#------------------------------------------------------------------------------
#$Date: 2017-06-17 05:23:04 +0300 (Sat, 17 Jun 2017) $
#$Revision: 197902 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/33/7043357.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043357
loop_
_publ_author_name
'Gebauer, Ireen'
'Gräsing, Daniel'
'Matysik, Jörg'
'Zahn, Stefan'
'Zeckert, Kornelia'
_publ_section_title
;
 Penta- and hexaorganostannate(iv) complexes based on O-heterocyclic
 ligands
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT01336A
_journal_year                    2017
_chemical_formula_moiety         'C32 H38 Li2 O8 Sn'
_chemical_formula_sum            'C32 H38 Li2 O8 Sn'
_chemical_formula_weight         683.19
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2016-09-14T09:19:09-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2017-03-06 deposited with the CCDC.
2017-05-30 downloaded from the CCDC.
;
_cell_angle_alpha                101.143(3)
_cell_angle_beta                 90.176(3)
_cell_angle_gamma                102.155(3)
_cell_formula_units_Z            2
_cell_length_a                   9.5043(4)
_cell_length_b                   10.5786(4)
_cell_length_c                   16.1355(5)
_cell_measurement_reflns_used    8767
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      32.531
_cell_measurement_theta_min      2.792
_cell_volume                     1554.41(10)
_computing_cell_refinement
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.34a (release 02-06-2014 CrysAlis171 .NET)
        (compiled Jun  2 2014,16:24:16)
;
_computing_data_collection
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.34a (release 02-06-2014 CrysAlis171 .NET)
        (compiled Jun  2 2014,16:24:16)
;
_computing_data_reduction
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.34a (release 02-06-2014 CrysAlis171 .NET)
        (compiled Jun  2 2014,16:24:16)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution
;
            SHELXS-97
            Program for Crystal Structure Analysis (Release 97-2)
            G. M. Sheldrick, Institut für Anorganische Chemie der Universität,
            Tammanstrasse 4, D-3400 Göttingen, Germany, 1998.
;
_diffrn_ambient_temperature      130(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.356
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0273134
_diffrn_orient_matrix_UB_12      -0.0438339
_diffrn_orient_matrix_UB_13      -0.0383718
_diffrn_orient_matrix_UB_21      0.0637555
_diffrn_orient_matrix_UB_22      -0.0250991
_diffrn_orient_matrix_UB_23      -0.0023627
_diffrn_orient_matrix_UB_31      -0.0320821
_diffrn_orient_matrix_UB_32      -0.0484319
_diffrn_orient_matrix_UB_33      0.0230991
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0214
_diffrn_reflns_av_unetI/netI     0.0393
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            17098
_diffrn_reflns_theta_full        30.51
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.49
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.871
_exptl_absorpt_correction_T_max  0.8451
_exptl_absorpt_correction_T_min  0.8451
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.34a (release 02-06-2014 CrysAlis171 .NET)
        (compiled Jun  2 2014,16:24:16)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.46
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             700
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.941
_refine_diff_density_min         -0.511
_refine_diff_density_rms         0.076
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     395
_refine_ls_number_reflns         9487
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0483
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0266P)²+0.3712P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0635
_refine_ls_wR_factor_ref         0.0697
_reflns_number_gt                7067
_reflns_number_total             9487
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt01336a2.cif
_cod_data_source_block           x2129
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7043357
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.1447(2) 0.29831(18) 0.50166(12) 0.0188(4) Uani 1 1 d .
C2 C -0.1453(3) 0.1775(2) 0.45593(14) 0.0310(5) Uani 1 1 d .
H2 H -0.0806 0.1582 0.4128 0.037 Uiso 1 1 calc R
C3 C -0.2581(3) 0.0823(2) 0.48209(14) 0.0298(5) Uani 1 1 d .
