#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:45:19 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179934 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/29/7022991.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7022991
loop_
_publ_author_name
'Wang, Kun'
'Yi, Xiu-Chun'
'Wang, Xuan'
'Li, Xiu-Bing'
'Gao, En-Qing'
_publ_section_title
;
 Structures and magnetic properties of copper(II) and manganese(II)
 polymers derived from pseudohalides and a flexible zwitterionic
 dicarboxylate ligand.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8748
_journal_page_last               8760
_journal_paper_doi               10.1039/c3dt50460c
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C20 H18 Mn2 N6 O9'
_chemical_formula_weight         596.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 121.662(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.682(3)
_cell_length_b                   10.8253(11)
_cell_length_c                   12.0065(12)
_cell_measurement_reflns_used    7476
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.42
_cell_measurement_theta_min      2.21
_cell_volume                     2398.6(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0237
_diffrn_reflns_av_sigmaI/netI    0.0174
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            12117
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         2.18
_exptl_absorpt_coefficient_mu    1.116
_exptl_absorpt_correction_T_max  0.9361
_exptl_absorpt_correction_T_min  0.9160
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 1999)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       octahedral
_exptl_crystal_F_000             1208
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.810
_refine_diff_density_min         -0.285
_refine_diff_density_rms         0.068
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     170
_refine_ls_number_reflns         2487
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.061
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0443P)²+3.1939P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0819
_refine_ls_wR_factor_ref         0.0868
_reflns_number_gt                2234
_reflns_number_total             2487
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt50460c.txt
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7022991
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Mn1 Mn 0.5000 0.39043(3) 0.2500 0.02696(13) Uani 1 2 d S
Mn2 Mn 0.5000 0.5000 0.0000 0.02881(13) Uani 1 2 d S
C1 C 0.43645(12) 0.24099(18) 0.3885(2) 0.0350(4) Uani 1 1 d .
C2 C 0.39219(12) 0.13311(18) 0.3890(2) 0.0350(4) Uani 1 1 d .
C3 C 0.34805(13) 0.1488(2) 0.4388(2) 0.0417(5) Uani 1 1 d .
H3A H 0.3473 0.2239 0.4758 0.050 Uiso 1 1 calc R
C4 C 0.30528(13) 0.0530(2) 0.4335(2) 0.0437(5) Uani 1 1 d .
H4A H 0.2750 0.0638 0.4659 0.052 Uiso 1 1 calc R
C5 C 0.34976(15) -0.0741(2) 0.3363(2) 0.0485(6) Uani 1 1 d .
H5A H 0.3507 -0.1511 0.3028 0.058 Uiso 1 1 calc R
C6 C 0.39323(14) 0.0194(2) 0.3374(2) 0.0447(5) Uani 1 1 d .
H6A H 0.4228 0.0063 0.3039 0.054 Uiso 1 1 calc R
C7 C 0.25713(14) -0.1550(2) 0.3734(2) 0.0494(6) Uani 1 1 d .
H7A H 0.2583 -0.2226 0.3215 0.059 Uiso 1 1 calc R
H7B H 0.2080 -0.1233 0.3293 0.059 Uiso 1 1 calc R
C8 C 0.27778(12) -0.20256(19) 0.5064(2) 0.0393(5) Uani 1 1 d .
H8A H 0.2800 -0.1344 0.5608 0.047 Uiso 1 1 calc R
H8B H 0.3254 -0.2405 0.5481 0.047 Uiso 1 1 calc R
C9 C 0.35895(13) 0.4612(2) -0.0286(2) 0.0460(6) Uani 1 1 d .
C10 C 0.60926(14) 0.6033(2) 0.2668(2) 0.0438(5) Uani 1 1 d .
N1 N 0.41673(10) 0.41785(17) 0.03673(17) 0.0366(4) Uani 1 1 d .
N2 N 0.56512(11) 0.52774(17) 0.21274(18) 0.0387(4) Uani 1 1 d .
N3 N 0.30668(10) -0.05570(16) 0.38219(18) 0.0403(4) Uani 1 1 d .
