#------------------------------------------------------------------------------
#$Date: 2016-03-26 18:08:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180413 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/82/7208222.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208222
loop_
_publ_author_name
'Yan, Xuhuan'
'Yan, Zhenzhong'
'Zhang, Ye'
'Liu, Weisheng'
'Tang, Yu'
'Tan, Minyu'
_publ_section_title
;
 Anions make the difference: conversion from zero- to one-dimensional
 structures and luminescent properties of lanthanide-based complexes
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              4989
_journal_paper_doi               10.1039/c2ce25210d
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C59 H51 Eu N12 O26'
_chemical_formula_weight         1496.08
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.5600(10)
_cell_angle_beta                 109.3340(10)
_cell_angle_gamma                114.1270(10)
_cell_formula_units_Z            2
_cell_length_a                   13.6916(11)
_cell_length_b                   15.9050(12)
_cell_length_c                   17.5187(13)
_cell_measurement_temperature    294(2)
_cell_volume                     3144.3(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0284
_diffrn_reflns_av_sigmaI/netI    0.0665
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            16559
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.69
_exptl_absorpt_coefficient_mu    1.093
_exptl_absorpt_correction_T_max  0.8192
_exptl_absorpt_correction_T_min  0.7008
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.580
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.655
_refine_diff_density_min         -0.806
_refine_diff_density_rms         0.076
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     876
_refine_ls_number_reflns         11520
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0776
_refine_ls_R_factor_gt           0.0498
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0487P)²+0.8839P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1025
_refine_ls_wR_factor_ref         0.1184
_reflns_number_gt                8184
_reflns_number_total             11520
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25210d.txt
_cod_data_source_block           852908
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7208222
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.96297(2) 0.690071(18) 0.729834(17) 0.05094(10) Uani 1 1 d .
C1 C 1.0614(4) 0.8947(3) 0.6636(3) 0.0511(12) Uani 1 1 d .
C2 C 1.1699(4) 0.9637(3) 0.6636(3) 0.0515(12) Uani 1 1 d .
C3 C 1.1847(4) 1.0442(3) 0.6395(3) 0.0563(13) Uani 1 1 d .
H3 H 1.2571 1.0861 0.6411 0.068 Uiso 1 1 calc R
C4 C 1.0910(5) 1.0637(4) 0.6124(3) 0.0600(14) Uani 1 1 d .
C5 C 0.9845(5) 1.0034(4) 0.6116(3) 0.0597(13) Uani 1 1 d .
H5 H 0.9223 1.0172 0.5940 0.072 Uiso 1 1 calc R
C6 C 0.9711(4) 0.9220(3) 0.6372(3) 0.0533(12) Uani 1 1 d .
C7 C 1.2074(5) -0.0401(5) 0.8804(4) 0.0811(19) Uani 1 1 d .
H7 H 1.1966 -0.1022 0.8777 0.097 Uiso 1 1 calc R
C8 C 1.1152(5) -0.0210(4) 0.8738(3) 0.0652(15) Uani 1 1 d .
C9 C 1.1311(6) 0.0717(5) 0.8796(4) 0.088(2) Uani 1 1 d .
C10 C 1.3148(6) 0.0317(7) 0.8907(4) 0.111(3) Uani 1 1 d .
H10 H 1.3773 0.0192 0.8971 0.134 Uiso 1 1 calc R
C11 C 1.3273(7) 0.1207(7) 0.8914(5) 0.121(4) Uani 1 1 d .
H11 H 1.3988 0.1682 0.8959 0.145 Uiso 1 1 calc R
C12 C 1.2419(8) 0.1443(5) 0.8858(5) 0.114(3) Uani 1 1 d .
H12 H 1.2542 0.2063 0.8860 0.136 Uiso 1 1 calc R
C13 C 0.5888(4) 0.4900(4) 0.6942(3) 0.0539(12) Uani 1 1 d .
C14 C 0.7123(4) 0.5507(3) 0.7439(3) 0.0489(12) Uani 1 1 d .
C15 C 0.7562(4) 0.5242(3) 0.8191(3) 0.0494(12) Uani 1 1 d .
C16 C 0.6867(4) 0.4469(3) 0.8387(3) 0.0546(13) Uani 1 1 d .
H16 H 0.7187 0.4328 0.8881 0.065 Uiso 1 1 calc R
C17 C 0.5713(4) 0.3914(3) 0.7856(3) 0.0530(12) Uani 1 1 d .
C18 C 0.5195(4) 0.4119(3) 0.7125(3) 0.0543(13) Uani 1 1 d .
H18 H 0.4401 0.3736 0.6770 0.065 Uiso 1 1 calc R
C19 C 1.2331(4) 0.7094(3) 0.8215(3) 0.0469(11) Uani 1 1 d .
C20 C 1.3462(5) 0.6586(3) 0.7615(3) 0.0574(13) Uani 1 1 d .
H20 H 1.3566 0.6384 0.7143 0.069 Uiso 1 1 calc R
C21 C 1.3200(4) 0.7213(4) 0.9017(3) 0.0566(13) Uani 1 1 d .
C22 C 1.4219(5) 0.6692(4) 0.8408(4) 0.0603(14) Uani 1 1 d .
C23 C 1.4100(5) 0.7016(4) 0.9119(4) 0.0640(14) Uani 1 1 d .
H23 H 1.4626 0.7097 0.9655 0.077 Uiso 1 1 calc R
C24 C 1.2541(4) 0.6782(3) 0.7525(3) 0.0486(12) Uani 1 1 d .
C25 C 0.7030(6) 0.3876(4) 0.5846(4) 0.0820(18) Uani 1 1 d .
H25 H 0.7490 0.4411 0.5720 0.098 Uiso 1 1 calc R
C26 C 0.7522(4) 0.3704(3) 0.6603(3) 0.0544(13) Uani 1 1 d .
C27 C 0.6809(5) 0.2893(4) 0.6776(4) 0.0576(13) Uani 1 1 d .
C28 C 0.5646(5) 0.2292(4) 0.6205(5) 0.0836(19) Uani 1 1 d .
H28 H 0.5171 0.1751 0.6316 0.100 Uiso 1 1 calc R
C29 C 0.6756(6) 0.1822(4) 0.7668(5) 0.085(2) Uani 1 1 d .
