#------------------------------------------------------------------------------
#$Date: 2019-11-17 13:32:49 +0200 (Sun, 17 Nov 2019) $
#$Revision: 230185 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/70/7057009.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7057009
loop_
_publ_author_name
'Moreno-Alcántar, Guillermo'
'Romo-Islas, Guillermo'
'Flores-Álamo, Marcos'
'Torrens, Hugo'
_publ_section_title
;
 Aurophilicity vs. thiophilicity: directing the crystalline supramolecular
 arrangement in luminescent gold compounds
;
_journal_issue                   10
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              7845
_journal_paper_doi               10.1039/C7NJ04354F
_journal_volume                  42
_journal_year                    2018
_chemical_formula_sum            'C38 H32 Au2 F2 P2 S2'
_chemical_formula_weight         1046.63
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2017-08-31T18:15:04-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2017-11-07 deposited with the CCDC.
2018-02-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.857(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.5947(5)
_cell_length_b                   19.9982(10)
_cell_length_c                   15.8994(7)
_cell_measurement_reflns_used    6538
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      29.107
_cell_measurement_theta_min      3.907
_cell_volume                     3488.8(3)
_computing_cell_refinement
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics
;
          'Ortep-3 for Windows (Farrugia, 1997)'
      L. J. Farrugia, J. Appl. Crystallogr., 1997, 30, 565.
;
_computing_publication_material
;    
        'WinGX publication routines (Farrugia, 1999)'                 
    L. J. Farrugia, J. Appl. Crystallogr., 1999, 32, 837-838.
;
_computing_structure_refinement
;
      'SHELXS-2014 (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. C71, 3--8.
;
_computing_structure_solution
;
      'SHELXS-2014 (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. A71, 3--8.
;
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 10.4685
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.853
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0169196
_diffrn_orient_matrix_UB_12      -0.0310189
_diffrn_orient_matrix_UB_13      0.0142327
_diffrn_orient_matrix_UB_21      -0.0472341
_diffrn_orient_matrix_UB_22      0.0161377
_diffrn_orient_matrix_UB_23      0.0115624
_diffrn_orient_matrix_UB_31      -0.0407847
_diffrn_orient_matrix_UB_32      -0.0058777
_diffrn_orient_matrix_UB_33      -0.0434305
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0562
_diffrn_reflns_av_unetI/netI     0.0788
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.853
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            20116
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.853
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.556
_diffrn_reflns_theta_min         3.576
_exptl_absorpt_coefficient_mu    8.65
_exptl_absorpt_correction_T_max  0.334
_exptl_absorpt_correction_T_min  0.118
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
Analytical numeric absorption correction using a multifaceted crystal
                        model based on expressions derived by R.C. Clark & J.S.
        (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.993
_exptl_crystal_description       block
_exptl_crystal_F_000             1992
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.45
_refine_diff_density_min         -2.747
_refine_diff_density_rms         0.203
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         8324
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.078
_refine_ls_R_factor_gt           0.0552
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0345P)²+15.1760P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1113
_refine_ls_wR_factor_ref         0.1239
_reflns_Friedel_coverage         0
_reflns_number_gt                6287
_reflns_number_total             8324
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7nj04354f2.cif
_cod_data_source_block           6-gmeaufb
_cod_depositor_comments
'Adding full bibliography for 7057004--7057010.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7057009
_shelx_estimated_absorpt_t_min   0.129
_shelx_estimated_absorpt_t_max   0.399
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.32180(3) 0.36083(2) 0.08922(2) 0.02777(10) Uani 1 1 d . . . . .
Au2 Au 0.16889(3) 0.35310(2) -0.10408(2) 0.02794(10) Uani 1 1 d . . . . .
C32 C 0.1448(8) 0.4504(4) 0.1723(6) 0.037(2) Uani 1 1 d . . . . .
C25 C 0.0346(9) 0.4808(5) 0.1677(8) 0.048(3) Uani 1 1 d . . . . .
H8 H -0.020065 0.494769 0.111883 0.057 Uiso 1 1 calc R U . . .
