#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:42:58 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180481 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/50/7215073.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7215073
loop_
_publ_author_name
'Ahmad, Waqar'
'Zhang, Lijuan'
'Zhou, Yunshan'
_publ_section_title
;
 2-D lanthanide--organic complexes constructed from
 6,7-dihydropyrido(2,3-d)pyridazine-5,8-dione: synthesis, characterization
 and photoluminescence for sensing small molecules
;
_journal_issue                   17
_journal_name_full               CrystEngComm
_journal_page_first              3521
_journal_paper_doi               10.1039/c3ce42575d
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C9 H6 Eu N3 O7'
_chemical_formula_weight         420.13
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.372(4)
_cell_angle_beta                 101.829(4)
_cell_angle_gamma                102.587(5)
_cell_formula_units_Z            2
_cell_length_a                   7.1628(4)
_cell_length_b                   7.9091(4)
_cell_length_c                   10.2589(4)
_cell_measurement_reflns_used    5364
_cell_measurement_temperature    101.893(2)
_cell_measurement_theta_max      1.0000
_cell_measurement_theta_min      0.80476
_cell_volume                     553.73(5)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      101.829
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_sigmaI/netI    0.0389
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            7234
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.98
_exptl_absorpt_coefficient_mu    5.704
_exptl_absorpt_correction_T_max  0.8039
_exptl_absorpt_correction_T_min  0.7635
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    2.520
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             400
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.706
_refine_diff_density_min         -0.656
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     187
_refine_ls_number_reflns         2171
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0220
_refine_ls_R_factor_gt           0.0200
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0136P)²+0.2902P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0426
_refine_ls_wR_factor_ref         0.0432
_reflns_number_gt                2047
_reflns_number_total             2171
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce42575d2.cif
_cod_data_source_block           752
_cod_database_code               7215073
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.28511(3) 0.79400(2) 0.924828(16) 0.00631(6) Uani 1 1 d D
O6 O 0.0857(4) 0.9956(3) 0.8532(2) 0.0098(5) Uani 1 1 d .
O5 O -0.0951(3) 1.1652(3) 0.9191(2) 0.0097(5) Uani 1 1 d .
O4 O 0.7416(3) 0.4906(3) 0.9967(2) 0.0098(5) Uani 1 1 d .
O1 O 0.5111(4) 0.9426(3) 1.1203(2) 0.0092(5) Uani 1 1 d .
O3 O 0.5670(4) 0.6810(3) 0.9112(2) 0.0110(5) Uani 1 1 d .
OW7 O -0.0309(4) 0.6116(3) 0.8071(2) 0.0118(6) Uani 1 1 d .
O2 O 0.6773(4) 0.6794(3) 1.5972(2) 0.0169(6) Uani 1 1 d .
N2 N 0.4988(4) 0.7145(4) 1.2492(3) 0.0111(7) Uani 1 1 d .
N1 N 0.7256(4) 1.1696(4) 1.3282(3) 0.0095(6) Uani 1 1 d .
C9 C -0.0037(5) 1.0472(4) 0.9344(3) 0.0080(7) Uani 1 1 d U
N3 N 0.5485(5) 0.6563(4) 1.3752(3) 0.0134(7) Uani 1 1 d .
H3 H 0.5125 0.5462 1.3813 0.016 Uiso 1 1 calc R
C8 C 0.5881(5) 0.5504(4) 0.9731(3) 0.0086(7) Uani 1 1 d .
C6 C 0.5564(5) 0.8807(5) 1.2373(3) 0.0099(7) Uani 1 1 d .
C5 C 0.6678(5) 0.9997(5) 1.3505(3) 0.0087(7) Uani 1 1 d .
C2 C 0.8543(6) 1.2278(5) 1.5653(4) 0.0150(8) Uani 1 1 d .
H2 H 0.9134 1.3098 1.6366 0.018 Uiso 1 1 calc R
C7 C 0.6465(5) 0.7510(5) 1.4893(3) 0.0117(8) Uani 1 1 d .
C1 C 0.8159(5) 1.2783(5) 1.4340(3) 0.0141(8) Uani 1 1 d .
