167 Uiso 0.313(6) 1 calc PR 2
H8AB H -0.1747 -0.5837 0.3476 0.167 Uiso 0.313(6) 1 calc PR 2
C9 C -0.1095(4) -0.5827(6) 0.2573(5) 0.137(4) Uani 0.687(6) 1 d PDU 1
H9 H -0.1290 -0.6595 0.2276 0.164 Uiso 0.687(6) 1 calc PR 1
C9A C -0.0707(8) -0.6011(6) 0.2756(6) 0.137(4) Uani 0.313(6) 1 d PDU 2
H9A H -0.1192 -0.6678 0.2218 0.164 Uiso 0.313(6) 1 calc PR 2
C10 C -0.2029(5) -0.5702(7) 0.2311(7) 0.177(5) Uani 0.687(6) 1 d PDU 1
H10A H -0.1948 -0.5033 0.2755 0.266 Uiso 0.687(6) 1 calc PR 1
H10B H -0.2647 -0.6295 0.2313 0.266 Uiso 0.687(6) 1 calc PR 1
H10C H -0.2084 -0.5698 0.1701 0.266 Uiso 0.687(6) 1 calc PR 1
C10A C -0.0480(15) -0.6242(12) 0.3584(9) 0.177(5) Uani 0.313(6) 1 d PD 2
H10D H 0.0255 -0.5855 0.3852 0.266 Uiso 0.313(6) 1 calc PR 2
H10E H -0.0727 -0.7005 0.3387 0.266 Uiso 0.313(6) 1 calc PR 2
H10F H -0.0823 -0.6015 0.4040 0.266 Uiso 0.313(6) 1 calc PR 2
C11 C 0.0149(6) -0.5388(6) 0.1676(6) 0.157(4) Uani 1 1 d . .
H11 H -0.0300 -0.6077 0.1222 0.188 Uiso 1 1 calc R .
C12 C 0.0985(5) -0.4679(5) 0.1396(5) 0.132(3) Uani 1 1 d U .
C13 C 0.1094(7) -0.5132(7) 0.0451(6) 0.188(4) Uani 1 1 d U .
H13 H 0.0665 -0.5864 0.0083 0.225 Uiso 1 1 calc R .
C14 C 0.1806(7) -0.4514(7) 0.0093(6) 0.184(4) Uani 1 1 d U .
H14 H 0.1860 -0.4821 -0.0508 0.221 Uiso 1 1 calc R .
C15 C 0.2468(6) -0.3385(6) 0.0657(5) 0.161(4) Uani 1 1 d . .
H15 H 0.2942 -0.2937 0.0425 0.194 Uiso 1 1 calc R .
C16 C 0.2379(4) -0.2988(5) 0.1551(4) 0.096(2) Uani 1 1 d . .
C17 C 0.1664(4) -0.3586(4) 0.1942(4) 0.095(2) Uani 1 1 d . .
C18 C 0.2371(4) 0.0963(4) 0.5577(5) 0.112(2) Uani 1 1 d . .
H18A H 0.2994 0.1304 0.5392 0.168 Uiso 1 1 calc R .
H18B H 0.2520 0.1230 0.6244 0.168 Uiso 1 1 calc R .
H18C H 0.1863 0.1125 0.5356 0.168 Uiso 1 1 calc R .
C19 C 0.3710(4) -0.1170(4) 0.1786(4) 0.113(3) Uani 1 1 d . .
H19A H 0.3317 -0.1082 0.1339 0.170 Uiso 1 1 calc R .
H19B H 0.4123 -0.1467 0.1491 0.170 Uiso 1 1 calc R .
H19C H 0.4155 -0.0479 0.2288 0.170 Uiso 1 1 calc R .
C20 C 0.4249(3) 0.3541(3) 0.5299(4) 0.0682(15) Uani 1 1 d . .
C21 C 0.4703(3) 0.3750(3) 0.6207(4) 0.0686(15) Uani 1 1 d . .
C22 C 0.4656(4) 0.4481(4) 0.6964(4) 0.0898(19) Uani 1 1 d . .
H22 H 0.4913 0.4568 0.7558 0.108 Uiso 1 1 calc R .
C23 C 0.4211(4) 0.5117(4) 0.6846(5) 0.098(2) Uani 1 1 d . .
H23 H 0.4189 0.5634 0.7361 0.117 Uiso 1 1 calc R .
C24 C 0.3834(3) 0.4966(4) 0.6004(4) 0.092(2) Uani 1 1 d . .
H24 H 0.3563 0.5401 0.5935 0.110 Uiso 1 1 calc R .
C25 C 0.3818(3) 0.4181(4) 0.5202(4) 0.0787(17) Uani 1 1 d . .
C26 C 0.3346(3) 0.4088(4) 0.4285(4) 0.0814(17) Uani 1 1 d . .
H26 H 0.3206 0.4638 0.4290 0.098 Uiso 1 1 calc R .
C27 C 0.2729(4) 0.3423(5) 0.2735(5) 0.176(2) Uani 1 1 d DU .
H27 H 0.3301 0.4083 0.2740 0.211 Uiso 1 1 calc R .
C28 C 0.2608(5) 0.2603(5) 0.1849(4) 0.158(2) Uani 1 1 d DU .
H28A H 0.2698 0.2892 0.1376 0.190 Uiso 1 1 calc R .
H28B H 0.1919 0.1983 0.1652 0.190 Uiso 1 1 calc R .
C29 C 0.1835(4) 0.3597(6) 0.2608(6) 0.176(2) Uani 1 1 d DU .
H29A H 0.1268 0.2954 0.2134 0.264 Uiso 1 1 calc R .
H29B H 0.2020 0.4190 0.2422 0.264 Uiso 1 1 calc R .
H29C H 0.1631 0.3762 0.3183 0.264 Uiso 1 1 calc R .
C30 C 0.3970(4) 0.2107(5) 0.1410(4) 0.102(2) Uani 1 1 d . .
H30 H 0.3843 0.2212 0.0873 0.122 Uiso 1 1 calc R .
C31 C 0.4745(4) 0.1793(4) 0.1483(4) 0.0897(18) Uani 1 1 d U .
C32 C 0.5176(5) 0.1600(5) 0.0734(5) 0.130(3) Uani 1 1 d . .
H32 H 0.4915 0.1624 0.0192 0.156 Uiso 1 1 calc R .
C33 C 0.5971(5) 0.1375(6) 0.0772(4) 0.153(3) Uani 1 1 d . .
H33 H 0.6253 0.1262 0.0260 0.183 Uiso 1 1 calc R .
C34 C 0.6363(5) 0.1312(5) 0.1542(4) 0.108(2) Uani 1 1 d . .
H34 H 0.6887 0.1126 0.1550 0.130 Uiso 1 1 calc R .
C35 C 0.5963(4) 0.1532(4) 0.2328(4) 0.0791(17) Uani 1 1 d . .
C36 C 0.5125(4) 0.1748(4) 0.2296(4) 0.0760(16) Uani 1 1 d U .
C37 C 0.5721(4) 0.3353(4) 0.7113(4) 0.111(2) Uani 1 1 d . .
H37A H 0.5235 0.3197 0.7488 0.167 Uiso 1 1 calc R .
H37B H 0.6243 0.4101 0.7409 0.167 Uiso 1 1 calc R .
H37C H 0.6041 0.2905 0.7044 0.167 Uiso 1 1 calc R .
C38 C 0.7181(4) 0.1377(5) 0.3237(4) 0.125(2) Uani 1 1 d . .
H38A H 0.7504 0.1653 0.3886 0.188 Uiso 1 1 calc R .
H38B H 0.7661 0.1765 0.2943 0.188 Uiso 1 1 calc R .
H38C H 0.6979 0.0622 0.2945 0.188 Uiso 1 1 calc R .
C39 C 0.2458(3) 0.0123(4) 0.3265(3) 0.0700(15) Uani 1 1 d . .
C40 C 0.7306(4) 0.3423(4) 0.5375(4) 0.0833(17) Uani 1 1 d U .
C41 C 0.4720(3) 0.0420(3) 0.5801(3) 0.0557(12) Uani 1 1 d . .
C42 C -0.0764(7) -0.2670(8) 0.2489(7) 0.208(4) Uiso 1 1 d . .
H42A H -0.0644 -0.3254 0.2123 0.250 Uiso 1 1 calc R .
H42B H -0.0444 -0.2446 0.3136 0.250 Uiso 1 1 calc R .
C43 C -0.1877(9) -0.3117(11) 0.2389(9) 0.315(7) Uiso 1 1 d . .
H43A H -0.2221 -0.3877 0.1999 0.472 Uiso 1 1 calc R .
H43B H -0.2125 -0.2758 0.2110 0.472 Uiso 1 1 calc R .
H43C H -0.2020 -0.3010 0.2991 0.472 Uiso 1 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O2 66.34(11) . .
O1 Eu1 O3 59.01(10) . .
O1 Eu1 O4 122.27(10) . .
O1 Eu1 O9 85.56(12) . .
O1 Eu1 O10 127.80(12) . .
O1 Eu1 O12 73.58(12) . 2_656
O1 Eu1 O15 164.0(2) . 2_656
O1 Eu1 O16 95.43(14) . .
O1 Eu1 O19 110.2(2) . .
O1 Eu1 O20 130.0(2) . 2_656
O1 Eu1 C39 107.09(13) . .
O2 Eu1 O3 120.36(10) . .
O2 Eu1 O4 58.36(10) . .
O2 Eu1 O12 72.41(12) . 2_656
O2 Eu1 O16 131.41(17) . .
O2 Eu1 O19 167.5(3) . .
O2 Eu1 C39 105.57(12) . .
O3 Eu1 O4 144.13(12) . .
O3 Eu1 C39 71.53(13) . .
O4 Eu1 C39 74.75(13) . .
O9 Eu1 O2 82.89(11) . .
O9 Eu1 O3 71.36(12) . .
O9 Eu1 O4 73.03(12) . .
O9 Eu1 O10 53.86(9) . .
O9 Eu1 O12 152.43(9) . 2_656
O9 Eu1 O15 110.0(2) . 2_656
O9 Eu1 O16 142.82(17) . .
O9 Eu1 O19 109.1(3) . .
O9 Eu1 O20 142.2(2) . 2_656
O9 Eu1 C39 26.55(10) . .
O10 Eu1 O2 127.59(12) . .
O10 Eu1 O3 76.10(11) . .
O10 Eu1 O4 79.65(11) . .
O10 Eu1 O12 153.50(9) . 2_656
O10 Eu1 O15 67.1(2) . 2_656
O10 Eu1 O16 99.65(15) . .
O10 Eu1 O19 64.4(3) . .
O10 Eu1 O20 99.64(19) . 2_656
O10 Eu1 C39 27.32(10) . .
O12 Eu1 O3 110.68(13) 2_656 .
O12 Eu1 O4 102.84(13) 2_656 .
O12 Eu1 C39 177.51(14) 2_656 .
O15 Eu1 O2 110.73(18) 2_656 .
O15 Eu1 O3 128.37(18) 2_656 .
O15 Eu1 O4 61.84(14) 2_656 .
O15 Eu1 O12 90.5(2) 2_656 2_656
O15 Eu1 O16 74.58(18) 2_656 .
O15 Eu1 O19 69.0(3) 2_656 .
O15 Eu1 C39 88.9(2) 2_656 .
O16 Eu1 O3 77.42(16) . .
O16 Eu1 O4 133.05(15) . .
O16 Eu1 O12 59.10(16) . 2_656
O16 Eu1 O19 36.1(3) . .
O16 Eu1 C39 122.98(16) . .
O19 Eu1 O3 62.8(2) . .
O19 Eu1 O4 127.3(2) . .
O19 Eu1 O12 95.1(3) . 2_656
O19 Eu1 C39 86.9(3) . .
O20 Eu1 O2 99.05(18) 2_656 .
O20 Eu1 O3 133.66(18) 2_656 .
O20 Eu1 O4 76.1(2) 2_656 .
O20 Eu1 O12 56.6(2) 2_656 2_656
O20 Eu1 O15 34.0(3) 2_656 2_656
O20 Eu1 O16 57.5(2) 2_656 .
O20 Eu1 O19 73.7(3) 2_656 .
O20 Eu1 C39 122.9(2) 2_656 .
O5 Eu2 O6 66.70(12) . .
