#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:21:29 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180179 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/75/7107552.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7107552
loop_
_publ_author_name
'Nicola Giri'
'William Clegg'
'Ross W. Harrington'
'Peter N. Horton'
'Michael B. Hursthouse'
'Stuart L. James'
_publ_section_title
;
 Selective formation of a polar incomplete coordination cage induced by
 remote ligand substituents
;
_journal_name_full               Chem.Commun.
_journal_page_first              4061
_journal_paper_doi               10.1039/c2cc17832j
_journal_volume                  48
_journal_year                    2012
_chemical_formula_moiety         'C212 H276 Ag6 N27 O9 P12 3+,3 N O3 -'
_chemical_formula_sum            'C212 H276 Ag6 N30 O18 P12'
_chemical_formula_weight         4551.55
_chemical_name_systematic        ?
_space_group_IT_number           148
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   30.408(2)
_cell_length_b                   30.408(2)
_cell_length_c                   53.007(6)
_cell_measurement_reflns_used    7899
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      2.910
_cell_volume                     42446(6)
_computing_cell_refinement
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
_computing_data_collection       'COLLECT (Hooft, R.W.W., 1998)'
_computing_data_reduction
'DENZO (Otwinowski & Minor, 1997) & COLLECT (Hooft, R.W.W., 1998)'
_computing_molecular_graphics    'ORTEP3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997b)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.955
_diffrn_measured_fraction_theta_max 0.882
_diffrn_measurement_device_type  'Bruker-Nonius KappaCCD'
_diffrn_measurement_method       'φ & ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Bruker-Nonius FR591 rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1128
_diffrn_reflns_av_sigmaI/netI    0.1873
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_h_min       -39
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       62
_diffrn_reflns_limit_l_min       -63
_diffrn_reflns_number            76905
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.92
_exptl_absorpt_coefficient_mu    0.53
_exptl_absorpt_correction_T_max  0.885
_exptl_absorpt_correction_T_min  0.834
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2.10 (Sheldrick, G.M., 2003)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.068
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             14184
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.24
_refine_diff_density_max         0.828
_refine_diff_density_min         -1.209
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1455
_refine_ls_number_reflns         19094
_refine_ls_number_restraints     7152
_refine_ls_restrained_S_all      0.918
_refine_ls_R_factor_all          0.2219
_refine_ls_R_factor_gt           0.1219
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3425
_refine_ls_wR_factor_ref         0.3760
_reflns_number_gt                7069
_reflns_number_total             19094
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc17832j.txt
_cod_data_source_block           2006src1214sq
_cod_original_cell_volume        42445(7)
_cod_original_sg_symbol_H-M      'R -3'
_cod_database_code               7107552
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1830(3) 0.5022(3) -0.02210(19) 0.0786(15) Uani 1 1 d U A .
H1A H 0.1512 0.4731 -0.0285 0.094 Uiso 1 1 calc R . .
H1B H 0.1764 0.5308 -0.0201 0.094 Uiso 1 1 calc R . .
C2 C 0.2420(3) 0.4783(3) -0.0417(2) 0.0824(16) Uani 1 1 d U B .
H2A H 0.2121 0.4439 -0.0438 0.099 Uiso 1 1 calc R . .
H2B H 0.2554 0.4801 -0.0245 0.099 Uiso 1 1 calc R . .
C3 C 0.1986(3) 0.5151(4) -0.0683(2) 0.0820(19) Uani 1 1 d U . .
H3A H 0.1801 0.4791 -0.0735 0.098 Uiso 1 1 calc R . .
H3B H 0.2265 0.5334 -0.0805 0.098 Uiso 1 1 calc R . .
C4 C 0.2227(3) 0.5174(3) -0.0431(2) 0.0793(14) Uani 1 1 d U . .
C5 C 0.2669(3) 0.5702(3) -0.03662(19) 0.073(2) Uani 1 1 d U . .
H5A H 0.2847 0.5875 -0.0521 0.110 Uiso 1 1 calc R . .
H5B H 0.2905 0.5667 -0.0253 0.110 Uiso 1 1 calc R . .
H5C H 0.2539 0.5900 -0.0283 0.110 Uiso 1 1 calc R . .
C6 C 0.3449(4) 0.6251(4) 0.0845(2) 0.088(2) Uani 1 1 d U A .
C7 C 0.3333 0.6667 0.0735(3) 0.084(2) Uani 1 3 d SU . .
C8 C 0.3333 0.6667 0.0447(3) 0.081(3) Uani 1 3 d SU . .
H8A H 0.3273 0.6337 0.0386 0.122 Uiso 0.33 1 calc PR . .
H8B H 0.3663 0.6936 0.0386 0.122 Uiso 0.33 1 calc PR . .
H8C H 0.3064 0.6727 0.0386 0.122 Uiso 0.33 1 calc PR . .
P1 P 0.19312(9) 0.48480(9) 0.00990(6) 0.0796(7) Uani 1 1 d DU . .
P2 P 0.29138(10) 0.48448(11) -0.06446(7) 0.0950(8) Uani 1 1 d DU . .
P3 P 0.46027(10) 0.61490(10) -0.07207(6) 0.0827(8) Uani 1 1 d DU . .
P4 P 0.29724(11) 0.55696(11) 0.07823(6) 0.0890(8) Uani 1 1 d DU . .
Ag1 Ag 0.26921(3) 0.53360(3) 0.035227(16) 0.0800(3) Uani 1 1 d U A .
Ag2 Ag 0.37512(3) 0.55475(3) -0.058789(17) 0.0845(3) Uani 1 1 d U A .
C11 C 0.1402(10) 0.4802(17) 0.0285(3) 0.0901(19) Uani 0.33(3) 1 d PDU A 1
C12 C 0.1446(9) 0.5228(15) 0.0409(6) 0.089(2) Uani 0.33(3) 1 d PDU A 1
H12 H 0.1757 0.5538 0.0390 0.107 Uiso 0.33(3) 1 calc PR A 1
C13 C 0.1075(9) 0.5242(12) 0.0556(6) 0.088(2) Uani 0.33(3) 1 d PDU A 1
H13 H 0.1137 0.5550 0.0632 0.106 Uiso 0.33(3) 1 calc PR A 1
C14 C 0.0610(8) 0.4795(11) 0.0592(5) 0.088(2) Uani 0.33(3) 1 d PDU A 1
C15 C 0.0552(11) 0.4364(12) 0.0471(6) 0.089(2) Uani 0.33(3) 1 d PDU A 1
H15 H 0.0241 0.4054 0.0491 0.106 Uiso 0.33(3) 1 calc PR A 1
C16 C 0.0932(13) 0.4366(15) 0.0323(5) 0.089(2) Uani 0.33(3) 1 d PDU A 1
H16 H 0.0867 0.4058 0.0244 0.107 Uiso 0.33(3) 1 calc PR A 1
C17 C 0.0373(12) 0.5221(11) 0.0906(9) 0.094(5) Uani 0.33(3) 1 d PDU A 1
H17A H 0.0685 0.5298 0.0996 0.141 Uiso 0.33(3) 1 calc PR A 1
H17B H 0.0099 0.5136 0.1027 0.141 Uiso 0.33(3) 1 calc PR A 1
H17C H 0.0432 0.5519 0.0807 0.141 Uiso 0.33(3) 1 calc PR A 1