H3 H -0.282 -0.01 0.46 0.036 Uiso 1 1 calc R
C4 C -0.3225(2) 0.14831(19) 0.54309(13) 0.0241(4) Uani 1 1 d .
H4 H -0.4018 0.1103 0.5725 0.029 Uiso 1 1 calc R
C5 C -0.0432(2) 0.47240(18) 0.35928(12) 0.0182(4) Uani 1 1 d .
C6 C -0.1624(2) 0.4383(2) 0.30699(13) 0.0260(4) Uani 1 1 d .
H6 H -0.2587 0.417 0.3241 0.031 Uiso 1 1 calc R
C7 C -0.1212(3) 0.4394(2) 0.22188(13) 0.0293(5) Uani 1 1 d .
H7 H -0.1835 0.4196 0.1728 0.035 Uiso 1 1 calc R
C8 C 0.0219(3) 0.4739(2) 0.22523(12) 0.0261(4) Uani 1 1 d .
H8 H 0.0792 0.4825 0.1777 0.031 Uiso 1 1 calc R
C9 C 0.1906(2) 0.40246(18) 0.47712(12) 0.0190(4) Uani 1 1 d .
C10 C 0.2311(3) 0.3019(2) 0.50316(16) 0.0379(6) Uani 1 1 d .
H10 H 0.1762 0.2479 0.5374 0.045 Uiso 1 1 calc R
C11 C 0.3684(3) 0.2876(2) 0.47202(14) 0.0309(5) Uani 1 1 d .
H11 H 0.4212 0.2246 0.4818 0.037 Uiso 1 1 calc R
C12 C 0.4070(2) 0.3793(2) 0.42698(15) 0.0312(5) Uani 1 1 d .
H12 H 0.4945 0.3938 0.3985 0.037 Uiso 1 1 calc R
C13 C 0.3654(2) -0.20153(18) 0.01173(12) 0.0196(4) Uani 1 1 d .
C14 C 0.3885(3) -0.3256(2) -0.01026(14) 0.0278(5) Uani 1 1 d .
H14 H 0.4707 -0.3484 -0.0375 0.033 Uiso 1 1 calc R
C15 C 0.2704(3) -0.4167(2) 0.01390(14) 0.0298(5) Uani 1 1 d .
H15 H 0.2596 -0.5096 0.0058 0.036 Uiso 1 1 calc R
C16 C 0.1790(2) -0.3468(2) 0.04970(15) 0.0301(5) Uani 1 1 d .
H16 H 0.0897 -0.3826 0.0713 0.036 Uiso 1 1 calc R
C17 C 0.5165(2) 0.05729(18) 0.14165(12) 0.0192(4) Uani 1 1 d .
C18 C 0.6215(2) 0.1221(2) 0.20007(13) 0.0252(4) Uani 1 1 d .
H18 H 0.7186 0.1562 0.1885 0.03 Uiso 1 1 calc R
C19 C 0.5639(3) 0.1315(2) 0.28256(13) 0.0296(5) Uani 1 1 d .
H19 H 0.6146 0.1722 0.335 0.036 Uiso 1 1 calc R
C20 C 0.4262(3) 0.0723(2) 0.27116(13) 0.0285(5) Uani 1 1 d .
H20 H 0.3607 0.064 0.3152 0.034 Uiso 1 1 calc R
C21 C 0.6971(2) -0.08768(19) 0.00326(12) 0.0195(4) Uani 1 1 d .
C22 C 0.7333(2) -0.1668(2) 0.05232(13) 0.0275(5) Uani 1 1 d .
H22 H 0.6795 -0.1941 0.0977 0.033 Uiso 1 1 calc R
C23 C 0.8642(2) -0.2032(2) 0.02573(13) 0.0268(4) Uani 1 1 d .
H23 H 0.9129 -0.2586 0.0494 0.032 Uiso 1 1 calc R
C24 C 0.9051(2) -0.1448(2) -0.03851(14) 0.0277(5) Uani 1 1 d .
