#------------------------------------------------------------------------------
#$Date: 2022-01-01 01:00:11 +0200 (Sat, 01 Jan 2022) $
#$Revision: 271656 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/12/94/7129484.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7129484
loop_
_publ_author_name
'Lu, Hui'
'Chen, Bin'
'Li, Yu'
'Shi, Jiye'
'Li, Jiang'
'Wang, Lihua'
'Luo, Shihua'
'Fan, Chunhai'
'Shen, Jianlei'
'Chen, Jing'
_publ_section_title
;
 Benzyl-rich ligand engineering of the photostability of atomically
 precise gold nanoclusters
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/D1CC06467C
_journal_year                    2022
_chemical_formula_sum            'C164 H142 Au8 P8'
_chemical_formula_weight         3936.26
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-11-16 deposited with the CCDC.	2021-12-30 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.922(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   24.4379(19)
_cell_length_b                   17.5485(14)
_cell_length_c                   39.122(3)
_cell_measurement_reflns_used    9118
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      59.35
_cell_measurement_theta_min      4.50
_cell_volume                     16353(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34138
_diffrn_reflns_av_R_equivalents  0.0424
_diffrn_reflns_av_unetI/netI     0.0383
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       49
_diffrn_reflns_limit_l_min       -49
_diffrn_reflns_number            157524
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         58.999
_diffrn_reflns_theta_min         2.774
_exptl_absorpt_coefficient_mu    9.740
_exptl_absorpt_correction_T_max  0.752
_exptl_absorpt_correction_T_min  0.467
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_description       block
_exptl_crystal_F_000             7512
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.120
_refine_diff_density_max         4.474
_refine_diff_density_min         -3.295
_refine_diff_density_rms         0.210
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1748
_refine_ls_number_reflns         35702
_refine_ls_number_restraints     279
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0581
_refine_ls_R_factor_gt           0.0521
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0843P)²+139.7594P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1619
_refine_ls_wR_factor_ref         0.1669
_reflns_Friedel_coverage         0.000
_reflns_number_gt                30456
_reflns_number_total             35702
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1cc06467c2.cif
_cod_data_source_block           platon_sq
_cod_original_cell_volume        16352(2)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7129484
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.234
_shelx_estimated_absorpt_t_max   0.388
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.95143(2) -0.00277(2) 0.72877(2) 0.03403(8) Uani 1 1 d . . . . .
Au2 Au 1.04938(2) 0.02253(2) 0.77195(2) 0.03336(7) Uani 1 1 d . . . . .
Au3 Au 1.01102(2) 0.12813(2) 0.71560(2) 0.03688(8) Uani 1 1 d . . . . .
Au4 Au 1.04806(2) -0.00609(2) 0.70015(2) 0.03662(8) Uani 1 1 d . . . . .
Au5 Au 0.95296(2) 0.02771(2) 0.80059(2) 0.03672(8) Uani 1 1 d . . . . .
Au6 Au 0.98876(2) -0.10749(2) 0.78523(2) 0.03600(8) Uani 1 1 d . . . . .
Au7 Au 1.08492(2) 0.12633(2) 0.66069(2) 0.04292(9) Uani 1 1 d . . . . .
Au8 Au 0.91334(2) -0.10207(2) 0.83971(2) 0.04796(10) Uani 1 1 d . . . . .
P1 P 1.02161(7) -0.23083(11) 0.78324(5) 0.0369(4) Uani 1 1 d . . . . .
P2 P 1.08174(8) -0.11932(12) 0.68266(5) 0.0391(4) Uani 1 1 d . . . . .
P3 P 0.91942(8) 0.14166(12) 0.81800(5) 0.0398(4) Uani 1 1 d . . . . .
P4 P 0.97824(8) 0.25211(11) 0.71680(5) 0.0396(4) Uani 1 1 d . . . . .
P5 P 1.13786(7) 0.04225(12) 0.80726(5) 0.0388(4) Uani 1 1 d . . . . .
P6 P 1.17312(8) 0.16722(14) 0.68695(5) 0.0448(4) Uani 1 1 d . . . . .
P7 P 0.86330(8) -0.02679(14) 0.69412(5) 0.0455(5) Uani 1 1 d . . . . .
P8 P 0.82505(9) -0.14176(18) 0.81300(6) 0.0591(6) Uani 1 1 d . . . . .
C1 C 1.0953(3) -0.2308(5) 0.7792(2) 0.0429(17) Uani 1 1 d . . . . .
H1A H 1.1196 -0.2183 0.8023 0.052 Uiso 1 1 calc R U . . .
H1B H 1.1052 -0.2827 0.7728 0.052 Uiso 1 1 calc R U . . .
C2 C 1.1076(3) -0.1743(5) 0.7519(2) 0.0422(16) Uani 1 1 d . . . . .
H2A H 1.0972 -0.1224 0.7580 0.051 Uiso 1 1 calc R U . . .
H2B H 1.1485 -0.1745 0.7529 0.051 Uiso 1 1 calc R U . . .
C3 C 1.0767(3) -0.1921(5) 0.7149(2) 0.0435(17) Uani 1 1 d . . . . .
H3A H 1.0365 -0.2001 0.7148 0.052 Uiso 1 1 calc R U . . .
H3B H 1.0914 -0.2406 0.7076 0.052 Uiso 1 1 calc R U . . .
C4 C 0.9817(3) -0.2920(5) 0.7490(2) 0.0424(16) Uani 1 1 d . . . . .
C5 C 1.0061(4) -0.3489(6) 0.7325(3) 0.060(2) Uani 1 1 d . . . . .
H5 H 1.0458 -0.3539 0.7374 0.072 Uiso 1 1 calc R U . . .
C6 C 0.9725(6) -0.3986(8) 0.7088(3) 0.085(4) Uani 1 1 d . . . . .
H6 H 0.9894 -0.4346 0.6963 0.102 Uiso 1 1 calc R U . . .
C7 C 0.9162(6) -0.3954(10) 0.7038(3) 0.101(5) Uani 1 1 d . . . . .
H7 H 0.8937 -0.4334 0.6902 0.121 Uiso 1 1 calc R U . . .
C8 C 0.8902(5) -0.3356(10) 0.7188(3) 0.094(5) Uani 1 1 d . . . . .
H8 H 0.8505 -0.3303 0.7133 0.112 Uiso 1 1 calc R U . . .
C9 C 0.9240(4) -0.2846(7) 0.7418(2) 0.059(2) Uani 1 1 d . . . . .
H9 H 0.9072 -0.2450 0.7525 0.071 Uiso 1 1 calc R U . . .
C10 C 1.0245(3) -0.2873(5) 0.8226(2) 0.0422(16) Uani 1 1 d . . . . .
C11 C 1.0158(5) -0.3657(6) 0.8218(3) 0.063(2) Uani 1 1 d . . . . .
H11 H 1.0067 -0.3912 0.7999 0.075 Uiso 1 1 calc R U . . .
C12 C 1.0199(6) -0.4065(6) 0.8517(3) 0.079(3) Uani 1 1 d . . . . .
H12 H 1.0144 -0.4601 0.8507 0.094 Uiso 1 1 calc R U . . .
C13 C 1.0323(6) -0.3692(6) 0.8839(3) 0.075(3) Uani 1 1 d . . . . .
H13 H 1.0361 -0.3975 0.9050 0.090 Uiso 1 1 calc R U . . .
C14 C 1.0390(6) -0.2919(6) 0.8852(3) 0.080(4) Uani 1 1 d . . . . .
H14 H 1.0465 -0.2663 0.9072 0.096 Uiso 1 1 calc R U . . .
C15 C 1.0347(5) -0.2510(6) 0.8544(3) 0.062(2) Uani 1 1 d . . . . .
H15 H 1.0390 -0.1972 0.8554 0.074 Uiso 1 1 calc R U . . .
C16 C 1.1537(3) -0.1229(5) 0.6765(2) 0.0447(17) Uani 1 1 d . . . . .
C17 C 1.1840(4) -0.1899(6) 0.6804(2) 0.054(2) Uani 1 1 d . . . . .
H17 H 1.1696 -0.2344 0.6890 0.065 Uiso 1 1 calc R U . . .
C18 C 1.2365(4) -0.1916(6) 0.6714(3) 0.062(3) Uani 1 1 d . . . . .
H18 H 1.2577 -0.2374 0.6740 0.075 Uiso 1 1 calc R U . . .
C19 C 1.2575(4) -0.1264(7) 0.6585(3) 0.061(3) Uani 1 1 d . . . . .
H19 H 1.2924 -0.1282 0.6516 0.074 Uiso 1 1 calc R U . . .
C20 C 1.2275(4) -0.0589(6) 0.6559(3) 0.060(2) Uani 1 1 d . . . . .
H20 H 1.2427 -0.0136 0.6484 0.072 Uiso 1 1 calc R U . . .
C21 C 1.1746(3) -0.0578(5) 0.6642(2) 0.0487(18) Uani 1 1 d . . . . .
H21 H 1.1531 -0.0122 0.6615 0.058 Uiso 1 1 calc R U . . .
C22 C 1.0424(4) -0.1586(5) 0.6413(2) 0.0509(19) Uani 1 1 d . . . . .
C23 C 1.0481(5) -0.2360(7) 0.6334(3) 0.070(3) Uani 1 1 d . . . . .
H23 H 1.0710 -0.2691 0.6498 0.084 Uiso 1 1 calc R U . . .
C24 C 1.0193(6) -0.2630(9) 0.6010(4) 0.092(4) Uani 1 1 d . . . . .
H24 H 1.0230 -0.3150 0.5952 0.110 Uiso 1 1 calc R U . . .
C25 C 0.9859(7) -0.2163(10) 0.5774(4) 0.103(5) Uani 1 1 d . U . . .
H25 H 0.9668 -0.2363 0.5554 0.124 Uiso 1 1 calc R U . . .
C26 C 0.9795(7) -0.1422(9) 0.5847(3) 0.101(5) Uani 1 1 d . U . . .
H26 H 0.9561 -0.1105 0.5678 0.121 Uiso 1 1 calc R U . . .
C27 C 1.0077(5) -0.1117(8) 0.6172(3) 0.078(3) Uani 1 1 d . . . . .
H27 H 1.0030 -0.0596 0.6226 0.093 Uiso 1 1 calc R U . . .
C28 C 0.9242(3) 0.2155(5) 0.7856(2) 0.0441(17) Uani 1 1 d . . . . .
H28A H 0.9091 0.2638 0.7929 0.053 Uiso 1 1 calc R U . . .
H28B H 0.9643 0.2240 0.7856 0.053 Uiso 1 1 calc R U . . .
C29 C 0.8926(3) 0.1961(5) 0.7483(2) 0.0439(17) Uani 1 1 d . . . . .
H29A H 0.8517 0.1957 0.7473 0.053 Uiso 1 1 calc R U . . .
H29B H 0.9034 0.1444 0.7422 0.053 Uiso 1 1 calc R U . . .
C30 C 0.9049(3) 0.2531(5) 0.7213(2) 0.0437(17) Uani 1 1 d . . . . .
