#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:22:32 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180390 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/59/7205950.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205950
loop_
_publ_author_name
'Jin, Juan'
'Jia, Ming-Jun'
'Peng, Yu'
'Yu, Jie-Hui'
'Xu, Ji-Qing'
_publ_section_title
;
 New organically decorated cadmium halides incorporating the second or
 the third inorganic anionic groups
;
_journal_issue                   8
_journal_name_full               CrystEngComm
_journal_page_first              2942
_journal_paper_doi               10.1039/c1ce05038a
_journal_volume                  13
_journal_year                    2011
_chemical_formula_sum            'C18 H58 Br8 Cd3 N10 O13 S4'
_chemical_formula_weight         1727.46
_chemical_name_systematic
;
?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   27.198(5)
_cell_length_b                   13.261(3)
_cell_length_c                   13.222(3)
_cell_measurement_temperature    293(2)
_cell_volume                     4768.8(18)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        PROCESS-AUTO
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0670
_diffrn_reflns_av_sigmaI/netI    0.0408
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            40872
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         3.00
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.265
_exptl_absorpt_correction_T_max  0.438
_exptl_absorpt_correction_T_min  0.421
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
Higashi, T.(1995).Program for Absorption Correction.
Rigaku Corporation, Tokyo,Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.406
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       strip
_exptl_crystal_F_000             3312
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.125
_refine_diff_density_min         -2.269
_refine_diff_density_rms         0.305
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         5685
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0558
_refine_ls_R_factor_gt           0.0435
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0528P)²+23.8430P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1119
_refine_ls_wR_factor_ref         0.1167
_reflns_number_gt                4582
_reflns_number_total             5685
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1ce05038a.txt
_cod_data_source_block           1
_cod_original_cell_volume        4768.8(16)
_cod_original_sg_symbol_H-M      Pnma
_cod_database_code               7205950
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cd1 Cd 0.36319(2) 0.2500 -0.23786(5) 0.02995(16) Uani 1 2 d S . .
Cd2 Cd 0.37150(8) 0.2500 0.1500(6) 0.0213(6) Uani 0.86(2) 2 d SP . .
Cd2' Cd 0.3761(4) 0.2500 0.190(3) 0.017(4) Uani 0.14(2) 2 d SP . .
Cd3 Cd 0.40117(2) -0.2500 0.25349(4) 0.02201(14) Uani 1 2 d S . .
Br1 Br 0.38271(4) 0.2500 -0.44125(8) 0.0414(2) Uani 1 2 d S . .
Br2 Br 0.26660(3) 0.2500 -0.22949(6) 0.02845(19) Uani 1 2 d S . .
Br3 Br 0.40575(16) 0.2500 -0.04009(12) 0.0347(7) Uani 0.830(14) 2 d SP . .
Br3' Br 0.3791(11) 0.2500 -0.0202(11) 0.052(5) Uani 0.170(14) 2 d SP . .
Br4 Br 0.27559(4) 0.2500 0.08054(8) 0.0340(3) Uani 0.881(3) 2 d SP . .
Br4' Br 0.2870(4) 0.2500 0.2522(8) 0.061(3) Uani 0.119(3) 2 d SP . .
Br5 Br 0.46168(4) 0.2500 0.24572(7) 0.0392(2) Uani 1 2 d S . .
Br6 Br 0.49933(3) -0.2500 0.25076(7) 0.0322(2) Uani 1 2 d S . .
Br7 Br 0.36649(3) -0.2500 0.07216(6) 0.02732(18) Uani 1 2 d S . .
Br8 Br 0.36963(3) -0.2500 0.43688(6) 0.02939(19) Uani 1 2 d S . .
S1 S 0.37190(4) 0.00361(9) 0.25186(9) 0.0143(2) Uani 1 1 d . . .
S2 S 0.38378(8) -0.12353(14) -0.24906(17) 0.0532(5) Uani 1 1 d . . .
N1 N 0.22292(16) 0.0645(3) 0.9396(3) 0.0228(10) Uani 1 1 d . . .
