#------------------------------------------------------------------------------
#$Date: 2016-03-26 13:59:47 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180243 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/29/7112917.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7112917
loop_
_publ_author_name
'Molon, Mariusz'
'Cadenbach, Thomas'
'Bollermann, Timo'
'Gemel, Christian'
'Fischer, Roland A.'
_publ_section_title
;
 One electron organozinc ligands in metal rich molecules by Ga/Zn
 exchange: from Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units.
;
_journal_issue                   31
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              5677
_journal_page_last               5679
_journal_paper_doi               10.1039/c0cc00146e
_journal_volume                  46
_journal_year                    2010
_chemical_formula_sum            'C62 H96 Cl2 Rh2 Zn8'
_chemical_formula_weight         1641.07
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.371(4)
_cell_angle_beta                 103.069(3)
_cell_angle_gamma                100.675(3)
_cell_formula_units_Z            1
_cell_length_a                   10.5803(4)
_cell_length_b                   12.4484(5)
_cell_length_c                   16.6142(7)
_cell_measurement_reflns_used    7015
_cell_measurement_temperature    105(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      3.01
_cell_volume                     1996.15(15)
_computing_cell_refinement       'CrysAlis RED 1.171.13, Oxford Diffraction'
_computing_data_collection       'CrysAlis CCD 1.171.13, Oxford Diffraction'
_computing_data_reduction        'CrysAlis RED 1.171.13, Oxford Diffraction'
_computing_molecular_graphics    SHELXL-97
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      105(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Sapphire2-CCD, Oxford Diffraction'
_diffrn_measurement_method       '560 images at 1.0 deg. in ω and 25 sec.'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0888
_diffrn_reflns_av_sigmaI/netI    0.1350
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            12176
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    2.855
_exptl_absorpt_correction_T_max  0.755
_exptl_absorpt_correction_T_min  0.507
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.365
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cubic
_exptl_crystal_F_000             832
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_platon_squeeze_details
;
;
_refine_diff_density_max         1.153
_refine_diff_density_min         -1.331
_refine_diff_density_rms         0.192
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.871
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         7015
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.871
_refine_ls_R_factor_all          0.0926
_refine_ls_R_factor_gt           0.0634
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0900P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1519
_refine_ls_wR_factor_ref         0.1601
_reflns_number_gt                4290
_reflns_number_total             7015
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0cc00146e.txt
_cod_data_source_block           1
_cod_original_cell_volume        1996.15(14)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7112917
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 0.75084(6) 0.52593(5) 0.28290(4) 0.01635(18) Uani 1 1 d .
Zn1 Zn 0.90955(9) 0.50066(8) 0.40088(6) 0.0227(2) Uani 1 1 d .
Zn2 Zn 0.80856(9) 0.51866(8) 0.14998(6) 0.0218(2) Uani 1 1 d .
Zn3 Zn 0.97000(9) 0.65357(8) 0.31331(6) 0.0221(2) Uani 1 1 d .
Zn4 Zn 0.80323(9) 0.34664(8) 0.22656(6) 0.0231(2) Uani 1 1 d .
Cl1 Cl 1.0409(2) 0.3882(2) 0.44917(14) 0.0377(6) Uani 1 1 d .
C1 C 0.5529(8) 0.4701(8) 0.3037(6) 0.029(2) Uani 1 1 d .
C2 C 0.5334(8) 0.4842(8) 0.2185(5) 0.028(2) Uani 1 1 d .
C3 C 0.5886(9) 0.6012(8) 0.2291(6) 0.029(2) Uani 1 1 d .
C4 C 0.6414(8) 0.6564(7) 0.3227(6) 0.028(2) Uani 1 1 d .
C5 C 0.6156(8) 0.5728(8) 0.3653(5) 0.026(2) Uani 1 1 d .
C6 C 0.4937(9) 0.3584(9) 0.3210(7) 0.044(3) Uani 1 1 d .
