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#$Date: 2017-09-13 04:50:55 +0300 (Wed, 13 Sep 2017) $
#$Revision: 200806 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/06/7120641.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7120641
loop_
_publ_author_name
'Zhang, Jun'
'Chen, Haifeng'
'Wang, Jiwei'
'Hu, Zejun'
'Xu, Sheng'
'Shi, Min'
_publ_section_title
;
 Catalytic domino amination and oxidative coupling of gold acetylides and
 isolation of key vinylene digold intermediates as a new class of ditopic
 N-heterocyclic carbene complexes
;
_journal_name_full               'Chem. Commun.'
_journal_paper_doi               10.1039/C7CC06069F
_journal_year                    2017
_chemical_formula_sum            'C58 H74 Au2 Cl4 N4 O2'
_chemical_formula_weight         1394.94
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      trigonal
_space_group_IT_number           154
_space_group_name_Hall           'P 32 2"'
_space_group_name_H-M_alt        'P 32 2 1'
_symmetry_space_group_name_Hall  'P 32 2"'
_symmetry_space_group_name_H-M   'P 32 2 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-12-02 deposited with the CCDC.
2017-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   15.803(2)
_cell_length_b                   15.803(2)
_cell_length_c                   21.901(3)
_cell_measurement_reflns_used    9875
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.75
_cell_measurement_theta_min      2.38
_cell_volume                     4736.7(11)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_unetI/netI     0.0398
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            34011
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.357
_diffrn_reflns_theta_min         1.755
_exptl_absorpt_coefficient_mu    4.850
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_correction_T_min  0.435
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_description       prism
_exptl_crystal_F_000             2076
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.240
_exptl_crystal_size_min          0.220
_refine_diff_density_max         0.883
_refine_diff_density_min         -0.388
_refine_diff_density_rms         0.076
_refine_ls_abs_structure_details
; 
 Flack x determined using 2555 quotients [(I+)-(I-)]/[(I+)+(I-)] 
 (Parsons and Flack (2004), Acta Cryst. A60, s61). 
;
_refine_ls_abs_structure_Flack   0.002(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         7149
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0380
_refine_ls_R_factor_gt           0.0270
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[σ²(Fo²)+(0.0291P)²+1.0360P] 
 where P=(Fo²+2Fc²)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0620
_refine_ls_wR_factor_ref         0.0669
_reflns_Friedel_coverage         0.803
_reflns_Friedel_fraction_full    0.996
_reflns_Friedel_fraction_max     0.995
_reflns_number_gt                6235
_reflns_number_total             7149
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7cc06069f2.cif
_cod_data_source_block           mo_51010b
_cod_original_cell_volume        4736.5(15)
_cod_database_code               7120641
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.195
_shelx_estimated_absorpt_t_max   0.415
_shelxl_version_number           2013-2
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z+2/3'
'-x+y, -x, z+1/3'
'y, x, -z'
'x-y, -y, -z+1/3'
'-x, -x+y, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Au1 Au 0.60241(2) 0.11418(2) 0.23385(2) 0.04918(9) Uani 1 1 d . .
Cl1 Cl 0.5083(2) 0.09982(19) 0.31665(11) 0.1006(9) Uani 1 1 d . .
N1 N 0.7308(3) 0.2029(3) 0.1253(2) 0.0371(10) Uani 1 1 d . .
N2 N 0.8061(3) 0.1392(3) 0.0664(2) 0.0381(11) Uani 1 1 d . .
O1 O 0.7858(4) -0.0111(3) 0.0872(2) 0.0615(14) Uani 1 1 d . .
C1 C 0.6844(4) 0.1190(4) 0.1637(2) 0.0320(11) Uani 1 1 d . .
C2 C 0.7870(4) 0.2098(4) 0.0797(2) 0.0394(12) Uani 1 1 d . .
H2 H 0.807(5) 0.269(5) 0.053(3) 0.057(19) Uiso 1 1 d . .
C3 C 0.7638(4) 0.0496(4) 0.1008(3) 0.0382(12) Uani 1 1 d . .