H1 H 0.8562 1.3953 1.4204 0.017 Uiso 1 1 calc R
C4 C 0.7095(5) 0.9366(5) 1.4769(3) 0.0101(8) Uani 1 1 d .
C3 C 0.8025(5) 1.0546(5) 1.5861(3) 0.0125(8) Uani 1 1 d .
H3A H 0.8291 1.0166 1.6716 0.015 Uiso 1 1 calc R
H7A H -0.090(5) 0.560(4) 0.860(4) 0.019 Uiso 1 1 d D
H7B H -0.094(5) 0.661(5) 0.755(3) 0.019 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O1 113.26(8) 2_577 2_677
O5 Eu1 O4 84.56(8) 2_577 2_667
O1 Eu1 O4 148.58(8) 2_677 2_667
O5 Eu1 O6 68.61(7) 2_577 .
O1 Eu1 O6 71.03(8) 2_677 .
O4 Eu1 O6 140.27(8) 2_667 .
O5 Eu1 O1 73.71(8) 2_577 .
O1 Eu1 O1 66.92(9) 2_677 .
O4 Eu1 O1 96.03(8) 2_667 .
O6 Eu1 O1 103.43(8) . .
O5 Eu1 O3 139.67(8) 2_577 .
O1 Eu1 O3 82.51(8) 2_677 .
O4 Eu1 O3 68.19(8) 2_667 .
O6 Eu1 O3 148.83(8) . .
O1 Eu1 O3 80.02(8) . .
O5 Eu1 OW7 81.25(8) 2_577 .
O1 Eu1 OW7 134.07(8) 2_677 .
O4 Eu1 OW7 71.86(8) 2_667 .
O6 Eu1 OW7 75.40(9) . .
O1 Eu1 OW7 153.20(8) . .
O3 Eu1 OW7 115.16(9) . .
O5 Eu1 N1 137.77(8) 2_577 2_677
O1 Eu1 N1 65.92(9) 2_677 2_677
O4 Eu1 N1 118.60(9) 2_667 2_677
O6 Eu1 N1 72.04(8) . 2_677
O1 Eu1 N1 131.26(9) . 2_677
O3 Eu1 N1 82.43(8) . 2_677
OW7 Eu1 N1 74.54(9) . 2_677
O5 Eu1 C9 20.36(8) 2_577 2_577
O1 Eu1 C9 98.88(8) 2_677 2_577
O4 Eu1 C9 103.61(8) 2_667 2_577
O6 Eu1 C9 48.57(8) . 2_577
O1 Eu1 C9 79.10(8) . 2_577
O3 Eu1 C9 156.56(8) . 2_577
OW7 Eu1 C9 80.71(9) . 2_577
N1 Eu1 C9 119.68(8) 2_677 2_577
O5 Eu1 C8 122.30(8) 2_577 .
O1 Eu1 C8 100.93(9) 2_677 .
O4 Eu1 C8 48.52(8) 2_667 .
O6 Eu1 C8 168.91(8) . .
O1 Eu1 C8 79.51(8) . .
O3 Eu1 C8 20.40(8) . .
OW7 Eu1 C8 106.90(9) . .
N1 Eu1 C8 97.88(8) 2_677 .
C9 Eu1 C8 142.12(8) 2_577 .
O5 Eu1 C8 99.33(8) 2_577 2_667
O1 Eu1 C8 128.09(8) 2_677 2_667
O4 Eu1 C8 20.64(8) 2_667 2_667
O6 Eu1 C8 160.88(9) . 2_667
O1 Eu1 C8 86.42(8) . 2_667
O3 Eu1 C8 48.30(8) . 2_667
OW7 Eu1 C8 88.39(9) . 2_667
N1 Eu1 C8 113.78(9) 2_677 2_667
C9 Eu1 C8 119.56(8) 2_577 2_667
C8 Eu1 C8 28.16(12) . 2_667
O5 Eu1 C9 48.56(8) 2_577 .
O1 Eu1 C9 80.91(8) 2_677 .
O4 Eu1 C9 127.60(8) 2_667 .
O6 Eu1 C9 20.37(8) . .
O1 Eu1 C9 91.91(8) . .
O3 Eu1 C9 163.34(9) . .