O5 Eu2 O7 58.40(11) . .
O5 Eu2 O8 121.15(11) . .
O5 Eu2 O10 73.51(10) . .
O5 Eu2 O12 123.85(11) . .
O5 Eu2 O16 172.85(14) . 2_656
O5 Eu2 O20 120.29(19) . .
O5 Eu2 C40 103.50(13) . .
O6 Eu2 O7 122.77(11) . .
O6 Eu2 O8 58.22(11) . .
O6 Eu2 O10 73.04(10) . .
O6 Eu2 O16 117.94(15) . 2_656
O6 Eu2 O20 170.23(17) . .
O6 Eu2 C40 105.82(14) . .
O7 Eu2 C40 74.14(14) . .
O8 Eu2 O7 147.41(9) . .
O8 Eu2 C40 74.75(14) . .
O10 Eu2 O7 104.05(10) . .
O10 Eu2 O8 106.59(10) . .
O10 Eu2 O16 102.16(12) . 2_656
O10 Eu2 O20 101.67(15) . .
O10 Eu2 C40 177.00(14) . .
O12 Eu2 O6 128.14(12) . .
O12 Eu2 O7 76.35(12) . .
O12 Eu2 O8 80.45(12) . .
O12 Eu2 O10 155.26(11) . .
O12 Eu2 O16 58.49(13) . 2_656
O12 Eu2 O20 55.29(16) . .
O12 Eu2 C40 27.11(14) . .
O13 Eu2 O5 82.32(11) . .
O13 Eu2 O6 83.45(11) . .
O13 Eu2 O7 74.91(11) . .
O13 Eu2 O8 72.91(11) . .
O13 Eu2 O10 151.31(11) . .
O13 Eu2 O12 53.29(12) . .
O13 Eu2 O16 103.30(13) . 2_656
O13 Eu2 O20 103.79(15) . .
O13 Eu2 C40 26.18(13) . .
O16 Eu2 O7 118.38(14) 2_656 .
O16 Eu2 O8 65.28(15) 2_656 .
O16 Eu2 O20 54.4(2) 2_656 .
O16 Eu2 C40 80.83(15) 2_656 .
O17 Eu2 O5 98.87(19) . .
O17 Eu2 O6 145.95(16) . .
O17 Eu2 O7 61.97(17) . .
O17 Eu2 O8 138.67(19) . .
O17 Eu2 O10 73.28(16) . .
O17 Eu2 O12 85.78(18) . .
O17 Eu2 O13 126.69(16) . .
O17 Eu2 O16 74.3(2) . 2_656
O17 Eu2 O18 79.1(3) . 2_656
O17 Eu2 O20 31.4(2) . .
O17 Eu2 C40 107.58(19) . .
O18 Eu2 O5 145.1(2) 2_656 .
O18 Eu2 O6 95.5(3) 2_656 .
O18 Eu2 O7 139.5(3) 2_656 .
O18 Eu2 O8 62.5(3) 2_656 .
O18 Eu2 O10 72.6(3) 2_656 .
O18 Eu2 O12 90.9(3) 2_656 .
O18 Eu2 O13 127.0(3) 2_656 .
O18 Eu2 O16 32.7(2) 2_656 2_656
O18 Eu2 O20 74.9(3) 2_656 .
O18 Eu2 C40 110.3(3) 2_656 .
O20 Eu2 O7 66.13(19) . .
O20 Eu2 O8 117.17(19) . .
O20 Eu2 C40 79.87(17) . .
O1 Zn1 Eu1 43.72(9) . .
O1 Zn1 N1 89.91(15) . .
O1 Zn1 N2 146.7(2) . .
O2 Zn1 Eu1 44.71(8) . .
O2 Zn1 O1 81.76(14) . .
O2 Zn1 N1 145.06(19) . .
O2 Zn1 N2 90.04(18) . .
O14 Zn1 Eu1 96.35(8) 2_656 .
O14 Zn1 O1 108.20(14) 2_656 .
O14 Zn1 O2 108.96(16) 2_656 .
O14 Zn1 N1 105.89(19) 2_656 .
O14 Zn1 N2 105.0(2) 2_656 .
N1 Zn1 Eu1 133.26(13) . .
N2 Zn1 Eu1 134.49(16) . .
N2 Zn1 N1 78.5(2) . .
O5 Zn2 Eu2 43.86(10) . .
O5 Zn2 O6 81.91(13) . .
O5 Zn2 N3 90.84(16) . .
O5 Zn2 N4 151.53(13) . .
O6 Zn2 Eu2 44.09(9) . .
O6 Zn2 N3 142.53(13) . .
O6 Zn2 N4 89.44(17) . .
O11 Zn2 Eu2 94.81(10) . .
O11 Zn2 O5 106.43(13) . .
O11 Zn2 O6 107.13(13) . .
O11 Zn2 N3 110.17(14) . .
O11 Zn2 N4 102.04(14) . .
N3 Zn2 Eu2 133.70(12) . .
N4 Zn2 Eu2 133.51(14) . .
N4 Zn2 N3 79.66(19) . .
Zn1 O1 Eu1 100.62(15) . .
C1 O1 Eu1 131.8(3) . .
C1 O1 Zn1 127.5(3) . .
Zn1 O2 Eu1 99.63(14) . .
C17 O2 Eu1 132.2(3) . .
C17 O2 Zn1 127.0(3) . .
C2 O3 Eu1 117.2(3) . .
C2 O3 C18 117.5(4) . .
C18 O3 Eu1 125.1(3) . .
C16 O4 Eu1 117.5(3) . .
C16 O4 C19 118.3(4) . .
C19 O4 Eu1 124.2(3) . .
Zn2 O5 Eu2 100.65(13) . .
C20 O5 Eu2 132.6(3) . .
C20 O5 Zn2 126.7(3) . .
Zn2 O6 Eu2 100.16(13) . .
C36 O6 Eu2 132.9(3) . .
C36 O6 Zn2 126.7(3) . .
C21 O7 Eu2 117.6(3) . .
C21 O7 C37 116.3(4) . .
C37 O7 Eu2 125.8(3) . .
C35 O8 Eu2 118.2(3) . .
C35 O8 C38 116.7(4) . .
C38 O8 Eu2 125.1(3) . .
C39 O9 Eu1 96.6(3) . .
Eu1 O10 Eu2 115.51(13) . .
C39 O10 Eu1 95.1(2) . .
C39 O10 Eu2 149.4(3) . .
C39 O11 Zn2 118.6(3) . .
Eu2 O12 Eu1 115.23(11) . 2_656
C40 O12 Eu1 149.7(3) . 2_656
C40 O12 Eu2 94.2(3) . .
C40 O13 Eu2 97.9(3) . .
C40 O14 Zn1 115.9(3) . 2_656
Eu1 O15 Eu2 100.8(3) 2_656 2_656
C41 O15 Eu1 125.9(5) . 2_656
C41 O15 Eu2 91.7(4) . 2_656
Eu1 O16 Eu2 112.0(2) . 2_656
C41 O16 Eu1 115.9(4) . .
C41 O16 Eu2 107.2(4) . 2_656
C41 O17 Eu2 132.9(5) . .
C41 O18 Eu2 127.5(6) . 2_656
Eu1 O19 Eu2 102.9(4) . .
C41 O19 Eu1 122.5(7) . .
C41 O19 Eu2 98.1(5) . .
Eu1 O20 Eu2 112.3(3) 2_656 .
C41 O20 Eu1 117.8(5) . 2_656
C41 O20 Eu2 106.5(4) . .
C42 O21 H21 109.5 . .
C7 N1 Zn1 123.6(4) . .
C7 N1 C8 124.9(6) . .
C7 N1 C8A 124.7(6) . .
C8 N1 Zn1 111.1(5) . .
C8 N1 C8A 27.8(8) . .
C8A N1 Zn1 107.4(6) . .
C9 N2 Zn1 113.7(4) . .
C9A N2 Zn1 109.3(4) . .
C9A N2 C9 31.6(6) . .
C11 N2 Zn1 125.0(4) . .
C11 N2 C9 119.9(5) . .
C11 N2 C9A 122.4(6) . .
C26 N3 Zn2 126.3(4) . .
C26 N3 C27 117.4(5) . .
C27 N3 Zn2 115.0(4) . .
C28 N4 Zn2 108.6(4) . .
C30 N4 Zn2 126.0(5) . .
C30 N4 C28 125.4(5) . .
O1 C1 C2 118.1(4) . .
O1 C1 C6 124.8(5) . .
C2 C1 C6 117.2(5) . .
C1 C2 O3 113.9(5) . .
C3 C2 O3 123.5(5) . .
C3 C2 C1 122.6(5) . .
C2 C3 H3 120.5 . .
C2 C3 C4 119.1(7) . .
C4 C3 H3 120.5 . .
C3 C4 H4 120.1 . .
C5 C4 C3 119.8(7) . .
C5 C4 H4 120.1 . .
C4 C5 H5 119.2 . .
C4 C5 C6 121.6(7) . .
C6 C5 H5 119.2 . .
C5 C6 C1 119.7(6) . .
C5 C6 C7 116.5(5) . .
C7 C6 C1 123.8(6) . .
N1 C7 C6 130.2(6) . .
N1 C7 H7 114.9 . .
C6 C7 H7 114.9 . .
N1 C8 H8A 111.2 . .
N1 C8 H8B 111.2 . .
N1 C8 C9 102.6(5) . .
H8A C8 H8B 109.2 . .
C9 C8 H8A 111.2 . .
C9 C8 H8B 111.2 . .
N1 C8A H8AA 109.2 . .
N1 C8A H8AB 109.2 . .
N1 C8A C9A 112.1(7) . .
H8AA C8A H8AB 107.9 . .
C9A C8A H8AA 109.2 . .
C9A C8A H8AB 109.2 . .
N2 C9 H9 108.4 . .
N2 C9 C10 124.0(7) . .
C8 C9 N2 110.1(5) . .
C8 C9 H9 108.4 . .
C8 C9 C10 96.4(7) . .
C10 C9 H9 108.4 . .
N2 C9A C8A 94.7(8) . .
N2 C9A H9A 111.4 . .
N2 C9A C10A 129.7(9) . .
C8A C9A H9A 111.4 . .
C8A C9A C10A 93.3(12) . .
C10A C9A H9A 111.4 . .
C9A C10A H10D 109.5 . .
C9A C10A H10E 109.5 . .
C9A C10A H10F 109.5 . .
H10D C10A H10E 109.5 . .
H10D C10A H10F 109.5 . .
H10E C10A H10F 109.5 . .
N2 C11 H11 116.6 . .
N2 C11 C12 126.7(6) . .
C12 C11 H11 116.6 . .
C11 C12 C13 117.4(6) . .
C17 C12 C11 125.0(7) . .
C17 C12 C13 117.6(7) . .
C12 C13 H13 118.9 . .
C14 C13 C12 122.1(7) . .
C14 C13 H13 118.9 . .
C13 C14 H14 120.4 . .
C13 C14 C15 119.1(8) . .
C15 C14 H14 120.4 . .
C14 C15 H15 121.2 . .
C16 C15 C14 117.7(7) . .
C16 C15 H15 121.2 . .
C15 C16 O4 121.5(6) . .
C15 C16 C17 125.1(6) . .
C17 C16 O4 113.4(5) . .
O2 C17 C12 123.5(6) . .
O2 C17 C16 118.2(5) . .
C16 C17 C12 118.3(6) . .
O3 C18 H18A 109.5 . .
O3 C18 H18B 109.5 . .
O3 C18 H18C 109.5 . .
H18A C18 H18B 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O4 C19 H19A 109.5 . .
O4 C19 H19B 109.5 . .
O4 C19 H19C 109.5 . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O5 C20 C21 117.7(5) . .
O5 C20 C25 124.8(5) . .
C25 C20 C21 117.5(5) . .
O7 C21 C20 113.0(4) . .
C22 C21 O7 125.5(5) . .
C22 C21 C20 121.4(5) . .
C21 C22 H22 120.1 . .
C21 C22 C23 119.7(6) . .
C23 C22 H22 120.1 . .
C22 C23 H23 120.4 . .
C24 C23 C22 119.1(6) . .
C24 C23 H23 120.4 . .
C23 C24 H24 118.4 . .
C23 C24 C25 123.2(6) . .
C25 C24 H24 118.4 . .