H29A H 0.6439 0.1308 0.7158 0.102 Uiso 1 1 calc R
H29B H 0.6120 0.1761 0.7826 0.102 Uiso 1 1 calc R
C30 C 0.8748(4) 0.4417(3) 0.7189(3) 0.0507(12) Uani 1 1 d .
C31 C 1.0528(4) 0.4815(4) 0.8452(3) 0.0653(15) Uani 1 1 d .
H31A H 1.0498 0.4839 0.8999 0.078 Uiso 1 1 calc R
H31B H 1.0763 0.5457 0.8387 0.078 Uiso 1 1 calc R
C32 C 1.1448(4) 0.4530(3) 0.8438(3) 0.0550(13) Uani 1 1 d .
C33 C 1.1502(6) 0.4202(4) 0.7700(4) 0.0800(18) Uani 1 1 d .
H33 H 1.0947 0.4136 0.7184 0.096 Uiso 1 1 calc R
C34 C 1.2298(5) 0.4628(4) 0.9190(4) 0.0788(17) Uani 1 1 d .
H34 H 1.2273 0.4842 0.9697 0.095 Uiso 1 1 calc R
C35 C 0.7706(7) 0.1766(5) 0.8373(5) 0.101(2) Uani 1 1 d .
H35A H 0.8033 0.2304 0.8866 0.122 Uiso 1 1 calc R
H35B H 0.7351 0.1179 0.8520 0.122 Uiso 1 1 calc R
C36 C 0.8243(6) 0.0927(4) 0.7471(4) 0.0805(18) Uani 1 1 d .
H36A H 0.7582 0.0388 0.7485 0.097 Uiso 1 1 calc R
H36B H 0.8870 0.0759 0.7559 0.097 Uiso 1 1 calc R
C37 C 0.7873(5) 0.1084(4) 0.6611(4) 0.0680(15) Uani 1 1 d .
C38 C 0.8545(6) 0.1905(5) 0.6472(4) 0.0785(17) Uani 1 1 d .
H38 H 0.9239 0.2373 0.6918 0.094 Uiso 1 1 calc R
C39 C 0.6872(6) 0.0385(5) 0.5934(5) 0.094(2) Uani 1 1 d .
H39 H 0.6412 -0.0194 0.6006 0.113 Uiso 1 1 calc R
C40 C 0.8230(8) 0.2062(6) 0.5696(6) 0.101(2) Uani 1 1 d .
H40 H 0.8700 0.2635 0.5622 0.121 Uiso 1 1 calc R
C41 C 0.7244(10) 0.1388(9) 0.5043(6) 0.118(3) Uani 1 1 d .
H41 H 0.7034 0.1499 0.4518 0.142 Uiso 1 1 calc R
C42 C 0.6544(8) 0.0542(7) 0.5137(5) 0.118(3) Uani 1 1 d .
H42 H 0.5860 0.0078 0.4681 0.142 Uiso 1 1 calc R
C43 C 0.8018(5) -0.1775(4) 0.8509(5) 0.099(2) Uani 1 1 d .
H43A H 0.7836 -0.2302 0.8056 0.119 Uiso 1 1 calc R
H43B H 0.8072 -0.1992 0.9010 0.119 Uiso 1 1 calc R
C44 C 1.0008(5) -0.1068(4) 0.8578(3) 0.0602(14) Uani 1 1 d .
C46 C 1.2375(8) 0.3970(6) 0.7722(6) 0.116(3) Uani 1 1 d .
H46 H 1.2387 0.3724 0.7220 0.140 Uiso 1 1 calc R
C47 C 1.3227(8) 0.4099(6) 0.8483(8) 0.124(3) Uani 1 1 d .
H47 H 1.3834 0.3968 0.8496 0.149 Uiso 1 1 calc R
C48 C 1.3178(6) 0.4416(6) 0.9206(6) 0.103(2) Uani 1 1 d .
H48 H 1.3745 0.4493 0.9721 0.124 Uiso 1 1 calc R
C49 C 0.5882(8) 0.3279(6) 0.5276(5) 0.110(3) Uani 1 1 d .
H49 H 0.5574 0.3399 0.4768 0.132 Uiso 1 1 calc R
C50 C 0.5207(7) 0.2513(6) 0.5469(5) 0.113(3) Uani 1 1 d .
H50 H 0.4423 0.2122 0.5093 0.136 Uiso 1 1 calc R
C51 C 0.6940(4) -0.0998(3) 0.8893(2) 0.0771(17) Uani 1 1 d G
H51 H 0.7447 -0.0828 0.9458 0.093 Uiso 1 1 calc R
C52 C 0.7068(3) -0.1511(3) 0.8269(3) 0.0624(14) Uani 1 1 d G
C53 C 0.6309(5) -0.1764(3) 0.7425(3) 0.107(3) Uani 1 1 d G
H53 H 0.6395 -0.2107 0.7008 0.128 Uiso 1 1 calc R
C59 C 0.5422(4) -0.1505(4) 0.7205(3) 0.162(6) Uani 1 1 d G
H59 H 0.4914 -0.1674 0.6641 0.194 Uiso 1 1 calc R
C58 C 0.5293(4) -0.0992(4) 0.7829(5) 0.167(6) Uani 1 1 d G
H58 H 0.4699 -0.0818 0.7682 0.200 Uiso 1 1 calc R
C60 C 0.6052(5) -0.0738(3) 0.8673(4) 0.128(3) Uani 1 1 d G
H60 H 0.5966 -0.0395 0.9090 0.154 Uiso 1 1 calc R
C54 C 0.9582(9) 0.1870(6) 0.8975(5) 0.121(3) Uani 1 1 d .
H54A H 0.9847 0.2468 0.9385 0.145 Uiso 1 1 calc R
H54B H 0.9228 0.1347 0.9194 0.145 Uiso 1 1 calc R
C55 C 0.8564(6) 0.6432(5) 0.5087(4) 0.101(2) Uani 1 1 d .
H55A H 0.9350 0.6968 0.5284 0.121 Uiso 1 1 calc R
H55B H 0.8010 0.6616 0.4744 0.121 Uiso 1 1 calc R
C56 C 0.8478(8) 0.5597(7) 0.4579(5) 0.139(3) Uani 1 1 d .
