#------------------------------------------------------------------------------
#$Date: 2017-09-27 16:12:17 +0300 (Wed, 27 Sep 2017) $
#$Revision: 201370 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/02/14/7021473.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7021473
loop_
_publ_author_name
'Song, Xue-Zhi'
'Song, Shu-Yan'
'Zhao, Shu-Na'
'Hao, Zhao-Min'
'Zhu, Min'
'Meng, Xing'
'Zhang, Hong-Jie'
_publ_section_title
;
 Two high-connected metal-organic frameworks based on d(10)-metal
 clusters: syntheses, structural topologies and luminescent properties.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8183
_journal_page_last               8187
_journal_paper_doi               10.1039/c3dt50687h
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C20 H12 N O7 Zn2'
_chemical_formula_weight         509.05
_chemical_name_systematic        ?
_space_group_IT_number           130
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4a 2ac'
_symmetry_space_group_name_H-M   'P 4/n c c :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   16.2782(3)
_cell_length_b                   16.2782(3)
_cell_length_c                   30.4992(12)
_cell_measurement_temperature    185(2)
_cell_volume                     8081.7(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      185(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0805
_diffrn_reflns_av_sigmaI/netI    0.0503
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            32557
_diffrn_reflns_theta_full        26.04
_diffrn_reflns_theta_max         26.04
_diffrn_reflns_theta_min         2.22
_exptl_absorpt_coefficient_mu    2.416
_exptl_absorpt_correction_T_max  0.6567
_exptl_absorpt_correction_T_min  0.5947
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Sheldrick, 1996'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.673
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4080
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.19
_platon_squeeze_details
;
;
_refine_diff_density_max         2.878
_refine_diff_density_min         -0.695
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     275
_refine_ls_number_reflns         3964
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0761
_refine_ls_R_factor_gt           0.0513
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0742P)²+13.4896P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1356
_refine_ls_wR_factor_ref         0.1460
_reflns_number_gt                2907
_reflns_number_total             3964
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt50687h.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Tetragonal' changed to 'tetragonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'multi-scans' was replaced
with the value 'multi-scan' as specified in the replacement file
'src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5376 2017-05-30 11:51:03Z andrius 
;
_cod_original_sg_symbol_H-M      'P 4/n c c'
_cod_database_code               7021473
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z'
'y, -x+1/2, z'
'-x, y+1/2, -z+1/2'
'x+1/2, -y, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y, -x, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z'
'-y, x-1/2, -z'
'x, -y-1/2, z-1/2'
'-x-1/2, y, z-1/2'
'-y-1/2, -x-1/2, z-1/2'
'y, x, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C2 C 0.5919(3) 0.0062(3) 0.15390(16) 0.0162(10) Uani 1 1 d .
C3 C 0.6377(3) 0.0058(3) 0.11526(16) 0.0187(10) Uani 1 1 d .
H3 H 0.6124 0.0215 0.0885 0.022 Uiso 1 1 calc R
C4 C 0.7200(3) -0.0172(3) 0.11537(17) 0.0216(11) Uani 1 1 d .
C5 C 0.7544(3) -0.0425(3) 0.15474(15) 0.0213(11) Uani 1 1 d .
H5 H 0.8103 -0.0594 0.1553 0.026 Uiso 1 1 calc R
C6 C 0.7086(3) -0.0436(3) 0.19395(15) 0.0173(10) Uani 1 1 d .
C7 C 0.6278(3) -0.0184(3) 0.19312(16) 0.0161(10) Uani 1 1 d .
H7 H 0.5965 -0.0179 0.2194 0.019 Uiso 1 1 calc R
C8 C 0.7489(3) -0.0668(3) 0.23584(16) 0.0192(10) Uani 1 1 d .
C9 C 0.7690(3) -0.0124(3) 0.07415(17) 0.0233(11) Uani 1 1 d .
C10 C 0.7353(3) -0.0336(3) 0.03414(17) 0.0244(11) Uani 1 1 d .
H10 H 0.6801 -0.0522 0.0329 0.029 Uiso 1 1 calc R
C11 C 0.7807(3) -0.0281(3) -0.00433(17) 0.0237(11) Uani 1 1 d .
C12 C 0.8617(3) 0.0005(4) -0.00265(18) 0.0295(13) Uani 1 1 d .
H12 H 0.8933 0.0047 -0.0288 0.035 Uiso 1 1 calc R
C13 C 0.8955(3) 0.0224(4) 0.03725(18) 0.0330(14) Uani 1 1 d .
H13 H 0.9504 0.0420 0.0385 0.040 Uiso 1 1 calc R
C14 C 0.8504(3) 0.0160(4) 0.07521(18) 0.0306(13) Uani 1 1 d .
