#------------------------------------------------------------------------------
#$Date: 2019-10-03 03:02:38 +0300 (Thu, 03 Oct 2019) $
#$Revision: 219046 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/42/7124261.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7124261
loop_
_publ_author_name
'Zhang, Jing'
'Li, Jing'
'Feng, Xin'
'Kong, Ming'
'Hu, Zhaobo'
'Zheng, You-Xuan'
'Song, You'
_publ_section_title
;
 Light-controlled efficient photoluminescence based on an europium
 β-diketonate with single-crystal-to-single-crystal [2+2] cycloaddition
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC05227E
_journal_year                    2019
_chemical_formula_sum            'C110 H76 Eu2 F18 N4 O14'
_chemical_formula_weight         2323.66
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2019-07-05 deposited with the CCDC.    2019-10-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.7680(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.1434(11)
_cell_length_b                   15.3452(13)
_cell_length_c                   23.763(2)
_cell_measurement_reflns_used    9950
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      2.18
_cell_volume                     4748.7(7)
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            35191
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.008
_diffrn_reflns_theta_max         25.008
_diffrn_reflns_theta_min         1.584
_exptl_absorpt_coefficient_mu    1.414
_exptl_crystal_density_diffrn    1.625
_exptl_crystal_description       block
_exptl_crystal_F_000             2328
_refine_diff_density_max         1.397
_refine_diff_density_min         -0.946
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     672
_refine_ls_number_reflns         8323
_refine_ls_number_restraints     56
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0408
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0362P)²+10.9680P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0882
_refine_ls_wR_factor_ref         0.0915
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7456
_reflns_number_total             8323
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9cc05227e2.cif
_cod_data_source_block           1a
_cod_original_cell_volume        4748.8(7)
_cod_database_code               7124261
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.1271(4) 0.4436(3) 1.14123(18) 0.0423(11) Uani 1 1 d . .
H1 H 0.086834 0.423374 1.167760 0.051 Uiso 1 1 calc R U
C2 C 0.0999(3) 0.4233(3) 1.08259(17) 0.0305(9) Uani 1 1 d . .
C3 C 0.1628(3) 0.4553(2) 1.04307(17) 0.0267(8) Uani 1 1 d . .
C4 C 0.2494(3) 0.5070(3) 1.06297(19) 0.0341(9) Uani 1 1 d . .
H4 H 0.290529 0.528777 1.037329 0.041 Uiso 1 1 calc R U
C5 C 0.2731(4) 0.5251(3) 1.1194(2) 0.0422(11) Uani 1 1 d . .
H5 H 0.330094 0.559211 1.131973 0.051 Uiso 1 1 calc R U
C6 C 0.2120(4) 0.4926(3) 1.1585(2) 0.0485(12) Uani 1 1 d . .
H6 H 0.229605 0.504691 1.196903 0.058 Uiso 1 1 calc R U
C7 C 0.0130(3) 0.3734(3) 1.06208(18) 0.0354(10) Uani 1 1 d . .
H7 H -0.029915 0.353718 1.087486 0.043 Uiso 1 1 calc R U
C8 C -0.0101(3) 0.3530(3) 1.00596(17) 0.0322(9) Uani 1 1 d . .
H8 H -0.068165 0.319948 0.993641 0.039 Uiso 1 1 calc R U
C9 C 0.0541(3) 0.3820(3) 0.96621(16) 0.0272(8) Uani 1 1 d . .
C10 C 0.1375(3) 0.4329(3) 0.98510(17) 0.0281(9) Uani 1 1 d . .
H10 H 0.178672 0.453271 0.959033 0.034 Uiso 1 1 calc R U
C11 C 0.0360(3) 0.3561(3) 0.90501(16) 0.0253(8) Uani 1 1 d . .
C12 C -0.0571(3) 0.3150(3) 0.88205(18) 0.0373(10) Uani 1 1 d . .
H12 H -0.106233 0.303977 0.905850 0.045 Uiso 1 1 calc R U
C13 C -0.0772(3) 0.2912(3) 0.82633(18) 0.0334(10) Uani 1 1 d . .
