#------------------------------------------------------------------------------
#$Date: 2021-02-05 00:41:39 +0200 (Fri, 05 Feb 2021) $
#$Revision: 261556 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/76/7127634.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7127634
loop_
_publ_author_name
'Takemoto, Shin'
'Yoshii, Kaname'
'Yamano, Takahiro'
'Tsurusaki, Akihiro'
'Matsuzaka, Hiroyuki'
_publ_section_title
;
 Metal-metal multiple bond formation induced by σ-acceptor Lewis acid
 ligands.
;
_journal_issue                   7
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              923
_journal_page_last               926
_journal_paper_doi               10.1039/d0cc07278h
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C32 H42 Cl2 N2 Ru2 Zn'
_chemical_formula_weight         793.09
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2020-10-29 deposited with the CCDC.	2020-12-18 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.836(4)
_cell_length_b                   18.860(3)
_cell_length_c                   19.709(4)
_cell_measurement_reflns_used    41421
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.45
_cell_measurement_theta_min      3.08
_cell_volume                     6630(2)
_computing_cell_refinement       'rigaku process auto'
_computing_data_collection       'rigaku process auto'
_computing_data_reduction        'rigaku process auto'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'rigaku r-axis rapid'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_sigmaI/netI    0.0198
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            56481
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.08
_exptl_absorpt_coefficient_mu    1.802
_exptl_absorpt_correction_T_max  0.7146
_exptl_absorpt_correction_T_min  0.4661
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   abscor
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.589
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3200
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.459
_refine_diff_density_min         -0.411
_refine_diff_density_rms         0.074
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         7479
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0256
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0358P)²+2.8534P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0619
_refine_ls_wR_factor_ref         0.0666
_reflns_number_gt                6163
_reflns_number_total             7479
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d0cc07278h2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
'Adding full bibliography for 7127634--7127637.cif.'
_cod_original_sg_symbol_H-M      Pbca
_cod_database_code               7127634
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x, -y+1/2, z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, -z'
'-x, y-1/2, -z-1/2'
'x-1/2, y, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.259929(10) 0.156570(9) 0.372592(9) 0.03176(5) Uani 1 1 d . . .
Ru2 Ru 0.148868(10) 0.187890(9) 0.436450(9) 0.03358(6) Uani 1 1 d . . .
Zn1 Zn 0.219458(19) 0.288900(15) 0.373634(16) 0.04677(8) Uani 1 1 d . . .
Cl1 Cl 0.16153(6) 0.32109(4) 0.27738(5) 0.0770(3) Uani 1 1 d . . .
Cl2 Cl 0.28621(5) 0.36411(5) 0.43618(5) 0.0756(2) Uani 1 1 d . . .
N1 N 0.15138(11) 0.15232(10) 0.33744(10) 0.0364(4) Uani 1 1 d . . .
H1 H 0.1427 0.1890 0.3085 0.044 Uiso 1 1 calc R . .
N2 N 0.25431(11) 0.17377(10) 0.47554(9) 0.0367(4) Uani 1 1 d . . .
H2 H 0.2751 0.2164 0.4861 0.044 Uiso 1 1 calc R . .
C1 C 0.11181(13) 0.09100(12) 0.31511(12) 0.0394(5) Uani 1 1 d . . .
C2 C 0.12041(16) 0.02605(13) 0.34629(15) 0.0497(6) Uani 1 1 d . . .
H2A H 0.1544 0.0213 0.3818 0.060 Uiso 1 1 calc R . .
C3 C 0.07920(17) -0.03186(15) 0.32552(17) 0.0612(8) Uani 1 1 d . . .
H3 H 0.0857 -0.0753 0.3471 0.073 Uiso 1 1 calc R . .
C4 C 0.02870(18) -0.02606(18) 0.27320(18) 0.0714(9) Uani 1 1 d . . .
H4 H 0.0007 -0.0651 0.2595 0.086 Uiso 1 1 calc R . .
C5 C 0.02026(18) 0.03792(19) 0.24158(17) 0.0719(9) Uani 1 1 d . . .
H5 H -0.0141 0.0423 0.2063 0.086 Uiso 1 1 calc R . .
C6 C 0.06211(16) 0.09653(16) 0.26111(14) 0.0552(7) Uani 1 1 d . . .
H6 H 0.0569 0.1393 0.2381 0.066 Uiso 1 1 calc R . .
