#------------------------------------------------------------------------------
#$Date: 2016-03-26 12:59:59 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180218 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/04/7110469.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7110469
loop_
_publ_author_name
'Uhl, Werner'
'Benter, Maike'
_publ_section_title
;
 The insertion of alkylgallium(I) groups [Ga--C(SiMe3)3] into P--P bonds
 of P4: formation of a P4(GaR)3 cage
;
_journal_issue                   9
_journal_name_full               'Chemical Communications'
_journal_page_first              771
_journal_paper_doi               10.1039/a900670b
_journal_year                    1999
_chemical_formula_sum            'C50 H121 Ga3 P4 Si9'
_chemical_formula_weight         1308.32
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           62
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.132(3)
_cell_length_b                   32.368(6)
_cell_length_c                   17.233(3)
_cell_measurement_temperature    293(2)
_cell_volume                     7325(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      218
_diffrn_measured_fraction_theta_full 0.922
_diffrn_measured_fraction_theta_max 0.922
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0994
_diffrn_reflns_av_sigmaI/netI    0.0607
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            51232
_diffrn_reflns_theta_full        26.01
_diffrn_reflns_theta_max         26.01
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    1.359
_exptl_crystal_density_diffrn    1.186
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2800
_refine_diff_density_max         1.430
_refine_diff_density_min         -0.640
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     414
_refine_ls_number_reflns         7293
_refine_ls_number_restraints     170
_refine_ls_restrained_S_all      1.093
_refine_ls_R_factor_all          0.0917
_refine_ls_R_factor_gt           0.0587
_refine_ls_shift/su_max          0.546
_refine_ls_shift/su_mean         0.029
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1500
_refine_ls_wR_factor_ref         0.1654
_reflns_number_gt                4973
_reflns_number_total             7293
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            900670bsup1.cif
_cod_data_source_block           P4(GaR)3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_sg_symbol_H-M      Pnma
_cod_database_code               7110469
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.61157(12) 0.7500 -0.03066(10) 0.0278(4) Uani 1 d S . .
P2 P 0.53143(12) 0.71636(5) 0.18073(8) 0.0450(4) Uani 1 d . . .
P3 P 0.40152(14) 0.7500 0.13323(11) 0.0409(5) Uani 1 d S . .
Ga1 Ga 0.62638(4) 0.700464(16) 0.06770(3) 0.03016(16) Uani 1 d . . .
Ga2 Ga 0.43724(5) 0.7500 -0.00207(4) 0.0303(2) Uani 1 d S . .
C1 C 0.7027(4) 0.64812(16) 0.0640(3) 0.0449(13) Uani 1 d D . .
Si1 Si 0.7644(7) 0.6401(4) -0.0339(4) 0.044(2) Uani 0.502(4) d PDU A 1
C11 C 0.8542(16) 0.6816(6) -0.0608(13) 0.056(7) Uiso 0.502(4) d PDU A 1
H11A H 0.8200 0.7078 -0.0588 0.067 Uiso 0.502(4) calc PR A 1
H11B H 0.8791 0.6768 -0.1125 0.067 Uiso 0.502(4) calc PR A 1
H11C H 0.9104 0.6817 -0.0252 0.067 Uiso 0.502(4) calc PR A 1
C12 C 0.6702(12) 0.6381(5) -0.1148(8) 0.055(4) Uiso 0.502(4) d PDU A 1
H12A H 0.6248 0.6152 -0.1069 0.066 Uiso 0.502(4) calc PR A 1
H12B H 0.7054 0.6347 -0.1632 0.066 Uiso 0.502(4) calc PR A 1
H12C H 0.6318 0.6633 -0.1159 0.066 Uiso 0.502(4) calc PR A 1
C13 C 0.8403(16) 0.5906(6) -0.0435(15) 0.049(6) Uani 0.502(4) d PDU A 1
H13A H 0.8882 0.5888 -0.0015 0.059 Uiso 0.502(4) calc PR A 1
H13B H 0.8762 0.5907 -0.0920 0.059 Uiso 0.502(4) calc PR A 1
H13C H 0.7949 0.5674 -0.0417 0.059 Uiso 0.502(4) calc PR A 1
Si2 Si 0.5803(2) 0.61117(9) 0.06836(18) 0.0412(9) Uani 0.502(4) d PDU A 1
C21 C 0.536(2) 0.6036(10) 0.1708(15) 0.065(12) Uani 0.502(4) d PDU A 1
H21A H 0.4658 0.5956 0.1709 0.077 Uiso 0.502(4) calc PR A 1
H21B H 0.5442 0.6289 0.1991 0.077 Uiso 0.502(4) calc PR A 1
H21C H 0.5761 0.5823 0.1949 0.077 Uiso 0.502(4) calc PR A 1
C22 C 0.6084(18) 0.5592(6) 0.0265(15) 0.078(7) Uani 0.502(4) d PDU A 1
