#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:50:46 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179939 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/34/7023481.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7023481
loop_
_publ_author_name
'Moon, So Yun'
'Kim, Euni'
'Noh, Tae Hwan'
'Lee, Young-A'
'Jung, Ok-Sang'
_publ_section_title
;
 Triple-meso helices as alcohol reservoirs and discriminators: structural
 properties and thermal behaviors of silver(I) coordination molecular
 braids containing diethylbis(4-pyridyl)silanes.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13974
_journal_page_last               13980
_journal_paper_doi               10.1039/c3dt51398j
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C46 H58 Ag3 F9 N6 O10 S3 Si3'
_chemical_formula_weight         1530.04
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.1120(10)
_cell_angle_beta                 102.7410(10)
_cell_angle_gamma                91.4050(10)
_cell_formula_units_Z            2
_cell_length_a                   11.87020(10)
_cell_length_b                   14.0565(2)
_cell_length_c                   20.2429(2)
_cell_measurement_reflns_used    9922
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.70
_cell_measurement_theta_min      2.19
_cell_volume                     3095.65(6)
_computing_cell_refinement       'Bruker AFEX2'
_computing_data_collection       'Bruker AFEX2'
_computing_data_reduction        'Bruker AFEX2'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker Breeze CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0314
_diffrn_reflns_av_unetI/netI     0.0403
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            48328
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    1.181
_exptl_absorpt_correction_T_max  0.7258
_exptl_absorpt_correction_T_min  0.6625
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.641
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1536
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.29
_refine_diff_density_max         5.264
_refine_diff_density_min         -4.263
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     868
_refine_ls_number_reflns         12111
_refine_ls_number_restraints     153
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.1183
_refine_ls_R_factor_gt           0.0847
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0783P)²+30.6914P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2001
_refine_ls_wR_factor_ref         0.2247
_reflns_number_gt                8444
_reflns_number_total             12111
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt51398j.txt
_cod_data_source_block           939630
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7023481
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.0000 0.5000 0.0000 0.0522(3) Uani 1 2 d S . .
Ag2 Ag 0.67958(10) 0.12413(7) 0.25043(5) 0.0915(4) Uani 1 1 d D . .
Ag3 Ag -0.10415(7) -0.02005(7) -0.22092(5) 0.0698(3) Uani 1 1 d . . .
Ag4 Ag -0.5000 0.5000 0.0000 0.0633(3) Uani 1 2 d S . .
Si1 Si 1.0116(2) 0.57693(16) 0.35336(11) 0.0394(5) Uani 1 1 d . . .
Si2 Si 0.2634(2) -0.22851(19) -0.00948(16) 0.0637(8) Uani 1 1 d D . .
Si3 Si -0.5078(2) 0.24965(17) -0.35078(12) 0.0421(5) Uani 1 1 d . . .
S1 S 0.2363(2) 0.29259(16) -0.01363(11) 0.0484(5) Uani 1 1 d . . .
S2 S 0.1345(2) 0.04610(19) 0.69917(13) 0.0578(6) Uani 1 1 d . . .
S3 S 0.3329(2) 0.2847(2) 0.29459(14) 0.0638(7) Uani 1 1 d D . .
F1 F 0.2918(9) 0.2868(7) 0.1155(4) 0.123(3) Uani 1 1 d . . .
F2 F 0.1927(10) 0.1552(6) 0.0398(5) 0.134(4) Uani 1 1 d . . .
F3 F 0.3649(9) 0.1741(8) 0.0390(6) 0.141(4) Uani 1 1 d . . .
F4 F -0.0545(8) -0.0298(15) 0.5957(12) 0.139(9) Uani 0.65 1 d PD A 1
F5 F 0.1060(17) 0.017(2) 0.5615(8) 0.181(14) Uani 0.65 1 d PD A 1
F6 F 0.073(3) -0.1064(10) 0.5865(13) 0.206(17) Uani 0.65 1 d PD A 1
F4' F -0.0450(13) 0.023(2) 0.5995(15) 0.091(8) Uani 0.35 1 d PDU A 2
F5' F 0.076(5) 0.053(2) 0.573(2) 0.18(2) Uani 0.35 1 d PDU A 2
F6' F 0.091(5) -0.0944(19) 0.568(2) 0.119(13) Uani 0.35 1 d PDU A 2
F7 F 0.3643(11) 0.2205(8) 0.4026(5) 0.165(4) Uani 1 1 d DU . .
F8 F 0.1921(14) 0.2521(15) 0.3682(9) 0.140(6) Uani 0.60 1 d PDU B 1
F9 F 0.322(3) 0.3616(17) 0.4240(12) 0.165(10) Uani 0.60 1 d PDU B 1
O8 O 0.4474(14) 0.3063(13) 0.3171(11) 0.084(5) Uani 0.60 1 d P C 1
O9 O 0.296(3) 0.373(4) 0.287(3) 0.105(14) Uani 0.60 1 d P C 1
C46 C 0.3016(14) 0.2753(14) 0.3688(7) 0.122(11) Uani 0.60 1 d PDU B 1
F8' F 0.455(2) 0.3725(17) 0.4253(11) 0.124(7) Uani 0.40 1 d PU C 2
F9' F 0.262(3) 0.337(2) 0.417(2) 0.134(12) Uani 0.40 1 d PDU C 2
O8' O 0.456(2) 0.273(2) 0.2766(16) 0.082(8) Uani 0.40 1 d P C 2
O9' O 0.252(4) 0.361(5) 0.282(4) 0.066(10) Uani 0.40 1 d P C 2
C46' C 0.344(4) 0.309(7) 0.3816(10) 0.19(3) Uani 0.40 1 d PDU C 2
O1 O 0.2121(7) 0.2160(5) -0.0830(4) 0.075(2) Uani 1 1 d . . .
O2 O 0.3410(8) 0.3541(6) 0.0006(4) 0.090(3) Uani 1 1 d . . .
O3 O 0.1400(8) 0.3410(7) 0.0057(4) 0.095(3) Uani 1 1 d . . .
O4 O 0.1090(10) 0.1459(7) 0.7145(6) 0.089(3) Uani 0.80 1 d P D 1
O5 O 0.2562(8) 0.0343(8) 0.6972(5) 0.066(3) Uani 0.80 1 d P D 1
O6 O 0.0917(10) -0.0193(9) 0.7296(6) 0.086(3) Uani 0.80 1 d P D 1
O4' O 0.047(3) 0.095(3) 0.755(2) 0.075(11) Uani 0.20 1 d P D 2
O5' O 0.233(7) 0.085(6) 0.700(4) 0.13(3) Uani 0.20 1 d PU D 2
O6' O 0.167(5) -0.031(4) 0.723(3) 0.089(14) Uani 0.20 1 d PU . 2
O7 O 0.2795(7) 0.1868(6) 0.2492(4) 0.082(2) Uani 1 1 d . C .
