#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:32:38 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180084 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/30/7053060.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7053060
loop_
_publ_author_name
'Sarwar, Masood'
'Madalan, Augustin M.'
'Tiseanu, Carmen'
'Novitchi, Ghenadie'
'Maxim, Catalin'
'Marinescu, Gabriela'
'Luneau, Dominique'
'Andruh, Marius'
_publ_section_title
;
 A new synthetic route towards binuclear 3d--4f complexes, using
 non-compartmental ligands derived from o-vanillin. Syntheses, crystal
 structures, magnetic and luminescent properties
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2280
_journal_paper_doi               10.1039/c3nj00199g
_journal_volume                  37
_journal_year                    2013
_chemical_formula_sum            'C32 H35 Ho N8 Ni O14'
_chemical_formula_weight         979.32
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.995(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.8478(5)
_cell_length_b                   19.3966(6)
_cell_length_c                   15.1553(5)
_cell_measurement_reflns_used    43187
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.52
_cell_measurement_theta_min      2.49
_cell_volume                     3730.3(2)
_computing_cell_refinement       X-Area
_computing_data_collection       X-Area
_computing_data_reduction        X-Area
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'STOE IPDS II'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0472
_diffrn_reflns_av_sigmaI/netI    0.0371
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            55338
_diffrn_reflns_theta_full        29.52
_diffrn_reflns_theta_max         29.52
_diffrn_reflns_theta_min         2.49
_exptl_absorpt_coefficient_mu    2.688
_exptl_absorpt_correction_T_max  0.4751
_exptl_absorpt_correction_T_min  0.2776
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.744
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1960
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.057
_refine_diff_density_min         -0.728
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.955
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         10374
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.955
_refine_ls_R_factor_all          0.0495
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0249P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0496
_refine_ls_wR_factor_ref         0.0534
_reflns_number_gt                8009
_reflns_number_total             10374
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3nj00199g.txt
_cod_data_source_block           shelxl4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7053060
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.1375(4) 0.2868(2) 0.6881(4) 0.118(2) Uani 1 1 d .
H1A H -0.1093 0.3314 0.6776 0.176 Uiso 1 1 calc R
H1B H -0.1792 0.2901 0.7352 0.176 Uiso 1 1 calc R
H1C H -0.1808 0.2709 0.6346 0.176 Uiso 1 1 calc R
C2 C -0.0793(2) 0.17338(16) 0.72981(17) 0.0471(7) Uani 1 1 d .
C3 C -0.1735(2) 0.1523(2) 0.75494(19) 0.0629(9) Uani 1 1 d .
H3 H -0.2241 0.1849 0.7631 0.076 Uiso 1 1 calc R
C4 C -0.1929(3) 0.0835(2) 0.7680(2) 0.0705(11) Uani 1 1 d .
H4 H -0.2568 0.0700 0.7843 0.085 Uiso 1 1 calc R
C5 C -0.1193(3) 0.0352(2) 0.75722(19) 0.0597(8) Uani 1 1 d .
H5 H -0.1335 -0.0112 0.7656 0.072 Uiso 1 1 calc R
C6 C -0.0217(2) 0.05443(15) 0.73358(16) 0.0431(6) Uani 1 1 d .
C7 C -0.0012(2) 0.12406(15) 0.71849(15) 0.0378(5) Uani 1 1 d .
C8 C 0.0524(2) 0.00070(14) 0.72004(16) 0.0431(6) Uani 1 1 d .
H8 H 0.0257 -0.0438 0.7115 0.052 Uiso 1 1 calc R
C9 C 0.2095(2) -0.05545(14) 0.70721(18) 0.0463(6) Uani 1 1 d .
H9A H 0.1685 -0.0837 0.6616 0.056 Uiso 1 1 calc R
H9B H 0.2189 -0.0812 0.7628 0.056 Uiso 1 1 calc R
C10 C 0.3160(2) -0.04139(15) 0.68088(17) 0.0462(6) Uani 1 1 d .
H10A H 0.3436 -0.0840 0.6602 0.055 Uiso 1 1 calc R
H10B H 0.3076 -0.0090 0.6315 0.055 Uiso 1 1 calc R
C11 C 0.3944(2) -0.01271(14) 0.75582(17) 0.0428(6) Uani 1 1 d .
