#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:45:17 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180275 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/61/7116106.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116106
loop_
_publ_author_name
'Holger Braunschweig'
'Rian D. Dewhurst'
'Florian Hupp'
'Christoph Schneider'
_publ_section_title
;
 Silver(I) and thallium(I) cations as unsupported bridges between two
 metal bases
;
_journal_name_full               Chem.Commun.
_journal_page_first              15685
_journal_paper_doi               10.1039/C4cc08508F
_journal_volume                  50
_journal_year                    2014
_chemical_formula_moiety
'C72 H132 Ag P4 Pt2, C24 H12 B Cl8,0.5( C6 H12), C4 H8 O'
_chemical_formula_sum            'C103 H158 Ag B Cl8 O P4 Pt2'
_chemical_formula_weight         2328.63
_chemical_name_common
;
?
;
_chemical_name_systematic
; 
?
;
_chemical_properties_physical
'Air-sensitive, Moisture-sensitive, Oxygen-sensitive, Light-sensitive'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.5480(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.5269(9)
_cell_length_b                   16.7472(7)
_cell_length_c                   27.9343(11)
_cell_measurement_temperature    100(2)
_cell_volume                     10237.2(7)
_computing_cell_refinement       'Saint+ ver. 7.68A (Bruker AXS)'
_computing_data_collection       'APEX2 ver. 2010.3 (Bruker AXS)'
_computing_data_reduction        'Saint+ ver. 7.68A (Bruker AXS)'
_computing_molecular_graphics    'XP ver. 5.1 (Bruker AXS, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker X8-APEX II'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'multi-layer mirror'
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0319
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            96564
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.50
_exptl_absorpt_coefficient_mu    3.233
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6353
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sadabs 2008/1 (Bruker 2008)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.511
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4752
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.033
_refine_diff_density_min         -0.814
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1127
_refine_ls_number_reflns         20925
_refine_ls_number_restraints     202
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0317
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0211P)²+9.2616P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0502
_refine_ls_wR_factor_ref         0.0526
_reflns_number_gt                18207
_reflns_number_total             20925
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4cc08508f2.cif
_cod_data_source_block           3
_cod_original_cell_volume        10237.1(7)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7116106
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.218834(5) 0.404608(6) 0.583639(4) 0.01145(3) Uani 1 1 d . . .
Pt2 Pt 0.289843(4) 0.121881(6) 0.653046(4) 0.01072(3) Uani 1 1 d . . .
Ag1 Ag 0.253973(9) 0.258291(12) 0.607941(8) 0.01530(5) Uani 1 1 d . . .
P1 P 0.27068(3) 0.46091(4) 0.66184(3) 0.01281(14) Uani 1 1 d . . .
P2 P 0.16136(3) 0.37589(4) 0.50092(3) 0.01142(14) Uani 1 1 d . . .
P3 P 0.36170(3) 0.11583(4) 0.61763(3) 0.01173(14) Uani 1 1 d . . .
P4 P 0.21807(3) 0.09153(4) 0.68798(3) 0.01322(15) Uani 1 1 d . . .
C11 C 0.28958(12) 0.40076(17) 0.72141(10) 0.0157(6) Uani 1 1 d . . .
H11 H 0.2528 0.3670 0.7164 0.019 Uiso 1 1 calc R . .
C12 C 0.34176(13) 0.34246(18) 0.72792(11) 0.0200(6) Uani 1 1 d . . .
H12A H 0.3336 0.3131 0.6953 0.024 Uiso 1 1 calc R . .
H12B H 0.3803 0.3726 0.7358 0.024 Uiso 1 1 calc R . .
C13 C 0.34881(15) 0.2832(2) 0.77098(12) 0.0304(8) Uani 1 1 d . . .
H13A H 0.3117 0.2495 0.7614 0.036 Uiso 1 1 calc R . .
H13B H 0.3841 0.2479 0.7753 0.036 Uiso 1 1 calc R . .
C14 C 0.35850(14) 0.3249(2) 0.82171(12) 0.0336(9) Uani 1 1 d . . .
H14A H 0.3583 0.2847 0.8477 0.040 Uiso 1 1 calc R . .
H14B H 0.3989 0.3514 0.8342 0.040 Uiso 1 1 calc R . .
C15 C 0.30905(16) 0.3866(2) 0.81594(13) 0.0389(9) Uani 1 1 d . . .
H15A H 0.3191 0.4162 0.8487 0.047 Uiso 1 1 calc R . .
H15B H 0.2696 0.3589 0.8089 0.047 Uiso 1 1 calc R . .
C16 C 0.30244(14) 0.4457(2) 0.77238(10) 0.0252(7) Uani 1 1 d . . .
H16A H 0.3405 0.4772 0.7809 0.030 Uiso 1 1 calc R . .
H16B H 0.2685 0.4831 0.7686 0.030 Uiso 1 1 calc R . .
C21 C 0.34386(12) 0.50608(17) 0.66393(10) 0.0150(6) Uani 1 1 d . . .
H21 H 0.3759 0.4642 0.6784 0.018 Uiso 1 1 calc R . .
C22 C 0.36483(13) 0.57859(19) 0.69921(11) 0.0225(7) Uani 1 1 d . . .
H22A H 0.3325 0.6200 0.6882 0.027 Uiso 1 1 calc R . .
H22B H 0.3705 0.5627 0.7348 0.027 Uiso 1 1 calc R . .
C23 C 0.42438(14) 0.61410(19) 0.69885(12) 0.0253(7) Uani 1 1 d . . .
H23A H 0.4339 0.6634 0.7198 0.030 Uiso 1 1 calc R . .
H23B H 0.4581 0.5757 0.7147 0.030 Uiso 1 1 calc R . .
C24 C 0.42060(14) 0.63351(19) 0.64464(12) 0.0255(7) Uani 1 1 d . . .
H24A H 0.4607 0.6534 0.6457 0.031 Uiso 1 1 calc R . .
H24B H 0.3899 0.6761 0.6299 0.031 Uiso 1 1 calc R . .
C25 C 0.40270(14) 0.55937(19) 0.61075(11) 0.0244(7) Uani 1 1 d . . .
H25A H 0.4352 0.5186 0.6240 0.029 Uiso 1 1 calc R . .
H25B H 0.3990 0.5734 0.5753 0.029 Uiso 1 1 calc R . .
C26 C 0.34229(13) 0.52457(19) 0.60960(10) 0.0208(7) Uani 1 1 d . . .
H26A H 0.3334 0.4749 0.5889 0.025 Uiso 1 1 calc R . .
H26B H 0.3090 0.5630 0.5927 0.025 Uiso 1 1 calc R . .
C31 C 0.22097(12) 0.54187(17) 0.66883(11) 0.0173(6) Uani 1 1 d . . .
H31 H 0.2440 0.5739 0.7002 0.021 Uiso 1 1 calc R . .
C32 C 0.20154(14) 0.59661(18) 0.62175(12) 0.0240(7) Uani 1 1 d . . .
H32A H 0.1835 0.5639 0.5903 0.029 Uiso 1 1 calc R . .
H32B H 0.2381 0.6237 0.6200 0.029 Uiso 1 1 calc R . .
C33 C 0.15497(14) 0.65972(19) 0.62310(14) 0.0334(8) Uani 1 1 d . . .
H33A H 0.1745 0.6970 0.6520 0.040 Uiso 1 1 calc R . .
H33B H 0.1415 0.6909 0.5907 0.040 Uiso 1 1 calc R . .
C34 C 0.10002(14) 0.6215(2) 0.62954(14) 0.0354(9) Uani 1 1 d . . .
H34A H 0.0780 0.5884 0.5989 0.042 Uiso 1 1 calc R . .
H34B H 0.0718 0.6636 0.6321 0.042 Uiso 1 1 calc R . .
C35 C 0.11922(14) 0.5694(2) 0.67768(13) 0.0321(8) Uani 1 1 d . . .
H35A H 0.0827 0.5439 0.6806 0.038 Uiso 1 1 calc R . .
H35B H 0.1386 0.6031 0.7085 0.038 Uiso 1 1 calc R . .
C36 C 0.16412(12) 0.50519(18) 0.67539(12) 0.0216(7) Uani 1 1 d . . .
H36A H 0.1435 0.4689 0.6462 0.026 Uiso 1 1 calc R . .
H36B H 0.1771 0.4733 0.7074 0.026 Uiso 1 1 calc R . .
C41 C 0.10674(12) 0.29236(16) 0.48568(10) 0.0133(6) Uani 1 1 d . . .
H41 H 0.0794 0.2976 0.4487 0.016 Uiso 1 1 calc R . .
C42 C 0.06662(13) 0.29793(18) 0.51801(12) 0.0208(6) Uani 1 1 d . . .
H42A H 0.0925 0.2928 0.5549 0.025 Uiso 1 1 calc R . .
H42B H 0.0464 0.3508 0.5128 0.025 Uiso 1 1 calc R . .
C43 C 0.01831(14) 0.23249(19) 0.50307(13) 0.0284(7) Uani 1 1 d . . .
H43A H -0.0057 0.2357 0.5256 0.034 Uiso 1 1 calc R . .
H43B H -0.0100 0.2413 0.4672 0.034 Uiso 1 1 calc R . .
C44 C 0.04620(13) 0.14951(18) 0.50748(12) 0.0225(7) Uani 1 1 d . . .
H44A H 0.0132 0.1094 0.4945 0.027 Uiso 1 1 calc R . .
H44B H 0.0700 0.1375 0.5441 0.027 Uiso 1 1 calc R . .
C45 C 0.08780(13) 0.14405(17) 0.47680(11) 0.0182(6) Uani 1 1 d . . .
H45A H 0.0630 0.1490 0.4396 0.022 Uiso 1 1 calc R . .
H45B H 0.1081 0.0912 0.4826 0.022 Uiso 1 1 calc R . .
C46 C 0.13623(12) 0.20975(17) 0.49266(11) 0.0172(6) Uani 1 1 d . . .
H46A H 0.1619 0.2058 0.4715 0.021 Uiso 1 1 calc R . .
H46B H 0.1630 0.2023 0.5292 0.021 Uiso 1 1 calc R . .
C51 C 0.11241(12) 0.46630(16) 0.47981(10) 0.0141(6) Uani 1 1 d . . .
H51 H 0.0976 0.4780 0.5084 0.017 Uiso 1 1 calc R . .