H14 H 0.8745 0.0311 0.1024 0.037 Uiso 1 1 calc R
C15 C 0.7435(3) -0.0540(3) -0.04660(17) 0.0256(12) Uani 1 1 d .
C16 C 0.3709(3) -0.1085(4) 0.1938(2) 0.0375(15) Uani 1 1 d .
H16 H 0.4255 -0.0982 0.2033 0.045 Uiso 1 1 calc R
C17 C 0.3452(3) -0.1878(4) 0.1924(2) 0.0391(15) Uani 1 1 d .
H17 H 0.3815 -0.2305 0.2010 0.047 Uiso 1 1 calc R
C18 C 0.2663(3) -0.2068(3) 0.1784(2) 0.0318(13) Uani 1 1 d .
C19 C 0.2189(4) -0.1408(4) 0.1666(3) 0.0508(19) Uani 1 1 d .
H19 H 0.1640 -0.1495 0.1570 0.061 Uiso 1 1 calc R
C20 C 0.2497(4) -0.0619(4) 0.1684(2) 0.0408(15) Uani 1 1 d .
H20 H 0.2155 -0.0181 0.1588 0.049 Uiso 1 1 calc R
N1 N 0.3245(3) -0.0440(3) 0.18266(15) 0.0286(10) Uani 1 1 d .
O3 O 0.7084(2) -0.0902(2) 0.26816(12) 0.0265(8) Uani 1 1 d .
O4 O 0.8268(2) -0.0585(2) 0.23707(11) 0.0235(8) Uani 1 1 d .
O5 O 0.6663(2) -0.0611(2) -0.04762(11) 0.0288(9) Uani 1 1 d .
O6 O 0.7859(2) -0.0670(3) -0.07984(12) 0.0390(10) Uani 1 1 d .
O7 O 0.32258(19) 0.14940(19) 0.15299(10) 0.0136(7) Uani 1 1 d D
H7O H 0.2714(13) 0.151(4) 0.1566(17) 0.026(16) Uiso 1 1 d D
C1 C 0.5060(3) 0.0394(3) 0.15408(16) 0.0160(10) Uani 1 1 d .
O1 O 0.47562(19) 0.0563(2) 0.19043(11) 0.0226(8) Uani 1 1 d .
O2 O 0.4714(2) 0.0477(2) 0.11728(11) 0.0224(8) Uani 1 1 d .
Zn1 Zn 0.36117(3) 0.09004(4) 0.20387(2) 0.0244(2) Uani 1 1 d .
Zn2 Zn 0.37532(3) 0.11400(4) 0.100303(19) 0.02198(19) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C7 C2 C3 120.1(4) . .
C7 C2 C1 119.5(4) . .
C3 C2 C1 120.3(4) . .
C4 C3 C2 121.0(5) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C5 C4 C3 118.1(5) . .
C5 C4 C9 121.9(4) . .
C3 C4 C9 120.0(5) . .
C4 C5 C6 121.7(4) . .
C4 C5 H5 119.2 . .
C6 C5 H5 119.2 . .
C7 C6 C5 119.0(4) . .
C7 C6 C8 120.8(4) . .
C5 C6 C8 120.0(4) . .
C6 C7 C2 120.2(4) . .
C6 C7 H7 119.9 . .
C2 C7 H7 119.9 . .
O3 C8 O4 122.3(4) . .
O3 C8 C6 121.7(4) . .
O4 C8 C6 115.9(4) . .
C10 C9 C14 118.5(5) . .
C10 C9 C4 121.2(4) . .
C14 C9 C4 120.2(5) . .
C9 C10 C11 121.2(4) . .
C9 C10 H10 119.4 . .
C11 C10 H10 119.4 . .
C10 C11 C12 119.5(5) . .
C10 C11 C15 119.8(4) . .
C12 C11 C15 120.7(5) . .
C13 C12 C11 119.5(5) . .
C13 C12 H12 120.2 . .
C11 C12 H12 120.2 . .
C14 C13 C12 120.6(5) . .
C14 C13 H13 119.7 . .
C12 C13 H13 119.7 . .
C13 C14 C9 120.6(5) . .
C13 C14 H14 119.7 . .
C9 C14 H14 119.7 . .
O6 C15 O5 121.1(5) . .
O6 C15 C11 121.9(5) . .
O5 C15 C11 117.0(4) . .
N1 C16 C17 124.3(5) . .
N1 C16 H16 117.8 . .
C17 C16 H16 117.8 . .
C16 C17 C18 120.5(5) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C19 C18 C17 115.2(5) . .
C19 C18 C18 122.4(6) . 2_545
C17 C18 C18 122.4(6) . 2_545
C18 C19 C20 121.0(6) . .
C18 C19 H19 119.5 . .
C20 C19 H19 119.5 . .