C4 C 0.7011(4) 0.0458(4) 0.1483(2) 0.0328(11) Uani 1 1 d . .
C5 C 0.7133(4) 0.2845(4) 0.1355(3) 0.0434(14) Uani 1 1 d . .
C6 C 0.7784(5) 0.3607(5) 0.1724(3) 0.0514(15) Uani 1 1 d . .
C7 C 0.7621(6) 0.4398(5) 0.1778(4) 0.0674(19) Uani 1 1 d . .
H7 H 0.8043 0.4933 0.2016 0.081 Uiso 1 1 calc R U
C8 C 0.6862(7) 0.4402(6) 0.1490(5) 0.082(3) Uani 1 1 d . .
H8 H 0.6768 0.4934 0.1535 0.098 Uiso 1 1 calc R U
C9 C 0.6237(6) 0.3630(6) 0.1136(4) 0.074(2) Uani 1 1 d . .
H9 H 0.5723 0.3647 0.0942 0.088 Uiso 1 1 calc R U
C10 C 0.6347(6) 0.2823(5) 0.1060(3) 0.0561(16) Uani 1 1 d . .
C11 C 0.8610(5) 0.3583(6) 0.2065(4) 0.0652(19) Uani 1 1 d . .
H11 H 0.8572 0.2958 0.1975 0.078 Uiso 1 1 calc R U
C12 C 0.9596(7) 0.4397(10) 0.1836(7) 0.135(5) Uani 1 1 d . .
H12A H 0.9722 0.4232 0.1437 0.203 Uiso 1 1 calc R U
H12B H 1.0102 0.4474 0.2112 0.203 Uiso 1 1 calc R U
H12C H 0.9584 0.4998 0.1814 0.203 Uiso 1 1 calc R U
C13 C 0.8505(10) 0.3641(11) 0.2762(5) 0.122(4) Uani 1 1 d . .
H13A H 0.8521 0.4240 0.2863 0.183 Uiso 1 1 calc R U
H13B H 0.9034 0.3621 0.2965 0.183 Uiso 1 1 calc R U
H13C H 0.7896 0.3097 0.2894 0.183 Uiso 1 1 calc R U
C14 C 0.5618(6) 0.1938(6) 0.0680(4) 0.072(2) Uani 1 1 d . .
H14 H 0.5824 0.1448 0.0699 0.086 Uiso 1 1 calc R U
C15 C 0.5642(9) 0.2218(10) 0.0014(5) 0.122(4) Uani 1 1 d . .
H15A H 0.5343 0.2616 -0.0028 0.183 Uiso 1 1 calc R U
H15B H 0.5289 0.1637 -0.0228 0.183 Uiso 1 1 calc R U
H15C H 0.6307 0.2578 -0.0123 0.183 Uiso 1 1 calc R U
C16 C 0.4605(8) 0.1482(9) 0.0940(6) 0.124(4) Uani 1 1 d . .
H16A H 0.4607 0.1270 0.1350 0.187 Uiso 1 1 calc R U
H16B H 0.4168 0.0931 0.0695 0.187 Uiso 1 1 calc R U
H16C H 0.4391 0.1954 0.0940 0.187 Uiso 1 1 calc R U
C17 C 0.8683(5) 0.1496(5) 0.0146(3) 0.0459(14) Uani 1 1 d . .
C18 C 0.9663(5) 0.1823(5) 0.0259(3) 0.0582(17) Uani 1 1 d . .
C19 C 1.0219(7) 0.1884(8) -0.0250(4) 0.085(3) Uani 1 1 d . .
H19 H 1.0882 0.2108 -0.0201 0.102 Uiso 1 1 calc R U
C20 C 0.9818(8) 0.1625(10) -0.0812(4) 0.113(4) Uani 1 1 d . .
H20 H 1.0206 0.1659 -0.1141 0.135 Uiso 1 1 calc R U
C21 C 0.8867(9) 0.1320(10) -0.0904(4) 0.104(4) Uani 1 1 d . .