C7 C 0.27490(13) 0.12202(13) 0.52484(11) 0.0403(5) Uani 1 1 d . . .
C8 C 0.32091(19) 0.14103(18) 0.57820(15) 0.0618(8) Uani 1 1 d . . .
H8 H 0.3361 0.1880 0.5829 0.074 Uiso 1 1 calc R . .
C9 C 0.3446(2) 0.0912(2) 0.62458(17) 0.0814(11) Uani 1 1 d . . .
H9 H 0.3760 0.1044 0.6600 0.098 Uiso 1 1 calc R . .
C10 C 0.3217(2) 0.0217(2) 0.61837(17) 0.0780(10) Uani 1 1 d . . .
H10 H 0.3381 -0.0121 0.6493 0.094 Uiso 1 1 calc R . .
C11 C 0.27468(19) 0.00255(17) 0.56675(15) 0.0633(8) Uani 1 1 d . . .
H11 H 0.2586 -0.0442 0.5630 0.076 Uiso 1 1 calc R . .
C12 C 0.25093(16) 0.05236(14) 0.52009(13) 0.0501(6) Uani 1 1 d . . .
H12 H 0.2187 0.0390 0.4853 0.060 Uiso 1 1 calc R . .
C13 C 0.35363(15) 0.19763(14) 0.30626(14) 0.0493(6) Uani 1 1 d . . .
C14 C 0.38293(15) 0.16647(19) 0.36592(14) 0.0576(8) Uani 1 1 d . . .
C15 C 0.36438(16) 0.09292(17) 0.36585(14) 0.0561(7) Uani 1 1 d . . .
C16 C 0.32172(15) 0.07857(13) 0.30758(14) 0.0495(6) Uani 1 1 d . . .
C17 C 0.31363(15) 0.14386(13) 0.27139(12) 0.0443(6) Uani 1 1 d . . .
C18 C 0.3694(2) 0.27077(17) 0.2815(2) 0.0857(12) Uani 1 1 d . . .
H18A H 0.3721 0.3026 0.3195 0.103 Uiso 1 1 calc R . .
H18B H 0.3300 0.2857 0.2516 0.103 Uiso 1 1 calc R . .
H18C H 0.4163 0.2712 0.2576 0.103 Uiso 1 1 calc R . .
C19 C 0.4312(2) 0.2043(3) 0.4170(2) 0.1066(16) Uani 1 1 d . . .
H19A H 0.4823 0.1891 0.4120 0.128 Uiso 1 1 calc R . .
H19B H 0.4140 0.1933 0.4620 0.128 Uiso 1 1 calc R . .
H19C H 0.4281 0.2545 0.4097 0.128 Uiso 1 1 calc R . .
C20 C 0.3933(2) 0.0388(2) 0.4156(2) 0.1042(16) Uani 1 1 d . . .
H20A H 0.3567 0.0020 0.4213 0.125 Uiso 1 1 calc R . .
H20B H 0.4025 0.0612 0.4585 0.125 Uiso 1 1 calc R . .
H20C H 0.4391 0.0187 0.3987 0.125 Uiso 1 1 calc R . .
C21 C 0.2969(2) 0.00755(17) 0.2840(2) 0.0847(12) Uani 1 1 d . . .
H21A H 0.3351 -0.0129 0.2557 0.102 Uiso 1 1 calc R . .
H21B H 0.2513 0.0122 0.2585 0.102 Uiso 1 1 calc R . .
H21C H 0.2884 -0.0226 0.3225 0.102 Uiso 1 1 calc R . .
C22 C 0.2741(2) 0.1527(2) 0.20454(15) 0.0729(10) Uani 1 1 d . . .
H22A H 0.2554 0.2003 0.2008 0.087 Uiso 1 1 calc R . .
H22B H 0.2330 0.1199 0.2019 0.087 Uiso 1 1 calc R . .
H22C H 0.3086 0.1436 0.1682 0.087 Uiso 1 1 calc R . .
C23 C 0.03330(15) 0.16049(15) 0.47242(16) 0.0549(7) Uani 1 1 d . . .
C24 C 0.03078(15) 0.22454(16) 0.43365(14) 0.0533(7) Uani 1 1 d . . .
C25 C 0.07253(16) 0.27683(14) 0.46763(15) 0.0546(7) Uani 1 1 d . . .
C26 C 0.10451(15) 0.24443(16) 0.52612(14) 0.0536(7) Uani 1 1 d . . .