H24 H 0.9897 -0.1514 -0.0687 0.033 Uiso 1 1 calc R
C25 C -0.4429(2) 0.2713(2) 0.75408(14) 0.0275(5) Uani 1 1 d .
H25A H -0.4424 0.2713 0.8154 0.033 Uiso 1 1 calc R
H25B H -0.377 0.2154 0.7281 0.033 Uiso 1 1 calc R
C26 C -0.5918(3) 0.2131(2) 0.71654(16) 0.0377(6) Uani 1 1 d .
H26A H -0.6599 0.2598 0.7479 0.057 Uiso 1 1 calc R
H26B H -0.6176 0.1196 0.7198 0.057 Uiso 1 1 calc R
H26C H -0.5954 0.2218 0.6572 0.057 Uiso 1 1 calc R
C27 C -0.4695(3) 0.4949(2) 0.78743(15) 0.0314(5) Uani 1 1 d .
H27A H -0.4961 0.4709 0.8425 0.038 Uiso 1 1 calc R
H27B H -0.5593 0.4909 0.7548 0.038 Uiso 1 1 calc R
C28 C -0.3784(3) 0.6315(2) 0.80142(15) 0.0345(5) Uani 1 1 d .
H28A H -0.294 0.637 0.838 0.052 Uiso 1 1 calc R
H28B H -0.4346 0.6946 0.8284 0.052 Uiso 1 1 calc R
H28C H -0.3468 0.6525 0.747 0.052 Uiso 1 1 calc R
C29 C -0.0298(2) 0.0237(2) 0.23083(15) 0.0287(5) Uani 1 1 d .
H29A H -0.097 -0.0012 0.2745 0.034 Uiso 1 1 calc R
H29B H -0.0871 0.0192 0.1786 0.034 Uiso 1 1 calc R
C30 C 0.0561(3) 0.1601(2) 0.26038(15) 0.0339(5) Uani 1 1 d .
H30A H 0.1085 0.1651 0.3137 0.051 Uiso 1 1 calc R
H30B H -0.0085 0.222 0.2692 0.051 Uiso 1 1 calc R
H30C H 0.1249 0.183 0.2177 0.051 Uiso 1 1 calc R
C31 C 0.0115(3) -0.1916(2) 0.23640(16) 0.0372(6) Uani 1 1 d .
H31A H 0.0747 -0.2522 0.2138 0.045 Uiso 1 1 calc R
H31B H -0.0854 -0.2285 0.2086 0.045 Uiso 1 1 calc R
C32 C 0.0008(3) -0.1870(3) 0.32780(15) 0.0439(6) Uani 1 1 d .
H32A H 0.0943 -0.1433 0.3567 0.066 Uiso 1 1 calc R
H32B H -0.0267 -0.277 0.3382 0.066 Uiso 1 1 calc R
H32C H -0.0721 -0.1376 0.3495 0.066 Uiso 1 1 calc R
O1 O -0.25765(16) 0.28024(13) 0.55775(9) 0.0230(3) Uani 1 1 d .
O2 O 0.07497(15) 0.49529(13) 0.30707(8) 0.0205(3) Uani 1 1 d .
O3 O 0.30255(16) 0.45109(14) 0.42715(10) 0.0283(3) Uani 1 1 d .
O4 O 0.80709(16) -0.07322(14) -0.05494(9) 0.0245(3) Uani 1 1 d .
O5 O 0.23194(16) -0.21418(13) 0.05118(10) 0.0268(3) Uani 1 1 d .
O6 O 0.39112(16) 0.02451(14) 0.18654(8) 0.0232(3) Uani 1 1 d .
O7 O -0.39040(16) 0.40386(13) 0.74180(9) 0.0239(3) Uani 1 1 d .
O8 O 0.06668(17) -0.06584(14) 0.21446(9) 0.0271(3) Uani 1 1 d .