O1 O 0.44942(9) 0.24356(13) 0.29864(15) 0.0416(4) Uani 1 1 d .
O2 O 0.45411(10) 0.31755(14) 0.47793(16) 0.0460(4) Uani 1 1 d .
O3 O 0.30021(12) 0.5045(3) -0.0954(3) 0.0928(9) Uani 1 1 d .
O4 O 0.65540(13) 0.6794(2) 0.3215(2) 0.0839(7) Uani 1 1 d .
O5 O 0.0000 0.3178(4) 0.2500 0.1051(12) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Mn1 O1 86.24(8) . 2_655
O1 Mn1 N1 90.42(6) . 2_655
O1 Mn1 N1 100.69(6) 2_655 2_655
O1 Mn1 N1 100.69(6) . .
O1 Mn1 N1 90.42(6) 2_655 .
N1 Mn1 N1 164.82(10) 2_655 .
O1 Mn1 N2 172.76(7) . .
O1 Mn1 N2 88.40(6) 2_655 .
N1 Mn1 N2 85.79(7) 2_655 .
N1 Mn1 N2 84.20(7) . .
O1 Mn1 N2 88.40(6) . 2_655
O1 Mn1 N2 172.76(7) 2_655 2_655
N1 Mn1 N2 84.20(7) 2_655 2_655
N1 Mn1 N2 85.79(7) . 2_655
N2 Mn1 N2 97.34(10) . 2_655
O1 Mn1 Mn2 76.89(4) . 2_655
O1 Mn1 Mn2 139.77(4) 2_655 2_655
N1 Mn1 Mn2 44.28(5) 2_655 2_655
N1 Mn1 Mn2 128.24(5) . 2_655
N2 Mn1 Mn2 104.38(5) . 2_655
N2 Mn1 Mn2 42.80(5) 2_655 2_655
O1 Mn1 Mn2 139.77(4) . .
O1 Mn1 Mn2 76.89(4) 2_655 .
N1 Mn1 Mn2 128.24(5) 2_655 .
N1 Mn1 Mn2 44.28(5) . .
N2 Mn1 Mn2 42.80(5) . .
N2 Mn1 Mn2 104.38(5) 2_655 .
Mn2 Mn1 Mn2 136.874(14) 2_655 .
O2 Mn2 O2 180.0 6_565 2_655
O2 Mn2 N2 89.49(7) 6_565 .
O2 Mn2 N2 90.51(7) 2_655 .
O2 Mn2 N2 90.51(7) 6_565 5_665
O2 Mn2 N2 89.49(7) 2_655 5_665
N2 Mn2 N2 180.0 . 5_665
O2 Mn2 N1 91.15(7) 6_565 .
O2 Mn2 N1 88.85(7) 2_655 .
N2 Mn2 N1 85.32(7) . .
N2 Mn2 N1 94.68(7) 5_665 .
O2 Mn2 N1 88.85(7) 6_565 5_665
O2 Mn2 N1 91.15(7) 2_655 5_665
N2 Mn2 N1 94.68(7) . 5_665
N2 Mn2 N1 85.32(7) 5_665 5_665
N1 Mn2 N1 180.00(7) . 5_665
O2 Mn2 Mn1 102.99(4) 6_565 .
O2 Mn2 Mn1 77.01(4) 2_655 .
N2 Mn2 Mn1 44.14(5) . .
N2 Mn2 Mn1 135.86(5) 5_665 .
N1 Mn2 Mn1 44.11(5) . .
N1 Mn2 Mn1 135.89(5) 5_665 .
O2 Mn2 Mn1 77.01(4) 6_565 5_665
O2 Mn2 Mn1 102.99(4) 2_655 5_665
N2 Mn2 Mn1 135.86(5) . 5_665
N2 Mn2 Mn1 44.14(5) 5_665 5_665
N1 Mn2 Mn1 135.89(5) . 5_665
N1 Mn2 Mn1 44.11(5) 5_665 5_665
Mn1 Mn2 Mn1 180.000(12) . 5_665
O2 C1 O1 128.46(19) . .
O2 C1 C2 114.70(18) . .
O1 C1 C2 116.83(18) . .