H21 H 0.8618 0.1171 -0.1298 0.124 Uiso 1 1 calc R U
C22 C 0.8247(6) 0.1221(6) -0.0424(3) 0.0637(19) Uani 1 1 d . .
C23 C 1.0124(6) 0.2091(6) 0.0888(3) 0.0635(19) Uani 1 1 d . .
H23 H 0.9616 0.2021 0.1174 0.076 Uiso 1 1 calc R U
C24 C 1.0952(9) 0.3150(8) 0.0922(6) 0.129(5) Uani 1 1 d . .
H24A H 1.0951 0.3414 0.1316 0.194 Uiso 1 1 calc R U
H24B H 1.0860 0.3527 0.0612 0.194 Uiso 1 1 calc R U
H24C H 1.1565 0.3176 0.0858 0.194 Uiso 1 1 calc R U
C25 C 1.0447(11) 0.1377(11) 0.1082(5) 0.128(5) Uani 1 1 d . .
H25A H 0.9905 0.0722 0.1052 0.192 Uiso 1 1 calc R U
H25B H 1.0674 0.1509 0.1497 0.192 Uiso 1 1 calc R U
H25C H 1.0966 0.1447 0.0821 0.192 Uiso 1 1 calc R U
C26 C 0.7176(7) 0.0830(9) -0.0536(4) 0.084(3) Uani 1 1 d . .
H26 H 0.6909 0.0931 -0.0157 0.100 Uiso 1 1 calc R U
C27 C 0.6990(9) 0.1390(10) -0.1030(6) 0.122(4) Uani 1 1 d . .
H27A H 0.7230 0.2051 -0.0899 0.183 Uiso 1 1 calc R U
H27B H 0.6300 0.1084 -0.1107 0.183 Uiso 1 1 calc R U
H27C H 0.7320 0.1390 -0.1398 0.183 Uiso 1 1 calc R U
C28 C 0.6615(9) -0.0272(10) -0.0660(8) 0.142(5) Uani 1 1 d . .
H28A H 0.6876 -0.0411 -0.1018 0.212 Uiso 1 1 calc R U
H28B H 0.5937 -0.0485 -0.0723 0.212 Uiso 1 1 calc R U
H28C H 0.6682 -0.0612 -0.0317 0.212 Uiso 1 1 calc R U
C29 C 0.8533(13) 0.8249(13) 0.0260(7) 0.184(7) Uani 1 1 d D .
H29A H 0.8857 0.8819 0.0522 0.220 Uiso 1 1 calc R U
H29B H 0.9025 0.8087 0.0137 0.220 Uiso 1 1 calc R U
Cl2 Cl 0.7705(4) 0.7304(5) 0.07044(19) 0.198(2) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Au1 Cl1 176.27(16) . .
C2 N1 C1 122.9(5) . .
C2 N1 C5 117.6(5) . .
C1 N1 C5 119.5(4) . .
C2 N2 C3 121.5(4) . .
C2 N2 C17 120.2(4) . .
C3 N2 C17 118.3(5) . .
C4 C1 N1 114.8(4) . .
C4 C1 Au1 124.3(4) . .
N1 C1 Au1 121.0(4) . .
N1 C2 N2 122.0(5) . .
N1 C2 H2 114(4) . .
N2 C2 H2 124(4) . .
O1 C3 C4 128.4(5) . .
O1 C3 N2 118.2(5) . .
C4 C3 N2 113.4(5) . .
C1 C4 C3 125.4(5) . .
C1 C4 C4 119.3(4) . 5
C3 C4 C4 115.2(4) . 5
C10 C5 C6 124.1(6) . .
C10 C5 N1 117.9(6) . .
C6 C5 N1 117.9(5) . .
C5 C6 C7 115.8(6) . .
C5 C6 C11 122.6(6) . .
C7 C6 C11 121.6(7) . .
C8 C7 C6 121.4(7) . .
C8 C7 H7 119.3 . .
C6 C7 H7 119.3 . .
C7 C8 C9 120.5(7) . .
C7 C8 H8 119.8 . .
C9 C8 H8 119.8 . .