C9 C 0.0049(10) 0.4905(5) 0.2441(8) 0.055(3) Uani 1 1 d . . . . .
H9 H -0.070739 0.510921 0.240175 0.066 Uiso 1 1 calc R U . . .
C10 C 0.0810(11) 0.4717(5) 0.3245(9) 0.059(3) Uani 1 1 d . . . . .
H10 H 0.060767 0.478857 0.377125 0.071 Uiso 1 1 calc R U . . .
C11 C 0.1881(12) 0.4421(6) 0.3273(7) 0.060(3) Uani 1 1 d . . . . .
C12 C 0.2219(9) 0.4295(5) 0.2534(6) 0.046(3) Uani 1 1 d . . . . .
H12 H 0.295967 0.407049 0.258219 0.055 Uiso 1 1 calc R U . . .
C13 C -0.1181(7) 0.2937(4) -0.1160(5) 0.0264(18) Uani 1 1 d . . . . .
C14 C -0.1521(8) 0.3604(5) -0.1201(6) 0.039(2) Uani 1 1 d . . . . .
H14 H -0.094251 0.394246 -0.119518 0.046 Uiso 1 1 calc R U . . .
C15 C -0.2695(8) 0.3782(5) -0.1251(6) 0.041(2) Uani 1 1 d . . . . .
H15 H -0.292317 0.423996 -0.128493 0.049 Uiso 1 1 calc R U . . .
C16 C -0.3521(9) 0.3299(5) -0.1252(6) 0.041(2) Uani 1 1 d . . . . .
H16 H -0.432301 0.342347 -0.127968 0.049 Uiso 1 1 calc R U . . .
C17 C -0.3207(8) 0.2629(5) -0.1212(6) 0.042(2) Uani 1 1 d . . . . .
H17 H -0.379698 0.229648 -0.122371 0.05 Uiso 1 1 calc R U . . .
C18 C -0.2038(7) 0.2445(4) -0.1155(5) 0.0296(19) Uani 1 1 d . . . . .
H18 H -0.1815 0.198584 -0.111334 0.036 Uiso 1 1 calc R U . . .
C19 C 0.0794(7) 0.2103(4) -0.0195(5) 0.0273(18) Uani 1 1 d . . . . .
C20 C 0.1060(7) 0.2351(4) 0.0659(5) 0.0276(18) Uani 1 1 d . . . . .
H20 H 0.101973 0.28186 0.074757 0.033 Uiso 1 1 calc R U . . .
C21 C 0.1385(8) 0.1927(5) 0.1386(5) 0.035(2) Uani 1 1 d . . . . .
H21 H 0.158777 0.210528 0.19703 0.042 Uiso 1 1 calc R U . . .
C22 C 0.1411(9) 0.1256(5) 0.1262(6) 0.044(2) Uani 1 1 d . . . . .
H22 H 0.162381 0.096601 0.176164 0.053 Uiso 1 1 calc R U . . .
C23 C 0.1133(10) 0.0990(5) 0.0419(6) 0.050(3) Uani 1 1 d . . . . .
H23 H 0.114641 0.051996 0.033736 0.06 Uiso 1 1 calc R U . . .
C24 C 0.0832(8) 0.1420(5) -0.0310(6) 0.036(2) Uani 1 1 d . . . . .
H24 H 0.065216 0.12407 -0.089201 0.043 Uiso 1 1 calc R U . . .
C8 C 0.0126(7) 0.2214(4) -0.2120(5) 0.0277(19) Uani 1 1 d . . . . .
H25A H 0.088969 0.197858 -0.208725 0.033 Uiso 1 1 calc R U . . .
H25B H -0.052053 0.187562 -0.218633 0.033 Uiso 1 1 calc R U . . .
C26 C 0.4140(6) 0.2125(4) 0.0186(5) 0.0232(17) Uani 1 1 d . . . . .
C27 C 0.3915(7) 0.2326(5) -0.0692(5) 0.031(2) Uani 1 1 d . . . . .
H27 H 0.399296 0.278393 -0.0822 0.038 Uiso 1 1 calc R U . . .