O10 O 0.640(3) 0.106(3) 0.3632(19) 0.134(11) Uani 0.35 1 d PDU E 1
H10A H 0.5619 0.0733 0.3438 0.160 Uiso 0.35 1 d PR E 1
C43 C 0.663(10) 0.142(4) 0.4433(19) 0.25(6) Uani 0.35 1 d PD E 1
H43A H 0.7429 0.1699 0.4637 0.295 Uiso 0.35 1 calc PR E 1
H43B H 0.6491 0.0856 0.4586 0.295 Uiso 0.35 1 calc PR E 1
H43C H 0.6133 0.1925 0.4593 0.295 Uiso 0.35 1 calc PR E 1
O10' O 0.5689(9) 0.1570(10) 0.3518(5) 0.084(4) Uani 0.65 1 d PD F 2
H10D H 0.4951 0.1809 0.3568 0.101 Uiso 0.65 1 d PR F 2
C43' C 0.651(2) 0.186(2) 0.4242(8) 0.111(10) Uani 0.65 1 d PD F 2
H43D H 0.7293 0.1882 0.4190 0.134 Uiso 0.65 1 calc PR F 2
H43E H 0.6390 0.1369 0.4463 0.134 Uiso 0.65 1 calc PR F 2
H43F H 0.6371 0.2514 0.4538 0.134 Uiso 0.65 1 calc PR F 2
N1 N 1.0196(7) 0.5400(5) 0.1148(4) 0.0460(17) Uani 1 1 d . . .
N2 N 0.7861(9) 0.2681(7) 0.2962(5) 0.073(3) Uani 1 1 d . . .
N3 N 0.5493(7) 0.0138(6) 0.1663(4) 0.057(2) Uani 1 1 d . . .
N4 N 0.0102(7) -0.0823(6) -0.1520(4) 0.0552(19) Uani 1 1 d . . .
N5 N -0.2267(7) 0.0535(7) -0.2753(5) 0.066(2) Uani 1 1 d . . .
N6 N -0.5216(8) 0.4308(6) -0.1133(4) 0.062(2) Uani 1 1 d . . .
C1 C 1.0833(8) 0.4883(6) 0.1511(4) 0.046(2) Uani 1 1 d . . .
H1A H 1.1273 0.4410 0.1273 0.055 Uiso 1 1 calc R . .
C2 C 1.0873(8) 0.5013(6) 0.2222(4) 0.047(2) Uani 1 1 d . . .
H2A H 1.1333 0.4631 0.2450 0.056 Uiso 1 1 calc R . .
C3 C 1.0230(7) 0.5714(6) 0.2602(4) 0.0398(18) Uani 1 1 d . . .
C4 C 0.9608(8) 0.6281(7) 0.2231(5) 0.050(2) Uani 1 1 d . . .
H4A H 0.9184 0.6777 0.2461 0.060 Uiso 1 1 calc R . .
C5 C 0.9614(9) 0.6110(7) 0.1519(5) 0.053(2) Uani 1 1 d . . .
H5A H 0.9194 0.6506 0.1285 0.063 Uiso 1 1 calc R . .
C6 C 1.1574(8) 0.5756(7) 0.4113(4) 0.049(2) Uani 1 1 d D . .
H6A H 1.1974 0.5247 0.3826 0.059 Uiso 1 1 calc R . .
H6B H 1.2013 0.6406 0.4233 0.059 Uiso 1 1 calc R . .
C7 C 1.1621(10) 0.5565(9) 0.4776(4) 0.072(3) Uani 1 1 d D . .
H7A H 1.2417 0.5577 0.5018 0.086 Uiso 1 1 calc R . .
H7B H 1.1218 0.4913 0.4671 0.086 Uiso 1 1 calc R . .
H7C H 1.1261 0.6077 0.5080 0.086 Uiso 1 1 calc R . .
C8 C 0.9358(9) 0.6880(7) 0.3955(4) 0.055(2) Uani 1 1 d D . .
H8A H 0.9818 0.7491 0.4007 0.066 Uiso 1 1 calc R . .
H8B H 0.8619 0.6845 0.3622 0.066 Uiso 1 1 calc R . .
C9 C 0.9137(11) 0.6982(9) 0.4646(5) 0.082(3) Uani 1 1 d D . .
H9A H 0.8754 0.7578 0.4807 0.099 Uiso 1 1 calc R . .
H9B H 0.9860 0.7036 0.4989 0.099 Uiso 1 1 calc R . .
H9C H 0.8651 0.6398 0.4603 0.099 Uiso 1 1 calc R . .
C10 C 0.9208(8) 0.4552(6) 0.3354(4) 0.0430(19) Uani 1 1 d . . .
C11 C 0.9674(10) 0.3643(7) 0.3211(5) 0.061(3) Uani 1 1 d . . .
H11A H 1.0467 0.3636 0.3243 0.073 Uiso 1 1 calc R . .
C12 C 0.8994(11) 0.2740(7) 0.3023(6) 0.068(3) Uani 1 1 d . . .
H12A H 0.9351 0.2144 0.2934 0.082 Uiso 1 1 calc R . .
C13 C 0.7393(10) 0.3553(10) 0.3109(6) 0.073(3) Uani 1 1 d . . .
H13A H 0.6600 0.3532 0.3082 0.088 Uiso 1 1 calc R . .
C14 C 0.8015(8) 0.4502(8) 0.3302(5) 0.056(2) Uani 1 1 d . . .
H14A H 0.7640 0.5088 0.3393 0.067 Uiso 1 1 calc R . .
C15 C 0.4410(10) 0.0361(7) 0.1473(5) 0.058(2) Uani 1 1 d . H .
H15A H 0.4233 0.1009 0.1703 0.069 Uiso 1 1 calc R . .
C16 C 0.3536(8) -0.0321(6) 0.0950(5) 0.051(2) Uani 1 1 d . . .
H16A H 0.2790 -0.0134 0.0841 0.061 Uiso 1 1 calc R H .
C17 C 0.3785(7) -0.1288(6) 0.0592(4) 0.0405(18) Uani 1 1 d . H .
C18 C 0.4914(7) -0.1498(6) 0.0792(5) 0.046(2) Uani 1 1 d . . .
H18A H 0.5128 -0.2131 0.0562 0.055 Uiso 1 1 calc R H .
C19 C 0.5726(8) -0.0785(7) 0.1328(5) 0.054(2) Uani 1 1 d . H .
H19A H 0.6472 -0.0960 0.1459 0.064 Uiso 1 1 calc R . .
C21 C 0.2633(15) -0.4041(12) -0.1341(9) 0.178(10) Uani 1 1 d D . .