H56A H 0.9021 0.5412 0.4921 0.208 Uiso 1 1 calc R
H56B H 0.8664 0.5751 0.4114 0.208 Uiso 1 1 calc R
H56C H 0.7691 0.5074 0.4367 0.208 Uiso 1 1 calc R
C57 C 1.0606(8) 0.1856(5) 0.8902(5) 0.131(4) Uani 1 1 d .
H57A H 1.0715 0.2091 0.8434 0.157 Uiso 1 1 calc R
H57B H 1.1307 0.2269 0.9416 0.157 Uiso 1 1 calc R
N1 N 1.1770(4) 0.6645(3) 0.6671(3) 0.0580(11) Uani 1 1 d .
N2 N 1.3046(5) 0.7542(5) 0.9766(3) 0.0793(15) Uani 1 1 d .
N3 N 0.5293(5) 0.5127(4) 0.6201(3) 0.0794(14) Uani 1 1 d .
N4 N 0.8783(4) 0.5799(3) 0.8806(3) 0.0606(11) Uani 1 1 d .
N5 N 0.4998(5) 0.3084(4) 0.8064(4) 0.0772(14) Uani 1 1 d .
N6 N 1.2728(4) 0.9484(4) 0.6901(3) 0.0699(13) Uani 1 1 d .
N7 N 1.1063(6) 1.1490(4) 0.5848(4) 0.0862(16) Uani 1 1 d .
N8 N 0.8551(4) 0.8605(3) 0.6341(3) 0.0675(12) Uani 1 1 d .
N9 N 1.5171(5) 0.6455(4) 0.8507(4) 0.0788(14) Uani 1 1 d .
N10 N 0.8655(5) 0.1780(3) 0.8170(3) 0.0789(14) Uani 1 1 d .
N11 N 0.9353(3) 0.4163(3) 0.7796(3) 0.0583(11) Uani 1 1 d .
H11A H 0.9028 0.3574 0.7801 0.070 Uiso 1 1 calc R
N12 N 0.9158(4) -0.0951(3) 0.8680(3) 0.0807(15) Uani 1 1 d .
H12' H 0.9271 -0.0377 0.8851 0.097 Uiso 1 1 calc R
O1 O 0.7755(3) 0.6205(2) 0.7247(2) 0.0616(9) Uani 1 1 d .
O2 O 1.0765(3) 0.6530(3) 0.6516(2) 0.0640(9) Uani 1 1 d .
O3 O 1.1504(3) 0.7271(2) 0.8187(2) 0.0533(8) Uani 1 1 d .
O4 O 0.9202(3) 0.5243(2) 0.7112(2) 0.0651(10) Uani 1 1 d .
O5 O 0.8314(3) 0.6225(3) 0.5805(2) 0.0713(10) Uani 1 1 d D
O6 O 1.0498(3) 0.8197(2) 0.6858(2) 0.0651(10) Uani 1 1 d .
O7 O 0.9523(3) 0.6387(2) 0.8633(2) 0.0646(10) Uani 1 1 d .
O8 O 0.9898(3) -0.1886(2) 0.8366(2) 0.0660(10) Uani 1 1 d .
O9 O 1.2126(4) 0.6638(3) 0.6123(2) 0.0899(13) Uani 1 1 d .
O10 O 1.3587(6) 0.8365(4) 1.0134(4) 0.138(2) Uani 1 1 d .
O11 O 1.2362(5) 0.6922(4) 0.9964(3) 0.125(2) Uani 1 1 d .
O12 O 0.9052(4) 0.5650(4) 0.9493(3) 0.1125(19) Uani 1 1 d .
O13 O 0.4012(4) 0.2537(3) 0.7549(3) 0.1123(17) Uani 1 1 d .
O14 O 0.5848(5) 0.5681(4) 0.5908(3) 0.142(2) Uani 1 1 d .
O15 O 1.2620(4) 0.8710(4) 0.6984(4) 0.127(2) Uani 1 1 d .
O16 O 1.3673(3) 1.0126(3) 0.7008(3) 0.0972(14) Uani 1 1 d .
O17 O 1.2011(4) 1.1990(4) 0.5842(4) 0.128(2) Uani 1 1 d .
O18 O 1.0214(5) 1.1619(4) 0.5582(4) 0.135(2) Uani 1 1 d .
O19 O 0.7774(4) 0.8770(4) 0.6009(4) 0.142(2) Uani 1 1 d .
O20 O 0.8396(4) 0.7929(3) 0.6636(3) 0.0996(15) Uani 1 1 d .
O21 O 0.4253(4) 0.4729(5) 0.5886(4) 0.161(3) Uani 1 1 d .
O22 O 1.5233(4) 0.6134(4) 0.7875(4) 0.1078(16) Uani 1 1 d .
O23 O 1.5864(4) 0.6604(4) 0.9221(4) 0.1080(16) Uani 1 1 d .
O24 O 0.5429(4) 0.2999(4) 0.8760(4) 0.136(2) Uani 1 1 d .
O25 O 0.7297(3) 0.2746(2) 0.7531(2) 0.0668(10) Uani 1 1 d .
O26 O 1.0411(4) 0.0887(3) 0.8764(3) 0.1080(17) Uani 1 1 d .
H5O H 0.762(3) 0.583(3) 0.586(3) 0.050(13) Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Eu1 O3 86.26(12) . .
O6 Eu1 O1 128.16(12) . .
O3 Eu1 O1 139.02(12) . .
O6 Eu1 O8 81.29(13) . 1_565
O3 Eu1 O8 83.28(12) . 1_565
O1 Eu1 O8 81.47(12) . 1_565
O6 Eu1 O4 140.96(13) . .
O3 Eu1 O4 85.70(12) . .
O1 Eu1 O4 79.08(12) . .
O8 Eu1 O4 135.28(12) 1_565 .
O6 Eu1 O5 81.82(13) . .
O3 Eu1 O5 139.69(13) . .
O1 Eu1 O5 74.59(13) . .
O8 Eu1 O5 131.95(14) 1_565 .
O4 Eu1 O5 80.02(12) . .