C27 C 0.07877(16) 0.17255(16) 0.52913(15) 0.0550(7) Uani 1 1 d . . .
C28 C -0.01186(19) 0.09504(18) 0.4578(2) 0.0884(12) Uani 1 1 d . . .
H28A H -0.0616 0.1008 0.4755 0.106 Uiso 1 1 calc R . .
H28B H 0.0115 0.0548 0.4789 0.106 Uiso 1 1 calc R . .
H28C H -0.0143 0.0876 0.4097 0.106 Uiso 1 1 calc R . .
C29 C -0.0137(2) 0.2362(2) 0.36990(18) 0.0862(12) Uani 1 1 d . . .
H29A H -0.0631 0.2523 0.3814 0.103 Uiso 1 1 calc R . .
H29B H -0.0171 0.1925 0.3451 0.103 Uiso 1 1 calc R . .
H29C H 0.0108 0.2713 0.3424 0.103 Uiso 1 1 calc R . .
C30 C 0.0747(2) 0.35468(16) 0.4507(2) 0.0849(12) Uani 1 1 d . . .
H30A H 0.0714 0.3607 0.4024 0.102 Uiso 1 1 calc R . .
H30B H 0.1209 0.3747 0.4667 0.102 Uiso 1 1 calc R . .
H30C H 0.0333 0.3782 0.4721 0.102 Uiso 1 1 calc R . .
C31 C 0.1516(2) 0.2797(2) 0.57935(18) 0.0838(12) Uani 1 1 d . . .
H31A H 0.1250 0.2800 0.6217 0.101 Uiso 1 1 calc R . .
H31B H 0.1622 0.3275 0.5658 0.101 Uiso 1 1 calc R . .
H31C H 0.1978 0.2541 0.5846 0.101 Uiso 1 1 calc R . .
C32 C 0.0915(2) 0.1220(2) 0.58721(18) 0.0894(12) Uani 1 1 d . . .
H32A H 0.1414 0.1282 0.6046 0.107 Uiso 1 1 calc R . .
H32B H 0.0854 0.0741 0.5715 0.107 Uiso 1 1 calc R . .
H32C H 0.0558 0.1315 0.6225 0.107 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 N2 107.00(8) . . ?
N1 Ru1 C14 156.78(9) . . ?
N2 Ru1 C14 95.39(9) . . ?
N1 Ru1 C15 138.43(10) . . ?
N2 Ru1 C15 100.67(9) . . ?
C14 Ru1 C15 37.59(12) . . ?
N1 Ru1 C17 95.68(9) . . ?
N2 Ru1 C17 157.20(9) . . ?
C14 Ru1 C17 61.81(10) . . ?
C15 Ru1 C17 61.77(10) . . ?
N1 Ru1 C16 104.16(9) . . ?
N2 Ru1 C16 133.75(9) . . ?
C14 Ru1 C16 62.11(11) . . ?
C15 Ru1 C16 36.68(11) . . ?
C17 Ru1 C16 37.35(9) . . ?
N1 Ru1 C13 120.97(9) . . ?
N2 Ru1 C13 123.56(9) . . ?
C14 Ru1 C13 36.92(11) . . ?
C15 Ru1 C13 61.96(10) . . ?
C17 Ru1 C13 36.85(10) . . ?
C16 Ru1 C13 61.97(9) . . ?
N1 Ru1 Ru2 54.17(5) . . ?
N2 Ru1 Ru2 53.75(5) . . ?
C14 Ru1 Ru2 145.53(8) . . ?
C15 Ru1 Ru2 148.20(7) . . ?
C17 Ru1 Ru2 147.63(7) . . ?
C16 Ru1 Ru2 149.35(7) . . ?
C13 Ru1 Ru2 145.38(7) . . ?
N1 Ru1 Zn1 77.21(5) . . ?
N2 Ru1 Zn1 80.05(6) . . ?
C14 Ru1 Zn1 101.28(9) . . ?
C15 Ru1 Zn1 138.85(9) . . ?
C17 Ru1 Zn1 103.31(7) . . ?
C16 Ru1 Zn1 140.52(7) . . ?
C13 Ru1 Zn1 83.16(7) . . ?
Ru2 Ru1 Zn1 62.226(9) . . ?
N2 Ru2 N1 107.05(8) . . ?
N2 Ru2 C24 157.12(9) . . ?
N1 Ru2 C24 95.65(9) . . ?
N2 Ru2 C26 95.20(9) . . ?