N1 C20 C19 123.5(5) . .
N1 C20 H20 118.3 . .
C19 C20 H20 118.3 . .
C20 N1 C16 115.5(5) . .
C20 N1 Zn1 121.8(4) . .
C16 N1 Zn1 121.0(4) . .
C8 O3 Zn1 149.4(3) . 7_545
C8 O4 Zn1 106.5(3) . 6
C15 O5 Zn2 114.1(3) . 9_655
C15 O6 Zn2 142.5(4) . 12_655
Zn2 O7 Zn1 112.23(16) . .
Zn2 O7 H7O 124(4) . .
Zn1 O7 H7O 104(4) . .
O1 C1 O2 126.2(4) . .
O1 C1 C2 116.9(4) . .
O2 C1 C2 116.8(4) . .
C1 O1 Zn1 128.1(3) . .
C1 O2 Zn2 130.3(3) . .
O7 Zn1 O4 141.07(14) . 6_455
O7 Zn1 O1 106.13(14) . .
O4 Zn1 O1 112.72(14) 6_455 .
O7 Zn1 O3 89.46(13) . 7_545
O4 Zn1 O3 88.63(14) 6_455 7_545
O1 Zn1 O3 89.15(14) . 7_545
O7 Zn1 N1 99.24(14) . .
O4 Zn1 N1 86.41(15) 6_455 .
O1 Zn1 N1 85.67(14) . .
O3 Zn1 N1 170.83(14) 7_545 .
O7 Zn2 O5 132.19(14) . 9_655
O7 Zn2 O2 107.51(14) . .
O5 Zn2 O2 104.56(15) 9_655 .
O7 Zn2 O6 103.30(15) . 11_665
O5 Zn2 O6 105.61(16) 9_655 11_665
O2 Zn2 O6 99.03(16) . 11_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C2 C7 1.391(6) .
C2 C3 1.394(7) .
C2 C1 1.500(6) .
C3 C4 1.390(6) .
C3 H3 0.9500 .
C4 C5 1.387(6) .
C4 C9 1.491(7) .
C5 C6 1.409(6) .
C5 H5 0.9500 .
C6 C7 1.378(6) .
C6 C8 1.484(6) .
C7 H7 0.9500 .
C8 O3 1.245(6) .
C8 O4 1.276(6) .
C9 C10 1.382(7) .
C9 C14 1.403(7) .
C10 C11 1.390(7) .
C10 H10 0.9500 .
C11 C12 1.399(7) .
C11 C15 1.486(7) .
C12 C13 1.382(7) .
C12 H12 0.9500 .
C13 C14 1.375(7) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C15 O6 1.245(6) .
C15 O5 1.262(6) .
C16 N1 1.337(7) .
C16 C17 1.357(8) .
C16 H16 0.9500 .
C17 C18 1.389(7) .
C17 H17 0.9500 .
C18 C19 1.372(8) .
C18 C18 1.501(11) 2_545
C19 C20 1.379(8) .
C19 H19 0.9500 .
C20 N1 1.326(7) .
C20 H20 0.9500 .
N1 Zn1 2.353(4) .
O3 Zn1 2.251(3) 7_545
O4 Zn1 1.955(3) 6
O5 Zn2 1.945(3) 9_655
O6 Zn2 1.981(4) 12_655
O7 Zn2 1.911(3) .
O7 Zn1 1.933(3) .
O7 H7O 0.84(2) .
C1 O1 1.244(5) .
C1 O2 1.263(5) .
O1 Zn1 1.985(3) .
O2 Zn2 1.969(3) .
Zn1 O4 1.955(3) 6_455
Zn1 O3 2.251(3) 7_545
Zn2 O5 1.945(3) 9_655
Zn2 O6 1.981(4) 11_665
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O7 H7O O7 0.84(2) 2.03(2) 2.856(4) 165(5) 4
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 C2 C3 C4 -1.5(7) . .
C1 C2 C3 C4 173.7(4) . .
C2 C3 C4 C5 2.2(7) . .
C2 C3 C4 C9 -176.3(4) . .
C3 C4 C5 C6 -1.2(8) . .
C9 C4 C5 C6 177.3(5) . .
C4 C5 C6 C7 -0.5(7) . .
C4 C5 C6 C8 -176.8(5) . .
C5 C6 C7 C2 1.2(7) . .
C8 C6 C7 C2 177.4(4) . .
C3 C2 C7 C6 -0.2(7) . .
C1 C2 C7 C6 -175.5(4) . .
C7 C6 C8 O3 23.7(7) . .
C5 C6 C8 O3 -160.1(5) . .
C7 C6 C8 O4 -154.0(4) . .
C5 C6 C8 O4 22.2(6) . .
C5 C4 C9 C10 142.6(6) . .