O6 Eu1 O2 71.43(12) . .
O3 Eu1 O2 66.93(11) . .
O1 Eu1 O2 138.25(12) . .
O8 Eu1 O2 140.23(12) 1_565 .
O4 Eu1 O2 70.27(12) . .
O5 Eu1 O2 72.77(12) . .
O6 Eu1 O7 142.81(12) . .
O3 Eu1 O7 72.84(11) . .
O1 Eu1 O7 66.20(11) . .
O8 Eu1 O7 66.26(12) 1_565 .
O4 Eu1 O7 69.06(11) . .
O5 Eu1 O7 133.45(12) . .
O2 Eu1 O7 123.75(12) . .
O6 Eu1 O20 59.57(12) . .
O3 Eu1 O20 137.24(12) . .
O1 Eu1 O20 68.63(11) . .
O8 Eu1 O20 67.82(14) 1_565 .
O4 Eu1 O20 136.97(13) . .
O5 Eu1 O20 64.80(14) . .
O2 Eu1 O20 117.70(12) . .
O7 Eu1 O20 118.55(12) . .
O6 Eu1 H5O 98.9(7) . .
O3 Eu1 H5O 151.9(9) . .
O1 Eu1 H5O 55.1(6) . .
O8 Eu1 H5O 124.7(9) 1_565 .
O4 Eu1 H5O 72.9(9) . .
O5 Eu1 H5O 20.2(5) . .
O2 Eu1 H5O 88.4(7) . .
O7 Eu1 H5O 114.1(6) . .
O20 Eu1 H5O 65.5(10) . .
O6 C1 C6 124.7(4) . .
O6 C1 C2 123.0(5) . .
C6 C1 C2 112.3(4) . .
C3 C2 C1 124.4(5) . .
C3 C2 N6 115.6(4) . .
C1 C2 N6 120.0(4) . .
C2 C3 C4 119.4(5) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C5 C4 C3 120.8(5) . .
C5 C4 N7 119.9(5) . .
C3 C4 N7 119.4(5) . .
C4 C5 C6 119.1(5) . .
C4 C5 H5 120.4 . .
C6 C5 H5 120.4 . .
C5 C6 C1 124.0(4) . .
C5 C6 N8 116.2(5) . .
C1 C6 N8 119.8(4) . .
C10 C7 C8 121.0(7) . .
C10 C7 H7 119.5 . .
C8 C7 H7 119.5 . .
C9 C8 C7 120.0(6) . .
C9 C8 C44 124.4(6) . .
C7 C8 C44 115.6(5) . .
O26 C9 C8 118.6(6) . .
O26 C9 C12 123.5(7) . .
C8 C9 C12 117.9(8) . .
C11 C10 C7 118.5(9) . .
C11 C10 H10 120.7 . .
C7 C10 H10 120.7 . .
C12 C11 C10 123.5(8) . .
C12 C11 H11 118.2 . .
C10 C11 H11 118.2 . .
C11 C12 C9 118.8(8) . .
C11 C12 H12 120.6 . .
C9 C12 H12 120.6 . .
C18 C13 C14 124.5(5) . .
C18 C13 N3 116.3(5) . .
C14 C13 N3 119.2(5) . .
O1 C14 C13 123.6(5) . .
O1 C14 C15 123.7(4) . .
C13 C14 C15 112.7(4) . .
C16 C15 C14 123.1(4) . .
C16 C15 N4 115.4(4) . .
C14 C15 N4 121.4(4) . .
C17 C16 C15 119.7(5) . .
C17 C16 H16 120.2 . .
C15 C16 H16 120.2 . .
C16 C17 C18 121.8(5) . .
C16 C17 N5 118.9(5) . .
C18 C17 N5 119.3(5) . .
C13 C18 C17 118.2(5) . .
C13 C18 H18 120.9 . .
C17 C18 H18 120.9 . .
O3 C19 C24 127.3(5) . .
O3 C19 C21 120.0(4) . .
C24 C19 C21 112.7(4) . .
C22 C20 C24 119.5(5) . .
C22 C20 H20 120.3 . .
C24 C20 H20 120.3 . .
C23 C21 C19 124.9(5) . .
C23 C21 N2 119.2(5) . .
C19 C21 N2 115.9(5) . .
C20 C22 C23 121.3(5) . .
C20 C22 N9 119.8(5) . .
C23 C22 N9 118.9(6) . .
C21 C23 C22 118.3(5) . .
C21 C23 H23 120.8 . .
C22 C23 H23 120.8 . .
C20 C24 C19 123.3(5) . .
C20 C24 N1 116.5(4) . .
C19 C24 N1 120.2(4) . .
C49 C25 C26 121.9(7) . .
C49 C25 H25 119.0 . .
C26 C25 H25 119.0 . .
C25 C26 C27 117.9(5) . .
C25 C26 C30 117.5(5) . .
C27 C26 C30 124.6(5) . .
O25 C27 C28 122.5(6) . .
O25 C27 C26 117.1(4) . .
C28 C27 C26 120.3(6) . .
C50 C28 C27 118.8(7) . .
C50 C28 H28 120.6 . .
C27 C28 H28 120.6 . .
O25 C29 C35 106.7(5) . .
O25 C29 H29A 110.4 . .
C35 C29 H29A 110.4 . .
O25 C29 H29B 110.4 . .
C35 C29 H29B 110.4 . .
H29A C29 H29B 108.6 . .
O4 C30 N11 120.8(5) . .
O4 C30 C26 120.3(5) . .
N11 C30 C26 118.9(4) . .
N11 C31 C32 113.9(4) . .
N11 C31 H31A 108.8 . .
C32 C31 H31A 108.8 . .
N11 C31 H31B 108.8 . .
C32 C31 H31B 108.8 . .
H31A C31 H31B 107.7 . .
C33 C32 C34 117.9(6) . .
C33 C32 C31 122.5(5) . .
C34 C32 C31 119.5(5) . .
C32 C33 C46 120.3(7) . .
C32 C33 H33 119.9 . .
C46 C33 H33 119.9 . .
C48 C34 C32 121.3(6) . .
C48 C34 H34 119.3 . .
C32 C34 H34 119.3 . .
N10 C35 C29 114.3(5) . .