C52 C 0.15001(13) 0.53957(18) 0.47682(12) 0.0224(7) Uani 1 1 d . . .
H52A H 0.1873 0.5427 0.5084 0.027 Uiso 1 1 calc R . .
H52B H 0.1628 0.5343 0.4469 0.027 Uiso 1 1 calc R . .
C53 C 0.11235(13) 0.61603(18) 0.47136(13) 0.0255(7) Uani 1 1 d . . .
H53A H 0.1023 0.6234 0.5025 0.031 Uiso 1 1 calc R . .
H53B H 0.1368 0.6625 0.4684 0.031 Uiso 1 1 calc R . .
C54 C 0.05368(13) 0.61227(18) 0.42434(12) 0.0238(7) Uani 1 1 d . . .
H54A H 0.0636 0.6117 0.3928 0.029 Uiso 1 1 calc R . .
H54B H 0.0288 0.6604 0.4232 0.029 Uiso 1 1 calc R . .
C55 C 0.01687(13) 0.53781(18) 0.42547(12) 0.0267(7) Uani 1 1 d . . .
H55A H -0.0195 0.5348 0.3932 0.032 Uiso 1 1 calc R . .
H55B H 0.0025 0.5417 0.4546 0.032 Uiso 1 1 calc R . .
C56 C 0.05488(13) 0.46184(19) 0.43127(11) 0.0244(7) Uani 1 1 d . . .
H56A H 0.0303 0.4149 0.4332 0.029 Uiso 1 1 calc R . .
H56B H 0.0664 0.4553 0.4008 0.029 Uiso 1 1 calc R . .
C61 C 0.20426(12) 0.36714(17) 0.45758(10) 0.0143(6) Uani 1 1 d . . .
H61 H 0.2168 0.4227 0.4528 0.017 Uiso 1 1 calc R . .
C62 C 0.16795(13) 0.33574(19) 0.40323(10) 0.0188(6) Uani 1 1 d . . .
H62A H 0.1531 0.2811 0.4055 0.023 Uiso 1 1 calc R . .
H62B H 0.1319 0.3703 0.3866 0.023 Uiso 1 1 calc R . .
C63 C 0.20781(13) 0.3346(2) 0.37070(11) 0.0247(7) Uani 1 1 d . . .
H63A H 0.1842 0.3117 0.3365 0.030 Uiso 1 1 calc R . .
H63B H 0.2191 0.3900 0.3656 0.030 Uiso 1 1 calc R . .
C64 C 0.26542(14) 0.28593(19) 0.39598(11) 0.0233(7) Uani 1 1 d . . .
H64A H 0.2906 0.2877 0.3743 0.028 Uiso 1 1 calc R . .
H64B H 0.2543 0.2295 0.3987 0.028 Uiso 1 1 calc R . .
C65 C 0.30257(13) 0.31818(19) 0.44965(11) 0.0210(7) Uani 1 1 d . . .
H65A H 0.3388 0.2838 0.4660 0.025 Uiso 1 1 calc R . .
H65B H 0.3172 0.3727 0.4466 0.025 Uiso 1 1 calc R . .
C66 C 0.26416(12) 0.32045(18) 0.48347(10) 0.0182(6) Uani 1 1 d . . .
H66A H 0.2881 0.3458 0.5168 0.022 Uiso 1 1 calc R . .
H66B H 0.2545 0.2652 0.4905 0.022 Uiso 1 1 calc R . .
C71 C 0.33133(12) 0.10156(17) 0.54691(10) 0.0144(6) Uani 1 1 d . . .
H71 H 0.3187 0.1560 0.5321 0.017 Uiso 1 1 calc R . .
C72 C 0.27281(12) 0.05097(19) 0.52740(10) 0.0188(6) Uani 1 1 d . . .
H72A H 0.2823 -0.0041 0.5409 0.023 Uiso 1 1 calc R . .
H72B H 0.2425 0.0737 0.5405 0.023 Uiso 1 1 calc R . .
C73 C 0.24530(13) 0.04840(19) 0.46860(10) 0.0211(7) Uani 1 1 d . . .
H73A H 0.2092 0.0128 0.4574 0.025 Uiso 1 1 calc R . .
H73B H 0.2316 0.1026 0.4551 0.025 Uiso 1 1 calc R . .
C74 C 0.29164(13) 0.0184(2) 0.44660(11) 0.0241(7) Uani 1 1 d . . .
H74A H 0.2733 0.0196 0.4085 0.029 Uiso 1 1 calc R . .
H74B H 0.3025 -0.0377 0.4574 0.029 Uiso 1 1 calc R . .
C75 C 0.34918(14) 0.0695(2) 0.46497(11) 0.0248(7) Uani 1 1 d . . .
H75A H 0.3390 0.1244 0.4513 0.030 Uiso 1 1 calc R . .
H75B H 0.3793 0.0473 0.4514 0.030 Uiso 1 1 calc R . .
C76 C 0.37748(13) 0.07241(19) 0.52384(10) 0.0199(6) Uani 1 1 d . . .
H76A H 0.4132 0.1087 0.5346 0.024 Uiso 1 1 calc R . .
H76B H 0.3920 0.0184 0.5373 0.024 Uiso 1 1 calc R . .
C81 C 0.40788(12) 0.02770(16) 0.65050(10) 0.0149(6) Uani 1 1 d . . .
H81 H 0.4142 0.0346 0.6877 0.018 Uiso 1 1 calc R . .
C82 C 0.37274(12) -0.05120(17) 0.63459(11) 0.0180(6) Uani 1 1 d . . .
H82A H 0.3318 -0.0454 0.6366 0.022 Uiso 1 1 calc R . .
H82B H 0.3671 -0.0636 0.5985 0.022 Uiso 1 1 calc R . .
C83 C 0.40684(13) -0.12005(18) 0.66942(12) 0.0233(7) Uani 1 1 d . . .
H83A H 0.4088 -0.1102 0.7049 0.028 Uiso 1 1 calc R . .
H83B H 0.3842 -0.1705 0.6572 0.028 Uiso 1 1 calc R . .
C84 C 0.47139(14) -0.12835(18) 0.66958(12) 0.0250(7) Uani 1 1 d . . .
H84A H 0.4934 -0.1708 0.6940 0.030 Uiso 1 1 calc R . .
H84B H 0.4695 -0.1439 0.6348 0.030 Uiso 1 1 calc R . .
C85 C 0.50577(13) -0.04973(18) 0.68518(12) 0.0239(7) Uani 1 1 d . . .
H85A H 0.5472 -0.0556 0.6842 0.029 Uiso 1 1 calc R . .
H85B H 0.5103 -0.0366 0.7210 0.029 Uiso 1 1 calc R . .
C86 C 0.47253(12) 0.01837(18) 0.64966(11) 0.0200(6) Uani 1 1 d . . .
H86A H 0.4699 0.0070 0.6141 0.024 Uiso 1 1 calc R . .
H86B H 0.4956 0.0687 0.6611 0.024 Uiso 1 1 calc R . .
C91 C 0.42047(12) 0.19415(17) 0.62783(10) 0.0143(6) Uani 1 1 d . . .
H91 H 0.4524 0.1719 0.6159 0.017 Uiso 1 1 calc R . .
C92 C 0.39648(12) 0.27072(17) 0.59725(11) 0.0180(6) Uani 1 1 d . . .
H92A H 0.3785 0.2578 0.5601 0.022 Uiso 1 1 calc R . .
H92B H 0.3638 0.2936 0.6075 0.022 Uiso 1 1 calc R . .
C93 C 0.44721(13) 0.33248(18) 0.60642(12) 0.0238(7) Uani 1 1 d . . .
H93A H 0.4771 0.3123 0.5920 0.029 Uiso 1 1 calc R . .
H93B H 0.4294 0.3825 0.5881 0.029 Uiso 1 1 calc R . .
C94 C 0.47990(13) 0.35033(19) 0.66326(12) 0.0253(7) Uani 1 1 d . . .
H94A H 0.4514 0.3773 0.6767 0.030 Uiso 1 1 calc R . .
H94B H 0.5146 0.3869 0.6678 0.030 Uiso 1 1 calc R . .
C95 C 0.50351(13) 0.27366(18) 0.69348(12) 0.0243(7) Uani 1 1 d . . .
H95A H 0.5351 0.2496 0.6824 0.029 Uiso 1 1 calc R . .
H95B H 0.5227 0.2864 0.7306 0.029 Uiso 1 1 calc R . .
C96 C 0.45197(12) 0.21386(17) 0.68522(10) 0.0178(6) Uani 1 1 d . . .
H96A H 0.4217 0.2364 0.6984 0.021 Uiso 1 1 calc R . .
H96B H 0.4687 0.1643 0.7046 0.021 Uiso 1 1 calc R . .
C101 C 0.17132(12) 0.16827(17) 0.70419(10) 0.0149(6) Uani 1 1 d . . .
H101 H 0.1999 0.2009 0.7329 0.018 Uiso 1 1 calc R . .
C102 C 0.12305(13) 0.13392(17) 0.72342(11) 0.0182(6) Uani 1 1 d . . .
H10A H 0.0960 0.0972 0.6971 0.022 Uiso 1 1 calc R . .
H10B H 0.1438 0.1026 0.7551 0.022 Uiso 1 1 calc R . .
C103 C 0.08400(14) 0.19922(19) 0.73487(12) 0.0239(7) Uani 1 1 d . . .
H10C H 0.0515 0.1740 0.7442 0.029 Uiso 1 1 calc R . .
H10D H 0.1099 0.2314 0.7646 0.029 Uiso 1 1 calc R . .
C104 C 0.05510(13) 0.25358(19) 0.68869(11) 0.0226(7) Uani 1 1 d . . .
H10E H 0.0321 0.2967 0.6978 0.027 Uiso 1 1 calc R . .
H10F H 0.0259 0.2226 0.6599 0.027 Uiso 1 1 calc R . .
C105 C 0.10403(13) 0.28991(17) 0.67170(11) 0.0197(6) Uani 1 1 d . . .
H10G H 0.0844 0.3238 0.6410 0.024 Uiso 1 1 calc R . .
H10H H 0.1313 0.3242 0.6995 0.024 Uiso 1 1 calc R . .
C106 C 0.14165(13) 0.22508(17) 0.65899(11) 0.0179(6) Uani 1 1 d . . .