C18 C -0.0187(11) 0.4302(11) 0.0824(8) 0.098(5) Uani 0.33(3) 1 d PDU A 1
H18A H -0.0427 0.4129 0.0686 0.146 Uiso 0.33(3) 1 calc PR A 1
H18B H -0.0364 0.4362 0.0963 0.146 Uiso 0.33(3) 1 calc PR A 1
H18C H -0.0051 0.4089 0.0883 0.146 Uiso 0.33(3) 1 calc PR A 1
N1 N 0.0229(8) 0.4788(10) 0.0735(6) 0.090(2) Uani 0.33(3) 1 d PDU A 1
C211 C 0.1390(5) 0.4814(9) 0.02536(18) 0.0899(18) Uani 0.67(3) 1 d PDU A 2
C212 C 0.1419(5) 0.5268(8) 0.0328(3) 0.088(2) Uani 0.67(3) 1 d PDU A 2
H212 H 0.1718 0.5582 0.0294 0.106 Uiso 0.67(3) 1 calc PR A 2
C213 C 0.1019(5) 0.5263(6) 0.0450(3) 0.089(2) Uani 0.67(3) 1 d PDU A 2
H213 H 0.1043 0.5576 0.0497 0.107 Uiso 0.67(3) 1 calc PR A 2
C214 C 0.0577(5) 0.4808(6) 0.0505(3) 0.088(2) Uani 0.67(3) 1 d PDU A 2
C215 C 0.0540(6) 0.4352(7) 0.0429(3) 0.088(2) Uani 0.67(3) 1 d PDU A 2
H215 H 0.0241 0.4038 0.0463 0.106 Uiso 0.67(3) 1 calc PR A 2
C216 C 0.0946(7) 0.4363(8) 0.0303(3) 0.0883(19) Uani 0.67(3) 1 d PDU A 2
H216 H 0.0919 0.4052 0.0250 0.106 Uiso 0.67(3) 1 calc PR A 2
C217 C 0.0280(5) 0.5269(5) 0.0757(5) 0.088(3) Uani 0.67(3) 1 d PDU A 2
H21A H 0.0620 0.5425 0.0832 0.132 Uiso 0.67(3) 1 calc PR A 2
H21B H 0.0028 0.5187 0.0891 0.132 Uiso 0.67(3) 1 calc PR A 2
H21C H 0.0265 0.5507 0.0638 0.132 Uiso 0.67(3) 1 calc PR A 2
C218 C -0.0252(6) 0.4326(6) 0.0710(4) 0.098(4) Uani 0.67(3) 1 d PDU A 2
H21D H -0.0360 0.4073 0.0575 0.147 Uiso 0.67(3) 1 calc PR A 2
H21E H -0.0534 0.4380 0.0755 0.147 Uiso 0.67(3) 1 calc PR A 2
H21F H -0.0149 0.4205 0.0857 0.147 Uiso 0.67(3) 1 calc PR A 2
N201 N 0.0171(4) 0.4798(5) 0.0623(4) 0.088(2) Uani 0.67(3) 1 d PDU A 2
C21 C 0.1811(8) 0.4199(5) 0.0099(5) 0.108(2) Uani 0.400(12) 1 d PDU A 1
C22 C 0.1496(9) 0.3818(8) -0.0066(5) 0.111(3) Uani 0.400(12) 1 d PDU A 1
H22 H 0.1323 0.3887 -0.0196 0.133 Uiso 0.400(12) 1 calc PR A 1
C23 C 0.1434(9) 0.3334(7) -0.0043(5) 0.113(2) Uani 0.400(12) 1 d PDU A 1
H23 H 0.1217 0.3079 -0.0159 0.136 Uiso 0.400(12) 1 calc PR A 1
C24 C 0.1674(8) 0.3210(6) 0.0141(4) 0.116(3) Uani 0.400(12) 1 d PDU A 1
C25 C 0.1992(9) 0.3594(7) 0.0308(5) 0.112(3) Uani 0.400(12) 1 d PDU A 1
H25 H 0.2162 0.3522 0.0438 0.134 Uiso 0.400(12) 1 calc PR A 1
C26 C 0.2064(9) 0.4089(7) 0.0286(5) 0.109(2) Uani 0.400(12) 1 d PDU A 1
H26 H 0.2285 0.4348 0.0399 0.131 Uiso 0.400(12) 1 calc PR A 1
C27 C 0.1272(14) 0.2346(9) -0.0037(6) 0.131(4) Uani 0.400(12) 1 d PDU A 1
H27A H 0.1196 0.2008 0.0019 0.196 Uiso 0.400(12) 1 calc PR A 1
H27B H 0.1451 0.2426 -0.0199 0.196 Uiso 0.400(12) 1 calc PR A 1
H27C H 0.0954 0.2352 -0.0056 0.196 Uiso 0.400(12) 1 calc PR A 1
C28 C 0.1763(12) 0.2551(9) 0.0367(6) 0.127(4) Uani 0.400(12) 1 d PDU A 1
H28A H 0.2033 0.2846 0.0455 0.191 Uiso 0.400(12) 1 calc PR A 1
H28B H 0.1893 0.2332 0.0309 0.191 Uiso 0.400(12) 1 calc PR A 1
H28C H 0.1477 0.2360 0.0483 0.191 Uiso 0.400(12) 1 calc PR A 1
N2 N 0.1590(9) 0.2722(6) 0.0151(5) 0.120(3) Uani 0.400(12) 1 d PDU A 1
C221 C 0.1780(6) 0.4187(4) 0.0061(3) 0.108(2) Uani 0.600(12) 1 d PDU A 2
C222 C 0.1406(7) 0.3846(6) -0.0103(4) 0.110(2) Uani 0.600(12) 1 d PDU A 2
H222 H 0.1227 0.3968 -0.0201 0.132 Uiso 0.600(12) 1 calc PR A 2
C223 C 0.1276(6) 0.3340(5) -0.0133(4) 0.113(3) Uani 0.600(12) 1 d PDU A 2
H223 H 0.1014 0.3127 -0.0247 0.136 Uiso 0.600(12) 1 calc PR A 2
C224 C 0.1531(6) 0.3150(4) 0.0006(3) 0.116(2) Uani 0.600(12) 1 d PDU A 2
C225 C 0.1898(6) 0.3483(5) 0.0171(4) 0.113(2) Uani 0.600(12) 1 d PDU A 2
H225 H 0.2069 0.3358 0.0272 0.135 Uiso 0.600(12) 1 calc PR A 2
C226 C 0.2035(7) 0.3997(5) 0.0198(4) 0.111(2) Uani 0.600(12) 1 d PDU A 2
H226 H 0.2301 0.4211 0.0310 0.133 Uiso 0.600(12) 1 calc PR A 2
C227 C 0.0973(8) 0.2291(6) -0.0165(5) 0.138(5) Uani 0.600(12) 1 d PDU A 2
H22A H 0.0759 0.2437 -0.0207 0.207 Uiso 0.600(12) 1 calc PR A 2
H22B H 0.0774 0.1977 -0.0069 0.207 Uiso 0.600(12) 1 calc PR A 2
H22C H 0.1096 0.2215 -0.0321 0.207 Uiso 0.600(12) 1 calc PR A 2
C228 C 0.1632(8) 0.2460(7) 0.0167(5) 0.126(4) Uani 0.600(12) 1 d PDU A 2
H22D H 0.1713 0.2657 0.0324 0.189 Uiso 0.600(12) 1 calc PR A 2
H22E H 0.1943 0.2491 0.0095 0.189 Uiso 0.600(12) 1 calc PR A 2
H22F H 0.1390 0.2102 0.0203 0.189 Uiso 0.600(12) 1 calc PR A 2
N202 N 0.1406(6) 0.2654(4) -0.0013(3) 0.122(3) Uani 0.600(12) 1 d PDU A 2
C31 C 0.2731(10) 0.4800(11) -0.0974(3) 0.116(2) Uani 0.452(13) 1 d PDU B 1
C32 C 0.3048(9) 0.5174(10) -0.1143(4) 0.120(3) Uani 0.452(13) 1 d PDU B 1
H32 H 0.3357 0.5450 -0.1082 0.143 Uiso 0.452(13) 1 calc PR B 1
C33 C 0.2936(8) 0.5163(9) -0.1399(4) 0.123(3) Uani 0.452(13) 1 d PDU B 1
H33 H 0.3164 0.5427 -0.1508 0.148 Uiso 0.452(13) 1 calc PR B 1
C34 C 0.2488(8) 0.4763(8) -0.1493(3) 0.128(3) Uani 0.452(13) 1 d PDU B 1
C35 C 0.2166(9) 0.4387(9) -0.1324(4) 0.124(3) Uani 0.452(13) 1 d PDU B 1
H35 H 0.1855 0.4111 -0.1384 0.148 Uiso 0.452(13) 1 calc PR B 1
C36 C 0.2290(11) 0.4408(10) -0.1070(4) 0.118(3) Uani 0.452(13) 1 d PDU B 1
H36 H 0.2063 0.4144 -0.0961 0.141 Uiso 0.452(13) 1 calc PR B 1
C37 C 0.2727(10) 0.5107(11) -0.1917(4) 0.142(5) Uani 0.452(13) 1 d PDU B 1
H37A H 0.2643 0.5375 -0.1946 0.213 Uiso 0.452(13) 1 calc PR B 1
H37B H 0.2713 0.4940 -0.2077 0.213 Uiso 0.452(13) 1 calc PR B 1
H37C H 0.3070 0.5256 -0.1846 0.213 Uiso 0.452(13) 1 calc PR B 1
C38 C 0.1951(11) 0.4259(10) -0.1838(5) 0.143(4) Uani 0.452(13) 1 d PDU B 1
H38A H 0.1887 0.3981 -0.1723 0.214 Uiso 0.452(13) 1 calc PR B 1
H38B H 0.2044 0.4191 -0.2005 0.214 Uiso 0.452(13) 1 calc PR B 1
H38C H 0.1643 0.4284 -0.1853 0.214 Uiso 0.452(13) 1 calc PR B 1
N3 N 0.2363(8) 0.4734(9) -0.1741(3) 0.134(3) Uani 0.452(13) 1 d PDU B 1
C231 C 0.2666(8) 0.4718(9) -0.0963(3) 0.115(2) Uani 0.548(13) 1 d PDU B 2
C232 C 0.2915(7) 0.5068(9) -0.1151(4) 0.120(3) Uani 0.548(13) 1 d PDU B 2
H232 H 0.3213 0.5378 -0.1110 0.144 Uiso 0.548(13) 1 calc PR B 2
C233 C 0.2743(7) 0.4981(8) -0.1398(4) 0.124(3) Uani 0.548(13) 1 d PDU B 2
H233 H 0.2921 0.5228 -0.1525 0.149 Uiso 0.548(13) 1 calc PR B 2
C234 C 0.2307(7) 0.4527(7) -0.1457(3) 0.129(3) Uani 0.548(13) 1 d PDU B 2