N10 C35 H35A 108.7 . .
C29 C35 H35A 108.7 . .
N10 C35 H35B 108.7 . .
C29 C35 H35B 108.7 . .
H35A C35 H35B 107.6 . .
N10 C36 C37 113.3(5) . .
N10 C36 H36A 108.9 . .
C37 C36 H36A 108.9 . .
N10 C36 H36B 108.9 . .
C37 C36 H36B 108.9 . .
H36A C36 H36B 107.7 . .
C38 C37 C39 118.0(6) . .
C38 C37 C36 120.8(6) . .
C39 C37 C36 121.1(6) . .
C37 C38 C40 121.9(7) . .
C37 C38 H38 119.0 . .
C40 C38 H38 119.0 . .
C37 C39 C42 120.3(7) . .
C37 C39 H39 119.9 . .
C42 C39 H39 119.9 . .
C41 C40 C38 119.8(8) . .
C41 C40 H40 120.1 . .
C38 C40 H40 120.1 . .
C40 C41 C42 121.1(9) . .
C40 C41 H41 119.5 . .
C42 C41 H41 119.5 . .
C41 C42 C39 118.8(8) . .
C41 C42 H42 120.6 . .
C39 C42 H42 120.6 . .
C52 C43 N12 111.1(5) . .
C52 C43 H43A 109.4 . .
N12 C43 H43A 109.4 . .
C52 C43 H43B 109.4 . .
N12 C43 H43B 109.4 . .
H43A C43 H43B 108.0 . .
O8 C44 N12 120.9(5) . .
O8 C44 C8 118.5(5) . .
N12 C44 C8 120.6(5) . .
C47 C46 C33 120.4(8) . .
C47 C46 H46 119.8 . .
C33 C46 H46 119.8 . .
C48 C47 C46 119.6(8) . .
C48 C47 H47 120.2 . .
C46 C47 H47 120.2 . .
C47 C48 C34 120.4(8) . .
C47 C48 H48 119.8 . .
C34 C48 H48 119.8 . .
C50 C49 C25 118.9(7) . .
C50 C49 H49 120.5 . .
C25 C49 H49 120.5 . .
C49 C50 C28 122.1(7) . .
C49 C50 H50 118.9 . .
C28 C50 H50 118.9 . .
C52 C51 C60 120.0 . .
C52 C51 H51 120.0 . .
C60 C51 H51 120.0 . .
C53 C52 C51 120.0 . .
C53 C52 C43 120.5(5) . .
C51 C52 C43 119.5(5) . .
C52 C53 C59 120.0 . .
C52 C53 H53 120.0 . .
C59 C53 H53 120.0 . .
C58 C59 C53 120.0 . .
C58 C59 H59 120.0 . .
C53 C59 H59 120.0 . .
C60 C58 C59 120.0 . .
C60 C58 H58 120.0 . .
C59 C58 H58 120.0 . .
C58 C60 C51 120.0 . .
C58 C60 H60 120.0 . .
C51 C60 H60 120.0 . .
C57 C54 N10 115.2(7) . .
C57 C54 H54A 108.5 . .
N10 C54 H54A 108.5 . .
C57 C54 H54B 108.5 . .
N10 C54 H54B 108.5 . .
H54A C54 H54B 107.5 . .
O5 C55 C56 110.5(6) . .
O5 C55 H55A 109.5 . .
C56 C55 H55A 109.5 . .
O5 C55 H55B 109.5 . .
C56 C55 H55B 109.5 . .
H55A C55 H55B 108.1 . .
C55 C56 H56A 109.5 . .
C55 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
C55 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
O26 C57 C54 108.2(7) . .
O26 C57 H57A 110.1 . .
C54 C57 H57A 110.1 . .
O26 C57 H57B 110.1 . .
C54 C57 H57B 110.1 . .
H57A C57 H57B 108.4 . .
O9 N1 O2 121.8(5) . .
O9 N1 C24 118.7(5) . .
O2 N1 C24 119.5(4) . .
O10 N2 O11 125.0(6) . .
O10 N2 C21 118.3(6) . .
O11 N2 C21 116.6(6) . .
O21 N3 O14 121.2(6) . .
O21 N3 C13 118.3(5) . .
O14 N3 C13 120.5(5) . .
O12 N4 O7 120.7(4) . .
O12 N4 C15 118.3(4) . .
O7 N4 C15 121.0(4) . .
O13 N5 O24 123.9(6) . .
O13 N5 C17 118.5(6) . .
O24 N5 C17 117.6(5) . .
O15 N6 O16 120.8(5) . .
O15 N6 C2 119.8(5) . .
O16 N6 C2 119.4(5) . .
O18 N7 O17 124.2(5) . .
O18 N7 C4 117.8(5) . .
O17 N7 C4 117.8(6) . .
O19 N8 O20 121.4(5) . .
O19 N8 C6 118.4(5) . .
O20 N8 C6 120.1(5) . .
O22 N9 O23 123.8(6) . .
O22 N9 C22 118.1(6) . .
O23 N9 C22 118.1(6) . .
C35 N10 C36 112.0(5) . .
C35 N10 C54 106.3(6) . .
C36 N10 C54 113.5(5) . .
C30 N11 C31 124.5(4) . .
C30 N11 H11A 117.8 . .
C31 N11 H11A 117.8 . .
C44 N12 C43 122.0(5) . .
C44 N12 H12' 119.0 . .
C43 N12 H12' 119.0 . .
C14 O1 Eu1 137.8(3) . .
N1 O2 Eu1 139.0(3) . .
C19 O3 Eu1 141.3(3) . .
C30 O4 Eu1 156.0(3) . .
C55 O5 Eu1 128.8(4) . .
C55 O5 H5O 134(3) . .
Eu1 O5 H5O 98(3) . .
C1 O6 Eu1 155.5(3) . .
N4 O7 Eu1 136.7(3) . .
C44 O8 Eu1 147.1(4) . 1_545
N8 O20 Eu1 138.8(3) . .
C27 O25 C29 120.4(5) . .
C9 O26 C57 118.7(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O6 2.287(3) .
Eu1 O3 2.295(3) .
Eu1 O1 2.308(3) .