H21A H 0.3109 -0.4522 -0.1571 0.214 Uiso 0.50 1 calc PR G 1
H21B H 0.2298 -0.3684 -0.1656 0.214 Uiso 0.50 1 calc PR G 1
H21C H 0.2025 -0.4390 -0.1238 0.214 Uiso 0.50 1 calc PR G 1
H21D H 0.2991 -0.4436 -0.1708 0.214 Uiso 0.50 1 calc PR G 2
H21E H 0.1908 -0.3859 -0.1563 0.214 Uiso 0.50 1 calc PR G 2
H21F H 0.2495 -0.4430 -0.1051 0.214 Uiso 0.50 1 calc PR G 2
C20 C 0.3334(12) -0.3331(15) -0.0680(9) 0.078(8) Uani 0.50 1 d PDU H 1
H20A H 0.3955 -0.3010 -0.0801 0.093 Uiso 0.50 1 calc PR H 1
H20B H 0.3694 -0.3717 -0.0386 0.093 Uiso 0.50 1 calc PR H 1
C22 C 0.1727(17) -0.2569(17) 0.0597(10) 0.072(6) Uani 0.50 1 d PDU H 1
H22A H 0.1047 -0.3016 0.0281 0.087 Uiso 0.50 1 calc PR H 1
H22B H 0.2206 -0.2982 0.0821 0.087 Uiso 0.50 1 calc PR H 1
C23 C 0.130(5) -0.189(4) 0.117(2) 0.26(3) Uani 0.50 1 d PDU H 1
H23A H 0.0482 -0.2056 0.1086 0.307 Uiso 0.50 1 calc PR H 1
H23B H 0.1451 -0.1206 0.1189 0.307 Uiso 0.50 1 calc PR H 1
H23C H 0.1692 -0.1953 0.1621 0.307 Uiso 0.50 1 calc PR H 1
C20' C 0.3390(13) -0.3137(13) -0.0895(9) 0.078(9) Uani 0.50 1 d PDU H 2
H20C H 0.3533 -0.2741 -0.1187 0.094 Uiso 0.50 1 calc PR H 2
H20D H 0.4129 -0.3318 -0.0678 0.094 Uiso 0.50 1 calc PR H 2
C22' C 0.1896(15) -0.3036(14) 0.0349(9) 0.057(5) Uani 0.50 1 d PDU H 2
H22C H 0.1183 -0.2741 0.0419 0.068 Uiso 0.50 1 calc PR H 2
H22D H 0.1672 -0.3715 0.0002 0.068 Uiso 0.50 1 calc PR H 2
C23' C 0.248(2) -0.314(2) 0.1022(12) 0.106(9) Uani 0.50 1 d PDU H 2
H23D H 0.1955 -0.3492 0.1182 0.127 Uiso 0.50 1 calc PR H 2
H23E H 0.2738 -0.2477 0.1376 0.127 Uiso 0.50 1 calc PR H 2
H23F H 0.3139 -0.3509 0.0957 0.127 Uiso 0.50 1 calc PR H 2
C24 C 0.1618(7) -0.1668(6) -0.0642(5) 0.047(2) Uani 1 1 d . H .
C25 C 0.0461(8) -0.2058(8) -0.0948(6) 0.061(3) Uani 1 1 d . . .
H25A H 0.0163 -0.2601 -0.0849 0.073 Uiso 1 1 calc R H .
C26 C -0.0243(8) -0.1648(8) -0.1394(6) 0.063(3) Uani 1 1 d . H .
H26A H -0.0994 -0.1957 -0.1620 0.075 Uiso 1 1 calc R . .
C27 C 0.1205(9) -0.0428(7) -0.1218(5) 0.061(3) Uani 1 1 d . H .
H27A H 0.1469 0.0137 -0.1305 0.073 Uiso 1 1 calc R . .
C28 C 0.1962(8) -0.0824(7) -0.0787(5) 0.057(2) Uani 1 1 d . . .
H28A H 0.2721 -0.0520 -0.0588 0.068 Uiso 1 1 calc R H .
C29 C -0.1969(9) 0.1351(9) -0.2897(7) 0.074(3) Uani 1 1 d . . .
H29A H -0.1183 0.1550 -0.2818 0.089 Uiso 1 1 calc R . .
C30 C -0.2769(8) 0.1914(8) -0.3158(6) 0.066(3) Uani 1 1 d . . .
H30A H -0.2512 0.2471 -0.3256 0.079 Uiso 1 1 calc R . .
C31 C -0.3940(7) 0.1666(6) -0.3274(4) 0.0435(19) Uani 1 1 d . . .
C32 C -0.4261(8) 0.0804(7) -0.3140(5) 0.054(2) Uani 1 1 d . . .
H32A H -0.5042 0.0591 -0.3218 0.065 Uiso 1 1 calc R . .
C33 C -0.3409(9) 0.0262(8) -0.2887(5) 0.063(3) Uani 1 1 d . . .
H33A H -0.3642 -0.0319 -0.2807 0.076 Uiso 1 1 calc R . .
C34 C -0.4570(8) 0.3373(7) -0.3937(5) 0.059(2) Uani 1 1 d D . .
H34A H -0.3823 0.3725 -0.3640 0.071 Uiso 1 1 calc R . .
H34B H -0.4453 0.2969 -0.4402 0.071 Uiso 1 1 calc R . .
C35 C -0.5343(11) 0.4115(8) -0.4039(7) 0.087(4) Uani 1 1 d D . .
H35A H -0.5015 0.4527 -0.4260 0.104 Uiso 1 1 calc R . .
H35B H -0.5449 0.4535 -0.3581 0.104 Uiso 1 1 calc R . .
H35C H -0.6080 0.3777 -0.4345 0.104 Uiso 1 1 calc R . .
C36 C -0.6455(8) 0.1693(7) -0.4083(4) 0.053(2) Uani 1 1 d D . .
H36A H -0.6736 0.1327 -0.3811 0.063 Uiso 1 1 calc R . .
H36B H -0.7034 0.2136 -0.4182 0.063 Uiso 1 1 calc R . .
C37 C -0.6358(10) 0.0974(8) -0.4760(4) 0.075(3) Uani 1 1 d D . .
H37A H -0.7100 0.0598 -0.5016 0.090 Uiso 1 1 calc R . .
H37B H -0.5803 0.0518 -0.4671 0.090 Uiso 1 1 calc R . .
H37C H -0.6105 0.1328 -0.5043 0.090 Uiso 1 1 calc R . .
C38 C -0.5236(8) 0.3282(6) -0.2587(4) 0.048(2) Uani 1 1 d . . .
C39 C -0.6004(8) 0.2973(7) -0.2243(5) 0.050(2) Uani 1 1 d . . .
H39A H -0.6542 0.2409 -0.2498 0.060 Uiso 1 1 calc R . .
C40 C -0.5968(8) 0.3494(7) -0.1531(5) 0.050(2) Uani 1 1 d . . .