OW7 Eu1 C9 78.18(9) . .
N1 Eu1 C9 92.29(8) 2_677 .
C9 Eu1 C9 28.31(11) 2_577 .
C8 Eu1 C9 169.52(8) . .
C8 Eu1 C9 146.41(8) 2_667 .
C9 O6 Eu1 118.2(2) . .
C9 O5 Eu1 118.4(2) . 2_577
C8 O4 Eu1 117.8(2) . 2_667
C6 O1 Eu1 118.4(2) . 2_677
C6 O1 Eu1 127.2(2) . .
Eu1 O1 Eu1 113.08(9) 2_677 .
C8 O3 Eu1 117.3(2) . .
Eu1 OW7 H7A 111(2) . .
Eu1 OW7 H7B 114(3) . .
H7A OW7 H7B 114(4) . .
C6 N2 N3 116.9(3) . .
C1 N1 C5 116.9(3) . .
C1 N1 Eu1 130.4(2) . 2_677
C5 N1 Eu1 110.7(2) . 2_677
O5 C9 O6 126.4(3) . .
O5 C9 C9 118.1(4) . 2_577
O6 C9 C9 115.6(4) . 2_577
O5 C9 Eu1 41.25(15) . 2_577
O6 C9 Eu1 166.1(2) . 2_577
C9 C9 Eu1 77.2(2) 2_577 2_577
O5 C9 Eu1 166.3(2) . .
O6 C9 Eu1 41.46(15) . .
C9 C9 Eu1 74.5(2) 2_577 .
Eu1 C9 Eu1 151.69(11) 2_577 .
C7 N3 N2 127.9(3) . .
C7 N3 H3 116.0 . .
N2 N3 H3 116.0 . .
O3 C8 O4 126.1(3) . .
O3 C8 C8 117.7(4) . 2_667
O4 C8 C8 116.1(4) . 2_667
O3 C8 Eu1 42.32(16) . .
O4 C8 Eu1 165.0(2) . .
C8 C8 Eu1 76.3(2) 2_667 .
O3 C8 Eu1 164.4(2) . 2_667
O4 C8 Eu1 41.52(16) . 2_667
C8 C8 Eu1 75.5(2) 2_667 2_667
Eu1 C8 Eu1 151.84(12) . 2_667
N2 C6 O1 119.2(3) . .
N2 C6 C5 121.8(3) . .
O1 C6 C5 119.0(3) . .
N2 C6 Eu1 152.3(2) . 2_677
O1 C6 Eu1 40.62(16) . 2_677
C5 C6 Eu1 81.6(2) . 2_677
N1 C5 C4 122.8(3) . .
N1 C5 C6 117.7(3) . .
C4 C5 C6 119.5(3) . .
C3 C2 C1 118.5(3) . .
C3 C2 H2 120.8 . .
C1 C2 H2 120.8 . .
O2 C7 N3 120.5(3) . .
O2 C7 C4 124.1(3) . .
N3 C7 C4 115.4(3) . .
N1 C1 C2 124.1(3) . .
N1 C1 H1 118.0 . .
C2 C1 H1 118.0 . .
C3 C4 C5 118.7(3) . .
C3 C4 C7 122.8(3) . .
C5 C4 C7 118.4(3) . .
C2 C3 C4 118.9(3) . .
C2 C3 H3A 120.6 . .
C4 C3 H3A 120.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.363(2) 2_577
Eu1 O1 2.384(2) 2_677
Eu1 O4 2.390(2) 2_667
Eu1 O6 2.396(2) .
Eu1 O1 2.398(2) .
Eu1 O3 2.407(2) .
Eu1 OW7 2.457(3) .
Eu1 N1 2.605(3) 2_677
Eu1 C9 3.152(3) 2_577
Eu1 C8 3.177(3) .
Eu1 C8 3.188(3) 2_667
Eu1 C9 3.190(3) .
O6 C9 1.260(4) .
O5 C9 1.247(4) .
O5 Eu1 2.363(2) 2_577
O4 C8 1.271(4) .
O4 Eu1 2.390(2) 2_667
O1 C6 1.313(4) .