C12 C 0.4861(3) -0.04755(19) 0.7867(2) 0.0664(9) Uani 1 1 d .
H12 H 0.5013 -0.0888 0.7601 0.080 Uiso 1 1 calc R
C13 C 0.5554(3) -0.0211(2) 0.8571(3) 0.0829(12) Uani 1 1 d .
H13 H 0.6173 -0.0445 0.8786 0.099 Uiso 1 1 calc R
C14 C 0.5327(3) 0.0394(2) 0.8951(2) 0.0665(9) Uani 1 1 d .
H14 H 0.5786 0.0582 0.9425 0.080 Uiso 1 1 calc R
C15 C 0.4402(2) 0.07202(17) 0.86163(18) 0.0499(7) Uani 1 1 d .
H15 H 0.4242 0.1132 0.8880 0.060 Uiso 1 1 calc R
C16 C 0.3712(3) 0.0457(2) 0.39990(19) 0.0659(9) Uani 1 1 d .
H16A H 0.3236 0.0119 0.3699 0.099 Uiso 1 1 calc R
H16B H 0.4424 0.0304 0.4011 0.099 Uiso 1 1 calc R
H16C H 0.3610 0.0888 0.3687 0.099 Uiso 1 1 calc R
C17 C 0.4117(2) 0.10145(14) 0.54219(16) 0.0395(5) Uani 1 1 d .
C18 C 0.5148(2) 0.11576(16) 0.5339(2) 0.0506(7) Uani 1 1 d .
H18 H 0.5453 0.0942 0.4894 0.061 Uiso 1 1 calc R
C19 C 0.5740(2) 0.16230(18) 0.5916(2) 0.0574(7) Uani 1 1 d .
H19 H 0.6436 0.1717 0.5861 0.069 Uiso 1 1 calc R
C20 C 0.5282(2) 0.19379(16) 0.6563(2) 0.0507(7) Uani 1 1 d .
H20 H 0.5668 0.2256 0.6940 0.061 Uiso 1 1 calc R
C21 C 0.4245(2) 0.17933(14) 0.66708(17) 0.0395(5) Uani 1 1 d .
C22 C 0.36312(19) 0.13280(13) 0.60984(15) 0.0334(5) Uani 1 1 d .
C23 C 0.3822(2) 0.21595(14) 0.73737(16) 0.0403(6) Uani 1 1 d .
H23 H 0.4141 0.2575 0.7566 0.048 Uiso 1 1 calc R
C24 C 0.2786(3) 0.24272(16) 0.8448(2) 0.0572(8) Uani 1 1 d .
H24A H 0.2778 0.2898 0.8232 0.069 Uiso 1 1 calc R
H24B H 0.3328 0.2394 0.8969 0.069 Uiso 1 1 calc R
C25 C 0.1733(3) 0.22668(15) 0.87204(19) 0.0502(7) Uani 1 1 d .
H25A H 0.1546 0.2636 0.9098 0.060 Uiso 1 1 calc R
H25B H 0.1202 0.2251 0.8190 0.060 Uiso 1 1 calc R
C26 C 0.1722(2) 0.15972(16) 0.92118(16) 0.0437(6) Uani 1 1 d .
C27 C 0.1527(3) 0.1577(2) 1.00900(19) 0.0639(9) Uani 1 1 d .
H27 H 0.1402 0.1984 1.0380 0.077 Uiso 1 1 calc R
C28 C 0.1519(3) 0.0957(2) 1.0530(2) 0.0762(11) Uani 1 1 d .
H28 H 0.1380 0.0940 1.1114 0.091 Uiso 1 1 calc R
C29 C 0.1720(3) 0.0369(2) 1.00942(19) 0.0641(9) Uani 1 1 d .
H29 H 0.1719 -0.0057 1.0376 0.077 Uiso 1 1 calc R
C30 C 0.1925(2) 0.04150(16) 0.92319(17) 0.0494(7) Uani 1 1 d .
H30 H 0.2066 0.0012 0.8939 0.059 Uiso 1 1 calc R
C31 C 0.4015(3) 0.3497(2) 0.5631(3) 0.0735(10) Uani 1 1 d .