H40A H -0.6490 0.3271 -0.1318 0.060 Uiso 1 1 calc R . .
C41 C -0.4506(12) 0.4638(9) -0.1466(6) 0.087(4) Uani 1 1 d . . .
H41A H -0.3986 0.5212 -0.1205 0.105 Uiso 1 1 calc R . .
C42 C -0.4524(11) 0.4154(9) -0.2177(6) 0.084(4) Uani 1 1 d . . .
H42A H -0.4038 0.4426 -0.2388 0.100 Uiso 1 1 calc R . .
C44 C 0.2747(12) 0.2259(11) 0.0493(7) 0.080(4) Uani 1 1 d . . .
C45 C 0.0566(8) -0.0109(9) 0.6045(6) 0.109(6) Uani 1 1 d D A .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N1 179.999(1) 2_765 .
N2 Ag2 N3 152.6(3) . .
N2 Ag2 O6' 94.3(13) . 2_656
N3 Ag2 O6' 104.6(13) . 2_656
N5 Ag3 N4 171.3(3) . .
N6 Ag4 N6 179.998(1) . 2_465
C6 Si1 C8 112.5(4) . .
C6 Si1 C10 108.5(4) . .
C8 Si1 C10 110.1(4) . .
C6 Si1 C3 111.0(4) . .
C8 Si1 C3 111.0(4) . .
C10 Si1 C3 103.4(3) . .
C24 Si2 C17 108.8(4) . .
C24 Si2 C22' 114.5(7) . .
C17 Si2 C22' 111.2(6) . .
C24 Si2 C20 111.9(8) . .
C17 Si2 C20 110.2(5) . .
C22' Si2 C20 99.9(12) . .
C24 Si2 C22 105.3(7) . .
C17 Si2 C22 98.6(7) . .
C22' Si2 C22 21.2(7) . .
C20 Si2 C22 120.9(11) . .
C24 Si2 C20' 98.4(8) . .
C17 Si2 C20' 107.8(5) . .
C22' Si2 C20' 115.2(9) . .
C20 Si2 C20' 16.6(11) . .
C22 Si2 C20' 136.4(9) . .
C36 Si3 C34 111.8(4) . .
C36 Si3 C38 112.3(4) . .
C34 Si3 C38 108.2(4) . .
C36 Si3 C31 109.9(4) . .
C34 Si3 C31 112.9(4) . .
C38 Si3 C31 101.3(4) . .
O3 S1 O2 117.7(6) . .
O3 S1 O1 115.3(5) . .
O2 S1 O1 111.9(5) . .
O3 S1 C44 103.1(5) . .
O2 S1 C44 101.5(6) . .
O1 S1 C44 105.0(6) . .
O5' S2 O6' 100(4) . .
O5' S2 O4 82(3) . .
O6' S2 O4 149(2) . .
O5' S2 O6 137(3) . .
O6' S2 O6 40(2) . .
O4 S2 O6 122.4(8) . .
O5' S2 O5 31(3) . .
O6' S2 O5 72(2) . .
O4 S2 O5 113.1(7) . .
O6 S2 O5 111.6(7) . .
O5' S2 O4' 128(4) . .
O6' S2 O4' 98(3) . .
O4 S2 O4' 58.5(14) . .
O6 S2 O4' 64.0(15) . .
O5 S2 O4' 142.9(12) . .
O5' S2 C45 107(3) . .
O6' S2 C45 107(2) . .
O4 S2 C45 101.7(6) . .
O6 S2 C45 101.4(6) . .
O5 S2 C45 103.2(5) . .
O4' S2 C45 113.8(11) . .
O8 S3 O9 102.7(18) . .
O8 S3 O7 122.5(8) . .
O9 S3 O7 124(2) . .
O8 S3 O9' 123(2) . .
O9 S3 O9' 20(3) . .
O7 S3 O9' 108(3) . .
O8 S3 O8' 31.7(11) . .
O9 S3 O8' 108(2) . .
O7 S3 O8' 97.3(10) . .
O9' S3 O8' 126(2) . .
O8 S3 C46' 81.9(19) . .
O9 S3 C46' 101(3) . .
O7 S3 C46' 115(3) . .
O9' S3 C46' 100(3) . .
O8' S3 C46' 110.9(17) . .
O8 S3 C46 100.3(11) . .
O9 S3 C46 108(2) . .
O7 S3 C46 94.9(8) . .
O9' S3 C46 99(3) . .
O8' S3 C46 125.0(13) . .
C46' S3 C46 22(3) . .
C45 F4' F5' 48.3(13) . .
C45 F5' F4' 48.4(13) . .
C46 F7 C46' 26(2) . .
F9 C46 F8 97.6(17) . .
F9 C46 F7 97.1(15) . .
F8 C46 F7 105.5(13) . .
F9 C46 S3 114.2(17) . .
F8 C46 S3 119.5(11) . .
F7 C46 S3 118.8(8) . .
F9' C46' F7 95(4) . .
F9' C46' F8' 109(4) . .
F7 C46' F8' 98.5(19) . .
F9' C46' S3 127(3) . .
F7 C46' S3 113(4) . .
F8' C46' S3 111(4) . .
S2 O6' Ag2 145(4) . 2_656
C43 O10 H10A 108.2 . .
O10 C43 H43A 109.5 . .
O10 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
O10 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C43' O10' H10A 94.1 . .
C43' O10' H10D 109.6 . .
H10A O10' H10D 108.0 . .
O10' C43' H43D 109.5 . .
O10' C43' H43E 109.5 . .
H43D C43' H43E 109.5 . .
O10' C43' H43F 109.5 . .
H43D C43' H43F 109.5 . .
H43E C43' H43F 109.5 . .
C1 N1 C5 116.6(7) . .
C1 N1 Ag1 120.5(6) . .
C5 N1 Ag1 122.6(6) . .
C12 N2 C13 116.4(9) . .
C12 N2 Ag2 121.6(8) . .
C13 N2 Ag2 121.5(8) . .
C19 N3 C15 117.3(8) . .
C19 N3 Ag2 121.8(7) . .
C15 N3 Ag2 120.9(6) . .
C27 N4 C26 117.1(8) . .
C27 N4 Ag3 121.4(6) . .
C26 N4 Ag3 121.5(6) . .
C29 N5 C33 116.6(8) . .
C29 N5 Ag3 122.7(7) . .
C33 N5 Ag3 120.2(7) . .
C40 N6 C41 117.1(8) . .
C40 N6 Ag4 122.9(6) . .
C41 N6 Ag4 119.7(7) . .
N1 C1 C2 123.3(8) . .
N1 C1 H1A 118.4 . .
C2 C1 H1A 118.4 . .
C1 C2 C3 120.5(8) . .
C1 C2 H2A 119.7 . .