H1A H 0.2020 0.0750 0.8879 0.080 Uiso 1 1 calc . . .
H1BA H 0.2346 0.1247 0.9596 0.080 Uiso 1 1 calc . . .
N2 N 0.27248(16) -0.0713(3) 1.0757(3) 0.0235(10) Uani 1 1 d . . .
H2A H 0.2936 -0.0807 1.1272 0.080 Uiso 1 1 calc . . .
H2BA H 0.2613 -0.1323 1.0564 0.080 Uiso 1 1 calc . . .
N3 N 0.47251(17) -0.0652(4) 1.0666(3) 0.0247(10) Uani 1 1 d . . .
H3A H 0.4811 -0.1269 1.0445 0.080 Uiso 1 1 calc . . .
H3B H 0.4514 -0.0730 1.1184 0.080 Uiso 1 1 calc . . .
N4 N 0.46561(16) 0.0645(4) 0.4482(3) 0.0246(10) Uani 1 1 d . . .
H4A H 0.4393 0.0721 0.4076 0.080 Uiso 1 1 calc . . .
H4B H 0.4759 0.1263 0.4667 0.080 Uiso 1 1 calc . . .
N5 N 0.3761(2) 0.0835(4) -0.2326(4) 0.0402(14) Uani 1 1 d . . .
O1 O 0.37073(14) 0.0722(3) 0.1644(3) 0.0245(8) Uani 1 1 d . . .
O2 O 0.41433(13) -0.0658(3) 0.2412(3) 0.0227(8) Uani 1 1 d . . .
O3 O 0.37687(13) 0.0604(3) 0.3480(3) 0.0219(8) Uani 1 1 d . . .
O4 O 0.32610(13) -0.0562(3) 0.2549(3) 0.0240(8) Uani 1 1 d . . .
OW1 O 0.3387(2) 0.2500 0.3113(5) 0.0354(14) Uani 1 2 d S . .
OW2 O 0.2678(3) 0.2500 0.4932(6) 0.0497(19) Uani 1 2 d S . .
OW3 O 0.5137(4) 0.2500 0.4998(9) 0.094(4) Uani 1 2 d S . .
OW4 O 0.2254(3) 0.2500 0.3101(8) 0.102(4) Uani 1 2 d S . .
OW5 O 0.4717(3) -0.2500 0.9527(7) 0.060(2) Uani 1 2 d S . .
C1 C 0.1958(2) 0.0156(5) 1.0257(4) 0.0277(12) Uani 1 1 d . . .
H1B H 0.1802 -0.0457 1.0020 0.033 Uiso 1 1 calc R . .
H1C H 0.1703 0.0608 1.0495 0.033 Uiso 1 1 calc R . .
C2 C 0.2300(2) -0.0091(4) 1.1118(4) 0.0245(12) Uani 1 1 d . . .
H2B H 0.2422 0.0529 1.1417 0.029 Uiso 1 1 calc R . .
H2C H 0.2122 -0.0459 1.1635 0.029 Uiso 1 1 calc R . .
C3 C 0.2642(2) 0.0003(5) 0.9050(4) 0.0274(13) Uani 1 1 d . . .
H3C H 0.2819 0.0349 0.8514 0.033 Uiso 1 1 calc R . .
H3D H 0.2512 -0.0619 0.8772 0.033 Uiso 1 1 calc R . .
C4 C 0.2993(2) -0.0241(5) 0.9893(4) 0.0278(12) Uani 1 1 d . . .
H4C H 0.3244 -0.0701 0.9649 0.033 Uiso 1 1 calc R . .
H4D H 0.3154 0.0371 1.0119 0.033 Uiso 1 1 calc R . .
C5 C 0.4479(2) -0.0096(5) 0.9840(4) 0.0305(13) Uani 1 1 d . . .
H5A H 0.4353 0.0538 1.0098 0.037 Uiso 1 1 calc R . .