C32 C 0.3804(4) 0.3074(3) 0.4836(3) 0.0895(13) Uani 1 1 d .
H32A H 0.4082 0.2620 0.4966 0.134 Uiso 1 1 calc R
H32B H 0.4132 0.3277 0.4371 0.134 Uiso 1 1 calc R
H32C H 0.3057 0.3046 0.4643 0.134 Uiso 1 1 calc R
Ho1 Ho 0.103648(9) 0.159039(6) 0.543358(7) 0.03333(3) Uani 1 1 d .
N1 N 0.15097(18) 0.00842(11) 0.71861(13) 0.0378(5) Uani 1 1 d .
N2 N 0.37129(18) 0.04750(12) 0.79262(13) 0.0403(5) Uani 1 1 d .
N3 N 0.30541(18) 0.19612(11) 0.77489(13) 0.0387(5) Uani 1 1 d .
N4 N 0.19285(18) 0.10191(12) 0.87938(13) 0.0412(5) Uani 1 1 d .
N5 N -0.12113(19) 0.12427(15) 0.52063(13) 0.0468(6) Uani 1 1 d .
N6 N 0.1323(2) 0.17347(14) 0.36163(15) 0.0536(6) Uani 1 1 d .
N7 N 0.1326(2) 0.30588(14) 0.56394(18) 0.0563(6) Uani 1 1 d .
N8 N 0.4202(4) 0.3813(2) 0.6253(3) 0.1060(13) Uani 1 1 d .
Ni1 Ni 0.23020(2) 0.101966(15) 0.748115(18) 0.03184(7) Uani 1 1 d .
O1 O -0.05399(17) 0.23988(12) 0.71292(16) 0.0613(6) Uani 1 1 d .
O2 O 0.08636(13) 0.14406(9) 0.68870(10) 0.0355(4) Uani 1 1 d .
O3 O 0.35083(16) 0.05440(10) 0.48918(12) 0.0476(5) Uani 1 1 d .
O4 O 0.26409(13) 0.11815(9) 0.61785(10) 0.0328(3) Uani 1 1 d .
O5 O -0.04843(15) 0.07945(11) 0.52307(13) 0.0477(4) Uani 1 1 d .
O6 O -0.08973(17) 0.18548(12) 0.52895(13) 0.0544(5) Uani 1 1 d .
O7 O -0.21313(17) 0.10766(15) 0.50976(16) 0.0737(7) Uani 1 1 d .
O8 O 0.04169(17) 0.16594(12) 0.38122(12) 0.0539(5) Uani 1 1 d .
O9 O 0.20703(17) 0.18294(11) 0.42660(13) 0.0526(5) Uani 1 1 d .
O10 O 0.1488(2) 0.17072(17) 0.28481(14) 0.0895(9) Uani 1 1 d .
O11 O 0.19266(19) 0.26245(11) 0.60636(15) 0.0626(6) Uani 1 1 d .
O12 O 0.0594(2) 0.28137(12) 0.50836(18) 0.0731(7) Uani 1 1 d .
O13 O 0.1451(3) 0.36730(13) 0.5752(2) 0.0985(11) Uani 1 1 d .
O14 O 0.13828(19) 0.05107(12) 0.48128(15) 0.0512(5) Uani 1 1 d .
H1W H 0.206(3) 0.0477(18) 0.490(2) 0.062(10) Uiso 1 1 d .