C3 C2 H2A 119.7 . .
C4 C3 C2 115.9(7) . .
C4 C3 Si1 123.2(6) . .
C2 C3 Si1 120.6(6) . .
C5 C4 C3 120.2(8) . .
C5 C4 H4A 119.9 . .
C3 C4 H4A 119.9 . .
N1 C5 C4 123.3(8) . .
N1 C5 H5A 118.3 . .
C4 C5 H5A 118.3 . .
C7 C6 Si1 118.2(7) . .
C7 C6 H6A 107.8 . .
Si1 C6 H6A 107.8 . .
C7 C6 H6B 107.8 . .
Si1 C6 H6B 107.8 . .
H6A C6 H6B 107.1 . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C9 C8 Si1 117.3(7) . .
C9 C8 H8A 108.0 . .
Si1 C8 H8A 108.0 . .
C9 C8 H8B 108.0 . .
Si1 C8 H8B 108.0 . .
H8A C8 H8B 107.2 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C11 C10 C14 115.8(8) . .
C11 C10 Si1 121.4(7) . .
C14 C10 Si1 122.7(7) . .
C10 C11 C12 121.7(10) . .
C10 C11 H11A 119.2 . .
C12 C11 H11A 119.2 . .
N2 C12 C11 123.1(11) . .
N2 C12 H12A 118.4 . .
C11 C12 H12A 118.4 . .
N2 C13 C14 124.3(11) . .
N2 C13 H13A 117.8 . .
C14 C13 H13A 117.8 . .
C10 C14 C13 118.8(10) . .
C10 C14 H14A 120.6 . .
C13 C14 H14A 120.6 . .
N3 C15 C16 123.4(8) . .
N3 C15 H15A 118.3 . .
C16 C15 H15A 118.3 . .
C15 C16 C17 119.3(8) . .
C15 C16 H16A 120.4 . .
C17 C16 H16A 120.4 . .
C18 C17 C16 116.3(8) . .
C18 C17 Si2 121.5(6) . .
C16 C17 Si2 122.2(7) . .
C19 C18 C17 120.9(8) . .
C19 C18 H18A 119.5 . .
C17 C18 H18A 119.5 . .
N3 C19 C18 122.8(9) . .
N3 C19 H19A 118.6 . .
C18 C19 H19A 118.6 . .
C20 C21 C20' 23.9(15) . .
C20 C21 H21A 109.5 . .
C20' C21 H21A 106.9 . .
C20 C21 H21B 109.5 . .
C20' C21 H21B 88.9 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
C20' C21 H21C 130.0 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C20 C21 H21D 120.3 . .
C20' C21 H21D 109.5 . .
H21A C21 H21D 20.5 . .
H21B C21 H21D 89.0 . .
H21C C21 H21D 116.7 . .
C20 C21 H21E 119.2 . .
C20' C21 H21E 109.5 . .
H21A C21 H21E 127.5 . .
H21B C21 H21E 37.1 . .
H21C C21 H21E 72.7 . .
H21D C21 H21E 109.5 . .
C20 C21 H21F 85.5 . .
C20' C21 H21F 109.5 . .
H21A C21 H21F 92.1 . .
H21B C21 H21F 146.5 . .
H21C C21 H21F 37.5 . .
H21D C21 H21F 109.5 . .
H21E C21 H21F 109.5 . .
C21 C20 Si2 119.5(10) . .
C21 C20 H20A 107.4 . .
Si2 C20 H20A 107.4 . .
C21 C20 H20B 107.4 . .
Si2 C20 H20B 107.4 . .
H20A C20 H20B 107.0 . .
C23 C22 Si2 131(3) . .
C23 C22 H22A 104.5 . .
Si2 C22 H22A 104.5 . .
C23 C22 H22B 104.5 . .
Si2 C22 H22B 104.5 . .
H22A C22 H22B 105.7 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C20' Si2 109.8(9) . .
C21 C20' H20C 109.7 . .
Si2 C20' H20C 109.7 . .
C21 C20' H20D 109.7 . .
Si2 C20' H20D 109.7 . .
H20C C20' H20D 108.2 . .
C23' C22' Si2 121.3(15) . .
C23' C22' H22C 107.0 . .
Si2 C22' H22C 107.0 . .
C23' C22' H22D 107.0 . .
Si2 C22' H22D 107.0 . .
H22C C22' H22D 106.8 . .
C22' C23' H23D 109.5 . .
C22' C23' H23E 109.5 . .
H23D C23' H23E 109.5 . .
C22' C23' H23F 109.5 . .
H23D C23' H23F 109.5 . .
H23E C23' H23F 109.5 . .
C28 C24 C25 115.5(8) . .
C28 C24 Si2 123.2(6) . .
C25 C24 Si2 121.2(7) . .
C26 C25 C24 120.4(9) . .
C26 C25 H25A 119.8 . .
C24 C25 H25A 119.8 . .
N4 C26 C25 123.0(9) . .
N4 C26 H26A 118.5 . .
C25 C26 H26A 118.5 . .
N4 C27 C28 122.6(9) . .
N4 C27 H27A 118.7 . .
C28 C27 H27A 118.7 . .
C27 C28 C24 121.2(8) . .
C27 C28 H28A 119.4 . .
C24 C28 H28A 119.4 . .
N5 C29 C30 123.0(10) . .
N5 C29 H29A 118.5 . .
C30 C29 H29A 118.5 . .
C31 C30 C29 121.2(9) . .
C31 C30 H30A 119.4 . .
C29 C30 H30A 119.4 . .
C30 C31 C32 116.3(8) . .
C30 C31 Si3 123.5(7) . .
C32 C31 Si3 119.9(7) . .
C31 C32 C33 119.6(9) . .
C31 C32 H32A 120.2 . .
C33 C32 H32A 120.2 . .
N5 C33 C32 123.3(9) . .
N5 C33 H33A 118.3 . .
C32 C33 H33A 118.3 . .
C35 C34 Si3 115.2(7) . .
C35 C34 H34A 108.5 . .
Si3 C34 H34A 108.5 . .
C35 C34 H34B 108.5 . .
Si3 C34 H34B 108.5 . .
H34A C34 H34B 107.5 . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C37 C36 Si3 115.3(7) . .
C37 C36 H36A 108.4 . .
Si3 C36 H36A 108.4 . .
C37 C36 H36B 108.4 . .
Si3 C36 H36B 108.4 . .
H36A C36 H36B 107.5 . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C42 C38 C39 115.0(8) . .
C42 C38 Si3 121.9(7) . .
C39 C38 Si3 122.8(7) . .
C40 C39 C38 120.7(8) . .
C40 C39 H39A 119.7 . .
C38 C39 H39A 119.7 . .
N6 C40 C39 122.8(8) . .
N6 C40 H40A 118.6 . .
C39 C40 H40A 118.6 . .