H6A H 0.4038 0.3579 0.3273 0.066 Uiso 1 1 calc R
H6B H 0.5517 0.3536 0.3743 0.066 Uiso 1 1 calc R
H6C H 0.4881 0.2926 0.2723 0.066 Uiso 1 1 calc R
C7 C 0.4504(9) 0.3896(9) 0.1332(6) 0.040(3) Uani 1 1 d .
H7A H 0.3561 0.3923 0.1209 0.060 Uiso 1 1 calc R
H7B H 0.4572 0.3144 0.1391 0.060 Uiso 1 1 calc R
H7C H 0.4852 0.4022 0.0855 0.060 Uiso 1 1 calc R
C8 C 0.5703(10) 0.6587(9) 0.1606(7) 0.048(3) Uani 1 1 d .
H8A H 0.4852 0.6808 0.1541 0.072 Uiso 1 1 calc R
H8B H 0.5690 0.6059 0.1056 0.072 Uiso 1 1 calc R
H8C H 0.6445 0.7273 0.1769 0.072 Uiso 1 1 calc R
C9 C 0.6968(11) 0.7857(8) 0.3631(8) 0.053(3) Uani 1 1 d .
H9A H 0.6237 0.8207 0.3729 0.080 Uiso 1 1 calc R
H9B H 0.7375 0.8176 0.3238 0.080 Uiso 1 1 calc R
H9C H 0.7649 0.8021 0.4185 0.080 Uiso 1 1 calc R
C10 C 0.6306(10) 0.6000(9) 0.4627(6) 0.044(3) Uani 1 1 d .
H10A H 0.5482 0.6164 0.4742 0.066 Uiso 1 1 calc R
H10B H 0.7065 0.6669 0.4946 0.066 Uiso 1 1 calc R
H10C H 0.6468 0.5339 0.4816 0.066 Uiso 1 1 calc R
C11 C 0.8045(9) 0.5289(8) 0.0327(5) 0.029(2) Uani 1 1 d .
H11A H 0.7331 0.4656 -0.0106 0.044 Uiso 1 1 calc R
H11B H 0.8911 0.5241 0.0223 0.044 Uiso 1 1 calc R
H11C H 0.7872 0.6022 0.0281 0.044 Uiso 1 1 calc R
C12 C 1.1902(9) 0.6845(8) 0.3058(8) 0.044(3) Uani 1 1 d .
C13 C 1.1234(10) 0.7480(10) 0.2578(6) 0.049(3) Uani 1 1 d .
C14 C 1.0862(9) 0.8281(8) 0.3168(7) 0.037(2) Uani 1 1 d .
C15 C 1.1289(8) 0.8155(7) 0.4005(5) 0.0248(19) Uani 1 1 d .
C16 C 1.1922(8) 0.7269(8) 0.3947(7) 0.034(2) Uani 1 1 d .
C17 C 1.2535(12) 0.5946(12) 0.2657(12) 0.118(7) Uani 1 1 d .
H17A H 1.3469 0.6303 0.2710 0.177 Uiso 1 1 calc R
H17B H 1.2039 0.5590 0.2043 0.177 Uiso 1 1 calc R
H17C H 1.2510 0.5360 0.2957 0.177 Uiso 1 1 calc R
C18 C 1.1035(14) 0.7430(14) 0.1668(7) 0.109(7) Uani 1 1 d .
H18A H 1.1840 0.7896 0.1605 0.164 Uiso 1 1 calc R
H18B H 1.0262 0.7727 0.1475 0.164 Uiso 1 1 calc R
H18C H 1.0869 0.6633 0.1314 0.164 Uiso 1 1 calc R
C19 C 1.0195(12) 0.9158(11) 0.2918(11) 0.091(6) Uani 1 1 d .
H19A H 1.0880 0.9844 0.2979 0.136 Uiso 1 1 calc R
H19B H 0.9633 0.9361 0.3297 0.136 Uiso 1 1 calc R
H19C H 0.9635 0.8842 0.2314 0.136 Uiso 1 1 calc R
C20 C 1.1137(12) 0.8884(10) 0.4844(7) 0.065(4) Uani 1 1 d .
