#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:13:40 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180066 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/12/7051244.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051244
loop_
_publ_author_name
'Slawin, Alexandra M. Z.'
'Wainwright, Matthew'
'Derek Woollins, J.'
_publ_section_title
;
 Phosphino-urea chemistry: preparation and structure of chelate and
 P--N bond cleavage complexes
;
_journal_issue                   2
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              69
_journal_paper_doi               10.1039/a908153d
_journal_volume                  24
_journal_year                    2000
_chemical_formula_analytical     'C27 H26 Cl2 N2 O P2 Pd'
_chemical_formula_moiety         'C27 H26 Cl2 N2 O P2 Pd'
_chemical_formula_structural     'C27 H26 Cl2 N2 O P2 Pd'
_chemical_formula_sum            'C27 H26 Cl2 N2 O P2 Pd'
_chemical_formula_weight         633.74
_chemical_melting_point          ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 101.70
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.90760(10)
_cell_length_b                   14.6999(2)
_cell_length_c                   19.0506(2)
_cell_measurement_reflns_used    57
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      337
_cell_measurement_theta_min      23
_cell_volume                     2716.90(5)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       SMART
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_sigmaI/netI    0.0288
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11787
_diffrn_reflns_theta_max         23.27
_diffrn_reflns_theta_min         1.76
_diffrn_standards_decay_%        -
_diffrn_standards_interval_count -
_diffrn_standards_interval_time  -
_diffrn_standards_number         -
_exptl_absorpt_coefficient_mu    1.021
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.864823
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.549
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    -
_exptl_crystal_description       plate
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          .05
_exptl_crystal_size_mid          .05
_exptl_crystal_size_min          .1
_refine_diff_density_max         0.380
_refine_diff_density_min         -0.492
_refine_diff_density_rms         0.054
_refine_ls_extinction_coef       0.0010(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   0.964
_refine_ls_goodness_of_fit_obs   0.985
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     317
_refine_ls_number_reflns         3866
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.061
_refine_ls_restrained_S_obs      0.985
_refine_ls_R_factor_all          0.0390
_refine_ls_R_factor_obs          0.0263
_refine_ls_shift/esd_max         -0.003
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0365P)²+0.7524P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0690
_refine_ls_wR_factor_obs         0.0576
_reflns_number_observed          3178
_reflns_number_total             3916
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            a908153d.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/adriana/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' value '-' was changed to '?' - the value is
undefined or not given.

Automatic conversion script
Id: cif_fix_values 1569 2011-02-09 13:29:24Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value '-' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0365P)^2^+0.7524P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0365P)^2^+0.7524P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2716.94(5)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7051244
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pd1 Pd 0.15257(2) 0.672025(14) 0.295752(11) 0.02905(10) Uani 1 d . .
Cl1 Cl 0.19327(9) 0.67203(5) 0.42152(4) 0.0459(2) Uani 1 d . .
Cl2 Cl -0.08251(8) 0.70045(6) 0.28820(5) 0.0546(2) Uani 1 d . .
P1 P 0.37538(8) 0.64966(5) 0.30634(4) 0.0302(2) Uani 1 d . .
C1 C 0.4314(4) 0.5420(2) 0.3494(2) 0.0413(8) Uani 1 d . .
C2 C 0.3388(4) 0.4705(2) 0.3351(2) 0.0514(9) Uani 1 d . .
H2A H 0.2501(4) 0.4806(2) 0.3089(2) 0.062 Uiso 1 calc R .
C3 C 0.3784(6) 0.3841(3) 0.3599(2) 0.0768(14) Uani 1 d . .
H3A H 0.3166(6) 0.3360(3) 0.3499(2) 0.092 Uiso 1 calc R .
C4 C 0.5089(7) 0.3693(3) 0.3993(2) 0.087(2) Uani 1 d . .
H4A H 0.5353(7) 0.3111(3) 0.4157(2) 0.104 Uiso 1 calc R .
C5 C 0.5993(6) 0.4394(4) 0.4142(3) 0.092(2) Uani 1 d . .
H5A H 0.6872(6) 0.4289(4) 0.4411(3) 0.110 Uiso 1 calc R .