H30A H 0.8956 0.3050 0.7282 0.052 Uiso 1 1 calc R U . . .
H30B H 0.8800 0.2417 0.6982 0.052 Uiso 1 1 calc R U . . .
C31 C 0.8478(3) 0.1448(5) 0.8244(2) 0.0434(17) Uani 1 1 d . . . . .
C32 C 0.8167(4) 0.2125(6) 0.8204(2) 0.055(2) Uani 1 1 d . . . . .
H32 H 0.8312 0.2571 0.8119 0.066 Uiso 1 1 calc R U . . .
C33 C 0.7644(4) 0.2145(6) 0.8291(3) 0.061(2) Uani 1 1 d . . . . .
H33 H 0.7430 0.2601 0.8259 0.073 Uiso 1 1 calc R U . . .
C34 C 0.7436(4) 0.1503(7) 0.8422(3) 0.062(3) Uani 1 1 d . . . . .
H34 H 0.7088 0.1526 0.8492 0.075 Uiso 1 1 calc R U . . .
C35 C 0.7735(4) 0.0819(7) 0.8451(3) 0.061(2) Uani 1 1 d . . . . .
H35 H 0.7583 0.0370 0.8529 0.073 Uiso 1 1 calc R U . . .
C36 C 0.8259(3) 0.0798(6) 0.8366(2) 0.052(2) Uani 1 1 d . . . . .
H36 H 0.8468 0.0337 0.8391 0.062 Uiso 1 1 calc R U . . .
C37 C 0.9588(4) 0.1831(5) 0.8590(2) 0.0486(19) Uani 1 1 d . . . . .
C38 C 0.9534(4) 0.2597(7) 0.8666(3) 0.065(3) Uani 1 1 d . . . . .
H38 H 0.9305 0.2921 0.8499 0.078 Uiso 1 1 calc R U . . .
C39 C 0.9814(5) 0.2884(8) 0.8984(3) 0.077(3) Uani 1 1 d . . . . .
H39 H 0.9779 0.3409 0.9035 0.092 Uiso 1 1 calc R U . . .
C40 C 1.0146(6) 0.2412(9) 0.9229(3) 0.091(4) Uani 1 1 d . . . . .
H40 H 1.0337 0.2616 0.9449 0.109 Uiso 1 1 calc R U . . .
C41 C 1.0201(6) 0.1672(8) 0.9161(3) 0.083(3) Uani 1 1 d . . . . .
H41 H 1.0429 0.1354 0.9332 0.099 Uiso 1 1 calc R U . . .
C42 C 0.9918(5) 0.1360(7) 0.8833(3) 0.064(3) Uani 1 1 d . . . . .
H42 H 0.9957 0.0836 0.8782 0.077 Uiso 1 1 calc R U . . .
C43 C 1.0185(3) 0.3133(5) 0.7506(2) 0.0468(18) Uani 1 1 d . . . . .
C44 C 0.9939(4) 0.3715(6) 0.7669(3) 0.061(2) Uani 1 1 d . . . . .
H44 H 0.9542 0.3766 0.7620 0.073 Uiso 1 1 calc R U . . .
C45 C 1.0279(6) 0.4216(7) 0.7902(3) 0.084(4) Uani 1 1 d . . . . .
H45 H 1.0108 0.4585 0.8022 0.100 Uiso 1 1 calc R U . . .
C46 C 1.0841(6) 0.4186(9) 0.7958(3) 0.092(4) Uani 1 1 d . . . . .
H46 H 1.1066 0.4560 0.8100 0.110 Uiso 1 1 calc R U . . .
C47 C 1.1098(5) 0.3585(9) 0.7803(3) 0.089(4) Uani 1 1 d . . . . .
H47 H 1.1495 0.3538 0.7853 0.106 Uiso 1 1 calc R U . . .
C48 C 1.0766(4) 0.3073(7) 0.7580(2) 0.061(2) Uani 1 1 d . . . . .
H48 H 1.0937 0.2675 0.7477 0.073 Uiso 1 1 calc R U . . .
C49 C 0.9750(3) 0.3072(5) 0.6769(2) 0.0421(16) Uani 1 1 d . . . . .
C50 C 0.9868(4) 0.3858(5) 0.6774(3) 0.056(2) Uani 1 1 d . . . . .
H50 H 0.9972 0.4118 0.6992 0.067 Uiso 1 1 calc R U . . .
C51 C 0.9835(5) 0.4249(6) 0.6472(3) 0.070(3) Uani 1 1 d . . . . .
H51 H 0.9922 0.4777 0.6480 0.084 Uiso 1 1 calc R U . . .
C52 C 0.9675(5) 0.3887(7) 0.6152(3) 0.074(3) Uani 1 1 d . . . . .
H52 H 0.9640 0.4167 0.5941 0.089 Uiso 1 1 calc R U . . .
C53 C 0.9567(6) 0.3112(7) 0.6143(3) 0.077(3) Uani 1 1 d . . . . .
H53 H 0.9464 0.2857 0.5924 0.092 Uiso 1 1 calc R U . . .
C54 C 0.9608(5) 0.2710(5) 0.6450(2) 0.058(2) Uani 1 1 d . . . . .
H54 H 0.9537 0.2177 0.6442 0.070 Uiso 1 1 calc R U . . .
C55 C 1.1898(3) 0.0596(6) 0.7812(2) 0.052(2) Uani 1 1 d . . . . .
H55A H 1.2258 0.0746 0.7971 0.063 Uiso 1 1 calc R U . . .
H55B H 1.1963 0.0119 0.7693 0.063 Uiso 1 1 calc R U . . .
C56 C 1.1718(3) 0.1213(5) 0.7541(2) 0.0472(18) Uani 1 1 d . . . . .
H56A H 1.1781 0.1720 0.7655 0.057 Uiso 1 1 calc R U . . .
H56B H 1.1312 0.1161 0.7435 0.057 Uiso 1 1 calc R U . . .
C57 C 1.2053(3) 0.1149(6) 0.7257(2) 0.052(2) Uani 1 1 d . . . . .
H57A H 1.2083 0.0606 0.7195 0.062 Uiso 1 1 calc R U . . .
H57B H 1.2437 0.1346 0.7349 0.062 Uiso 1 1 calc R U . . .
C58 C 1.1706(3) -0.0375(5) 0.8345(2) 0.0474(18) Uani 1 1 d . . . . .
C59 C 1.2290(4) -0.0511(8) 0.8406(3) 0.072(3) Uani 1 1 d . . . . .
H59 H 1.2525 -0.0199 0.8301 0.086 Uiso 1 1 calc R U . . .
C60 C 1.2514(5) -0.1119(8) 0.8626(3) 0.082(4) Uani 1 1 d . . . . .
H60 H 1.2906 -0.1213 0.8669 0.098 Uiso 1 1 calc R U . . .
C61 C 1.2188(5) -0.1577(7) 0.8779(3) 0.072(3) Uani 1 1 d . . . . .
H61 H 1.2350 -0.1989 0.8924 0.087 Uiso 1 1 calc R U . . .
C62 C 1.1636(5) -0.1441(8) 0.8721(3) 0.081(3) Uani 1 1 d . . . . .
H62 H 1.1407 -0.1754 0.8830 0.098 Uiso 1 1 calc R U . . .
C63 C 1.1388(4) -0.0840(6) 0.8500(3) 0.066(3) Uani 1 1 d . . . . .
H63 H 1.0995 -0.0759 0.8458 0.079 Uiso 1 1 calc R U . . .
C64 C 1.1424(3) 0.1218(5) 0.8378(2) 0.0427(16) Uani 1 1 d . . . . .
C65 C 1.1885(4) 0.1304(6) 0.8661(3) 0.063(2) Uani 1 1 d . . . . .
H65 H 1.2179 0.0938 0.8699 0.076 Uiso 1 1 calc R U . . .
C66 C 1.1913(5) 0.1910(7) 0.8881(3) 0.079(3) Uani 1 1 d . . . . .
H66 H 1.2227 0.1965 0.9072 0.095 Uiso 1 1 calc R U . . .
C67 C 1.1489(5) 0.2446(6) 0.8828(3) 0.069(3) Uani 1 1 d . . . . .
H67 H 1.1512 0.2866 0.8984 0.082 Uiso 1 1 calc R U . . .
C68 C 1.1033(5) 0.2374(6) 0.8551(3) 0.071(3) Uani 1 1 d . . . . .
H68 H 1.0740 0.2742 0.8514 0.085 Uiso 1 1 calc R U . . .
C69 C 1.1006(4) 0.1762(6) 0.8327(3) 0.059(2) Uani 1 1 d . . . . .
H69 H 1.0694 0.1714 0.8134 0.071 Uiso 1 1 calc R U . . .
C70 C 1.1767(4) 0.2673(6) 0.6998(2) 0.052(2) Uani 1 1 d . . . . .
C71 C 1.2205(4) 0.2953(6) 0.7258(3) 0.058(2) Uani 1 1 d . . . . .
H71 H 1.2490 0.2618 0.7377 0.069 Uiso 1 1 calc R U . . .
C72 C 1.2225(4) 0.3712(7) 0.7343(3) 0.067(3) Uani 1 1 d . . . . .
H72 H 1.2523 0.3896 0.7524 0.080 Uiso 1 1 calc R U . . .
C73 C 1.1818(5) 0.4219(7) 0.7170(3) 0.074(3) Uani 1 1 d . . . . .
H73 H 1.1842 0.4746 0.7228 0.088 Uiso 1 1 calc R U . . .
C74 C 1.1388(5) 0.3949(7) 0.6918(3) 0.076(3) Uani 1 1 d . . . . .
H74 H 1.1107 0.4290 0.6799 0.091 Uiso 1 1 calc R U . . .
C75 C 1.1353(4) 0.3173(7) 0.6832(3) 0.063(2) Uani 1 1 d . . . . .
H75 H 1.1045 0.2989 0.6658 0.076 Uiso 1 1 calc R U . . .
C76 C 1.2211(3) 0.1563(5) 0.6577(2) 0.0439(17) Uani 1 1 d . . . . .
C77 C 1.2795(3) 0.1586(6) 0.6707(2) 0.056(2) Uani 1 1 d . . . . .
H77 H 1.2945 0.1665 0.6950 0.067 Uiso 1 1 calc R U . . .
C78 C 1.3155(4) 0.1494(6) 0.6479(3) 0.060(2) Uani 1 1 d . . . . .
H78 H 1.3550 0.1516 0.6566 0.072 Uiso 1 1 calc R U . . .
C79 C 1.2938(4) 0.1371(6) 0.6125(3) 0.059(2) Uani 1 1 d . . . . .
H79 H 1.3183 0.1302 0.5970 0.071 Uiso 1 1 calc R U . . .
C80 C 1.2360(4) 0.1349(6) 0.5997(2) 0.059(2) Uani 1 1 d . . . . .
H80 H 1.2213 0.1271 0.5754 0.070 Uiso 1 1 calc R U . . .