H10I H 0.1739 0.2504 0.6493 0.021 Uiso 1 1 calc R . .
H10J H 0.1149 0.1941 0.6290 0.021 Uiso 1 1 calc R . .
C111 C 0.25882(13) 0.03696(17) 0.74861(10) 0.0173(6) Uani 1 1 d . . .
H111 H 0.2284 0.0060 0.7583 0.021 Uiso 1 1 calc R . .
C112 C 0.30445(13) -0.02176(17) 0.73992(11) 0.0197(6) Uani 1 1 d . . .
H11A H 0.2822 -0.0587 0.7116 0.024 Uiso 1 1 calc R . .
H11B H 0.3344 0.0083 0.7297 0.024 Uiso 1 1 calc R . .
C113 C 0.33813(14) -0.06970(19) 0.78852(12) 0.0249(7) Uani 1 1 d . . .
H11C H 0.3085 -0.1030 0.7972 0.030 Uiso 1 1 calc R . .
H11D H 0.3679 -0.1058 0.7821 0.030 Uiso 1 1 calc R . .
C114 C 0.37150(16) -0.0151(2) 0.83350(12) 0.0326(8) Uani 1 1 d . . .
H11E H 0.3905 -0.0475 0.8650 0.039 Uiso 1 1 calc R . .
H11F H 0.4045 0.0135 0.8265 0.039 Uiso 1 1 calc R . .
C115 C 0.32787(17) 0.0450(2) 0.84203(12) 0.0345(8) Uani 1 1 d . . .
H11G H 0.3511 0.0824 0.8698 0.041 Uiso 1 1 calc R . .
H11H H 0.2980 0.0166 0.8532 0.041 Uiso 1 1 calc R . .
C116 C 0.29372(15) 0.09229(18) 0.79283(11) 0.0243(7) Uani 1 1 d . . .
H11I H 0.2648 0.1297 0.7993 0.029 Uiso 1 1 calc R . .
H11J H 0.3234 0.1241 0.7832 0.029 Uiso 1 1 calc R . .
C121 C 0.15964(13) 0.02072(17) 0.64504(11) 0.0186(6) Uani 1 1 d . . .
H121 H 0.1203 0.0511 0.6317 0.022 Uiso 1 1 calc R . .
C122 C 0.17476(13) -0.00064(19) 0.59818(11) 0.0227(7) Uani 1 1 d . . .
H12C H 0.2153 -0.0269 0.6097 0.027 Uiso 1 1 calc R . .
H12D H 0.1774 0.0490 0.5798 0.027 Uiso 1 1 calc R . .
C123 C 0.12741(14) -0.05595(19) 0.56110(12) 0.0265(7) Uani 1 1 d . . .
H12E H 0.0877 -0.0278 0.5464 0.032 Uiso 1 1 calc R . .
H12F H 0.1405 -0.0709 0.5325 0.032 Uiso 1 1 calc R . .
C124 C 0.11995(15) -0.13010(19) 0.58875(13) 0.0323(8) Uani 1 1 d . . .
H12G H 0.1591 -0.1596 0.6017 0.039 Uiso 1 1 calc R . .
H12H H 0.0888 -0.1652 0.5643 0.039 Uiso 1 1 calc R . .
C125 C 0.10064(15) -0.1099(2) 0.63340(14) 0.0319(8) Uani 1 1 d . . .
H12I H 0.0970 -0.1598 0.6511 0.038 Uiso 1 1 calc R . .
H12J H 0.0601 -0.0838 0.6202 0.038 Uiso 1 1 calc R . .
C126 C 0.14716(13) -0.05400(18) 0.67208(12) 0.0223(7) Uani 1 1 d . . .
H12K H 0.1859 -0.0832 0.6894 0.027 Uiso 1 1 calc R . .
H12L H 0.1312 -0.0373 0.6988 0.027 Uiso 1 1 calc R . .
B200 B 0.17868(14) 0.7150(2) 0.84481(12) 0.0148(7) Uani 1 1 d . . .
Cl1 Cl 0.06461(4) 1.00089(5) 0.79833(3) 0.03103(18) Uani 1 1 d . . .
Cl2 Cl -0.01345(3) 0.75148(5) 0.66999(3) 0.02788(18) Uani 1 1 d . . .
Cl3 Cl 0.28536(4) 0.77108(5) 0.70620(3) 0.02466(16) Uani 1 1 d . . .
Cl4 Cl 0.39774(3) 0.59380(6) 0.87489(3) 0.0332(2) Uani 1 1 d . . .
Cl5 Cl 0.14742(4) 0.39637(5) 0.81921(3) 0.03217(19) Uani 1 1 d . . .
Cl6 Cl 0.02155(3) 0.56672(5) 0.91053(3) 0.02573(17) Uani 1 1 d . . .
Cl7 Cl 0.25440(4) 0.70028(5) 1.05246(3) 0.03181(19) Uani 1 1 d . . .
Cl8 Cl 0.32023(4) 0.94539(5) 0.96020(3) 0.0350(2) Uani 1 1 d . . .
C201 C 0.15837(12) 0.55667(17) 0.83291(10) 0.0160(6) Uani 1 1 d . . .
H201 H 0.1874 0.5531 0.8167 0.019 Uiso 1 1 calc R . .
C202 C 0.14554(12) 0.63094(17) 0.84938(10) 0.0140(6) Uani 1 1 d . . .
C203 C 0.08750(12) 0.48904(18) 0.86389(10) 0.0176(6) Uani 1 1 d . . .
H203 H 0.0690 0.4414 0.8695 0.021 Uiso 1 1 calc R . .
C204 C 0.10088(12) 0.63230(18) 0.87199(10) 0.0171(6) Uani 1 1 d . . .
H204 H 0.0893 0.6817 0.8824 0.021 Uiso 1 1 calc R . .
C205 C 0.07396(11) 0.56253(18) 0.87917(10) 0.0165(6) Uani 1 1 d . . .
C206 C 0.12950(12) 0.48829(17) 0.83991(11) 0.0180(6) Uani 1 1 d . . .
C211 C 0.23407(12) 0.73565(16) 0.77658(10) 0.0154(6) Uani 1 1 d . . .
H211 H 0.1997 0.7650 0.7549 0.019 Uiso 1 1 calc R . .
C212 C 0.23302(12) 0.70172(17) 0.82196(10) 0.0145(6) Uani 1 1 d . . .
C213 C 0.33584(13) 0.68476(18) 0.79247(11) 0.0200(6) Uani 1 1 d . . .
H213 H 0.3706 0.6801 0.7830 0.024 Uiso 1 1 calc R . .
C214 C 0.28480(13) 0.72690(17) 0.76281(11) 0.0181(6) Uani 1 1 d . . .
C215 C 0.28469(12) 0.65724(18) 0.85155(11) 0.0177(6) Uani 1 1 d . . .
H215 H 0.2856 0.6321 0.8823 0.021 Uiso 1 1 calc R . .
C216 C 0.33397(12) 0.64965(18) 0.83660(11) 0.0198(6) Uani 1 1 d . . .
C221 C 0.21471(12) 0.75284(16) 0.90292(10) 0.0141(6) Uani 1 1 d . . .
C222 C 0.24841(12) 0.82351(17) 0.90817(10) 0.0176(6) Uani 1 1 d . . .
H222 H 0.2490 0.8497 0.8782 0.021 Uiso 1 1 calc R . .
C223 C 0.28289(12) 0.81977(18) 1.00093(11) 0.0199(6) Uani 1 1 d . . .
H223 H 0.3051 0.8426 1.0336 0.024 Uiso 1 1 calc R . .
C224 C 0.21800(12) 0.71595(17) 0.94875(10) 0.0161(6) Uani 1 1 d . . .
H224 H 0.1970 0.6671 0.9473 0.019 Uiso 1 1 calc R . .
C225 C 0.28065(12) 0.85574(18) 0.95572(11) 0.0197(6) Uani 1 1 d . . .
C226 C 0.25134(13) 0.74928(18) 0.99617(10) 0.0189(6) Uani 1 1 d . . .
C231 C 0.12518(12) 0.77428(17) 0.80734(10) 0.0151(6) Uani 1 1 d . . .
C232 C 0.11800(12) 0.85440(18) 0.81766(11) 0.0182(6) Uani 1 1 d . . .
H232 H 0.1451 0.8777 0.8486 0.022 Uiso 1 1 calc R . .
C233 C 0.08329(12) 0.74396(18) 0.76080(10) 0.0171(6) Uani 1 1 d . . .
H233 H 0.0860 0.6896 0.7521 0.021 Uiso 1 1 calc R . .
C234 C 0.07202(13) 0.90059(18) 0.78348(11) 0.0195(6) Uani 1 1 d . . .
C235 C 0.03121(13) 0.87067(19) 0.73783(11) 0.0210(7) Uani 1 1 d . . .
H235 H -0.0001 0.9030 0.7147 0.025 Uiso 1 1 calc R . .
C236 C 0.03803(12) 0.7920(2) 0.72737(10) 0.0201(7) Uani 1 1 d . . .