N6 C41 C42 122.2(10) . .
N6 C41 H41A 118.9 . .
C42 C41 H41A 118.9 . .
C41 C42 C38 122.0(10) . .
C41 C42 H42A 119.0 . .
C38 C42 H42A 119.0 . .
F1 C44 F2 106.9(10) . .
F1 C44 F3 111.5(12) . .
F2 C44 F3 102.7(11) . .
F1 C44 S1 111.4(9) . .
F2 C44 S1 111.9(10) . .
F3 C44 S1 112.1(8) . .
F6' C45 F4 106(3) . .
F6' C45 F5 77(2) . .
F4 C45 F5 125.7(18) . .
F6' C45 F5' 104.2(8) . .
F4 C45 F5' 110(3) . .
F5 C45 F5' 28(2) . .
F6' C45 F6 24(2) . .
F4 C45 F6 92.7(18) . .
F5 C45 F6 101.2(13) . .
F5' C45 F6 128(2) . .
F6' C45 F4' 132(3) . .
F4 C45 F4' 32.1(15) . .
F5 C45 F4' 107.2(19) . .
F5' C45 F4' 83(3) . .
F6 C45 F4' 124(2) . .
F6' C45 S2 116(3) . .
F4 C45 S2 113.2(11) . .
F5 C45 S2 112.8(10) . .
F5' C45 S2 107(2) . .
F6 C45 S2 105.7(13) . .
F4' C45 S2 106.0(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.161(6) 2_765
Ag1 N1 2.162(6) .
Ag2 N2 2.164(8) .
Ag2 N3 2.165(7) .
Ag2 O6' 2.33(5) 2_656
Ag3 N5 2.123(8) .
Ag3 N4 2.140(7) .
Ag4 N6 2.131(7) .
Ag4 N6 2.131(7) 2_465
Si1 C6 1.869(9) .
Si1 C8 1.874(9) .
Si1 C10 1.884(8) .
Si1 C3 1.897(8) .
Si2 C24 1.878(9) .
Si2 C17 1.886(8) .
Si2 C22' 1.8993(15) .
Si2 C20 1.8997(15) .
Si2 C22 2.070(2) .
Si2 C20' 2.070(2) .
Si3 C36 1.873(9) .
Si3 C34 1.879(9) .
Si3 C38 1.883(8) .
Si3 C31 1.889(9) .
S1 O3 1.409(8) .
S1 O2 1.415(8) .
S1 O1 1.424(7) .
S1 C44 1.804(11) .
S2 O5' 1.27(8) .
S2 O6' 1.36(5) .
S2 O4 1.391(9) .
S2 O6 1.403(9) .
S2 O5 1.466(10) .
S2 O4' 1.70(4) .
S2 C45 1.828(12) .
S3 O8 1.327(16) .
S3 O9 1.38(4) .
S3 O7 1.419(8) .
S3 O9' 1.50(4) .
S3 O8' 1.58(3) .
S3 C46' 1.653(5) .
S3 C46 1.668(5) .
F1 C44 1.301(15) .
F2 C44 1.310(15) .
F3 C44 1.326(13) .
F4 C45 1.300(4) .
F5 C45 1.301(5) .
F6 C45 1.301(5) .
F4' C45 1.302(5) .
F4' F5' 1.73(4) .
F5' C45 1.301(5) .
F6' C45 1.299(4) .
F7 C46 1.330(5) .
F7 C46' 1.45(8) .
F8 C46 1.329(5) .
F9 C46 1.326(5) .
F8' C46' 1.49(7) .
F9' C46' 1.323(5) .
O6' Ag2 2.33(5) 2_656
O10 C43 1.491(5) .
O10 H10A 0.9600 .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
O10' C43' 1.489(4) .
O10' H10A 1.1323 .
O10' H10D 0.9600 .
C43' H43D 0.9600 .
C43' H43E 0.9600 .
C43' H43F 0.9600 .
N1 C1 1.331(10) .
N1 C5 1.345(11) .
N2 C12 1.321(14) .
N2 C13 1.330(15) .
N3 C19 1.321(12) .
N3 C15 1.334(13) .
N4 C27 1.337(12) .
N4 C26 1.338(12) .
N5 C29 1.331(13) .
N5 C33 1.342(13) .
N6 C40 1.336(12) .
N6 C41 1.348(13) .
C1 C2 1.380(11) .
C1 H1A 0.9300 .
C2 C3 1.394(12) .
C2 H2A 0.9300 .
C3 C4 1.386(11) .
C4 C5 1.382(12) .
C4 H4A 0.9300 .
C5 H5A 0.9300 .
C6 C7 1.442(2) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 C9 1.442(2) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 C11 1.374(13) .
C10 C14 1.395(13) .
C11 C12 1.380(13) .
C11 H11A 0.9300 .
C12 H12A 0.9300 .
C13 C14 1.400(14) .
C13 H13A 0.9300 .
C14 H14A 0.9300 .
C15 C16 1.385(13) .
C15 H15A 0.9300 .
C16 C17 1.389(12) .
C16 H16A 0.9300 .
C17 C18 1.381(11) .
C18 C19 1.374(12) .
C18 H18A 0.9300 .
C19 H19A 0.9300 .
C21 C20 1.4398(15) .
C21 C20' 1.440(2) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C21 H21D 0.9600 .
C21 H21E 0.9600 .
C21 H21F 0.9600 .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C22 C23 1.4396(15) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C20' H20C 0.9700 .
C20' H20D 0.9700 .
C22' C23' 1.440(2) .
C22' H22C 0.9700 .
C22' H22D 0.9700 .
C23' H23D 0.9600 .
C23' H23E 0.9600 .
C23' H23F 0.9600 .
C24 C28 1.385(12) .
C24 C25 1.392(12) .
C25 C26 1.370(13) .
C25 H25A 0.9300 .
C26 H26A 0.9300 .
C27 C28 1.368(12) .
C27 H27A 0.9300 .
C28 H28A 0.9300 .
C29 C30 1.377(14) .
C29 H29A 0.9300 .
C30 C31 1.374(13) .
C30 H30A 0.9300 .
C31 C32 1.388(12) .
C32 C33 1.389(13) .
C32 H32A 0.9300 .
C33 H33A 0.9300 .
C34 C35 1.442(2) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 C37 1.442(2) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 C42 1.371(13) .
C38 C39 1.402(12) .
C39 C40 1.377(12) .
C39 H39A 0.9300 .
C40 H40A 0.9300 .
C41 C42 1.371(14) .
C41 H41A 0.9300 .
C42 H42A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C46' F7 C46 F9 -48(3) . .
C46' F7 C46 F8 -148(3) . .
C46' F7 C46 S3 75(2) . .
O8 S3 C46 F9 66.1(17) . .
O9 S3 C46 F9 -41(2) . .