C14 C -0.1829(3) 0.2558(5) 0.8041(2) 0.0570(16) Uani 1 1 d . .
C15 C 0.1873(4) 0.1842(4) 1.0713(3) 0.0643(16) Uani 1 1 d . U
H15 H 0.199765 0.242244 1.063398 0.077 Uiso 1 1 calc R U
C16 C 0.1685(4) 0.1262(4) 1.0282(2) 0.0519(12) Uani 1 1 d . U
C17 C 0.1474(4) 0.0378(5) 1.0401(2) 0.0614(15) Uani 1 1 d . U
C18 C 0.1475(4) 0.0103(5) 1.0985(3) 0.0715(18) Uani 1 1 d . U
H18 H 0.133992 -0.047054 1.107631 0.086 Uiso 1 1 calc R U
C19 C 0.1671(4) 0.0687(6) 1.1369(3) 0.0753(19) Uani 1 1 d . U
H19 H 0.167543 0.051235 1.174444 0.090 Uiso 1 1 calc R U
C20 C 0.1880(5) 0.1573(6) 1.1274(3) 0.0778(19) Uani 1 1 d . U
H20 H 0.201834 0.196278 1.157455 0.093 Uiso 1 1 calc R U
C21 C 0.1659(3) 0.1523(4) 0.9709(2) 0.0448(12) Uani 1 1 d . U
H21 H 0.180511 0.209828 0.962485 0.054 Uiso 1 1 calc R U
C22 C 0.1421(3) 0.0935(3) 0.92752(19) 0.0375(10) Uani 1 1 d . .
C23 C 0.1223(3) 0.0056(3) 0.9405(2) 0.0458(12) Uani 1 1 d . U
H23 H 0.106188 -0.034370 0.911212 0.055 Uiso 1 1 calc R U
C24 C 0.1265(4) -0.0214(4) 0.9959(2) 0.0580(15) Uani 1 1 d . U
H24 H 0.115259 -0.079709 1.003830 0.070 Uiso 1 1 calc R U
C25 C 0.1356(3) 0.1270(3) 0.86825(18) 0.0321(9) Uani 1 1 d . .
C26 C 0.0811(3) 0.0805(3) 0.82296(18) 0.0321(9) Uani 1 1 d . .
H26 H 0.047357 0.029493 0.830673 0.038 Uiso 1 1 calc R U
C27 C 0.0761(3) 0.1081(2) 0.76718(17) 0.0275(9) Uani 1 1 d . .
C28 C 0.0108(4) 0.0555(3) 0.72118(18) 0.0353(10) Uani 1 1 d . .
C29 C 0.6281(3) 0.3355(3) 1.08364(17) 0.0331(9) Uani 1 1 d . .
H29 H 0.600536 0.362723 1.113083 0.040 Uiso 1 1 calc R U
C30 C 0.5734(3) 0.3374(3) 1.02766(16) 0.0257(8) Uani 1 1 d . .
C31 C 0.6175(3) 0.2952(2) 0.98373(16) 0.0212(8) Uani 1 1 d . .
C32 C 0.7135(3) 0.2536(3) 0.99650(17) 0.0280(9) Uani 1 1 d . .
H32 H 0.742976 0.226382 0.967697 0.034 Uiso 1 1 calc R U
C33 C 0.7636(3) 0.2528(3) 1.05077(17) 0.0328(9) Uani 1 1 d . .
H33 H 0.826614 0.224811 1.058775 0.039 Uiso 1 1 calc R U
C34 C 0.7199(3) 0.2944(3) 1.09453(18) 0.0335(10) Uani 1 1 d . .
H34 H 0.754462 0.293587 1.131367 0.040 Uiso 1 1 calc R U
C35 C 0.4766(3) 0.3770(3) 1.01471(18) 0.0377(10) Uani 1 1 d . .
H35 H 0.447448 0.404839 1.043415 0.045 Uiso 1 1 calc R U
C36 C 0.4247(3) 0.3756(3) 0.96126(18) 0.0353(10) Uani 1 1 d . .