C235 C 0.2051(8) 0.4171(8) -0.1268(3) 0.123(3) Uani 0.548(13) 1 d PDU B 2
H235 H 0.1752 0.3860 -0.1307 0.148 Uiso 0.548(13) 1 calc PR B 2
C236 C 0.2233(9) 0.4271(9) -0.1021(3) 0.118(3) Uani 0.548(13) 1 d PDU B 2
H236 H 0.2057 0.4029 -0.0892 0.141 Uiso 0.548(13) 1 calc PR B 2
C237 C 0.2537(8) 0.4670(10) -0.1894(4) 0.142(4) Uani 0.548(13) 1 d PDU B 2
H23A H 0.2429 0.4826 -0.2023 0.214 Uiso 0.548(13) 1 calc PR B 2
H23B H 0.2592 0.4409 -0.1971 0.214 Uiso 0.548(13) 1 calc PR B 2
H23C H 0.2854 0.4931 -0.1817 0.214 Uiso 0.548(13) 1 calc PR B 2
C238 C 0.1669(9) 0.3981(9) -0.1767(5) 0.151(5) Uani 0.548(13) 1 d PDU B 2
H23D H 0.1676 0.3682 -0.1704 0.226 Uiso 0.548(13) 1 calc PR B 2
H23E H 0.1631 0.3959 -0.1951 0.226 Uiso 0.548(13) 1 calc PR B 2
H23F H 0.1383 0.3995 -0.1691 0.226 Uiso 0.548(13) 1 calc PR B 2
N203 N 0.2143(7) 0.4438(7) -0.1700(3) 0.134(3) Uani 0.548(13) 1 d PDU B 2
C41 C 0.2921(4) 0.4271(3) -0.0576(5) 0.113(2) Uani 0.695(14) 1 d PDU B 1
C42 C 0.3078(5) 0.4049(5) -0.0755(4) 0.116(2) Uani 0.695(14) 1 d PDU B 1
H42 H 0.3182 0.4206 -0.0916 0.139 Uiso 0.695(14) 1 calc PR B 1
C43 C 0.3088(5) 0.3612(5) -0.0710(4) 0.116(2) Uani 0.695(14) 1 d PDU B 1
H43 H 0.3201 0.3479 -0.0841 0.139 Uiso 0.695(14) 1 calc PR B 1
C44 C 0.2943(5) 0.3355(5) -0.0482(3) 0.116(2) Uani 0.695(14) 1 d PDU B 1
C45 C 0.2791(5) 0.3568(5) -0.0298(4) 0.116(2) Uani 0.695(14) 1 d PDU B 1
H45 H 0.2697 0.3414 -0.0136 0.139 Uiso 0.695(14) 1 calc PR B 1
C46 C 0.2773(6) 0.4011(5) -0.0348(5) 0.113(2) Uani 0.695(14) 1 d PDU B 1
H46 H 0.2653 0.4141 -0.0219 0.135 Uiso 0.695(14) 1 calc PR B 1
C47 C 0.3103(7) 0.2710(6) -0.0678(3) 0.123(3) Uani 0.695(14) 1 d PDU B 1
H47A H 0.2841 0.2607 -0.0808 0.184 Uiso 0.695(14) 1 calc PR B 1
H47B H 0.3127 0.2414 -0.0624 0.184 Uiso 0.695(14) 1 calc PR B 1
H47C H 0.3431 0.2968 -0.0747 0.184 Uiso 0.695(14) 1 calc PR B 1
C48 C 0.2820(7) 0.2651(7) -0.0222(3) 0.132(4) Uani 0.695(14) 1 d PDU B 1
H48A H 0.3030 0.2877 -0.0086 0.197 Uiso 0.695(14) 1 calc PR B 1
H48B H 0.2867 0.2356 -0.0231 0.197 Uiso 0.695(14) 1 calc PR B 1
H48C H 0.2462 0.2539 -0.0189 0.197 Uiso 0.695(14) 1 calc PR B 1
N4 N 0.2970(5) 0.2921(4) -0.0460(3) 0.120(2) Uani 0.695(14) 1 d PDU B 1
C241 C 0.2852(7) 0.4229(5) -0.0594(11) 0.113(2) Uani 0.305(14) 1 d PDU B 2
C242 C 0.2953(10) 0.4003(9) -0.0796(9) 0.115(2) Uani 0.305(14) 1 d PDU B 2
H242 H 0.3050 0.4178 -0.0953 0.138 Uiso 0.305(14) 1 calc PR B 2
C243 C 0.2916(10) 0.3534(10) -0.0777(7) 0.116(2) Uani 0.305(14) 1 d PDU B 2
H243 H 0.2985 0.3394 -0.0921 0.139 Uiso 0.305(14) 1 calc PR B 2
C244 C 0.2782(9) 0.3255(8) -0.0554(7) 0.117(2) Uani 0.305(14) 1 d PDU B 2
C245 C 0.2673(11) 0.3473(10) -0.0350(7) 0.115(2) Uani 0.305(14) 1 d PDU B 2
H245 H 0.2573 0.3297 -0.0194 0.138 Uiso 0.305(14) 1 calc PR B 2
C246 C 0.2709(11) 0.3944(10) -0.0373(9) 0.113(2) Uani 0.305(14) 1 d PDU B 2
H246 H 0.2632 0.4080 -0.0230 0.135 Uiso 0.305(14) 1 calc PR B 2
C247 C 0.2816(16) 0.2563(13) -0.0769(7) 0.123(4) Uani 0.305(14) 1 d PDU B 2
H24A H 0.2568 0.2527 -0.0897 0.184 Uiso 0.305(14) 1 calc PR B 2
H24B H 0.2773 0.2229 -0.0730 0.184 Uiso 0.305(14) 1 calc PR B 2
H24C H 0.3160 0.2785 -0.0833 0.184 Uiso 0.305(14) 1 calc PR B 2
C248 C 0.2471(16) 0.2469(12) -0.0324(7) 0.129(4) Uani 0.305(14) 1 d PDU B 2
H24D H 0.2687 0.2596 -0.0174 0.193 Uiso 0.305(14) 1 calc PR B 2
H24E H 0.2387 0.2118 -0.0357 0.193 Uiso 0.305(14) 1 calc PR B 2
H24F H 0.2157 0.2479 -0.0295 0.193 Uiso 0.305(14) 1 calc PR B 2
N204 N 0.2739(11) 0.2786(8) -0.0540(6) 0.119(3) Uani 0.305(14) 1 d PDU B 2
C51 C 0.4694(6) 0.6088(7) -0.1050(2) 0.127(3) Uani 0.692(11) 1 d PDU B 1
C52 C 0.5048(6) 0.6471(7) -0.1197(3) 0.132(3) Uani 0.692(11) 1 d PDU B 1
H52 H 0.5266 0.6792 -0.1122 0.158 Uiso 0.692(11) 1 calc PR B 1
C53 C 0.5096(6) 0.6405(6) -0.1452(3) 0.132(3) Uani 0.692(11) 1 d PDU B 1
H53 H 0.5350 0.6679 -0.1547 0.158 Uiso 0.692(11) 1 calc PR B 1
C54 C 0.4787(6) 0.5954(6) -0.1570(2) 0.133(3) Uani 0.692(11) 1 d PDU B 1
C55 C 0.4439(6) 0.5562(6) -0.1417(3) 0.131(3) Uani 0.692(11) 1 d PDU B 1
H55 H 0.4228 0.5236 -0.1489 0.157 Uiso 0.692(11) 1 calc PR B 1
C56 C 0.4391(7) 0.5632(7) -0.1165(3) 0.128(3) Uani 0.692(11) 1 d PDU B 1
H56 H 0.4142 0.5358 -0.1068 0.154 Uiso 0.692(11) 1 calc PR B 1
C57 C 0.5168(8) 0.6296(7) -0.1982(3) 0.151(5) Uani 0.692(11) 1 d PDU B 1
H57A H 0.4985 0.6449 -0.2061 0.226 Uiso 0.692(11) 1 calc PR B 1
H57B H 0.5302 0.6167 -0.2113 0.226 Uiso 0.692(11) 1 calc PR B 1
H57C H 0.5450 0.6551 -0.1881 0.226 Uiso 0.692(11) 1 calc PR B 1
C58 C 0.4470(9) 0.5380(7) -0.1933(4) 0.157(5) Uani 0.692(11) 1 d PDU B 1
H58A H 0.4655 0.5201 -0.1973 0.236 Uiso 0.692(11) 1 calc PR B 1
H58B H 0.4325 0.5430 -0.2088 0.236 Uiso 0.692(11) 1 calc PR B 1
H58C H 0.4196 0.5177 -0.1813 0.236 Uiso 0.692(11) 1 calc PR B 1
N5 N 0.4821(6) 0.5875(6) -0.1820(2) 0.141(3) Uani 0.692(11) 1 d PDU B 1
C251 C 0.4546(12) 0.6055(15) -0.1061(3) 0.128(3) Uani 0.308(11) 1 d PDU B 2
C252 C 0.4867(12) 0.6464(14) -0.1210(5) 0.132(3) Uani 0.308(11) 1 d PDU B 2
H252 H 0.5101 0.6771 -0.1128 0.158 Uiso 0.308(11) 1 calc PR B 2
C253 C 0.4867(12) 0.6450(12) -0.1475(5) 0.134(3) Uani 0.308(11) 1 d PDU B 2
H253 H 0.5098 0.6745 -0.1567 0.160 Uiso 0.308(11) 1 calc PR B 2
C254 C 0.4531(11) 0.6009(11) -0.1603(4) 0.136(3) Uani 0.308(11) 1 d PDU B 2
C255 C 0.4203(12) 0.5593(12) -0.1453(4) 0.132(3) Uani 0.308(11) 1 d PDU B 2
H255 H 0.3965 0.5286 -0.1534 0.158 Uiso 0.308(11) 1 calc PR B 2
C256 C 0.4213(13) 0.5616(14) -0.1192(5) 0.129(3) Uani 0.308(11) 1 d PDU B 2
H256 H 0.3986 0.5321 -0.1099 0.155 Uiso 0.308(11) 1 calc PR B 2
C257 C 0.4775(18) 0.6442(13) -0.2010(6) 0.150(6) Uani 0.308(11) 1 d PDU B 2
H25A H 0.4685 0.6363 -0.2188 0.226 Uiso 0.308(11) 1 calc PR B 2
H25B H 0.5143 0.6594 -0.1989 0.226 Uiso 0.308(11) 1 calc PR B 2
H25C H 0.4670 0.6682 -0.1952 0.226 Uiso 0.308(11) 1 calc PR B 2
C258 C 0.4116(16) 0.5524(13) -0.1994(6) 0.143(6) Uani 0.308(11) 1 d PDU B 2