H22A H 0.6678 0.5479 0.0510 0.093 Uiso 0.502(4) calc PR A 1
H22B H 0.6203 0.5618 -0.0283 0.093 Uiso 0.502(4) calc PR A 1
H22C H 0.5514 0.5412 0.0352 0.093 Uiso 0.502(4) calc PR A 1
C23 C 0.4716(8) 0.6354(4) 0.0131(7) 0.052(3) Uani 0.502(4) d PDU A 1
H23A H 0.4901 0.6381 -0.0406 0.063 Uiso 0.502(4) calc PR A 1
H23B H 0.4571 0.6622 0.0343 0.063 Uiso 0.502(4) calc PR A 1
H23C H 0.4123 0.6182 0.0174 0.063 Uiso 0.502(4) calc PR A 1
Si3 Si 0.7867(2) 0.63644(10) 0.14772(16) 0.0390(9) Uani 0.502(4) d PDU A 1
C31 C 0.745(2) 0.6611(16) 0.2431(9) 0.049(7) Uani 0.502(4) d PDU A 1
H31A H 0.7578 0.6903 0.2411 0.059 Uiso 0.502(4) calc PR A 1
H31B H 0.7836 0.6492 0.2850 0.059 Uiso 0.502(4) calc PR A 1
H31C H 0.6741 0.6562 0.2511 0.059 Uiso 0.502(4) calc PR A 1
C32 C 0.9193(12) 0.6580(7) 0.1345(16) 0.060(6) Uani 0.502(4) d PDU A 1
H32A H 0.9536 0.6431 0.0940 0.072 Uiso 0.502(4) calc PR A 1
H32B H 0.9567 0.6552 0.1820 0.072 Uiso 0.502(4) calc PR A 1
H32C H 0.9150 0.6867 0.1207 0.072 Uiso 0.502(4) calc PR A 1
C33 C 0.8052(11) 0.5800(4) 0.1680(8) 0.060(4) Uani 0.502(4) d PDU A 1
H33A H 0.7435 0.5687 0.1889 0.072 Uiso 0.502(4) calc PR A 1
H33B H 0.8594 0.5766 0.2048 0.072 Uiso 0.502(4) calc PR A 1
H33C H 0.8222 0.5660 0.1207 0.072 Uiso 0.502(4) calc PR A 1
Si1A Si 0.7811(8) 0.6468(4) -0.0313(4) 0.0383(19) Uani 0.498(4) d PDU A 2
C11A C 0.8687(12) 0.6904(5) -0.0497(9) 0.041(4) Uani 0.498(4) d PDU A 2
H11D H 0.9017 0.6865 -0.0989 0.049 Uiso 0.498(4) calc PR A 2
H11E H 0.9191 0.6915 -0.0094 0.049 Uiso 0.498(4) calc PR A 2
H11F H 0.8309 0.7157 -0.0505 0.049 Uiso 0.498(4) calc PR A 2
C12A C 0.6940(11) 0.6478(4) -0.1163(7) 0.045(4) Uiso 0.498(4) d PDU A 2
H12D H 0.6474 0.6704 -0.1112 0.054 Uiso 0.498(4) calc PR A 2
H12E H 0.6567 0.6223 -0.1187 0.054 Uiso 0.498(4) calc PR A 2
H12F H 0.7331 0.6511 -0.1630 0.054 Uiso 0.498(4) calc PR A 2
C13A C 0.8625(16) 0.5991(6) -0.0371(15) 0.055(7) Uani 0.498(4) d PDU A 2
H13D H 0.8950 0.5979 -0.0869 0.066 Uiso 0.498(4) calc PR A 2
H13E H 0.8207 0.5750 -0.0301 0.066 Uiso 0.498(4) calc PR A 2
H13F H 0.9135 0.6000 0.0029 0.066 Uiso 0.498(4) calc PR A 2
Si2A Si 0.6531(2) 0.60095(9) 0.09504(18) 0.0401(9) Uani 0.498(4) d PDU A 2
C21A C 0.542(2) 0.6068(9) 0.1662(12) 0.059(10) Uani 0.498(4) d PDU A 2
H21D H 0.5676 0.6156 0.2157 0.071 Uiso 0.498(4) calc PR A 2
H21E H 0.5081 0.5807 0.1719 0.071 Uiso 0.498(4) calc PR A 2
H21F H 0.4950 0.6269 0.1467 0.071 Uiso 0.498(4) calc PR A 2
C22A C 0.5856(17) 0.5713(6) 0.0130(13) 0.068(7) Uani 0.498(4) d PDU A 2
H22D H 0.5350 0.5887 -0.0104 0.082 Uiso 0.498(4) calc PR A 2
H22E H 0.5535 0.5471 0.0340 0.082 Uiso 0.498(4) calc PR A 2
H22F H 0.6346 0.5632 -0.0255 0.082 Uiso 0.498(4) calc PR A 2
C23A C 0.7448(10) 0.5630(4) 0.1387(9) 0.056(3) Uani 0.498(4) d PDU A 2
H23D H 0.7986 0.5575 0.1024 0.068 Uiso 0.498(4) calc PR A 2
H23E H 0.7097 0.5378 0.1506 0.068 Uiso 0.498(4) calc PR A 2
H23F H 0.7731 0.5744 0.1854 0.068 Uiso 0.498(4) calc PR A 2
Si3A Si 0.8117(2) 0.66861(10) 0.14408(16) 0.0355(8) Uani 0.498(4) d PDU A 2
C31A C 0.766(2) 0.6586(16) 0.2456(9) 0.048(9) Uani 0.498(4) d PDU A 2
H31D H 0.7459 0.6302 0.2505 0.058 Uiso 0.498(4) calc PR A 2
H31E H 0.7084 0.6760 0.2566 0.058 Uiso 0.498(4) calc PR A 2
H31F H 0.8195 0.6645 0.2817 0.058 Uiso 0.498(4) calc PR A 2
C32A C 0.9356(10) 0.6430(8) 0.1318(17) 0.060(6) Uani 0.498(4) d PDU A 2
H32D H 0.9613 0.6485 0.0807 0.072 Uiso 0.498(4) calc PR A 2
H32E H 0.9275 0.6137 0.1386 0.072 Uiso 0.498(4) calc PR A 2
H32F H 0.9826 0.6534 0.1697 0.072 Uiso 0.498(4) calc PR A 2
C33A C 0.8332(8) 0.7261(3) 0.1380(7) 0.046(3) Uani 0.498(4) d PD A 2
H33D H 0.8892 0.7336 0.1709 0.055 Uiso 0.498(4) calc PR A 2
H33E H 0.7729 0.7403 0.1547 0.055 Uiso 0.498(4) calc PR A 2
H33F H 0.8484 0.7336 0.0854 0.055 Uiso 0.498(4) calc PR A 2
Si4 Si 0.37274(16) 0.7500 -0.18081(13) 0.0445(5) Uani 1 d S . .
C41 C 0.2677(7) 0.7500 -0.2554(5) 0.055(2) Uani 1 d S . .
H41A H 0.2340 0.7237 -0.2551 0.066 Uiso 0.50 calc PR . .
H41B H 0.2961 0.7550 -0.3059 0.066 Uiso 0.50 calc PR . .
H41C H 0.2195 0.7713 -0.2432 0.066 Uiso 0.50 calc PR . .
C42 C 0.4551(5) 0.7039(2) -0.2020(4) 0.0602(17) Uani 1 d . . .