H36 H 0.360042 0.401125 0.954069 0.042 Uiso 1 1 calc R U
C37 C 0.4682(3) 0.3355(2) 0.91643(15) 0.0206(7) Uani 1 1 d . .
C38 C 0.5631(3) 0.2966(2) 0.92808(15) 0.0188(7) Uani 1 1 d . .
H38 H 0.592112 0.270513 0.898704 0.023 Uiso 1 1 calc R U
C39 C 0.4069(3) 0.3306(2) 0.85886(15) 0.0196(7) Uani 1 1 d . .
C40 C 0.4562(3) 0.3114(2) 0.81091(16) 0.0208(8) Uani 1 1 d . .
H40 H 0.527530 0.309144 0.815013 0.025 Uiso 1 1 calc R U
C41 C 0.4014(3) 0.2960(2) 0.75858(15) 0.0198(7) Uani 1 1 d . .
C42 C 0.4614(3) 0.2813(3) 0.70862(16) 0.0287(9) Uani 1 1 d . .
C43 C 0.0036(3) 0.3193(2) 0.65994(16) 0.0243(8) Uani 1 1 d . .
H43 H -0.037861 0.285364 0.679992 0.029 Uiso 1 1 calc R U
C44 C -0.0335(3) 0.3432(3) 0.60452(16) 0.0248(8) Uani 1 1 d . .
H44 H -0.098434 0.325053 0.588322 0.030 Uiso 1 1 calc R U
C45 C 0.0256(3) 0.3937(2) 0.57344(15) 0.0204(7) Uani 1 1 d . .
C46 C 0.1249(3) 0.4119(2) 0.59842(15) 0.0211(7) Uani 1 1 d . .
H46 H 0.169995 0.441169 0.578013 0.025 Uiso 1 1 calc R U
C47 C 0.1565(3) 0.3864(2) 0.65384(15) 0.0211(8) Uani 1 1 d . .
H47 H 0.223121 0.399989 0.669901 0.025 Uiso 1 1 calc R U
C48 C -0.0225(3) 0.4376(2) 0.51938(15) 0.0216(8) Uani 1 1 d . .
H48 H -0.084185 0.406303 0.502584 0.026 Uiso 1 1 calc R U
C49 C 0.0464(3) 0.4609(2) 0.47343(15) 0.0223(8) Uani 1 1 d . .
H49 H 0.118625 0.448153 0.486953 0.027 Uiso 1 1 calc R U
C50 C 0.0176(3) 0.4295(2) 0.41322(16) 0.0237(8) Uani 1 1 d . .
C51 C -0.0761(3) 0.3936(2) 0.39187(17) 0.0263(8) Uani 1 1 d . .
H51 H -0.119655 0.371751 0.416253 0.032 Uiso 1 1 calc R U
C52 C -0.1042(3) 0.3907(2) 0.33362(18) 0.0314(9) Uani 1 1 d . .
H52 H -0.167585 0.366447 0.319978 0.038 Uiso 1 1 calc R U
C53 C 0.0483(4) 0.4465(3) 0.31693(18) 0.0386(10) Uani 1 1 d . .
H53 H 0.093128 0.462308 0.291594 0.046 Uiso 1 1 calc R U
C54 C 0.0830(3) 0.4514(3) 0.37398(17) 0.0344(10) Uani 1 1 d . .
H54 H 0.149848 0.469321 0.386349 0.041 Uiso 1 1 calc R U
C55 C 0.1986(5) 0.5287(4) 0.8250(3) 0.0646(16) Uani 1 1 d . U
H55A H 0.142849 0.542110 0.845828 0.097 Uiso 1 1 calc R U
H55B H 0.222345 0.581294 0.809181 0.097 Uiso 1 1 calc R U
H55C H 0.253743 0.502846 0.850126 0.097 Uiso 1 1 calc R U
Eu1 Eu 0.16061(2) 0.31098(2) 0.79232(2) 0.01895(7) Uani 1 1 d . .