O1 Eu1 2.384(2) 2_677
O3 C8 1.246(4) .
OW7 H7A 0.82(3) .
OW7 H7B 0.80(3) .
O2 C7 1.257(4) .
N2 C6 1.306(5) .
N2 N3 1.386(4) .
N1 C1 1.327(5) .
N1 C5 1.357(4) .
N1 Eu1 2.605(3) 2_677
C9 C9 1.552(6) 2_577
C9 Eu1 3.152(3) 2_577
N3 C7 1.348(5) .
N3 H3 0.8600 .
C8 C8 1.549(7) 2_667
C8 Eu1 3.188(3) 2_667
C6 C5 1.453(5) .
C6 Eu1 3.222(3) 2_677
C5 C4 1.399(4) .
C2 C3 1.373(5) .
C2 C1 1.404(5) .
C2 H2 0.9300 .
C7 C4 1.455(5) .
C1 H1 0.9300 .
C4 C3 1.394(5) .
C3 H3A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Eu1 O6 C9 9.2(2) 2_577 .
O1 Eu1 O6 C9 -116.5(3) 2_677 .
O4 Eu1 O6 C9 60.1(3) 2_667 .
O1 Eu1 O6 C9 -57.0(3) . .
O3 Eu1 O6 C9 -149.9(2) . .
OW7 Eu1 O6 C9 95.4(3) . .
N1 Eu1 O6 C9 173.5(3) 2_677 .
C9 Eu1 O6 C9 4.9(3) 2_577 .
C8 Eu1 O6 C9 -161.2(4) . .
C8 Eu1 O6 C9 62.5(4) 2_667 .
O5 Eu1 O1 C6 68.6(3) 2_577 .
O1 Eu1 O1 C6 -166.5(3) 2_677 .
O4 Eu1 O1 C6 -13.9(3) 2_667 .
O6 Eu1 O1 C6 131.2(3) . .
O3 Eu1 O1 C6 -80.5(3) . .
OW7 Eu1 O1 C6 47.0(3) . .
N1 Eu1 O1 C6 -151.1(2) 2_677 .
C9 Eu1 O1 C6 88.8(3) 2_577 .
C8 Eu1 O1 C6 -59.8(3) . .
C8 Eu1 O1 C6 -32.2(3) 2_667 .
C9 Eu1 O1 C6 114.2(3) . .
O5 Eu1 O1 Eu1 -124.88(11) 2_577 2_677
O1 Eu1 O1 Eu1 0.0 2_677 2_677
O4 Eu1 O1 Eu1 152.60(10) 2_667 2_677
O6 Eu1 O1 Eu1 -62.29(11) . 2_677
O3 Eu1 O1 Eu1 86.05(10) . 2_677
OW7 Eu1 O1 Eu1 -146.42(14) . 2_677
N1 Eu1 O1 Eu1 15.46(16) 2_677 2_677
C9 Eu1 O1 Eu1 -104.66(11) 2_577 2_677
C8 Eu1 O1 Eu1 106.78(11) . 2_677
C8 Eu1 O1 Eu1 134.31(10) 2_667 2_677
C9 Eu1 O1 Eu1 -79.28(10) . 2_677
O5 Eu1 O3 C8 37.0(3) 2_577 .
O1 Eu1 O3 C8 154.5(3) 2_677 .
O4 Eu1 O3 C8 -14.0(2) 2_667 .
O6 Eu1 O3 C8 -173.8(2) . .
O1 Eu1 O3 C8 86.7(3) . .
OW7 Eu1 O3 C8 -70.0(3) . .
N1 Eu1 O3 C8 -139.0(3) 2_677 .
C9 Eu1 O3 C8 59.4(4) 2_577 .
C8 Eu1 O3 C8 -7.4(3) 2_667 .
C9 Eu1 O3 C8 148.7(3) . .
Eu1 O5 C9 O6 171.5(3) 2_577 .
Eu1 O5 C9 C9 -8.7(5) 2_577 2_577
Eu1 O5 C9 Eu1 -164.1(9) 2_577 .
Eu1 O6 C9 O5 171.5(3) . .