H2W H 0.106(3) 0.016(2) 0.485(3) 0.083(14) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ho Ho -0.2175 4.6783 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O1 C1 H1A 109.5
O1 C1 H1B 109.5
H1A C1 H1B 109.5
O1 C1 H1C 109.5
H1A C1 H1C 109.5
H1B C1 H1C 109.5
O1 C2 C3 125.1(3)
O1 C2 C7 114.9(2)
C3 C2 C7 119.9(3)
C4 C3 C2 120.8(3)
C4 C3 H3 119.6
C2 C3 H3 119.6
C5 C4 C3 120.3(3)
C5 C4 H4 119.9
C3 C4 H4 119.9
C4 C5 C6 120.9(3)
C4 C5 H5 119.6
C6 C5 H5 119.6
C7 C6 C5 119.6(3)
C7 C6 C8 121.8(2)
C5 C6 C8 118.5(3)
O2 C7 C6 121.7(2)
O2 C7 C2 119.7(3)
C6 C7 C2 118.5(2)
N1 C8 C6 126.4(3)
N1 C8 H8 116.8
C6 C8 H8 116.8
N1 C9 C10 112.3(2)
N1 C9 H9A 109.1
C10 C9 H9A 109.1
N1 C9 H9B 109.1
C10 C9 H9B 109.1
H9A C9 H9B 107.9
C11 C10 C9 113.3(2)
C11 C10 H10A 108.9
C9 C10 H10A 108.9
C11 C10 H10B 108.9
C9 C10 H10B 108.9
H10A C10 H10B 107.7
N2 C11 C12 121.2(3)
N2 C11 C10 118.0(2)
C12 C11 C10 120.8(3)
C11 C12 C13 119.7(3)
C11 C12 H12 120.1
C13 C12 H12 120.1
C14 C13 C12 119.6(3)
C14 C13 H13 120.2
C12 C13 H13 120.2
C13 C14 C15 118.3(3)
C13 C14 H14 120.9
C15 C14 H14 120.9
N2 C15 C14 123.4(3)
N2 C15 H15 118.3
C14 C15 H15 118.3
O3 C16 H16A 109.5
O3 C16 H16B 109.5
H16A C16 H16B 109.5
O3 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
O3 C17 C18 123.2(2)
O3 C17 C22 115.6(2)
C18 C17 C22 121.2(2)
C17 C18 C19 120.6(3)
C17 C18 H18 119.7
C19 C18 H18 119.7
C20 C19 C18 119.1(3)
C20 C19 H19 120.5
C18 C19 H19 120.5
C19 C20 C21 121.4(3)
C19 C20 H20 119.3
C21 C20 H20 119.3
C20 C21 C22 120.7(3)
C20 C21 C23 117.4(2)
C22 C21 C23 121.9(2)
O4 C22 C21 122.3(2)
O4 C22 C17 120.7(2)
C21 C22 C17 117.0(2)
N3 C23 C21 125.7(2)
N3 C23 H23 117.1
C21 C23 H23 117.1
N3 C24 C25 113.0(2)
N3 C24 H24A 109.0
C25 C24 H24A 109.0
N3 C24 H24B 109.0
C25 C24 H24B 109.0
H24A C24 H24B 107.8
C26 C25 C24 113.2(3)
C26 C25 H25A 108.9
C24 C25 H25A 108.9
C26 C25 H25B 108.9
C24 C25 H25B 108.9
H25A C25 H25B 107.8
N4 C26 C27 120.6(3)
N4 C26 C25 118.3(2)
C27 C26 C25 121.1(3)
C28 C27 C26 120.3(3)
C28 C27 H27 119.9
C26 C27 H27 119.9
C29 C28 C27 118.7(3)
C29 C28 H28 120.6
C27 C28 H28 120.6
C28 C29 C30 118.9(3)
C28 C29 H29 120.5
C30 C29 H29 120.5
N4 C30 C29 122.8(3)
N4 C30 H30 118.6
C29 C30 H30 118.6
N8 C31 C32 178.2(5)
C31 C32 H32A 109.5
C31 C32 H32B 109.5