O300 O 0.5675(5) 0.1117(7) 0.4750(4) 0.0437(19) Uani 0.560(8) 1 d PU A 1
C301 C 0.5971(7) 0.1870(11) 0.4812(6) 0.0502(17) Uani 0.560(8) 1 d PU A 1
H30A H 0.5911 0.2111 0.4473 0.060 Uiso 0.560(8) 1 calc PR A 1
H30B H 0.6415 0.1814 0.5010 0.060 Uiso 0.560(8) 1 calc PR A 1
C302 C 0.5671(4) 0.2384(5) 0.5106(4) 0.0559(15) Uani 0.560(8) 1 d PU A 1
H30C H 0.5889 0.2326 0.5482 0.067 Uiso 0.560(8) 1 calc PR A 1
H30D H 0.5673 0.2954 0.5013 0.067 Uiso 0.560(8) 1 calc PR A 1
C303 C 0.5063(4) 0.2094(5) 0.4957(4) 0.0538(14) Uani 0.560(8) 1 d PU A 1
H30E H 0.4779 0.2429 0.4680 0.065 Uiso 0.560(8) 1 calc PR A 1
H30F H 0.4928 0.2091 0.5253 0.065 Uiso 0.560(8) 1 calc PR A 1
C304 C 0.5090(8) 0.1198(10) 0.4754(7) 0.0489(17) Uani 0.560(8) 1 d PU A 1
H30G H 0.5017 0.0801 0.4987 0.059 Uiso 0.560(8) 1 calc PR A 1
H30H H 0.4780 0.1124 0.4404 0.059 Uiso 0.560(8) 1 calc PR A 1
O310 O 0.5566(7) 0.1194(9) 0.4605(5) 0.045(2) Uani 0.440(8) 1 d PU A 2
C311 C 0.5976(10) 0.1828(15) 0.4907(7) 0.0513(19) Uani 0.440(8) 1 d PU A 2
H31A H 0.6314 0.1940 0.4786 0.062 Uiso 0.440(8) 1 calc PR A 2
H31B H 0.6143 0.1706 0.5280 0.062 Uiso 0.440(8) 1 calc PR A 2
C312 C 0.5516(5) 0.2490(6) 0.4779(5) 0.0561(15) Uani 0.440(8) 1 d PU A 2
H31C H 0.5619 0.2879 0.5065 0.067 Uiso 0.440(8) 1 calc PR A 2
H31D H 0.5501 0.2772 0.4463 0.067 Uiso 0.440(8) 1 calc PR A 2
C313 C 0.4926(5) 0.2096(7) 0.4699(5) 0.0546(16) Uani 0.440(8) 1 d PU A 2
H31E H 0.4782 0.2237 0.4980 0.066 Uiso 0.440(8) 1 calc PR A 2
H31F H 0.4612 0.2264 0.4367 0.066 Uiso 0.440(8) 1 calc PR A 2
C314 C 0.5030(11) 0.1305(14) 0.4698(9) 0.0510(18) Uani 0.440(8) 1 d PU A 2
H31G H 0.4684 0.1039 0.4427 0.061 Uiso 0.440(8) 1 calc PR A 2
H31H H 0.5072 0.1070 0.5035 0.061 Uiso 0.440(8) 1 calc PR A 2
C401 C 0.4984(4) 0.4760(6) 0.5454(3) 0.163(3) Uani 1 1 d DU . .
H40A H 0.4709 0.4721 0.5649 0.195 Uiso 1 1 calc R . .
H40B H 0.5360 0.4459 0.5650 0.195 Uiso 1 1 calc R . .
C402 C 0.4704(4) 0.4380(5) 0.4986(3) 0.159(2) Uani 1 1 d DU . .
H40C H 0.4266 0.4520 0.4872 0.191 Uiso 1 1 calc R . .
H40D H 0.4731 0.3801 0.5065 0.191 Uiso 1 1 calc R . .
C403 C 0.4861(4) 0.4463(6) 0.4554(3) 0.172(3) Uani 1 1 d DU . .
H40E H 0.5209 0.4112 0.4579 0.207 Uiso 1 1 calc R . .
H40F H 0.4510 0.4325 0.4237 0.207 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
P2 Pt1 P1 167.76(3) .
P2 Pt1 Ag1 94.588(19) .
P1 Pt1 Ag1 97.641(19) .
P3 Pt2 P4 164.63(3) .
P3 Pt2 Ag1 89.371(19) .
P4 Pt2 Ag1 104.028(19) .
Pt1 Ag1 Pt2 166.759(10) .
C31 P1 C11 104.85(13) .
C31 P1 C21 108.21(13) .
C11 P1 C21 106.17(12) .
C31 P1 Pt1 105.56(9) .
C11 P1 Pt1 120.21(9) .
C21 P1 Pt1 111.20(9) .
C41 P2 C61 106.95(12) .
C41 P2 C51 104.28(12) .
C61 P2 C51 106.30(12) .
C41 P2 Pt1 120.21(9) .
C61 P2 Pt1 114.96(9) .
C51 P2 Pt1 102.65(9) .
C91 P3 C71 103.26(12) .
C91 P3 C81 102.60(12) .
C71 P3 C81 110.49(13) .
C91 P3 Pt2 122.63(9) .
C71 P3 Pt2 114.60(9) .
C81 P3 Pt2 102.42(9) .
C111 P4 C101 105.85(12) .
C111 P4 C121 106.52(13) .
C101 P4 C121 103.49(13) .
C111 P4 Pt2 106.46(9) .
C101 P4 Pt2 123.06(9) .
C121 P4 Pt2 110.40(9) .
C12 C11 C16 109.1(2) .
C12 C11 P1 111.82(19) .
C16 C11 P1 117.7(2) .
C12 C11 H11 105.8 .
C16 C11 H11 105.8 .
P1 C11 H11 105.8 .
C13 C12 C11 111.2(2) .
C13 C12 H12A 109.4 .
C11 C12 H12A 109.4 .
C13 C12 H12B 109.4 .
C11 C12 H12B 109.4 .
H12A C12 H12B 108.0 .
C14 C13 C12 111.9(3) .
C14 C13 H13A 109.2 .
C12 C13 H13A 109.2 .
C14 C13 H13B 109.2 .
C12 C13 H13B 109.2 .
H13A C13 H13B 107.9 .
C15 C14 C13 111.5(3) .
C15 C14 H14A 109.3 .
C13 C14 H14A 109.3 .
C15 C14 H14B 109.3 .
C13 C14 H14B 109.3 .
H14A C14 H14B 108.0 .
C14 C15 C16 112.0(3) .
C14 C15 H15A 109.2 .
C16 C15 H15A 109.2 .
C14 C15 H15B 109.2 .
C16 C15 H15B 109.2 .
H15A C15 H15B 107.9 .
C15 C16 C11 110.3(3) .
C15 C16 H16A 109.6 .
C11 C16 H16A 109.6 .
C15 C16 H16B 109.6 .
C11 C16 H16B 109.6 .
H16A C16 H16B 108.1 .
C22 C21 C26 111.2(2) .
C22 C21 P1 114.79(19) .
C26 C21 P1 111.38(18) .
C22 C21 H21 106.3 .
C26 C21 H21 106.3 .
P1 C21 H21 106.3 .
C23 C22 C21 112.7(2) .
C23 C22 H22A 109.1 .
C21 C22 H22A 109.1 .
C23 C22 H22B 109.1 .
C21 C22 H22B 109.1 .
H22A C22 H22B 107.8 .
C24 C23 C22 111.8(2) .
C24 C23 H23A 109.2 .
C22 C23 H23A 109.2 .
C24 C23 H23B 109.2 .
C22 C23 H23B 109.2 .
H23A C23 H23B 107.9 .
C23 C24 C25 110.3(3) .
C23 C24 H24A 109.6 .
C25 C24 H24A 109.6 .
C23 C24 H24B 109.6 .
C25 C24 H24B 109.6 .
H24A C24 H24B 108.1 .
C24 C25 C26 111.5(3) .
C24 C25 H25A 109.3 .
C26 C25 H25A 109.3 .
C24 C25 H25B 109.3 .
C26 C25 H25B 109.3 .
H25A C25 H25B 108.0 .
C25 C26 C21 111.8(2) .
C25 C26 H26A 109.2 .
C21 C26 H26A 109.2 .
C25 C26 H26B 109.2 .
C21 C26 H26B 109.2 .
H26A C26 H26B 107.9 .
C32 C31 C36 110.0(2) .
C32 C31 P1 110.5(2) .
C36 C31 P1 109.30(19) .
C32 C31 H31 109.0 .
C36 C31 H31 109.0 .
P1 C31 H31 109.0 .
C31 C32 C33 112.5(3) .
C31 C32 H32A 109.1 .
C33 C32 H32A 109.1 .
C31 C32 H32B 109.1 .
C33 C32 H32B 109.1 .
H32A C32 H32B 107.8 .
C34 C33 C32 111.2(3) .
C34 C33 H33A 109.4 .
C32 C33 H33A 109.4 .
C34 C33 H33B 109.4 .
C32 C33 H33B 109.4 .
H33A C33 H33B 108.0 .
C33 C34 C35 111.0(3) .
C33 C34 H34A 109.4 .
C35 C34 H34A 109.4 .
C33 C34 H34B 109.4 .
C35 C34 H34B 109.4 .
H34A C34 H34B 108.0 .
C34 C35 C36 110.6(3) .
C34 C35 H35A 109.5 .
C36 C35 H35A 109.5 .
C34 C35 H35B 109.5 .
C36 C35 H35B 109.5 .
H35A C35 H35B 108.1 .
C35 C36 C31 111.6(3) .
C35 C36 H36A 109.3 .
C31 C36 H36A 109.3 .
C35 C36 H36B 109.3 .
C31 C36 H36B 109.3 .
H36A C36 H36B 108.0 .
C46 C41 C42 109.2(2) .
C46 C41 P2 114.39(18) .
C42 C41 P2 110.29(18) .
C46 C41 H41 107.6 .
C42 C41 H41 107.6 .
P2 C41 H41 107.6 .
C43 C42 C41 110.8(2) .
C43 C42 H42A 109.5 .
C41 C42 H42A 109.5 .
C43 C42 H42B 109.5 .
C41 C42 H42B 109.5 .
H42A C42 H42B 108.1 .
C44 C43 C42 112.3(2) .
C44 C43 H43A 109.2 .
C42 C43 H43A 109.2 .
C44 C43 H43B 109.2 .
C42 C43 H43B 109.2 .
H43A C43 H43B 107.9 .
C43 C44 C45 110.9(2) .
C43 C44 H44A 109.5 .
C45 C44 H44A 109.5 .
C43 C44 H44B 109.5 .
C45 C44 H44B 109.5 .
H44A C44 H44B 108.1 .
C44 C45 C46 111.0(2) .
C44 C45 H45A 109.4 .
C46 C45 H45A 109.4 .
C44 C45 H45B 109.4 .
C46 C45 H45B 109.4 .
H45A C45 H45B 108.0 .
C45 C46 C41 111.1(2) .
C45 C46 H46A 109.4 .
C41 C46 H46A 109.4 .
C45 C46 H46B 109.4 .
C41 C46 H46B 109.4 .
H46A C46 H46B 108.0 .
C56 C51 C52 109.4(2) .
C56 C51 P2 119.0(2) .
C52 C51 P2 111.47(18) .
C56 C51 H51 105.3 .
C52 C51 H51 105.3 .
P2 C51 H51 105.3 .
C53 C52 C51 110.5(2) .
C53 C52 H52A 109.6 .
C51 C52 H52A 109.6 .
C53 C52 H52B 109.6 .
C51 C52 H52B 109.5 .
H52A C52 H52B 108.1 .