H5B H 0.4202 -0.0488 0.9596 0.037 Uiso 1 1 calc R . .
C6 C 0.5173(2) -0.0110(5) 1.1031(4) 0.0313(13) Uani 1 1 d . . .
H6A H 0.5338 -0.0516 1.1537 0.038 Uiso 1 1 calc R . .
H6B H 0.5077 0.0522 1.1342 0.038 Uiso 1 1 calc R . .
C7 C 0.5054(2) 0.0130(5) 0.3915(4) 0.0281(12) Uani 1 1 d . . .
H7A H 0.5156 0.0547 0.3350 0.034 Uiso 1 1 calc R . .
H7B H 0.4932 -0.0504 0.3647 0.034 Uiso 1 1 calc R . .
C8 C 0.4509(2) 0.0069(5) 0.5399(5) 0.0299(13) Uani 1 1 d . . .
H8A H 0.4365 -0.0569 0.5196 0.036 Uiso 1 1 calc R . .
H8B H 0.4262 0.0446 0.5768 0.036 Uiso 1 1 calc R . .
C9 C 0.3785(2) -0.0023(5) -0.2383(4) 0.0285(13) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Cd1 N5 161.6(3) 7_565 . ?
N5 Cd1 Br2 98.92(16) 7_565 . ?
N5 Cd1 Br2 98.92(16) . . ?
N5 Cd1 Br1 90.01(15) 7_565 . ?
N5 Cd1 Br1 90.01(15) . . ?
Br2 Cd1 Br1 103.58(4) . . ?
N5 Cd1 Br3 84.73(14) 7_565 . ?
N5 Cd1 Br3 84.73(14) . . ?
Br2 Cd1 Br3 111.47(9) . . ?
Br1 Cd1 Br3 144.95(9) . . ?
N5 Cd1 Br3' 86.90(17) 7_565 . ?
N5 Cd1 Br3' 86.90(17) . . ?
Br2 Cd1 Br3' 96.1(6) . . ?
Br1 Cd1 Br3' 160.3(6) . . ?
Br3 Cd1 Br3' 15.3(5) . . ?
Cd2' Cd2 Br3' 161.3(12) . . ?
Cd2' Cd2 OW1 36.2(9) . . ?
Br3' Cd2 OW1 162.5(8) . . ?
Cd2' Cd2 O1 85.6(2) . 7_565 ?
Br3' Cd2 O1 94.6(2) . 7_565 ?
OW1 Cd2 O1 85.55(18) . 7_565 ?
Cd2' Cd2 O1 85.6(2) . . ?
Br3' Cd2 O1 94.6(2) . . ?
OW1 Cd2 O1 85.55(18) . . ?
O1 Cd2 O1 170.7(4) 7_565 . ?
Cd2' Cd2 Br4' 73.0(9) . . ?
Br3' Cd2 Br4' 125.7(8) . . ?
OW1 Cd2 Br4' 36.8(3) . . ?
O1 Cd2 Br4' 87.23(12) 7_565 . ?
O1 Cd2 Br4' 87.23(12) . . ?
Cd2' Cd2 Br3 146.2(9) . . ?
Br3' Cd2 Br3 15.1(7) . . ?
OW1 Cd2 Br3 177.6(3) . . ?
O1 Cd2 Br3 94.50(17) 7_565 . ?
O1 Cd2 Br3 94.50(17) . . ?
Br4' Cd2 Br3 140.8(3) . . ?
Cd2' Cd2 Br5 49.2(9) . . ?
Br3' Cd2 Br5 112.0(7) . . ?
OW1 Cd2 Br5 85.4(3) . . ?
O1 Cd2 Br5 88.33(17) 7_565 . ?
O1 Cd2 Br5 88.33(17) . . ?
Br4' Cd2 Br5 122.3(4) . . ?
Br3 Cd2 Br5 96.96(9) . . ?
Cd2' Cd2 Br4 122.8(9) . . ?
Br3' Cd2 Br4 75.9(8) . . ?
OW1 Cd2 Br4 86.68(16) . . ?