H42A H 0.4773 0.7049 -0.2550 0.072 Uiso 1 calc R . .
H42B H 0.4168 0.6791 -0.1934 0.072 Uiso 1 calc R . .
H42C H 0.5133 0.7042 -0.1683 0.072 Uiso 1 calc R . .
C2 C 0.3238(5) 0.7500 -0.0769(4) 0.0425(18) Uani 1 d SD . .
Si5 Si 0.2758(3) 0.69207(11) -0.0506(2) 0.0514(13) Uani 0.511(6) d PDU B 3
C51 C 0.198(4) 0.6931(11) 0.0390(15) 0.070(10) Uani 0.511(6) d PDU B 3
H51A H 0.1506 0.7155 0.0364 0.083 Uiso 0.511(6) calc PR B 3
H51B H 0.2420 0.6968 0.0831 0.083 Uiso 0.511(6) calc PR B 3
H51C H 0.1620 0.6675 0.0441 0.083 Uiso 0.511(6) calc PR B 3
C52 C 0.3882(9) 0.6581(4) -0.0248(8) 0.060(4) Uani 0.511(6) d PDU B 3
H52A H 0.4054 0.6620 0.0289 0.073 Uiso 0.511(6) calc PR B 3
H52B H 0.4455 0.6654 -0.0566 0.073 Uiso 0.511(6) calc PR B 3
H52C H 0.3708 0.6297 -0.0336 0.073 Uiso 0.511(6) calc PR B 3
C53 C 0.2037(19) 0.6660(6) -0.1319(13) 0.094(8) Uani 0.511(6) d PDU B 3
H53A H 0.1450 0.6522 -0.1111 0.113 Uiso 0.511(6) calc PR B 3
H53B H 0.2471 0.6462 -0.1569 0.113 Uiso 0.511(6) calc PR B 3
H53C H 0.1824 0.6864 -0.1690 0.113 Uiso 0.511(6) calc PR B 3
Si5A Si 0.2179(3) 0.71465(13) -0.0635(2) 0.0490(13) Uani 0.489(6) d PDU . 4
C51A C 0.188(4) 0.6996(13) 0.0392(12) 0.078(13) Uani 0.489(6) d PDU . 4
H51D H 0.2366 0.6798 0.0571 0.093 Uiso 0.489(6) calc PR B 4
H51E H 0.1207 0.6877 0.0412 0.093 Uiso 0.489(6) calc PR B 4
H51F H 0.1898 0.7237 0.0717 0.093 Uiso 0.489(6) calc PR B 4
C52A C 0.0926(8) 0.7351(5) -0.1012(8) 0.067(6) Uani 0.489(6) d PD . 4
H52D H 0.0656 0.7549 -0.0653 0.081 Uiso 0.489(6) calc PR B 4
H52E H 0.0453 0.7126 -0.1069 0.081 Uiso 0.489(6) calc PR B 4
H52F H 0.1031 0.7480 -0.1507 0.081 Uiso 0.489(6) calc PR B 4
C53A C 0.2423(16) 0.6629(5) -0.1161(12) 0.067(5) Uani 0.489(6) d PDU . 4
H53D H 0.2498 0.6678 -0.1708 0.080 Uiso 0.489(6) calc PR B 4
H53E H 0.1858 0.6446 -0.1075 0.080 Uiso 0.489(6) calc PR B 4
H53F H 0.3034 0.6505 -0.0963 0.080 Uiso 0.489(6) calc PR B 4
CP1 C 0.4366(13) 0.5758(5) -0.2326(10) 0.165(6) Uiso 1 d U . .
HP1A H 0.3799 0.5778 -0.2676 0.198 Uiso 1 calc R . .
HP1B H 0.4330 0.5982 -0.1961 0.198 Uiso 1 calc R . .
CP2 C 0.5313(11) 0.5769(5) -0.2745(9) 0.149(5) Uiso 1 d U . .
HP2A H 0.5669 0.6020 -0.2624 0.179 Uiso 1 calc R . .
HP2B H 0.5176 0.5767 -0.3292 0.179 Uiso 1 calc R . .
CP3 C 0.5969(14) 0.5407(6) -0.2543(11) 0.180(6) Uiso 1 d U . .
HP3A H 0.6181 0.5259 -0.2998 0.216 Uiso 1 calc R . .
HP3B H 0.6557 0.5489 -0.2251 0.216 Uiso 1 calc R . .
CP4 C 0.5262(15) 0.5167(6) -0.2076(12) 0.197(7) Uiso 1 d U . .
HP4A H 0.5124 0.4912 -0.2340 0.237 Uiso 1 calc R . .
HP4B H 0.5587 0.5100 -0.1593 0.237 Uiso 1 calc R . .
CP5 C 0.4359(17) 0.5357(7) -0.1920(13) 0.221(8) Uiso 1 d U . .
HP5A H 0.4285 0.5399 -0.1371 0.265 Uiso 1 calc R . .
HP5B H 0.3802 0.5191 -0.2099 0.265 Uiso 1 calc R . .
CP6 C 0.9035(17) 0.4664(7) -0.0791(14) 0.221(9) Uiso 1 d U . .
HP6A H 0.9086 0.4958 -0.0846 0.266 Uiso 1 calc R . .
HP6B H 0.9686 0.4541 -0.0896 0.266 Uiso 1 calc R . .
CP7 C 0.867(2) 0.4551(8) -0.0029(15) 0.241(10) Uiso 1 d U . .
HP7A H 0.8927 0.4284 0.0113 0.290 Uiso 1 calc R . .
HP7B H 0.8902 0.4749 0.0348 0.290 Uiso 1 calc R . .
CP8 C 0.7644(18) 0.4544(7) -0.0040(13) 0.206(8) Uiso 1 d U . .
HP8A H 0.7369 0.4799 0.0149 0.248 Uiso 1 calc R . .
HP8B H 0.7389 0.4322 0.0274 0.248 Uiso 1 calc R . .
CP9 C 0.7379(19) 0.4481(8) -0.0863(15) 0.243(10) Uiso 1 d U . .
HP9A H 0.7065 0.4216 -0.0936 0.292 Uiso 1 calc R . .