C3 C2 C6 118.81(19) . .
C3 C2 C1 119.51(18) . .
C6 C2 C1 121.66(19) . .
C4 C3 C2 119.6(2) . .
C4 C3 H3A 120.2 . .
C2 C3 H3A 120.2 . .
N3 C4 C3 120.6(2) . .
N3 C4 H4A 119.7 . .
C3 C4 H4A 119.7 . .
N3 C5 C6 120.9(2) . .
N3 C5 H5A 119.6 . .
C6 C5 H5A 119.6 . .
C5 C6 C2 119.1(2) . .
C5 C6 H6A 120.5 . .
C2 C6 H6A 120.5 . .
N3 C7 C8 111.81(18) . .
N3 C7 H7A 109.3 . .
C8 C7 H7A 109.3 . .
N3 C7 H7B 109.3 . .
C8 C7 H7B 109.3 . .
H7A C7 H7B 107.9 . .
C7 C8 C8 110.1(2) . 7_546
C7 C8 H8A 109.6 . .
C8 C8 H8A 109.6 7_546 .
C7 C8 H8B 109.6 . .
C8 C8 H8B 109.6 7_546 .
H8A C8 H8B 108.2 . .
N1 C9 O3 179.5(3) . .
N2 C10 O4 178.6(3) . .
C9 N1 Mn1 138.82(17) . .
C9 N1 Mn2 113.31(16) . .
Mn1 N1 Mn2 91.61(7) . .
C10 N2 Mn2 125.69(16) . .
C10 N2 Mn1 140.47(17) . .
Mn2 N2 Mn1 93.07(7) . .
C5 N3 C4 121.03(19) . .
C5 N3 C7 120.2(2) . .
C4 N3 C7 118.7(2) . .
C1 O1 Mn1 128.37(13) . .
C1 O2 Mn2 128.73(13) . 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mn1 O1 2.1781(14) .
Mn1 O1 2.1781(14) 2_655
Mn1 N1 2.2475(18) 2_655
Mn1 N1 2.2475(18) .
Mn1 N2 2.2509(18) .
Mn1 N2 2.2509(18) 2_655
Mn1 Mn2 3.2275(3) 2_655
Mn1 Mn2 3.2275(3) .
Mn2 O2 2.1643(14) 6_565
Mn2 O2 2.1643(14) 2_655
Mn2 N2 2.1959(18) .
Mn2 N2 2.1959(18) 5_665
Mn2 N1 2.2540(18) .
Mn2 N1 2.2540(18) 5_665
Mn2 Mn1 3.2275(3) 5_665
C1 O2 1.247(2) .
C1 O1 1.250(2) .
C1 C2 1.514(3) .
C2 C3 1.380(3) .
C2 C6 1.384(3) .
C3 C4 1.370(3) .
C3 H3A 0.9300 .
C4 N3 1.336(3) .
C4 H4A 0.9300 .
C5 N3 1.325(3) .
C5 C6 1.378(3) .
C5 H5A 0.9300 .
C6 H6A 0.9300 .
C7 N3 1.484(3) .
C7 C8 1.505(3) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C8 1.528(4) 7_546
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 N1 1.172(3) .
C9 O3 1.188(3) .
C10 N2 1.164(3) .
C10 O4 1.192(3) .
O2 Mn2 2.1643(14) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Mn1 Mn2 O2 114.75(8) . 6_565
O1 Mn1 Mn2 O2 -177.57(7) 2_655 6_565
N1 Mn1 Mn2 O2 -84.19(8) 2_655 6_565
N1 Mn1 Mn2 O2 77.97(9) . 6_565
N2 Mn1 Mn2 O2 -75.48(9) . 6_565
N2 Mn1 Mn2 O2 9.77(7) 2_655 6_565
Mn2 Mn1 Mn2 O2 -23.68(5) 2_655 6_565
O1 Mn1 Mn2 O2 -65.25(8) . 2_655
O1 Mn1 Mn2 O2 2.43(7) 2_655 2_655
N1 Mn1 Mn2 O2 95.81(8) 2_655 2_655
N1 Mn1 Mn2 O2 -102.03(9) . 2_655
N2 Mn1 Mn2 O2 104.52(9) . 2_655
N2 Mn1 Mn2 O2 -170.23(7) 2_655 2_655
Mn2 Mn1 Mn2 O2 156.32(5) 2_655 2_655
O1 Mn1 Mn2 N2 -169.77(10) . .