O1 Cd2 Br4 91.05(14) 7_565 . ?
O1 Cd2 Br4 91.05(14) . . ?
Br4' Cd2 Br4 49.8(2) . . ?
Br3 Cd2 Br4 90.9(2) . . ?
Br5 Cd2 Br4 172.1(3) . . ?
Cd2 Cd2' OW1 134.1(13) . . ?
Cd2 Cd2' O1 81.3(11) . . ?
OW1 Cd2' O1 95.0(7) . . ?
Cd2 Cd2' O1 81.3(11) . 7_565 ?
OW1 Cd2' O1 95.0(7) . 7_565 ?
O1 Cd2' O1 162(2) . 7_565 ?
Cd2 Cd2' Br5 121.1(14) . . ?
OW1 Cd2' Br5 104.8(19) . . ?
O1 Cd2' Br5 95.8(4) . . ?
O1 Cd2' Br5 95.8(4) 7_565 . ?
Cd2 Cd2' Br4' 95.3(12) . . ?
OW1 Cd2' Br4' 38.8(3) . . ?
O1 Cd2' Br4' 89.3(2) . . ?
O1 Cd2' Br4' 89.3(2) 7_565 . ?
Br5 Cd2' Br4' 143.7(19) . . ?
Cd2 Cd2' Br3' 15.1(10) . . ?
OW1 Cd2' Br3' 149.3(13) . . ?
O1 Cd2' Br3' 82.0(10) . . ?
O1 Cd2' Br3' 82.0(10) 7_565 . ?
Br5 Cd2' Br3' 105.9(10) . . ?
Br4' Cd2' Br3' 110.4(14) . . ?
Cd2 Cd2' Br4 48.7(9) . . ?
OW1 Cd2' Br4 85.5(4) . . ?
O1 Cd2' Br4 83.1(7) . . ?
O1 Cd2' Br4 83.1(7) 7_565 . ?
Br5 Cd2' Br4 169.7(15) . . ?
Br4' Cd2' Br4 46.6(4) . . ?
Br3' Cd2' Br4 63.8(10) . . ?
O2 Cd3 O2 161.70(17) . 7 ?
O2 Cd3 Br8 96.33(9) . . ?
O2 Cd3 Br8 96.33(9) 7 . ?
O2 Cd3 Br7 89.53(9) . . ?
O2 Cd3 Br7 89.53(9) 7 . ?
Br8 Cd3 Br7 139.05(4) . . ?
O2 Cd3 Br6 81.63(8) . . ?
O2 Cd3 Br6 81.63(8) 7 . ?
Br8 Cd3 Br6 110.26(3) . . ?
Br7 Cd3 Br6 110.70(3) . . ?
Br3' Br3 Cd2 49.7(6) . . ?
Br3' Br3 Cd1 86.1(6) . . ?
Cd2 Br3 Cd1 135.78(19) . . ?
Br3 Br3' Cd2 115.2(9) . . ?
Br3 Br3' Cd2' 111.6(8) . . ?
Cd2 Br3' Cd2' 3.6(3) . . ?
Br3 Br3' Cd1 78.6(9) . . ?
Cd2 Br3' Cd1 166.2(14) . . ?
Cd2' Br3' Cd1 169.8(13) . . ?
Br4' Br4 Cd2 62.9(3) . . ?
Br4' Br4 Cd2' 54.4(7) . . ?
Cd2 Br4 Cd2' 8.5(5) . . ?
OW1 Br4' OW4 126.3(7) . . ?
OW1 Br4' Br4 126.9(7) . . ?
OW4 Br4' Br4 106.8(6) . . ?
OW1 Br4' Cd2' 47.8(11) . . ?
OW4 Br4' Cd2' 174.2(12) . . ?
Br4 Br4' Cd2' 79.0(10) . . ?
OW1 Br4' Cd2 59.5(5) . . ?
OW4 Br4' Cd2 174.1(6) . . ?
Br4 Br4' Cd2 67.3(3) . . ?