C81 C 1.2000(4) 0.1436(6) 0.6218(2) 0.052(2) Uani 1 1 d . . . . .
H81 H 1.1606 0.1412 0.6127 0.062 Uiso 1 1 calc R U . . .
C82 C 0.8127(5) -0.0450(9) 0.7204(3) 0.087(4) Uani 1 1 d D U . . .
H82A H 0.8052 0.0035 0.7314 0.105 Uiso 1 1 calc R U . . .
H82B H 0.7771 -0.0611 0.7045 0.105 Uiso 1 1 calc R U . . .
C83 C 0.8280(4) -0.1009(7) 0.7472(3) 0.072(3) Uani 1 1 d D U . . .
H83A H 0.8685 -0.0965 0.7585 0.086 Uiso 1 1 calc R U . . .
H83B H 0.8210 -0.1527 0.7372 0.086 Uiso 1 1 calc R U . . .
C84 C 0.7910(4) -0.0865(9) 0.7754(2) 0.087(4) Uani 1 1 d D . . . .
H84A H 0.7519 -0.1039 0.7664 0.105 Uiso 1 1 calc R U . . .
H84B H 0.7905 -0.0317 0.7815 0.105 Uiso 1 1 calc R U . . .
C85 C 0.8280(4) 0.0527(6) 0.6679(2) 0.058(2) Uani 1 1 d . . . . .
C86 C 0.7691(5) 0.0602(9) 0.6617(4) 0.087(4) Uani 1 1 d . U . . .
H86 H 0.7468 0.0260 0.6716 0.104 Uiso 1 1 calc R U . . .
C87 C 0.7447(6) 0.1221(10) 0.6394(4) 0.107(5) Uani 1 1 d . U . . .
H87 H 0.7050 0.1280 0.6338 0.129 Uiso 1 1 calc R U . . .
C88 C 0.7770(7) 0.1730(9) 0.6260(4) 0.101(5) Uani 1 1 d . . . . .
H88 H 0.7602 0.2149 0.6122 0.122 Uiso 1 1 calc R U . . .
C89 C 0.8317(6) 0.1630(8) 0.6325(4) 0.102(5) Uani 1 1 d . . . . .
H89 H 0.8540 0.1975 0.6227 0.123 Uiso 1 1 calc R U . . .
C90 C 0.8585(5) 0.1027(7) 0.6538(3) 0.079(3) Uani 1 1 d . . . . .
H90 H 0.8981 0.0973 0.6581 0.095 Uiso 1 1 calc R U . . .
C91 C 0.8600(3) -0.1055(5) 0.6632(2) 0.0453(17) Uani 1 1 d . . . . .
C92 C 0.8143(4) -0.1139(6) 0.6347(2) 0.059(2) Uani 1 1 d . . . . .
H92 H 0.7846 -0.0777 0.6309 0.070 Uiso 1 1 calc R U . . .
C93 C 0.8124(5) -0.1743(7) 0.6123(3) 0.072(3) Uani 1 1 d . . . . .
H93 H 0.7813 -0.1798 0.5929 0.086 Uiso 1 1 calc R U . . .
C94 C 0.8552(5) -0.2272(6) 0.6176(3) 0.070(3) Uani 1 1 d . . . . .
H94 H 0.8535 -0.2689 0.6019 0.084 Uiso 1 1 calc R U . . .
C95 C 0.9003(5) -0.2199(6) 0.6454(4) 0.080(3) Uani 1 1 d . . . . .
H95 H 0.9295 -0.2567 0.6494 0.096 Uiso 1 1 calc R U . . .
C96 C 0.9025(4) -0.1580(6) 0.6676(3) 0.067(3) Uani 1 1 d . . . . .
H96 H 0.9343 -0.1517 0.6864 0.081 Uiso 1 1 calc R U . . .
C97 C 0.7772(3) -0.1345(6) 0.8426(2) 0.050(2) Uani 1 1 d . . . . .
C98 C 0.7194(4) -0.1359(6) 0.8300(3) 0.059(2) Uani 1 1 d . . . . .
H98 H 0.7041 -0.1408 0.8055 0.070 Uiso 1 1 calc R U . . .
C99 C 0.6838(4) -0.1302(7) 0.8531(3) 0.064(3) Uani 1 1 d . . . . .
H99 H 0.6442 -0.1321 0.8443 0.077 Uiso 1 1 calc R U . . .
C100 C 0.7053(4) -0.1219(6) 0.8885(3) 0.065(3) Uani 1 1 d . . . . .
H100 H 0.6807 -0.1175 0.9041 0.078 Uiso 1 1 calc R U . . .
C101 C 0.7630(5) -0.1199(7) 0.9013(3) 0.068(3) Uani 1 1 d . . . . .
H101 H 0.7780 -0.1142 0.9257 0.081 Uiso 1 1 calc R U . . .
C102 C 0.7989(4) -0.1261(6) 0.8785(2) 0.056(2) Uani 1 1 d . . . . .
H102 H 0.8384 -0.1247 0.8874 0.067 Uiso 1 1 calc R U . . .
C103 C 0.8225(4) -0.2407(7) 0.7995(3) 0.071(3) Uani 1 1 d . . . . .
C104 C 0.7783(4) -0.2687(8) 0.7731(3) 0.072(3) Uani 1 1 d . . . . .
H104 H 0.7496 -0.2355 0.7612 0.087 Uiso 1 1 calc R U . . .
C105 C 0.7770(5) -0.3460(8) 0.7645(4) 0.083(4) Uani 1 1 d . . . . .
H105 H 0.7472 -0.3647 0.7466 0.100 Uiso 1 1 calc R U . . .
C106 C 0.8179(6) -0.3962(9) 0.7815(4) 0.092(4) Uani 1 1 d . . . . .
H106 H 0.8163 -0.4488 0.7757 0.110 Uiso 1 1 calc R U . . .
C107 C 0.8613(6) -0.3672(9) 0.8072(4) 0.093(4) Uani 1 1 d . . . . .
H107 H 0.8898 -0.4005 0.8192 0.112 Uiso 1 1 calc R U . . .
C108 C 0.8637(5) -0.2913(9) 0.8156(3) 0.081(4) Uani 1 1 d . . . . .
H108 H 0.8946 -0.2729 0.8329 0.097 Uiso 1 1 calc R U . . .
C109 C 0.9872(3) -0.0730(5) 0.8728(2) 0.0470(18) Uani 1 1 d . . . . .
C110 C 1.0283(4) -0.0629(6) 0.8937(3) 0.061(2) Uani 1 1 d . . . . .
C111 C 1.0799(4) -0.0527(6) 0.9198(3) 0.061(2) Uani 1 1 d . . . . .
C112 C 1.0992(5) -0.1109(7) 0.9441(3) 0.069(3) Uani 1 1 d . . . . .
H112 H 1.0773 -0.1557 0.9439 0.083 Uiso 1 1 calc R U . . .
C113 C 1.1495(5) -0.1042(7) 0.9683(3) 0.071(3) Uani 1 1 d . . . . .
H113 H 1.1625 -0.1452 0.9839 0.085 Uiso 1 1 calc R U . . .
C114 C 1.1821(4) -0.0372(6) 0.9702(3) 0.058(2) Uani 1 1 d . . . . .
C115 C 1.1614(4) 0.0205(6) 0.9462(3) 0.064(2) Uani 1 1 d . . . . .
H115 H 1.1824 0.0663 0.9469 0.076 Uiso 1 1 calc R U . . .
C116 C 1.1118(4) 0.0137(6) 0.9217(3) 0.063(2) Uani 1 1 d . . . . .
H116 H 1.0991 0.0545 0.9060 0.076 Uiso 1 1 calc R U . . .
C117 C 1.2386(4) -0.0308(6) 0.9948(3) 0.060(2) Uani 1 1 d . . . . .
C118 C 1.2519(4) -0.0636(6) 1.0263(3) 0.057(2) Uani 1 1 d . . . . .
C119 C 1.2792(4) 0.0174(7) 0.9808(3) 0.066(3) Uani 1 1 d . . . . .
C120 C 1.2882(5) 0.0040(10) 0.9470(3) 0.091(4) Uani 1 1 d . . . . .
H120 H 1.2709 -0.0385 0.9338 0.109 Uiso 1 1 calc R U . . .
C121 C 1.3215(6) 0.0516(13) 0.9332(4) 0.116(6) Uani 1 1 d . . . . .
H121 H 1.3267 0.0427 0.9101 0.140 Uiso 1 1 calc R U . . .
C122 C 1.3478(7) 0.1126(12) 0.9523(6) 0.124(7) Uani 1 1 d . . . . .
H122 H 1.3709 0.1454 0.9423 0.149 Uiso 1 1 calc R U . . .
C123 C 1.3408(7) 0.1267(10) 0.9865(5) 0.108(5) Uani 1 1 d . . . . .
H123 H 1.3596 0.1681 0.9998 0.129 Uiso 1 1 calc R U . . .
C124 C 1.3058(6) 0.0790(8) 1.0005(4) 0.086(4) Uani 1 1 d . . . . .
H124 H 1.3001 0.0882 1.0233 0.104 Uiso 1 1 calc R U . . .
C125 C 1.3112(4) -0.0680(6) 1.0469(3) 0.061(2) Uani 1 1 d . . . . .
C126 C 1.3232(5) -0.0544(7) 1.0823(3) 0.067(3) Uani 1 1 d . . . . .
H126 H 1.2936 -0.0405 1.0932 0.081 Uiso 1 1 calc R U . . .
C127 C 1.3768(5) -0.0604(7) 1.1024(3) 0.071(3) Uani 1 1 d . . . . .
H127 H 1.3836 -0.0499 1.1269 0.085 Uiso 1 1 calc R U . . .
C128 C 1.4191(5) -0.0805(7) 1.0882(3) 0.078(3) Uani 1 1 d . . . . .
H128 H 1.4561 -0.0841 1.1023 0.094 Uiso 1 1 calc R U . . .
C129 C 1.4092(5) -0.0961(8) 1.0532(4) 0.088(4) Uani 1 1 d . . . . .
H129 H 1.4395 -0.1114 1.0432 0.106 Uiso 1 1 calc R U . . .
C130 C 1.3558(5) -0.0900(7) 1.0318(3) 0.074(3) Uani 1 1 d . . . . .
H130 H 1.3495 -0.1004 1.0074 0.088 Uiso 1 1 calc R U . . .
C131 C 1.2102(5) -0.0964(7) 1.0445(3) 0.067(3) Uani 1 1 d . . . . .
C132 C 1.1640(5) -0.0544(9) 1.0485(3) 0.080(3) Uani 1 1 d . . . . .
H132 H 1.1591 -0.0039 1.0395 0.096 Uiso 1 1 calc R U . . .
C133 C 1.1241(6) -0.0859(10) 1.0657(4) 0.095(4) Uani 1 1 d . . . . .
H133 H 1.0930 -0.0569 1.0692 0.113 Uiso 1 1 calc R U . . .
C134 C 1.1322(7) -0.1613(11) 1.0775(4) 0.100(5) Uani 1 1 d . . . . .