HP9B H 0.6916 0.4691 -0.1036 0.292 Uiso 1 calc R . .
CP10 C 0.829(2) 0.4504(8) -0.1272(16) 0.260(11) Uiso 1 d U . .
HP1C H 0.8487 0.4234 -0.1446 0.313 Uiso 1 calc R . .
HP1D H 0.8210 0.4678 -0.1718 0.313 Uiso 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ga1 P1 Ga1 86.44(6) 7_575 .
Ga1 P1 Ga2 85.92(5) 7_575 .
Ga1 P1 Ga2 85.92(5) . .
P2 P2 P3 60.08(5) 7_575 .
P2 P2 Ga1 102.54(4) 7_575 .
P3 P2 Ga1 102.20(8) . .
P2 P3 P2 59.83(10) 7_575 .
P2 P3 Ga2 102.32(7) 7_575 .
P2 P3 Ga2 102.32(7) . .
C1 Ga1 P1 127.43(14) . .
C1 Ga1 P2 118.78(15) . .
P1 Ga1 P2 113.75(5) . .
C2 Ga2 P1 127.0(2) . .
C2 Ga2 P3 119.5(2) . .
P1 Ga2 P3 113.52(7) . .
Si2A C1 Si3 78.8(2) . .
Si2A C1 Si1 108.3(5) . .
Si3 C1 Si1 114.3(4) . .
Si2A C1 Si1A 116.0(5) . .
Si3 C1 Si1A 109.8(4) . .
Si1 C1 Si1A 9.2(6) . .
Si2A C1 Ga1 123.6(3) . .
Si3 C1 Ga1 116.9(3) . .
Si1 C1 Ga1 111.4(5) . .
Si1A C1 Ga1 108.5(4) . .
Si2A C1 Si2 33.58(17) . .
Si3 C1 Si2 109.0(3) . .
Si1 C1 Si2 107.2(4) . .
Si1A C1 Si2 116.4(5) . .
Ga1 C1 Si2 95.9(2) . .
Si2A C1 Si3A 109.3(3) . .
Si3 C1 Si3A 31.38(15) . .
Si1 C1 Si3A 109.8(4) . .
Si1A C1 Si3A 101.7(4) . .
Ga1 C1 Si3A 93.1(2) . .
Si2 C1 Si3A 135.4(3) . .
C11 Si1 C12 105.2(9) . .
C11 Si1 C13 104.9(10) . .
C12 Si1 C13 104.8(9) . .
C11 Si1 C1 113.5(9) . .
C12 Si1 C1 112.8(7) . .
C13 Si1 C1 114.8(10) . .
C22 Si2 C21 107.9(12) . .
C22 Si2 C23 109.2(8) . .
C21 Si2 C23 107.3(12) . .
C22 Si2 C1 111.4(8) . .
C21 Si2 C1 111.2(10) . .
C23 Si2 C1 109.9(4) . .
C1 Si3 C33 114.9(5) . .
C1 Si3 C32 112.2(9) . .
C33 Si3 C32 105.3(8) . .
C1 Si3 C31 114.6(11) . .
C33 Si3 C31 106.5(15) . .
C32 Si3 C31 102.2(12) . .
C11A Si1A C12A 103.5(7) . .
C11A Si1A C13A 105.3(9) . .
C12A Si1A C13A 108.8(10) . .
C11A Si1A C1 117.4(8) . .
C12A Si1A C1 109.9(7) . .
C13A Si1A C1 111.4(9) . .
Si1A C11A H11D 109.5 . .
Si1A C11A H11E 109.5 . .
H11D C11A H11E 109.5 . .
Si1A C11A H11F 109.5 . .
H11D C11A H11F 109.5 . .
H11E C11A H11F 109.5 . .
Si1A C12A H12D 109.5 . .
Si1A C12A H12E 109.5 . .
H12D C12A H12E 109.5 . .
Si1A C12A H12F 109.5 . .
H12D C12A H12F 109.5 . .
H12E C12A H12F 109.5 . .
Si1A C13A H13D 109.4 . .
Si1A C13A H13E 109.5 . .
H13D C13A H13E 109.5 . .
Si1A C13A H13F 109.5 . .
H13D C13A H13F 109.5 . .
H13E C13A H13F 109.5 . .
C1 Si2A C23A 117.1(5) . .
C1 Si2A C21A 113.2(9) . .
C23A Si2A C21A 107.2(11) . .
C1 Si2A C22A 112.6(9) . .
C23A Si2A C22A 105.3(7) . .
C21A Si2A C22A 99.7(10) . .
Si2A C21A H21D 109.4 . .
Si2A C21A H21E 109.4 . .
H21D C21A H21E 109.5 . .
Si2A C21A H21F 109.6 . .
H21D C21A H21F 109.5 . .
H21E C21A H21F 109.5 . .
Si2A C22A H22D 109.5 . .
Si2A C22A H22E 109.5 . .
H22D C22A H22E 109.5 . .
Si2A C22A H22F 109.5 . .
H22D C22A H22F 109.5 . .
H22E C22A H22F 109.5 . .
Si2A C23A H23D 109.5 . .
Si2A C23A H23E 109.5 . .
H23D C23A H23E 109.5 . .
Si2A C23A H23F 109.5 . .
H23D C23A H23F 109.5 . .
H23E C23A H23F 109.5 . .
C32A Si3A C31A 108.3(13) . .
C32A Si3A C33A 107.8(8) . .
C31A Si3A C33A 105.6(15) . .
C32A Si3A C1 112.7(7) . .
C31A Si3A C1 109.9(10) . .
C33A Si3A C1 112.2(4) . .
Si3A C31A H31D 109.6 . .
Si3A C31A H31E 109.4 . .
H31D C31A H31E 109.5 . .
Si3A C31A H31F 109.4 . .
H31D C31A H31F 109.5 . .
H31E C31A H31F 109.5 . .
Si3A C32A H32D 109.7 . .
Si3A C32A H32E 109.4 . .
H32D C32A H32E 109.5 . .
Si3A C32A H32F 109.4 . .
H32D C32A H32F 109.5 . .
H32E C32A H32F 109.5 . .
Si3A C33A H33D 109.5 . .
Si3A C33A H33E 109.5 . .