O7 S3 C46 F9 -169.6(15) . .
O9' S3 C46 F9 -60(3) . .
O8' S3 C46 F9 87.9(19) . .
C46' S3 C46 F9 33(5) . .
O8 S3 C46 F8 -178.9(15) . .
O9 S3 C46 F8 74(2) . .
O7 S3 C46 F8 -54.6(15) . .
O9' S3 C46 F8 55(3) . .
O8' S3 C46 F8 -157.1(16) . .
C46' S3 C46 F8 148(6) . .
O8 S3 C46 F7 -47.5(19) . .
O9 S3 C46 F7 -155(2) . .
O7 S3 C46 F7 76.8(17) . .
O9' S3 C46 F7 -174(3) . .
O8' S3 C46 F7 -26(2) . .
C46' S3 C46 F7 -81(5) . .
C46 F7 C46' F9' 66(3) . .
C46 F7 C46' F8' 175(3) . .
C46 F7 C46' S3 -68(4) . .
O8 S3 C46' F9' 157(8) . .
O9 S3 C46' F9' 55(8) . .
O7 S3 C46' F9' -81(8) . .
O9' S3 C46' F9' 35(8) . .
O8' S3 C46' F9' 170(7) . .
C46 S3 C46' F9' -56(4) . .
O8 S3 C46' F7 -88(3) . .
O9 S3 C46' F7 171(3) . .
O7 S3 C46' F7 34(3) . .
O9' S3 C46' F7 150(3) . .
O8' S3 C46' F7 -75(4) . .
C46 S3 C46' F7 59(7) . .
O8 S3 C46' F8' 21(4) . .
O9 S3 C46' F8' -80(4) . .
O7 S3 C46' F8' 144(4) . .
O9' S3 C46' F8' -101(4) . .
O8' S3 C46' F8' 34(5) . .
C46 S3 C46' F8' 168(9) . .
O5' S2 O6' Ag2 -10(6) . 2_656
O4 S2 O6' Ag2 -103(6) . 2_656
O6 S2 O6' Ag2 -171(8) . 2_656
O5 S2 O6' Ag2 2(4) . 2_656
O4' S2 O6' Ag2 -141(5) . 2_656
C45 S2 O6' Ag2 101(5) . 2_656
N1 Ag1 N1 C1 -91(37) 2_765 .
N1 Ag1 N1 C5 95(37) 2_765 .
N3 Ag2 N2 C12 -109.7(11) . .
O6' Ag2 N2 C12 24.0(15) 2_656 .
N3 Ag2 N2 C13 61.5(12) . .
O6' Ag2 N2 C13 -164.8(15) 2_656 .
N2 Ag2 N3 C19 120.3(9) . .
O6' Ag2 N3 C19 -11.5(15) 2_656 .
N2 Ag2 N3 C15 -61.0(12) . .
O6' Ag2 N3 C15 167.2(15) 2_656 .
N5 Ag3 N4 C27 -98(2) . .
N5 Ag3 N4 C26 85(2) . .
N4 Ag3 N5 C29 101(2) . .
N4 Ag3 N5 C33 -71(2) . .
N6 Ag4 N6 C40 7(22) 2_465 .
N6 Ag4 N6 C41 -167(22) 2_465 .
C5 N1 C1 C2 3.0(13) . .
Ag1 N1 C1 C2 -171.4(7) . .
N1 C1 C2 C3 -0.1(13) . .
C1 C2 C3 C4 -2.6(12) . .
C1 C2 C3 Si1 171.5(7) . .
C6 Si1 C3 C4 -139.3(7) . .
C8 Si1 C3 C4 -13.4(9) . .
C10 Si1 C3 C4 104.6(8) . .
C6 Si1 C3 C2 47.1(8) . .
C8 Si1 C3 C2 173.0(7) . .
C10 Si1 C3 C2 -69.0(8) . .
C2 C3 C4 C5 2.3(13) . .
Si1 C3 C4 C5 -171.6(7) . .
C1 N1 C5 C4 -3.2(14) . .
Ag1 N1 C5 C4 171.0(7) . .
C3 C4 C5 N1 0.6(15) . .
C8 Si1 C6 C7 68.7(9) . .
C10 Si1 C6 C7 -53.3(9) . .
C3 Si1 C6 C7 -166.3(8) . .
C6 Si1 C8 C9 -59.0(10) . .
C10 Si1 C8 C9 62.1(10) . .
C3 Si1 C8 C9 175.9(8) . .
C6 Si1 C10 C11 -40.6(8) . .
C8 Si1 C10 C11 -164.1(7) . .
C3 Si1 C10 C11 77.2(8) . .
C6 Si1 C10 C14 144.4(7) . .
C8 Si1 C10 C14 20.9(8) . .
C3 Si1 C10 C14 -97.7(7) . .
C14 C10 C11 C12 0.6(13) . .
Si1 C10 C11 C12 -174.8(8) . .
C13 N2 C12 C11 -1.5(16) . .
Ag2 N2 C12 C11 170.2(8) . .
C10 C11 C12 N2 0.4(16) . .
C12 N2 C13 C14 1.7(16) . .
Ag2 N2 C13 C14 -169.9(7) . .
C11 C10 C14 C13 -0.4(12) . .
Si1 C10 C14 C13 174.9(7) . .
N2 C13 C14 C10 -0.8(15) . .
C19 N3 C15 C16 0.2(14) . .
Ag2 N3 C15 C16 -178.6(7) . .
N3 C15 C16 C17 -0.9(14) . .
C15 C16 C17 C18 0.1(13) . .
C15 C16 C17 Si2 177.0(7) . .
C24 Si2 C17 C18 -144.7(7) . .
C22' Si2 C17 C18 88.2(10) . .
C20 Si2 C17 C18 -21.6(12) . .
C22 Si2 C17 C18 105.8(9) . .
C20' Si2 C17 C18 -39.0(11) . .
C24 Si2 C17 C16 38.6(8) . .
C22' Si2 C17 C16 -88.5(10) . .
C20 Si2 C17 C16 161.7(12) . .
C22 Si2 C17 C16 -70.9(9) . .
C20' Si2 C17 C16 144.3(10) . .
C16 C17 C18 C19 1.2(13) . .
Si2 C17 C18 C19 -175.6(7) . .
C15 N3 C19 C18 1.3(14) . .
Ag2 N3 C19 C18 -180.0(7) . .
C17 C18 C19 N3 -2.0(14) . .
C20' C21 C20 Si2 93(2) . .
C24 Si2 C20 C21 -44(3) . .
C17 Si2 C20 C21 -165(2) . .
C22' Si2 C20 C21 78(2) . .
C22 Si2 C20 C21 81(3) . .
C20' Si2 C20 C21 -80.8(17) . .
C24 Si2 C22 C23 -64(4) . .