H20A H 1.1926 0.9538 0.5121 0.097 Uiso 1 1 calc R
H20B H 1.1058 0.8419 0.5236 0.097 Uiso 1 1 calc R
H20C H 1.0330 0.9163 0.4715 0.097 Uiso 1 1 calc R
C21 C 1.2615(11) 0.6909(12) 0.4672(9) 0.086(5) Uani 1 1 d .
H21A H 1.3553 0.7358 0.4901 0.129 Uiso 1 1 calc R
H21B H 1.2581 0.6092 0.4465 0.129 Uiso 1 1 calc R
H21C H 1.2170 0.7036 0.5132 0.129 Uiso 1 1 calc R
C22 C 0.7573(8) 0.2136(7) 0.0839(5) 0.0222(18) Uani 1 1 d .
C23 C 0.7017(9) 0.1626(7) 0.1410(5) 0.0247(19) Uani 1 1 d .
C24 C 0.8120(9) 0.1689(7) 0.2119(5) 0.027(2) Uani 1 1 d .
C25 C 0.9330(8) 0.2225(6) 0.1974(5) 0.0188(18) Uani 1 1 d .
C26 C 0.8988(8) 0.2500(7) 0.1189(5) 0.0235(19) Uani 1 1 d .
C27 C 0.6790(8) 0.2199(7) -0.0012(5) 0.027(2) Uani 1 1 d .
H27A H 0.6780 0.1534 -0.0479 0.041 Uiso 1 1 calc R
H27B H 0.7210 0.2905 -0.0113 0.041 Uiso 1 1 calc R
H27C H 0.5868 0.2200 -0.0002 0.041 Uiso 1 1 calc R
C28 C 0.5569(8) 0.1031(8) 0.1227(6) 0.034(2) Uani 1 1 d .
H28A H 0.5381 0.0249 0.0840 0.051 Uiso 1 1 calc R
H28B H 0.5003 0.1454 0.0950 0.051 Uiso 1 1 calc R
H28C H 0.5377 0.1002 0.1773 0.051 Uiso 1 1 calc R
C29 C 0.7957(9) 0.1125(8) 0.2801(5) 0.030(2) Uani 1 1 d .
H29A H 0.8036 0.0335 0.2613 0.046 Uiso 1 1 calc R
H29B H 0.7072 0.1118 0.2891 0.046 Uiso 1 1 calc R
H29C H 0.8656 0.1552 0.3345 0.046 Uiso 1 1 calc R
C30 C 1.0747(9) 0.2334(8) 0.2503(6) 0.034(2) Uani 1 1 d .
H30A H 1.1065 0.1682 0.2234 0.051 Uiso 1 1 calc R
H30B H 1.0747 0.2339 0.3094 0.051 Uiso 1 1 calc R
H30C H 1.1341 0.3050 0.2523 0.051 Uiso 1 1 calc R
C31 C 0.9962(8) 0.3018(7) 0.0788(6) 0.029(2) Uani 1 1 d .
H31A H 1.0159 0.2409 0.0372 0.043 Uiso 1 1 calc R
H31B H 1.0793 0.3468 0.1240 0.043 Uiso 1 1 calc R
H31C H 0.9579 0.3520 0.0488 0.043 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Rh1 C2 38.1(3) . .
C1 Rh1 C4 60.9(3) . .
C2 Rh1 C4 62.3(3) . .
C1 Rh1 C3 62.7(3) . .
C2 Rh1 C3 37.3(3) . .
C4 Rh1 C3 38.5(3) . .
C1 Rh1 C5 35.5(3) . .
C2 Rh1 C5 62.0(3) . .
C4 Rh1 C5 37.0(3) . .
C3 Rh1 C5 63.1(3) . .
C1 Rh1 Zn1 104.9(2) . .
C2 Rh1 Zn1 141.9(2) . .
C4 Rh1 Zn1 114.4(2) . .