C54 C53 C52 111.1(3) .
C54 C53 H53A 109.4 .
C52 C53 H53A 109.4 .
C54 C53 H53B 109.4 .
C52 C53 H53B 109.4 .
H53A C53 H53B 108.0 .
C53 C54 C55 111.0(2) .
C53 C54 H54A 109.4 .
C55 C54 H54A 109.4 .
C53 C54 H54B 109.4 .
C55 C54 H54B 109.4 .
H54A C54 H54B 108.0 .
C54 C55 C56 111.6(3) .
C54 C55 H55A 109.3 .
C56 C55 H55A 109.3 .
C54 C55 H55B 109.3 .
C56 C55 H55B 109.3 .
H55A C55 H55B 108.0 .
C51 C56 C55 110.3(2) .
C51 C56 H56A 109.6 .
C55 C56 H56A 109.6 .
C51 C56 H56B 109.6 .
C55 C56 H56B 109.6 .
H56A C56 H56B 108.1 .
C62 C61 C66 111.8(2) .
C62 C61 P2 115.86(18) .
C66 C61 P2 111.05(18) .
C62 C61 H61 105.8 .
C66 C61 H61 105.8 .
P2 C61 H61 105.8 .
C63 C62 C61 110.6(2) .
C63 C62 H62A 109.5 .
C61 C62 H62A 109.5 .
C63 C62 H62B 109.5 .
C61 C62 H62B 109.5 .
H62A C62 H62B 108.1 .
C64 C63 C62 111.7(2) .
C64 C63 H63A 109.3 .
C62 C63 H63A 109.3 .
C64 C63 H63B 109.3 .
C62 C63 H63B 109.3 .
H63A C63 H63B 107.9 .
C63 C64 C65 111.0(2) .
C63 C64 H64A 109.4 .
C65 C64 H64A 109.4 .
C63 C64 H64B 109.4 .
C65 C64 H64B 109.4 .
H64A C64 H64B 108.0 .
C66 C65 C64 111.1(2) .
C66 C65 H65A 109.4 .
C64 C65 H65A 109.4 .
C66 C65 H65B 109.4 .
C64 C65 H65B 109.4 .
H65A C65 H65B 108.0 .
C65 C66 C61 111.7(2) .
C65 C66 H66A 109.3 .
C61 C66 H66A 109.3 .
C65 C66 H66B 109.3 .
C61 C66 H66B 109.3 .
H66A C66 H66B 107.9 .
C76 C71 C72 110.9(2) .
C76 C71 P3 115.74(18) .
C72 C71 P3 113.20(18) .
C76 C71 H71 105.3 .
C72 C71 H71 105.3 .
P3 C71 H71 105.3 .
C73 C72 C71 111.6(2) .
C73 C72 H72A 109.3 .
C71 C72 H72A 109.3 .
C73 C72 H72B 109.3 .
C71 C72 H72B 109.3 .
H72A C72 H72B 108.0 .
C74 C73 C72 111.1(2) .
C74 C73 H73A 109.4 .
C72 C73 H73A 109.4 .
C74 C73 H73B 109.4 .
C72 C73 H73B 109.4 .
H73A C73 H73B 108.0 .
C73 C74 C75 111.0(2) .
C73 C74 H74A 109.4 .
C75 C74 H74A 109.4 .
C73 C74 H74B 109.4 .
C75 C74 H74B 109.4 .
H74A C74 H74B 108.0 .
C74 C75 C76 111.2(2) .
C74 C75 H75A 109.4 .
C76 C75 H75A 109.4 .
C74 C75 H75B 109.4 .
C76 C75 H75B 109.4 .
H75A C75 H75B 108.0 .
C75 C76 C71 111.5(2) .
C75 C76 H76A 109.3 .
C71 C76 H76A 109.3 .
C75 C76 H76B 109.3 .
C71 C76 H76B 109.3 .
H76A C76 H76B 108.0 .
C82 C81 C86 109.8(2) .
C82 C81 P3 112.62(18) .
C86 C81 P3 118.30(19) .
C82 C81 H81 104.9 .
C86 C81 H81 104.9 .
P3 C81 H81 104.9 .
C83 C82 C81 111.3(2) .
C83 C82 H82A 109.4 .
C81 C82 H82A 109.4 .
C83 C82 H82B 109.4 .
C81 C82 H82B 109.4 .
H82A C82 H82B 108.0 .
C84 C83 C82 111.1(2) .
C84 C83 H83A 109.4 .
C82 C83 H83A 109.4 .
C84 C83 H83B 109.4 .
C82 C83 H83B 109.4 .
H83A C83 H83B 108.0 .
C85 C84 C83 110.2(2) .
C85 C84 H84A 109.6 .
C83 C84 H84A 109.6 .
C85 C84 H84B 109.6 .
C83 C84 H84B 109.6 .
H84A C84 H84B 108.1 .
C84 C85 C86 111.6(2) .
C84 C85 H85A 109.3 .
C86 C85 H85A 109.3 .
C84 C85 H85B 109.3 .
C86 C85 H85B 109.3 .
H85A C85 H85B 108.0 .
C85 C86 C81 109.8(2) .
C85 C86 H86A 109.7 .
C81 C86 H86A 109.7 .
C85 C86 H86B 109.7 .
C81 C86 H86B 109.7 .
H86A C86 H86B 108.2 .
C92 C91 C96 109.9(2) .
C92 C91 P3 114.00(18) .
C96 C91 P3 111.11(18) .
C92 C91 H91 107.2 .
C96 C91 H91 107.2 .
P3 C91 H91 107.2 .
C93 C92 C91 111.6(2) .
C93 C92 H92A 109.3 .
C91 C92 H92A 109.3 .
C93 C92 H92B 109.3 .
C91 C92 H92B 109.3 .
H92A C92 H92B 108.0 .
C94 C93 C92 111.9(2) .
C94 C93 H93A 109.2 .
C92 C93 H93A 109.2 .
C94 C93 H93B 109.2 .
C92 C93 H93B 109.2 .
H93A C93 H93B 107.9 .
C93 C94 C95 110.8(3) .
C93 C94 H94A 109.5 .
C95 C94 H94A 109.5 .
C93 C94 H94B 109.5 .
C95 C94 H94B 109.5 .
H94A C94 H94B 108.1 .
C96 C95 C94 111.2(2) .
C96 C95 H95A 109.4 .
C94 C95 H95A 109.4 .
C96 C95 H95B 109.4 .
C94 C95 H95B 109.4 .
H95A C95 H95B 108.0 .
C95 C96 C91 110.6(2) .
C95 C96 H96A 109.5 .
C91 C96 H96A 109.5 .
C95 C96 H96B 109.5 .
C91 C96 H96B 109.5 .
H96A C96 H96B 108.1 .
C106 C101 C102 110.5(2) .
C106 C101 P4 111.21(18) .
C102 C101 P4 114.0(2) .
C106 C101 H101 106.9 .
C102 C101 H101 106.9 .
P4 C101 H101 106.9 .
C103 C102 C101 112.5(2) .
C103 C102 H10A 109.1 .
C101 C102 H10A 109.1 .
C103 C102 H10B 109.1 .
C101 C102 H10B 109.1 .
H10A C102 H10B 107.8 .
C104 C103 C102 111.4(2) .
C104 C103 H10C 109.3 .
C102 C103 H10C 109.3 .
C104 C103 H10D 109.3 .
C102 C103 H10D 109.3 .
H10C C103 H10D 108.0 .
C103 C104 C105 110.5(2) .
C103 C104 H10E 109.6 .
C105 C104 H10E 109.6 .
C103 C104 H10F 109.6 .
C105 C104 H10F 109.6 .
H10E C104 H10F 108.1 .
C106 C105 C104 111.0(2) .
C106 C105 H10G 109.4 .
C104 C105 H10G 109.4 .
C106 C105 H10H 109.4 .
C104 C105 H10H 109.4 .
H10G C105 H10H 108.0 .
C105 C106 C101 112.3(2) .
C105 C106 H10I 109.1 .
C101 C106 H10I 109.1 .
C105 C106 H10J 109.1 .
C101 C106 H10J 109.1 .
H10I C106 H10J 107.9 .
C116 C111 C112 108.5(2) .
C116 C111 P4 112.7(2) .
C112 C111 P4 109.14(18) .
C116 C111 H111 108.8 .
C112 C111 H111 108.8 .
P4 C111 H111 108.8 .
C113 C112 C111 111.1(2) .
C113 C112 H11A 109.4 .
C111 C112 H11A 109.4 .
C113 C112 H11B 109.4 .
C111 C112 H11B 109.4 .
H11A C112 H11B 108.0 .
C114 C113 C112 111.2(3) .
C114 C113 H11C 109.4 .
C112 C113 H11C 109.4 .
C114 C113 H11D 109.4 .
C112 C113 H11D 109.4 .
H11C C113 H11D 108.0 .
C115 C114 C113 110.8(3) .
C115 C114 H11E 109.5 .
C113 C114 H11E 109.5 .
C115 C114 H11F 109.5 .
C113 C114 H11F 109.5 .
H11E C114 H11F 108.1 .
C114 C115 C116 111.3(3) .
C114 C115 H11G 109.4 .
C116 C115 H11G 109.4 .
C114 C115 H11H 109.4 .
C116 C115 H11H 109.4 .
H11G C115 H11H 108.0 .
C111 C116 C115 111.2(3) .
C111 C116 H11I 109.4 .
C115 C116 H11I 109.4 .
C111 C116 H11J 109.4 .
C115 C116 H11J 109.4 .
H11I C116 H11J 108.0 .
C122 C121 C126 112.2(2) .
C122 C121 P4 110.54(19) .
C126 C121 P4 115.2(2) .
C122 C121 H121 106.1 .
C126 C121 H121 106.1 .
P4 C121 H121 106.1 .
C121 C122 C123 112.6(2) .
C121 C122 H12C 109.1 .
C123 C122 H12C 109.1 .
C121 C122 H12D 109.1 .
C123 C122 H12D 109.1 .
H12C C122 H12D 107.8 .
C124 C123 C122 110.3(3) .
C124 C123 H12E 109.6 .
C122 C123 H12E 109.6 .
C124 C123 H12F 109.6 .
C122 C123 H12F 109.6 .
H12E C123 H12F 108.1 .
C123 C124 C125 111.4(3) .
C123 C124 H12G 109.3 .