Sn1 Sn 0 0.5 0.5 0.01503(5) Uani 1 2 d S
Sn2 Sn 0.5 0 0 0.01574(5) Uani 1 2 d S
Li1 Li -0.2705(4) 0.4327(3) 0.6464(2) 0.0231(7) Uani 1 1 d .
Li2 Li 0.2047(4) -0.0505(3) 0.1279(2) 0.0252(8) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 O1 105.66(16) . .
C2 C1 Sn1 131.55(15) . .
O1 C1 Sn1 122.78(12) . .
C1 C2 C3 109.70(19) . .
C1 C2 H2 125.2 . .
C3 C2 H2 125.2 . .
C4 C3 C2 106.36(18) . .
C4 C3 H3 126.8 . .
C2 C3 H3 126.8 . .
C3 C4 O1 109.98(18) . .
C3 C4 H4 125 . .
O1 C4 H4 125 . .
C6 C5 O2 105.94(16) . .
C6 C5 Sn1 135.31(15) . .
O2 C5 Sn1 118.75(13) . .
C5 C6 C7 109.48(19) . .
C5 C6 H6 125.3 . .
C7 C6 H6 125.3 . .
C8 C7 C6 106.24(19) . .
C8 C7 H7 126.9 . .
C6 C7 H7 126.9 . .
C7 C8 O2 110.38(18) . .
C7 C8 H8 124.8 . .
O2 C8 H8 124.8 . .
C10 C9 O3 104.97(17) . .
C10 C9 Sn1 134.64(15) . .
O3 C9 Sn1 120.35(12) . .
C9 C10 C11 110.29(19) . .
C9 C10 H10 124.9 . .
C11 C10 H10 124.9 . .
C12 C11 C10 106.06(19) . .
C12 C11 H11 127 . .
C10 C11 H11 127 . .
C11 C12 O3 110.07(19) . .
C11 C12 H12 125 . .
O3 C12 H12 125 . .
C14 C13 O5 105.82(16) . .
C14 C13 Sn2 132.53(15) . .
O5 C13 Sn2 121.60(12) . .
C13 C14 C15 109.49(19) . .
C13 C14 H14 125.3 . .
C15 C14 H14 125.3 . .
C16 C15 C14 106.75(19) . .
C16 C15 H15 126.6 . .
C14 C15 H15 126.6 . .
C15 C16 O5 110.21(19) . .
C15 C16 H16 124.9 . .
O5 C16 H16 124.9 . .
C18 C17 O6 106.24(16) . .
C18 C17 Sn2 135.51(15) . .
O6 C17 Sn2 118.24(13) . .
C17 C18 C19 109.3(2) . .
C17 C18 H18 125.4 . .
C19 C18 H18 125.4 . .
C20 C19 C18 106.38(19) . .
C20 C19 H19 126.8 . .
C18 C19 H19 126.8 . .
C19 C20 O6 110.33(18) . .
C19 C20 H20 124.8 . .
O6 C20 H20 124.8 . .
C22 C21 O4 105.68(17) . .
C22 C21 Sn2 131.06(15) . .
O4 C21 Sn2 123.14(13) . .
C21 C22 C23 109.66(18) . .
C21 C22 H22 125.2 . .
C23 C22 H22 125.2 . .
C24 C23 C22 106.57(19) . .
C24 C23 H23 126.7 . .
C22 C23 H23 126.7 . .
C23 C24 O4 109.98(19) . .
C23 C24 H24 125 . .
O4 C24 H24 125 . .
O7 C25 C26 112.61(19) . .
O7 C25 H25A 109.1 . .
C26 C25 H25A 109.1 . .
O7 C25 H25B 109.1 . .
C26 C25 H25B 109.1 . .
H25A C25 H25B 107.8 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
O7 C27 C28 109.29(18) . .
O7 C27 H27A 109.8 . .
C28 C27 H27A 109.8 . .