C8 C9 C10 121.7(8) . .
C8 C9 H9 119.2 . .
C10 C9 H9 119.2 . .
C9 C10 C5 116.5(7) . .
C9 C10 C14 121.4(7) . .
C5 C10 C14 122.1(6) . .
C6 C11 C12 110.1(8) . .
C6 C11 C13 111.4(7) . .
C12 C11 C13 111.7(9) . .
C6 C11 H11 107.8 . .
C12 C11 H11 107.8 . .
C13 C11 H11 107.8 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C13 H13A 109.5 . .
C11 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C11 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C16 C14 C15 111.7(9) . .
C16 C14 C10 111.5(7) . .
C15 C14 C10 110.9(8) . .
C16 C14 H14 107.5 . .
C15 C14 H14 107.5 . .
C10 C14 H14 107.5 . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C14 C16 H16A 109.5 . .
C14 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C14 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C22 C17 C18 124.5(6) . .
C22 C17 N2 117.6(6) . .
C18 C17 N2 117.9(5) . .
C17 C18 C19 115.5(7) . .
C17 C18 C23 123.9(6) . .
C19 C18 C23 120.6(7) . .
C20 C19 C18 121.6(9) . .
C20 C19 H19 119.2 . .
C18 C19 H19 119.2 . .
C21 C20 C19 121.1(8) . .
C21 C20 H20 119.5 . .
C19 C20 H20 119.5 . .
C20 C21 C22 121.7(8) . .
C20 C21 H21 119.1 . .
C22 C21 H21 119.1 . .
C17 C22 C21 115.5(8) . .
C17 C22 C26 123.9(6) . .
C21 C22 C26 120.6(7) . .
C25 C23 C18 110.0(7) . .
C25 C23 C24 112.4(10) . .
C18 C23 C24 112.3(8) . .
C25 C23 H23 107.3 . .
C18 C23 H23 107.3 . .
C24 C23 H23 107.3 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C23 C25 H25A 109.5 . .
C23 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C23 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C22 C26 C27 112.6(9) . .
C22 C26 C28 112.9(8) . .
C27 C26 C28 111.4(10) . .
C22 C26 H26 106.5 . .
C27 C26 H26 106.5 . .
C28 C26 H26 106.5 . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C26 C28 H28A 109.5 . .
C26 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C26 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C29 C29 Cl2 121.4(8) 4 .
C29 C29 H29A 107.0 4 .
Cl2 C29 H29A 107.0 . .
C29 C29 H29B 107.0 4 .
Cl2 C29 H29B 107.0 . .
H29A C29 H29B 106.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C1 1.987(5) .
Au1 Cl1 2.2837(19) .
N1 C2 1.303(7) .
N1 C1 1.425(6) .
N1 C5 1.466(7) .
N2 C2 1.325(7) .
N2 C3 1.442(7) .
N2 C17 1.456(7) .
O1 C3 1.209(7) .
C1 C4 1.351(7) .
C2 H2 1.01(7) .
C3 C4 1.416(8) .
C4 C4 1.489(10) 5
C5 C10 1.383(9) .
C5 C6 1.388(9) .
C6 C7 1.402(9) .
C6 C11 1.522(10) .
C7 C8 1.357(12) .
C7 H7 0.9300 .
C8 C9 1.364(12) .
C8 H8 0.9300 .
C9 C10 1.381(10) .
C9 H9 0.9300 .
C10 C14 1.537(11) .
C11 C12 1.527(13) .
C11 C13 1.543(14) .
C11 H11 0.9800 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 C16 1.501(14) .
C14 C15 1.518(13) .
C14 H14 0.9800 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C22 1.387(9) .
C17 C18 1.387(10) .
C18 C19 1.393(10) .
C18 C23 1.516(11) .
C19 C20 1.352(14) .
C19 H19 0.9300 .
C20 C21 1.343(15) .
C20 H20 0.9300 .
C21 C22 1.392(11) .
C21 H21 0.9300 .
C22 C26 1.502(12) .
C23 C25 1.513(14) .
C23 C24 1.526(13) .