C125 C124 H12G 109.3 .
C123 C124 H12H 109.3 .
C125 C124 H12H 109.3 .
H12G C124 H12H 108.0 .
C124 C125 C126 111.3(3) .
C124 C125 H12I 109.4 .
C126 C125 H12I 109.4 .
C124 C125 H12J 109.4 .
C126 C125 H12J 109.4 .
H12I C125 H12J 108.0 .
C125 C126 C121 111.3(3) .
C125 C126 H12K 109.4 .
C121 C126 H12K 109.4 .
C125 C126 H12L 109.4 .
C121 C126 H12L 109.4 .
H12K C126 H12L 108.0 .
C202 B200 C212 112.0(2) .
C202 B200 C231 107.1(2) .
C212 B200 C231 111.0(2) .
C202 B200 C221 109.8(2) .
C212 B200 C221 104.0(2) .
C231 B200 C221 112.9(2) .
C206 C201 C202 121.0(3) .
C206 C201 H201 119.5 .
C202 C201 H201 119.5 .
C201 C202 C204 116.6(3) .
C201 C202 B200 125.0(2) .
C204 C202 B200 118.4(2) .
C205 C203 C206 116.5(3) .
C205 C203 H203 121.8 .
C206 C203 H203 121.8 .
C205 C204 C202 120.6(3) .
C205 C204 H204 119.7 .
C202 C204 H204 119.7 .
C203 C205 C204 122.8(3) .
C203 C205 Cl6 118.3(2) .
C204 C205 Cl6 118.9(2) .
C201 C206 C203 122.5(3) .
C201 C206 Cl5 119.5(2) .
C203 C206 Cl5 118.0(2) .
C214 C211 C212 120.8(3) .
C214 C211 H211 119.6 .
C212 C211 H211 119.6 .
C211 C212 C215 116.7(2) .
C211 C212 B200 125.0(2) .
C215 C212 B200 118.2(2) .
C214 C213 C216 116.7(3) .
C214 C213 H213 121.7 .
C216 C213 H213 121.7 .
C213 C214 C211 122.4(3) .
C213 C214 Cl3 117.8(2) .
C211 C214 Cl3 119.8(2) .
C216 C215 C212 120.9(3) .
C216 C215 H215 119.5 .
C212 C215 H215 119.5 .
C215 C216 C213 122.6(3) .
C215 C216 Cl4 119.4(2) .
C213 C216 Cl4 118.0(2) .
C224 C221 C222 116.0(2) .
C224 C221 B200 124.4(2) .
C222 C221 B200 119.4(2) .
C225 C222 C221 121.5(3) .
C225 C222 H222 119.2 .
C221 C222 H222 119.2 .
C226 C223 C225 116.6(3) .
C226 C223 H223 121.7 .
C225 C223 H223 121.7 .
C226 C224 C221 121.3(3) .
C226 C224 H224 119.4 .
C221 C224 H224 119.4 .
C222 C225 C223 122.3(3) .
C222 C225 Cl8 119.8(2) .
C223 C225 Cl8 117.9(2) .
C223 C226 C224 122.3(3) .
C223 C226 Cl7 118.2(2) .
C224 C226 Cl7 119.5(2) .
C232 C231 C233 116.2(3) .
C232 C231 B200 124.9(2) .
C233 C231 B200 118.9(3) .
C234 C232 C231 121.1(3) .
C234 C232 H232 119.4 .
C231 C232 H232 119.4 .
C236 C233 C231 121.1(3) .
C236 C233 H233 119.4 .
C231 C233 H233 119.4 .
C235 C234 C232 122.5(3) .
C235 C234 Cl1 118.1(2) .
C232 C234 Cl1 119.4(2) .
C236 C235 C234 116.7(3) .
C236 C235 H235 121.6 .
C234 C235 H235 121.6 .
C235 C236 C233 122.3(3) .
C235 C236 Cl2 118.1(2) .
C233 C236 Cl2 119.5(2) .
C304 O300 C301 110.9(13) .
O300 C301 C302 105.2(11) .
O300 C301 H30A 110.7 .
C302 C301 H30A 110.7 .
O300 C301 H30B 110.7 .
C302 C301 H30B 110.7 .
H30A C301 H30B 108.8 .
C303 C302 C301 105.3(9) .
C303 C302 H30C 110.7 .
C301 C302 H30C 110.7 .
C303 C302 H30D 110.7 .
C301 C302 H30D 110.7 .
H30C C302 H30D 108.8 .
C302 C303 C304 104.8(9) .
C302 C303 H30E 110.8 .
C304 C303 H30E 110.8 .
C302 C303 H30F 110.8 .
C304 C303 H30F 110.8 .
H30E C303 H30F 108.9 .
O300 C304 C303 105.1(13) .
O300 C304 H30G 110.7 .
C303 C304 H30G 110.7 .
O300 C304 H30H 110.7 .
C303 C304 H30H 110.7 .
H30G C304 H30H 108.8 .
C314 O310 C311 104.1(16) .
O310 C311 C312 97.7(14) .
O310 C311 H31A 112.2 .
C312 C311 H31A 112.2 .
O310 C311 H31B 112.2 .
C312 C311 H31B 112.2 .
H31A C311 H31B 109.8 .
C313 C312 C311 105.2(12) .
C313 C312 H31C 110.7 .
C311 C312 H31C 110.7 .
C313 C312 H31D 110.7 .
C311 C312 H31D 110.7 .
H31C C312 H31D 108.8 .
C314 C313 C312 106.1(13) .
C314 C313 H31E 110.5 .
C312 C313 H31E 110.5 .
C314 C313 H31F 110.5 .
C312 C313 H31F 110.5 .
H31E C313 H31F 108.7 .
C313 C314 O310 108(2) .
C313 C314 H31G 110.1 .
O310 C314 H31G 110.1 .
C313 C314 H31H 110.1 .
O310 C314 H31H 110.1 .
H31G C314 H31H 108.4 .
C403 C401 C402 117.8(8) 3_666
C403 C401 H40A 107.9 3_666
C402 C401 H40A 107.9 .
C403 C401 H40B 107.9 3_666
C402 C401 H40B 107.9 .
H40A C401 H40B 107.2 .
C401 C402 C403 125.9(6) .
C401 C402 H40C 105.8 .
C403 C402 H40C 105.8 .
C401 C402 H40D 105.8 .
C403 C402 H40D 105.8 .
H40C C402 H40D 106.2 .
C401 C403 C402 105.6(8) 3_666
C401 C403 H40E 110.6 3_666
C402 C403 H40E 110.6 .
C401 C403 H40F 110.6 3_666
C402 C403 H40F 110.6 .
H40E C403 H40F 108.8 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P2 2.2592(7) .
Pt1 P1 2.2785(7) .
Pt1 Ag1 2.5955(3) .
Pt2 P3 2.2530(7) .
Pt2 P4 2.2961(7) .
Pt2 Ag1 2.5957(2) .
P1 C31 1.847(3) .
P1 C11 1.854(3) .
P1 C21 1.862(3) .
P2 C41 1.841(3) .
P2 C61 1.845(3) .
P2 C51 1.862(3) .
P3 C91 1.850(3) .
P3 C71 1.853(3) .
P3 C81 1.863(3) .
P4 C111 1.852(3) .
P4 C101 1.853(3) .
P4 C121 1.877(3) .
C11 C12 1.526(4) .
C11 C16 1.539(4) .
C11 H11 1.0000 .
C12 C13 1.521(4) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.520(5) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.519(5) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C16 1.532(4) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C21 C22 1.527(4) .
C21 C26 1.536(4) .
C21 H21 1.0000 .
C22 C23 1.525(4) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.519(4) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.524(4) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.525(4) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C31 C32 1.529(4) .
C31 C36 1.543(4) .
C31 H31 1.0000 .
C32 C33 1.533(4) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 C34 1.511(5) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C34 C35 1.525(5) .
C34 H34A 0.9900 .
C34 H34B 0.9900 .
C35 C36 1.526(4) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C41 C46 1.528(4) .
C41 C42 1.530(4) .
C41 H41 1.0000 .
C42 C43 1.523(4) .
C42 H42A 0.9900 .
C42 H42B 0.9900 .
C43 C44 1.522(4) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44 C45 1.522(4) .
C44 H44A 0.9900 .
C44 H44B 0.9900 .
C45 C46 1.528(4) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 H46A 0.9900 .
C46 H46B 0.9900 .
C51 C56 1.526(4) .
C51 C52 1.533(4) .
C51 H51 1.0000 .
C52 C53 1.533(4) .
C52 H52A 0.9900 .
C52 H52B 0.9900 .
C53 C54 1.518(4) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 C55 1.525(4) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 C56 1.529(4) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C56 H56A 0.9900 .
C56 H56B 0.9900 .
C61 C62 1.536(4) .
C61 C66 1.540(4) .
C61 H61 1.0000 .
C62 C63 1.527(4) .
C62 H62A 0.9900 .
C62 H62B 0.9900 .
C63 C64 1.515(4) .
C63 H63A 0.9900 .
C63 H63B 0.9900 .
C64 C65 1.530(4) .
C64 H64A 0.9900 .
C64 H64B 0.9900 .
C65 C66 1.529(4) .
C65 H65A 0.9900 .
C65 H65B 0.9900 .
C66 H66A 0.9900 .
C66 H66B 0.9900 .
C71 C76 1.532(4) .
C71 C72 1.536(4) .
C71 H71 1.0000 .
C72 C73 1.529(4) .
C72 H72A 0.9900 .
C72 H72B 0.9900 .
C73 C74 1.521(4) .
C73 H73A 0.9900 .
C73 H73B 0.9900 .
C74 C75 1.523(4) .
C74 H74A 0.9900 .
C74 H74B 0.9900 .
C75 C76 1.531(4) .
C75 H75A 0.9900 .
C75 H75B 0.9900 .
C76 H76A 0.9900 .
C76 H76B 0.9900 .
C81 C82 1.535(4) .
C81 C86 1.538(4) .
C81 H81 1.0000 .
C82 C83 1.532(4) .
C82 H82A 0.9900 .
C82 H82B 0.9900 .
C83 C84 1.523(4) .
C83 H83A 0.9900 .
C83 H83B 0.9900 .
C84 C85 1.523(4) .
C84 H84A 0.9900 .
C84 H84B 0.9900 .
C85 C86 1.525(4) .