C6 C 0.5616(4) 0.5266(3) 0.3895(2) 0.0734(12) Uani 1 d . .
H6A H 0.6239(4) 0.5744(3) 0.4001(2) 0.088 Uiso 1 calc R .
C7 C 0.4716(3) 0.7427(2) 0.3546(2) 0.0353(7) Uani 1 d . .
C8 C 0.5132(3) 0.7428(2) 0.4284(2) 0.0487(9) Uani 1 d . .
H8A H 0.4977(3) 0.6920(2) 0.4548(2) 0.058 Uiso 1 calc R .
C9 C 0.5778(4) 0.8185(3) 0.4631(2) 0.0679(12) Uani 1 d . .
H9A H 0.6047(4) 0.8187(3) 0.5127(2) 0.081 Uiso 1 calc R .
C10 C 0.6024(4) 0.8934(3) 0.4246(2) 0.0728(12) Uani 1 d . .
H10A H 0.6470(4) 0.9439(3) 0.4481(2) 0.087 Uiso 1 calc R .
C11 C 0.5614(4) 0.8935(2) 0.3521(2) 0.0657(11) Uani 1 d . .
H11A H 0.5780(4) 0.9445(2) 0.3262(2) 0.079 Uiso 1 calc R .
C12 C 0.4956(4) 0.8195(2) 0.3162(2) 0.0481(8) Uani 1 d . .
H12A H 0.4674(4) 0.8208(2) 0.2666(2) 0.058 Uiso 1 calc R .
N1 N 0.4404(3) 0.6468(2) 0.23052(13) 0.0374(6) Uani 1 d . .
C13 C 0.3789(3) 0.6419(2) 0.1588(2) 0.0335(7) Uani 1 d . .
O13 O 0.4526(2) 0.6340(2) 0.11483(11) 0.0499(6) Uani 1 d . .
N2 N 0.2382(3) 0.6444(2) 0.13469(12) 0.0344(6) Uani 1 d . .
P2 P 0.10729(8) 0.66881(5) 0.17746(4) 0.0302(2) Uani 1 d . .
C14 C -0.0128(3) 0.5777(2) 0.14656(15) 0.0323(7) Uani 1 d . .
C15 C 0.0386(3) 0.4893(2) 0.1451(2) 0.0420(8) Uani 1 d . .
H15A H 0.1333(3) 0.4794(2) 0.1555(2) 0.050 Uiso 1 calc R .
C16 C -0.0505(4) 0.4166(2) 0.1281(2) 0.0513(9) Uani 1 d . .
H16A H -0.0156(4) 0.3580(2) 0.1274(2) 0.062 Uiso 1 calc R .
C17 C -0.1907(4) 0.4308(2) 0.1123(2) 0.0485(9) Uani 1 d . .
H17A H -0.2503(4) 0.3817(2) 0.1010(2) 0.058 Uiso 1 calc R .
C18 C -0.2427(4) 0.5170(2) 0.1132(2) 0.0482(9) Uani 1 d . .
H18A H -0.3375(4) 0.5262(2) 0.1021(2) 0.058 Uiso 1 calc R .
C19 C -0.1547(3) 0.5905(2) 0.1304(2) 0.0386(7) Uani 1 d . .
H19A H -0.1908(3) 0.6488(2) 0.1312(2) 0.046 Uiso 1 calc R .
C20 C 0.0400(3) 0.7765(2) 0.1390(2) 0.0414(8) Uani 1 d . .
C21 C 0.0818(4) 0.8540(2) 0.1796(2) 0.0581(10) Uani 1 d . .
H21A H 0.1354(4) 0.8485(2) 0.2256(2) 0.070 Uiso 1 calc R .
C22 C 0.0434(5) 0.9392(3) 0.1515(3) 0.084(2) Uani 1 d . .
H22A H 0.0713(5) 0.9911(3) 0.1785(3) 0.101 Uiso 1 calc R .
C23 C -0.0351(6) 0.9468(3) 0.0844(4) 0.100(2) Uani 1 d . .