H134 H 1.1048 -0.1844 1.0880 0.121 Uiso 1 1 calc R U . . .
C135 C 1.1773(7) -0.2021(11) 1.0745(4) 0.100(5) Uani 1 1 d . . . . .
H135 H 1.1824 -0.2525 1.0836 0.120 Uiso 1 1 calc R U . . .
C136 C 1.2170(6) -0.1692(8) 1.0579(3) 0.083(3) Uani 1 1 d . . . . .
H136 H 1.2491 -0.1979 1.0558 0.099 Uiso 1 1 calc R U . . .
C137 C 1.0110(3) 0.0963(5) 0.6286(2) 0.0487(19) Uani 1 1 d . . . . .
C138 C 0.9691(4) 0.0839(6) 0.6085(3) 0.062(2) Uani 1 1 d . . . . .
C139 C 0.9174(4) 0.0715(8) 0.5829(3) 0.071(3) Uani 1 1 d . . . . .
C140 C 0.8988(5) 0.1277(9) 0.5573(3) 0.084(4) Uani 1 1 d . . . . .
H140 H 0.9209 0.1720 0.5566 0.101 Uiso 1 1 calc R U . . .
C141 C 0.8480(6) 0.1184(11) 0.5331(3) 0.103(5) Uani 1 1 d . . . . .
H141 H 0.8344 0.1576 0.5166 0.123 Uiso 1 1 calc R U . . .
C142 C 0.8159(5) 0.0492(11) 0.5330(3) 0.103(5) Uani 1 1 d . U . . .
C143 C 0.8358(6) -0.0043(11) 0.5582(4) 0.115(6) Uani 1 1 d . U . . .
H143 H 0.8155 -0.0503 0.5586 0.138 Uiso 1 1 calc R U . . .
C144 C 0.8847(5) 0.0077(9) 0.5829(3) 0.101(5) Uani 1 1 d . U . . .
H144 H 0.8965 -0.0296 0.6006 0.122 Uiso 1 1 calc R U . . .
C147 C 0.6870(5) 0.0499(8) 0.4564(3) 0.091(4) Uani 1 1 d D U . . .
C148 C 0.6804(5) 0.0357(7) 0.4213(3) 0.078(3) Uani 1 1 d . . . . .
H148 H 0.7121 0.0218 0.4124 0.094 Uiso 1 1 calc R U . . .
C149 C 0.6282(6) 0.0411(7) 0.3987(3) 0.075(3) Uani 1 1 d . . . . .
H149 H 0.6248 0.0319 0.3744 0.090 Uiso 1 1 calc R U . . .
C150 C 0.5830(5) 0.0591(7) 0.4105(3) 0.079(3) Uani 1 1 d . . . . .
H150 H 0.5473 0.0611 0.3948 0.095 Uiso 1 1 calc R U . . .
C151 C 0.5880(6) 0.0745(10) 0.4448(4) 0.102(5) Uani 1 1 d . . . . .
H151 H 0.5556 0.0888 0.4529 0.123 Uiso 1 1 calc R U . . .
C152 C 0.6397(6) 0.0697(10) 0.4686(4) 0.110(5) Uani 1 1 d . U . . .
H152 H 0.6426 0.0799 0.4928 0.132 Uiso 1 1 calc R U . . .
C145 C 0.7604(6) 0.0302(9) 0.5074(4) 0.059(3) Uani 0.685(5) 1 d . U P A 1
C146 C 0.7489(6) 0.0588(9) 0.4751(4) 0.059(3) Uani 0.685(5) 1 d D U P A 1
C153 C 0.7202(7) -0.0145(10) 0.5228(4) 0.067(4) Uani 0.685(5) 1 d . U P A 1
C154 C 0.6923(8) -0.0784(12) 0.5057(6) 0.088(5) Uani 0.685(5) 1 d . U P A 1
H154 H 0.6979 -0.0912 0.4831 0.105 Uiso 0.685(5) 1 calc R U P A 1
C155 C 0.6576(10) -0.1231(16) 0.5199(7) 0.113(8) Uani 0.685(5) 1 d . U P A 1
H155 H 0.6391 -0.1661 0.5078 0.136 Uiso 0.685(5) 1 calc R U P A 1
C156 C 0.6506(10) -0.1017(13) 0.5541(7) 0.112(8) Uani 0.685(5) 1 d D U P A 1
H156 H 0.6266 -0.1317 0.5647 0.134 Uiso 0.685(5) 1 calc R U P A 1
C157 C 0.6766(7) -0.0408(12) 0.5720(5) 0.078(5) Uani 0.685(5) 1 d D U P A 1
H157 H 0.6717 -0.0288 0.5948 0.094 Uiso 0.685(5) 1 calc R U P A 1
C158 C 0.7103(8) 0.0028(12) 0.5560(5) 0.080(5) Uani 0.685(5) 1 d . U P A 1
H158 H 0.7278 0.0467 0.5679 0.096 Uiso 0.685(5) 1 calc R U P A 1
C159 C 0.7911(7) 0.0872(10) 0.4563(4) 0.066(4) Uani 0.685(5) 1 d . U P A 1
C160 C 0.7879(9) 0.1565(12) 0.4409(4) 0.086(5) Uani 0.685(5) 1 d . U P A 1
H160 H 0.7561 0.1873 0.4414 0.103 Uiso 0.685(5) 1 calc R U P A 1
C161 C 0.8268(9) 0.1842(13) 0.4250(5) 0.098(6) Uani 0.685(5) 1 d D U P A 1
H161 H 0.8249 0.2340 0.4153 0.118 Uiso 0.685(5) 1 calc R U P A 1
C162 C 0.8685(10) 0.1356(14) 0.4238(5) 0.113(7) Uani 0.685(5) 1 d D U P A 1
H162 H 0.8950 0.1540 0.4114 0.135 Uiso 0.685(5) 1 calc R U P A 1
C163 C 0.8796(10) 0.0647(12) 0.4374(6) 0.099(6) Uani 0.685(5) 1 d D U P A 1
H163 H 0.9113 0.0344 0.4360 0.119 Uiso 0.685(5) 1 calc R U P A 1
C164 C 0.8383(8) 0.0445(14) 0.4531(6) 0.091(6) Uani 0.685(5) 1 d . U P A 1
H164 H 0.8413 -0.0049 0.4633 0.109 Uiso 0.685(5) 1 calc R U P A 1
C245 C 0.7547(11) 0.0846(16) 0.5113(5) 0.047(5) Uani 0.315(5) 1 d D U P A 2
C246 C 0.7329(11) 0.0275(17) 0.4881(6) 0.049(5) Uani 0.315(5) 1 d D U P A 2
C253 C 0.7651(8) -0.0491(14) 0.4910(6) 0.039(5) Uani 0.315(5) 1 d D U P A 2
C254 C 0.7347(12) -0.1174(13) 0.4904(7) 0.048(6) Uani 0.315(5) 1 d D U P A 2
H254 H 0.6952 -0.1159 0.4880 0.057 Uiso 0.315(5) 1 calc R U P A 2
C255 C 0.7628(11) -0.1882(16) 0.4933(8) 0.072(9) Uani 0.315(5) 1 d D U P A 2
H255 H 0.7409 -0.2333 0.4920 0.086 Uiso 0.315(5) 1 calc R U P A 2
C256 C 0.8212(10) -0.1958(13) 0.4980(7) 0.051(6) Uani 0.315(5) 1 d D U P A 2
H256 H 0.8396 -0.2437 0.5015 0.061 Uiso 0.315(5) 1 calc R U P A 2
C257 C 0.8497(11) -0.1278(12) 0.4971(7) 0.059(7) Uani 0.315(5) 1 d D U P A 2
H257 H 0.8890 -0.1299 0.4985 0.071 Uiso 0.315(5) 1 calc R U P A 2
C258 C 0.8236(8) -0.0559(13) 0.4943(6) 0.045(5) Uani 0.315(5) 1 d D U P A 2
H258 H 0.8456 -0.0113 0.4946 0.054 Uiso 0.315(5) 1 calc R U P A 2
C259 C 0.7223(10) 0.1598(14) 0.5081(6) 0.044(5) Uani 0.315(5) 1 d . U P A 2
C260 C 0.7110(11) 0.2030(14) 0.4780(8) 0.053(6) Uani 0.315(5) 1 d D U P A 2
H260 H 0.7248 0.1869 0.4583 0.063 Uiso 0.315(5) 1 calc R U P A 2
C261 C 0.6797(13) 0.2697(15) 0.4759(7) 0.063(8) Uani 0.315(5) 1 d D U P A 2
H261 H 0.6707 0.2977 0.4545 0.076 Uiso 0.315(5) 1 calc R U P A 2
C262 C 0.6622(12) 0.2946(15) 0.5045(6) 0.047(6) Uani 0.315(5) 1 d D U P A 2
H262 H 0.6437 0.3423 0.5039 0.057 Uiso 0.315(5) 1 calc R U P A 2
C263 C 0.6714(16) 0.2502(18) 0.5348(9) 0.077(10) Uani 0.315(5) 1 d D U P A 2
H263 H 0.6556 0.2647 0.5539 0.093 Uiso 0.315(5) 1 calc R U P A 2
C264 C 0.7039(16) 0.1846(19) 0.5370(8) 0.073(9) Uani 0.315(5) 1 d D U P A 2
H264 H 0.7133 0.1570 0.5584 0.088 Uiso 0.315(5) 1 calc R U P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -5.1040 5.8603 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2543 0.3332 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P7 Au1 Au2 176.25(5) . . ?
P7 Au1 Au3 119.42(6) . . ?
Au2 Au1 Au3 63.250(11) . . ?
P7 Au1 Au4 120.95(5) . . ?
Au2 Au1 Au4 62.579(12) . . ?
Au3 Au1 Au4 55.644(11) . . ?
P7 Au1 Au5 114.64(5) . . ?
Au2 Au1 Au5 61.835(11) . . ?
Au3 Au1 Au5 97.661(13) . . ?
Au4 Au1 Au5 124.409(13) . . ?
P7 Au1 Au6 115.46(6) . . ?
Au2 Au1 Au6 61.784(11) . . ?
Au3 Au1 Au6 125.030(13) . . ?
Au4 Au1 Au6 98.161(12) . . ?
Au5 Au1 Au6 55.128(11) . . ?
P5 Au2 Au1 176.63(5) . . ?
P5 Au2 Au5 120.54(5) . . ?
Au1 Au2 Au5 62.767(12) . . ?
P5 Au2 Au6 117.89(5) . . ?
Au1 Au2 Au6 62.946(11) . . ?
Au5 Au2 Au6 55.705(11) . . ?
P5 Au2 Au4 114.71(5) . . ?
Au1 Au2 Au4 61.995(11) . . ?
Au5 Au2 Au4 124.757(13) . . ?
Au6 Au2 Au4 98.512(13) . . ?
P5 Au2 Au3 117.53(5) . . ?
Au1 Au2 Au3 61.566(11) . . ?