C28 C 0.3582(8) 0.1867(5) -0.1372(5) 0.040(2) Uani 1 1 d . . . . .
H28 H 0.342543 0.201003 -0.196808 0.048 Uiso 1 1 calc R U . . .
C29 C 0.3474(8) 0.1199(6) -0.1190(6) 0.046(3) Uani 1 1 d . . . . .
H29 H 0.32359 0.088295 -0.166034 0.055 Uiso 1 1 calc R U . . .
C30 C 0.3711(9) 0.0996(5) -0.0335(7) 0.050(3) Uani 1 1 d . . . . .
H30 H 0.365827 0.053413 -0.021042 0.06 Uiso 1 1 calc R U . . .
C31 C 0.4026(8) 0.1450(5) 0.0354(6) 0.038(2) Uani 1 1 d . . . . .
H31 H 0.416678 0.130125 0.094656 0.045 Uiso 1 1 calc R U . . .
C7 C 0.4764(7) 0.2314(4) 0.2084(4) 0.0263(18) Uani 1 1 d . . . . .
H32A H 0.399538 0.208369 0.205208 0.032 Uiso 1 1 calc R U . . .
H32B H 0.54041 0.19697 0.21627 0.032 Uiso 1 1 calc R U . . .
C33 C 0.6079(7) 0.3002(4) 0.1085(5) 0.0256(18) Uani 1 1 d . . . . .
C34 C 0.6373(8) 0.3665(5) 0.1046(6) 0.041(2) Uani 1 1 d . . . . .
H34 H 0.577884 0.400116 0.100658 0.05 Uiso 1 1 calc R U . . .
C35 C 0.7549(9) 0.3844(5) 0.1064(7) 0.050(3) Uani 1 1 d . . . . .
H35 H 0.774662 0.430105 0.102026 0.06 Uiso 1 1 calc R U . . .
C36 C 0.8420(8) 0.3357(6) 0.1144(6) 0.043(2) Uani 1 1 d . . . . .
H36 H 0.922439 0.347663 0.117145 0.052 Uiso 1 1 calc R U . . .
C37 C 0.8112(8) 0.2702(5) 0.1183(6) 0.040(2) Uani 1 1 d . . . . .
H37 H 0.87075 0.236448 0.123639 0.047 Uiso 1 1 calc R U . . .
C38 C 0.6950(8) 0.2525(5) 0.1147(5) 0.035(2) Uani 1 1 d . . . . .
H38 H 0.674947 0.206557 0.1165 0.042 Uiso 1 1 calc R U . . .
F1 F 0.2709(7) 0.4227(4) 0.4076(4) 0.081(2) Uani 1 1 d . . . . .
P1 P 0.45581(18) 0.27651(11) 0.10433(12) 0.0237(5) Uani 1 1 d . . . . .
P2 P 0.03433(18) 0.26945(11) -0.11067(12) 0.0232(4) Uani 1 1 d . . . . .
S1 S 0.1778(2) 0.44371(13) 0.07228(16) 0.0464(7) Uani 1 1 d . . . . .