Eu1 O6 C9 C9 -8.4(5) . 2_577
Eu1 O6 C9 Eu1 -164.4(9) . 2_577
O5 Eu1 C9 O5 161.2(11) 2_577 .
O1 Eu1 C9 O5 28.8(10) 2_677 .
O4 Eu1 C9 O5 -165.8(10) 2_667 .
O6 Eu1 C9 O5 -30.2(9) . .
O1 Eu1 C9 O5 95.1(11) . .
O3 Eu1 C9 O5 34.6(12) . .
OW7 Eu1 C9 O5 -110.1(11) . .
N1 Eu1 C9 O5 -36.4(11) 2_677 .
C9 Eu1 C9 O5 157.6(13) 2_577 .
C8 Eu1 C9 O5 129.8(9) . .
C8 Eu1 C9 O5 -178.5(10) 2_667 .
O5 Eu1 C9 O6 -168.5(3) 2_577 .
O1 Eu1 C9 O6 59.0(3) 2_677 .
O4 Eu1 C9 O6 -135.6(2) 2_667 .
O1 Eu1 C9 O6 125.3(3) . .
O3 Eu1 C9 O6 64.8(4) . .
OW7 Eu1 C9 O6 -79.8(3) . .
N1 Eu1 C9 O6 -6.2(3) 2_677 .
C9 Eu1 C9 O6 -172.2(5) 2_577 .
C8 Eu1 C9 O6 160.0(4) . .
C8 Eu1 C9 O6 -148.3(2) 2_667 .
O5 Eu1 C9 C9 3.6(2) 2_577 2_577
O1 Eu1 C9 C9 -128.8(3) 2_677 2_577
O4 Eu1 C9 C9 36.6(3) 2_667 2_577
O6 Eu1 C9 C9 172.2(5) . 2_577
O1 Eu1 C9 C9 -62.5(3) . 2_577
O3 Eu1 C9 C9 -123.0(3) . 2_577
OW7 Eu1 C9 C9 92.3(3) . 2_577
N1 Eu1 C9 C9 166.0(3) 2_677 2_577
C8 Eu1 C9 C9 -27.8(7) . 2_577
C8 Eu1 C9 C9 23.9(4) 2_667 2_577
O5 Eu1 C9 Eu1 3.6(2) 2_577 2_577
O1 Eu1 C9 Eu1 -128.8(3) 2_677 2_577
O4 Eu1 C9 Eu1 36.6(3) 2_667 2_577
O6 Eu1 C9 Eu1 172.2(5) . 2_577
O1 Eu1 C9 Eu1 -62.5(3) . 2_577
O3 Eu1 C9 Eu1 -123.0(3) . 2_577
OW7 Eu1 C9 Eu1 92.3(3) . 2_577
N1 Eu1 C9 Eu1 166.0(3) 2_677 2_577
C9 Eu1 C9 Eu1 0.0 2_577 2_577
C8 Eu1 C9 Eu1 -27.8(7) . 2_577
C8 Eu1 C9 Eu1 23.9(4) 2_667 2_577
C6 N2 N3 C7 1.6(5) . .
Eu1 O3 C8 O4 -167.1(3) . .
Eu1 O3 C8 C8 12.9(5) . 2_667
Eu1 O3 C8 Eu1 159.1(8) . 2_667
Eu1 O4 C8 O3 -166.9(3) 2_667 .
Eu1 O4 C8 C8 13.0(5) 2_667 2_667
Eu1 O4 C8 Eu1 157.6(7) 2_667 .
O5 Eu1 C8 O3 -152.5(2) 2_577 .
O1 Eu1 C8 O3 -25.8(3) 2_677 .
O4 Eu1 C8 O3 162.6(3) 2_667 .
O6 Eu1 C8 O3 16.8(6) . .
O1 Eu1 C8 O3 -89.6(3) . .
OW7 Eu1 C8 O3 117.2(2) . .
N1 Eu1 C8 O3 41.1(3) 2_677 .
C9 Eu1 C8 O3 -146.1(2) 2_577 .
C8 Eu1 C8 O3 168.2(5) 2_667 .
C9 Eu1 C8 O3 -125.0(5) . .
O5 Eu1 C8 O4 -108.4(9) 2_577 .