Eu1 O8 2.344(4) 1_565
Eu1 O4 2.411(3) .
Eu1 O5 2.428(4) .
Eu1 O2 2.572(4) .
Eu1 O7 2.593(3) .
Eu1 O20 2.875(5) .
Eu1 H5O 2.72(4) .
C1 O6 1.260(5) .
C1 C6 1.428(7) .
C1 C2 1.442(6) .
C2 C3 1.351(6) .
C2 N6 1.460(6) .
C3 C4 1.386(7) .
C3 H3 0.9300 .
C4 C5 1.374(7) .
C4 N7 1.449(6) .
C5 C6 1.379(7) .
C5 H5 0.9300 .
C6 N8 1.465(6) .
C7 C10 1.379(8) .
C7 C8 1.386(8) .
C7 H7 0.9300 .
C8 C9 1.386(8) .
C8 C44 1.506(7) .
C9 O26 1.351(8) .
C9 C12 1.441(10) .
C10 C11 1.353(11) .
C10 H10 0.9300 .
C11 C12 1.345(12) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C18 1.369(6) .
C13 C14 1.431(7) .
C13 N3 1.458(7) .
C14 O1 1.260(5) .
C14 C15 1.443(7) .
C15 C16 1.375(6) .
C15 N4 1.455(6) .
C16 C17 1.357(7) .
C16 H16 0.9300 .
C17 C18 1.390(7) .
C17 N5 1.457(6) .
C18 H18 0.9300 .
C19 O3 1.262(5) .
C19 C24 1.414(6) .
C19 C21 1.440(7) .
C20 C22 1.372(7) .
C20 C24 1.382(7) .
C20 H20 0.9300 .
C21 C23 1.354(7) .
C21 N2 1.469(7) .
C22 C23 1.378(7) .
C22 N9 1.462(7) .
C23 H23 0.9300 .
C24 N1 1.446(6) .
C25 C49 1.376(9) .
C25 C26 1.389(7) .
C25 H25 0.9300 .
C26 C27 1.402(7) .
C26 C30 1.482(7) .
C27 O25 1.365(6) .
C27 C28 1.391(8) .
C28 C50 1.381(10) .
C28 H28 0.9300 .
C29 O25 1.440(6) .
C29 C35 1.509(9) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 O4 1.248(5) .
C30 N11 1.329(6) .
C31 N11 1.457(6) .
C31 C32 1.509(7) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 C33 1.374(7) .
C32 C34 1.380(7) .
C33 C46 1.378(9) .
C33 H33 0.9300 .
C34 C48 1.370(9) .
C34 H34 0.9300 .
C35 N10 1.450(8) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 N10 1.482(7) .
C36 C37 1.508(8) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 C38 1.360(8) .
C37 C39 1.377(8) .
C38 C40 1.370(9) .
C38 H38 0.9300 .
C39 C42 1.405(10) .
C39 H39 0.9300 .
C40 C41 1.339(10) .
C40 H40 0.9300 .
C41 C42 1.362(11) .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 C52 1.473(7) .
C43 N12 1.474(7) .
C43 H43A 0.9700 .
C43 H43B 0.9700 .
C44 O8 1.244(6) .
C44 N12 1.314(6) .
C46 C47 1.375(11) .
C46 H46 0.9300 .
C47 C48 1.342(11) .
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 C50 1.353(11) .
C49 H49 0.9300 .
C50 H50 0.9300 .
C51 C52 1.3900 .
C51 C60 1.3900 .
C51 H51 0.9300 .
C52 C53 1.3900 .
C53 C59 1.3900 .
C53 H53 0.9300 .
C59 C58 1.3900 .
C59 H59 0.9300 .
C58 C60 1.3900 .
C58 H58 0.9300 .
C60 H60 0.9300 .
C54 C57 1.457(11) .
C54 N10 1.497(9) .
C54 H54A 0.9700 .
C54 H54B 0.9700 .
C55 O5 1.448(7) .
C55 C56 1.450(10) .
C55 H55A 0.9700 .
C55 H55B 0.9700 .
C56 H56A 0.9600 .
C56 H56B 0.9600 .
C56 H56C 0.9600 .
C57 O26 1.429(7) .
C57 H57A 0.9700 .
C57 H57B 0.9700 .
N1 O9 1.213(5) .
N1 O2 1.239(5) .
N2 O10 1.173(6) .
N2 O11 1.228(7) .
N3 O21 1.181(6) .
N3 O14 1.198(6) .
N4 O12 1.219(5) .
N4 O7 1.219(5) .
N5 O13 1.202(6) .
N5 O24 1.216(6) .
N6 O15 1.210(6) .
N6 O16 1.212(5) .
N7 O18 1.213(7) .
N7 O17 1.218(6) .
N8 O19 1.178(6) .
N8 O20 1.218(5) .
N9 O22 1.208(6) .
N9 O23 1.218(6) .
N11 H11A 0.8600 .
N12 H12' 0.8600 .
O5 H5O 0.948(19) .
O8 Eu1 2.344(4) 1_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O6 C1 C2 C3 179.4(5) . .
C6 C1 C2 C3 -1.5(7) . .
O6 C1 C2 N6 0.0(8) . .
C6 C1 C2 N6 179.1(4) . .
C1 C2 C3 C4 -0.2(8) . .
N6 C2 C3 C4 179.2(5) . .
C2 C3 C4 C5 1.5(8) . .
C2 C3 C4 N7 -178.7(5) . .
C3 C4 C5 C6 -0.9(8) . .
N7 C4 C5 C6 179.4(5) . .
C4 C5 C6 C1 -1.1(8) . .
C4 C5 C6 N8 -179.5(5) . .
O6 C1 C6 C5 -178.7(5) . .
C2 C1 C6 C5 2.2(7) . .
O6 C1 C6 N8 -0.4(8) . .
C2 C1 C6 N8 -179.5(4) . .
C10 C7 C8 C9 -1.5(9) . .
C10 C7 C8 C44 176.7(5) . .
C7 C8 C9 O26 -177.4(6) . .
C44 C8 C9 O26 4.6(9) . .
C7 C8 C9 C12 4.8(9) . .
C44 C8 C9 C12 -173.2(5) . .
C8 C7 C10 C11 -2.3(10) . .