C3 Rh1 Zn1 152.7(2) . .
C5 Rh1 Zn1 92.4(2) . .
C1 Rh1 Zn2 129.7(2) . .
C2 Rh1 Zn2 93.1(2) . .
C4 Rh1 Zn2 115.3(2) . .
C3 Rh1 Zn2 85.0(2) . .
C5 Rh1 Zn2 148.1(2) . .
Zn1 Rh1 Zn2 118.65(4) . .
C1 Rh1 Zn4 102.8(2) . .
C2 Rh1 Zn4 101.7(2) . .
C4 Rh1 Zn4 162.8(2) . .
C3 Rh1 Zn4 131.3(2) . .
C5 Rh1 Zn4 131.7(2) . .
Zn1 Rh1 Zn4 73.50(4) . .
Zn2 Rh1 Zn4 69.52(4) . .
C1 Rh1 Zn3 155.2(2) . .
C2 Rh1 Zn3 147.1(2) . .
C4 Rh1 Zn3 98.6(2) . .
C3 Rh1 Zn3 111.1(2) . .
C5 Rh1 Zn3 119.7(2) . .
Zn1 Rh1 Zn3 69.14(4) . .
Zn2 Rh1 Zn3 70.07(3) . .
Zn4 Rh1 Zn3 98.48(4) . .
Cl1 Zn1 Rh1 147.82(7) . .
Cl1 Zn1 Cl1 87.09(8) . 2_766
Rh1 Zn1 Cl1 124.34(7) . 2_766
Cl1 Zn1 Zn3 127.18(8) . .
Rh1 Zn1 Zn3 55.75(3) . .
Cl1 Zn1 Zn3 106.44(7) 2_766 .
Cl1 Zn1 Zn4 94.41(7) . .
Rh1 Zn1 Zn4 53.41(3) . .
Cl1 Zn1 Zn4 169.02(8) 2_766 .
Zn3 Zn1 Zn4 81.30(4) . .
C11 Zn2 Rh1 162.1(3) . .
C11 Zn2 Zn4 135.3(3) . .
Rh1 Zn2 Zn4 55.35(3) . .
C11 Zn2 Zn3 132.1(3) . .
Rh1 Zn2 Zn3 55.22(3) . .
Zn4 Zn2 Zn3 83.13(4) . .
C14 Zn3 C15 36.4(3) . .
C14 Zn3 C16 59.7(3) . .
C15 Zn3 C16 35.2(3) . .
C14 Zn3 C13 35.4(4) . .
C15 Zn3 C13 59.9(3) . .
C16 Zn3 C13 60.2(3) . .
C14 Zn3 C12 58.8(3) . .
C15 Zn3 C12 59.0(3) . .
C16 Zn3 C12 36.0(4) . .
C13 Zn3 C12 35.7(4) . .
C14 Zn3 Rh1 146.3(2) . .
C15 Zn3 Rh1 148.4(2) . .
C16 Zn3 Rh1 150.6(2) . .
C13 Zn3 Rh1 146.8(2) . .
C12 Zn3 Rh1 150.4(2) . .
C14 Zn3 Zn1 148.6(3) . .
C15 Zn3 Zn1 112.3(2) . .
C16 Zn3 Zn1 95.5(2) . .
C13 Zn3 Zn1 148.9(3) . .
C12 Zn3 Zn1 113.3(3) . .
Rh1 Zn3 Zn1 55.11(3) . .
C14 Zn3 Zn2 114.1(3) . .
C15 Zn3 Zn2 150.2(2) . .
C16 Zn3 Zn2 142.1(3) . .
C13 Zn3 Zn2 92.9(2) . .
C12 Zn3 Zn2 106.7(3) . .
Rh1 Zn3 Zn2 54.71(3) . .
Zn1 Zn3 Zn2 97.32(4) . .
C24 Zn4 C23 37.4(3) . .
C24 Zn4 C25 37.2(3) . .
C23 Zn4 C25 60.9(3) . .
C24 Zn4 Rh1 157.8(2) . .