H25D H 0.3980 0.5227 -0.1882 0.215 Uiso 0.308(11) 1 calc PR B 2
H25E H 0.4263 0.5461 -0.2144 0.215 Uiso 0.308(11) 1 calc PR B 2
H25F H 0.3842 0.5586 -0.2044 0.215 Uiso 0.308(11) 1 calc PR B 2
N205 N 0.4513(12) 0.5972(11) -0.1859(4) 0.140(4) Uani 0.308(11) 1 d PDU B 2
C61 C 0.5071(3) 0.6051(3) -0.05615(17) 0.0886(19) Uani 0.852(15) 1 d PDU B 1
C62 C 0.5584(4) 0.6315(4) -0.0625(2) 0.091(2) Uani 0.852(15) 1 d PDU B 1
H62 H 0.5693 0.6552 -0.0759 0.109 Uiso 0.852(15) 1 calc PR B 1
C63 C 0.5935(4) 0.6243(4) -0.0499(2) 0.090(2) Uani 0.852(15) 1 d PDU B 1
H63 H 0.6282 0.6429 -0.0549 0.108 Uiso 0.852(15) 1 calc PR B 1
C64 C 0.5794(3) 0.5904(3) -0.0301(2) 0.0884(19) Uani 0.852(15) 1 d PDU B 1
C65 C 0.5279(4) 0.5631(4) -0.0234(2) 0.089(2) Uani 0.852(15) 1 d PDU B 1
H65 H 0.5169 0.5395 -0.0099 0.107 Uiso 0.852(15) 1 calc PR B 1
C66 C 0.4933(4) 0.5710(4) -0.0369(2) 0.0878(19) Uani 0.852(15) 1 d PDU B 1
H66 H 0.4584 0.5517 -0.0325 0.105 Uiso 0.852(15) 1 calc PR B 1
C67 C 0.6647(4) 0.6021(5) -0.0274(3) 0.098(3) Uani 0.852(15) 1 d PDU B 1
H67A H 0.6633 0.5997 -0.0458 0.146 Uiso 0.852(15) 1 calc PR B 1
H67B H 0.6793 0.5822 -0.0206 0.146 Uiso 0.852(15) 1 calc PR B 1
H67C H 0.6859 0.6377 -0.0224 0.146 Uiso 0.852(15) 1 calc PR B 1
C68 C 0.5960(5) 0.5400(6) 0.0001(3) 0.098(3) Uani 0.852(15) 1 d PDU B 1
H68A H 0.5713 0.5407 0.0117 0.146 Uiso 0.852(15) 1 calc PR B 1
H68B H 0.6249 0.5429 0.0097 0.146 Uiso 0.852(15) 1 calc PR B 1
H68C H 0.5800 0.5080 -0.0094 0.146 Uiso 0.852(15) 1 calc PR B 1
N6 N 0.6139(3) 0.5825(3) -0.0175(2) 0.094(2) Uani 0.852(15) 1 d PDU B 1
C261 C 0.5157(12) 0.6119(15) -0.0624(7) 0.090(2) Uani 0.148(15) 1 d PDU B 2
C262 C 0.5663(14) 0.6383(19) -0.0694(10) 0.091(2) Uani 0.148(15) 1 d PDU B 2
H262 H 0.5769 0.6641 -0.0818 0.109 Uiso 0.148(15) 1 calc PR B 2
C263 C 0.6021(12) 0.6284(18) -0.0587(10) 0.091(2) Uani 0.148(15) 1 d PDU B 2
H263 H 0.6365 0.6473 -0.0641 0.109 Uiso 0.148(15) 1 calc PR B 2
C264 C 0.5886(13) 0.5914(15) -0.0404(8) 0.091(2) Uani 0.148(15) 1 d PDU B 2
C265 C 0.5376(13) 0.5645(18) -0.0335(10) 0.089(2) Uani 0.148(15) 1 d PDU B 2
H265 H 0.5269 0.5385 -0.0211 0.107 Uiso 0.148(15) 1 calc PR B 2
C266 C 0.5019(12) 0.5748(18) -0.0442(10) 0.089(2) Uani 0.148(15) 1 d PDU B 2
H266 H 0.4675 0.5559 -0.0389 0.107 Uiso 0.148(15) 1 calc PR B 2
C267 C 0.660(2) 0.577(3) -0.0457(13) 0.096(4) Uani 0.148(15) 1 d PDU B 2
H26A H 0.6422 0.5521 -0.0592 0.144 Uiso 0.148(15) 1 calc PR B 2
H26B H 0.6796 0.5656 -0.0357 0.144 Uiso 0.148(15) 1 calc PR B 2
H26C H 0.6830 0.6100 -0.0532 0.144 Uiso 0.148(15) 1 calc PR B 2
C268 C 0.605(3) 0.546(4) -0.0076(13) 0.094(4) Uani 0.148(15) 1 d PDU B 2
H26D H 0.5975 0.5629 0.0063 0.141 Uiso 0.148(15) 1 calc PR B 2
H26E H 0.6311 0.5386 -0.0024 0.141 Uiso 0.148(15) 1 calc PR B 2
H26F H 0.5739 0.5148 -0.0122 0.141 Uiso 0.148(15) 1 calc PR B 2
N206 N 0.6229(14) 0.5805(18) -0.0296(9) 0.093(2) Uani 0.148(15) 1 d PDU B 2
C71 C 0.3281(8) 0.5275(9) 0.0936(3) 0.1003(19) Uani 0.417(19) 1 d PDU A 1
C72 C 0.3717(9) 0.5503(8) 0.1078(4) 0.101(2) Uani 0.417(19) 1 d PDU A 1
H72 H 0.3897 0.5861 0.1100 0.121 Uiso 0.417(19) 1 calc PR A 1
C73 C 0.3891(8) 0.5208(8) 0.1187(4) 0.104(2) Uani 0.417(19) 1 d PDU A 1
H73 H 0.4194 0.5374 0.1284 0.125 Uiso 0.417(19) 1 calc PR A 1
C74 C 0.3654(8) 0.4684(8) 0.1164(4) 0.1060(19) Uani 0.417(19) 1 d PDU A 1
C75 C 0.3212(9) 0.4460(8) 0.1017(4) 0.104(2) Uani 0.417(19) 1 d PDU A 1
H75 H 0.3033 0.4102 0.0993 0.125 Uiso 0.417(19) 1 calc PR A 1
C76 C 0.3031(9) 0.4751(9) 0.0906(4) 0.102(2) Uani 0.417(19) 1 d PDU A 1
H76 H 0.2730 0.4589 0.0808 0.123 Uiso 0.417(19) 1 calc PR A 1
C77 C 0.4337(9) 0.4653(10) 0.1405(7) 0.110(4) Uani 0.417(19) 1 d PDU A 1
H77A H 0.4593 0.4904 0.1291 0.164 Uiso 0.417(19) 1 calc PR A 1
H77B H 0.4430 0.4396 0.1448 0.164 Uiso 0.417(19) 1 calc PR A 1
H77C H 0.4321 0.4822 0.1559 0.164 Uiso 0.417(19) 1 calc PR A 1
C78 C 0.3560(12) 0.3855(8) 0.1270(7) 0.114(4) Uani 0.417(19) 1 d PDU A 1
H78A H 0.3214 0.3728 0.1333 0.172 Uiso 0.417(19) 1 calc PR A 1
H78B H 0.3733 0.3723 0.1375 0.172 Uiso 0.417(19) 1 calc PR A 1
H78C H 0.3546 0.3744 0.1095 0.172 Uiso 0.417(19) 1 calc PR A 1
N7 N 0.3837(8) 0.4406(8) 0.1280(4) 0.109(2) Uani 0.417(19) 1 d PDU A 1
C271 C 0.3265(5) 0.5230(6) 0.0908(3) 0.1001(18) Uani 0.583(19) 1 d PDU A 2
C272 C 0.3594(6) 0.5425(7) 0.1106(3) 0.102(2) Uani 0.583(19) 1 d PDU A 2
H272 H 0.3667 0.5748 0.1168 0.122 Uiso 0.583(19) 1 calc PR A 2
C273 C 0.3828(7) 0.5195(6) 0.1224(3) 0.105(2) Uani 0.583(19) 1 d PDU A 2
H273 H 0.4052 0.5359 0.1361 0.126 Uiso 0.583(19) 1 calc PR A 2
C274 C 0.3737(6) 0.4720(6) 0.1143(3) 0.1062(19) Uani 0.583(19) 1 d PDU A 2
C275 C 0.3404(7) 0.4512(7) 0.0941(3) 0.103(2) Uani 0.583(19) 1 d PDU A 2
H275 H 0.3327 0.4187 0.0880 0.124 Uiso 0.583(19) 1 calc PR A 2
C276 C 0.3181(7) 0.4759(7) 0.0827(3) 0.102(2) Uani 0.583(19) 1 d PDU A 2
H276 H 0.2963 0.4602 0.0687 0.122 Uiso 0.583(19) 1 calc PR A 2
C277 C 0.4113(10) 0.4595(8) 0.1518(3) 0.115(4) Uani 0.583(19) 1 d PDU A 2
H27D H 0.4359 0.4959 0.1531 0.172 Uiso 0.583(19) 1 calc PR A 2
H27E H 0.4271 0.4400 0.1575 0.172 Uiso 0.583(19) 1 calc PR A 2
H27F H 0.3817 0.4512 0.1624 0.172 Uiso 0.583(19) 1 calc PR A 2
C278 C 0.3810(10) 0.3955(7) 0.1170(4) 0.112(3) Uani 0.583(19) 1 d PDU A 2
H27G H 0.3928 0.3970 0.0997 0.168 Uiso 0.583(19) 1 calc PR A 2
H27H H 0.3440 0.3738 0.1177 0.168 Uiso 0.583(19) 1 calc PR A 2
H27I H 0.3968 0.3814 0.1281 0.168 Uiso 0.583(19) 1 calc PR A 2
N207 N 0.3951(6) 0.4467(6) 0.1255(3) 0.110(2) Uani 0.583(19) 1 d PDU A 2
C81 C 0.2475(5) 0.5417(5) 0.1009(3) 0.095(2) Uani 0.598(9) 1 d PDU A 1
C82 C 0.2567(6) 0.5612(5) 0.1256(3) 0.098(3) Uani 0.598(9) 1 d PDU A 1
H82 H 0.2903 0.5835 0.1312 0.117 Uiso 0.598(9) 1 calc PR A 1
C83 C 0.2158(5) 0.5471(5) 0.1414(3) 0.098(2) Uani 0.598(9) 1 d PDU A 1
H83 H 0.2227 0.5603 0.1580 0.118 Uiso 0.598(9) 1 calc PR A 1
C84 C 0.1656(5) 0.5154(5) 0.1348(3) 0.099(2) Uani 0.598(9) 1 d PDU A 1