H33D C33A H33E 109.5 . .
Si3A C33A H33F 109.5 . .
H33D C33A H33F 109.5 . .
H33E C33A H33F 109.5 . .
C42 Si4 C42 105.2(5) 7_575 .
C42 Si4 C41 106.8(3) 7_575 .
C42 Si4 C41 106.8(3) . .
C42 Si4 C2 112.2(2) 7_575 .
C42 Si4 C2 112.2(2) . .
C41 Si4 C2 113.2(4) . .
Si4 C41 H41A 109.5 . .
Si4 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
Si4 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
Si4 C42 H42A 109.5 . .
Si4 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
Si4 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
Si5A C2 Si5A 78.2(4) . 7_575
Si5A C2 Si4 112.3(3) . .
Si5A C2 Si4 112.3(3) 7_575 .
Si5A C2 Ga2 119.7(3) . .
Si5A C2 Ga2 119.7(3) 7_575 .
Si4 C2 Ga2 111.1(3) . .
Si5A C2 Si5 108.5(4) . 7_575
Si5A C2 Si5 31.93(16) 7_575 7_575
Si4 C2 Si5 108.4(2) . 7_575
Ga2 C2 Si5 95.1(2) . 7_575
Si5A C2 Si5 31.93(16) . .
Si5A C2 Si5 108.5(4) 7_575 .
Si4 C2 Si5 108.4(2) . .
Ga2 C2 Si5 95.1(2) . .
Si5 C2 Si5 135.0(4) 7_575 .
C51 Si5 C53 110.6(15) . .
C51 Si5 C52 104.1(19) . .
C53 Si5 C52 107.8(8) . .
C51 Si5 C2 109.9(11) . .
C53 Si5 C2 113.7(8) . .
C52 Si5 C2 110.3(4) . .
C2 Si5A C51A 116.5(12) . .
C2 Si5A C52A 113.7(5) . .
C51A Si5A C52A 103.3(19) . .
C2 Si5A C53A 111.1(7) . .
C51A Si5A C53A 104.7(13) . .
C52A Si5A C53A 106.6(7) . .
C2 Si5A Si5A 50.91(19) . 7_575
C51A Si5A Si5A 105.0(12) . 7_575
C52A Si5A Si5A 69.5(5) . 7_575
C53A Si5A Si5A 150.1(7) . 7_575
C2 Si5A C52A 93.6(4) . 7_575
C51A Si5A C52A 106.5(19) . 7_575
C52A Si5A C52A 22.1(7) . 7_575
C53A Si5A C52A 125.0(7) . 7_575
Si5A Si5A C52A 47.4(3) 7_575 7_575
CP2 CP1 CP5 105.3(15) . .
CP2 CP1 HP1A 110.7 . .
CP5 CP1 HP1A 110.7 . .
CP2 CP1 HP1B 110.7 . .
CP5 CP1 HP1B 110.7 . .
HP1A CP1 HP1B 108.8 . .
CP1 CP2 CP3 111.3(14) . .
CP1 CP2 HP2A 109.4 . .
CP3 CP2 HP2A 109.4 . .
CP1 CP2 HP2B 109.3 . .
CP3 CP2 HP2B 109.4 . .
HP2A CP2 HP2B 108.0 . .
CP4 CP3 CP2 100.3(15) . .
CP4 CP3 HP3A 111.7 . .
CP2 CP3 HP3A 111.7 . .
CP4 CP3 HP3B 111.7 . .
CP2 CP3 HP3B 111.7 . .
HP3A CP3 HP3B 109.5 . .
CP5 CP4 CP3 115.1(19) . .
CP5 CP4 HP4A 108.5 . .
CP3 CP4 HP4A 108.5 . .
CP5 CP4 HP4B 108.5 . .
CP3 CP4 HP4B 108.5 . .
HP4A CP4 HP4B 107.5 . .
CP4 CP5 CP1 107.4(19) . .
CP4 CP5 HP5A 110.2 . .
CP1 CP5 HP5A 110.2 . .
CP4 CP5 HP5B 110.2 . .
CP1 CP5 HP5B 110.2 . .
HP5A CP5 HP5B 108.5 . .
CP10 CP6 CP7 102(2) . .
CP10 CP6 HP6A 111.3 . .
CP7 CP6 HP6A 111.2 . .
CP10 CP6 HP6B 111.3 . .
CP7 CP6 HP6B 111.3 . .
HP6A CP6 HP6B 109.2 . .
CP8 CP7 CP6 109(2) . .
CP8 CP7 HP7A 109.9 . .
CP6 CP7 HP7A 109.9 . .
CP8 CP7 HP7B 109.9 . .
CP6 CP7 HP7B 109.9 . .
HP7A CP7 HP7B 108.3 . .
CP7 CP8 CP9 105(2) . .
CP7 CP8 HP8A 110.8 . .
CP9 CP8 HP8A 110.9 . .
CP7 CP8 HP8B 110.8 . .
CP9 CP8 HP8B 110.8 . .
HP8A CP8 HP8B 108.9 . .
CP10 CP9 CP8 106(2) . .
CP10 CP9 HP9A 110.6 . .
CP8 CP9 HP9A 110.6 . .
CP10 CP9 HP9B 110.5 . .
CP8 CP9 HP9B 110.5 . .
HP9A CP9 HP9B 108.7 . .
CP6 CP10 CP9 109(2) . .
CP6 CP10 HP1C 109.9 . .
CP9 CP10 HP1C 109.9 . .
CP6 CP10 HP1D 109.9 . .
CP9 CP10 HP1D 109.9 . .
HP1C CP10 HP1D 108.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
P1 Ga1 2.3413(13) 7_575
P1 Ga1 2.3413(13) .
P1 Ga2 2.3417(18) .
P2 P2 2.178(3) 7_575
P2 P3 2.183(2) .
P2 Ga1 2.3693(15) .
P3 P2 2.183(2) 7_575
P3 Ga2 2.378(2) .
Ga1 C1 1.970(5) .
Ga2 C2 1.971(7) .
C1 Si2A 1.744(6) .
C1 Si3 1.855(5) .
C1 Si1 1.889(7) .