C23 H23 0.9800 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 C27 1.517(14) .
C26 C28 1.534(17) .
C26 H26 0.9800 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 C29 1.38(2) 4
C29 Cl2 1.713(15) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C2 H2 Cl1 1.01(7) 2.47(7) 3.449(6) 162(5) 2_654
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C2 N1 C1 C4 -1.6(8) .
C5 N1 C1 C4 176.5(5) .
C2 N1 C1 Au1 178.4(5) .
C5 N1 C1 Au1 -3.6(7) .
C1 N1 C2 N2 -1.0(9) .
C5 N1 C2 N2 -179.1(6) .
C3 N2 C2 N1 1.5(9) .
C17 N2 C2 N1 179.3(6) .
C2 N2 C3 O1 -178.4(6) .
C17 N2 C3 O1 3.7(9) .
C2 N2 C3 C4 0.6(8) .
C17 N2 C3 C4 -177.3(5) .
N1 C1 C4 C3 3.9(8) .
Au1 C1 C4 C3 -176.1(4) .
N1 C1 C4 C4 -179.4(5) 5
Au1 C1 C4 C4 0.7(7) 5
O1 C3 C4 C1 175.5(7) .
N2 C3 C4 C1 -3.4(8) .
O1 C3 C4 C4 -1.4(10) 5
N2 C3 C4 C4 179.7(5) 5
C2 N1 C5 C10 89.4(7) .
C1 N1 C5 C10 -88.7(7) .
C2 N1 C5 C6 -88.5(7) .
C1 N1 C5 C6 93.4(7) .
C10 C5 C6 C7 -1.6(10) .
N1 C5 C6 C7 176.2(6) .
C10 C5 C6 C11 177.0(7) .
N1 C5 C6 C11 -5.3(9) .
C5 C6 C7 C8 0.9(11) .
C11 C6 C7 C8 -177.6(8) .
C6 C7 C8 C9 -0.4(14) .
C7 C8 C9 C10 0.3(14) .
C8 C9 C10 C5 -0.8(12) .
C8 C9 C10 C14 177.7(8) .
C6 C5 C10 C9 1.5(10) .
N1 C5 C10 C9 -176.3(6) .
C6 C5 C10 C14 -177.0(7) .
N1 C5 C10 C14 5.3(9) .
C5 C6 C11 C12 116.7(9) .
C7 C6 C11 C12 -64.9(10) .
C5 C6 C11 C13 -118.7(9) .
C7 C6 C11 C13 59.7(11) .
C9 C10 C14 C16 -60.5(11) .
C5 C10 C14 C16 117.9(9) .
C9 C10 C14 C15 64.6(11) .
C5 C10 C14 C15 -117.0(9) .
C2 N2 C17 C22 -85.6(8) .
C3 N2 C17 C22 92.3(7) .
C2 N2 C17 C18 97.0(7) .
C3 N2 C17 C18 -85.1(7) .
C22 C17 C18 C19 1.1(11) .
N2 C17 C18 C19 178.3(7) .
C22 C17 C18 C23 -178.0(7) .
N2 C17 C18 C23 -0.8(10) .
C17 C18 C19 C20 -0.9(14) .
C23 C18 C19 C20 178.3(10) .
C18 C19 C20 C21 1.6(19) .
C19 C20 C21 C22 -2(2) .
C18 C17 C22 C21 -1.9(12) .
N2 C17 C22 C21 -179.1(8) .
C18 C17 C22 C26 177.5(8) .
N2 C17 C22 C26 0.3(11) .
C20 C21 C22 C17 2.5(17) .
C20 C21 C22 C26 -176.9(12) .
C17 C18 C23 C25 113.5(10) .
C19 C18 C23 C25 -65.6(11) .
C17 C18 C23 C24 -120.6(9) .
C19 C18 C23 C24 60.3(12) .
C17 C22 C26 C27 126.6(9) .
C21 C22 C26 C27 -54.0(13) .
C17 C22 C26 C28 -106.2(11) .
C21 C22 C26 C28 73.2(13) .