C85 C 0.1578(6) 0.4962(6) 0.1106(3) 0.098(2) Uani 0.598(9) 1 d PDU A 1
H85 H 0.1242 0.4733 0.1050 0.118 Uiso 0.598(9) 1 calc PR A 1
C86 C 0.1979(6) 0.5098(6) 0.0942(3) 0.096(2) Uani 0.598(9) 1 d PDU A 1
H86 H 0.1909 0.4964 0.0776 0.116 Uiso 0.598(9) 1 calc PR A 1
C87 C 0.1325(7) 0.5273(7) 0.1744(3) 0.104(4) Uani 0.598(9) 1 d PDU A 1
H87A H 0.1359 0.5074 0.1881 0.156 Uiso 0.598(9) 1 calc PR A 1
H87B H 0.1029 0.5312 0.1776 0.156 Uiso 0.598(9) 1 calc PR A 1
H87C H 0.1632 0.5609 0.1737 0.156 Uiso 0.598(9) 1 calc PR A 1
C88 C 0.0748(6) 0.4634(7) 0.1422(4) 0.113(4) Uani 0.598(9) 1 d PDU A 1
H88A H 0.0613 0.4796 0.1312 0.169 Uiso 0.598(9) 1 calc PR A 1
H88B H 0.0525 0.4486 0.1569 0.169 Uiso 0.598(9) 1 calc PR A 1
H88C H 0.0767 0.4365 0.1329 0.169 Uiso 0.598(9) 1 calc PR A 1
N8 N 0.1263(5) 0.5016(5) 0.1508(2) 0.105(2) Uani 0.598(9) 1 d PDU A 1
C281 C 0.2389(7) 0.5323(5) 0.0967(4) 0.095(2) Uani 0.402(9) 1 d PDU A 2
C282 C 0.2396(7) 0.5389(7) 0.1228(4) 0.097(2) Uani 0.402(9) 1 d PDU A 2
H282 H 0.2711 0.5565 0.1314 0.116 Uiso 0.402(9) 1 calc PR A 2
C283 C 0.1946(7) 0.5199(8) 0.1363(4) 0.099(2) Uani 0.402(9) 1 d PDU A 2
H283 H 0.1965 0.5250 0.1540 0.119 Uiso 0.402(9) 1 calc PR A 2
C284 C 0.1471(6) 0.4938(7) 0.1251(3) 0.100(2) Uani 0.402(9) 1 d PDU A 2
C285 C 0.1471(8) 0.4874(9) 0.0992(4) 0.099(2) Uani 0.402(9) 1 d PDU A 2
H285 H 0.1156 0.4695 0.0906 0.119 Uiso 0.402(9) 1 calc PR A 2
C286 C 0.1913(8) 0.5062(9) 0.0858(4) 0.096(2) Uani 0.402(9) 1 d PDU A 2
H286 H 0.1892 0.5011 0.0680 0.116 Uiso 0.402(9) 1 calc PR A 2
C287 C 0.1077(10) 0.4818(12) 0.1659(3) 0.104(4) Uani 0.402(9) 1 d PDU A 2
H28D H 0.1183 0.4589 0.1732 0.156 Uiso 0.402(9) 1 calc PR A 2
H28E H 0.0748 0.4740 0.1730 0.156 Uiso 0.402(9) 1 calc PR A 2
H28F H 0.1331 0.5170 0.1699 0.156 Uiso 0.402(9) 1 calc PR A 2
C288 C 0.0555(7) 0.4613(12) 0.1255(5) 0.109(4) Uani 0.402(9) 1 d PDU A 2
H28G H 0.0492 0.4899 0.1262 0.164 Uiso 0.402(9) 1 calc PR A 2
H28H H 0.0277 0.4318 0.1339 0.164 Uiso 0.402(9) 1 calc PR A 2
H28I H 0.0577 0.4530 0.1079 0.164 Uiso 0.402(9) 1 calc PR A 2
N208 N 0.1033(6) 0.4752(8) 0.1384(3) 0.104(3) Uani 0.402(9) 1 d PDU A 2
N11 N 0.3557(3) 0.5505(3) 0.00246(17) 0.0810(15) Uani 1 1 d U A .
O11 O 0.3515(2) 0.5838(2) 0.01347(13) 0.0836(15) Uani 1 1 d U . .
O12 O 0.3228(2) 0.5058(2) 0.00621(14) 0.0906(19) Uani 1 1 d U . .
O13 O 0.3899(2) 0.5599(2) -0.01386(13) 0.0851(14) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C4 C1 P1 122.3(6) . .
C4 C1 H1A 106.7 . .
P1 C1 H1A 106.7 . .
C4 C1 H1B 106.7 . .
P1 C1 H1B 106.7 . .
H1A C1 H1B 106.6 . .
C4 C2 P2 118.8(7) . .
C4 C2 H2A 107.6 . .
P2 C2 H2A 107.6 . .
C4 C2 H2B 107.6 . .
P2 C2 H2B 107.6 . .
H2A C2 H2B 107.0 . .
C4 C3 P3 120.9(7) . 3_565
C4 C3 H3A 107.1 . .
P3 C3 H3A 107.1 3_565 .
C4 C3 H3B 107.1 . .
P3 C3 H3B 107.1 3_565 .
H3A C3 H3B 106.8 . .
C3 C4 C5 113.6(8) . .
C3 C4 C1 109.8(7) . .
C5 C4 C1 107.4(8) . .
C3 C4 C2 111.4(8) . .
C5 C4 C2 108.5(7) . .
C1 C4 C2 105.8(8) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C7 C6 P4 117.4(6) . .
C8 C7 C6 111.7(7) . 3_565
C8 C7 C6 111.7(7) . 2_665
C6 C7 C6 107.2(8) 3_565 2_665
C8 C7 C6 111.7(7) . .
C6 C7 C6 107.2(8) 3_565 .
C6 C7 C6 107.2(8) 2_665 .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C211 P1 C21 104.9(8) . .
C21 P1 C11 103.0(14) . .
C211 P1 C221 105.5(8) . .
C11 P1 C221 104.2(14) . .
C211 P1 C1 99.0(4) . .
C21 P1 C1 109.9(10) . .
C11 P1 C1 104.6(5) . .
C221 P1 C1 103.1(7) . .
C211 P1 Ag1 110.4(5) . .
C21 P1 Ag1 105.9(10) . .
C11 P1 Ag1 106.2(11) . .
C221 P1 Ag1 111.7(7) . .
C1 P1 Ag1 125.1(3) . .
C41 P2 C231 100.9(9) . .
C241 P2 C231 95.8(16) . .
C41 P2 C31 106.0(10) . .
C241 P2 C31 101.3(17) . .
C41 P2 C2 99.9(8) . .
C241 P2 C2 98.0(16) . .
C231 P2 C2 110.7(6) . .
C31 P2 C2 114.4(7) . .
C41 P2 Ag2 108.6(3) . .
C241 P2 Ag2 114.9(4) . .
C231 P2 Ag2 116.9(8) . .
C31 P2 Ag2 109.7(10) . .
C2 P2 Ag2 117.0(3) . .
C51 P3 C61 105.2(4) . .
C51 P3 C261 94.3(12) . .
C61 P3 C251 117.3(5) . .
C261 P3 C251 106.9(12) . .
C51 P3 C3 103.2(7) . 2_665
C61 P3 C3 103.3(4) . 2_665
C261 P3 C3 99.5(12) . 2_665
C251 P3 C3 103.8(13) . 2_665
C51 P3 Ag2 111.6(6) . .
C61 P3 Ag2 112.0(3) . .
C261 P3 Ag2 123.7(17) . .
C251 P3 Ag2 100.8(12) . .
C3 P3 Ag2 120.1(3) 2_665 .
C71 P4 C81 98.7(5) . .
C271 P4 C81 101.4(4) . .
C71 P4 C281 101.3(7) . .
C271 P4 C281 103.0(5) . .
C71 P4 C6 99.4(9) . .
C271 P4 C6 103.8(7) . .
C81 P4 C6 104.6(6) . .
C281 P4 C6 114.5(7) . .
C71 P4 Ag1 118.7(7) . .
C271 P4 Ag1 112.7(6) . .
C81 P4 Ag1 115.3(6) . .
C281 P4 Ag1 104.9(8) . .
C6 P4 Ag1 117.2(3) . .
P4 Ag1 P1 142.07(10) . .
P4 Ag1 O11 99.18(17) . .
P1 Ag1 O11 118.66(17) . .
P2 Ag2 P3 154.54(11) . .
P2 Ag2 O13 105.22(17) . .
P3 Ag2 O13 98.32(16) . .
C16 C11 C12 112.9(13) . .
C16 C11 P1 126(2) . .
C12 C11 P1 121(2) . .
C13 C12 C11 126.1(15) . .
C13 C12 H12 117.0 . .
C11 C12 H12 117.0 . .
C12 C13 C14 119.3(15) . .
C12 C13 H13 120.4 . .
C14 C13 H13 120.4 . .
N1 C14 C15 122.1(15) . .
N1 C14 C13 121.7(14) . .
C15 C14 C13 116.2(13) . .
C14 C15 C16 122.9(15) . .
C14 C15 H15 118.5 . .
C16 C15 H15 118.5 . .
C15 C16 C11 122.5(15) . .
C15 C16 H16 118.7 . .
C11 C16 H16 118.7 . .
N1 C17 H17A 109.5 . .
N1 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
N1 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N1 C18 H18A 109.5 . .
N1 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N1 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C14 N1 C18 119.4(16) . .
C14 N1 C17 116.8(14) . .
C18 N1 C17 115.1(16) . .
C216 C211 C212 118.5(10) . .
C216 C211 P1 123.5(13) . .
C212 C211 P1 118.0(12) . .
C213 C212 C211 120.3(11) . .
C213 C212 H212 119.9 . .
C211 C212 H212 119.9 . .
C212 C213 C214 121.4(11) . .
C212 C213 H213 119.3 . .
C214 C213 H213 119.3 . .
N201 C214 C215 119.1(10) . .
N201 C214 C213 122.0(10) . .
C215 C214 C213 118.9(10) . .
C214 C215 C216 119.2(11) . .
C214 C215 H215 120.4 . .
C216 C215 H215 120.4 . .
C211 C216 C215 121.7(11) . .
C211 C216 H216 119.1 . .
C215 C216 H216 119.1 . .