Cd2' Br4' Cd2 11.7(8) . . ?
Cd2' Br5 Cd2 9.7(8) . . ?
O1 S1 O4 109.6(2) . . ?
O1 S1 O2 109.0(2) . . ?
O4 S1 O2 109.0(2) . . ?
O1 S1 O3 111.2(2) . . ?
O4 S1 O3 109.0(2) . . ?
O2 S1 O3 109.0(2) . . ?
C3 N1 C1 111.0(4) . . ?
C4 N2 C2 113.0(4) . . ?
C5 N3 C6 111.6(4) . . ?
C7 N4 C8 111.8(4) . . ?
C9 N5 Cd1 172.1(5) . . ?
S1 O1 Cd2 132.7(3) . . ?
S1 O1 Cd2' 119.9(11) . . ?
Cd2 O1 Cd2' 13.1(9) . . ?
S1 O2 Cd3 119.6(2) . . ?
Br4' OW1 Cd2' 93.3(11) . . ?
Br4' OW1 Cd2 83.6(5) . . ?
Cd2' OW1 Cd2 9.7(8) . . ?
N1 C1 C2 111.4(4) . . ?
N2 C2 C1 110.8(4) . . ?
N1 C3 C4 112.1(5) . . ?
N2 C4 C3 110.3(4) . . ?
N3 C5 C6 111.5(4) . 5_657 ?
N3 C6 C5 110.6(5) . 5_657 ?
N4 C7 C8 110.4(4) . 5_656 ?
N4 C8 C7 111.5(5) . 5_656 ?
N5 C9 S2 177.8(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 N5 2.237(6) 7_565 ?
Cd1 N5 2.237(6) . ?
Cd1 Br2 2.6294(12) . ?
Cd1 Br1 2.7412(13) . ?
Cd1 Br3 2.8596(16) . ?
Cd1 Br3' 2.911(11) . ?
Cd2 Cd2' 0.54(4) . ?
Cd2 Br3' 2.259(18) . ?
Cd2 OW1 2.313(9) . ?
Cd2 O1 2.366(4) 7_565 ?
Cd2 O1 2.366(4) . ?
Cd2 Br4' 2.667(12) . ?
Cd2 Br3 2.680(7) . ?
Cd2 Br5 2.760(5) . ?
Cd2 Br4 2.765(5) . ?
Cd2' OW1 1.90(3) . ?
Cd2' O1 2.387(8) . ?
Cd2' O1 2.387(8) 7_565 ?
Cd2' Br5 2.44(2) . ?
Cd2' Br4' 2.561(15) . ?
Cd2' Br3' 2.78(5) . ?
Cd2' Br4 3.09(3) . ?
Cd3 O2 2.474(4) . ?
Cd3 O2 2.474(4) 7 ?
Cd3 Br8 2.5720(11) . ?
Cd3 Br7 2.5764(10) . ?
Cd3 Br6 2.6700(11) . ?
Br3 Br3' 0.77(3) . ?
Br4 Br4' 2.290(10) . ?
Br4' OW1 1.609(12) . ?
Br4' OW4 1.842(15) . ?
S1 O1 1.472(4) . ?
S1 O4 1.477(4) . ?
S1 O2 1.483(4) . ?
S1 O3 1.484(4) . ?
S2 C9 1.620(7) . ?
N1 C3 1.482(7) . ?
N1 C1 1.503(7) . ?
N2 C4 1.493(7) . ?
N2 C2 1.498(7) . ?
N3 C5 1.479(7) . ?
N3 C6 1.493(7) . ?
N4 C7 1.483(7) . ?
N4 C8 1.487(7) . ?
N5 C9 1.142(8) . ?
C1 C2 1.506(7) . ?
C3 C4 1.503(8) . ?
C5 C6 1.516(8) 5_657 ?
C6 C5 1.516(8) 5_657 ?
C7 C8 1.518(8) 5_656 ?
C8 C7 1.518(8) 5_656 ?