H32A C32 H32B 109.5
C31 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
O2 Ho1 O4 72.49(6)
O2 Ho1 O14 109.03(7)
O4 Ho1 O14 71.59(7)
O2 Ho1 O9 152.16(7)
O4 Ho1 O9 82.78(6)
O14 Ho1 O9 73.73(8)
O2 Ho1 O11 80.53(7)
O4 Ho1 O11 76.35(7)
O14 Ho1 O11 141.33(9)
O9 Ho1 O11 81.41(8)
O2 Ho1 O8 155.51(7)
O4 Ho1 O8 128.68(6)
O14 Ho1 O8 72.74(8)
O9 Ho1 O8 52.32(7)
O11 Ho1 O8 113.94(8)
O2 Ho1 O5 81.10(6)
O4 Ho1 O5 118.05(6)
O14 Ho1 O5 65.91(8)
O9 Ho1 O5 122.88(7)
O11 Ho1 O5 151.54(8)
O8 Ho1 O5 77.53(7)
O2 Ho1 O12 106.06(8)
O4 Ho1 O12 125.88(7)
O14 Ho1 O12 144.43(9)
O9 Ho1 O12 78.10(9)
O11 Ho1 O12 51.08(8)
O8 Ho1 O12 72.97(8)
O5 Ho1 O12 114.89(8)
O2 Ho1 O6 82.23(6)
O4 Ho1 O6 154.12(6)
O14 Ho1 O6 113.01(8)
O9 Ho1 O6 123.10(7)
O11 Ho1 O6 105.30(8)
O8 Ho1 O6 75.02(7)
O5 Ho1 O6 50.58(7)
O12 Ho1 O6 66.11(8)
O2 Ho1 N6 177.54(7)
O4 Ho1 N6 105.29(7)
O14 Ho1 N6 69.01(8)
O9 Ho1 N6 26.46(7)
O11 Ho1 N6 100.06(8)
O8 Ho1 N6 26.04(7)
O5 Ho1 N6 99.22(7)
O12 Ho1 N6 76.06(9)
O6 Ho1 N6 99.87(7)
O2 Ho1 N7 92.98(7)
O4 Ho1 N7 101.22(7)
O14 Ho1 N7 152.65(8)
O9 Ho1 N7 79.25(8)
O11 Ho1 N7 25.43(7)
O8 Ho1 N7 94.03(8)
O5 Ho1 N7 135.78(8)
O12 Ho1 N7 25.66(8)
O6 Ho1 N7 85.23(8)
N6 Ho1 N7 88.48(8)
O2 Ho1 N5 80.81(6)
O4 Ho1 N5 139.39(7)
O14 Ho1 N5 89.58(8)
O9 Ho1 N5 126.99(6)
O11 Ho1 N5 129.08(8)
O8 Ho1 N5 74.75(6)
O5 Ho1 N5 25.44(7)
O12 Ho1 N5 90.35(8)
O6 Ho1 N5 25.14(7)
N6 Ho1 N5 100.53(7)
N7 Ho1 N5 110.36(8)
C8 N1 C9 115.4(2)
C8 N1 Ni1 123.19(19)
C9 N1 Ni1 120.90(17)
C15 N2 C11 117.8(2)
C15 N2 Ni1 119.8(2)
C11 N2 Ni1 122.30(17)
C23 N3 C24 114.9(2)
C23 N3 Ni1 123.22(18)
C24 N3 Ni1 121.71(18)
C26 N4 C30 118.7(2)
C26 N4 Ni1 122.43(18)
C30 N4 Ni1 118.83(18)
O7 N5 O6 123.9(3)
O7 N5 O5 121.2(3)
O6 N5 O5 114.9(2)
O7 N5 Ho1 177.6(2)
O6 N5 Ho1 58.34(14)
O5 N5 Ho1 56.55(13)
O10 N6 O8 121.9(3)
O10 N6 O9 121.5(3)
O8 N6 O9 116.6(2)
O10 N6 Ho1 171.5(2)
O8 N6 Ho1 59.64(12)
O9 N6 Ho1 57.57(13)
O13 N7 O11 122.2(3)
O13 N7 O12 122.5(3)
O11 N7 O12 115.3(3)
O13 N7 Ho1 178.2(2)
O11 N7 Ho1 56.56(14)
O12 N7 Ho1 58.82(15)
N3 Ni1 O2 95.37(8)
N3 Ni1 N1 178.37(8)
O2 Ni1 N1 83.05(8)
N3 Ni1 O4 83.93(7)
O2 Ni1 O4 80.61(6)
N1 Ni1 O4 95.37(7)
N3 Ni1 N2 91.58(9)
O2 Ni1 N2 171.09(7)
N1 Ni1 N2 89.95(9)
O4 Ni1 N2 94.63(7)
N3 Ni1 N4 89.07(8)
O2 Ni1 N4 95.16(8)