C20 C25 C26 124.0(5) . .
C24 C25 C20 118.8(6) . .
C24 C25 C26 117.2(5) . .
N3 C26 C25 125.9(5) . .
N3 C26 H26 117.1 . .
C25 C26 H26 117.1 . .
N3 C27 H27 102.5 . .
N3 C27 C28 114.9(6) . .
N3 C27 C29 125.4(6) . .
C28 C27 H27 102.5 . .
C28 C27 C29 105.7(6) . .
C29 C27 H27 102.5 . .
N4 C28 H28A 110.1 . .
N4 C28 H28B 110.1 . .
C27 C28 N4 108.1(5) . .
C27 C28 H28A 110.1 . .
C27 C28 H28B 110.1 . .
H28A C28 H28B 108.4 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29B 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N4 C30 H30 115.7 . .
N4 C30 C31 128.6(6) . .
C31 C30 H30 115.7 . .
C32 C31 C30 117.7(6) . .
C32 C31 C36 119.6(6) . .
C36 C31 C30 122.6(6) . .
C31 C32 H32 119.2 . .
C33 C32 C31 121.5(7) . .
C33 C32 H32 119.2 . .
C32 C33 H33 119.4 . .
C34 C33 C32 121.2(7) . .
C34 C33 H33 119.4 . .
C33 C34 H34 120.5 . .
C33 C34 C35 118.9(7) . .
C35 C34 H34 120.5 . .
O8 C35 C34 124.9(6) . .
O8 C35 C36 114.6(5) . .
C34 C35 C36 120.5(5) . .
O6 C36 C31 126.0(5) . .
O6 C36 C35 115.9(5) . .
C31 C36 C35 118.1(5) . .
O7 C37 H37A 109.5 . .
O7 C37 H37B 109.5 . .
O7 C37 H37C 109.5 . .
H37A C37 H37B 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
O8 C38 H38A 109.5 . .
O8 C38 H38B 109.5 . .
O8 C38 H38C 109.5 . .
H38A C38 H38B 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
O9 C39 Eu1 56.8(3) . .
O9 C39 O10 114.4(4) . .
O10 C39 Eu1 57.6(2) . .
O11 C39 Eu1 177.8(3) . .
O11 C39 O9 125.0(4) . .
O11 C39 O10 120.5(4) . .
O12 C40 Eu2 58.7(2) . .
O13 C40 Eu2 55.9(2) . .
O13 C40 O12 114.6(4) . .
O14 C40 Eu2 178.2(5) . .
O14 C40 O12 122.0(5) . .
O14 C40 O13 123.4(5) . .
Eu2 C41 Eu1 79.74(9) 2_656 .
Eu2 C41 Eu1 79.53(10) . .
Eu2 C41 Eu2 129.07(15) 2_656 .
O15 C41 Eu1 144.9(5) . .
O15 C41 Eu2 66.4(4) . 2_656
O15 C41 Eu2 114.3(4) . .
O15 C41 O16 112.1(6) . .
O15 C41 O20 67.2(5) . .
O16 C41 Eu1 42.5(3) . .
O16 C41 Eu2 121.6(3) . .
O16 C41 Eu2 49.4(3) . 2_656
O16 C41 O20 161.7(6) . .
O17 C41 Eu1 80.2(3) . .
O17 C41 Eu2 31.6(4) . .
O17 C41 Eu2 155.1(4) . 2_656
O17 C41 O15 129.0(6) . .
O17 C41 O16 118.9(5) . .
O17 C41 O19 45.0(5) . .
O17 C41 O20 63.6(5) . .
O18 C41 Eu1 108.2(4) . .
O18 C41 Eu2 35.6(5) . 2_656
O18 C41 Eu2 154.6(6) . .
O18 C41 O15 46.4(5) . .
O18 C41 O16 67.4(5) . .
O18 C41 O17 169.2(7) . .
O18 C41 O19 139.5(8) . .
O18 C41 O20 113.5(7) . .
O19 C41 Eu1 39.6(5) . .
O19 C41 Eu2 60.4(5) . .
O19 C41 Eu2 118.8(5) . 2_656
O19 C41 O15 174.0(7) . .
O19 C41 O16 73.9(6) . .
O19 C41 O20 106.9(7) . .
O20 C41 Eu1 127.8(4) . .
O20 C41 Eu2 119.9(4) . 2_656
O20 C41 Eu2 49.8(4) . .
O21 C42 H42A 107.4 . .
O21 C42 H42B 107.4 . .
H42A C42 H42B 107.0 . .
C43 C42 O21 119.5(11) . .
C43 C42 H42A 107.4 . .
C43 C42 H42B 107.4 . .
C42 C43 H43A 109.5 . .
C42 C43 H43B 109.5 . .
C42 C43 H43C 109.5 . .
H43A C43 H43B 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.402(3) .
Eu1 O2 2.437(3) .
Eu1 O3 2.768(4) .
Eu1 O4 2.776(3) .
Eu1 O9 2.404(4) .
Eu1 O10 2.418(3) .
Eu1 O12 2.485(4) 2_656
Eu1 O15 2.429(5) 2_656
Eu1 O16 2.450(5) .
Eu1 O19 2.461(8) .
Eu1 O20 2.419(8) 2_656
Eu1 C39 2.853(5) .
Eu2 O5 2.420(3) .
Eu2 O6 2.427(3) .
Eu2 O7 2.794(3) .
Eu2 O8 2.786(4) .
Eu2 O10 2.491(2) .
Eu2 O12 2.426(3) .
Eu2 O13 2.368(3) .
Eu2 O16 2.552(7) 2_656
Eu2 O17 2.309(7) .
Eu2 O18 2.356(9) 2_656
Eu2 O20 2.575(8) .
Eu2 C40 2.832(4) .
Zn1 O1 2.026(3) .
Zn1 O2 2.020(4) .
Zn1 O14 1.952(4) 2_656
Zn1 N1 2.054(5) .
Zn1 N2 2.028(5) .
Zn2 O5 2.028(3) .
Zn2 O6 2.037(3) .
Zn2 O11 1.970(3) .
Zn2 N3 2.041(5) .
Zn2 N4 2.038(5) .
O1 C1 1.326(6) .
O2 C17 1.296(7) .
O3 C2 1.391(5) .
O3 C18 1.439(6) .
O4 C16 1.394(6) .
O4 C19 1.463(6) .
O5 C20 1.311(6) .
O6 C36 1.326(6) .
O7 C21 1.392(6) .
O7 C37 1.415(6) .
O8 C35 1.358(6) .
O8 C38 1.414(7) .
O9 C39 1.284(5) .
O10 C39 1.314(5) .
O11 C39 1.251(6) .
O12 Eu1 2.485(4) 2_656
O12 C40 1.294(6) .
O13 C40 1.262(6) .
O14 Zn1 1.952(4) 2_656
O14 C40 1.258(5) .
O15 Eu1 2.429(5) 2_656
O15 Eu2 2.943(8) 2_656
O15 C41 1.196(7) .
O16 Eu2 2.552(7) 2_656
O16 C41 1.332(6) .
O17 C41 1.182(8) .
O18 Eu2 2.356(9) 2_656
O18 C41 1.173(10) .
O19 C41 1.193(10) .
O20 Eu1 2.419(8) 2_656
O20 C41 1.355(7) .
O21 H21 0.8200 .
O21 C42 1.490(12) .
N1 C7 1.297(9) .
N1 C8 1.484(6) .
N1 C8A 1.484(7) .
N2 C9 1.508(6) .
N2 C9A 1.467(8) .
N2 C11 1.251(10) .
N3 C26 1.242(6) .
N3 C27 1.388(8) .
N4 C28 1.533(8) .
N4 C30 1.271(8) .
C1 C2 1.377(7) .
C1 C6 1.402(7) .
C2 C3 1.346(8) .
C3 H3 0.9300 .
C3 C4 1.389(9) .
C4 H4 0.9300 .
C4 C5 1.339(11) .
C5 H5 0.9300 .
C5 C6 1.367(10) .
C6 C7 1.383(9) .
C7 H7 0.9300 .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C8 C9 1.486(7) .
C8A H8AA 0.9700 .
C8A H8AB 0.9700 .
C8A C9A 1.486(9) .
C9 H9 0.9800 .
C9 C10 1.520(8) .
C9A H9A 0.9800 .
C9A C10A 1.507(9) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C10A H10D 0.9600 .
C10A H10E 0.9600 .
C10A H10F 0.9600 .
C11 H11 0.9300 .
C11 C12 1.448(10) .
C12 C13 1.466(11) .
C12 C17 1.395(8) .
C13 H13 0.9300 .
C13 C14 1.366(12) .
C14 H14 0.9300 .
C14 C15 1.432(10) .
C15 H15 0.9300 .
C15 C16 1.372(9) .
C16 C17 1.389(8) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 C21 1.407(7) .
C20 C25 1.400(7) .
C21 C22 1.352(7) .
C22 H22 0.9300 .
C22 C23 1.420(8) .
C23 H23 0.9300 .
C23 C24 1.306(8) .
C24 H24 0.9300 .
C24 C25 1.399(8) .
C25 C26 1.494(8) .
C26 H26 0.9300 .
C27 H27 0.9800 .
C27 C28 1.454(7) .
C27 C29 1.466(7) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 H30 0.9300 .
C30 C31 1.424(9) .
C31 C32 1.381(9) .
C31 C36 1.396(8) .
C32 H32 0.9300 .
C32 C33 1.358(10) .
C33 H33 0.9300 .
C33 C34 1.357(9) .
C34 H34 0.9300 .
C34 C35 1.407(8) .
C35 C36 1.411(8) .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
C41 Eu2 3.209(5) 2_656
C42 H42A 0.9700 .
C42 H42B 0.9700 .
C42 C43 1.455(14) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 Zn1 O1 C1 177.2(5) . .
Eu1 Zn1 O2 C17 168.5(6) . .
Eu1 Zn1 N1 C7 -11.5(7) . .
Eu1 Zn1 N1 C8 175.1(4) . .
Eu1 Zn1 N1 C8A 145.9(7) . .
Eu1 Zn1 N2 C9 -146.9(4) . .
Eu1 Zn1 N2 C9A 179.5(5) . .
Eu1 Zn1 N2 C11 19.6(9) . .
Eu1 O1 C1 C2 -3.3(8) . .
Eu1 O1 C1 C6 176.2(4) . .
Eu1 O2 C17 C12 175.4(5) . .
Eu1 O2 C17 C16 -4.8(9) . .
Eu1 O3 C2 C1 0.3(6) . .
Eu1 O3 C2 C3 -177.2(5) . .
Eu1 O4 C16 C15 -176.7(6) . .
Eu1 O4 C16 C17 5.2(7) . .
Eu1 O9 C39 O10 0.5(5) . .
Eu1 O9 C39 O11 -178.7(5) . .
Eu1 O10 C39 O9 -0.5(5) . .
Eu1 O10 C39 O11 178.7(4) . .
Eu1 O12 C40 Eu2 166.6(8) 2_656 .
Eu1 O12 C40 O13 167.7(5) 2_656 .
Eu1 O12 C40 O14 -11.4(12) 2_656 .
Eu1 O15 C41 Eu1 87.9(9) 2_656 .
Eu1 O15 C41 Eu2 104.7(5) 2_656 2_656
Eu1 O15 C41 Eu2 -19.2(7) 2_656 .
Eu1 O15 C41 O16 124.2(6) 2_656 .
Eu1 O15 C41 O17 -52.3(10) 2_656 .
Eu1 O15 C41 O18 140.6(11) 2_656 .
Eu1 O15 C41 O19 -47(7) 2_656 .
Eu1 O15 C41 O20 -36.0(6) 2_656 .
Eu1 O16 C41 Eu2 -9.3(6) . .
Eu1 O16 C41 Eu2 -125.9(4) . 2_656
Eu1 O16 C41 O15 -149.7(4) . .
Eu1 O16 C41 O17 27.2(7) . .
Eu1 O16 C41 O18 -162.5(7) . .
Eu1 O16 C41 O19 29.3(6) . .
Eu1 O16 C41 O20 -66(2) . .
Eu1 O19 C41 Eu2 111.0(8) . .
Eu1 O19 C41 Eu2 -10.0(10) . 2_656
Eu1 O19 C41 O15 140(7) . .
Eu1 O19 C41 O16 -31.3(6) . .