C1 C 0.3231(12) 0.4392(8) -0.2157(6) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
C2 C 0.2346(10) 0.4152(8) -0.2913(7) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
H2 H 0.166386 0.391366 -0.286083 0.044 Uiso 0.638(10) 1 calc R U P A 1
C3 C 0.2461(10) 0.4259(6) -0.3746(6) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
H3 H 0.185646 0.409465 -0.426338 0.044 Uiso 0.638(10) 1 calc R U P A 1
C4 C 0.3460(10) 0.4607(6) -0.3823(6) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
H4 H 0.35379 0.468069 -0.439263 0.044 Uiso 0.638(10) 1 calc R U P A 1
C5 C 0.4344(8) 0.4848(5) -0.3067(7) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
C6 C 0.4230(10) 0.4740(6) -0.2234(6) 0.0368(18) Uani 0.638(10) 1 d G . P A 1
H6 H 0.483417 0.490475 -0.171676 0.044 Uiso 0.638(10) 1 calc R U P A 1
F2 F 0.5234(9) 0.5178(5) -0.3180(7) 0.067(3) Uani 0.638(10) 1 d . . P A 1
S2 S 0.3162(12) 0.4295(6) -0.1075(5) 0.0334(13) Uani 0.638(10) 1 d . . P A 1
C1P C 0.339(2) 0.4438(15) -0.1911(11) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
C2P C 0.4482(18) 0.4752(12) -0.1868(10) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
H2P H 0.503 0.489017 -0.131052 0.044 Uiso 0.362(10) 1 calc R U P A 2
C3P C 0.4766(15) 0.4863(10) -0.2641(13) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
H3P H 0.550905 0.507748 -0.261227 0.044 Uiso 0.362(10) 1 calc R U P A 2
C4P C 0.3964(18) 0.4660(10) -0.3457(11) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
H4P H 0.415816 0.473634 -0.398557 0.044 Uiso 0.362(10) 1 calc R U P A 2
C5P C 0.2877(17) 0.4346(12) -0.3500(10) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
C6P C 0.2592(18) 0.4235(15) -0.2726(14) 0.0368(18) Uani 0.362(10) 1 d G . P A 2
H6P H 0.184914 0.40206 -0.275542 0.044 Uiso 0.362(10) 1 calc R U P A 2
F2P F 0.1944(19) 0.4192(10) -0.4284(12) 0.073(6) Uani 0.362(10) 1 d . . P A 2
S2P S 0.318(2) 0.4363(13) -0.0851(9) 0.0334(13) Uani 0.362(10) 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-4 -27 0 0.1445
4 27 0 0.1445
-4 7 -18 0.1831
4 -7 18 0.1831
15 -7 -13 0.0662
-15 7 13 0.0662
-15 2 -2 0.1784
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
P1 Au1 S1 177.49(9) .
P1 Au1 Au2 103.20(5) .
S1 Au1 Au2 75.69(6) .
P2 Au2 S2 172.8(3) .
P2 Au2 S2P 175.1(5) .
P2 Au2 Au1 104.72(5) .
S2 Au2 Au1 78.13(19) .
S2P Au2 Au1 70.5(4) .
C12 C32 C25 119.2(10) .
C12 C32 S1 124.0(8) .
C25 C32 S1 116.7(8) .
C9 C25 C32 120.0(10) .
C9 C25 H8 120 .
C32 C25 H8 120 .
C10 C9 C25 121.4(10) .
C10 C9 H9 119.3 .
C25 C9 H9 119.3 .
C9 C10 C11 117.5(11) .
C9 C10 H10 121.2 .
C11 C10 H10 121.2 .
C10 C11 C12 124.0(11) .
C10 C11 F1 120.4(11) .
C12 C11 F1 115.6(11) .
C32 C12 C11 117.8(10) .
C32 C12 H12 121.1 .
C11 C12 H12 121.1 .
C14 C13 C18 119.0(8) .
C14 C13 P2 121.3(7) .
C18 C13 P2 119.7(7) .
C15 C14 C13 120.6(9) .
C15 C14 H14 119.7 .
C13 C14 H14 119.7 .
C16 C15 C14 119.8(9) .
C16 C15 H15 120.1 .
C14 C15 H15 120.1 .
C15 C16 C17 120.9(9) .
C15 C16 H16 119.6 .
C17 C16 H16 119.6 .
C18 C17 C16 120.0(9) .
C18 C17 H17 120 .
C16 C17 H17 120 .
C17 C18 C13 119.7(9) .
C17 C18 H18 120.1 .
C13 C18 H18 120.1 .
C24 C19 C20 118.5(8) .
C24 C19 P2 123.6(6) .
C20 C19 P2 117.9(7) .
C19 C20 C21 121.1(8) .
C19 C20 H20 119.5 .
C21 C20 H20 119.5 .
C22 C21 C20 119.7(8) .
C22 C21 H21 120.2 .
C20 C21 H21 120.2 .
C21 C22 C23 120.9(9) .
C21 C22 H22 119.5 .
C23 C22 H22 119.5 .
C22 C23 C24 119.2(9) .
C22 C23 H23 120.4 .
C24 C23 H23 120.4 .