C7 C10 C11 C12 2.8(13) . .
C10 C11 C12 C9 0.6(13) . .
O26 C9 C12 C11 177.9(7) . .
C8 C9 C12 C11 -4.4(11) . .
C18 C13 C14 O1 177.7(5) . .
N3 C13 C14 O1 -4.3(7) . .
C18 C13 C14 C15 -3.3(7) . .
N3 C13 C14 C15 174.7(4) . .
O1 C14 C15 C16 -178.9(5) . .
C13 C14 C15 C16 2.0(7) . .
O1 C14 C15 N4 2.2(7) . .
C13 C14 C15 N4 -176.8(4) . .
C14 C15 C16 C17 0.4(8) . .
N4 C15 C16 C17 179.3(4) . .
C15 C16 C17 C18 -1.9(8) . .
C15 C16 C17 N5 178.5(4) . .
C14 C13 C18 C17 2.1(7) . .
N3 C13 C18 C17 -176.0(4) . .
C16 C17 C18 C13 0.7(7) . .
N5 C17 C18 C13 -179.7(4) . .
O3 C19 C21 C23 177.8(5) . .
C24 C19 C21 C23 -2.6(7) . .
O3 C19 C21 N2 0.0(7) . .
C24 C19 C21 N2 179.6(5) . .
C24 C20 C22 C23 -1.8(8) . .
C24 C20 C22 N9 177.9(4) . .
C19 C21 C23 C22 1.2(8) . .
N2 C21 C23 C22 178.9(5) . .
C20 C22 C23 C21 1.2(8) . .
N9 C22 C23 C21 -178.6(5) . .
C22 C20 C24 C19 0.1(7) . .
C22 C20 C24 N1 -179.4(4) . .
O3 C19 C24 C20 -178.6(4) . .
C21 C19 C24 C20 1.9(6) . .
O3 C19 C24 N1 0.9(7) . .
C21 C19 C24 N1 -178.6(4) . .
C49 C25 C26 C27 0.0(9) . .
C49 C25 C26 C30 -177.2(6) . .
C25 C26 C27 O25 -178.6(5) . .
C30 C26 C27 O25 -1.6(7) . .
C25 C26 C27 C28 -0.5(8) . .
C30 C26 C27 C28 176.5(5) . .
O25 C27 C28 C50 177.6(6) . .
C26 C27 C28 C50 -0.4(9) . .
C25 C26 C30 O4 18.1(7) . .
C27 C26 C30 O4 -158.9(5) . .
C25 C26 C30 N11 -161.9(5) . .
C27 C26 C30 N11 21.1(7) . .
N11 C31 C32 C33 41.8(7) . .
N11 C31 C32 C34 -140.3(5) . .
C34 C32 C33 C46 0.8(9) . .
C31 C32 C33 C46 178.7(6) . .
C33 C32 C34 C48 0.8(9) . .
C31 C32 C34 C48 -177.2(6) . .
O25 C29 C35 N10 -64.3(6) . .
N10 C36 C37 C38 45.3(8) . .
N10 C36 C37 C39 -137.5(6) . .
C39 C37 C38 C40 2.4(9) . .
C36 C37 C38 C40 179.7(6) . .
C38 C37 C39 C42 -2.5(10) . .
C36 C37 C39 C42 -179.8(6) . .
C37 C38 C40 C41 -1.2(11) . .
C38 C40 C41 C42 -0.1(12) . .
C40 C41 C42 C39 0.0(13) . .
C37 C39 C42 C41 1.3(12) . .
C9 C8 C44 O8 165.3(5) . .
C7 C8 C44 O8 -12.7(7) . .
C9 C8 C44 N12 -16.3(9) . .
C7 C8 C44 N12 165.6(5) . .
C32 C33 C46 C47 -2.6(11) . .
C33 C46 C47 C48 2.8(13) . .
C46 C47 C48 C34 -1.2(13) . .
C32 C34 C48 C47 -0.6(11) . .
C26 C25 C49 C50 1.3(11) . .
C25 C49 C50 C28 -2.3(12) . .
C27 C28 C50 C49 1.8(11) . .
C60 C51 C52 C53 0.0 . .
C60 C51 C52 C43 179.5(4) . .
N12 C43 C52 C53 100.6(5) . .
N12 C43 C52 C51 -78.9(6) . .
C51 C52 C53 C59 0.0 . .
C43 C52 C53 C59 -179.5(4) . .
C52 C53 C59 C58 0.0 . .
C53 C59 C58 C60 0.0 . .
C59 C58 C60 C51 0.0 . .
C52 C51 C60 C58 0.0 . .
N10 C54 C57 O26 -93.4(8) . .
C20 C24 N1 O9 -20.4(6) . .
C19 C24 N1 O9 160.1(5) . .
C20 C24 N1 O2 158.9(4) . .
C19 C24 N1 O2 -20.6(6) . .
C23 C21 N2 O10 84.8(8) . .
C19 C21 N2 O10 -97.3(7) . .
C23 C21 N2 O11 -94.3(7) . .
C19 C21 N2 O11 83.7(7) . .
C18 C13 N3 O21 11.3(9) . .
C14 C13 N3 O21 -166.9(6) . .
C18 C13 N3 O14 -166.6(6) . .
C14 C13 N3 O14 15.2(9) . .
C16 C15 N4 O12 -11.8(7) . .
C14 C15 N4 O12 167.1(5) . .
C16 C15 N4 O7 166.8(5) . .
C14 C15 N4 O7 -14.2(7) . .
C16 C17 N5 O13 -172.1(5) . .
C18 C17 N5 O13 8.3(8) . .
C16 C17 N5 O24 9.4(8) . .
C18 C17 N5 O24 -170.2(6) . .
C3 C2 N6 O15 -167.1(6) . .
C1 C2 N6 O15 12.3(8) . .
C3 C2 N6 O16 10.4(8) . .
C1 C2 N6 O16 -170.2(5) . .
C5 C4 N7 O18 -3.2(9) . .
C3 C4 N7 O18 177.0(6) . .
C5 C4 N7 O17 -177.9(6) . .
C3 C4 N7 O17 2.3(9) . .
C5 C6 N8 O19 9.1(8) . .