Eu1 O19 C41 O17 146.1(12) . .
Eu1 O19 C41 O18 -48.3(15) . .
Eu1 O19 C41 O20 129.6(7) . .
Eu1 O20 C41 Eu1 -110.1(5) 2_656 .
Eu1 O20 C41 Eu2 -127.1(6) 2_656 .
Eu1 O20 C41 Eu2 -9.3(6) 2_656 2_656
Eu1 O20 C41 O15 32.7(5) 2_656 .
Eu1 O20 C41 O16 -59(2) 2_656 .
Eu1 O20 C41 O17 -161.4(6) 2_656 .
Eu1 O20 C41 O18 30.1(8) 2_656 .
Eu1 O20 C41 O19 -148.4(6) 2_656 .
Eu2 Zn2 O5 C20 178.2(4) . .
Eu2 Zn2 O6 C36 174.6(4) . .
Eu2 Zn2 O11 C39 -3.2(4) . .
Eu2 Zn2 N3 C26 -9.0(5) . .
Eu2 Zn2 N3 C27 157.6(3) . .
Eu2 Zn2 N4 C28 -172.4(2) . .
Eu2 Zn2 N4 C30 5.1(5) . .
Eu2 O5 C20 C21 -10.7(6) . .
Eu2 O5 C20 C25 167.2(3) . .
Eu2 O6 C36 C31 176.2(3) . .
Eu2 O6 C36 C35 -4.7(6) . .
Eu2 O7 C21 C20 2.5(4) . .
Eu2 O7 C21 C22 -176.9(4) . .
Eu2 O8 C35 C34 -174.0(4) . .
Eu2 O8 C35 C36 2.9(5) . .
Eu2 O10 C39 Eu1 177.8(7) . .
Eu2 O10 C39 O9 177.4(4) . .
Eu2 O10 C39 O11 -3.4(10) . .
Eu2 O12 C40 O13 1.0(5) . .
Eu2 O12 C40 O14 -178.0(5) . .
Eu2 O13 C40 O12 -1.0(6) . .
Eu2 O13 C40 O14 178.0(5) . .
Eu2 O15 C41 Eu1 -16.8(7) 2_656 .
Eu2 O15 C41 Eu2 -123.9(2) 2_656 .
Eu2 O15 C41 O16 19.5(5) 2_656 .
Eu2 O15 C41 O17 -157.0(7) 2_656 .
Eu2 O15 C41 O18 36.0(8) 2_656 .
Eu2 O15 C41 O19 -152(7) 2_656 .
Eu2 O15 C41 O20 -140.7(4) 2_656 .
Eu2 O16 C41 Eu1 125.9(4) 2_656 .
Eu2 O16 C41 Eu2 116.6(3) 2_656 .
Eu2 O16 C41 O15 -23.8(6) 2_656 .
Eu2 O16 C41 O17 153.1(5) 2_656 .
Eu2 O16 C41 O18 -36.6(6) 2_656 .
Eu2 O16 C41 O19 155.2(6) 2_656 .
Eu2 O16 C41 O20 60(2) 2_656 .
Eu2 O17 C41 Eu1 -86.0(5) . .
Eu2 O17 C41 Eu2 -49.5(12) . 2_656
Eu2 O17 C41 O15 72.1(9) . .
Eu2 O17 C41 O16 -104.3(6) . .
Eu2 O17 C41 O18 133(4) . .
Eu2 O17 C41 O19 -107.1(10) . .
Eu2 O17 C41 O20 55.3(6) . .
Eu2 O18 C41 Eu1 38.8(10) 2_656 .
Eu2 O18 C41 Eu2 -65.4(14) 2_656 .
Eu2 O18 C41 O15 -112.4(12) 2_656 .
Eu2 O18 C41 O16 51.1(7) 2_656 .
Eu2 O18 C41 O17 178(3) 2_656 .
Eu2 O18 C41 O19 68.8(16) 2_656 .
Eu2 O18 C41 O20 -109.1(7) 2_656 .
Eu2 O19 C41 Eu1 -111.0(8) . .
Eu2 O19 C41 Eu2 -121.0(3) . 2_656
Eu2 O19 C41 O15 29(7) . .
Eu2 O19 C41 O16 -142.3(5) . .
Eu2 O19 C41 O17 35.1(6) . .
Eu2 O19 C41 O18 -159.3(10) . .
Eu2 O19 C41 O20 18.7(6) . .
Eu2 O20 C41 Eu1 17.0(6) . .
Eu2 O20 C41 Eu2 117.8(3) . 2_656
Eu2 O20 C41 O15 159.8(5) . .
Eu2 O20 C41 O16 68(2) . .
Eu2 O20 C41 O17 -34.3(5) . .
Eu2 O20 C41 O18 157.2(6) . .
Eu2 O20 C41 O19 -21.4(7) . .
Zn1 O1 C1 C2 -179.6(4) . .
Zn1 O1 C1 C6 -0.1(8) . .
Zn1 O2 C17 C12 10.8(10) . .
Zn1 O2 C17 C16 -169.5(5) . .
Zn1 O14 C40 Eu2 -106(13) 2_656 .
Zn1 O14 C40 O12 4.7(8) 2_656 .
Zn1 O14 C40 O13 -174.2(4) 2_656 .
Zn1 N1 C7 C6 3.4(12) . .
Zn1 N1 C8 C9 -51.9(7) . .
Zn1 N1 C8A C9A 32.1(13) . .
Zn1 N2 C9 C8 -22.1(9) . .
Zn1 N2 C9 C10 90.8(8) . .
Zn1 N2 C9A C8A 61.4(8) . .
Zn1 N2 C9A C10A -36.9(15) . .
Zn1 N2 C11 C12 -5.8(15) . .
Zn2 O5 C20 C21 171.7(3) . .
Zn2 O5 C20 C25 -10.3(6) . .
Zn2 O6 C36 C31 3.5(6) . .
Zn2 O6 C36 C35 -177.4(3) . .
Zn2 O11 C39 Eu1 34(11) . .
Zn2 O11 C39 O9 -176.7(4) . .
Zn2 O11 C39 O10 4.2(7) . .
Zn2 N3 C26 C25 -11.0(7) . .
Zn2 N3 C27 C28 4.7(6) . .
Zn2 N3 C27 C29 138.7(5) . .
Zn2 N4 C28 C27 40.0(6) . .
Zn2 N4 C30 C31 2.9(8) . .
O1 Eu1 Zn1 O2 139.6(2) . .
O1 Eu1 Zn1 O14 -109.77(19) . 2_656
O1 Eu1 Zn1 N1 9.1(3) . .
O1 Eu1 Zn1 N2 131.9(3) . .
O1 Eu1 O2 Zn1 -24.36(14) . .
O1 Eu1 O2 C17 168.0(6) . .
O1 Eu1 O3 C2 -1.2(3) . .
O1 Eu1 O3 C18 -175.5(4) . .
O1 Eu1 O4 C16 -23.9(4) . .
O1 Eu1 O4 C19 155.1(4) . .
O1 Eu1 O9 C39 144.6(3) . .
O1 Eu1 O10 Eu2 134.95(14) . .
O1 Eu1 O10 C39 -46.3(3) . .
O1 Eu1 O16 Eu2 96.51(19) . 2_656
O1 Eu1 O16 C41 -140.1(4) . .
O1 Eu1 O19 Eu2 -153.5(2) . .
O1 Eu1 O19 C41 98.0(8) . .
O1 Eu1 C39 O9 -37.2(3) . .
O1 Eu1 C39 O10 143.3(3) . .
O1 Eu1 C39 O11 113(11) . .
O1 Eu1 C41 Eu2 82.13(13) . 2_656
O1 Eu1 C41 Eu2 -144.65(11) . .
O1 Eu1 C41 O15 97.7(7) . .
O1 Eu1 C41 O16 43.4(5) . .
O1 Eu1 C41 O17 -112.6(4) . .
O1 Eu1 C41 O18 60.4(7) . .
O1 Eu1 C41 O19 -89.0(8) . .
O1 Eu1 C41 O20 -157.8(5) . .
O1 Zn1 O2 Eu1 26.91(14) . .
O1 Zn1 O2 C17 -164.6(5) . .
O1 Zn1 N1 C7 -5.2(6) . .
O1 Zn1 N1 C8 -178.6(5) . .
O1 Zn1 N1 C8A 152.2(7) . .
O1 Zn1 N2 C9 -77.4(6) . .
O1 Zn1 N2 C9A -111.0(6) . .
O1 Zn1 N2 C11 89.2(9) . .
O1 C1 C2 O3 1.5(7) . .
O1 C1 C2 C3 179.0(6) . .
O1 C1 C6 C5 179.0(6) . .
O1 C1 C6 C7 -4.1(10) . .
O2 Eu1 Zn1 O1 -139.6(2) . .
O2 Eu1 Zn1 O14 110.6(2) . 2_656
O2 Eu1 Zn1 N1 -130.5(3) . .
O2 Eu1 Zn1 N2 -7.7(3) . .
O2 Eu1 O1 Zn1 24.36(13) . .
O2 Eu1 O1 C1 -152.7(5) . .
O2 Eu1 O3 C2 25.4(4) . .
O2 Eu1 O3 C18 -148.9(4) . .
O2 Eu1 O4 C16 -5.1(4) . .
O2 Eu1 O4 C19 173.9(5) . .
O2 Eu1 O9 C39 -148.8(3) . .
O2 Eu1 O10 Eu2 -137.56(14) . .
O2 Eu1 O10 C39 41.2(3) . .
O2 Eu1 O16 Eu2 33.5(3) . 2_656
O2 Eu1 O16 C41 156.9(4) . .
O2 Eu1 O19 Eu2 134.9(9) . .
O2 Eu1 O19 C41 26.3(17) . .
O2 Eu1 C39 O9 32.3(3) . .
O2 Eu1 C39 O10 -147.2(3) . .
O2 Eu1 C39 O11 -178(100) . .
O2 Eu1 C41 Eu2 2.3(3) . 2_656
O2 Eu1 C41 Eu2 135.5(2) . .
O2 Eu1 C41 O15 17.9(8) . .
O2 Eu1 C41 O16 -36.4(5) . .
O2 Eu1 C41 O17 167.6(4) . .
O2 Eu1 C41 O18 -19.5(7) . .
O2 Eu1 C41 O19 -168.8(8) . .
O2 Eu1 C41 O20 122.4(5) . .
O2 Zn1 O1 Eu1 -27.43(14) . .
O2 Zn1 O1 C1 149.8(4) . .
O2 Zn1 N1 C7 -80.6(7) . .
O2 Zn1 N1 C8 106.1(5) . .
O2 Zn1 N1 C8A 76.8(8) . .
O2 Zn1 N2 C9 -152.3(5) . .
O2 Zn1 N2 C9A 174.1(6) . .
O2 Zn1 N2 C11 14.2(8) . .
O3 Eu1 Zn1 O1 -0.49(16) . .
O3 Eu1 Zn1 O2 139.11(18) . .
O3 Eu1 Zn1 O14 -110.27(15) . 2_656
O3 Eu1 Zn1 N1 8.6(2) . .
O3 Eu1 Zn1 N2 131.4(3) . .
O3 Eu1 O1 Zn1 179.43(19) . .
O3 Eu1 O1 C1 2.4(4) . .
O3 Eu1 O2 Zn1 -49.12(19) . .
O3 Eu1 O2 C17 143.3(5) . .
O3 Eu1 O4 C16 -104.3(4) . .
O3 Eu1 O4 C19 74.7(4) . .
O3 Eu1 O9 C39 85.8(3) . .
O3 Eu1 O10 Eu2 104.63(15) . .
O3 Eu1 O10 C39 -76.6(3) . .
O3 Eu1 O16 Eu2 153.1(2) . 2_656
O3 Eu1 O16 C41 -83.5(4) . .
O3 Eu1 O19 Eu2 -117.2(4) . .
O3 Eu1 O19 C41 134.3(9) . .
O3 Eu1 C39 O9 -85.1(3) . .
O3 Eu1 C39 O10 95.4(3) . .
O3 Eu1 C39 O11 65(11) . .
O3 Eu1 C41 Eu2 -96.75(11) . .
O3 Eu1 C41 Eu2 130.03(11) . 2_656
O3 Eu1 C41 O15 145.6(7) . .