Au5 Au2 Au3 97.212(12) . . ?
Au6 Au2 Au3 124.509(13) . . ?
Au4 Au2 Au3 55.020(11) . . ?
P4 Au3 Au4 167.78(5) . . ?
P4 Au3 Au1 124.27(5) . . ?
Au4 Au3 Au1 62.236(12) . . ?
P4 Au3 Au2 130.07(5) . . ?
Au4 Au3 Au2 61.999(12) . . ?
Au1 Au3 Au2 55.184(11) . . ?
P4 Au3 Au7 106.30(5) . . ?
Au4 Au3 Au7 63.247(11) . . ?
Au1 Au3 Au7 121.427(14) . . ?
Au2 Au3 Au7 112.612(13) . . ?
P2 Au4 Au3 175.51(5) . . ?
P2 Au4 Au1 121.22(5) . . ?
Au3 Au4 Au1 62.119(11) . . ?
P2 Au4 Au2 121.16(5) . . ?
Au3 Au4 Au2 62.981(11) . . ?
Au1 Au4 Au2 55.427(10) . . ?
P2 Au4 Au7 109.97(5) . . ?
Au3 Au4 Au7 65.769(13) . . ?
Au1 Au4 Au7 123.635(14) . . ?
Au2 Au4 Au7 115.308(14) . . ?
P3 Au5 Au6 175.27(5) . . ?
P3 Au5 Au2 121.62(5) . . ?
Au6 Au5 Au2 62.205(11) . . ?
P3 Au5 Au1 121.54(5) . . ?
Au6 Au5 Au1 62.608(11) . . ?
Au2 Au5 Au1 55.399(10) . . ?
P3 Au5 Au8 109.07(5) . . ?
Au6 Au5 Au8 66.330(13) . . ?
Au2 Au5 Au8 124.489(14) . . ?
Au1 Au5 Au8 114.993(15) . . ?
P1 Au6 Au5 168.85(5) . . ?
P1 Au6 Au2 123.19(5) . . ?
Au5 Au6 Au2 62.089(12) . . ?
P1 Au6 Au1 128.85(5) . . ?
Au5 Au6 Au1 62.263(12) . . ?
Au2 Au6 Au1 55.271(11) . . ?
P1 Au6 Au8 108.31(5) . . ?
Au5 Au6 Au8 62.655(12) . . ?
Au2 Au6 Au8 120.994(14) . . ?
Au1 Au6 Au8 111.917(14) . . ?
C137 Au7 P6 168.8(3) . . ?
C137 Au7 Au4 77.9(3) . . ?
P6 Au7 Au4 111.66(6) . . ?
C137 Au7 Au3 81.7(3) . . ?
P6 Au7 Au3 108.80(5) . . ?
Au4 Au7 Au3 50.984(10) . . ?
C109 Au8 P8 168.1(2) . . ?
C109 Au8 Au5 78.2(2) . . ?
P8 Au8 Au5 112.01(7) . . ?
C109 Au8 Au6 82.4(2) . . ?
P8 Au8 Au6 108.68(6) . . ?
Au5 Au8 Au6 51.015(10) . . ?
C10 P1 C4 102.4(4) . . ?
C10 P1 C1 102.7(3) . . ?
C4 P1 C1 108.1(4) . . ?
C10 P1 Au6 115.4(3) . . ?
C4 P1 Au6 116.3(3) . . ?
C1 P1 Au6 110.8(3) . . ?
C3 P2 C22 104.2(4) . . ?
C3 P2 C16 106.4(4) . . ?
C22 P2 C16 101.7(4) . . ?
C3 P2 Au4 108.3(3) . . ?
C22 P2 Au4 115.8(3) . . ?
C16 P2 Au4 119.0(3) . . ?
C31 P3 C37 101.5(4) . . ?
C31 P3 C28 106.6(4) . . ?
C37 P3 C28 102.9(4) . . ?
C31 P3 Au5 118.7(3) . . ?
C37 P3 Au5 116.7(3) . . ?
C28 P3 Au5 109.0(3) . . ?
C43 P4 C49 102.8(4) . . ?
C43 P4 C30 107.8(4) . . ?
C49 P4 C30 102.8(3) . . ?
C43 P4 Au3 115.9(3) . . ?
C49 P4 Au3 115.4(3) . . ?
C30 P4 Au3 111.0(3) . . ?
C55 P5 C64 106.8(4) . . ?
C55 P5 C58 100.6(4) . . ?
C64 P5 C58 104.4(4) . . ?
C55 P5 Au2 111.5(3) . . ?
C64 P5 Au2 114.6(3) . . ?
C58 P5 Au2 117.5(3) . . ?
C57 P6 C76 104.8(4) . . ?
C57 P6 C70 106.0(5) . . ?
C76 P6 C70 106.1(4) . . ?
C57 P6 Au7 114.2(3) . . ?
C76 P6 Au7 111.0(3) . . ?
C70 P6 Au7 114.1(3) . . ?
C82 P7 C91 108.0(5) . . ?
C82 P7 C85 99.0(6) . . ?
C91 P7 C85 105.1(4) . . ?
C82 P7 Au1 111.5(3) . . ?
C91 P7 Au1 115.0(3) . . ?
C85 P7 Au1 116.7(3) . . ?
C84 P8 C103 107.4(6) . . ?
C84 P8 C97 103.6(5) . . ?
C103 P8 C97 105.4(4) . . ?
C84 P8 Au8 115.2(3) . . ?
C103 P8 Au8 113.1(4) . . ?
C97 P8 Au8 111.2(3) . . ?
C2 C1 P1 114.1(5) . . ?
C2 C1 H1A 108.7 . . ?
P1 C1 H1A 108.7 . . ?
C2 C1 H1B 108.7 . . ?
P1 C1 H1B 108.7 . . ?
H1A C1 H1B 107.6 . . ?
C3 C2 C1 113.5(7) . . ?
C3 C2 H2A 108.9 . . ?
C1 C2 H2A 108.9 . . ?
C3 C2 H2B 108.9 . . ?
C1 C2 H2B 108.9 . . ?
H2A C2 H2B 107.7 . . ?
C2 C3 P2 115.0(6) . . ?
C2 C3 H3A 108.5 . . ?
P2 C3 H3A 108.5 . . ?
C2 C3 H3B 108.5 . . ?
P2 C3 H3B 108.5 . . ?
H3A C3 H3B 107.5 . . ?
C9 C4 C5 119.8(8) . . ?
C9 C4 P1 116.7(7) . . ?
C5 C4 P1 123.2(6) . . ?
C4 C5 C6 120.4(10) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C7 C6 C5 120.0(12) . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C8 120.5(12) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
C9 C8 C7 119.0(11) . . ?
C9 C8 H8 120.5 . . ?
C7 C8 H8 120.5 . . ?
C4 C9 C8 119.9(10) . . ?
C4 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C15 C10 C11 118.3(8) . . ?
C15 C10 P1 118.7(7) . . ?
C11 C10 P1 123.0(7) . . ?
C12 C11 C10 121.5(10) . . ?
C12 C11 H11 119.2 . . ?
C10 C11 H11 119.2 . . ?
C11 C12 C13 119.4(11) . . ?
C11 C12 H12 120.3 . . ?
C13 C12 H12 120.3 . . ?
C14 C13 C12 120.1(10) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C13 C14 C15 119.7(10) . . ?
C13 C14 H14 120.1 . . ?
C15 C14 H14 120.1 . . ?
C10 C15 C14 120.8(10) . . ?
C10 C15 H15 119.6 . . ?
C14 C15 H15 119.6 . . ?
C17 C16 C21 120.7(7) . . ?
C17 C16 P2 121.6(7) . . ?
C21 C16 P2 117.3(6) . . ?
C16 C17 C18 119.3(9) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C19 C18 C17 120.3(9) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C20 C19 C18 119.9(8) . . ?
C20 C19 H19 120.0 . . ?
C18 C19 H19 120.0 . . ?
C19 C20 C21 119.6(9) . . ?
C19 C20 H20 120.2 . . ?
C21 C20 H20 120.2 . . ?
C16 C21 C20 120.1(8) . . ?
C16 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C27 C22 C23 119.8(10) . . ?
C27 C22 P2 120.0(8) . . ?
C23 C22 P2 120.2(8) . . ?
C24 C23 C22 118.4(12) . . ?
C24 C23 H23 120.8 . . ?
C22 C23 H23 120.8 . . ?
C25 C24 C23 121.2(13) . . ?
C25 C24 H24 119.4 . . ?
C23 C24 H24 119.4 . . ?
C26 C25 C24 121.2(12) . . ?
C26 C25 H25 119.4 . . ?
C24 C25 H25 119.4 . . ?
C25 C26 C27 120.1(14) . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C22 C27 C26 119.2(13) . . ?
C22 C27 H27 120.4 . . ?
C26 C27 H27 120.4 . . ?
C29 C28 P3 113.9(6) . . ?
C29 C28 H28A 108.8 . . ?
P3 C28 H28A 108.8 . . ?
C29 C28 H28B 108.8 . . ?
P3 C28 H28B 108.8 . . ?
H28A C28 H28B 107.7 . . ?
C28 C29 C30 112.2(7) . . ?
C28 C29 H29A 109.2 . . ?
C30 C29 H29A 109.2 . . ?
C28 C29 H29B 109.2 . . ?
C30 C29 H29B 109.2 . . ?
H29A C29 H29B 107.9 . . ?
C29 C30 P4 113.9(5) . . ?
C29 C30 H30A 108.8 . . ?
P4 C30 H30A 108.8 . . ?
C29 C30 H30B 108.8 . . ?
P4 C30 H30B 108.8 . . ?
H30A C30 H30B 107.7 . . ?
C36 C31 C32 119.5(7) . . ?
C36 C31 P3 118.5(6) . . ?
C32 C31 P3 121.7(7) . . ?
C33 C32 C31 120.0(9) . . ?
C33 C32 H32 120.0 . . ?
C31 C32 H32 120.0 . . ?
C34 C33 C32 120.3(9) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C33 C34 C35 120.0(8) . . ?
C33 C34 H34 120.0 . . ?
C35 C34 H34 120.0 . . ?
C36 C35 C34 119.7(10) . . ?
C36 C35 H35 120.1 . . ?
C34 C35 H35 120.1 . . ?
C31 C36 C35 120.4(9) . . ?
C31 C36 H36 119.8 . . ?
C35 C36 H36 119.8 . . ?
C42 C37 C38 120.2(9) . . ?
C42 C37 P3 118.7(7) . . ?
C38 C37 P3 121.0(7) . . ?
C39 C38 C37 119.8(11) . . ?
C39 C38 H38 120.1 . . ?
C37 C38 H38 120.1 . . ?
C38 C39 C40 120.3(12) . . ?
C38 C39 H39 119.9 . . ?
C40 C39 H39 119.9 . . ?
C41 C40 C39 120.8(12) . . ?
C41 C40 H40 119.6 . . ?
C39 C40 H40 119.6 . . ?
C40 C41 C42 120.1(12) . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C37 C42 C41 118.9(11) . . ?