C85 H85A 0.9900 .
C85 H85B 0.9900 .
C86 H86A 0.9900 .
C86 H86B 0.9900 .
C91 C92 1.529(4) .
C91 C96 1.535(4) .
C91 H91 1.0000 .
C92 C93 1.528(4) .
C92 H92A 0.9900 .
C92 H92B 0.9900 .
C93 C94 1.518(4) .
C93 H93A 0.9900 .
C93 H93B 0.9900 .
C94 C95 1.525(4) .
C94 H94A 0.9900 .
C94 H94B 0.9900 .
C95 C96 1.524(4) .
C95 H95A 0.9900 .
C95 H95B 0.9900 .
C96 H96A 0.9900 .
C96 H96B 0.9900 .
C101 C106 1.529(4) .
C101 C102 1.536(4) .
C101 H101 1.0000 .
C102 C103 1.535(4) .
C102 H10A 0.9900 .
C102 H10B 0.9900 .
C103 C104 1.520(4) .
C103 H10C 0.9900 .
C103 H10D 0.9900 .
C104 C105 1.524(4) .
C104 H10E 0.9900 .
C104 H10F 0.9900 .
C105 C106 1.523(4) .
C105 H10G 0.9900 .
C105 H10H 0.9900 .
C106 H10I 0.9900 .
C106 H10J 0.9900 .
C111 C116 1.521(4) .
C111 C112 1.539(4) .
C111 H111 1.0000 .
C112 C113 1.525(4) .
C112 H11A 0.9900 .
C112 H11B 0.9900 .
C113 C114 1.519(4) .
C113 H11C 0.9900 .
C113 H11D 0.9900 .
C114 C115 1.517(5) .
C114 H11E 0.9900 .
C114 H11F 0.9900 .
C115 C116 1.533(4) .
C115 H11G 0.9900 .
C115 H11H 0.9900 .
C116 H11I 0.9900 .
C116 H11J 0.9900 .
C121 C122 1.520(4) .
C121 C126 1.545(4) .
C121 H121 1.0000 .
C122 C123 1.524(4) .
C122 H12C 0.9900 .
C122 H12D 0.9900 .
C123 C124 1.506(5) .
C123 H12E 0.9900 .
C123 H12F 0.9900 .
C124 C125 1.514(5) .
C124 H12G 0.9900 .
C124 H12H 0.9900 .
C125 C126 1.541(4) .
C125 H12I 0.9900 .
C125 H12J 0.9900 .
C126 H12K 0.9900 .
C126 H12L 0.9900 .
B200 C202 1.637(4) .
B200 C212 1.640(4) .
B200 C231 1.642(4) .
B200 C221 1.657(4) .
Cl1 C234 1.754(3) .
Cl2 C236 1.753(3) .
Cl3 C214 1.750(3) .
Cl4 C216 1.758(3) .
Cl5 C206 1.750(3) .
Cl6 C205 1.757(3) .
Cl7 C226 1.752(3) .
Cl8 C225 1.747(3) .
C201 C206 1.382(4) .
C201 C202 1.397(4) .
C201 H201 0.9500 .
C202 C204 1.411(4) .
C203 C205 1.378(4) .
C203 C206 1.383(4) .
C203 H203 0.9500 .
C204 C205 1.378(4) .
C204 H204 0.9500 .
C211 C214 1.390(4) .
C211 C212 1.398(4) .
C211 H211 0.9500 .
C212 C215 1.406(4) .
C213 C214 1.377(4) .
C213 C216 1.381(4) .
C213 H213 0.9500 .
C215 C216 1.375(4) .
C215 H215 0.9500 .
C221 C224 1.398(4) .
C221 C222 1.402(4) .
C222 C225 1.375(4) .
C222 H222 0.9500 .
C223 C226 1.375(4) .
C223 C225 1.382(4) .
C223 H223 0.9500 .
C224 C226 1.385(4) .
C224 H224 0.9500 .
C231 C232 1.396(4) .
C231 C233 1.406(4) .
C232 C234 1.386(4) .
C232 H232 0.9500 .
C233 C236 1.387(4) .
C233 H233 0.9500 .
C234 C235 1.378(4) .
C235 C236 1.371(4) .
C235 H235 0.9500 .
O300 C304 1.39(2) .
O300 C301 1.42(2) .
C301 C302 1.530(19) .
C301 H30A 0.9900 .
C301 H30B 0.9900 .
C302 C303 1.420(11) .
C302 H30C 0.9900 .
C302 H30D 0.9900 .
C303 C304 1.61(2) .
C303 H30E 0.9900 .
C303 H30F 0.9900 .
C304 H30G 0.9900 .
C304 H30H 0.9900 .
O310 C314 1.39(3) .
O310 C311 1.47(3) .
C311 C312 1.50(3) .
C311 H31A 0.9900 .
C311 H31B 0.9900 .
C312 C313 1.479(14) .
C312 H31C 0.9900 .
C312 H31D 0.9900 .
C313 C314 1.35(2) .
C313 H31E 0.9900 .
C313 H31F 0.9900 .
C314 H31G 0.9900 .
C314 H31H 0.9900 .
C401 C403 1.353(10) 3_666
C401 C402 1.383(5) .
C401 H40A 0.9900 .
C401 H40B 0.9900 .
C402 C403 1.394(4) .
C402 H40C 0.9900 .
C402 H40D 0.9900 .
C403 C401 1.353(10) 3_666
C403 H40E 0.9900 .
C403 H40F 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
P2 Pt1 Ag1 Pt2 -149.63(4) . .
P1 Pt1 Ag1 Pt2 30.92(5) . .
P3 Pt2 Ag1 Pt1 -133.13(4) . .
P4 Pt2 Ag1 Pt1 54.48(5) . .
P2 Pt1 P1 C31 37.48(16) . .
Ag1 Pt1 P1 C31 -145.08(10) . .
P2 Pt1 P1 C11 155.51(14) . .
Ag1 Pt1 P1 C11 -27.05(10) . .
P2 Pt1 P1 C21 -79.64(15) . .
Ag1 Pt1 P1 C21 97.79(10) . .
P1 Pt1 P2 C41 -133.89(14) . .
Ag1 Pt1 P2 C41 48.66(10) . .
P1 Pt1 P2 C61 96.08(15) . .
Ag1 Pt1 P2 C61 -81.37(10) . .
P1 Pt1 P2 C51 -18.85(16) . .
Ag1 Pt1 P2 C51 163.69(9) . .
P4 Pt2 P3 C91 -151.44(12) . .
Ag1 Pt2 P3 C91 57.55(10) . .
P4 Pt2 P3 C71 82.20(14) . .
Ag1 Pt2 P3 C71 -68.80(10) . .
P4 Pt2 P3 C81 -37.47(14) . .
Ag1 Pt2 P3 C81 171.52(9) . .
P3 Pt2 P4 C111 63.42(14) . .
Ag1 Pt2 P4 C111 -146.55(10) . .
P3 Pt2 P4 C101 -174.42(12) . .
Ag1 Pt2 P4 C101 -24.39(11) . .
P3 Pt2 P4 C121 -51.80(14) . .
Ag1 Pt2 P4 C121 98.22(10) . .
C31 P1 C11 C12 -167.0(2) . .
C21 P1 C11 C12 -52.6(2) . .
Pt1 P1 C11 C12 74.6(2) . .
C31 P1 C11 C16 -39.6(2) . .
C21 P1 C11 C16 74.8(2) . .
Pt1 P1 C11 C16 -158.00(17) . .
C16 C11 C12 C13 58.7(3) . .
P1 C11 C12 C13 -169.3(2) . .
C11 C12 C13 C14 -56.4(3) . .
C12 C13 C14 C15 52.9(4) . .
C13 C14 C15 C16 -53.1(4) . .
C14 C15 C16 C11 56.4(4) . .
C12 C11 C16 C15 -58.4(3) . .
P1 C11 C16 C15 172.8(2) . .
C31 P1 C21 C22 33.9(2) . .
C11 P1 C21 C22 -78.2(2) . .
Pt1 P1 C21 C22 149.38(18) . .
C31 P1 C21 C26 -93.6(2) . .
C11 P1 C21 C26 154.3(2) . .
Pt1 P1 C21 C26 21.9(2) . .
C26 C21 C22 C23 -51.5(3) . .
P1 C21 C22 C23 -179.1(2) . .
C21 C22 C23 C24 54.0(4) . .
C22 C23 C24 C25 -55.9(3) . .
C23 C24 C25 C26 57.0(3) . .
C24 C25 C26 C21 -55.7(3) . .
C22 C21 C26 C25 52.2(3) . .
P1 C21 C26 C25 -178.3(2) . .
C11 P1 C31 C32 -179.85(19) . .
C21 P1 C31 C32 67.2(2) . .
Pt1 P1 C31 C32 -52.0(2) . .
C11 P1 C31 C36 -58.6(2) . .
C21 P1 C31 C36 -171.60(18) . .
Pt1 P1 C31 C36 69.27(19) . .
C36 C31 C32 C33 53.3(3) . .
P1 C31 C32 C33 174.1(2) . .
C31 C32 C33 C34 -54.8(4) . .
C32 C33 C34 C35 56.2(4) . .
C33 C34 C35 C36 -57.6(4) . .
C34 C35 C36 C31 57.1(3) . .
C32 C31 C36 C35 -54.6(3) . .
P1 C31 C36 C35 -176.1(2) . .
C61 P2 C41 C46 59.6(2) . .
C51 P2 C41 C46 171.95(19) . .
Pt1 P2 C41 C46 -73.9(2) . .
C61 P2 C41 C42 -176.81(19) . .
C51 P2 C41 C42 -64.5(2) . .
Pt1 P2 C41 C42 49.7(2) . .
C46 C41 C42 C43 -57.4(3) . .
P2 C41 C42 C43 176.0(2) . .
C41 C42 C43 C44 56.1(3) . .
C42 C43 C44 C45 -54.1(3) . .
C43 C44 C45 C46 54.3(3) . .
C44 C45 C46 C41 -57.5(3) . .
C42 C41 C46 C45 58.6(3) . .
P2 C41 C46 C45 -177.28(18) . .
C41 P2 C51 C56 -36.8(2) . .
C61 P2 C51 C56 76.0(2) . .
Pt1 P2 C51 C56 -162.9(2) . .
C41 P2 C51 C52 -165.58(19) . .