C23 Zn4 Rh1 140.9(2) . .
C25 Zn4 Rh1 158.0(2) . .
C24 Zn4 C22 59.9(3) . .
C23 Zn4 C22 35.5(3) . .
C25 Zn4 C22 58.3(3) . .
Rh1 Zn4 C22 134.9(2) . .
C24 Zn4 C26 59.8(3) . .
C23 Zn4 C26 58.9(3) . .
C25 Zn4 C26 34.8(3) . .
Rh1 Zn4 C26 142.4(2) . .
C22 Zn4 C26 34.1(3) . .
C24 Zn4 Zn2 145.9(2) . .
C23 Zn4 Zn2 118.2(2) . .
C25 Zn4 Zn2 118.2(2) . .
Rh1 Zn4 Zn2 55.13(3) . .
C22 Zn4 Zn2 87.58(19) . .
C26 Zn4 Zn2 87.8(2) . .
C24 Zn4 Zn1 115.4(2) . .
C23 Zn4 Zn1 146.3(2) . .
C25 Zn4 Zn1 111.6(2) . .
Rh1 Zn4 Zn1 53.10(3) . .
C22 Zn4 Zn1 169.0(2) . .
C26 Zn4 Zn1 135.17(19) . .
Zn2 Zn4 Zn1 94.56(4) . .
Zn1 Cl1 Zn1 92.91(8) . 2_766
C5 C1 C2 110.0(8) . .
C5 C1 C6 125.5(8) . .
C2 C1 C6 124.1(8) . .
C5 C1 Rh1 73.8(5) . .
C2 C1 Rh1 70.8(5) . .
C6 C1 Rh1 128.3(6) . .
C3 C2 C1 107.8(7) . .
C3 C2 C7 127.3(8) . .
C1 C2 C7 124.5(8) . .
C3 C2 Rh1 71.9(5) . .
C1 C2 Rh1 71.1(5) . .
C7 C2 Rh1 128.3(6) . .
C2 C3 C4 105.5(7) . .
C2 C3 C8 126.3(9) . .
C4 C3 C8 127.0(9) . .
C2 C3 Rh1 70.8(4) . .
C4 C3 Rh1 70.6(5) . .
C8 C3 Rh1 132.5(6) . .
C5 C4 C3 108.7(7) . .
C5 C4 C9 128.0(9) . .
C3 C4 C9 122.8(9) . .
C5 C4 Rh1 72.7(5) . .
C3 C4 Rh1 70.9(4) . .
C9 C4 Rh1 128.4(6) . .
C1 C5 C4 108.0(7) . .
C1 C5 C10 126.4(8) . .
C4 C5 C10 124.5(8) . .
C1 C5 Rh1 70.7(5) . .
C4 C5 Rh1 70.3(4) . .
C10 C5 Rh1 133.7(6) . .
C13 C12 C16 108.7(8) . .
C13 C12 C17 122.5(12) . .
C16 C12 C17 128.7(12) . .
C13 C12 Zn3 71.8(5) . .
C16 C12 Zn3 71.4(5) . .
C17 C12 Zn3 125.9(7) . .
C14 C13 C12 106.5(8) . .
C14 C13 C18 123.5(13) . .
C12 C13 C18 129.8(13) . .
C14 C13 Zn3 70.4(5) . .
C12 C13 Zn3 72.5(5) . .
C18 C13 Zn3 125.8(7) . .
C13 C14 C15 109.2(9) . .
C13 C14 C19 122.7(11) . .
C15 C14 C19 128.0(11) . .
C13 C14 Zn3 74.2(5) . .
C15 C14 Zn3 72.1(5) . .
C19 C14 Zn3 123.0(6) . .
C16 C15 C14 108.6(8) . .
C16 C15 C20 124.6(9) . .
C14 C15 C20 126.7(9) . .
C16 C15 Zn3 73.8(5) . .
C14 C15 Zn3 71.5(5) . .
C20 C15 Zn3 122.3(6) . .