O1 Eu1 C8 O4 18.4(9) 2_677 .
O4 Eu1 C8 O4 -153.3(9) 2_667 .
O6 Eu1 C8 O4 61.0(11) . .
O1 Eu1 C8 O4 -45.4(9) . .
O3 Eu1 C8 O4 44.2(8) . .
OW7 Eu1 C8 O4 161.4(9) . .
N1 Eu1 C8 O4 85.2(9) 2_677 .
C9 Eu1 C8 O4 -101.9(9) 2_577 .
C8 Eu1 C8 O4 -147.6(11) 2_667 .
C9 Eu1 C8 O4 -80.8(10) . .
O5 Eu1 C8 C8 39.2(3) 2_577 2_667
O1 Eu1 C8 C8 166.0(2) 2_677 2_667
O4 Eu1 C8 C8 -5.6(2) 2_667 2_667
O6 Eu1 C8 C8 -151.4(3) . 2_667
O1 Eu1 C8 C8 102.2(3) . 2_667
O3 Eu1 C8 C8 -168.2(5) . 2_667
OW7 Eu1 C8 C8 -51.0(3) . 2_667
N1 Eu1 C8 C8 -127.1(2) 2_677 2_667
C9 Eu1 C8 C8 45.7(3) 2_577 2_667
C9 Eu1 C8 C8 66.8(6) . 2_667
O5 Eu1 C8 Eu1 39.2(3) 2_577 2_667
O1 Eu1 C8 Eu1 166.0(2) 2_677 2_667
O4 Eu1 C8 Eu1 -5.6(2) 2_667 2_667
O6 Eu1 C8 Eu1 -151.4(3) . 2_667
O1 Eu1 C8 Eu1 102.2(3) . 2_667
O3 Eu1 C8 Eu1 -168.2(5) . 2_667
OW7 Eu1 C8 Eu1 -51.0(3) . 2_667
N1 Eu1 C8 Eu1 -127.1(2) 2_677 2_667
C9 Eu1 C8 Eu1 45.7(3) 2_577 2_667
C8 Eu1 C8 Eu1 0.0 2_667 2_667
C9 Eu1 C8 Eu1 66.8(6) . 2_667
N3 N2 C6 O1 -179.2(3) . .
N3 N2 C6 C5 0.1(5) . .
N3 N2 C6 Eu1 144.4(4) . 2_677
Eu1 O1 C6 N2 -155.0(3) 2_677 .
Eu1 O1 C6 N2 11.0(4) . .
Eu1 O1 C6 C5 25.6(4) 2_677 .
Eu1 O1 C6 C5 -168.4(2) . .
Eu1 O1 C6 Eu1 165.9(3) . 2_677
C1 N1 C5 C4 -3.7(5) . .
Eu1 N1 C5 C4 161.8(3) 2_677 .
C1 N1 C5 C6 175.7(3) . .
Eu1 N1 C5 C6 -18.9(4) 2_677 .
N2 C6 C5 N1 178.4(3) . .
O1 C6 C5 N1 -2.2(5) . .
Eu1 C6 C5 N1 14.3(3) 2_677 .
N2 C6 C5 C4 -2.2(5) . .
O1 C6 C5 C4 177.2(3) . .
Eu1 C6 C5 C4 -166.3(3) 2_677 .
N2 N3 C7 O2 178.6(3) . .
N2 N3 C7 C4 -1.1(5) . .
C5 N1 C1 C2 0.1(5) . .
Eu1 N1 C1 C2 -161.9(3) 2_677 .
C3 C2 C1 N1 2.6(6) . .
N1 C5 C4 C3 4.5(5) . .
C6 C5 C4 C3 -174.8(3) . .
N1 C5 C4 C7 -178.0(3) . .
C6 C5 C4 C7 2.7(5) . .
O2 C7 C4 C3 -3.4(6) . .
N3 C7 C4 C3 176.2(3) . .
O2 C7 C4 C5 179.3(3) . .
N3 C7 C4 C5 -1.1(5) . .
C1 C2 C3 C4 -1.7(5) . .
C5 C4 C3 C2 -1.6(5) . .
C7 C4 C3 C2 -179.0(3) . .