O3 Eu1 C41 O16 91.3(4) . .
O3 Eu1 C41 O17 -64.7(4) . .
O3 Eu1 C41 O18 108.3(7) . .
O3 Eu1 C41 O19 -41.1(8) . .
O3 Eu1 C41 O20 -109.9(6) . .
O3 C2 C3 C4 178.5(6) . .
O4 Eu1 Zn1 O1 -145.60(17) . .
O4 Eu1 Zn1 O2 -6.00(18) . .
O4 Eu1 Zn1 O14 104.62(15) . 2_656
O4 Eu1 Zn1 N1 -136.5(2) . .
O4 Eu1 Zn1 N2 -13.7(3) . .
O4 Eu1 O1 Zn1 41.8(2) . .
O4 Eu1 O1 C1 -135.2(4) . .
O4 Eu1 O2 Zn1 173.0(2) . .
O4 Eu1 O2 C17 5.4(5) . .
O4 Eu1 O3 C2 102.2(4) . .
O4 Eu1 O3 C18 -72.0(4) . .
O4 Eu1 O9 C39 -89.7(3) . .
O4 Eu1 O10 Eu2 -102.02(16) . .
O4 Eu1 O10 C39 76.8(3) . .
O4 Eu1 O16 Eu2 -48.9(3) . 2_656
O4 Eu1 O16 C41 74.6(5) . .
O4 Eu1 O19 Eu2 21.7(5) . .
O4 Eu1 O19 C41 -86.8(9) . .
O4 Eu1 C39 O9 82.5(3) . .
O4 Eu1 C39 O10 -97.0(3) . .
O4 Eu1 C39 O11 -128(11) . .
O4 Eu1 C41 Eu2 50.41(15) . .
O4 Eu1 C41 Eu2 -82.81(13) . 2_656
O4 Eu1 C41 O15 -67.2(7) . .
O4 Eu1 C41 O16 -121.5(4) . .
O4 Eu1 C41 O17 82.5(4) . .
O4 Eu1 C41 O18 -104.5(7) . .
O4 Eu1 C41 O19 106.1(8) . .
O4 Eu1 C41 O20 37.3(6) . .
O4 C16 C17 O2 -1.2(9) . .
O4 C16 C17 C12 178.6(6) . .
O5 Eu2 Zn2 O6 141.45(16) . .
O5 Eu2 Zn2 O11 -108.79(16) . .
O5 Eu2 Zn2 N3 15.2(2) . .
O5 Eu2 Zn2 N4 139.59(19) . .
O5 Eu2 O6 Zn2 -23.20(10) . .
O5 Eu2 O6 C36 162.7(4) . .
O5 Eu2 O7 C21 -4.9(3) . .
O5 Eu2 O7 C37 -178.2(4) . .
O5 Eu2 O8 C35 -26.7(3) . .
O5 Eu2 O8 C38 151.4(3) . .
O5 Eu2 O10 Eu1 -146.91(18) . .
O5 Eu2 O10 C39 35.5(6) . .
O5 Eu2 O12 Eu1 141.28(15) . 2_656
O5 Eu2 O12 C40 -46.1(4) . .
O5 Eu2 O13 C40 143.9(4) . .
O5 Eu2 O17 C41 175.5(5) . .
O5 Eu2 O19 Eu1 95.6(3) . .
O5 Eu2 O19 C41 -138.3(5) . .
O5 Eu2 O20 Eu1 -147.89(19) . 2_656
O5 Eu2 O20 C41 81.8(5) . .
O5 Eu2 C40 O12 142.0(3) . .
O5 Eu2 C40 O13 -36.9(4) . .
O5 Eu2 C40 O14 -106(13) . .
O5 Eu2 C41 Eu1 83.35(10) . .
O5 Eu2 C41 Eu2 150.81(15) . 2_656
O5 Eu2 C41 O15 -130.7(5) . .
O5 Eu2 C41 O16 89.8(4) . .
O5 Eu2 C41 O17 -4.9(6) . .
O5 Eu2 C41 O18 -166.2(11) . .
O5 Eu2 C41 O19 46.1(6) . .
O5 Eu2 C41 O20 -110.2(5) . .
O5 Zn2 O6 Eu2 25.86(11) . .
O5 Zn2 O6 C36 -159.6(3) . .
O5 Zn2 O11 C39 -46.4(4) . .
O5 Zn2 N3 C26 1.4(4) . .
O5 Zn2 N3 C27 168.1(4) . .
O5 Zn2 N4 C28 -101.9(4) . .
O5 Zn2 N4 C30 75.5(6) . .
O5 C20 C21 O7 3.8(6) . .
O5 C20 C21 C22 -176.8(4) . .
O5 C20 C25 C24 -179.7(4) . .
O5 C20 C25 C26 -0.5(7) . .
O6 Eu2 Zn2 O5 -141.45(16) . .
O6 Eu2 Zn2 O11 109.76(15) . .
O6 Eu2 Zn2 N3 -126.3(2) . .
O6 Eu2 Zn2 N4 -1.86(18) . .
O6 Eu2 O5 Zn2 23.35(10) . .
O6 Eu2 O5 C20 -154.6(4) . .
O6 Eu2 O7 C21 13.6(3) . .
O6 Eu2 O7 C37 -159.7(3) . .
O6 Eu2 O8 C35 -3.4(3) . .
O6 Eu2 O8 C38 174.7(4) . .
O6 Eu2 O10 Eu1 143.03(18) . .
O6 Eu2 O10 C39 -34.6(6) . .
O6 Eu2 O12 Eu1 -133.24(16) . 2_656
O6 Eu2 O12 C40 39.4(4) . .
O6 Eu2 O13 C40 -148.8(4) . .
O6 Eu2 O17 C41 114.5(6) . .
O6 Eu2 O19 Eu1 28.9(5) . .
O6 Eu2 O19 C41 155.0(4) . .
O6 Eu2 O20 Eu1 78.3(10) . 2_656
O6 Eu2 O20 C41 -52.0(13) . .
O6 Eu2 C40 O12 -148.8(3) . .
O6 Eu2 C40 O13 32.3(4) . .
O6 Eu2 C40 O14 -37(13) . .
O6 Eu2 C41 Eu1 -1.6(3) . .
O6 Eu2 C41 Eu2 65.8(3) . 2_656
O6 Eu2 C41 O15 144.4(4) . .
O6 Eu2 C41 O16 4.8(6) . .
O6 Eu2 C41 O17 -89.8(6) . .
O6 Eu2 C41 O18 108.8(11) . .
O6 Eu2 C41 O19 -38.8(6) . .
O6 Eu2 C41 O20 164.8(5) . .
O6 Zn2 O5 Eu2 -25.97(12) . .
O6 Zn2 O5 C20 152.2(3) . .
O6 Zn2 O11 C39 40.1(4) . .
O6 Zn2 N3 C26 -76.3(5) . .
O6 Zn2 N3 C27 90.4(4) . .
O6 Zn2 N4 C28 -173.7(3) . .
O6 Zn2 N4 C30 3.8(4) . .
O7 Eu2 Zn2 O5 5.52(14) . .
O7 Eu2 Zn2 O6 146.97(13) . .
O7 Eu2 Zn2 O11 -103.27(13) . .
O7 Eu2 Zn2 N3 20.72(17) . .
O7 Eu2 Zn2 N4 145.11(16) . .
O7 Eu2 O5 Zn2 -173.53(16) . .
O7 Eu2 O5 C20 8.5(3) . .
O7 Eu2 O6 Zn2 -40.30(14) . .
O7 Eu2 O6 C36 145.6(3) . .
O7 Eu2 O8 C35 -105.7(3) . .
O7 Eu2 O8 C38 72.4(4) . .
O7 Eu2 O10 Eu1 -96.51(16) . .
O7 Eu2 O10 C39 85.9(7) . .
O7 Eu2 O12 Eu1 105.60(19) . 2_656
O7 Eu2 O12 C40 -81.8(3) . .
O7 Eu2 O13 C40 84.7(3) . .
O7 Eu2 O17 C41 -137.6(6) . .
O7 Eu2 O19 Eu1 149.3(3) . .
O7 Eu2 O19 C41 -84.6(5) . .
O7 Eu2 O20 Eu1 -125.1(3) . 2_656
O7 Eu2 O20 C41 104.6(5) . .
O7 Eu2 C40 O12 90.9(3) . .
O7 Eu2 C40 O13 -88.0(3) . .
O7 Eu2 C40 O14 -157(13) . .
O7 Eu2 C41 Eu1 126.48(11) . .
O7 Eu2 C41 Eu2 -166.07(19) . 2_656
O7 Eu2 C41 O15 -87.5(5) . .
O7 Eu2 C41 O16 132.9(5) . .
O7 Eu2 C41 O17 38.3(6) . .
O7 Eu2 C41 O18 -123.1(11) . .
O7 Eu2 C41 O19 89.3(6) . .
O7 Eu2 C41 O20 -67.1(5) . .
O7 C21 C22 C23 174.3(4) . .
O8 Eu2 Zn2 O5 -142.78(14) . .
O8 Eu2 Zn2 O6 -1.33(13) . .
O8 Eu2 Zn2 O11 108.43(12) . .
O8 Eu2 Zn2 N3 -127.58(17) . .
O8 Eu2 Zn2 N4 -3.19(16) . .
O8 Eu2 O5 Zn2 44.84(14) . .
O8 Eu2 O5 C20 -133.2(4) . .
O8 Eu2 O6 Zn2 178.44(15) . .
O8 Eu2 O6 C36 4.4(3) . .
O8 Eu2 O7 C21 94.6(3) . .
O8 Eu2 O7 C37 -78.7(4) . .
O8 Eu2 O10 Eu1 94.75(16) . .
O8 Eu2 O10 C39 -82.9(7) . .
O8 Eu2 O12 Eu1 -97.46(18) . 2_656
O8 Eu2 O12 C40 75.1(3) . .
O8 Eu2 O13 C40 -90.1(3) . .
O8 Eu2 O17 C41 9.5(7) . .
O8 Eu2 O19 Eu1 -52.2(4) . .
O8 Eu2 O19 C41 73.9(6) . .
O8 Eu2 O20 Eu1 18.8(3) . 2_656
O8 Eu2 O20 C41 -111.5(4) . .
O8 Eu2 C40 O12 -98.9(3) . .
O8 Eu2 C40 O13 82.2(3) . .
O8 Eu2 C40 O14 13(13) . .
O8 Eu2 C41 Eu1 -84.28(11) . .
O8 Eu2 C41 Eu2 -16.8(2) . 2_656
O8 Eu2 C41 O15 61.7(5) . .
O8 Eu2 C41 O16 -77.9(5) . .
O8 Eu2 C41 O17 -172.5(6) . .
O8 Eu2 C41 O18 26.2(11) . .
O8 Eu2 C41 O19 -121.5(6) . .
O8 Eu2 C41 O20 82.1(5) . .
O8 C35 C36 O6 0.4(6) . .
O8 C35 C36 C31 179.6(4) . .
O9 Eu1 Zn1 O1 -72.25(17) . .
O9 Eu1 Zn1 O2 67.35(18) . .
O9 Eu1 Zn1 O14 177.97(15) . 2_656
O9 Eu1 Zn1 N1 -63.1(2) . .
O9 Eu1 Zn1 N2 59.6(3) . .
O9 Eu1 O1 Zn1 108.53(14) . .
O9 Eu1 O1 C1 -68.5(4) . .
O9 Eu1 O2 Zn1 -112.62(16) . .
O9 Eu1 O2 C17 79.8(5) . .
O9 Eu1 O3 C2 95.0(3) . .
O9 Eu1 O3 C18 -79.3(4) . .
O9 Eu1 O4 C16 -97.1(4) . .
O9 Eu1 O4 C19 81.9(4) . .
O9 Eu1 O10 Eu2 -178.5(2) . .
O9 Eu1 O10 C39 0.3(3) . .
O9 Eu1 O16 Eu2 -173.68(13) . 2_656
O9 Eu1 O16 C41 -50.3(5) . .
O9 Eu1 O19 Eu2 -61.2(3) . .
O9 Eu1 O19 C41 -169.7(7) . .
O9 Eu1 C39 O10 -179.5(5) . .
O9 Eu1 C39 O11 150(11) . .