N201 C217 H21A 109.5 . .
N201 C217 H21B 109.5 . .
H21A C217 H21B 109.5 . .
N201 C217 H21C 109.5 . .
H21A C217 H21C 109.5 . .
H21B C217 H21C 109.5 . .
N201 C218 H21D 109.5 . .
N201 C218 H21E 109.5 . .
H21D C218 H21E 109.5 . .
N201 C218 H21F 109.5 . .
H21D C218 H21F 109.5 . .
H21E C218 H21F 109.5 . .
C214 N201 C218 120.9(10) . .
C214 N201 C217 115.7(9) . .
C218 N201 C217 117.9(11) . .
C22 C21 C26 118.9(12) . .
C22 C21 P1 125.9(17) . .
C26 C21 P1 115.3(16) . .
C21 C22 C23 120.0(14) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C24 C23 C22 122.7(15) . .
C24 C23 H23 118.6 . .
C22 C23 H23 118.6 . .
N2 C24 C23 118.9(13) . .
N2 C24 C25 123.7(14) . .
C23 C24 C25 117.4(12) . .
C24 C25 C26 120.6(14) . .
C24 C25 H25 119.7 . .
C26 C25 H25 119.7 . .
C21 C26 C25 120.5(14) . .
C21 C26 H26 119.8 . .
C25 C26 H26 119.8 . .
N2 C27 H27A 109.5 . .
N2 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
N2 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
N2 C28 H28A 109.5 . .
N2 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
N2 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C24 N2 C27 120.9(14) . .
C24 N2 C28 120.5(14) . .
C27 N2 C28 118.1(15) . .
C226 C221 C222 115.8(10) . .
C226 C221 P1 120.9(12) . .
C222 C221 P1 123.2(12) . .
C221 C222 C223 124.7(12) . .
C221 C222 H222 117.7 . .
C223 C222 H222 117.7 . .
C224 C223 C222 119.4(12) . .
C224 C223 H223 120.3 . .
C222 C223 H223 120.3 . .
N202 C224 C225 122.4(11) . .
N202 C224 C223 121.2(11) . .
C225 C224 C223 116.4(11) . .
C224 C225 C226 124.2(12) . .
C224 C225 H225 117.9 . .
C226 C225 H225 117.9 . .
C221 C226 C225 119.5(12) . .
C221 C226 H226 120.2 . .
C225 C226 H226 120.2 . .
N202 C227 H22A 109.5 . .
N202 C227 H22B 109.5 . .
H22A C227 H22B 109.5 . .
N202 C227 H22C 109.5 . .
H22A C227 H22C 109.5 . .
H22B C227 H22C 109.5 . .
N202 C228 H22D 109.5 . .
N202 C228 H22E 109.5 . .
H22D C228 H22E 109.5 . .
N202 C228 H22F 109.5 . .
H22D C228 H22F 109.5 . .
H22E C228 H22F 109.5 . .
C224 N202 C228 118.0(12) . .
C224 N202 C227 121.5(12) . .
C228 N202 C227 118.8(12) . .
C36 C31 C32 116.5(13) . .
C36 C31 P2 123.6(18) . .
C32 C31 P2 119.9(18) . .
C31 C32 C33 123.2(14) . .
C31 C32 H32 118.4 . .
C33 C32 H32 118.4 . .
C34 C33 C32 119.4(14) . .
C34 C33 H33 120.3 . .
C32 C33 H33 120.3 . .
N3 C34 C33 121.6(14) . .
N3 C34 C35 120.5(14) . .
C33 C34 C35 117.9(13) . .
C36 C35 C34 121.3(15) . .
C36 C35 H35 119.4 . .
C34 C35 H35 119.4 . .
C31 C36 C35 121.7(15) . .
C31 C36 H36 119.1 . .
C35 C36 H36 119.1 . .
N3 C37 H37A 109.5 . .
N3 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
N3 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
N3 C38 H38A 109.5 . .
N3 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
N3 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C34 N3 C38 118.9(15) . .
C34 N3 C37 119.4(14) . .
C38 N3 C37 119.0(15) . .
C236 C231 C232 119.2(12) . .
C236 C231 P2 120.7(16) . .
C232 C231 P2 120.1(15) . .
C231 C232 C233 121.9(14) . .
C231 C232 H232 119.1 . .
C233 C232 H232 119.1 . .
C232 C233 C234 118.8(14) . .
C232 C233 H233 120.6 . .
C234 C233 H233 120.6 . .
N203 C234 C233 118.8(13) . .
N203 C234 C235 121.4(13) . .
C233 C234 C235 119.7(12) . .
C234 C235 C236 119.9(13) . .
C234 C235 H235 120.0 . .
C236 C235 H235 120.0 . .
C231 C236 C235 120.4(13) . .
C231 C236 H236 119.8 . .
C235 C236 H236 119.8 . .
N203 C237 H23A 109.5 . .
N203 C237 H23B 109.5 . .
H23A C237 H23B 109.5 . .
N203 C237 H23C 109.5 . .
H23A C237 H23C 109.5 . .
H23B C237 H23C 109.5 . .
N203 C238 H23D 109.5 . .
N203 C238 H23E 109.5 . .
H23D C238 H23E 109.5 . .
N203 C238 H23F 109.5 . .
H23D C238 H23F 109.5 . .
H23E C238 H23F 109.5 . .
C234 N203 C238 120.6(14) . .
C234 N203 C237 116.0(13) . .
C238 N203 C237 117.9(14) . .
C42 C41 C46 114.5(10) . .
C42 C41 P2 120.7(14) . .
C46 C41 P2 124.8(14) . .
C43 C42 C41 122.4(12) . .
C43 C42 H42 118.8 . .
C41 C42 H42 118.8 . .
C42 C43 C44 123.2(12) . .
C42 C43 H43 118.4 . .
C44 C43 H43 118.4 . .
N4 C44 C45 126.3(12) . .
N4 C44 C43 117.8(11) . .
C45 C44 C43 116.0(10) . .
C44 C45 C46 120.4(12) . .
C44 C45 H45 119.8 . .
C46 C45 H45 119.8 . .
C41 C46 C45 123.5(12) . .
C41 C46 H46 118.2 . .
C45 C46 H46 118.2 . .
N4 C47 H47A 109.5 . .
N4 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
N4 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
N4 C48 H48A 109.5 . .
N4 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
N4 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C44 N4 C48 118.0(11) . .
C44 N4 C47 121.0(11) . .
C48 N4 C47 120.8(11) . .
C242 C241 C246 114.8(14) . .
C242 C241 P2 118(3) . .
C246 C241 P2 128(3) . .
C243 C242 C241 122.0(16) . .
C243 C242 H242 119.0 . .
C241 C242 H242 119.0 . .
C242 C243 C244 122.8(16) . .
C242 C243 H243 118.6 . .
C244 C243 H243 118.6 . .
N204 C244 C243 121.9(15) . .
N204 C244 C245 122.1(15) . .
C243 C244 C245 115.9(13) . .
C246 C245 C244 120.5(16) . .
C246 C245 H245 119.7 . .
C244 C245 H245 119.7 . .
C245 C246 C241 123.9(16) . .
C245 C246 H246 118.1 . .
C241 C246 H246 118.1 . .
N204 C247 H24A 109.5 . .
N204 C247 H24B 109.5 . .
H24A C247 H24B 109.5 . .
N204 C247 H24C 109.5 . .
H24A C247 H24C 109.5 . .
H24B C247 H24C 109.5 . .
N204 C248 H24D 109.5 . .
N204 C248 H24E 109.5 . .
H24D C248 H24E 109.5 . .
N204 C248 H24F 109.5 . .
H24D C248 H24F 109.5 . .
H24E C248 H24F 109.5 . .
C244 N204 C248 117.7(15) . .
C244 N204 C247 118.8(16) . .
C248 N204 C247 120.8(17) . .
C56 C51 C52 117.3(11) . .
C56 C51 P3 118.6(12) . .
C52 C51 P3 124.1(13) . .
C51 C52 C53 121.7(13) . .
C51 C52 H52 119.2 . .
C53 C52 H52 119.2 . .
C54 C53 C52 121.5(13) . .
C54 C53 H53 119.2 . .
C52 C53 H53 119.2 . .
N5 C54 C53 123.2(12) . .
N5 C54 C55 120.7(12) . .
C53 C54 C55 116.0(11) . .
C56 C55 C54 122.0(13) . .
C56 C55 H55 119.0 . .
C54 C55 H55 119.0 . .
C51 C56 C55 121.5(13) . .
C51 C56 H56 119.3 . .
C55 C56 H56 119.3 . .
N5 C57 H57A 109.5 . .
N5 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
N5 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
N5 C58 H58A 109.5 . .
N5 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
N5 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
C54 N5 C57 120.4(12) . .
C54 N5 C58 119.9(12) . .
C57 N5 C58 119.5(12) . .
C252 C251 C256 115.3(14) . .
C252 C251 P3 117(2) . .
C256 C251 P3 128(2) . .
C251 C252 C253 123.8(16) . .
C251 C252 H252 118.1 . .
C253 C252 H252 118.1 . .
C254 C253 C252 120.4(16) . .
C254 C253 H253 119.8 . .
C252 C253 H253 119.8 . .
N205 C254 C253 123.2(16) . .
N205 C254 C255 120.6(16) . .
C253 C254 C255 116.1(14) . .
C256 C255 C254 122.2(16) . .
C256 C255 H255 118.9 . .
C254 C255 H255 118.9 . .
C251 C256 C255 122.2(16) . .
C251 C256 H256 118.9 . .
C255 C256 H256 118.9 . .
N205 C257 H25A 109.5 . .
N205 C257 H25B 109.5 . .
H25A C257 H25B 109.5 . .
N205 C257 H25C 109.5 . .
H25A C257 H25C 109.5 . .
H25B C257 H25C 109.5 . .
N205 C258 H25D 109.5 . .
N205 C258 H25E 109.5 . .
H25D C258 H25E 109.5 . .
N205 C258 H25F 109.5 . .
H25D C258 H25F 109.5 . .