N1 Ni1 N4 91.50(8)
O4 Ni1 N4 171.41(8)
N2 Ni1 N4 90.51(8)
N3 Ni1 Ho1 91.89(6)
O2 Ni1 Ho1 39.42(4)
N1 Ni1 Ho1 86.62(5)
O4 Ni1 Ho1 41.29(4)
N2 Ni1 Ho1 134.94(6)
N4 Ni1 Ho1 134.45(6)
C2 O1 C1 117.8(3)
C7 O2 Ni1 118.44(15)
C7 O2 Ho1 125.60(14)
Ni1 O2 Ho1 104.73(7)
C17 O3 C16 117.4(2)
C22 O4 Ni1 117.27(13)
C22 O4 Ho1 132.14(14)
Ni1 O4 Ho1 101.99(7)
N5 O5 Ho1 98.01(16)
N5 O6 Ho1 96.52(16)
N6 O8 Ho1 94.32(15)
N6 O9 Ho1 95.97(16)
N7 O11 Ho1 98.01(18)
N7 O12 Ho1 95.52(17)
Ho1 O14 H1W 105(2)
Ho1 O14 H2W 126(3)
H1W O14 H2W 116(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 O1 1.413(4)
C1 H1A 0.9600
C1 H1B 0.9600
C1 H1C 0.9600
C2 O1 1.364(4)
C2 C3 1.386(4)
C2 C7 1.416(4)
C3 C4 1.378(6)
C3 H3 0.9300
C4 C5 1.359(5)
C4 H4 0.9300
C5 C6 1.407(4)
C5 H5 0.9300
C6 C7 1.401(4)
C6 C8 1.447(4)
C7 O2 1.334(3)
C8 N1 1.279(3)
C8 H8 0.9300
C9 N1 1.473(3)
C9 C10 1.509(4)
C9 H9A 0.9700
C9 H9B 0.9700
C10 C11 1.502(4)
C10 H10A 0.9700
C10 H10B 0.9700
C11 N2 1.347(4)
C11 C12 1.375(4)
C12 C13 1.378(5)
C12 H12 0.9300
C13 C14 1.358(6)
C13 H13 0.9300
C14 C15 1.372(4)
C14 H14 0.9300
C15 N2 1.347(3)
C15 H15 0.9300
C16 O3 1.428(3)
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 O3 1.376(3)
C17 C18 1.378(4)
C17 C22 1.418(3)
C18 C19 1.396(4)
C18 H18 0.9300
C19 C20 1.363(4)
C19 H19 0.9300
C20 C21 1.396(4)
C20 H20 0.9300
C21 C22 1.405(4)
C21 C23 1.454(4)
C22 O4 1.328(3)
C23 N3 1.273(3)
C23 H23 0.9300
C24 N3 1.474(3)
C24 C25 1.507(5)
C24 H24A 0.9700
C24 H24B 0.9700
C25 C26 1.498(4)
C25 H25A 0.9700
C25 H25B 0.9700
C26 N4 1.335(4)
C26 C27 1.393(4)
C27 C28 1.375(5)
C27 H27 0.9300
C28 C29 1.364(5)
C28 H28 0.9300
C29 C30 1.375(4)
C29 H29 0.9300
C30 N4 1.347(4)
C30 H30 0.9300
C31 N8 1.119(5)
C31 C32 1.448(6)
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
Ho1 O2 2.2668(16)
Ho1 O4 2.3292(16)
Ho1 O14 2.366(2)
Ho1 O9 2.418(2)
Ho1 O11 2.429(2)
Ho1 O8 2.4654(18)
Ho1 O5 2.4714(19)
Ho1 O12 2.478(2)
Ho1 O6 2.513(2)
Ho1 N6 2.849(2)
Ho1 N7 2.883(3)
Ho1 N5 2.933(2)
N1 Ni1 2.094(2)
N2 Ni1 2.115(2)
N3 Ni1 2.076(2)
N4 Ni1 2.118(2)
N5 O7 1.211(3)
N5 O6 1.254(3)
N5 O5 1.272(3)
N6 O10 1.216(3)
N6 O8 1.254(3)
N6 O9 1.276(3)
N7 O13 1.211(3)
N7 O11 1.250(3)
N7 O12 1.254(3)
Ni1 O2 2.0910(17)
Ni1 O4 2.1105(15)
O14 H1W 0.86(4)
O14 H2W 0.81(4)