C19 C24 C23 120.6(9) .
C19 C24 H24 119.7 .
C23 C24 H24 119.7 .
C7 C8 P2 109.3(6) 4_565
C7 C8 H25A 109.8 4_565
P2 C8 H25A 109.8 .
C7 C8 H25B 109.8 4_565
P2 C8 H25B 109.8 .
H25A C8 H25B 108.3 .
C31 C26 C27 118.2(8) .
C31 C26 P1 123.9(6) .
C27 C26 P1 117.8(6) .
C28 C27 C26 120.7(9) .
C28 C27 H27 119.7 .
C26 C27 H27 119.7 .
C27 C28 C29 120.2(8) .
C27 C28 H28 119.9 .
C29 C28 H28 119.9 .
C30 C29 C28 119.8(9) .
C30 C29 H29 120.1 .
C28 C29 H29 120.1 .
C29 C30 C31 120.9(10) .
C29 C30 H30 119.6 .
C31 C30 H30 119.6 .
C30 C31 C26 120.3(9) .
C30 C31 H31 119.9 .
C26 C31 H31 119.9 .
C8 C7 P1 111.5(6) 4_666
C8 C7 H32A 109.3 4_666
P1 C7 H32A 109.3 .
C8 C7 H32B 109.3 4_666
P1 C7 H32B 109.3 .
H32A C7 H32B 108 .
C38 C33 C34 119.2(8) .
C38 C33 P1 120.5(7) .
C34 C33 P1 120.3(7) .
C33 C34 C35 119.9(9) .
C33 C34 H34 120 .
C35 C34 H34 120 .
C36 C35 C34 120.0(10) .
C36 C35 H35 120 .
C34 C35 H35 120 .
C37 C36 C35 119.2(9) .
C37 C36 H36 120.4 .
C35 C36 H36 120.4 .
C36 C37 C38 120.8(9) .
C36 C37 H37 119.6 .
C38 C37 H37 119.6 .
C33 C38 C37 120.8(9) .
C33 C38 H38 119.6 .
C37 C38 H38 119.6 .
C33 P1 C26 103.5(4) .
C33 P1 C7 104.8(4) .
C26 P1 C7 104.8(4) .
C33 P1 Au1 116.0(3) .
C26 P1 Au1 116.1(2) .
C7 P1 Au1 110.4(3) .
C13 P2 C19 103.7(4) .
C13 P2 C8 104.3(4) .
C19 P2 C8 106.6(4) .
C13 P2 Au2 116.9(3) .
C19 P2 Au2 115.4(3) .
C8 P2 Au2 109.1(3) .
C32 S1 Au1 108.1(3) .
C2 C1 C6 120 .
C2 C1 S2 123.7(7) .
C6 C1 S2 116.3(7) .
C1 C2 C3 120 .
C1 C2 H2 120 .
C3 C2 H2 120 .
C4 C3 C2 120 .
C4 C3 H3 120 .
C2 C3 H3 120 .
C3 C4 C5 120 .
C3 C4 H4 120 .
C5 C4 H4 120 .
F2 C5 C6 122.8(8) .
F2 C5 C4 117.2(8) .
C6 C5 C4 120 .
C5 C6 C1 120 .
C5 C6 H6 120 .
C1 C6 H6 120 .
C1 S2 Au2 111.4(5) .
C2P C1P C6P 120 .
C2P C1P S2P 113.1(14) .
C6P C1P S2P 126.9(14) .
C1P C2P C3P 120 .
C1P C2P H2P 120 .
C3P C2P H2P 120 .
C4P C3P C2P 120 .
C4P C3P H3P 120 .
C2P C3P H3P 120 .
C3P C4P C5P 120 .
C3P C4P H4P 120 .
C5P C4P H4P 120 .
C4P C5P C6P 120 .
C4P C5P F2P 124.9(15) .
C6P C5P F2P 114.7(15) .
C5P C6P C1P 120 .
C5P C6P H6P 120 .
C1P C6P H6P 120 .
C1P S2P Au2 105.0(11) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.253(2) .
Au1 S1 2.305(2) .