C37 C42 H42 120.6 . . ?
C41 C42 H42 120.6 . . ?
C48 C43 C44 118.8(9) . . ?
C48 C43 P4 118.0(7) . . ?
C44 C43 P4 122.8(7) . . ?
C45 C44 C43 120.0(10) . . ?
C45 C44 H44 120.0 . . ?
C43 C44 H44 120.0 . . ?
C46 C45 C44 121.2(12) . . ?
C46 C45 H45 119.4 . . ?
C44 C45 H45 119.4 . . ?
C45 C46 C47 119.3(11) . . ?
C45 C46 H46 120.4 . . ?
C47 C46 H46 120.4 . . ?
C48 C47 C46 119.8(11) . . ?
C48 C47 H47 120.1 . . ?
C46 C47 H47 120.1 . . ?
C47 C48 C43 120.7(11) . . ?
C47 C48 H48 119.7 . . ?
C43 C48 H48 119.7 . . ?
C54 C49 C50 118.4(8) . . ?
C54 C49 P4 119.0(7) . . ?
C50 C49 P4 122.6(7) . . ?
C51 C50 C49 120.8(10) . . ?
C51 C50 H50 119.6 . . ?
C49 C50 H50 119.6 . . ?
C50 C51 C52 120.6(10) . . ?
C50 C51 H51 119.7 . . ?
C52 C51 H51 119.7 . . ?
C51 C52 C53 119.3(10) . . ?
C51 C52 H52 120.3 . . ?
C53 C52 H52 120.3 . . ?
C54 C53 C52 120.3(10) . . ?
C54 C53 H53 119.8 . . ?
C52 C53 H53 119.8 . . ?
C49 C54 C53 120.5(9) . . ?
C49 C54 H54 119.7 . . ?
C53 C54 H54 119.7 . . ?
C56 C55 P5 112.4(6) . . ?
C56 C55 H55A 109.1 . . ?
P5 C55 H55A 109.1 . . ?
C56 C55 H55B 109.1 . . ?
P5 C55 H55B 109.1 . . ?
H55A C55 H55B 107.9 . . ?
C55 C56 C57 109.8(7) . . ?
C55 C56 H56A 109.7 . . ?
C57 C56 H56A 109.7 . . ?
C55 C56 H56B 109.7 . . ?
C57 C56 H56B 109.7 . . ?
H56A C56 H56B 108.2 . . ?
C56 C57 P6 111.9(6) . . ?
C56 C57 H57A 109.2 . . ?
P6 C57 H57A 109.2 . . ?
C56 C57 H57B 109.2 . . ?
P6 C57 H57B 109.2 . . ?
H57A C57 H57B 107.9 . . ?
C63 C58 C59 118.7(9) . . ?
C63 C58 P5 119.9(7) . . ?
C59 C58 P5 121.3(8) . . ?
C60 C59 C58 118.1(11) . . ?
C60 C59 H59 121.0 . . ?
C58 C59 H59 121.0 . . ?
C61 C60 C59 122.3(11) . . ?
C61 C60 H60 118.8 . . ?
C59 C60 H60 118.8 . . ?
C62 C61 C60 119.1(11) . . ?
C62 C61 H61 120.5 . . ?
C60 C61 H61 120.5 . . ?
C61 C62 C63 121.0(12) . . ?
C61 C62 H62 119.5 . . ?
C63 C62 H62 119.5 . . ?
C58 C63 C62 120.8(10) . . ?
C58 C63 H63 119.6 . . ?
C62 C63 H63 119.6 . . ?
C69 C64 C65 118.5(8) . . ?
C69 C64 P5 120.1(7) . . ?
C65 C64 P5 121.4(7) . . ?
C66 C65 C64 120.2(10) . . ?
C66 C65 H65 119.9 . . ?
C64 C65 H65 119.9 . . ?
C65 C66 C67 120.5(10) . . ?
C65 C66 H66 119.8 . . ?
C67 C66 H66 119.8 . . ?
C68 C67 C66 120.3(10) . . ?
C68 C67 H67 119.8 . . ?
C66 C67 H67 119.8 . . ?
C67 C68 C69 119.1(10) . . ?
C67 C68 H68 120.5 . . ?
C69 C68 H68 120.5 . . ?
C68 C69 C64 121.4(9) . . ?
C68 C69 H69 119.3 . . ?
C64 C69 H69 119.3 . . ?
C75 C70 C71 118.8(10) . . ?
C75 C70 P6 119.7(7) . . ?
C71 C70 P6 121.5(8) . . ?
C72 C71 C70 120.0(10) . . ?
C72 C71 H71 120.0 . . ?
C70 C71 H71 120.0 . . ?
C71 C72 C73 121.4(10) . . ?
C71 C72 H72 119.3 . . ?
C73 C72 H72 119.3 . . ?
C74 C73 C72 118.9(12) . . ?
C74 C73 H73 120.5 . . ?
C72 C73 H73 120.5 . . ?
C73 C74 C75 120.7(11) . . ?
C73 C74 H74 119.7 . . ?
C75 C74 H74 119.7 . . ?
C70 C75 C74 120.2(10) . . ?
C70 C75 H75 119.9 . . ?
C74 C75 H75 119.9 . . ?
C81 C76 C77 118.9(7) . . ?
C81 C76 P6 120.2(6) . . ?
C77 C76 P6 120.9(6) . . ?
C78 C77 C76 119.9(8) . . ?
C78 C77 H77 120.0 . . ?
C76 C77 H77 120.0 . . ?
C79 C78 C77 120.1(9) . . ?
C79 C78 H78 119.9 . . ?
C77 C78 H78 119.9 . . ?
C78 C79 C80 119.8(8) . . ?
C78 C79 H79 120.1 . . ?
C80 C79 H79 120.1 . . ?
C81 C80 C79 120.9(9) . . ?
C81 C80 H80 119.6 . . ?
C79 C80 H80 119.6 . . ?
C80 C81 C76 120.3(8) . . ?
C80 C81 H81 119.8 . . ?
C76 C81 H81 119.8 . . ?
C83 C82 P7 116.1(9) . . ?
C83 C82 H82A 108.3 . . ?
P7 C82 H82A 108.3 . . ?
C83 C82 H82B 108.3 . . ?
P7 C82 H82B 108.3 . . ?
H82A C82 H82B 107.4 . . ?
C82 C83 C84 107.7(9) . . ?
C82 C83 H83A 110.2 . . ?
C84 C83 H83A 110.2 . . ?
C82 C83 H83B 110.2 . . ?
C84 C83 H83B 110.2 . . ?
H83A C83 H83B 108.5 . . ?
C83 C84 P8 104.4(9) . . ?
C83 C84 H84A 110.9 . . ?
P8 C84 H84A 110.9 . . ?
C83 C84 H84B 110.9 . . ?
P8 C84 H84B 110.9 . . ?
H84A C84 H84B 108.9 . . ?
C90 C85 C86 120.3(11) . . ?
C90 C85 P7 119.5(7) . . ?
C86 C85 P7 120.1(10) . . ?
C85 C86 C87 116.4(14) . . ?
C85 C86 H86 121.8 . . ?
C87 C86 H86 121.8 . . ?
C88 C87 C86 121.8(13) . . ?
C88 C87 H87 119.1 . . ?
C86 C87 H87 119.1 . . ?
C89 C88 C87 119.2(14) . . ?
C89 C88 H88 120.4 . . ?
C87 C88 H88 120.4 . . ?
C88 C89 C90 121.9(16) . . ?
C88 C89 H89 119.0 . . ?
C90 C89 H89 119.0 . . ?
C85 C90 C89 120.3(11) . . ?
C85 C90 H90 119.8 . . ?
C89 C90 H90 119.8 . . ?
C96 C91 C92 118.6(9) . . ?
C96 C91 P7 120.4(7) . . ?
C92 C91 P7 121.0(7) . . ?
C93 C92 C91 119.8(10) . . ?
C93 C92 H92 120.1 . . ?
C91 C92 H92 120.1 . . ?
C92 C93 C94 120.6(10) . . ?
C92 C93 H93 119.7 . . ?
C94 C93 H93 119.7 . . ?
C95 C94 C93 120.2(10) . . ?
C95 C94 H94 119.9 . . ?
C93 C94 H94 119.9 . . ?
C94 C95 C96 118.9(11) . . ?
C94 C95 H95 120.5 . . ?
C96 C95 H95 120.5 . . ?
C91 C96 C95 121.7(10) . . ?
C91 C96 H96 119.1 . . ?
C95 C96 H96 119.1 . . ?
C98 C97 C102 119.1(8) . . ?
C98 C97 P8 121.2(7) . . ?
C102 C97 P8 119.6(6) . . ?
C97 C98 C99 120.2(9) . . ?
C97 C98 H98 119.9 . . ?
C99 C98 H98 119.9 . . ?
C100 C99 C98 120.5(9) . . ?
C100 C99 H99 119.8 . . ?
C98 C99 H99 119.8 . . ?
C99 C100 C101 119.8(9) . . ?
C99 C100 H100 120.1 . . ?
C101 C100 H100 120.1 . . ?
C102 C101 C100 120.1(9) . . ?
C102 C101 H101 119.9 . . ?
C100 C101 H101 119.9 . . ?
C101 C102 C97 120.3(9) . . ?
C101 C102 H102 119.9 . . ?
C97 C102 H102 119.9 . . ?
C108 C103 C104 118.1(12) . . ?
C108 C103 P8 120.5(9) . . ?
C104 C103 P8 121.4(10) . . ?
C105 C104 C103 119.3(13) . . ?
C105 C104 H104 120.4 . . ?
C103 C104 H104 120.4 . . ?
C106 C105 C104 121.9(12) . . ?
C106 C105 H105 119.1 . . ?
C104 C105 H105 119.1 . . ?
C107 C106 C105 117.8(14) . . ?
C107 C106 H106 121.1 . . ?
C105 C106 H106 121.1 . . ?
C108 C107 C106 121.2(15) . . ?
C108 C107 H107 119.4 . . ?
C106 C107 H107 119.4 . . ?
C107 C108 C103 121.7(12) . . ?
C107 C108 H108 119.1 . . ?
C103 C108 H108 119.1 . . ?
C110 C109 Au8 172.9(9) . . ?
C109 C110 C111 178.4(12) . . ?
C116 C111 C112 118.1(9) . . ?
C116 C111 C110 122.1(9) . . ?
C112 C111 C110 119.7(10) . . ?
C113 C112 C111 121.1(11) . . ?
C113 C112 H112 119.5 . . ?
C111 C112 H112 119.5 . . ?
C112 C113 C114 120.8(10) . . ?
C112 C113 H113 119.6 . . ?
C114 C113 H113 119.6 . . ?
C115 C114 C113 117.0(9) . . ?
C115 C114 C117 121.4(9) . . ?
C113 C114 C117 121.5(10) . . ?
C116 C115 C114 122.5(10) . . ?
C116 C115 H115 118.8 . . ?
C114 C115 H115 118.8 . . ?