O7 C27 H27B 109.8 . .
C28 C27 H27B 109.8 . .
H27A C27 H27B 108.3 . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
O8 C29 C30 109.05(19) . .
O8 C29 H29A 109.9 . .
C30 C29 H29A 109.9 . .
O8 C29 H29B 109.9 . .
C30 C29 H29B 109.9 . .
H29A C29 H29B 108.3 . .
C29 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
O8 C31 C32 114.2(2) . .
O8 C31 H31A 108.7 . .
C32 C31 H31A 108.7 . .
O8 C31 H31B 108.7 . .
C32 C31 H31B 108.7 . .
H31A C31 H31B 107.6 . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C4 O1 C1 108.30(15) . .
C4 O1 Li1 134.08(15) . .
C1 O1 Li1 116.85(15) . .
C8 O2 C5 107.96(16) . .
C8 O2 Li1 129.55(16) . 2_566
C5 O2 Li1 122.00(15) . 2_566
C12 O3 C9 108.58(15) . .
C12 O3 Li1 130.17(17) . 2_566
C9 O3 Li1 119.42(16) . 2_566
C24 O4 C21 108.12(15) . .
C24 O4 Li2 136.04(17) . 2_655
C21 O4 Li2 115.50(16) . 2_655
C16 O5 C13 107.71(15) . .
C16 O5 Li2 132.99(16) . .
C13 O5 Li2 114.45(15) . .
C20 O6 C17 107.79(16) . .
C20 O6 Li2 130.36(17) . .
C17 O6 Li2 121.19(15) . .
C25 O7 C27 112.34(15) . .
C25 O7 Li1 119.12(15) . .
C27 O7 Li1 125.79(16) . .
C31 O8 C29 113.76(16) . .
C31 O8 Li2 120.14(16) . .
C29 O8 Li2 120.42(16) . .
C5 Sn1 C5 180 2_566 .
C5 Sn1 C9 90.50(7) 2_566 2_566
C5 Sn1 C9 89.50(7) . 2_566
C5 Sn1 C9 89.50(7) 2_566 .
C5 Sn1 C9 90.50(7) . .
C9 Sn1 C9 180.00(10) 2_566 .
C5 Sn1 C1 89.05(7) 2_566 .
C5 Sn1 C1 90.95(7) . .
C9 Sn1 C1 90.74(7) 2_566 .
C9 Sn1 C1 89.26(7) . .
C5 Sn1 C1 90.95(7) 2_566 2_566
C5 Sn1 C1 89.05(7) . 2_566
C9 Sn1 C1 89.26(7) 2_566 2_566
C9 Sn1 C1 90.74(7) . 2_566
C1 Sn1 C1 180 . 2_566
C17 Sn2 C17 180.00(3) . 2_655
C17 Sn2 C21 89.63(7) . .
C17 Sn2 C21 90.37(7) 2_655 .
C17 Sn2 C21 90.37(7) . 2_655
C17 Sn2 C21 89.63(7) 2_655 2_655
C21 Sn2 C21 180.00(8) . 2_655
C17 Sn2 C13 88.86(7) . .
C17 Sn2 C13 91.14(7) 2_655 .
C21 Sn2 C13 87.38(7) . .
C21 Sn2 C13 92.62(7) 2_655 .
C17 Sn2 C13 91.14(7) . 2_655
C17 Sn2 C13 88.86(7) 2_655 2_655
C21 Sn2 C13 92.62(7) . 2_655
C21 Sn2 C13 87.38(7) 2_655 2_655
C13 Sn2 C13 180.00(14) . 2_655
O3 Li1 O2 104.67(17) 2_566 2_566
O3 Li1 O7 122.38(19) 2_566 .
O2 Li1 O7 106.55(18) 2_566 .
O3 Li1 O1 97.42(17) 2_566 .
O2 Li1 O1 105.37(18) 2_566 .