C15 C16 C12 106.9(9) . .
C15 C16 C21 126.8(11) . .
C12 C16 C21 126.0(10) . .
C15 C16 Zn3 71.0(5) . .
C12 C16 Zn3 72.6(5) . .
C21 C16 Zn3 126.4(6) . .
C26 C22 C23 108.6(7) . .
C26 C22 C27 125.9(7) . .
C23 C22 C27 125.4(7) . .
C26 C22 Zn4 73.3(5) . .
C23 C22 Zn4 67.2(4) . .
C27 C22 Zn4 128.3(5) . .
C22 C23 C24 107.0(7) . .
C22 C23 C28 125.1(7) . .
C24 C23 C28 127.6(8) . .
C22 C23 Zn4 77.3(5) . .
C24 C23 Zn4 67.8(5) . .
C28 C23 Zn4 125.3(6) . .
C25 C24 C23 107.9(7) . .
C25 C24 C29 128.8(8) . .
C23 C24 C29 122.8(8) . .
C25 C24 Zn4 75.1(5) . .
C23 C24 Zn4 74.9(5) . .
C29 C24 Zn4 122.3(6) . .
C26 C25 C24 108.4(7) . .
C26 C25 C30 125.5(8) . .
C24 C25 C30 125.7(8) . .
C26 C25 Zn4 77.9(5) . .
C24 C25 Zn4 67.7(5) . .
C30 C25 Zn4 126.4(5) . .
C22 C26 C25 108.1(7) . .
C22 C26 C31 126.7(8) . .
C25 C26 C31 125.1(7) . .
C22 C26 Zn4 72.7(5) . .
C25 C26 Zn4 67.3(4) . .
C31 C26 Zn4 128.2(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C1 2.213(8) .
Rh1 C2 2.209(8) .
Rh1 C4 2.219(8) .
Rh1 C3 2.223(8) .
Rh1 C5 2.250(8) .
Rh1 Zn1 2.4029(11) .
Rh1 Zn2 2.4062(11) .
Rh1 Zn4 2.4126(11) .
Rh1 Zn3 2.4214(11) .
Zn1 Cl1 2.304(2) .
Zn1 Cl1 2.414(2) 2_766
Zn1 Zn3 2.7374(13) .
Zn1 Zn4 2.8811(13) .
Zn2 C11 1.976(8) .
Zn2 Zn4 2.7473(14) .
Zn2 Zn3 2.7714(13) .
Zn3 C14 2.270(8) .
Zn3 C15 2.277(8) .
Zn3 C16 2.312(8) .
Zn3 C13 2.319(9) .
Zn3 C12 2.327(8) .
Zn4 C24 2.187(8) .
Zn4 C23 2.281(8) .
Zn4 C25 2.285(8) .
Zn4 C22 2.415(8) .
Zn4 C26 2.423(8) .
Cl1 Zn1 2.414(2) 2_766
C1 C5 1.361(13) .
C1 C2 1.442(12) .
C1 C6 1.538(12) .
C2 C3 1.415(12) .
C2 C7 1.547(12) .
C3 C4 1.463(13) .
C3 C8 1.483(13) .
C4 C5 1.417(12) .
C4 C9 1.524(12) .
C5 C10 1.533(12) .
C12 C13 1.424(16) .
C12 C16 1.434(15) .
C12 C17 1.500(15) .
C13 C14 1.394(15) .
C13 C18 1.462(14) .
C14 C15 1.419(13) .
C14 C19 1.497(14) .
C15 C16 1.387(12) .
C15 C20 1.523(13) .
C16 C21 1.477(14) .
C22 C26 1.417(11) .
C22 C23 1.436(11) .
C22 C27 1.497(11) .
C23 C24 1.434(11) .
C23 C28 1.498(12) .
C24 C25 1.431(12) .
C24 C29 1.499(11) .
C25 C26 1.415(11) .
C25 C30 1.519(11) .
C26 C31 1.483(11) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 -0.011 0.000 -0.008 547.9 3.8