H23A H -0.0607(6) 1.0042(3) 0.0658(4) 0.120 Uiso 1 calc R .
C24 C -0.0771(5) 0.8710(4) 0.0437(3) 0.091(2) Uani 1 d . .
H24A H -0.1300(5) 0.8773(4) -0.0023(3) 0.109 Uiso 1 calc R .
C25 C -0.0407(4) 0.7850(3) 0.0710(2) 0.0625(10) Uani 1 d . .
H25A H -0.0702(4) 0.7334(3) 0.0439(2) 0.075 Uiso 1 calc R .
C26 C 0.5937(3) 0.6389(3) 0.2428(2) 0.0581(10) Uani 1 d . .
H26A H 0.6319(3) 0.6428(3) 0.2932(2) 0.087 Uiso 1 calc R .
H26B H 0.6298(3) 0.6873(3) 0.2182(2) 0.087 Uiso 1 calc R .
H26C H 0.6181(3) 0.5815(3) 0.2248(2) 0.087 Uiso 1 calc R .
C27 C 0.1971(4) 0.6371(2) 0.0554(2) 0.0505(9) Uani 1 d . .
H27A H 0.0985(4) 0.6393(2) 0.0414(2) 0.076 Uiso 1 calc R .
H27B H 0.2300(4) 0.5806(2) 0.0400(2) 0.076 Uiso 1 calc R .
H27C H 0.2364(4) 0.6867(2) 0.0336(2) 0.076 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pd1 P2 94.76(3) . . ?
P1 Pd1 Cl2 177.62(3) . . ?
P2 Pd1 Cl2 86.98(3) . . ?
P1 Pd1 Cl1 86.84(3) . . ?
P2 Pd1 Cl1 177.82(3) . . ?
Cl2 Pd1 Cl1 91.47(3) . . ?
N1 P1 C7 101.51(13) . . ?
N1 P1 C1 103.24(13) . . ?
C7 P1 C1 110.34(14) . . ?
N1 P1 Pd1 118.19(9) . . ?
C7 P1 Pd1 110.47(10) . . ?
C1 P1 Pd1 112.36(11) . . ?
C2 C1 C6 119.5(3) . . ?
C2 C1 P1 116.3(3) . . ?
C6 C1 P1 124.0(3) . . ?
C1 C2 C3 119.9(4) . . ?
C4 C3 C2 120.2(4) . . ?
C5 C4 C3 120.1(4) . . ?
C4 C5 C6 120.6(5) . . ?
C1 C6 C5 119.7(4) . . ?
C8 C7 C12 119.1(3) . . ?
C8 C7 P1 122.4(2) . . ?
C12 C7 P1 118.4(2) . . ?
C9 C8 C7 120.0(3) . . ?
C10 C9 C8 120.4(4) . . ?
C9 C10 C11 119.7(3) . . ?
C10 C11 C12 121.1(4) . . ?
C11 C12 C7 119.7(3) . . ?
C13 N1 C26 112.4(2) . . ?
C13 N1 P1 132.6(2) . . ?
C26 N1 P1 114.7(2) . . ?
O13 C13 N2 118.5(3) . . ?
O13 C13 N1 118.6(3) . . ?
N2 C13 N1 122.9(3) . . ?
C13 N2 C27 112.8(2) . . ?
C13 N2 P2 131.5(2) . . ?
C27 N2 P2 115.0(2) . . ?
N2 P2 C14 101.67(13) . . ?
N2 P2 C20 104.14(13) . . ?
C14 P2 C20 110.58(14) . . ?
N2 P2 Pd1 118.41(9) . . ?
C14 P2 Pd1 109.41(9) . . ?
C20 P2 Pd1 112.04(11) . . ?
C19 C14 C15 118.6(3) . . ?
C19 C14 P2 122.7(2) . . ?
C15 C14 P2 118.5(2) . . ?
C16 C15 C14 120.3(3) . . ?
C17 C16 C15 120.2(3) . . ?
C18 C17 C16 120.2(3) . . ?
C17 C18 C19 120.3(3) . . ?
C14 C19 C18 120.4(3) . . ?
C25 C20 C21 119.9(3) . . ?