C1 Si1A 1.938(9) .
C1 Si2 2.005(6) .
C1 Si3A 2.096(6) .
Si1 C11 1.847(15) .
Si1 C12 1.865(12) .
Si1 C13 1.893(13) .
C11 H11A 0.9603 .
C11 H11B 0.9603 .
C11 H11C 0.9603 .
C12 H12A 0.9599 .
C12 H12B 0.9599 .
C12 H12C 0.9599 .
C13 H13A 0.9599 .
C13 H13B 0.9599 .
C13 H13C 0.9599 .
Si2 C22 1.867(14) .
Si2 C21 1.874(18) .
Si2 C23 1.887(11) .
C21 H21A 0.9599 .
C21 H21B 0.9599 .
C21 H21C 0.9599 .
C22 H22A 0.9599 .
C22 H22B 0.9599 .
C22 H22C 0.9599 .
C23 H23A 0.9599 .
C23 H23B 0.9599 .
C23 H23C 0.9599 .
Si3 C33 1.875(11) .
Si3 C32 1.890(16) .
Si3 C31 1.906(19) .
C31 H31A 0.9599 .
C31 H31B 0.9599 .
C31 H31C 0.9599 .
C32 H32A 0.9599 .
C32 H32B 0.9599 .
C32 H32C 0.9599 .
C33 H33A 0.9599 .
C33 H33B 0.9599 .
C33 H33C 0.9599 .
Si1A C11A 1.848(15) .
Si1A C12A 1.859(12) .
Si1A C13A 1.881(12) .
C11A H11D 0.9601 .
C11A H11E 0.9601 .
C11A H11F 0.9601 .
C12A H12D 0.9599 .
C12A H12E 0.9599 .
C12A H12F 0.9599 .
C13A H13D 0.9599 .
C13A H13E 0.9599 .
C13A H13F 0.9599 .
Si2A C23A 1.877(11) .
Si2A C21A 1.914(18) .
Si2A C22A 1.926(13) .
C21A H21D 0.9599 .
C21A H21E 0.9599 .
C21A H21F 0.9599 .
C22A H22D 0.9599 .
C22A H22E 0.9599 .
C22A H22F 0.9599 .
C23A H23D 0.9599 .
C23A H23E 0.9599 .
C23A H23F 0.9599 .
Si3A C32A 1.838(14) .
Si3A C31A 1.879(19) .
Si3A C33A 1.884(10) .
C31A H31D 0.9599 .
C31A H31E 0.9599 .
C31A H31F 0.9599 .
C32A H32D 0.9599 .
C32A H32E 0.9599 .
C32A H32F 0.9599 .
C33A H33D 0.9599 .
C33A H33E 0.9599 .
C33A H33F 0.9599 .
Si4 C42 1.878(7) 7_575
Si4 C42 1.878(7) .
Si4 C41 1.886(8) .
Si4 C2 1.903(8) .
C41 H41A 0.9599 .
C41 H41B 0.9599 .
C41 H41C 0.9599 .
C42 H42A 0.9599 .
C42 H42B 0.9599 .
C42 H42C 0.9599 .
C2 Si5A 1.815(5) .
C2 Si5A 1.815(5) 7_575
C2 Si5 2.029(4) 7_575
C2 Si5 2.029(4) .
Si5 C51 1.850(17) .
Si5 C53 1.889(15) .
Si5 C52 1.894(12) .
C51 H51A 0.9599 .
C51 H51B 0.9599 .
C51 H51C 0.9599 .
C52 H52A 0.9599 .
C52 H52B 0.9599 .
C52 H52C 0.9599 .
C53 H53A 0.9599 .
C53 H53B 0.9599 .
C53 H53C 0.9599 .
Si5A C51A 1.877(16) .
Si5A C52A 1.890(11) .
Si5A C53A 1.932(15) .
Si5A Si5A 2.288(8) 7_575
Si5A C52A 2.405(14) 7_575
C51A H51D 0.9599 .
C51A H51E 0.9599 .
C51A H51F 0.9599 .
C52A H52D 0.9599 .
C52A H52E 0.9599 .
C52A H52F 0.9599 .
C53A H53D 0.9599 .
C53A H53E 0.9599 .
C53A H53F 0.9599 .
CP1 CP2 1.438(18) .
CP1 CP5 1.47(2) .
CP1 HP1A 0.9600 .
CP1 HP1B 0.9600 .
CP2 CP3 1.495(19) .
CP2 HP2A 0.9600 .
CP2 HP2B 0.9600 .
CP3 CP4 1.45(2) .
CP3 HP3A 0.9600 .
CP3 HP3B 0.9600 .
CP4 CP5 1.36(2) .
CP4 HP4A 0.9600 .
CP4 HP4B 0.9600 .
CP5 HP5A 0.9600 .
CP5 HP5B 0.9600 .
CP6 CP10 1.38(3) .
CP6 CP7 1.45(3) .
CP6 HP6A 0.9600 .
CP6 HP6B 0.9600 .
CP7 CP8 1.35(3) .
CP7 HP7A 0.9600 .
CP7 HP7B 0.9600 .
CP8 CP9 1.47(2) .
CP8 HP8A 0.9600 .
CP8 HP8B 0.9600 .
CP9 CP10 1.39(3) .
CP9 HP9A 0.9600 .
CP9 HP9B 0.9600 .
CP10 HP1C 0.9600 .
CP10 HP1D 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ga1 P2 P3 P2 -97.58(6) . 7_575
P2 P2 P3 Ga2 97.22(5) 7_575 .
Ga1 P2 P3 Ga2 -0.36(7) . .
Ga1 P1 Ga1 C1 -140.1(2) 7_575 .
Ga2 P1 Ga1 C1 133.7(2) . .
Ga1 P1 Ga1 P2 42.35(7) 7_575 .
Ga2 P1 Ga1 P2 -43.81(6) . .
P2 P2 Ga1 C1 152.02(18) 7_575 .
P3 P2 Ga1 C1 -146.32(19) . .
P2 P2 Ga1 P1 -30.19(5) 7_575 .
P3 P2 Ga1 P1 31.47(9) . .
Ga1 P1 Ga2 C2 136.64(3) 7_575 .