N1 Ru2 C26 156.99(9) . . ?
C24 Ru2 C26 61.94(10) . . ?
N2 Ru2 C27 100.93(10) . . ?
N1 Ru2 C27 138.04(10) . . ?
C24 Ru2 C27 61.89(11) . . ?
C26 Ru2 C27 37.62(10) . . ?
N2 Ru2 C23 134.06(10) . . ?
N1 Ru2 C23 104.13(10) . . ?
C24 Ru2 C23 37.42(11) . . ?
C26 Ru2 C23 61.90(10) . . ?
C27 Ru2 C23 36.47(11) . . ?
N2 Ru2 C25 123.39(10) . . ?
N1 Ru2 C25 120.97(10) . . ?
C24 Ru2 C25 36.70(10) . . ?
C26 Ru2 C25 37.25(11) . . ?
C27 Ru2 C25 62.19(11) . . ?
C23 Ru2 C25 61.83(10) . . ?
N2 Ru2 Ru1 54.04(5) . . ?
N1 Ru2 Ru1 53.93(5) . . ?
C24 Ru2 Ru1 147.20(7) . . ?
C26 Ru2 Ru1 145.74(7) . . ?
C27 Ru2 Ru1 148.47(8) . . ?
C23 Ru2 Ru1 149.48(7) . . ?
C25 Ru2 Ru1 145.16(7) . . ?
N2 Ru2 Zn1 80.19(6) . . ?
N1 Ru2 Zn1 77.13(6) . . ?
C24 Ru2 Zn1 102.70(8) . . ?
C26 Ru2 Zn1 101.58(8) . . ?
C27 Ru2 Zn1 139.16(8) . . ?
C23 Ru2 Zn1 139.99(8) . . ?
C25 Ru2 Zn1 82.90(7) . . ?
Ru1 Ru2 Zn1 62.252(14) . . ?
Cl2 Zn1 Cl1 122.84(4) . . ?
Cl2 Zn1 Ru2 117.58(3) . . ?
Cl1 Zn1 Ru2 112.22(3) . . ?
Cl2 Zn1 Ru1 117.92(3) . . ?
Cl1 Zn1 Ru1 112.41(3) . . ?
Ru2 Zn1 Ru1 55.522(13) . . ?
C1 N1 Ru1 126.99(15) . . ?
C1 N1 Ru2 123.04(15) . . ?
Ru1 N1 Ru2 71.91(6) . . ?
C7 N2 Ru2 125.56(15) . . ?
C7 N2 Ru1 123.49(15) . . ?
Ru2 N2 Ru1 72.21(6) . . ?
C2 C1 C6 118.6(2) . . ?
C2 C1 N1 121.9(2) . . ?
C6 C1 N1 119.5(2) . . ?
C1 C2 C3 120.8(3) . . ?
C2 C3 C4 120.6(3) . . ?
C5 C4 C3 119.0(3) . . ?
C4 C5 C6 121.2(3) . . ?
C1 C6 C5 119.7(3) . . ?
C12 C7 C8 118.8(2) . . ?
C12 C7 N2 121.6(2) . . ?
C8 C7 N2 119.6(2) . . ?
C7 C8 C9 120.7(3) . . ?
C10 C9 C8 119.9(3) . . ?
C11 C10 C9 120.0(3) . . ?
C10 C11 C12 120.2(3) . . ?
C7 C12 C11 120.4(3) . . ?
C14 C13 C17 107.0(2) . . ?
C14 C13 C18 125.9(3) . . ?
C17 C13 C18 126.8(3) . . ?
C14 C13 Ru1 69.50(15) . . ?
C17 C13 Ru1 70.31(14) . . ?
C18 C13 Ru1 130.3(2) . . ?
C13 C14 C15 108.5(2) . . ?
C13 C14 C19 124.8(3) . . ?
C15 C14 C19 126.5(3) . . ?
C13 C14 Ru1 73.57(15) . . ?
C15 C14 Ru1 71.75(16) . . ?
C19 C14 Ru1 124.7(2) . . ?
C16 C15 C14 108.3(2) . . ?
C16 C15 C20 126.0(3) . . ?
C14 C15 C20 125.4(3) . . ?
C16 C15 Ru1 72.45(15) . . ?
C14 C15 Ru1 70.66(16) . . ?
C20 C15 Ru1 127.9(2) . . ?
C15 C16 C17 107.3(2) . . ?