O7 Li1 O1 118.65(17) . .
O8 Li2 O4 117.85(19) . 2_655
O8 Li2 O6 106.13(18) . .
O4 Li2 O6 102.17(17) 2_655 .
O8 Li2 O5 118.61(18) . .
O4 Li2 O5 105.49(17) 2_655 .
O6 Li2 O5 104.56(18) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.346(3) .
C1 O1 1.412(2) .
C1 Sn1 2.2871(18) .
C2 C3 1.434(3) .
C2 H2 0.95 .
C3 C4 1.322(3) .
C3 H3 0.95 .
C4 O1 1.376(2) .
C4 H4 0.95 .
C5 C6 1.353(3) .
C5 O2 1.415(2) .
C5 Sn1 2.2577(19) .
C6 C7 1.431(3) .
C6 H6 0.95 .
C7 C8 1.330(3) .
C7 H7 0.95 .
C8 O2 1.372(2) .
C8 H8 0.95 .
C9 C10 1.342(3) .
C9 O3 1.408(2) .
C9 Sn1 2.2643(19) .
C10 C11 1.426(3) .
C10 H10 0.95 .
C11 C12 1.315(3) .
C11 H11 0.95 .
C12 O3 1.370(2) .
C12 H12 0.95 .
C13 C14 1.356(3) .
C13 O5 1.414(2) .
C13 Sn2 2.2862(18) .
C14 C15 1.426(3) .
C14 H14 0.95 .
C15 C16 1.320(3) .
C15 H15 0.95 .
C16 O5 1.383(2) .
C16 H16 0.95 .
C17 C18 1.346(3) .
C17 O6 1.412(2) .
C17 Sn2 2.2446(19) .
C18 C19 1.435(3) .
C18 H18 0.95 .
C19 C20 1.322(3) .
C19 H19 0.95 .
C20 O6 1.375(2) .
C20 H20 0.95 .
C21 C22 1.350(3) .
C21 O4 1.412(2) .
C21 Sn2 2.263(2) .
C22 C23 1.422(3) .
C22 H22 0.95 .
C23 C24 1.326(3) .
C23 H23 0.95 .
C24 O4 1.372(2) .
C24 H24 0.95 .
C25 O7 1.438(2) .
C25 C26 1.494(3) .
C25 H25A 0.99 .
C25 H25B 0.99 .
C26 H26A 0.98 .
C26 H26B 0.98 .
C26 H26C 0.98 .
C27 O7 1.439(2) .
C27 C28 1.495(3) .
C27 H27A 0.99 .
C27 H27B 0.99 .
C28 H28A 0.98 .
C28 H28B 0.98 .
C28 H28C 0.98 .
C29 O8 1.442(2) .
C29 C30 1.486(3) .
C29 H29A 0.99 .
C29 H29B 0.99 .
C30 H30A 0.98 .
C30 H30B 0.98 .
C30 H30C 0.98 .
C31 O8 1.435(3) .
C31 C32 1.471(3) .
C31 H31A 0.99 .
C31 H31B 0.99 .
C32 H32A 0.98 .
C32 H32B 0.98 .
C32 H32C 0.98 .
O1 Li1 1.963(4) .
O2 Li1 1.942(4) 2_566
O3 Li1 1.931(4) 2_566
O4 Li2 1.941(4) 2_655
O5 Li2 1.990(4) .
O6 Li2 1.942(4) .
O7 Li1 1.951(4) .
O8 Li2 1.925(4) .
Sn1 C5 2.2577(19) 2_566
Sn1 C9 2.2643(19) 2_566
Sn1 C1 2.2871(18) 2_566
Sn2 C17 2.2446(19) 2_655
Sn2 C21 2.263(2) 2_655
Sn2 C13 2.2862(18) 2_655
Li1 O3 1.931(4) 2_566
Li1 O2 1.942(4) 2_566
Li2 O4 1.941(4) 2_655