F1 F -0.2467(2) 0.2494(3) 0.84253(15) 0.1006(16) Uani 1 1 d . .
F2 F -0.2302(3) 0.3084(3) 0.76477(19) 0.1089(17) Uani 1 1 d . .
F3 F -0.1788(3) 0.1792(3) 0.78025(19) 0.1012(16) Uani 1 1 d . .
F4 F -0.0539(2) 0.10743(17) 0.68847(12) 0.0521(7) Uani 1 1 d . .
F5 F 0.0692(2) 0.01665(17) 0.68662(13) 0.0566(8) Uani 1 1 d . .
F6 F -0.0458(2) -0.00705(17) 0.74106(11) 0.0461(7) Uani 1 1 d . .
F7 F 0.4364(2) 0.34189(19) 0.66825(11) 0.0466(7) Uani 1 1 d . .
F8 F 0.4380(2) 0.20490(17) 0.68356(11) 0.0410(6) Uani 1 1 d . .
F9 F 0.56204(18) 0.2836(2) 0.72231(11) 0.0586(9) Uani 1 1 d . .
N1 N 0.0966(2) 0.34296(19) 0.68573(12) 0.0205(6) Uani 1 1 d . .
N2 N -0.0461(3) 0.4203(2) 0.29560(15) 0.0355(8) Uani 1 1 d . .
O1 O 0.1057(2) 0.37231(19) 0.87548(11) 0.0308(6) Uani 1 1 d . .
O2 O -0.0188(2) 0.29456(19) 0.78777(11) 0.0305(6) Uani 1 1 d . .
O3 O 0.1774(2) 0.19948(19) 0.86170(12) 0.0343(7) Uani 1 1 d . .
O4 O 0.1195(2) 0.17248(17) 0.74812(11) 0.0285(6) Uani 1 1 d . .
O5 O 0.31237(19) 0.34387(18) 0.85565(11) 0.0261(6) Uani 1 1 d . .
O6 O 0.30496(18) 0.29106(17) 0.74434(10) 0.0233(6) Uani 1 1 d . .
O7 O 0.1645(2) 0.46961(19) 0.78070(12) 0.0341(7) Uani 1 1 d . U
H7A H 0.121(3) 0.501(3) 0.7586(19) 0.029(12) Uiso 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 C1 C2 120.2(4) . .
C6 C1 H1 119.9 . .
C2 C1 H1 119.9 . .
C7 C2 C3 118.5(4) . .
C7 C2 C1 122.9(4) . .
C3 C2 C1 118.6(4) . .
C10 C3 C4 122.3(4) . .
C10 C3 C2 118.6(4) . .
C4 C3 C2 119.1(4) . .
C5 C4 C3 120.6(4) . .
C5 C4 H4 119.7 . .
C3 C4 H4 119.7 . .
C4 C5 C6 120.3(4) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C1 C6 C5 121.2(4) . .
C1 C6 H6 119.4 . .
C5 C6 H6 119.4 . .
C8 C7 C2 121.8(4) . .
C8 C7 H7 119.1 . .
C2 C7 H7 119.1 . .
C7 C8 C9 120.3(4) . .
C7 C8 H8 119.8 . .
C9 C8 H8 119.8 . .
C10 C9 C8 118.8(4) . .
C10 C9 C11 119.0(3) . .
C8 C9 C11 122.2(4) . .
C9 C10 C3 121.9(4) . .
C9 C10 H10 119.0 . .
C3 C10 H10 119.0 . .
O1 C11 C12 122.1(4) . .
O1 C11 C9 117.4(3) . .
C12 C11 C9 120.5(3) . .
C13 C12 C11 122.5(4) . .
C13 C12 H12 118.8 . .
C11 C12 H12 118.8 . .
O2 C13 C12 129.1(4) . .
O2 C13 C14 112.1(4) . .
C12 C13 C14 118.8(4) . .
F3 C14 F1 107.5(5) . .
F3 C14 F2 106.5(5) . .
F1 C14 F2 104.5(5) . .