O1 Mn1 Mn2 N2 -102.09(9) 2_655 .
N1 Mn1 Mn2 N2 -8.71(9) 2_655 .
N1 Mn1 Mn2 N2 153.44(11) . .
N2 Mn1 Mn2 N2 85.25(12) 2_655 .
Mn2 Mn1 Mn2 N2 51.80(7) 2_655 .
O1 Mn1 Mn2 N2 10.23(10) . 5_665
O1 Mn1 Mn2 N2 77.91(9) 2_655 5_665
N1 Mn1 Mn2 N2 171.29(9) 2_655 5_665
N1 Mn1 Mn2 N2 -26.55(11) . 5_665
N2 Mn1 Mn2 N2 180.0 . 5_665
N2 Mn1 Mn2 N2 -94.75(12) 2_655 5_665
Mn2 Mn1 Mn2 N2 -128.20(7) 2_655 5_665
O1 Mn1 Mn2 N1 36.78(10) . .
O1 Mn1 Mn2 N1 104.46(8) 2_655 .
N1 Mn1 Mn2 N1 -162.16(11) 2_655 .
N2 Mn1 Mn2 N1 -153.44(11) . .
N2 Mn1 Mn2 N1 -68.20(8) 2_655 .
Mn2 Mn1 Mn2 N1 -101.64(7) 2_655 .
O1 Mn1 Mn2 N1 -143.22(10) . 5_665
O1 Mn1 Mn2 N1 -75.54(8) 2_655 5_665
N1 Mn1 Mn2 N1 17.84(11) 2_655 5_665
N1 Mn1 Mn2 N1 180.0 . 5_665
N2 Mn1 Mn2 N1 26.56(11) . 5_665
N2 Mn1 Mn2 N1 111.80(8) 2_655 5_665
Mn2 Mn1 Mn2 N1 78.36(7) 2_655 5_665
O1 Mn1 Mn2 Mn1 -54.37(7) . 5_665
O1 Mn1 Mn2 Mn1 13.31(5) 2_655 5_665
N1 Mn1 Mn2 Mn1 106.68(6) 2_655 5_665
N1 Mn1 Mn2 Mn1 -91.16(7) . 5_665
N2 Mn1 Mn2 Mn1 115.40(8) . 5_665
N2 Mn1 Mn2 Mn1 -159.35(5) 2_655 5_665
Mn2 Mn1 Mn2 Mn1 167.198(9) 2_655 5_665
O2 C1 C2 C3 29.0(3) . .
O1 C1 C2 C3 -149.7(2) . .
O2 C1 C2 C6 -152.8(2) . .
O1 C1 C2 C6 28.5(3) . .
C6 C2 C3 C4 -1.4(3) . .
C1 C2 C3 C4 176.8(2) . .
C2 C3 C4 N3 0.9(4) . .
N3 C5 C6 C2 0.9(4) . .
C3 C2 C6 C5 0.6(4) . .
C1 C2 C6 C5 -177.6(2) . .
N3 C7 C8 C8 175.7(2) . 7_546
O3 C9 N1 Mn1 -138(42) . .
O3 C9 N1 Mn2 99(42) . .
O1 Mn1 N1 C9 73.9(3) . .
O1 Mn1 N1 C9 160.1(3) 2_655 .
N1 Mn1 N1 C9 -62.5(3) 2_655 .
N2 Mn1 N1 C9 -111.5(3) . .
N2 Mn1 N1 C9 -13.7(3) 2_655 .
Mn2 Mn1 N1 C9 -7.8(3) 2_655 .
Mn2 Mn1 N1 C9 -129.3(3) . .
O1 Mn1 N1 Mn2 -156.82(6) . .
O1 Mn1 N1 Mn2 -70.57(6) 2_655 .