C61 P2 C51 C52 -52.8(2) . .
Pt1 P2 C51 C52 68.3(2) . .
C56 C51 C52 C53 59.0(3) . .
P2 C51 C52 C53 -167.3(2) . .
C51 C52 C53 C54 -57.3(3) . .
C52 C53 C54 C55 54.7(3) . .
C53 C54 C55 C56 -54.8(3) . .
C52 C51 C56 C55 -58.7(3) . .
P2 C51 C56 C55 171.6(2) . .
C54 C55 C56 C51 57.1(3) . .
C41 P2 C61 C62 35.2(2) . .
C51 P2 C61 C62 -75.8(2) . .
Pt1 P2 C61 C62 171.38(18) . .
C41 P2 C61 C66 -93.8(2) . .
C51 P2 C61 C66 155.3(2) . .
Pt1 P2 C61 C66 42.4(2) . .
C66 C61 C62 C63 -53.7(3) . .
P2 C61 C62 C63 177.7(2) . .
C61 C62 C63 C64 56.2(3) . .
C62 C63 C64 C65 -57.6(3) . .
C63 C64 C65 C66 56.2(3) . .
C64 C65 C66 C61 -54.1(3) . .
C62 C61 C66 C65 53.3(3) . .
P2 C61 C66 C65 -175.6(2) . .
C91 P3 C71 C76 61.8(2) . .
C81 P3 C71 C76 -47.3(2) . .
Pt2 P3 C71 C76 -162.35(18) . .
C91 P3 C71 C72 -168.6(2) . .
C81 P3 C71 C72 82.3(2) . .
Pt2 P3 C71 C72 -32.8(2) . .
C76 C71 C72 C73 -54.4(3) . .
P3 C71 C72 C73 173.6(2) . .
C71 C72 C73 C74 55.7(3) . .
C72 C73 C74 C75 -56.5(3) . .
C73 C74 C75 C76 56.5(3) . .
C74 C75 C76 C71 -55.5(3) . .
C72 C71 C76 C75 54.2(3) . .
P3 C71 C76 C75 -175.1(2) . .
C91 P3 C81 C82 -163.39(19) . .
C71 P3 C81 C82 -53.9(2) . .
Pt2 P3 C81 C82 68.7(2) . .
C91 P3 C81 C86 -33.5(2) . .
C71 P3 C81 C86 76.0(2) . .
Pt2 P3 C81 C86 -161.5(2) . .
C86 C81 C82 C83 56.8(3) . .
P3 C81 C82 C83 -169.10(19) . .
C81 C82 C83 C84 -56.2(3) . .
C82 C83 C84 C85 55.6(3) . .
C83 C84 C85 C86 -57.4(3) . .
C84 C85 C86 C81 58.5(3) . .
C82 C81 C86 C85 -57.4(3) . .
P3 C81 C86 C85 171.5(2) . .
C71 P3 C91 C92 55.8(2) . .
C81 P3 C91 C92 170.8(2) . .
Pt2 P3 C91 C92 -75.4(2) . .
C71 P3 C91 C96 -179.31(19) . .
C81 P3 C91 C96 -64.4(2) . .
Pt2 P3 C91 C96 49.5(2) . .
C96 C91 C92 C93 55.6(3) . .
P3 C91 C92 C93 -178.9(2) . .
C91 C92 C93 C94 -54.8(3) . .
C92 C93 C94 C95 54.3(3) . .
C93 C94 C95 C96 -56.2(3) . .
C94 C95 C96 C91 58.0(3) . .
C92 C91 C96 C95 -57.2(3) . .
P3 C91 C96 C95 175.64(19) . .
C111 P4 C101 C106 172.5(2) . .
C121 P4 C101 C106 -75.7(2) . .
Pt2 P4 C101 C106 50.0(2) . .
C111 P4 C101 C102 -61.8(2) . .
C121 P4 C101 C102 50.0(2) . .
Pt2 P4 C101 C102 175.77(16) . .
C106 C101 C102 C103 -52.1(3) . .
P4 C101 C102 C103 -178.3(2) . .
C101 C102 C103 C104 54.2(3) . .
C102 C103 C104 C105 -56.1(3) . .
C103 C104 C105 C106 57.4(3) . .
C104 C105 C106 C101 -56.8(3) . .
C102 C101 C106 C105 53.5(3) . .
P4 C101 C106 C105 -178.8(2) . .
C101 P4 C111 C116 -53.0(2) . .
C121 P4 C111 C116 -162.7(2) . .
Pt2 P4 C111 C116 79.5(2) . .
C101 P4 C111 C112 -173.59(19) . .
C121 P4 C111 C112 76.7(2) . .
Pt2 P4 C111 C112 -41.1(2) . .
C116 C111 C112 C113 58.2(3) . .
P4 C111 C112 C113 -178.6(2) . .
C111 C112 C113 C114 -57.5(3) . .
C112 C113 C114 C115 55.1(4) . .
C113 C114 C115 C116 -54.9(4) . .
C112 C111 C116 C115 -57.9(3) . .
P4 C111 C116 C115 -178.9(2) . .
C114 C115 C116 C111 57.3(4) . .
C111 P4 C121 C122 -114.0(2) . .
C101 P4 C121 C122 134.6(2) . .
Pt2 P4 C121 C122 1.2(2) . .
C111 P4 C121 C126 14.4(2) . .
C101 P4 C121 C126 -97.0(2) . .
Pt2 P4 C121 C126 129.59(19) . .
C126 C121 C122 C123 51.9(3) . .
P4 C121 C122 C123 -178.1(2) . .
C121 C122 C123 C124 -55.6(4) . .
C122 C123 C124 C125 58.5(3) . .
C123 C124 C125 C126 -57.9(4) . .
C124 C125 C126 C121 53.0(4) . .
C122 C121 C126 C125 -50.1(3) . .
P4 C121 C126 C125 -177.7(2) . .
C206 C201 C202 C204 -1.6(4) . .
C206 C201 C202 B200 177.8(2) . .
C212 B200 C202 C201 -4.0(4) . .
C231 B200 C202 C201 118.0(3) . .
C221 B200 C202 C201 -119.0(3) . .
C212 B200 C202 C204 175.4(2) . .
C231 B200 C202 C204 -62.6(3) . .
C221 B200 C202 C204 60.4(3) . .
C201 C202 C204 C205 2.9(4) . .
B200 C202 C204 C205 -176.6(2) . .
C206 C203 C205 C204 -0.9(4) . .
C206 C203 C205 Cl6 -179.3(2) . .
C202 C204 C205 C203 -1.7(4) . .
C202 C204 C205 Cl6 176.7(2) . .
C202 C201 C206 C203 -0.9(4) . .
C202 C201 C206 Cl5 -179.4(2) . .
C205 C203 C206 C201 2.2(4) . .
C205 C203 C206 Cl5 -179.3(2) . .
C214 C211 C212 C215 -1.6(4) . .
C214 C211 C212 B200 174.0(3) . .
C202 B200 C212 C211 119.4(3) . .
C231 B200 C212 C211 -0.3(4) . .
C221 B200 C212 C211 -122.0(3) . .
C202 B200 C212 C215 -65.0(3) . .
C231 B200 C212 C215 175.3(2) . .
C221 B200 C212 C215 53.5(3) . .
C216 C213 C214 C211 1.3(4) . .
C216 C213 C214 Cl3 -179.2(2) . .
C212 C211 C214 C213 0.3(4) . .
C212 C211 C214 Cl3 -179.2(2) . .
C211 C212 C215 C216 1.4(4) . .
B200 C212 C215 C216 -174.5(3) . .
C212 C215 C216 C213 0.2(4) . .
C212 C215 C216 Cl4 179.8(2) . .
C214 C213 C216 C215 -1.5(4) . .
C214 C213 C216 Cl4 178.9(2) . .
C202 B200 C221 C224 2.5(4) . .
C212 B200 C221 C224 -117.6(3) . .
C231 B200 C221 C224 122.0(3) . .
C202 B200 C221 C222 177.5(2) . .
C212 B200 C221 C222 57.4(3) . .
C231 B200 C221 C222 -63.1(3) . .
C224 C221 C222 C225 -2.5(4) . .
B200 C221 C222 C225 -177.9(3) . .
C222 C221 C224 C226 1.8(4) . .
B200 C221 C224 C226 177.0(3) . .
C221 C222 C225 C223 1.5(4) . .
C221 C222 C225 Cl8 -178.2(2) . .
C226 C223 C225 C222 0.3(4) . .
C226 C223 C225 Cl8 -180.0(2) . .
C225 C223 C226 C224 -1.0(4) . .
C225 C223 C226 Cl7 178.5(2) . .
C221 C224 C226 C223 -0.1(4) . .
C221 C224 C226 Cl7 -179.6(2) . .
C202 B200 C231 C232 134.1(3) . .
C212 B200 C231 C232 -103.3(3) . .
C221 B200 C231 C232 13.0(4) . .
C202 B200 C231 C233 -46.8(3) . .
C212 B200 C231 C233 75.8(3) . .
C221 B200 C231 C233 -167.8(2) . .
C233 C231 C232 C234 -0.1(4) . .
B200 C231 C232 C234 179.0(3) . .
C232 C231 C233 C236 0.5(4) . .
B200 C231 C233 C236 -178.7(2) . .
C231 C232 C234 C235 -0.1(4) . .
C231 C232 C234 Cl1 179.7(2) . .
C232 C234 C235 C236 0.0(4) . .
Cl1 C234 C235 C236 -179.8(2) . .
C234 C235 C236 C233 0.4(4) . .
C234 C235 C236 Cl2 179.4(2) . .
C231 C233 C236 C235 -0.6(4) . .
C231 C233 C236 Cl2 -179.6(2) . .
C304 O300 C301 C302 26.4(15) . .
O300 C301 C302 C303 -30.2(13) . .
C301 C302 C303 C304 22.1(12) . .
C301 O300 C304 C303 -12.5(15) . .
C302 C303 C304 O300 -7.1(13) . .
C314 O310 C311 C312 -42.3(16) . .
O310 C311 C312 C313 30.6(15) . .
C311 C312 C313 C314 -8.9(17) . .
C312 C313 C314 O310 -18.9(19) . .
C311 O310 C314 C313 40(2) . .
C403 C401 C402 C403 40.9(18) 3_666 .
C401 C402 C403 C401 -37.0(16) . 3_666