H25E C258 H25F 109.5 . .
C254 N205 C258 122.7(16) . .
C254 N205 C257 118.7(16) . .
C258 N205 C257 115.5(17) . .
C66 C61 C62 116.7(8) . .
C66 C61 P3 120.5(7) . .
C62 C61 P3 122.8(7) . .
C63 C62 C61 122.2(9) . .
C63 C62 H62 118.9 . .
C61 C62 H62 118.9 . .
C62 C63 C64 120.9(8) . .
C62 C63 H63 119.6 . .
C64 C63 H63 119.6 . .
N6 C64 C63 121.6(8) . .
N6 C64 C65 120.3(8) . .
C63 C64 C65 118.1(8) . .
C66 C65 C64 119.1(9) . .
C66 C65 H65 120.5 . .
C64 C65 H65 120.5 . .
C61 C66 C65 123.0(8) . .
C61 C66 H66 118.5 . .
C65 C66 H66 118.5 . .
N6 C67 H67A 109.5 . .
N6 C67 H67B 109.5 . .
H67A C67 H67B 109.5 . .
N6 C67 H67C 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
N6 C68 H68A 109.5 . .
N6 C68 H68B 109.5 . .
H68A C68 H68B 109.5 . .
N6 C68 H68C 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
C64 N6 C67 120.6(8) . .
C64 N6 C68 119.3(8) . .
C67 N6 C68 116.3(8) . .
C266 C261 C262 117.0(16) . .
C266 C261 P3 109(3) . .
C262 C261 P3 134(3) . .
C261 C262 C263 122.2(17) . .
C261 C262 H262 118.9 . .
C263 C262 H262 118.9 . .
C264 C263 C262 121.1(16) . .
C264 C263 H263 119.5 . .
C262 C263 H263 119.5 . .
N206 C264 C263 122.5(17) . .
N206 C264 C265 120.5(17) . .
C263 C264 C265 116.9(15) . .
C264 C265 C266 121.6(16) . .
C264 C265 H265 119.2 . .
C266 C265 H265 119.2 . .
C261 C266 C265 121.2(17) . .
C261 C266 H266 119.4 . .
C265 C266 H266 119.4 . .
N206 C267 H26A 109.5 . .
N206 C267 H26B 109.5 . .
H26A C267 H26B 109.5 . .
N206 C267 H26C 109.5 . .
H26A C267 H26C 109.5 . .
H26B C267 H26C 109.5 . .
N206 C268 H26D 109.5 . .
N206 C268 H26E 109.5 . .
H26D C268 H26E 109.5 . .
N206 C268 H26F 109.5 . .
H26D C268 H26F 109.5 . .
H26E C268 H26F 109.5 . .
C264 N206 C267 119.0(19) . .
C264 N206 C268 116(2) . .
C267 N206 C268 116(2) . .
C72 C71 C76 118.5(13) . .
C72 C71 P4 127.9(16) . .
C76 C71 P4 113.6(15) . .
C71 C72 C73 119.4(15) . .
C71 C72 H72 120.3 . .
C73 C72 H72 120.3 . .
C72 C73 C74 124.3(15) . .
C72 C73 H73 117.9 . .
C74 C73 H73 117.9 . .
N7 C74 C73 122.1(14) . .
N7 C74 C75 122.5(14) . .
C73 C74 C75 115.4(13) . .
C76 C75 C74 121.1(14) . .
C76 C75 H75 119.5 . .
C74 C75 H75 119.5 . .
C75 C76 C71 121.4(14) . .
C75 C76 H76 119.3 . .
C71 C76 H76 119.3 . .
N7 C77 H77A 109.5 . .
N7 C77 H77B 109.5 . .
H77A C77 H77B 109.5 . .
N7 C77 H77C 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
N7 C78 H78A 109.5 . .
N7 C78 H78B 109.5 . .
H78A C78 H78B 109.5 . .
N7 C78 H78C 109.5 . .
H78A C78 H78C 109.5 . .
H78B C78 H78C 109.5 . .
C74 N7 C78 121.1(14) . .
C74 N7 C77 121.5(14) . .
C78 N7 C77 117.3(14) . .
C272 C271 C276 113.8(11) . .
C272 C271 P4 120.2(13) . .
C276 C271 P4 126.0(13) . .
C271 C272 C273 125.7(13) . .
C271 C272 H272 117.2 . .
C273 C272 H272 117.2 . .
C272 C273 C274 120.1(13) . .
C272 C273 H273 119.9 . .
C274 C273 H273 119.9 . .
N207 C274 C275 121.4(12) . .
N207 C274 C273 123.0(12) . .
C275 C274 C273 115.6(11) . .
C276 C275 C274 122.4(13) . .
C276 C275 H275 118.8 . .
C274 C275 H275 118.8 . .
C275 C276 C271 122.4(13) . .
C275 C276 H276 118.8 . .
C271 C276 H276 118.8 . .
N207 C277 H27D 109.5 . .
N207 C277 H27E 109.5 . .
H27D C277 H27E 109.5 . .
N207 C277 H27F 109.5 . .
H27D C277 H27F 109.5 . .
H27E C277 H27F 109.5 . .
N207 C278 H27G 109.5 . .
N207 C278 H27H 109.5 . .
H27G C278 H27H 109.5 . .
N207 C278 H27I 109.5 . .
H27G C278 H27I 109.5 . .
H27H C278 H27I 109.5 . .
C274 N207 C278 119.7(12) . .
C274 N207 C277 117.0(12) . .
C278 N207 C277 117.1(12) . .
C86 C81 C82 117.2(10) . .
C86 C81 P4 119.6(11) . .
C82 C81 P4 123.2(11) . .
C83 C82 C81 118.4(12) . .
C83 C82 H82 120.8 . .
C81 C82 H82 120.8 . .
C82 C83 C84 125.1(13) . .
C82 C83 H83 117.5 . .
C84 C83 H83 117.5 . .
N8 C84 C83 123.9(11) . .
N8 C84 C85 120.9(11) . .
C83 C84 C85 115.2(11) . .
C86 C85 C84 121.1(12) . .
C86 C85 H85 119.4 . .
C84 C85 H85 119.4 . .
C81 C86 C85 123.0(12) . .
C81 C86 H86 118.5 . .
C85 C86 H86 118.5 . .
N8 C87 H87A 109.5 . .
N8 C87 H87B 109.5 . .
H87A C87 H87B 109.5 . .
N8 C87 H87C 109.5 . .
H87A C87 H87C 109.5 . .
H87B C87 H87C 109.5 . .
N8 C88 H88A 109.5 . .
N8 C88 H88B 109.5 . .
H88A C88 H88B 109.5 . .
N8 C88 H88C 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
C84 N8 C87 121.4(11) . .
C84 N8 C88 118.4(11) . .
C87 N8 C88 119.8(12) . .
C286 C281 C282 115.7(12) . .
C286 C281 P4 122.3(15) . .
C282 C281 P4 122.0(15) . .
C283 C282 C281 120.6(14) . .
C283 C282 H282 119.7 . .
C281 C282 H282 119.7 . .
C284 C283 C282 123.3(14) . .
C284 C283 H283 118.4 . .
C282 C283 H283 118.4 . .
N208 C284 C283 123.1(13) . .
N208 C284 C285 121.6(13) . .
C283 C284 C285 115.4(12) . .
C286 C285 C284 121.8(14) . .
C286 C285 H285 119.1 . .
C284 C285 H285 119.1 . .
C285 C286 C281 123.2(14) . .
C285 C286 H286 118.4 . .
C281 C286 H286 118.4 . .
N208 C287 H28D 109.5 . .
N208 C287 H28E 109.5 . .
H28D C287 H28E 109.5 . .
N208 C287 H28F 109.5 . .
H28D C287 H28F 109.5 . .
H28E C287 H28F 109.5 . .
N208 C288 H28G 109.5 . .
N208 C288 H28H 109.5 . .
H28G C288 H28H 109.5 . .
N208 C288 H28I 109.5 . .
H28G C288 H28I 109.5 . .
H28H C288 H28I 109.5 . .
C284 N208 C288 120.5(13) . .
C284 N208 C287 116.9(14) . .
C288 N208 C287 120.8(15) . .
O11 N11 O12 118.0(8) . .
O11 N11 O13 123.2(8) . .
O12 N11 O13 118.6(8) . .
N11 O11 Ag1 101.7(5) . .
N11 O13 Ag2 123.6(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C4 1.535(13) .
C1 P1 1.848(10) .
C1 H1A 0.990 .
C1 H1B 0.990 .
C2 C4 1.569(12) .
C2 P2 1.861(10) .
C2 H2A 0.990 .
C2 H2B 0.990 .
C3 C4 1.505(14) .
C3 P3 1.841(9) 3_565
C3 H3A 0.990 .
C3 H3B 0.990 .
C4 C5 1.531(12) .
C5 H5A 0.980 .
C5 H5B 0.980 .
C5 H5C 0.980 .
C6 C7 1.584(12) .
C6 P4 1.870(11) .
C7 C8 1.52(2) .
C7 C6 1.584(12) 3_565
C7 C6 1.584(12) 2_665
C8 H8A 0.980 .
C8 H8B 0.980 .
C8 H8C 0.980 .
P1 C211 1.796(10) .
P1 C21 1.818(12) .
P1 C11 1.832(12) .
P1 C221 1.834(10) .
P1 Ag1 2.434(3) .
P2 C41 1.795(10) .
P2 C241 1.806(13) .
P2 C231 1.808(11) .
P2 C31 1.814(12) .
P2 Ag2 2.387(3) .
P3 C51 1.794(10) .
P3 C61 1.805(9) .
P3 C261 1.806(14) .
P3 C251 1.821(13) .
P3 C3 1.841(9) 2_665
P3 Ag2 2.410(3) .
P4 C71 1.785(12) .
P4 C271 1.795(11) .
P4 C81 1.802(10) .
P4 C281 1.827(12) .
P4 Ag1 2.413(3) .
Ag1 O11 2.471(6) .
Ag2 O13 2.414(7) .
C11 C16 1.396(12) .