O9 Eu1 C41 Eu2 -176.76(11) . 2_656
O9 Eu1 C41 Eu2 -43.54(17) . .
O9 Eu1 C41 O15 -161.2(7) . .
O9 Eu1 C41 O16 144.5(4) . .
O9 Eu1 C41 O17 -11.5(5) . .
O9 Eu1 C41 O18 161.5(6) . .
O9 Eu1 C41 O19 12.2(9) . .
O9 Eu1 C41 O20 -56.7(6) . .
O10 Eu1 Zn1 O1 -70.1(2) . .
O10 Eu1 Zn1 O2 69.5(2) . .
O10 Eu1 Zn1 O14 -179.9(2) . 2_656
O10 Eu1 Zn1 N1 -61.0(3) . .
O10 Eu1 Zn1 N2 61.8(3) . .
O10 Eu1 O1 Zn1 144.56(13) . .
O10 Eu1 O1 C1 -32.5(5) . .
O10 Eu1 O2 Zn1 -144.84(13) . .
O10 Eu1 O2 C17 47.6(6) . .
O10 Eu1 O3 C2 151.1(3) . .
O10 Eu1 O3 C18 -23.2(4) . .
O10 Eu1 O4 C16 -152.3(4) . .
O10 Eu1 O4 C19 26.7(4) . .
O10 Eu1 O9 C39 -0.3(3) . .
O10 Eu1 O16 Eu2 -133.66(18) . 2_656
O10 Eu1 O16 C41 -10.2(5) . .
O10 Eu1 O19 Eu2 -30.3(2) . .
O10 Eu1 O19 C41 -138.8(9) . .
O10 Eu1 C39 O9 179.5(5) . .
O10 Eu1 C39 O11 -31(11) . .
O10 Eu1 C41 Eu2 -151.59(12) . 2_656
O10 Eu1 C41 Eu2 -18.37(10) . .
O10 Eu1 C41 O15 -136.0(7) . .
O10 Eu1 C41 O16 169.7(5) . .
O10 Eu1 C41 O17 13.7(4) . .
O10 Eu1 C41 O18 -173.3(7) . .
O10 Eu1 C41 O19 37.3(8) . .
O10 Eu1 C41 O20 -31.5(5) . .
O10 Eu2 Zn2 O5 109.92(16) . .
O10 Eu2 Zn2 O6 -108.63(15) . .
O10 Eu2 Zn2 O11 1.13(15) . .
O10 Eu2 Zn2 N3 125.12(19) . .
O10 Eu2 Zn2 N4 -110.49(18) . .
O10 Eu2 O5 Zn2 -54.89(12) . .
O10 Eu2 O5 C20 127.1(4) . .
O10 Eu2 O6 Zn2 55.75(11) . .
O10 Eu2 O6 C36 -118.3(4) . .
O10 Eu2 O7 C21 -65.0(3) . .
O10 Eu2 O7 C37 121.6(4) . .
O10 Eu2 O8 C35 53.7(3) . .
O10 Eu2 O8 C38 -128.2(4) . .
O10 Eu2 O12 Eu1 11.6(4) . 2_656
O10 Eu2 O12 C40 -175.8(3) . .
O10 Eu2 O13 C40 176.4(3) . .
O10 Eu2 O17 C41 105.8(6) . .
O10 Eu2 O19 Eu1 31.4(2) . .
O10 Eu2 O19 C41 157.5(6) . .
O10 Eu2 O20 Eu1 134.5(2) . 2_656
O10 Eu2 O20 C41 4.2(5) . .
O10 Eu2 C40 O12 144(3) . .
O10 Eu2 C40 O13 -35(3) . .
O10 Eu2 C40 O14 -104(13) . .
O10 Eu2 C41 Eu1 17.84(10) . .
O10 Eu2 C41 Eu2 85.29(17) . 2_656
O10 Eu2 C41 O15 163.8(5) . .
O10 Eu2 C41 O16 24.2(4) . .
O10 Eu2 C41 O17 -70.4(6) . .
O10 Eu2 C41 O18 128.3(11) . .
O10 Eu2 C41 O19 -19.4(6) . .
O10 Eu2 C41 O20 -175.8(5) . .
O11 Zn2 O5 Eu2 79.59(14) . .
O11 Zn2 O5 C20 -102.2(3) . .
O11 Zn2 O6 Eu2 -78.92(14) . .
O11 Zn2 O6 C36 95.7(3) . .
O11 Zn2 N3 C26 109.3(4) . .
O11 Zn2 N3 C27 -84.0(4) . .
O11 Zn2 N4 C28 78.9(3) . .
O11 Zn2 N4 C30 -103.6(4) . .
O12 Eu1 Zn1 O1 111.43(19) 2_656 .
O12 Eu1 Zn1 O2 -109.0(2) 2_656 .
O12 Eu1 Zn1 O14 1.66(17) 2_656 2_656
O12 Eu1 Zn1 N1 120.5(2) 2_656 .
O12 Eu1 Zn1 N2 -116.7(3) 2_656 .
O12 Eu1 O1 Zn1 -53.24(14) 2_656 .
O12 Eu1 O1 C1 129.8(5) 2_656 .
O12 Eu1 O2 Zn1 54.98(15) 2_656 .
O12 Eu1 O2 C17 -112.6(6) 2_656 .
O12 Eu1 O3 C2 -55.8(3) 2_656 .
O12 Eu1 O3 C18 129.9(4) 2_656 .
O12 Eu1 O4 C16 54.6(4) 2_656 .
O12 Eu1 O4 C19 -126.4(4) 2_656 .
O12 Eu1 O9 C39 -175.0(3) 2_656 .
O12 Eu1 O10 Eu2 -4.0(4) 2_656 .
O12 Eu1 O10 C39 174.8(3) 2_656 .
O12 Eu1 O16 Eu2 29.33(16) 2_656 2_656
O12 Eu1 O16 C41 152.8(5) 2_656 .
O12 Eu1 O19 Eu2 132.1(3) 2_656 .
O12 Eu1 O19 C41 23.6(8) 2_656 .
O12 Eu1 C39 O9 68(3) 2_656 .
O12 Eu1 C39 O10 -112(3) 2_656 .
O12 Eu1 C39 O11 -142(9) 2_656 .
O12 Eu1 C41 Eu2 148.31(13) 2_656 .
O12 Eu1 C41 Eu2 15.08(11) 2_656 2_656
O12 Eu1 C41 O15 30.7(7) 2_656 .
O12 Eu1 C41 O16 -23.6(4) 2_656 .
O12 Eu1 C41 O17 -179.6(4) 2_656 .
O12 Eu1 C41 O18 -6.7(7) 2_656 .
O12 Eu1 C41 O19 -156.0(8) 2_656 .
O12 Eu1 C41 O20 135.2(6) 2_656 .
O12 Eu2 Zn2 O5 -64.5(2) . .
O12 Eu2 Zn2 O6 77.0(2) . .
O12 Eu2 Zn2 O11 -173.3(2) . .
O12 Eu2 Zn2 N3 -49.3(3) . .
O12 Eu2 Zn2 N4 75.1(3) . .
O12 Eu2 O5 Zn2 144.74(13) . .
O12 Eu2 O5 C20 -33.3(4) . .
O12 Eu2 O6 Zn2 -138.85(13) . .
O12 Eu2 O6 C36 47.1(4) . .
O12 Eu2 O7 C21 140.5(3) . .
O12 Eu2 O7 C37 -32.9(4) . .
O12 Eu2 O8 C35 -150.7(3) . .
O12 Eu2 O8 C38 27.4(4) . .
O12 Eu2 O10 Eu1 -8.7(4) . .
O12 Eu2 O10 C39 173.7(6) . .
O12 Eu2 O13 C40 0.6(3) . .
O12 Eu2 O17 C41 -60.9(6) . .
O12 Eu2 O19 Eu1 -137.8(3) . .
O12 Eu2 O19 C41 -11.7(6) . .
O12 Eu2 O20 Eu1 -35.54(18) . 2_656
O12 Eu2 O20 C41 -165.8(6) . .
O12 Eu2 C40 O13 -178.9(6) . .
O12 Eu2 C40 O14 112(13) . .
O12 Eu2 C41 Eu1 -154.56(13) . .
O12 Eu2 C41 Eu2 -87.10(18) . 2_656
O12 Eu2 C41 O15 -8.6(5) . .
O12 Eu2 C41 O16 -148.2(5) . .
O12 Eu2 C41 O17 117.2(6) . .
O12 Eu2 C41 O18 -44.1(11) . .
O12 Eu2 C41 O19 168.2(6) . .
O12 Eu2 C41 O20 11.8(5) . .
O13 Eu2 Zn2 O5 -69.63(15) . .
O13 Eu2 Zn2 O6 71.83(14) . .
O13 Eu2 Zn2 O11 -178.41(14) . .
O13 Eu2 Zn2 N3 -54.43(19) . .
O13 Eu2 Zn2 N4 69.97(18) . .
O13 Eu2 O5 Zn2 109.50(14) . .
O13 Eu2 O5 C20 -68.5(4) . .
O13 Eu2 O6 Zn2 -107.63(13) . .
O13 Eu2 O6 C36 78.3(3) . .
O13 Eu2 O7 C21 85.3(3) . .
O13 Eu2 O7 C37 -88.0(4) . .
O13 Eu2 O8 C35 -96.3(3) . .
O13 Eu2 O8 C38 81.8(4) . .
O13 Eu2 O10 Eu1 179.34(19) . .
O13 Eu2 O10 C39 1.7(8) . .
O13 Eu2 O12 Eu1 -173.2(3) . 2_656
O13 Eu2 O12 C40 -0.6(3) . .
O13 Eu2 O17 C41 -97.5(6) . .
O13 Eu2 O19 Eu1 -175.47(15) . .
O13 Eu2 O19 C41 -49.4(8) . .
O13 Eu2 O20 Eu1 -58.8(3) . 2_656
O13 Eu2 O20 C41 170.9(4) . .
O13 Eu2 C40 O12 178.9(6) . .
O13 Eu2 C40 O14 -69(13) . .
O13 Eu2 C41 Eu1 -177.51(11) . .
O13 Eu2 C41 Eu2 -110.06(17) . 2_656
O13 Eu2 C41 O15 -31.5(5) . .
O13 Eu2 C41 O16 -171.1(4) . .
O13 Eu2 C41 O17 94.3(6) . .
O13 Eu2 C41 O18 -67.1(11) . .
O13 Eu2 C41 O19 145.3(6) . .
O13 Eu2 C41 O20 -11.1(5) . .
O14 Zn1 O1 Eu1 79.90(17) 2_656 .
O14 Zn1 O1 C1 -102.9(4) 2_656 .
O14 Zn1 O2 Eu1 -79.59(17) 2_656 .
O14 Zn1 O2 C17 88.9(5) 2_656 .
O14 Zn1 N1 C7 103.7(6) 2_656 .
O14 Zn1 N1 C8 -69.7(5) 2_656 .
O14 Zn1 N1 C8A -98.9(7) 2_656 .
O14 Zn1 N2 C9 98.0(5) 2_656 .
O14 Zn1 N2 C9A 64.4(6) 2_656 .
O14 Zn1 N2 C11 -95.4(8) 2_656 .
O15 Eu1 Zn1 O1 160.9(3) 2_656 .
O15 Eu1 Zn1 O2 -59.5(3) 2_656 .
O15 Eu1 Zn1 O14 51.1(2) 2_656 2_656
O15 Eu1 Zn1 N1 170.0(3) 2_656 .
O15 Eu1 Zn1 N2 -67.2(3) 2_656 .
O15 Eu1 O1 Zn1 -58.4(6) 2_656 .
O15 Eu1 O1 C1 124.6(7) 2_656 .
O15 Eu1 O2 Zn1 138.7(2) 2_656 .
O15 Eu1 O2 C17 -28.9(6) 2_656 .
O15 Eu1 O3 C2 -163.9(4) 2_656 .
O15 Eu1 O3 C18 21.8(5) 2_656 .
O15 Eu1 O4 C16 138.2(5) 2_656 .
O15 Eu1 O4 C19 -42.8(5) 2_656 .
O15 Eu1 O9 C39 -39.2(4) 2_656 .
O15 Eu1 O10 Eu2 -38.35(18) 2_656 .
O15 Eu1 O10 C39 140.4(3) 2_656 .