F3 C14 C13 112.5(4) . .
F1 C14 C13 115.0(4) . .
F2 C14 C13 110.3(5) . .
C16 C15 C20 120.4(7) . .
C16 C15 H15 119.8 . .
C20 C15 H15 119.8 . .
C15 C16 C21 121.3(6) . .
C15 C16 C17 119.9(5) . .
C21 C16 C17 118.8(5) . .
C24 C17 C16 119.9(5) . .
C24 C17 C18 120.5(6) . .
C16 C17 C18 119.5(7) . .
C19 C18 C17 116.9(8) . .
C19 C18 H18 121.5 . .
C17 C18 H18 121.5 . .
C18 C19 C20 125.8(7) . .
C18 C19 H19 117.1 . .
C20 C19 H19 117.1 . .
C15 C20 C19 117.5(7) . .
C15 C20 H20 121.3 . .
C19 C20 H20 121.3 . .
C22 C21 C16 120.6(5) . .
C22 C21 H21 119.7 . .
C16 C21 H21 119.7 . .
C21 C22 C23 119.5(4) . .
C21 C22 C25 117.4(4) . .
C23 C22 C25 123.0(4) . .
C24 C23 C22 120.7(6) . .
C24 C23 H23 119.6 . .
C22 C23 H23 119.6 . .
C23 C24 C17 120.4(6) . .
C23 C24 H24 119.8 . .
C17 C24 H24 119.8 . .
O3 C25 C26 122.7(4) . .
O3 C25 C22 116.8(4) . .
C26 C25 C22 120.5(4) . .
C27 C26 C25 122.1(4) . .
C27 C26 H26 118.9 . .
C25 C26 H26 118.9 . .
O4 C27 C26 128.4(4) . .
O4 C27 C28 113.4(3) . .
C26 C27 C28 118.2(4) . .
F4 C28 F5 106.4(4) . .
F4 C28 F6 107.0(4) . .
F5 C28 F6 106.8(3) . .
F4 C28 C27 110.7(3) . .
F5 C28 C27 111.2(4) . .
F6 C28 C27 114.3(3) . .
C34 C29 C30 120.9(4) . .
C34 C29 H29 119.6 . .
C30 C29 H29 119.6 . .
C35 C30 C31 119.0(3) . .
C35 C30 C29 122.8(4) . .
C31 C30 C29 118.2(4) . .
C32 C31 C38 122.1(3) . .
C32 C31 C30 119.5(3) . .
C38 C31 C30 118.4(3) . .
C33 C32 C31 120.7(4) . .
C33 C32 H32 119.7 . .
C31 C32 H32 119.7 . .
C32 C33 C34 120.1(4) . .
C32 C33 H33 120.0 . .
C34 C33 H33 120.0 . .
C29 C34 C33 120.8(4) . .
C29 C34 H34 119.6 . .
C33 C34 H34 119.6 . .
C36 C35 C30 121.5(4) . .
C36 C35 H35 119.2 . .
C30 C35 H35 119.2 . .
C35 C36 C37 120.5(4) . .
C35 C36 H36 119.7 . .
C37 C36 H36 119.7 . .
C38 C37 C36 118.9(3) . .
C38 C37 C39 121.6(3) . .
C36 C37 C39 119.3(3) . .
C37 C38 C31 121.6(3) . .
C37 C38 H38 119.2 . .
C31 C38 H38 119.2 . .
O5 C39 C40 122.9(3) . .
O5 C39 C37 117.1(3) . .
C40 C39 C37 120.0(3) . .
C41 C40 C39 121.6(3) . .
C41 C40 H40 119.2 . .
C39 C40 H40 119.2 . .
O6 C41 C40 129.5(3) . .
O6 C41 C42 112.7(3) . .
C40 C41 C42 117.8(3) . .
F9 C42 F8 107.2(3) . .
F9 C42 F7 107.3(3) . .
F8 C42 F7 105.7(3) . .
F9 C42 C41 114.2(3) . .
F8 C42 C41 111.5(3) . .