C11 C12 1.399(12) .
C12 C13 1.389(12) .
C12 H12 0.950 .
C13 C14 1.401(12) .
C13 H13 0.950 .
C14 N1 1.373(12) .
C14 C15 1.389(12) .
C15 C16 1.394(12) .
C15 H15 0.950 .
C16 H16 0.950 .
C17 N1 1.475(13) .
C17 H17A 0.980 .
C17 H17B 0.980 .
C17 H17C 0.980 .
C18 N1 1.462(13) .
C18 H18A 0.980 .
C18 H18B 0.980 .
C18 H18C 0.980 .
C211 C216 1.386(11) .
C211 C212 1.394(11) .
C212 C213 1.370(11) .
C212 H212 0.950 .
C213 C214 1.396(10) .
C213 H213 0.950 .
C214 N201 1.369(10) .
C214 C215 1.393(11) .
C215 C216 1.391(11) .
C215 H215 0.950 .
C216 H216 0.950 .
C217 N201 1.481(11) .
C217 H21A 0.980 .
C217 H21B 0.980 .
C217 H21C 0.980 .
C218 N201 1.440(11) .
C218 H21D 0.980 .
C218 H21E 0.980 .
C218 H21F 0.980 .
C21 C22 1.386(12) .
C21 C26 1.391(12) .
C22 C23 1.392(12) .
C22 H22 0.950 .
C23 C24 1.380(12) .
C23 H23 0.950 .
C24 N2 1.375(12) .
C24 C25 1.397(12) .
C25 C26 1.414(12) .
C25 H25 0.950 .
C26 H26 0.950 .
C27 N2 1.458(12) .
C27 H27A 0.980 .
C27 H27B 0.980 .
C27 H27C 0.980 .
C28 N2 1.461(12) .
C28 H28A 0.980 .
C28 H28B 0.980 .
C28 H28C 0.980 .
C221 C226 1.385(11) .
C221 C222 1.394(11) .
C222 C223 1.394(11) .
C222 H222 0.950 .
C223 C224 1.390(11) .
C223 H223 0.950 .
C224 N202 1.363(11) .
C224 C225 1.380(11) .
C225 C226 1.409(11) .
C225 H225 0.950 .
C226 H226 0.950 .
C227 N202 1.466(12) .
C227 H22A 0.980 .
C227 H22B 0.980 .
C227 H22C 0.980 .
C228 N202 1.461(12) .
C228 H22D 0.980 .
C228 H22E 0.980 .
C228 H22F 0.980 .
C31 C36 1.373(12) .
C31 C32 1.390(12) .
C32 C33 1.396(12) .
C32 H32 0.950 .
C33 C34 1.388(12) .
C33 H33 0.950 .
C34 N3 1.357(12) .
C34 C35 1.396(12) .
C35 C36 1.392(12) .
C35 H35 0.950 .
C36 H36 0.950 .
C37 N3 1.459(12) .
C37 H37A 0.980 .
C37 H37B 0.980 .
C37 H37C 0.980 .
C38 N3 1.456(12) .
C38 H38A 0.980 .
C38 H38B 0.980 .
C38 H38C 0.980 .
C231 C236 1.373(12) .
C231 C232 1.376(12) .
C232 C233 1.388(12) .
C232 H232 0.950 .
C233 C234 1.390(12) .
C233 H233 0.950 .
C234 N203 1.359(12) .
C234 C235 1.393(12) .
C235 C236 1.395(12) .
C235 H235 0.950 .
C236 H236 0.950 .
C237 N203 1.465(12) .
C237 H23A 0.980 .
C237 H23B 0.980 .
C237 H23C 0.980 .
C238 N203 1.460(12) .
C238 H23D 0.980 .
C238 H23E 0.980 .
C238 H23F 0.980 .
C41 C42 1.380(11) .
C41 C46 1.389(11) .
C42 C43 1.365(11) .
C42 H42 0.950 .
C43 C44 1.385(11) .
C43 H43 0.950 .
C44 N4 1.365(11) .
C44 C45 1.375(11) .
C45 C46 1.399(11) .
C45 H45 0.950 .
C46 H46 0.950 .
C47 N4 1.475(11) .
C47 H47A 0.980 .
C47 H47B 0.980 .
C47 H47C 0.980 .
C48 N4 1.447(11) .
C48 H48A 0.980 .
C48 H48B 0.980 .
C48 H48C 0.980 .
C241 C242 1.387(13) .
C241 C246 1.390(13) .
C242 C243 1.380(13) .
C242 H242 0.950 .
C243 C244 1.388(12) .
C243 H243 0.950 .
C244 N204 1.369(12) .
C244 C245 1.392(12) .
C245 C246 1.386(13) .
C245 H245 0.950 .
C246 H246 0.950 .
C247 N204 1.467(13) .
C247 H24A 0.980 .
C247 H24B 0.980 .
C247 H24C 0.980 .
C248 N204 1.455(13) .
C248 H24D 0.980 .
C248 H24E 0.980 .
C248 H24F 0.980 .
C51 C56 1.363(12) .
C51 C52 1.365(11) .
C52 C53 1.388(11) .
C52 H52 0.950 .
C53 C54 1.366(11) .
C53 H53 0.950 .
C54 N5 1.356(11) .
C54 C55 1.392(11) .
C55 C56 1.371(11) .
C55 H55 0.950 .
C56 H56 0.950 .
C57 N5 1.463(11) .
C57 H57A 0.980 .
C57 H57B 0.980 .
C57 H57C 0.980 .
C58 N5 1.470(11) .
C58 H58A 0.980 .
C58 H58B 0.980 .
C58 H58C 0.980 .
C251 C252 1.381(13) .
C251 C256 1.391(13) .
C252 C253 1.405(13) .
C252 H252 0.950 .
C253 C254 1.391(12) .
C253 H253 0.950 .
C254 N205 1.360(12) .
C254 C255 1.402(13) .
C255 C256 1.389(13) .
C255 H255 0.950 .
C256 H256 0.950 .
C257 N205 1.474(13) .
C257 H25A 0.980 .
C257 H25B 0.980 .
C257 H25C 0.980 .
C258 N205 1.475(13) .
C258 H25D 0.980 .
C258 H25E 0.980 .
C258 H25F 0.980 .
C61 C66 1.361(10) .
C61 C62 1.392(9) .
C62 C63 1.363(10) .
C62 H62 0.950 .
C63 C64 1.384(10) .
C63 H63 0.950 .
C64 N6 1.361(9) .
C64 C65 1.401(9) .
C65 C66 1.390(10) .
C65 H65 0.950 .
C66 H66 0.950 .
C67 N6 1.447(9) .
C67 H67A 0.980 .
C67 H67B 0.980 .
C67 H67C 0.980 .
C68 N6 1.460(10) .
C68 H68A 0.980 .
C68 H68B 0.980 .
C68 H68C 0.980 .
C261 C266 1.382(13) .
C261 C262 1.385(13) .
C262 C263 1.385(13) .
C262 H262 0.950 .
C263 C264 1.385(13) .
C263 H263 0.950 .
C264 N206 1.369(13) .
C264 C265 1.392(13) .
C265 C266 1.392(13) .
C265 H265 0.950 .
C266 H266 0.950 .
C267 N206 1.464(13) .
C267 H26A 0.980 .
C267 H26B 0.980 .
C267 H26C 0.980 .
C268 N206 1.471(14) .
C268 H26D 0.980 .
C268 H26E 0.980 .
C268 H26F 0.980 .
C71 C72 1.373(12) .
C71 C76 1.390(12) .
C72 C73 1.377(12) .
C72 H72 0.950 .
C73 C74 1.387(12) .
C73 H73 0.950 .
C74 N7 1.368(12) .
C74 C75 1.402(12) .
C75 C76 1.385(12) .
C75 H75 0.950 .
C76 H76 0.950 .
C77 N7 1.475(12) .
C77 H77A 0.980 .
C77 H77B 0.980 .
C77 H77C 0.980 .
C78 N7 1.451(12) .
C78 H78A 0.980 .
C78 H78B 0.980 .
C78 H78C 0.980 .
C271 C272 1.364(12) .
C271 C276 1.394(11) .
C272 C273 1.373(12) .
C272 H272 0.950 .
C273 C274 1.395(11) .
C273 H273 0.950 .
C274 N207 1.368(11) .
C274 C275 1.389(12) .
C275 C276 1.379(11) .
C275 H275 0.950 .
C276 H276 0.950 .
C277 N207 1.465(12) .
C277 H27D 0.980 .
C277 H27E 0.980 .
C277 H27F 0.980 .
C278 N207 1.464(12) .
C278 H27G 0.980 .
C278 H27H 0.980 .
C278 H27I 0.980 .
C81 C86 1.370(11) .
C81 C82 1.404(11) .
C82 C83 1.377(11) .
C82 H82 0.950 .
C83 C84 1.381(11) .
C83 H83 0.950 .
C84 N8 1.351(11) .
C84 C85 1.383(11) .
C85 C86 1.380(11) .
C85 H85 0.950 .
C86 H86 0.950 .
C87 N8 1.437(11) .
C87 H87A 0.980 .
C87 H87B 0.980 .
C87 H87C 0.980 .
C88 N8 1.478(11) .
C88 H88A 0.980 .
C88 H88B 0.980 .
C88 H88C 0.980 .
C281 C286 1.381(12) .
C281 C282 1.398(12) .
C282 C283 1.386(12) .
C282 H282 0.950 .
C283 C284 1.385(12) .
C283 H283 0.950 .
C284 N208 1.354(12) .
C284 C285 1.386(12) .
C285 C286 1.370(12) .
C285 H285 0.950 .
C286 H286 0.950 .
C287 N208 1.471(12) .
C287 H28D 0.980 .
C287 H28E 0.980 .
C287 H28F 0.980 .
C288 N208 1.461(12) .
C288 H28G 0.980 .
C288 H28H 0.980 .
C288 H28I 0.980 .
N11 O11 1.231(9) .
N11 O12 1.235(9) .
N11 O13 1.269(9) .