O15 Eu1 O16 Eu2 -70.8(3) 2_656 2_656
O15 Eu1 O16 C41 52.6(5) 2_656 .
O15 Eu1 O19 Eu2 43.5(3) 2_656 .
O15 Eu1 O19 C41 -65.0(8) 2_656 .
O15 Eu1 C39 O9 143.5(3) 2_656 .
O15 Eu1 C39 O10 -35.9(3) 2_656 .
O15 Eu1 C39 O11 -66(11) 2_656 .
O15 Eu1 C41 Eu2 51.7(2) 2_656 .
O15 Eu1 C41 Eu2 -81.5(2) 2_656 2_656
O15 Eu1 C41 O15 -65.9(8) 2_656 .
O15 Eu1 C41 O16 -120.2(5) 2_656 .
O15 Eu1 C41 O17 83.8(5) 2_656 .
O15 Eu1 C41 O18 -103.3(7) 2_656 .
O15 Eu1 C41 O19 107.4(9) 2_656 .
O15 Eu1 C41 O20 38.6(6) 2_656 .
O16 Eu1 Zn1 O1 77.7(2) . .
O16 Eu1 Zn1 O2 -142.7(2) . .
O16 Eu1 Zn1 O14 -32.1(2) . 2_656
O16 Eu1 Zn1 N1 86.8(3) . .
O16 Eu1 Zn1 N2 -150.4(3) . .
O16 Eu1 O1 Zn1 -108.78(19) . .
O16 Eu1 O1 C1 74.2(5) . .
O16 Eu1 O2 Zn1 51.2(3) . .
O16 Eu1 O2 C17 -116.3(6) . .
O16 Eu1 O3 C2 -105.5(4) . .
O16 Eu1 O3 C18 80.2(4) . .
O16 Eu1 O4 C16 114.1(4) . .
O16 Eu1 O4 C19 -66.9(5) . .
O16 Eu1 O9 C39 51.4(4) . .
O16 Eu1 O10 Eu2 30.3(2) . .
O16 Eu1 O10 C39 -150.9(3) . .
O16 Eu1 O19 Eu2 136.0(5) . .
O16 Eu1 O19 C41 27.4(6) . .
O16 Eu1 C39 O9 -145.7(3) . .
O16 Eu1 C39 O10 34.8(4) . .
O16 Eu1 C39 O11 4(11) . .
O16 Eu1 C41 Eu2 38.7(4) . 2_656
O16 Eu1 C41 Eu2 171.9(5) . .
O16 Eu1 C41 O15 54.3(8) . .
O16 Eu1 C41 O17 -156.0(7) . .
O16 Eu1 C41 O18 17.0(7) . .
O16 Eu1 C41 O19 -132.4(10) . .
O16 Eu1 C41 O20 158.8(8) . .
O16 Eu2 Zn2 O5 167.8(2) 2_656 .
O16 Eu2 Zn2 O6 -50.8(2) 2_656 .
O16 Eu2 Zn2 O11 59.0(2) 2_656 .
O16 Eu2 Zn2 N3 -177.0(3) 2_656 .
O16 Eu2 Zn2 N4 -52.7(3) 2_656 .
O16 Eu2 O5 Zn2 -108.4(10) 2_656 .
O16 Eu2 O5 C20 73.6(11) 2_656 .
O16 Eu2 O6 Zn2 150.77(13) 2_656 .
O16 Eu2 O6 C36 -23.3(4) 2_656 .
O16 Eu2 O7 C21 -177.5(3) 2_656 .
O16 Eu2 O7 C37 9.1(4) 2_656 .
O16 Eu2 O8 C35 149.7(3) 2_656 .
O16 Eu2 O8 C38 -32.2(4) 2_656 .
O16 Eu2 O10 Eu1 27.2(2) 2_656 .
O16 Eu2 O10 C39 -150.4(6) 2_656 .
O16 Eu2 O12 Eu1 -30.68(18) 2_656 2_656
O16 Eu2 O12 C40 141.9(4) 2_656 .
O16 Eu2 O13 C40 -31.6(4) 2_656 .
O16 Eu2 O17 C41 -2.4(5) 2_656 .
O16 Eu2 O19 Eu1 -84.5(3) 2_656 .
O16 Eu2 O19 C41 41.6(5) 2_656 .
O16 Eu2 O20 Eu1 37.8(2) 2_656 2_656
O16 Eu2 O20 C41 -92.5(5) 2_656 .
O16 Eu2 C40 O12 -32.2(3) 2_656 .
O16 Eu2 C40 O13 148.9(4) 2_656 .
O16 Eu2 C40 O14 80(13) 2_656 .
O16 Eu2 C41 Eu1 -94.53(14) 2_656 .
O16 Eu2 C41 Eu2 -27.08(17) 2_656 2_656
O16 Eu2 C41 O15 51.5(5) 2_656 .
O16 Eu2 C41 O16 -88.1(4) 2_656 .
O16 Eu2 C41 O17 177.3(6) 2_656 .
O16 Eu2 C41 O18 15.9(11) 2_656 .
O16 Eu2 C41 O19 -131.7(6) 2_656 .
O16 Eu2 C41 O20 71.9(5) 2_656 .
O17 Eu2 Zn2 O5 65.9(2) . .
O17 Eu2 Zn2 O6 -152.7(2) . .
O17 Eu2 Zn2 O11 -42.92(19) . .
O17 Eu2 Zn2 N3 81.1(2) . .
O17 Eu2 Zn2 N4 -154.5(2) . .
O17 Eu2 O5 Zn2 -124.41(16) . .
O17 Eu2 O5 C20 57.6(4) . .
O17 Eu2 O6 Zn2 47.1(4) . .
O17 Eu2 O6 C36 -127.0(4) . .
O17 Eu2 O7 C21 -127.1(3) . .
O17 Eu2 O7 C37 59.6(4) . .
O17 Eu2 O8 C35 137.1(3) . .
O17 Eu2 O8 C38 -44.9(4) . .
O17 Eu2 O10 Eu1 -42.0(2) . .
O17 Eu2 O10 C39 140.3(7) . .
O17 Eu2 O12 Eu1 43.4(2) . 2_656
O17 Eu2 O12 C40 -144.0(4) . .
O17 Eu2 O13 C40 48.6(4) . .
O17 Eu2 O19 Eu1 -172.9(12) . .
O17 Eu2 O19 C41 -46.9(8) . .
O17 Eu2 O20 Eu1 160.0(6) . 2_656
O17 Eu2 O20 C41 29.7(4) . .
O17 Eu2 C40 O12 38.0(4) . .
O17 Eu2 C40 O13 -140.9(4) . .
O17 Eu2 C40 O14 150(13) . .
O17 Eu2 C41 Eu1 88.2(6) . .
O17 Eu2 C41 Eu2 155.7(6) . 2_656
O17 Eu2 C41 O15 -125.8(8) . .
O17 Eu2 C41 O16 94.6(7) . .
O17 Eu2 C41 O18 -161.3(13) . .
O17 Eu2 C41 O19 51.0(7) . .
O17 Eu2 C41 O20 -105.4(7) . .
O18 Eu2 Zn2 O5 155.7(3) 2_656 .
O18 Eu2 Zn2 O6 -62.8(3) 2_656 .
O18 Eu2 Zn2 O11 46.9(3) 2_656 .
O18 Eu2 Zn2 N3 170.9(3) 2_656 .
O18 Eu2 Zn2 N4 -64.7(3) 2_656 .
O18 Eu2 O5 Zn2 -40.8(5) 2_656 .
O18 Eu2 O5 C20 141.2(5) 2_656 .
O18 Eu2 O6 Zn2 125.7(3) 2_656 .
O18 Eu2 O6 C36 -48.4(4) 2_656 .
O18 Eu2 O7 C21 -144.6(4) 2_656 .
O18 Eu2 O7 C37 42.1(5) 2_656 .
O18 Eu2 O8 C35 113.3(4) 2_656 .
O18 Eu2 O8 C38 -68.6(4) 2_656 .
O18 Eu2 O10 Eu1 41.5(3) 2_656 .
O18 Eu2 O10 C39 -136.2(7) 2_656 .
O18 Eu2 O12 Eu1 -35.5(3) 2_656 2_656
O18 Eu2 O12 C40 137.1(4) 2_656 .
O18 Eu2 O13 C40 -56.8(5) 2_656 .
O18 Eu2 O17 C41 30.9(6) 2_656 .
O18 Eu2 O19 Eu1 -50.3(3) 2_656 .
O18 Eu2 O19 C41 75.8(6) 2_656 .
O18 Eu2 O20 Eu1 66.4(3) 2_656 2_656
O18 Eu2 O20 C41 -63.9(5) 2_656 .
O18 Eu2 C40 O12 -46.6(4) 2_656 .
O18 Eu2 C40 O13 134.5(4) 2_656 .
O18 Eu2 C40 O14 65(13) 2_656 .
O18 Eu2 C41 Eu1 -58.3(3) 2_656 .
O18 Eu2 C41 Eu2 9.2(3) 2_656 2_656
O18 Eu2 C41 O15 87.7(6) 2_656 .
O18 Eu2 C41 O16 -51.9(5) 2_656 .
O18 Eu2 C41 O17 -146.5(6) 2_656 .
O18 Eu2 C41 O18 52.2(12) 2_656 .
O18 Eu2 C41 O19 -95.5(6) 2_656 .
O18 Eu2 C41 O20 108.1(6) 2_656 .
O19 Eu1 Zn1 O1 54.6(4) . .
O19 Eu1 Zn1 O2 -165.8(4) . .
O19 Eu1 Zn1 O14 -55.2(3) . 2_656
O19 Eu1 Zn1 N1 63.7(4) . .
O19 Eu1 Zn1 N2 -173.6(4) . .
O19 Eu1 O1 Zn1 -142.7(3) . .
O19 Eu1 O1 C1 40.3(5) . .
O19 Eu1 O2 Zn1 52.1(11) . .
O19 Eu1 O2 C17 -115.5(11) . .
O19 Eu1 O3 C2 -140.8(5) . .
O19 Eu1 O3 C18 44.9(5) . .
O19 Eu1 O4 C16 161.4(5) . .
O19 Eu1 O4 C19 -19.6(6) . .
O19 Eu1 O9 C39 34.7(4) . .
O19 Eu1 O10 Eu2 38.4(3) . .
O19 Eu1 O10 C39 -142.8(4) . .
O19 Eu1 O16 Eu2 -146.2(5) . 2_656
O19 Eu1 O16 C41 -22.8(5) . .
O19 Eu1 C39 O9 -147.4(4) . .
O19 Eu1 C39 O10 33.1(3) . .
O19 Eu1 C39 O11 3(11) . .
O19 Eu1 C41 Eu2 171.1(9) . 2_656
O19 Eu1 C41 Eu2 -55.7(8) . .
O19 Eu1 C41 O15 -173.3(12) . .
O19 Eu1 C41 O16 132.4(10) . .
O19 Eu1 C41 O17 -23.6(9) . .
O19 Eu1 C41 O18 149.3(11) . .
O19 Eu1 C41 O20 -68.8(10) . .
O20 Eu1 Zn1 O1 137.7(2) 2_656 .
O20 Eu1 Zn1 O2 -82.7(2) 2_656 .
O20 Eu1 Zn1 O14 28.0(2) 2_656 2_656
O20 Eu1 Zn1 N1 146.8(3) 2_656 .
O20 Eu1 Zn1 N2 -90.4(3) 2_656 .
O20 Eu1 O1 Zn1 -57.4(3) 2_656 .
O20 Eu1 O1 C1 125.6(5) 2_656 .
O20 Eu1 O2 Zn1 105.5(2) 2_656 .
O20 Eu1 O2 C17 -62.1(6) 2_656 .
O20 Eu1 O3 C2 -118.8(4) 2_656 .
O20 Eu1 O3 C18 66.9(5) 2_656 .
O20 Eu1 O4 C16 105.0(4) 2_656 .
O20 Eu1 O4 C19 -76.0(5) 2_656 .
O20 Eu1 O9 C39 -53.1(4) 2_656 .
O20 Eu1 O10 Eu2 -28.2(2) 2_656 .
O20 Eu1 O10 C39 150.6(3) 2_656 .
O20 Eu1 O16 Eu2 -38.3(2) 2_656 2_656
O20 Eu1 O16 C41 85.1(5) 2_656 .