C115 C116 C111 120.5(10) . . ?
C115 C116 H116 119.8 . . ?
C111 C116 H116 119.8 . . ?
C118 C117 C119 122.3(9) . . ?
C118 C117 C114 124.2(10) . . ?
C119 C117 C114 113.5(9) . . ?
C117 C118 C131 123.9(9) . . ?
C117 C118 C125 122.0(9) . . ?
C131 C118 C125 114.1(9) . . ?
C124 C119 C120 119.7(12) . . ?
C124 C119 C117 120.0(11) . . ?
C120 C119 C117 120.2(11) . . ?
C121 C120 C119 120.2(16) . . ?
C121 C120 H120 119.9 . . ?
C119 C120 H120 119.9 . . ?
C120 C121 C122 120.6(17) . . ?
C120 C121 H121 119.7 . . ?
C122 C121 H121 119.7 . . ?
C121 C122 C123 120.7(15) . . ?
C121 C122 H122 119.6 . . ?
C123 C122 H122 119.6 . . ?
C124 C123 C122 118.9(17) . . ?
C124 C123 H123 120.5 . . ?
C122 C123 H123 120.5 . . ?
C123 C124 C119 119.9(15) . . ?
C123 C124 H124 120.1 . . ?
C119 C124 H124 120.1 . . ?
C126 C125 C130 117.4(10) . . ?
C126 C125 C118 120.0(10) . . ?
C130 C125 C118 122.5(9) . . ?
C127 C126 C125 121.9(11) . . ?
C127 C126 H126 119.1 . . ?
C125 C126 H126 119.1 . . ?
C128 C127 C126 120.8(11) . . ?
C128 C127 H127 119.6 . . ?
C126 C127 H127 119.6 . . ?
C127 C128 C129 119.6(11) . . ?
C127 C128 H128 120.2 . . ?
C129 C128 H128 120.2 . . ?
C128 C129 C130 121.4(12) . . ?
C128 C129 H129 119.3 . . ?
C130 C129 H129 119.3 . . ?
C129 C130 C125 118.8(11) . . ?
C129 C130 H130 120.6 . . ?
C125 C130 H130 120.6 . . ?
C136 C131 C132 118.9(12) . . ?
C136 C131 C118 120.4(11) . . ?
C132 C131 C118 120.7(11) . . ?
C131 C132 C133 120.7(14) . . ?
C131 C132 H132 119.7 . . ?
C133 C132 H132 119.7 . . ?
C134 C133 C132 117.6(14) . . ?
C134 C133 H133 121.2 . . ?
C132 C133 H133 121.2 . . ?
C135 C134 C133 122.3(14) . . ?
C135 C134 H134 118.8 . . ?
C133 C134 H134 118.8 . . ?
C134 C135 C136 119.1(16) . . ?
C134 C135 H135 120.4 . . ?
C136 C135 H135 120.4 . . ?
C131 C136 C135 121.3(15) . . ?
C131 C136 H136 119.3 . . ?
C135 C136 H136 119.3 . . ?
C138 C137 Au7 174.6(9) . . ?
C137 C138 C139 177.6(12) . . ?
C144 C139 C140 118.4(10) . . ?
C144 C139 C138 122.8(10) . . ?
C140 C139 C138 118.8(11) . . ?
C141 C140 C139 119.9(13) . . ?
C141 C140 H140 120.0 . . ?
C139 C140 H140 120.0 . . ?
C140 C141 C142 120.1(13) . . ?
C140 C141 H141 120.0 . . ?
C142 C141 H141 120.0 . . ?
C143 C142 C141 117.9(11) . . ?
C143 C142 C145 116.2(14) . . ?
C141 C142 C145 125.8(13) . . ?
C143 C142 C245 139.3(14) . . ?
C141 C142 C245 96.5(15) . . ?
C142 C143 C144 121.0(13) . . ?
C142 C143 H143 119.5 . . ?
C144 C143 H143 119.5 . . ?
C139 C144 C143 122.6(12) . . ?
C139 C144 H144 118.7 . . ?
C143 C144 H144 118.7 . . ?
C148 C147 C152 118.0(11) . . ?
C148 C147 C246 132.0(15) . . ?
C152 C147 C246 107.5(16) . . ?
C148 C147 C146 112.4(12) . . ?
C152 C147 C146 128.1(11) . . ?
C147 C148 C149 121.0(11) . . ?
C147 C148 H148 119.5 . . ?
C149 C148 H148 119.5 . . ?
C150 C149 C148 121.0(11) . . ?
C150 C149 H149 119.5 . . ?
C148 C149 H149 119.5 . . ?
C149 C150 C151 119.8(11) . . ?
C149 C150 H150 120.1 . . ?
C151 C150 H150 120.1 . . ?
C150 C151 C152 121.3(13) . . ?
C150 C151 H151 119.4 . . ?
C152 C151 H151 119.4 . . ?
C147 C152 C151 119.0(13) . . ?
C147 C152 H152 120.5 . . ?
C151 C152 H152 120.5 . . ?
C146 C145 C153 124.5(15) . . ?
C146 C145 C142 120.5(14) . . ?
C153 C145 C142 114.6(13) . . ?
C145 C146 C159 125.3(14) . . ?
C145 C146 C147 113.1(14) . . ?
C159 C146 C147 121.1(13) . . ?
C154 C153 C158 116.7(17) . . ?
C154 C153 C145 121.4(17) . . ?
C158 C153 C145 121.8(16) . . ?
C155 C154 C153 123(2) . . ?
C155 C154 H154 118.4 . . ?
C153 C154 H154 118.4 . . ?
C154 C155 C156 116(2) . . ?
C154 C155 H155 121.8 . . ?
C156 C155 H155 121.8 . . ?
C157 C156 C155 123(2) . . ?
C157 C156 H156 118.4 . . ?
C155 C156 H156 118.4 . . ?
C156 C157 C158 117.6(19) . . ?
C156 C157 H157 121.2 . . ?
C158 C157 H157 121.2 . . ?
C157 C158 C153 123.0(19) . . ?
C157 C158 H158 118.5 . . ?
C153 C158 H158 118.5 . . ?
C160 C159 C164 114.1(18) . . ?
C160 C159 C146 123.1(18) . . ?
C164 C159 C146 122.8(17) . . ?
C161 C160 C159 124(2) . . ?
C161 C160 H160 118.1 . . ?
C159 C160 H160 118.1 . . ?
C162 C161 C160 114(2) . . ?
C162 C161 H161 122.9 . . ?
C160 C161 H161 122.9 . . ?
C161 C162 C163 131(2) . . ?
C161 C162 H162 114.4 . . ?
C163 C162 H162 114.4 . . ?
C164 C163 C162 108(2) . . ?
C164 C163 H163 125.8 . . ?
C162 C163 H163 125.8 . . ?
C163 C164 C159 128(2) . . ?
C163 C164 H164 116.0 . . ?
C159 C164 H164 116.0 . . ?
C246 C245 C259 117(2) . . ?
C246 C245 C142 104(2) . . ?
C259 C245 C142 138.7(19) . . ?
C245 C246 C147 117(2) . . ?
C245 C246 C253 117.9(19) . . ?
C147 C246 C253 124(2) . . ?
C254 C253 C258 117(2) . . ?
C254 C253 C246 119(2) . . ?
C258 C253 C246 125(2) . . ?
C253 C254 C255 120(3) . . ?
C253 C254 H254 119.9 . . ?
C255 C254 H254 119.9 . . ?
C256 C255 C254 124(3) . . ?
C256 C255 H255 118.1 . . ?
C254 C255 H255 118.1 . . ?
C257 C256 C255 115(2) . . ?
C257 C256 H256 122.7 . . ?
C255 C256 H256 122.7 . . ?
C256 C257 C258 123(3) . . ?
C256 C257 H257 118.3 . . ?
C258 C257 H257 118.3 . . ?
C257 C258 C253 121(2) . . ?
C257 C258 H258 119.5 . . ?
C253 C258 H258 119.5 . . ?
C264 C259 C260 119(2) . . ?
C264 C259 C245 118(2) . . ?
C260 C259 C245 123(2) . . ?
C259 C260 C261 121(3) . . ?
C259 C260 H260 119.4 . . ?
C261 C260 H260 119.4 . . ?
C262 C261 C260 119(3) . . ?
C262 C261 H261 120.3 . . ?
C260 C261 H261 120.3 . . ?
C261 C262 C263 120(2) . . ?
C261 C262 H262 120.0 . . ?
C263 C262 H262 120.0 . . ?
C264 C263 C262 120(3) . . ?
C264 C263 H263 120.1 . . ?
C262 C263 H263 120.1 . . ?
C259 C264 C263 120(3) . . ?
C259 C264 H264 120.0 . . ?
C263 C264 H264 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P7 2.3125(19) . ?
Au1 Au2 2.6405(4) . ?
Au1 Au3 2.8283(5) . ?
Au1 Au4 2.8313(4) . ?
Au1 Au5 2.8523(5) . ?
Au1 Au6 2.8613(4) . ?
Au2 P5 2.3167(18) . ?
Au2 Au5 2.8281(4) . ?
Au2 Au6 2.8311(4) . ?
Au2 Au4 2.8465(5) . ?
Au2 Au3 2.8720(4) . ?
Au3 P4 2.323(2) . ?
Au3 Au4 2.6415(5) . ?
Au3 Au7 3.1002(5) . ?
Au4 P2 2.312(2) . ?
Au4 Au7 3.0358(5) . ?
Au5 P3 2.320(2) . ?
Au5 Au6 2.6439(5) . ?
Au5 Au8 3.0213(5) . ?
Au6 P1 2.3160(19) . ?
Au6 Au8 3.1153(5) . ?
Au7 C137 2.026(8) . ?
Au7 P6 2.2861(19) . ?
Au8 C109 2.036(8) . ?
Au8 P8 2.286(2) . ?
P1 C10 1.818(8) . ?
P1 C4 1.820(8) . ?
P1 C1 1.842(7) . ?
P2 C3 1.820(8) . ?
P2 C22 1.822(9) . ?
P2 C16 1.827(8) . ?
P3 C31 1.823(8) . ?
P3 C37 1.828(9) . ?
P3 C28 1.833(8) . ?
P4 C43 1.814(9) . ?
P4 C49 1.823(8) . ?
P4 C30 1.841(7) . ?
P5 C55 1.822(8) . ?
P5 C64 1.824(8) . ?
P5 C58 1.832(9) . ?
P6 C57 1.796(9) . ?
P6 C76 1.823(8) . ?
P6 C70 1.824(10) . ?
P7 C82 1.803(10) . ?
P7 C91 1.827(9) . ?
P7 C85 1.830(11) . ?
P8 C84 1.802(12) . ?
P8 C103 1.812(13) . ?
P8 C97 1.824(8) . ?
C1 C2 1.536(10) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.507(11) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 C9 1.381(11) . ?
C4 C5 1.394(12) . ?
C5 C6 1.397(16) . ?
C5 H5 0.9500 . ?
C6 C7 1.348(19) . ?