C17 Si2 C22 C23 48(4) . .
C22' Si2 C22 C23 177(5) . .
C20 Si2 C22 C23 168(4) . .
C20' Si2 C22 C23 175(4) . .
C20 C21 C20' Si2 -57.9(5) . .
C24 Si2 C20' C21 -80.1(17) . .
C17 Si2 C20' C21 167.0(15) . .
C22' Si2 C20' C21 42(2) . .
C20 Si2 C20' C21 65.9(8) . .
C22 Si2 C20' C21 43(2) . .
C24 Si2 C22' C23' -150(2) . .
C17 Si2 C22' C23' -26(2) . .
C20 Si2 C22' C23' 91(2) . .
C22 Si2 C22' C23' -82(3) . .
C20' Si2 C22' C23' 97(2) . .
C17 Si2 C24 C28 30.7(9) . .
C22' Si2 C24 C28 155.8(10) . .
C20 Si2 C24 C28 -91.3(11) . .
C22 Si2 C24 C28 135.6(10) . .
C20' Si2 C24 C28 -81.4(9) . .
C17 Si2 C24 C25 -151.2(8) . .
C22' Si2 C24 C25 -26.0(11) . .
C20 Si2 C24 C25 86.8(11) . .
C22 Si2 C24 C25 -46.3(11) . .
C20' Si2 C24 C25 96.7(9) . .
C28 C24 C25 C26 3.7(15) . .
Si2 C24 C25 C26 -174.6(8) . .
C27 N4 C26 C25 3.5(16) . .
Ag3 N4 C26 C25 -179.1(8) . .
C24 C25 C26 N4 -4.9(17) . .
C26 N4 C27 C28 -1.2(16) . .
Ag3 N4 C27 C28 -178.6(8) . .
N4 C27 C28 C24 0.3(17) . .
C25 C24 C28 C27 -1.5(15) . .
Si2 C24 C28 C27 176.8(8) . .
C33 N5 C29 C30 1.2(18) . .
Ag3 N5 C29 C30 -170.7(9) . .
N5 C29 C30 C31 1.0(19) . .
C29 C30 C31 C32 -2.2(16) . .
C29 C30 C31 Si3 171.4(9) . .
C36 Si3 C31 C30 149.7(8) . .
C34 Si3 C31 C30 24.1(10) . .
C38 Si3 C31 C30 -91.4(9) . .
C36 Si3 C31 C32 -37.0(8) . .
C34 Si3 C31 C32 -162.6(7) . .
C38 Si3 C31 C32 82.0(8) . .
C30 C31 C32 C33 1.3(14) . .
Si3 C31 C32 C33 -172.5(7) . .
C29 N5 C33 C32 -2.2(16) . .
Ag3 N5 C33 C32 169.9(8) . .
C31 C32 C33 N5 1.0(16) . .
C36 Si3 C34 C35 63.3(10) . .
C38 Si3 C34 C35 -60.8(10) . .
C31 Si3 C34 C35 -172.1(8) . .
C34 Si3 C36 C37 66.0(9) . .
C38 Si3 C36 C37 -172.2(8) . .
C31 Si3 C36 C37 -60.2(9) . .
C36 Si3 C38 C42 -156.8(10) . .
C34 Si3 C38 C42 -32.9(11) . .
C31 Si3 C38 C42 86.0(10) . .
C36 Si3 C38 C39 29.8(9) . .
C34 Si3 C38 C39 153.6(8) . .
C31 Si3 C38 C39 -87.4(8) . .
C42 C38 C39 C40 -3.6(14) . .
Si3 C38 C39 C40 170.3(7) . .
C41 N6 C40 C39 2.8(15) . .
Ag4 N6 C40 C39 -171.5(7) . .
C38 C39 C40 N6 -0.2(14) . .
C40 N6 C41 C42 -1(2) . .
Ag4 N6 C41 C42 173.0(11) . .
N6 C41 C42 C38 -3(2) . .
C39 C38 C42 C41 4.9(19) . .
Si3 C38 C42 C41 -169.0(11) . .
O3 S1 C44 F1 -54.8(11) . .
O2 S1 C44 F1 67.5(10) . .
O1 S1 C44 F1 -175.8(9) . .
O3 S1 C44 F2 64.7(10) . .
O2 S1 C44 F2 -172.9(9) . .
O1 S1 C44 F2 -56.3(10) . .
O3 S1 C44 F3 179.5(11) . .
O2 S1 C44 F3 -58.2(12) . .
O1 S1 C44 F3 58.4(12) . .
F4' F5' C45 F6' 131(3) . .
F4' F5' C45 F4 18.3(19) . .
F4' F5' C45 F5 148(6) . .
F4' F5' C45 F6 129(3) . .
F4' F5' C45 S2 -104.8(16) . .
F5' F4' C45 F6' -103(2) . .
F5' F4' C45 F4 -146(4) . .
F5' F4' C45 F5 -15(3) . .
F5' F4' C45 F6 -132(3) . .
F5' F4' C45 S2 105(2) . .
O5' S2 C45 F6' 74(4) . .
O6' S2 C45 F6' -33(3) . .
O4 S2 C45 F6' 159(2) . .
O6 S2 C45 F6' -74(2) . .
O5 S2 C45 F6' 42(2) . .
O4' S2 C45 F6' -140(3) . .
O5' S2 C45 F4 -163(4) . .
O6' S2 C45 F4 90(3) . .
O4 S2 C45 F4 -77.6(15) . .
O6 S2 C45 F4 49.3(16) . .
O5 S2 C45 F4 164.9(14) . .
O4' S2 C45 F4 -17(2) . .
O5' S2 C45 F5 -13(4) . .
O6' S2 C45 F5 -119(3) . .
O4 S2 C45 F5 72.7(17) . .
O6 S2 C45 F5 -160.4(17) . .
O5 S2 C45 F5 -44.7(17) . .
O4' S2 C45 F5 133(2) . .
O5' S2 C45 F5' -42(4) . .
O6' S2 C45 F5' -149(3) . .
O4 S2 C45 F5' 43(2) . .
O6 S2 C45 F5' 170(2) . .
O5 S2 C45 F5' -74(2) . .
O4' S2 C45 F5' 104(3) . .
O5' S2 C45 F6 97(4) . .
O6' S2 C45 F6 -10(3) . .
O4 S2 C45 F6 -177.6(16) . .
O6 S2 C45 F6 -50.7(16) . .
O5 S2 C45 F6 65.0(16) . .
O4' S2 C45 F6 -117(2) . .
O5' S2 C45 F4' -130(4) . .
O6' S2 C45 F4' 124(3) . .
O4 S2 C45 F4' -44.3(17) . .
O6 S2 C45 F4' 82.6(17) . .
O5 S2 C45 F4' -161.8(16) . .
O4' S2 C45 F4' 16(2) . .