O20 Eu1 O19 Eu2 79.2(3) 2_656 .
O20 Eu1 O19 C41 -29.3(8) 2_656 .
O20 Eu1 C39 O9 144.3(3) 2_656 .
O20 Eu1 C39 O10 -35.2(4) 2_656 .
O20 Eu1 C39 O11 -66(11) 2_656 .
O20 Eu1 C41 Eu2 -42.5(2) 2_656 2_656
O20 Eu1 C41 Eu2 90.8(2) 2_656 .
O20 Eu1 C41 O15 -26.9(7) 2_656 .
O20 Eu1 C41 O16 -81.2(5) 2_656 .
O20 Eu1 C41 O17 122.8(5) 2_656 .
O20 Eu1 C41 O18 -64.2(7) 2_656 .
O20 Eu1 C41 O19 146.4(9) 2_656 .
O20 Eu1 C41 O20 77.6(6) 2_656 .
O20 Eu2 Zn2 O5 55.2(3) . .
O20 Eu2 Zn2 O6 -163.4(3) . .
O20 Eu2 Zn2 O11 -53.6(3) . .
O20 Eu2 Zn2 N3 70.4(3) . .
O20 Eu2 Zn2 N4 -165.2(3) . .
O20 Eu2 O5 Zn2 -148.98(17) . .
O20 Eu2 O5 C20 33.0(4) . .
O20 Eu2 O6 Zn2 114.1(10) . .
O20 Eu2 O6 C36 -60.0(11) . .
O20 Eu2 O7 C21 -161.8(3) . .
O20 Eu2 O7 C37 24.9(4) . .
O20 Eu2 O8 C35 166.7(3) . .
O20 Eu2 O8 C38 -15.2(4) . .
O20 Eu2 O10 Eu1 -28.5(2) . .
O20 Eu2 O10 C39 153.9(7) . .
O20 Eu2 O12 Eu1 35.4(2) . 2_656
O20 Eu2 O12 C40 -152.0(4) . .
O20 Eu2 O13 C40 24.5(4) . .
O20 Eu2 O17 C41 -48.1(6) . .
O20 Eu2 O19 Eu1 -139.4(5) . .
O20 Eu2 O19 C41 -13.4(4) . .
O20 Eu2 C40 O12 23.1(4) . .
O20 Eu2 C40 O13 -155.8(4) . .
O20 Eu2 C40 O14 135(13) . .
O20 Eu2 C41 Eu1 -166.4(5) . .
O20 Eu2 C41 Eu2 -98.9(5) . 2_656
O20 Eu2 C41 O15 -20.4(6) . .
O20 Eu2 C41 O16 -160.0(7) . .
O20 Eu2 C41 O17 105.4(7) . .
O20 Eu2 C41 O18 -56.0(11) . .
O20 Eu2 C41 O19 156.4(8) . .
N1 Zn1 O1 Eu1 -173.38(18) . .
N1 Zn1 O1 C1 3.8(4) . .
N1 Zn1 O2 Eu1 104.8(2) . .
N1 Zn1 O2 C17 -86.7(6) . .
N1 Zn1 N2 C9 -5.5(5) . .
N1 Zn1 N2 C9A -39.2(6) . .
N1 Zn1 N2 C11 161.0(8) . .
N1 C8 C9 N2 46.0(9) . .
N1 C8 C9 C10 -83.8(7) . .
N1 C8A C9A N2 -59.4(12) . .
N1 C8A C9A C10A 70.9(13) . .
N2 Zn1 O1 Eu1 -104.8(3) . .
N2 Zn1 O1 C1 72.4(6) . .
N2 Zn1 O2 Eu1 174.5(2) . .
N2 Zn1 O2 C17 -17.0(5) . .
N2 Zn1 N1 C7 -153.8(7) . .
N2 Zn1 N1 C8 32.9(5) . .
N2 Zn1 N1 C8A 3.6(8) . .
N2 C11 C12 C13 175.5(10) . .
N2 C11 C12 C17 -7.3(16) . .
N3 Zn2 O5 Eu2 -169.07(14) . .
N3 Zn2 O5 C20 9.1(4) . .
N3 Zn2 O6 Eu2 106.6(3) . .
N3 Zn2 O6 C36 -78.8(4) . .
N3 Zn2 O11 C39 -143.5(4) . .
N3 Zn2 N4 C28 -29.7(3) . .
N3 Zn2 N4 C30 147.7(4) . .
N3 C27 C28 N4 -29.2(7) . .
N4 Zn2 O5 Eu2 -99.5(4) . .
N4 Zn2 O5 C20 78.6(5) . .
N4 Zn2 O6 Eu2 178.65(13) . .
N4 Zn2 O6 C36 -6.8(3) . .
N4 Zn2 O11 C39 133.2(4) . .
N4 Zn2 N3 C26 -151.6(4) . .
N4 Zn2 N3 C27 15.1(4) . .
N4 C30 C31 C32 175.5(5) . .
N4 C30 C31 C36 -9.0(9) . .
C1 C2 C3 C4 1.2(10) . .
C1 C6 C7 N1 2.3(13) . .
C2 C1 C6 C5 -1.5(9) . .
C2 C1 C6 C7 175.4(7) . .
C2 C3 C4 C5 0.3(12) . .
C3 C4 C5 C6 -2.3(13) . .
C4 C5 C6 C1 3.0(12) . .
C4 C5 C6 C7 -174.1(8) . .
C5 C6 C7 N1 179.3(8) . .
C6 C1 C2 O3 -178.1(5) . .
C6 C1 C2 C3 -0.5(9) . .
C7 N1 C8 C9 134.9(8) . .
C7 N1 C8A C9A -170.8(9) . .
C8 N1 C7 C6 175.8(8) . .
C8 N1 C8A C9A -70.4(13) . .
C8A N1 C7 C6 -150.1(11) . .
C8A N1 C8 C9 35.5(10) . .
C9 N2 C9A C8A -42.8(8) . .
C9 N2 C9A C10A -141.0(17) . .
C9 N2 C11 C12 160.0(9) . .
C9A N2 C9 C8 66.4(9) . .
C9A N2 C9 C10 179.3(12) . .
C9A N2 C11 C12 -163.1(9) . .
C11 N2 C9 C8 170.6(9) . .
C11 N2 C9 C10 -76.5(11) . .
C11 N2 C9A C8A -138.2(9) . .
C11 N2 C9A C10A 123.6(14) . .
C11 C12 C13 C14 175.1(10) . .
C11 C12 C17 O2 4.6(13) . .
C11 C12 C17 C16 -175.2(8) . .
C12 C13 C14 C15 -0.1(18) . .
C13 C12 C17 O2 -178.3(8) . .
C13 C12 C17 C16 2.0(12) . .
C13 C14 C15 C16 2.5(16) . .
C14 C15 C16 O4 179.2(8) . .
C14 C15 C16 C17 -2.9(14) . .
C15 C16 C17 O2 -179.2(8) . .
C15 C16 C17 C12 0.6(12) . .
C17 C12 C13 C14 -2.2(16) . .
C18 O3 C2 C1 175.0(5) . .
C18 O3 C2 C3 -2.5(8) . .
C19 O4 C16 C15 4.2(10) . .
C19 O4 C16 C17 -173.9(6) . .
C20 C21 C22 C23 -5.0(7) . .
C20 C25 C26 N3 12.3(7) . .
C21 C20 C25 C24 -1.7(6) . .
C21 C20 C25 C26 177.5(4) . .
C21 C22 C23 C24 1.5(7) . .
C22 C23 C24 C25 1.8(8) . .
C23 C24 C25 C20 -1.7(7) . .
C23 C24 C25 C26 179.0(5) . .
C24 C25 C26 N3 -168.5(5) . .
C25 C20 C21 O7 -174.4(4) . .
C25 C20 C21 C22 5.1(7) . .
C26 N3 C27 C28 172.6(5) . .
C26 N3 C27 C29 -53.4(8) . .
C27 N3 C26 C25 -177.4(4) . .
C28 N4 C30 C31 179.9(5) . .
C29 C27 C28 N4 -171.7(5) . .
C30 N4 C28 C27 -137.4(6) . .
C30 C31 C32 C33 175.1(6) . .
C30 C31 C36 O6 5.3(8) . .
C30 C31 C36 C35 -173.8(5) . .
C31 C32 C33 C34 1.2(11) . .
C32 C31 C36 O6 -179.2(5) . .
C32 C31 C36 C35 1.7(7) . .
C32 C33 C34 C35 -2.9(10) . .
C33 C34 C35 O8 -179.3(5) . .
C33 C34 C35 C36 4.0(8) . .
C34 C35 C36 O6 177.4(4) . .
C34 C35 C36 C31 -3.4(7) . .
C36 C31 C32 C33 -0.6(9) . .
C37 O7 C21 C20 176.5(4) . .
C37 O7 C21 C22 -2.9(7) . .
C38 O8 C35 C34 7.7(7) . .
C38 O8 C35 C36 -175.4(4) . .
C39 Eu1 Zn1 O1 -71.40(19) . .
C39 Eu1 Zn1 O2 68.2(2) . .
C39 Eu1 Zn1 O14 178.83(18) . 2_656
C39 Eu1 Zn1 N1 -62.3(2) . .
C39 Eu1 Zn1 N2 60.5(3) . .
C39 Eu1 O1 Zn1 124.26(15) . .
C39 Eu1 O1 C1 -52.8(5) . .
C39 Eu1 O2 Zn1 -126.54(16) . .
C39 Eu1 O2 C17 65.9(6) . .
C39 Eu1 O3 C2 123.0(3) . .
C39 Eu1 O3 C18 -51.3(4) . .
C39 Eu1 O4 C16 -124.7(4) . .
C39 Eu1 O4 C19 54.3(4) . .
C39 Eu1 O10 Eu2 -178.8(4) . .
C39 Eu1 O16 Eu2 -149.07(17) . 2_656
C39 Eu1 O16 C41 -25.6(5) . .
C39 Eu1 O19 Eu2 -46.5(3) . .
C39 Eu1 O19 C41 -155.0(8) . .
C39 Eu1 C41 Eu2 -163.19(12) . 2_656
C39 Eu1 C41 Eu2 -29.96(14) . .
C39 Eu1 C41 O15 -147.6(7) . .
C39 Eu1 C41 O16 158.1(4) . .
C39 Eu1 C41 O17 2.1(4) . .
C39 Eu1 C41 O18 175.1(7) . .
C39 Eu1 C41 O19 25.7(8) . .
C39 Eu1 C41 O20 -43.1(6) . .
C40 Eu2 Zn2 O5 -68.20(19) . .
C40 Eu2 Zn2 O6 73.25(18) . .
C40 Eu2 Zn2 O11 -176.99(18) . .
C40 Eu2 Zn2 N3 -53.0(2) . .
C40 Eu2 Zn2 N4 71.4(2) . .
C40 Eu2 O5 Zn2 125.00(15) . .
C40 Eu2 O5 C20 -53.0(4) . .
C40 Eu2 O6 Zn2 -121.37(15) . .
C40 Eu2 O6 C36 64.6(4) . .
C40 Eu2 O7 C21 112.5(3) . .
C40 Eu2 O7 C37 -60.9(4) . .
C40 Eu2 O8 C35 -123.5(3) . .
C40 Eu2 O8 C38 54.6(4) . .
C40 Eu2 O10 Eu1 -149(3) . .
C40 Eu2 O10 C39 33(3) . .
C40 Eu2 O12 Eu1 -172.6(5) . 2_656
C40 Eu2 O17 C41 -77.2(6) . .
C40 Eu2 O19 Eu1 -151.8(2) . .
C40 Eu2 O19 C41 -25.8(7) . .
C40 Eu2 O20 Eu1 -48.1(2) . 2_656
C40 Eu2 O20 C41 -178.4(5) . .
C40 Eu2 C41 Eu1 -164.77(13) . .
C40 Eu2 C41 Eu2 -97.31(19) . 2_656
C40 Eu2 C41 O15 -18.8(5) . .
C40 Eu2 C41 O16 -158.4(4) . .
C40 Eu2 C41 O17 107.0(6) . .
C40 Eu2 C41 O18 -54.3(11) . .
C40 Eu2 C41 O19 158.0(6) . .
C40 Eu2 C41 O20 1.6(5) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 -0.013 -0.013 0.000 693.5 -1.6