C3 C4 C9 C10 -38.9(7) . .
C5 C4 C9 C14 -39.0(7) . .
C3 C4 C9 C14 139.4(5) . .
C14 C9 C10 C11 0.8(8) . .
C4 C9 C10 C11 179.2(5) . .
C9 C10 C11 C12 -0.9(8) . .
C9 C10 C11 C15 178.0(5) . .
C10 C11 C12 C13 0.3(8) . .
C15 C11 C12 C13 -178.5(5) . .
C11 C12 C13 C14 0.3(9) . .
C12 C13 C14 C9 -0.3(9) . .
C10 C9 C14 C13 -0.2(8) . .
C4 C9 C14 C13 -178.6(5) . .
C10 C11 C15 O6 -164.3(5) . .
C12 C11 C15 O6 14.6(8) . .
C10 C11 C15 O5 16.7(8) . .
C12 C11 C15 O5 -164.4(5) . .
N1 C16 C17 C18 0.5(10) . .
C16 C17 C18 C19 0.2(10) . .
C16 C17 C18 C18 -176.9(5) . 2_545
C17 C18 C19 C20 0.6(10) . .
C18 C18 C19 C20 177.8(5) 2_545 .
C18 C19 C20 N1 -2.3(11) . .
C19 C20 N1 C16 2.9(9) . .
C19 C20 N1 Zn1 -162.3(5) . .
C17 C16 N1 C20 -2.0(9) . .
C17 C16 N1 Zn1 163.3(5) . .
O4 C8 O3 Zn1 -165.3(4) . 7_545
C6 C8 O3 Zn1 17.1(9) . 7_545
O3 C8 O4 Zn1 0.6(5) . 6
C6 C8 O4 Zn1 178.2(3) . 6
O6 C15 O5 Zn2 11.7(7) . 9_655
C11 C15 O5 Zn2 -169.3(4) . 9_655
O5 C15 O6 Zn2 -133.2(5) . 12_655
C11 C15 O6 Zn2 47.9(9) . 12_655
C7 C2 C1 O1 11.9(6) . .
C3 C2 C1 O1 -163.4(4) . .
C7 C2 C1 O2 -168.3(4) . .
C3 C2 C1 O2 16.4(6) . .
O2 C1 O1 Zn1 7.0(7) . .
C2 C1 O1 Zn1 -173.2(3) . .
O1 C1 O2 Zn2 18.4(7) . .
C2 C1 O2 Zn2 -161.4(3) . .
Zn2 O7 Zn1 O4 -155.70(18) . 6_455
Zn2 O7 Zn1 O1 28.19(19) . .
Zn2 O7 Zn1 O3 117.15(17) . 7_545
Zn2 O7 Zn1 N1 -59.94(18) . .
C1 O1 Zn1 O7 -31.1(4) . .
C1 O1 Zn1 O4 151.6(4) . 6_455
C1 O1 Zn1 O3 -120.3(4) . 7_545
C1 O1 Zn1 N1 67.3(4) . .
C20 N1 Zn1 O7 -50.1(5) . .
C16 N1 Zn1 O7 145.5(4) . .
C20 N1 Zn1 O4 91.1(5) . 6_455
C16 N1 Zn1 O4 -73.3(4) . 6_455
C20 N1 Zn1 O1 -155.8(5) . .
C16 N1 Zn1 O1 39.8(4) . .
C20 N1 Zn1 O3 148.4(8) . 7_545
C16 N1 Zn1 O3 -16.0(12) . 7_545
Zn1 O7 Zn2 O5 116.0(2) . 9_655
Zn1 O7 Zn2 O2 -13.9(2) . .
Zn1 O7 Zn2 O6 -117.99(18) . 11_665
C1 O2 Zn2 O7 -12.9(4) . .
C1 O2 Zn2 O5 -157.0(4) . 9_655
C1 O2 Zn2 O6 94.2(4) . 11_665
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.250 0.750 0.500 209 29 ' '
2 0.250 0.750 1.000 209 29 ' '
3 0.131 0.869 0.250 7 1 ' '
4 0.131 0.631 0.750 7 1 ' '
5 0.250 0.250 0.408 109 21 ' '
6 0.250 0.250 0.908 109 21 ' '
7 0.369 0.631 0.250 7 1 ' '
8 0.369 0.869 0.750 7 1 ' '
9 0.750 0.250 0.000 209 29 ' '
10 0.750 0.250 0.500 209 29 ' '
11 0.631 0.131 0.250 7 1 ' '
12 0.631 0.369 0.750 7 1 ' '
13 0.750 0.750 0.092 109 21 ' '
14 0.750 0.750 0.592 109 21 ' '
15 0.869 0.369 0.250 7 1 ' '
16 0.869 0.131 0.750 7 1 ' '