C6 H6 0.9500 . ?
C7 C8 1.42(2) . ?
C7 H7 0.9500 . ?
C8 C9 1.400(15) . ?
C8 H8 0.9500 . ?
C9 H9 0.9500 . ?
C10 C15 1.372(13) . ?
C10 C11 1.391(13) . ?
C11 C12 1.355(14) . ?
C11 H11 0.9500 . ?
C12 C13 1.391(16) . ?
C12 H12 0.9500 . ?
C13 C14 1.366(16) . ?
C13 H13 0.9500 . ?
C14 C15 1.387(14) . ?
C14 H14 0.9500 . ?
C15 H15 0.9500 . ?
C16 C17 1.381(12) . ?
C16 C21 1.381(12) . ?
C17 C18 1.403(12) . ?
C17 H17 0.9500 . ?
C18 C19 1.394(15) . ?
C18 H18 0.9500 . ?
C19 C20 1.383(15) . ?
C19 H19 0.9500 . ?
C20 C21 1.404(12) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C27 1.388(15) . ?
C22 C23 1.409(15) . ?
C23 C24 1.386(16) . ?
C23 H23 0.9500 . ?
C24 C25 1.36(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.35(2) . ?
C25 H25 0.9500 . ?
C26 C27 1.412(16) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 C29 1.531(11) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.531(11) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C36 1.388(13) . ?
C31 C32 1.401(12) . ?
C32 C33 1.392(12) . ?
C32 H32 0.9500 . ?
C33 C34 1.382(15) . ?
C33 H33 0.9500 . ?
C34 C35 1.397(15) . ?
C34 H34 0.9500 . ?
C35 C36 1.394(12) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C42 1.374(14) . ?
C37 C38 1.390(14) . ?
C38 C39 1.372(15) . ?
C38 H38 0.9500 . ?
C39 C40 1.386(19) . ?
C39 H39 0.9500 . ?
C40 C41 1.339(19) . ?
C40 H40 0.9500 . ?
C41 C42 1.426(14) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C48 1.387(12) . ?
C43 C44 1.407(13) . ?
C44 C45 1.399(15) . ?
C44 H44 0.9500 . ?
C45 C46 1.344(19) . ?
C45 H45 0.9500 . ?
C46 C47 1.43(2) . ?
C46 H46 0.9500 . ?
C47 C48 1.383(16) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C54 1.373(13) . ?
C49 C50 1.409(12) . ?
C50 C51 1.352(13) . ?
C50 H50 0.9500 . ?
C51 C52 1.379(17) . ?
C51 H51 0.9500 . ?
C52 C53 1.383(17) . ?
C52 H52 0.9500 . ?
C53 C54 1.379(14) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C56 1.511(12) . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C56 C57 1.526(11) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C58 C63 1.357(14) . ?
C58 C59 1.414(13) . ?
C59 C60 1.402(16) . ?
C59 H59 0.9500 . ?
C60 C61 1.361(18) . ?
C60 H60 0.9500 . ?
C61 C62 1.338(17) . ?
C61 H61 0.9500 . ?
C62 C63 1.412(15) . ?
C62 H62 0.9500 . ?
C63 H63 0.9500 . ?
C64 C69 1.380(12) . ?
C64 C65 1.399(12) . ?
C65 C66 1.361(15) . ?
C65 H65 0.9500 . ?
C66 C67 1.381(16) . ?
C66 H66 0.9500 . ?
C67 C68 1.376(16) . ?
C67 H67 0.9500 . ?
C68 C69 1.377(14) . ?
C68 H68 0.9500 . ?
C69 H69 0.9500 . ?
C70 C75 1.386(14) . ?
C70 C71 1.392(13) . ?
C71 C72 1.372(15) . ?
C71 H71 0.9500 . ?
C72 C73 1.392(17) . ?
C72 H72 0.9500 . ?
C73 C74 1.357(17) . ?
C73 H73 0.9500 . ?
C74 C75 1.402(17) . ?
C74 H74 0.9500 . ?
C75 H75 0.9500 . ?
C76 C81 1.401(12) . ?
C76 C77 1.405(11) . ?
C77 C78 1.396(12) . ?
C77 H77 0.9500 . ?
C78 C79 1.382(14) . ?
C78 H78 0.9500 . ?
C79 C80 1.388(14) . ?
C79 H79 0.9500 . ?
C80 C81 1.373(12) . ?
C80 H80 0.9500 . ?
C81 H81 0.9500 . ?
C82 C83 1.427(13) . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C83 C84 1.596(13) . ?
C83 H83A 0.9900 . ?
C83 H83B 0.9900 . ?
C84 H84A 0.9900 . ?
C84 H84B 0.9900 . ?
C85 C90 1.346(16) . ?
C85 C86 1.412(13) . ?
C86 C87 1.44(2) . ?
C86 H86 0.9500 . ?
C87 C88 1.37(2) . ?
C87 H87 0.9500 . ?
C88 C89 1.32(2) . ?
C88 H88 0.9500 . ?
C89 C90 1.413(16) . ?
C89 H89 0.9500 . ?
C90 H90 0.9500 . ?
C91 C96 1.368(13) . ?
C91 C92 1.399(12) . ?
C92 C93 1.370(14) . ?
C92 H92 0.9500 . ?
C93 C94 1.380(16) . ?
C93 H93 0.9500 . ?
C94 C95 1.370(17) . ?
C94 H94 0.9500 . ?
C95 C96 1.385(16) . ?
C95 H95 0.9500 . ?
C96 H96 0.9500 . ?
C97 C98 1.390(12) . ?
C97 C102 1.392(12) . ?
C98 C99 1.391(12) . ?
C98 H98 0.9500 . ?
C99 C100 1.374(15) . ?
C99 H99 0.9500 . ?
C100 C101 1.388(15) . ?
C100 H100 0.9500 . ?
C101 C102 1.388(13) . ?
C101 H101 0.9500 . ?
C102 H102 0.9500 . ?
C103 C108 1.385(18) . ?
C103 C104 1.407(14) . ?
C104 C105 1.395(18) . ?
C104 H104 0.9500 . ?
C105 C106 1.39(2) . ?
C105 H105 0.9500 . ?
C106 C107 1.385(19) . ?
C106 H106 0.9500 . ?
C107 C108 1.37(2) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C109 C110 1.159(13) . ?
C110 C111 1.444(13) . ?
C111 C116 1.394(15) . ?
C111 C112 1.405(14) . ?
C112 C113 1.379(14) . ?
C112 H112 0.9500 . ?
C113 C114 1.413(15) . ?
C113 H113 0.9500 . ?
C114 C115 1.395(15) . ?
C114 C117 1.499(13) . ?
C115 C116 1.372(14) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C117 C118 1.334(14) . ?
C117 C119 1.498(15) . ?
C118 C131 1.485(14) . ?
C118 C125 1.492(13) . ?
C119 C124 1.401(17) . ?
C119 C120 1.408(17) . ?
C120 C121 1.36(2) . ?
C120 H120 0.9500 . ?
C121 C122 1.38(3) . ?
C121 H121 0.9500 . ?
C122 C123 1.41(3) . ?
C122 H122 0.9500 . ?
C123 C124 1.393(19) . ?
C123 H123 0.9500 . ?
C124 H124 0.9500 . ?
C125 C126 1.373(15) . ?
C125 C130 1.406(15) . ?
C126 C127 1.372(15) . ?
C126 H126 0.9500 . ?
C127 C128 1.329(18) . ?
C127 H127 0.9500 . ?
C128 C129 1.366(19) . ?
C128 H128 0.9500 . ?
C129 C130 1.388(16) . ?
C129 H129 0.9500 . ?
C130 H130 0.9500 . ?
C131 C136 1.376(18) . ?
C131 C132 1.386(17) . ?
C132 C133 1.417(18) . ?
C132 H132 0.9500 . ?
C133 C134 1.40(2) . ?
C133 H133 0.9500 . ?
C134 C135 1.34(2) . ?
C134 H134 0.9500 . ?
C135 C136 1.407(19) . ?
C135 H135 0.9500 . ?
C136 H136 0.9500 . ?
C137 C138 1.162(12) . ?
C138 C139 1.444(13) . ?
C139 C144 1.374(16) . ?
C139 C140 1.406(16) . ?
C140 C141 1.393(16) . ?
C140 H140 0.9500 . ?
C141 C142 1.45(2) . ?
C141 H141 0.9500 . ?
C142 C143 1.37(2) . ?
C142 C145 1.533(19) . ?
C142 C245 1.67(3) . ?
C143 C144 1.375(16) . ?
C143 H143 0.9500 . ?
C144 H144 0.9500 . ?
C147 C148 1.367(17) . ?
C147 C152 1.390(18) . ?
C147 C246 1.527(17) . ?
C147 C146 1.533(17) . ?
C148 C149 1.384(16) . ?
C148 H148 0.9500 . ?
C149 C150 1.327(18) . ?
C149 H149 0.9500 . ?
C150 C151 1.348(18) . ?
C150 H150 0.9500 . ?
C151 C152 1.395(17) . ?
C151 H151 0.9500 . ?
C152 H152 0.9500 . ?
C145 C146 1.33(2) . ?
C145 C153 1.49(2) . ?
C146 C159 1.48(2) . ?
C153 C154 1.40(3) . ?
C153 C158 1.40(2) . ?
C154 C155 1.36(3) . ?
C154 H154 0.9500 . ?
C155 C156 1.44(3) . ?
C155 H155 0.9500 . ?
C156 C157 1.355(17) . ?
C156 H156 0.9500 . ?
C157 C158 1.37(3) . ?
C157 H157 0.9500 . ?
C158 H158 0.9500 . ?
C159 C160 1.35(3) . ?
C159 C164 1.40(3) . ?
C160 C161 1.34(3) . ?
C160 H160 0.9500 . ?
C161 C162 1.338(17) . ?
C161 H161 0.9500 . ?
C162 C163 1.356(17) . ?
C162 H162 0.9500 . ?
C163 C164 1.34(3) . ?
C163 H163 0.9500 . ?
C164 H164 0.9500 . ?
C245 C246 1.38(4) . ?
C245 C259 1.53(4) . ?
C246 C253 1.55(3) . ?
C253 C254 1.41(3) . ?
C253 C258 1.410(17) . ?
C254 C255 1.411(19) . ?
C254 H254 0.9500 . ?
C255 C256 1.404(19) . ?
C255 H255 0.9500 . ?
C256 C257 1.387(18) . ?
C256 H256 0.9500 . ?
C257 C258 1.407(18) . ?
C257 H257 0.9500 . ?
C258 H258 0.9500 . ?
C259 C264 1.38(4) . ?
C259 C260 1.38(4) . ?
C260 C261 1.391(18) . ?
C260 H260 0.9500 . ?
C261 C262 1.358(18) . ?
C261 H261 0.9500 . ?
C262 C263 1.39(4) . ?
C262 H262 0.9500 . ?
C263 C264 1.389(19) . ?
C263 H263 0.9500 . ?
C264 H264 0.9500 . ?