F7 C42 C41 110.5(3) . .
N1 C43 C44 122.9(3) . .
N1 C43 H43 118.6 . .
C44 C43 H43 118.6 . .
C45 C44 C43 120.3(3) . .
C45 C44 H44 119.9 . .
C43 C44 H44 119.9 . .
C44 C45 C46 116.7(3) . .
C44 C45 C48 120.3(3) . .
C46 C45 C48 122.3(3) . .
C47 C46 C45 119.6(3) . .
C47 C46 H46 120.2 . .
C45 C46 H46 120.2 . .
N1 C47 C46 123.7(3) . .
N1 C47 H47 118.2 . .
C46 C47 H47 118.2 . .
C45 C48 C49 119.0(3) . .
C45 C48 C49 114.1(3) . 3_566
C49 C48 C49 89.6(3) . 3_566
C45 C48 H48 110.8 . .
C49 C48 H48 110.8 . .
C49 C48 H48 110.8 3_566 .
C50 C49 C48 119.9(3) . .
C50 C49 C48 112.6(3) . 3_566
C48 C49 C48 90.4(3) . 3_566
C50 C49 H49 110.8 . .
C48 C49 H49 110.8 . .
C48 C49 H49 110.8 3_566 .
C51 C50 C54 116.8(4) . .
C51 C50 C49 124.9(3) . .
C54 C50 C49 117.4(4) . .
C50 C51 C52 118.9(4) . .
C50 C51 H51 120.5 . .
C52 C51 H51 120.5 . .
N2 C52 C51 124.4(4) . .
N2 C52 H52 117.8 . .
C51 C52 H52 117.8 . .
N2 C53 C54 123.9(4) . .
N2 C53 H53 118.0 . .
C54 C53 H53 118.0 . .
C53 C54 C50 119.7(4) . .
C53 C54 H54 120.1 . .
C50 C54 H54 120.1 . .
O7 C55 H55A 109.5 . .
O7 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
O7 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
O2 Eu1 O6 145.81(9) . .
O2 Eu1 O3 87.33(10) . .
O6 Eu1 O3 103.72(10) . .
O2 Eu1 O5 142.85(9) . .
O6 Eu1 O5 70.98(9) . .
O3 Eu1 O5 73.84(10) . .
O2 Eu1 O1 70.60(9) . .
O6 Eu1 O1 143.44(9) . .
O3 Eu1 O1 73.64(10) . .
O5 Eu1 O1 73.43(9) . .
O2 Eu1 O4 73.80(10) . .
O6 Eu1 O4 79.75(9) . .
O3 Eu1 O4 70.04(9) . .
O5 Eu1 O4 125.67(9) . .
O1 Eu1 O4 129.51(9) . .
O2 Eu1 O7 97.88(10) . .
O6 Eu1 O7 92.50(10) . .
O3 Eu1 O7 142.69(10) . .
O5 Eu1 O7 80.35(10) . .
O1 Eu1 O7 73.44(10) . .
O4 Eu1 O7 146.85(9) . .
O2 Eu1 N1 77.64(9) . .
O6 Eu1 N1 74.35(9) . .
O3 Eu1 N1 143.24(10) . .
O5 Eu1 N1 134.95(9) . .
O1 Eu1 N1 129.53(9) . .
O4 Eu1 N1 73.58(9) . .
O7 Eu1 N1 73.29(9) . .
C43 N1 C47 116.4(3) . .
C43 N1 Eu1 123.2(2) . .
C47 N1 Eu1 120.3(2) . .
C53 N2 C52 115.5(4) . .
C11 O1 Eu1 135.4(3) . .
C13 O2 Eu1 131.9(3) . .
C25 O3 Eu1 136.3(3) . .
C27 O4 Eu1 128.7(2) . .
C39 O5 Eu1 138.0(2) . .
C41 O6 Eu1 134.6(2) . .
C55 O7 Eu1 124.2(3) . .
C55 O7 H7A 103(3) . .
Eu1 O7 H7A 126(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C6 1.361(7) .