Au1 Au2 3.0151(4) .
Au2 P2 2.267(2) .
Au2 S2 2.306(12) .
Au2 S2P 2.35(2) .
C32 C12 1.375(12) .
C32 C25 1.396(13) .
C32 S1 1.756(10) .
C25 C9 1.381(15) .
C25 H8 0.95 .
C9 C10 1.351(15) .
C9 H9 0.95 .
C10 C11 1.363(16) .
C10 H10 0.95 .
C11 C12 1.377(15) .
C11 F1 1.382(12) .
C12 H12 0.95 .
C13 C14 1.387(12) .
C13 C18 1.401(11) .
C13 P2 1.808(8) .
C14 C15 1.385(13) .
C14 H14 0.95 .
C15 C16 1.359(13) .
C15 H15 0.95 .
C16 C17 1.385(14) .
C16 H16 0.95 .
C17 C18 1.379(12) .
C17 H17 0.95 .
C18 H18 0.95 .
C19 C24 1.382(12) .
C19 C20 1.383(11) .
C19 P2 1.811(8) .
C20 C21 1.384(11) .
C20 H20 0.95 .
C21 C22 1.359(13) .
C21 H21 0.95 .
C22 C23 1.379(13) .
C22 H22 0.95 .
C23 C24 1.394(13) .
C23 H23 0.95 .
C24 H24 0.95 .
C8 C7 1.525(11) 4_565
C8 P2 1.821(8) .
C8 H25A 0.99 .
C8 H25B 0.99 .
C26 C31 1.391(12) .
C26 C27 1.394(11) .
C26 P1 1.817(8) .
C27 C28 1.374(12) .
C27 H27 0.95 .
C28 C29 1.381(14) .
C28 H28 0.95 .
C29 C30 1.359(14) .
C29 H29 0.95 .
C30 C31 1.379(13) .
C30 H30 0.95 .
C31 H31 0.95 .
C7 P1 1.831(7) .
C7 H32A 0.99 .
C7 H32B 0.99 .
C33 C38 1.370(12) .
C33 C34 1.374(12) .
C33 P1 1.807(8) .
C34 C35 1.402(13) .
C34 H34 0.95 .
C35 C36 1.378(14) .
C35 H35 0.95 .
C36 C37 1.365(14) .
C36 H36 0.95 .
C37 C38 1.376(12) .
C37 H37 0.95 .
C38 H38 0.95 .
C1 C2 1.39 .
C1 C6 1.39 .
C1 S2 1.758(10) .
C2 C3 1.39 .
C2 H2 0.95 .
C3 C4 1.39 .
C3 H3 0.95 .
C4 C5 1.39 .
C4 H4 0.95 .
C5 F2 1.287(12) .
C5 C6 1.39 .
C6 H6 0.95 .
C1P C2P 1.39 .
C1P C6P 1.39 .
C1P S2P 1.79(2) .
C2P C3P 1.39 .
C2P H2P 0.95 .
C3P C4P 1.39 .
C3P H3P 0.95 .
C4P C5P 1.39 .
C4P H4P 0.95 .
C5P C6P 1.39 .
C5P F2P 1.40(2) .
C6P H6P 0.95 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C12 C32 C25 C9 1.1(14) .
S1 C32 C25 C9 -177.1(8) .
C32 C25 C9 C10 0.5(16) .
C25 C9 C10 C11 -0.6(16) .
C9 C10 C11 C12 -1.0(18) .
C9 C10 C11 F1 178.9(10) .
C25 C32 C12 C11 -2.6(14) .
S1 C32 C12 C11 175.5(8) .
C10 C11 C12 C32 2.6(17) .
F1 C11 C12 C32 -177.3(9) .
C18 C13 C14 C15 -1.0(13) .
P2 C13 C14 C15 179.3(7) .
C13 C14 C15 C16 0.6(14) .
C14 C15 C16 C17 -0.7(15) .
C15 C16 C17 C18 1.1(14) .
C16 C17 C18 C13 -1.5(13) .
C14 C13 C18 C17 1.4(12) .
P2 C13 C18 C17 -178.8(6) .