C25 C20 P2 123.5(3) . . ?
C21 C20 P2 116.5(3) . . ?
C20 C21 C22 119.8(4) . . ?
C23 C22 C21 119.9(5) . . ?
C22 C23 C24 120.9(4) . . ?
C23 C24 C25 120.1(5) . . ?
C24 C25 C20 119.4(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 P1 2.2003(8) . ?
Pd1 P2 2.2072(8) . ?
Pd1 Cl2 2.3418(9) . ?
Pd1 Cl1 2.3476(8) . ?
P1 N1 1.697(2) . ?
P1 C7 1.808(3) . ?
P1 C1 1.816(3) . ?
C1 C2 1.386(5) . ?
C1 C6 1.378(5) . ?
C2 C3 1.384(5) . ?
C3 C4 1.374(7) . ?
C4 C5 1.357(7) . ?
C5 C6 1.391(6) . ?
C7 C8 1.383(4) . ?
C7 C12 1.391(4) . ?
C8 C9 1.383(5) . ?
C9 C10 1.371(5) . ?
C10 C11 1.359(5) . ?
C11 C12 1.377(5) . ?
N1 C13 1.380(4) . ?
N1 C26 1.494(4) . ?
C13 O13 1.224(3) . ?
C13 N2 1.377(4) . ?
N2 C27 1.486(4) . ?
N2 P2 1.704(2) . ?
P2 C14 1.809(3) . ?
P2 C20 1.814(3) . ?
C14 C19 1.390(4) . ?
C14 C15 1.397(4) . ?
C15 C16 1.382(4) . ?
C16 C17 1.376(5) . ?
C17 C18 1.369(5) . ?
C18 C19 1.386(4) . ?
C20 C25 1.383(5) . ?
C20 C21 1.391(5) . ?
C21 C22 1.386(5) . ?
C22 C23 1.359(7) . ?
C23 C24 1.374(7) . ?
C24 C25 1.387(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Pd1 P1 N1 4.98(10) . . . . ?
Cl2 Pd1 P1 N1 -131.8(8) . . . . ?
Cl1 Pd1 P1 N1 -176.51(10) . . . . ?
P2 Pd1 P1 C7 121.19(11) . . . . ?
Cl2 Pd1 P1 C7 -15.6(8) . . . . ?
Cl1 Pd1 P1 C7 -60.30(11) . . . . ?
P2 Pd1 P1 C1 -115.12(11) . . . . ?
Cl2 Pd1 P1 C1 108.1(8) . . . . ?
Cl1 Pd1 P1 C1 63.39(11) . . . . ?
N1 P1 C1 C2 -94.1(3) . . . . ?
C7 P1 C1 C2 158.1(2) . . . . ?
Pd1 P1 C1 C2 34.3(3) . . . . ?
N1 P1 C1 C6 80.4(3) . . . . ?
C7 P1 C1 C6 -27.4(4) . . . . ?
Pd1 P1 C1 C6 -151.1(3) . . . . ?
C6 C1 C2 C3 -1.3(5) . . . . ?
P1 C1 C2 C3 173.6(3) . . . . ?
C1 C2 C3 C4 0.6(6) . . . . ?
C2 C3 C4 C5 0.2(7) . . . . ?
C3 C4 C5 C6 -0.4(7) . . . . ?
C2 C1 C6 C5 1.1(6) . . . . ?
P1 C1 C6 C5 -173.3(3) . . . . ?
C4 C5 C6 C1 -0.2(7) . . . . ?
N1 P1 C7 C8 -144.4(3) . . . . ?
C1 P1 C7 C8 -35.4(3) . . . . ?
Pd1 P1 C7 C8 89.4(3) . . . . ?
N1 P1 C7 C12 40.4(3) . . . . ?
C1 P1 C7 C12 149.4(3) . . . . ?
Pd1 P1 C7 C12 -85.8(3) . . . . ?
C12 C7 C8 C9 -0.1(5) . . . . ?
P1 C7 C8 C9 -175.3(3) . . . . ?
C7 C8 C9 C10 -0.7(6) . . . . ?