Ga1 P1 Ga2 C2 -136.64(3) . .
Ga1 P1 Ga2 P3 -43.36(3) 7_575 .
Ga1 P1 Ga2 P3 43.36(3) . .
P2 P3 Ga2 C2 -149.30(6) 7_575 .
P2 P3 Ga2 C2 149.30(6) . .
P2 P3 Ga2 P1 30.70(6) 7_575 .
P2 P3 Ga2 P1 -30.70(6) . .
P1 Ga1 C1 Si2A -133.4(3) . .
P2 Ga1 C1 Si2A 44.1(4) . .
P1 Ga1 C1 Si3 132.3(2) . .
P2 Ga1 C1 Si3 -50.2(3) . .
P1 Ga1 C1 Si1 -1.7(5) . .
P2 Ga1 C1 Si1 175.7(4) . .
P1 Ga1 C1 Si1A 7.6(5) . .
P2 Ga1 C1 Si1A -174.9(4) . .
P1 Ga1 C1 Si2 -112.80(18) . .
P2 Ga1 C1 Si2 64.7(2) . .
P1 Ga1 C1 Si3A 110.99(17) . .
P2 Ga1 C1 Si3A -71.6(2) . .
Si2A C1 Si1 C11 -161.8(9) . .
Si3 C1 Si1 C11 -76.1(10) . .
Si1A C1 Si1 C11 -14(4) . .
Ga1 C1 Si1 C11 59.2(10) . .
Si2 C1 Si1 C11 162.9(9) . .
Si3A C1 Si1 C11 -42.5(10) . .
Si2A C1 Si1 C12 78.8(9) . .
Si3 C1 Si1 C12 164.4(7) . .
Si1A C1 Si1 C12 -133(5) . .
Ga1 C1 Si1 C12 -60.3(9) . .
Si2 C1 Si1 C12 43.5(9) . .
Si3A C1 Si1 C12 -162.0(7) . .
Si2A C1 Si1 C13 -41.2(9) . .
Si3 C1 Si1 C13 44.5(10) . .
Si1A C1 Si1 C13 107(5) . .
Ga1 C1 Si1 C13 179.8(8) . .
Si2 C1 Si1 C13 -76.5(9) . .
Si3A C1 Si1 C13 78.1(9) . .
Si2A C1 Si2 C22 -55.4(9) . .
Si3 C1 Si2 C22 -82.2(9) . .
Si1 C1 Si2 C22 42.0(10) . .
Si1A C1 Si2 C22 42.6(10) . .
Ga1 C1 Si2 C22 156.6(9) . .
Si3A C1 Si2 C22 -102.9(9) . .
Si2A C1 Si2 C21 65.0(12) . .
Si3 C1 Si2 C21 38.1(13) . .
Si1 C1 Si2 C21 162.3(13) . .
Si1A C1 Si2 C21 162.9(13) . .
Ga1 C1 Si2 C21 -83.0(12) . .
Si3A C1 Si2 C21 17.5(13) . .
Si2A C1 Si2 C23 -176.5(5) . .
Si3 C1 Si2 C23 156.7(5) . .
Si1 C1 Si2 C23 -79.1(6) . .
Si1A C1 Si2 C23 -78.5(6) . .
Ga1 C1 Si2 C23 35.5(5) . .
Si3A C1 Si2 C23 136.1(5) . .
Si2A C1 Si3 C33 28.8(6) . .
Si1 C1 Si3 C33 -76.3(7) . .
Si1A C1 Si3 C33 -85.0(7) . .
Ga1 C1 Si3 C33 150.9(5) . .
Si2 C1 Si3 C33 43.6(6) . .
Si3A C1 Si3 C33 -164.8(6) . .
Si2A C1 Si3 C32 149.1(7) . .
Si1 C1 Si3 C32 43.9(9) . .
Si1A C1 Si3 C32 35.2(9) . .
Ga1 C1 Si3 C32 -88.9(7) . .
Si2 C1 Si3 C32 163.8(7) . .
Si3A C1 Si3 C32 -44.6(7) . .
Si2A C1 Si3 C31 -95.0(15) . .
Si1 C1 Si3 C31 159.9(16) . .
Si1A C1 Si3 C31 151.2(16) . .
Ga1 C1 Si3 C31 27.1(15) . .
Si2 C1 Si3 C31 -80.2(15) . .
Si3A C1 Si3 C31 71.4(15) . .
Si2A C1 Si1A C11A -160.4(7) . .
Si3 C1 Si1A C11A -73.6(8) . .
Si1 C1 Si1A C11A 165(5) . .
Ga1 C1 Si1A C11A 55.3(8) . .
Si2 C1 Si1A C11A 162.0(7) . .
Si3A C1 Si1A C11A -42.0(8) . .
Si2A C1 Si1A C12A 81.7(8) . .
Si3 C1 Si1A C12A 168.5(6) . .
Si1 C1 Si1A C12A 48(4) . .
Ga1 C1 Si1A C12A -62.6(8) . .
Si2 C1 Si1A C12A 44.1(9) . .
Si3A C1 Si1A C12A -159.9(7) . .
Si2A C1 Si1A C13A -39.0(10) . .
Si3 C1 Si1A C13A 47.9(10) . .
Si1 C1 Si1A C13A -73(5) . .
Ga1 C1 Si1A C13A 176.8(9) . .
Si2 C1 Si1A C13A -76.5(9) . .
Si3A C1 Si1A C13A 79.5(9) . .
Si3 C1 Si2A C23A -32.3(6) . .
Si1 C1 Si2A C23A 79.8(7) . .
Si1A C1 Si2A C23A 74.3(7) . .
Ga1 C1 Si2A C23A -147.3(6) . .
Si2 C1 Si2A C23A 173.5(6) . .
Si3A C1 Si2A C23A -39.8(6) . .
Si3 C1 Si2A C21A 93.3(11) . .
Si1 C1 Si2A C21A -154.6(12) . .
Si1A C1 Si2A C21A -160.0(12) . .
Ga1 C1 Si2A C21A -21.7(12) . .
Si2 C1 Si2A C21A -60.9(11) . .
Si3A C1 Si2A C21A 85.8(11) . .