C24 C19 C20 C21 1.4(12) .
P2 C19 C20 C21 178.6(6) .
C19 C20 C21 C22 -1.8(13) .
C20 C21 C22 C23 0.8(15) .
C21 C22 C23 C24 0.6(16) .
C20 C19 C24 C23 0.0(14) .
P2 C19 C24 C23 -177.0(8) .
C22 C23 C24 C19 -1.0(15) .
C31 C26 C27 C28 0.5(12) .
P1 C26 C27 C28 -179.3(7) .
C26 C27 C28 C29 -0.4(13) .
C27 C28 C29 C30 -0.7(15) .
C28 C29 C30 C31 1.8(16) .
C29 C30 C31 C26 -1.7(15) .
C27 C26 C31 C30 0.6(13) .
P1 C26 C31 C30 -179.7(7) .
C38 C33 C34 C35 0.4(13) .
P1 C33 C34 C35 -178.9(7) .
C33 C34 C35 C36 -1.7(15) .
C34 C35 C36 C37 1.6(15) .
C35 C36 C37 C38 -0.2(15) .
C34 C33 C38 C37 1.0(12) .
P1 C33 C38 C37 -179.7(7) .
C36 C37 C38 C33 -1.1(14) .
C38 C33 P1 C26 -49.5(7) .
C34 C33 P1 C26 129.7(7) .
C38 C33 P1 C7 60.1(7) .
C34 C33 P1 C7 -120.7(7) .
C38 C33 P1 Au1 -177.9(5) .
C34 C33 P1 Au1 1.4(8) .
C31 C26 P1 C33 109.5(7) .
C27 C26 P1 C33 -70.8(7) .
C31 C26 P1 C7 -0.1(8) .
C27 C26 P1 C7 179.6(6) .
C31 C26 P1 Au1 -122.2(7) .
C27 C26 P1 Au1 57.5(7) .
C8 C7 P1 C33 71.2(6) 4_666
C8 C7 P1 C26 179.9(6) 4_666
C8 C7 P1 Au1 -54.4(6) 4_666
C14 C13 P2 C19 131.2(7) .
C18 C13 P2 C19 -48.5(7) .
C14 C13 P2 C8 -117.4(7) .
C18 C13 P2 C8 62.9(7) .
C14 C13 P2 Au2 3.0(8) .
C18 C13 P2 Au2 -176.7(5) .
C24 C19 P2 C13 104.4(8) .
C20 C19 P2 C13 -72.6(7) .
C24 C19 P2 C8 -5.3(8) .
C20 C19 P2 C8 177.7(6) .
C24 C19 P2 Au2 -126.5(7) .
C20 C19 P2 Au2 56.5(7) .
C7 C8 P2 C13 71.6(6) 4_565
C7 C8 P2 C19 -179.0(5) 4_565
C7 C8 P2 Au2 -53.9(6) 4_565
C12 C32 S1 Au1 22.3(9) .
C25 C32 S1 Au1 -159.6(6) .
C6 C1 C2 C3 0 .
S2 C1 C2 C3 179.0(13) .
C1 C2 C3 C4 0 .
C2 C3 C4 C5 0 .
C3 C4 C5 F2 -178.6(11) .
C3 C4 C5 C6 0 .
F2 C5 C6 C1 178.5(12) .
C4 C5 C6 C1 0 .
C2 C1 C6 C5 0 .
S2 C1 C6 C5 -179.0(12) .
C2 C1 S2 Au2 12.8(12) .
C6 C1 S2 Au2 -168.2(6) .
C6P C1P C2P C3P 0 .
S2P C1P C2P C3P -178(2) .
C1P C2P C3P C4P 0 .
C2P C3P C4P C5P 0 .
C3P C4P C5P C6P 0 .
C3P C4P C5P F2P 172(2) .
C4P C5P C6P C1P 0 .
F2P C5P C6P C1P -173.0(19) .
C2P C1P C6P C5P 0 .
S2P C1P C6P C5P 178(2) .
C2P C1P S2P Au2 -161.7(11) .
C6P C1P S2P Au2 20(2) .