C15 C16 C21 126.2(3) . . ?
C17 C16 C21 126.2(3) . . ?
C15 C16 Ru1 70.86(15) . . ?
C17 C16 Ru1 70.75(14) . . ?
C21 C16 Ru1 128.7(2) . . ?
C13 C17 C16 108.9(2) . . ?
C13 C17 C22 125.5(3) . . ?
C16 C17 C22 125.4(3) . . ?
C13 C17 Ru1 72.85(14) . . ?
C16 C17 Ru1 71.90(14) . . ?
C22 C17 Ru1 124.8(2) . . ?
C24 C23 C27 107.9(2) . . ?
C24 C23 C28 125.1(3) . . ?
C27 C23 C28 126.7(3) . . ?
C24 C23 Ru2 70.42(15) . . ?
C27 C23 Ru2 71.46(15) . . ?
C28 C23 Ru2 128.5(2) . . ?
C25 C24 C23 108.8(3) . . ?
C25 C24 C29 125.1(3) . . ?
C23 C24 C29 126.0(3) . . ?
C25 C24 Ru2 72.77(16) . . ?
C23 C24 Ru2 72.16(15) . . ?
C29 C24 Ru2 124.6(2) . . ?
C24 C25 C26 107.3(2) . . ?
C24 C25 C30 126.3(3) . . ?
C26 C25 C30 126.0(3) . . ?
C24 C25 Ru2 70.53(15) . . ?
C26 C25 Ru2 70.01(15) . . ?
C30 C25 Ru2 130.6(2) . . ?
C27 C26 C25 108.1(3) . . ?
C27 C26 C31 124.8(3) . . ?
C25 C26 C31 126.9(3) . . ?
C27 C26 Ru2 72.02(15) . . ?
C25 C26 Ru2 72.74(15) . . ?
C31 C26 Ru2 124.9(2) . . ?
C26 C27 C23 107.8(3) . . ?
C26 C27 C32 125.6(3) . . ?
C23 C27 C32 126.3(3) . . ?
C26 C27 Ru2 70.36(14) . . ?
C23 C27 Ru2 72.07(16) . . ?
C32 C27 Ru2 128.2(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.0579(19) . ?
Ru1 N2 2.0572(19) . ?
Ru1 C14 2.206(3) . ?
Ru1 C15 2.220(3) . ?
Ru1 C17 2.226(2) . ?
Ru1 C16 2.241(2) . ?
Ru1 C13 2.259(2) . ?
Ru1 Ru2 2.4201(5) . ?
Ru1 Zn1 2.5981(5) . ?
Ru2 N2 2.050(2) . ?
Ru2 N1 2.0640(19) . ?
Ru2 C24 2.217(3) . ?
Ru2 C26 2.210(3) . ?
Ru2 C27 2.232(3) . ?
Ru2 C23 2.240(3) . ?
Ru2 C25 2.246(3) . ?
Ru2 Zn1 2.5975(5) . ?
Zn1 Cl2 2.2246(9) . ?
Zn1 Cl1 2.2438(9) . ?
N1 C1 1.425(3) . ?
N2 C7 1.425(3) . ?
C1 C2 1.379(3) . ?
C1 C6 1.389(3) . ?
C2 C3 1.379(4) . ?
C3 C4 1.374(4) . ?
C4 C5 1.366(5) . ?
C5 C6 1.388(4) . ?
C7 C12 1.385(4) . ?
C7 C8 1.381(3) . ?
C8 C9 1.377(4) . ?
C9 C10 1.378(5) . ?
C10 C11 1.367(4) . ?
C11 C12 1.381(4) . ?
C13 C14 1.415(4) . ?
C13 C17 1.418(4) . ?
C13 C18 1.490(4) . ?
C14 C15 1.426(4) . ?
C14 C19 1.505(4) . ?
C15 C16 1.404(4) . ?
C15 C20 1.506(4) . ?
C16 C17 1.430(4) . ?
C16 C21 1.485(4) . ?
C17 C22 1.504(4) . ?
C23 C24 1.430(4) . ?
C23 C27 1.399(4) . ?
C23 C28 1.502(4) . ?
C24 C25 1.406(4) . ?
C24 C29 1.502(4) . ?
C25 C26 1.424(4) . ?
C25 C30 1.506(4) . ?
C26 C27 1.433(4) . ?
C26 C31 1.499(4) . ?
C27 C32 1.507(4) . ?