Si3 C1 Si2A C22A -154.6(7) . .
Si1 C1 Si2A C22A -42.4(8) . .
Si1A C1 Si2A C22A -47.9(9) . .
Ga1 C1 Si2A C22A 90.5(8) . .
Si2 C1 Si2A C22A 51.2(7) . .
Si3A C1 Si2A C22A -162.0(7) . .
Si2A C1 Si3A C32A 79.7(11) . .
Si3 C1 Si3A C32A 65.5(10) . .
Si1 C1 Si3A C32A -39.0(11) . .
Si1A C1 Si3A C32A -43.5(11) . .
Ga1 C1 Si3A C32A -153.1(10) . .
Si2 C1 Si3A C32A 105.3(11) . .
Si2A C1 Si3A C31A -41.2(16) . .
Si3 C1 Si3A C31A -55.3(16) . .
Si1 C1 Si3A C31A -159.8(17) . .
Si1A C1 Si3A C31A -164.3(16) . .
Ga1 C1 Si3A C31A 86.1(16) . .
Si2 C1 Si3A C31A -15.6(16) . .
Si2A C1 Si3A C33A -158.4(5) . .
Si3 C1 Si3A C33A -172.5(5) . .
Si1 C1 Si3A C33A 83.0(6) . .
Si1A C1 Si3A C33A 78.5(6) . .
Ga1 C1 Si3A C33A -31.1(5) . .
Si2 C1 Si3A C33A -132.8(5) . .
C42 Si4 C2 Si5A 163.9(3) 7_575 .
C42 Si4 C2 Si5A -78.0(4) . .
C41 Si4 C2 Si5A 42.9(2) . .
C42 Si4 C2 Si5A 78.0(4) 7_575 7_575
C42 Si4 C2 Si5A -163.9(3) . 7_575
C41 Si4 C2 Si5A -42.9(2) . 7_575
C42 Si4 C2 Ga2 -59.0(3) 7_575 .
C42 Si4 C2 Ga2 59.0(3) . .
C41 Si4 C2 Ga2 180.0 . .
C42 Si4 C2 Si5 44.1(4) 7_575 7_575
C42 Si4 C2 Si5 162.2(3) . 7_575
C41 Si4 C2 Si5 -76.8(3) . 7_575
C42 Si4 C2 Si5 -162.2(3) 7_575 .
C42 Si4 C2 Si5 -44.1(4) . .
C41 Si4 C2 Si5 76.8(3) . .
P1 Ga2 C2 Si5A 133.5(3) . .
P3 Ga2 C2 Si5A -46.5(3) . .
P1 Ga2 C2 Si5A -133.5(3) . 7_575
P3 Ga2 C2 Si5A 46.5(3) . 7_575
P1 Ga2 C2 Si4 0.0 . .
P3 Ga2 C2 Si4 180.0 . .
P1 Ga2 C2 Si5 -111.9(2) . 7_575
P3 Ga2 C2 Si5 68.1(2) . 7_575
P1 Ga2 C2 Si5 111.9(2) . .
P3 Ga2 C2 Si5 -68.1(2) . .
Si5A C2 Si5 C51 -63(2) . .
Si5A C2 Si5 C51 -44(2) 7_575 .
Si4 C2 Si5 C51 -165.6(19) . .
Ga2 C2 Si5 C51 80.1(19) . .
Si5 C2 Si5 C51 -22(2) 7_575 .
Si5A C2 Si5 C53 61.8(10) . .
Si5A C2 Si5 C53 81.0(10) 7_575 .
Si4 C2 Si5 C53 -41.1(10) . .
Ga2 C2 Si5 C53 -155.3(9) . .
Si5 C2 Si5 C53 102.3(11) 7_575 .
Si5A C2 Si5 C52 -177.0(6) . .
Si5A C2 Si5 C52 -157.7(6) 7_575 .
Si4 C2 Si5 C52 80.2(6) . .
Ga2 C2 Si5 C52 -34.0(6) . .
Si5 C2 Si5 C52 -136.5(7) 7_575 .
Si5A C2 Si5A C51A -88(2) 7_575 .
Si4 C2 Si5A C51A 162(2) . .
Ga2 C2 Si5A C51A 29(2) . .
Si5 C2 Si5A C51A -78(2) 7_575 .
Si5 C2 Si5A C51A 73(2) . .
Si5A C2 Si5A C52A 31.8(6) 7_575 .
Si4 C2 Si5A C52A -77.6(6) . .
Ga2 C2 Si5A C52A 149.5(5) . .
Si5 C2 Si5A C52A 42.1(7) 7_575 .
Si5 C2 Si5A C52A -166.8(6) . .
Si5A C2 Si5A C53A 152.1(6) 7_575 .
Si4 C2 Si5A C53A 42.7(7) . .
Ga2 C2 Si5A C53A -90.3(7) . .
Si5 C2 Si5A C53A 162.4(7) 7_575 .
Si5 C2 Si5A C53A -46.5(7) . .
Si4 C2 Si5A Si5A -109.4(4) . 7_575
Ga2 C2 Si5A Si5A 117.6(4) . 7_575
Si5 C2 Si5A Si5A 10.27(16) 7_575 7_575
Si5 C2 Si5A Si5A 161.3(3) . 7_575
Si5A C2 Si5A C52A 22.3(4) 7_575 7_575
Si4 C2 Si5A C52A -87.1(4) . 7_575
Ga2 C2 Si5A C52A 140.0(4) . 7_575
Si5 C2 Si5A C52A 32.6(5) 7_575 7_575
Si5 C2 Si5A C52A -176.3(5) . 7_575
CP5 CP1 CP2 CP3 -7(2) . .
CP1 CP2 CP3 CP4 8(2) . .
CP2 CP3 CP4 CP5 -7(2) . .
CP3 CP4 CP5 CP1 3(3) . .
CP2 CP1 CP5 CP4 3(2) . .
CP10 CP6 CP7 CP8 -31(3) . .
CP6 CP7 CP8 CP9 23(3) . .
CP7 CP8 CP9 CP10 -6(3) . .
CP7 CP6 CP10 CP9 26(3) . .
CP8 CP9 CP10 CP6 -13(3) . .