N1 Mn1 N1 Mn2 66.77(5) 2_655 .
N2 Mn1 N1 Mn2 17.78(7) . .
N2 Mn1 N1 Mn2 115.60(7) 2_655 .
Mn2 Mn1 N1 Mn2 121.53(4) 2_655 .
O2 Mn2 N1 C9 38.70(19) 6_565 .
O2 Mn2 N1 C9 -141.30(19) 2_655 .
N2 Mn2 N1 C9 128.10(19) . .
N2 Mn2 N1 C9 -51.90(19) 5_665 .
N1 Mn2 N1 C9 -86(100) 5_665 .
Mn1 Mn2 N1 C9 146.3(2) . .
Mn1 Mn2 N1 C9 -33.7(2) 5_665 .
O2 Mn2 N1 Mn1 -107.60(7) 6_565 .
O2 Mn2 N1 Mn1 72.40(7) 2_655 .
N2 Mn2 N1 Mn1 -18.20(7) . .
N2 Mn2 N1 Mn1 161.80(7) 5_665 .
N1 Mn2 N1 Mn1 127(100) 5_665 .
Mn1 Mn2 N1 Mn1 180.0 5_665 .
O4 C10 N2 Mn2 -70(12) . .
O4 C10 N2 Mn1 123(12) . .
O2 Mn2 N2 C10 -62.3(2) 6_565 .
O2 Mn2 N2 C10 117.7(2) 2_655 .
N2 Mn2 N2 C10 -149(100) 5_665 .
N1 Mn2 N2 C10 -153.5(2) . .
N1 Mn2 N2 C10 26.5(2) 5_665 .
Mn1 Mn2 N2 C10 -171.7(3) . .
Mn1 Mn2 N2 C10 8.3(3) 5_665 .
O2 Mn2 N2 Mn1 109.39(7) 6_565 .
O2 Mn2 N2 Mn1 -70.61(7) 2_655 .
N2 Mn2 N2 Mn1 22(100) 5_665 .
N1 Mn2 N2 Mn1 18.19(7) . .
N1 Mn2 N2 Mn1 -161.81(7) 5_665 .
Mn1 Mn2 N2 Mn1 180.0 5_665 .
O1 Mn1 N2 C10 -76.1(6) . .
O1 Mn1 N2 C10 -118.3(3) 2_655 .
N1 Mn1 N2 C10 -17.5(3) 2_655 .
N1 Mn1 N2 C10 151.1(3) . .
N2 Mn1 N2 C10 66.1(3) 2_655 .
Mn2 Mn1 N2 C10 23.1(3) 2_655 .
Mn2 Mn1 N2 C10 169.4(3) . .
O1 Mn1 N2 Mn2 114.5(5) . .
O1 Mn1 N2 Mn2 72.30(7) 2_655 .
N1 Mn1 N2 Mn2 173.15(7) 2_655 .
N1 Mn1 N2 Mn2 -18.28(7) . .
N2 Mn1 N2 Mn2 -103.27(8) 2_655 .
Mn2 Mn1 N2 Mn2 -146.32(4) 2_655 .
C6 C5 N3 C4 -1.5(4) . .
C6 C5 N3 C7 176.5(2) . .
C3 C4 N3 C5 0.6(4) . .
C3 C4 N3 C7 -177.4(2) . .
C8 C7 N3 C5 113.6(3) . .
C8 C7 N3 C4 -68.4(3) . .
O2 C1 O1 Mn1 -5.9(4) . .
C2 C1 O1 Mn1 172.58(14) . .
O1 Mn1 O1 C1 143.5(2) 2_655 .
N1 Mn1 O1 C1 42.84(19) 2_655 .
N1 Mn1 O1 C1 -126.76(19) . .
N2 Mn1 O1 C1 101.2(5) . .
N2 Mn1 O1 C1 -41.35(19) 2_655 .
Mn2 Mn1 O1 C1 0.30(18) 2_655 .
Mn2 Mn1 O1 C1 -151.94(16) . .
O1 C1 O2 Mn2 10.3(4) . 2_655
C2 C1 O2 Mn2 -168.22(14) . 2_655