C1 C6 N8 O19 -169.4(6) . .
C5 C6 N8 O20 -172.5(5) . .
C1 C6 N8 O20 9.0(8) . .
C20 C22 N9 O22 -2.8(8) . .
C23 C22 N9 O22 176.9(5) . .
C20 C22 N9 O23 176.3(5) . .
C23 C22 N9 O23 -3.9(8) . .
C29 C35 N10 C36 -63.9(6) . .
C29 C35 N10 C54 171.7(5) . .
C37 C36 N10 C35 91.0(6) . .
C37 C36 N10 C54 -148.6(6) . .
C57 C54 N10 C35 177.5(6) . .
C57 C54 N10 C36 53.9(9) . .
O4 C30 N11 C31 5.0(8) . .
C26 C30 N11 C31 -175.0(4) . .
C32 C31 N11 C30 -118.4(5) . .
O8 C44 N12 C43 -3.1(9) . .
C8 C44 N12 C43 178.6(6) . .
C52 C43 N12 C44 -152.7(6) . .
C13 C14 O1 Eu1 -141.5(4) . .
C15 C14 O1 Eu1 39.6(7) . .
O6 Eu1 O1 C14 178.9(4) . .
O3 Eu1 O1 C14 -40.0(6) . .
O8 Eu1 O1 C14 -109.3(5) 1_565 .
O4 Eu1 O1 C14 30.2(5) . .
O5 Eu1 O1 C14 112.8(5) . .
O2 Eu1 O1 C14 73.1(5) . .
O7 Eu1 O1 C14 -41.5(5) . .
O20 Eu1 O1 C14 -178.7(5) . .
O9 N1 O2 Eu1 -157.9(4) . .
C24 N1 O2 Eu1 22.8(7) . .
O6 Eu1 O2 N1 87.6(5) . .
O3 Eu1 O2 N1 -6.3(4) . .
O1 Eu1 O2 N1 -145.4(4) . .
O8 Eu1 O2 N1 38.4(5) 1_565 .
O4 Eu1 O2 N1 -100.1(5) . .
O5 Eu1 O2 N1 174.6(5) . .
O7 Eu1 O2 N1 -54.2(5) . .
O20 Eu1 O2 N1 126.3(4) . .
C24 C19 O3 Eu1 23.9(8) . .
C21 C19 O3 Eu1 -156.6(4) . .
O6 Eu1 O3 C19 -90.0(5) . .
O1 Eu1 O3 C19 119.6(5) . .
O8 Eu1 O3 C19 -171.7(5) 1_565 .
O4 Eu1 O3 C19 51.7(5) . .
O5 Eu1 O3 C19 -17.3(5) . .
O2 Eu1 O3 C19 -18.6(4) . .
O7 Eu1 O3 C19 121.1(5) . .
O20 Eu1 O3 C19 -125.1(5) . .
N11 C30 O4 Eu1 -96.8(9) . .
C26 C30 O4 Eu1 83.2(9) . .
O6 Eu1 O4 C30 -171.4(8) . .
O3 Eu1 O4 C30 109.9(8) . .
O1 Eu1 O4 C30 -31.9(8) . .
O8 Eu1 O4 C30 33.9(9) 1_565 .
O5 Eu1 O4 C30 -108.0(8) . .
O2 Eu1 O4 C30 176.9(8) . .
O7 Eu1 O4 C30 36.6(8) . .
O20 Eu1 O4 C30 -73.3(8) . .
C56 C55 O5 Eu1 113.5(6) . .
O6 Eu1 O5 C55 29.5(5) . .
O3 Eu1 O5 C55 -44.7(6) . .
O1 Eu1 O5 C55 162.9(5) . .
O8 Eu1 O5 C55 100.0(5) 1_565 .
O4 Eu1 O5 C55 -115.7(5) . .
O2 Eu1 O5 C55 -43.5(5) . .
O7 Eu1 O5 C55 -163.9(5) . .
O20 Eu1 O5 C55 89.7(5) . .
C6 C1 O6 Eu1 -17.3(12) . .
C2 C1 O6 Eu1 161.7(6) . .
O3 Eu1 O6 C1 -138.4(8) . .
O1 Eu1 O6 C1 17.2(9) . .
O8 Eu1 O6 C1 -54.6(8) 1_565 .
O4 Eu1 O6 C1 143.1(8) . .
O5 Eu1 O6 C1 80.2(8) . .
O2 Eu1 O6 C1 154.7(9) . .
O7 Eu1 O6 C1 -83.5(9) . .
O20 Eu1 O6 C1 14.7(8) . .
O12 N4 O7 Eu1 170.9(4) . .
C15 N4 O7 Eu1 -7.7(8) . .
O6 Eu1 O7 N4 147.4(4) . .
O3 Eu1 O7 N4 -153.9(5) . .
O1 Eu1 O7 N4 25.0(5) . .
O8 Eu1 O7 N4 116.0(5) 1_565 .
O4 Eu1 O7 N4 -61.9(5) . .
O5 Eu1 O7 N4 -10.1(6) . .
O2 Eu1 O7 N4 -108.3(5) . .
O20 Eu1 O7 N4 71.1(5) . .
N12 C44 O8 Eu1 108.1(7) . 1_545
C8 C44 O8 Eu1 -73.5(8) . 1_545
O19 N8 O20 Eu1 169.0(5) . .
C6 N8 O20 Eu1 -9.3(9) . .
O6 Eu1 O20 N8 1.7(6) . .
O3 Eu1 O20 N8 43.4(7) . .
O1 Eu1 O20 N8 -176.2(7) . .
O8 Eu1 O20 N8 94.5(6) 1_565 .
O4 Eu1 O20 N8 -132.0(6) . .
O5 Eu1 O20 N8 -93.7(6) . .
O2 Eu1 O20 N8 -41.8(7) . .
O7 Eu1 O20 N8 138.8(6) . .
C28 C27 O25 C29 18.3(7) . .
C26 C27 O25 C29 -163.6(4) . .
C35 C29 O25 C27 157.7(5) . .
C8 C9 O26 C57 174.2(6) . .
C12 C9 O26 C57 -8.1(10) . .
C54 C57 O26 C9 -170.7(6) . .