C1 C2 1.425(6) .
C1 H1 0.9300 .
C2 C7 1.407(6) .
C2 C3 1.420(6) .
C3 C10 1.415(6) .
C3 C4 1.415(6) .
C4 C5 1.364(6) .
C4 H4 0.9300 .
C5 C6 1.399(7) .
C5 H5 0.9300 .
C6 H6 0.9300 .
C7 C8 1.363(6) .
C7 H7 0.9300 .
C8 C9 1.420(5) .
C8 H8 0.9300 .
C9 C10 1.371(6) .
C9 C11 1.495(5) .
C10 H10 0.9300 .
C11 O1 1.252(4) .
C11 C12 1.418(6) .
C12 C13 1.365(6) .
C12 H12 0.9300 .
C13 O2 1.274(5) .
C13 C14 1.518(6) .
C14 F3 1.308(7) .
C14 F1 1.324(5) .
C14 F2 1.325(7) .
C15 C16 1.352(8) .
C15 C20 1.395(9) .
C15 H15 0.9300 .
C16 C21 1.417(7) .
C16 C17 1.420(9) .
C17 C24 1.388(9) .
C17 C18 1.450(8) .
C18 C19 1.281(10) .
C18 H18 0.9300 .
C19 C20 1.410(10) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.373(7) .
C21 H21 0.9300 .
C22 C23 1.417(7) .
C22 C25 1.491(6) .
C23 C24 1.374(7) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 O3 1.260(5) .
C25 C26 1.404(6) .
C26 C27 1.384(6) .
C26 H26 0.9300 .
C27 O4 1.256(5) .
C27 C28 1.527(6) .
C28 F4 1.336(5) .
C28 F5 1.338(5) .
C28 F6 1.339(5) .
C29 C34 1.355(6) .
C29 C30 1.425(5) .
C29 H29 0.9300 .
C30 C35 1.405(6) .
C30 C31 1.418(5) .
C31 C32 1.410(5) .
C31 C38 1.416(5) .
C32 C33 1.367(5) .
C32 H32 0.9300 .
C33 C34 1.406(6) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 C36 1.358(6) .
C35 H35 0.9300 .
C36 C37 1.416(5) .
C36 H36 0.9300 .
C37 C38 1.377(5) .
C37 C39 1.492(5) .
C38 H38 0.9300 .
C39 O5 1.252(4) .
C39 C40 1.415(5) .
C40 C41 1.371(5) .
C40 H40 0.9300 .
C41 O6 1.269(4) .
C41 C42 1.528(5) .
C42 F9 1.320(4) .
C42 F8 1.332(5) .
C42 F7 1.344(5) .
C43 N1 1.341(5) .
C43 C44 1.390(5) .
C43 H43 0.9300 .
C44 C45 1.380(5) .
C44 H44 0.9300 .
C45 C46 1.388(5) .
C45 C48 1.511(5) .
C46 C47 1.383(5) .
C46 H46 0.9300 .
C47 N1 1.342(5) .
C47 H47 0.9300 .
C48 C49 1.551(5) .
C48 C49 1.603(5) 3_566
C48 H48 0.9800 .
C49 C50 1.509(5) .
C49 H49 0.9800 .
C50 C51 1.382(6) .
C50 C54 1.391(5) .
C51 C52 1.384(6) .
C51 H51 0.9300 .
C52 N2 1.339(5) .
C52 H52 0.9300 .
C53 N2 1.337(6) .
C53 C54 1.373(6) .
C53 H53 0.9300 .
C54 H54 0.9300 .
C55 O7 1.416(6) .
C55 H55A 0.9600 .
C55 H55B 0.9600 .
C55 H55C 0.9600 .
Eu1 O2 2.359(3) .
Eu1 O6 2.362(2) .
Eu1 O3 2.366(3) .
Eu1 O5 2.385(3) .
Eu1 O1 2.387(3) .
Eu1 O4 2.400(3) .
Eu1 O7 2.451(3) .
Eu1 N1 2.606(3) .
O7 H7A 0.86(5) .