C8 C9 C10 C11 0.9(7) . . . . ?
C9 C10 C11 C12 -0.2(7) . . . . ?
C10 C11 C12 C7 -0.6(6) . . . . ?
C8 C7 C12 C11 0.7(5) . . . . ?
P1 C7 C12 C11 176.1(3) . . . . ?
C7 P1 N1 C13 -132.7(3) . . . . ?
C1 P1 N1 C13 113.0(3) . . . . ?
Pd1 P1 N1 C13 -11.8(3) . . . . ?
C7 P1 N1 C26 54.3(3) . . . . ?
C1 P1 N1 C26 -60.0(3) . . . . ?
Pd1 P1 N1 C26 175.3(2) . . . . ?
C26 N1 C13 O13 -1.5(4) . . . . ?
P1 N1 C13 O13 -174.6(2) . . . . ?
C26 N1 C13 N2 177.7(3) . . . . ?
P1 N1 C13 N2 4.6(4) . . . . ?
O13 C13 N2 C27 -0.3(4) . . . . ?
N1 C13 N2 C27 -179.4(3) . . . . ?
O13 C13 N2 P2 -170.4(2) . . . . ?
N1 C13 N2 P2 10.4(4) . . . . ?
C13 N2 P2 C14 -134.0(3) . . . . ?
C27 N2 P2 C14 56.0(2) . . . . ?
C13 N2 P2 C20 111.0(3) . . . . ?
C27 N2 P2 C20 -59.0(2) . . . . ?
C13 N2 P2 Pd1 -14.2(3) . . . . ?
C27 N2 P2 Pd1 175.9(2) . . . . ?
P1 Pd1 P2 N2 4.46(10) . . . . ?
Cl2 Pd1 P2 N2 -177.17(10) . . . . ?
Cl1 Pd1 P2 N2 -132.6(8) . . . . ?
P1 Pd1 P2 C14 120.22(10) . . . . ?
Cl2 Pd1 P2 C14 -61.42(11) . . . . ?
Cl1 Pd1 P2 C14 -16.8(8) . . . . ?
P1 Pd1 P2 C20 -116.78(12) . . . . ?
Cl2 Pd1 P2 C20 61.59(12) . . . . ?
Cl1 Pd1 P2 C20 106.2(8) . . . . ?
N2 P2 C14 C19 -141.8(2) . . . . ?
C20 P2 C14 C19 -31.7(3) . . . . ?
Pd1 P2 C14 C19 92.2(2) . . . . ?
N2 P2 C14 C15 44.1(3) . . . . ?
C20 P2 C14 C15 154.3(2) . . . . ?
Pd1 P2 C14 C15 -81.9(2) . . . . ?
C19 C14 C15 C16 -0.2(4) . . . . ?
P2 C14 C15 C16 174.1(2) . . . . ?
C14 C15 C16 C17 0.3(5) . . . . ?
C15 C16 C17 C18 0.1(5) . . . . ?
C16 C17 C18 C19 -0.4(5) . . . . ?
C15 C14 C19 C18 -0.1(4) . . . . ?
P2 C14 C19 C18 -174.2(2) . . . . ?
C17 C18 C19 C14 0.4(5) . . . . ?
N2 P2 C20 C25 74.8(3) . . . . ?
C14 P2 C20 C25 -33.7(4) . . . . ?
Pd1 P2 C20 C25 -156.1(3) . . . . ?
N2 P2 C20 C21 -100.6(3) . . . . ?
C14 P2 C20 C21 150.9(2) . . . . ?
Pd1 P2 C20 C21 28.6(3) . . . . ?
C25 C20 C21 C22 -0.6(5) . . . . ?
P2 C20 C21 C22 175.0(3) . . . . ?
C20 C21 C22 C23 0.1(6) . . . . ?
C21 C22 C23 C24 -0.1(7) . . . . ?
C22 C23 C24 C25 0.6(7) . . . . ?
C23 C24 C25 C20 -1.1(6) . . . . ?
C21 C20 C25 C24 1.0(6) . . . . ?
P2 C20 C25 C24 -174.2(3) . . . . ?
