#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/03/7220368.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7220368
loop_
_publ_author_name
'Ding, Yu-Jia'
'Li, Teng'
'Hong, Xu-Jia'
'Zhu, Li-Cai'
'Cai, Yue-Peng'
'Zhu, Si-Ming'
'Yu, Shu-Juan'
_publ_section_title
;
 Construction of four 3d--4f heterometallic pillar-layered frameworks
 containing left- and right-handed helical chains and a
 I−chemosensor
;
_journal_issue                   21
_journal_name_full               CrystEngComm
_journal_page_first              3945
_journal_paper_doi               10.1039/C5CE00324E
_journal_volume                  17
_journal_year                    2015
_chemical_formula_sum            'C20 H28 Eu2 N8 O32 S Zn4'
_chemical_formula_weight         1489.96
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-04-15 deposited with the CCDC.
2015-04-17 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 128.9370(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   25.1496(13)
_cell_length_b                   9.6309(5)
_cell_length_c                   20.0039(11)
_cell_measurement_reflns_used    5858
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.98
_cell_measurement_theta_min      2.36
_cell_volume                     3768.8(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0279
_diffrn_reflns_av_sigmaI/netI    0.0288
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            9486
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         2.08
_exptl_absorpt_coefficient_mu    5.967
_exptl_absorpt_correction_T_max  0.5598
_exptl_absorpt_correction_T_min  0.3536
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.626
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2888
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.799
_refine_diff_density_min         -0.839
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     303
_refine_ls_number_reflns         3415
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.099
_refine_ls_R_factor_all          0.0249
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0251P)²+15.7171P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0585
_refine_ls_wR_factor_ref         0.0596
_reflns_number_gt                3141
_reflns_number_total             3415
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce00324e1.cif
_cod_data_source_block           c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7220366--7220369.cif.
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7220368
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.154849(9) 0.84926(2) 0.419562(12) 0.01308(7) Uani 1 1 d .
Zn1 Zn 0.35396(2) 0.27697(5) 0.31922(3) 0.01556(12) Uani 1 1 d .
Zn2 Zn 0.05142(2) 0.27878(5) 0.43981(3) 0.01971(12) Uani 1 1 d .
S1 S 0.0000 0.32446(15) 0.2500 0.0238(3) Uani 1 2 d S
N1 N 0.29846(17) 0.4477(3) 0.2984(2) 0.0170(7) Uani 1 1 d .
N2 N 0.22376(17) 0.6232(4) 0.2451(2) 0.0174(7) Uani 1 1 d .
N3 N 0.00256(16) 0.4578(3) 0.4225(2) 0.0170(7) Uani 1 1 d .
N4 N -0.06773(17) 0.6391(3) 0.3752(2) 0.0174(7) Uani 1 1 d .
C1 C 0.34097(18) 0.4199(4) 0.4452(2) 0.0141(8) Uani 1 1 d .
C2 C 0.29713(19) 0.4919(4) 0.3619(2) 0.0142(8) Uani 1 1 d .
C3 C 0.2537(2) 0.5281(4) 0.2302(3) 0.0198(9) Uani 1 1 d .
H3 H 0.2443 0.5184 0.1775 0.024 Uiso 1 1 calc R
C4 C 0.25061(19) 0.6017(4) 0.3292(3) 0.0150(8) Uani 1 1 d .
C5 C 0.22277(19) 0.6873(4) 0.3617(3) 0.0136(8) Uani 1 1 d .
C6 C 0.1100(2) 0.5564(4) 0.4678(3) 0.0197(9) Uani 1 1 d .
C7 C 0.0375(2) 0.5744(4) 0.4311(3) 0.0160(8) Uani 1 1 d .
C8 C -0.0596(2) 0.5021(4) 0.3891(3) 0.0196(9) Uani 1 1 d .
H8 H -0.0942 0.4434 0.3765 0.023 Uiso 1 1 calc R
C9 C -0.00581(19) 0.6867(4) 0.4016(3) 0.0159(8) Uani 1 1 d .
C10 C -0.0017(2) 0.8336(4) 0.3848(3) 0.0176(9) Uani 1 1 d .
O1 O 0.37716(15) 0.3208(3) 0.44918(19) 0.0226(7) Uani 1 1 d .
O2 O 0.34182(15) 0.4518(3) 0.50641(18) 0.0219(7) Uani 1 1 d .
O3 O 0.23839(14) 0.6703(3) 0.43470(17) 0.0170(6) Uani 1 1 d .
O4 O 0.17931(14) 0.7799(3) 0.31165(17) 0.0169(6) Uani 1 1 d .
O5 O 0.04946(15) 0.8814(3) 0.3965(2) 0.0307(8) Uani 1 1 d .
O6 O -0.05520(14) 0.9047(3) 0.3536(2) 0.0220(7) Uani 1 1 d .
O7 O 0.14785(14) 0.6590(3) 0.4868(2) 0.0249(7) Uani 1 1 d .
O8 O 0.13028(15) 0.4321(3) 0.4792(2) 0.0290(7) Uani 1 1 d .
O9 O 0.02550(17) 0.2296(3) 0.3236(2) 0.0303(8) Uani 1 1 d .
O10 O -0.05645(18) 0.4089(4) 0.2300(2) 0.0387(9) Uani 1 1 d .
O1W O 0.23018(15) 1.0245(3) 0.4302(2) 0.0266(7) Uani 1 1 d .
O2W O 0.08672(15) 1.0044(3) 0.2995(2) 0.0283(7) Uani 1 1 d .
O3W O 0.07160(15) 0.6855(3) 0.3006(2) 0.0291(7) Uani 1 1 d .
O4W O -0.02702(19) 0.1605(3) 0.4203(3) 0.0405(9) Uani 1 1 d .
O5W O 0.1950(2) 0.3029(4) 0.3921(3) 0.0653(13) Uani 1 1 d .
O6W O 0.8503(4) 0.2672(8) 0.2732(5) 0.131(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O2W 142.82(10) . .
O7 Eu1 O2 104.91(11) . 7_566
O2W Eu1 O2 81.16(10) . 7_566
O7 Eu1 O5 74.91(10) . .
O2W Eu1 O5 73.80(11) . .
O2 Eu1 O5 67.76(11) 7_566 .
O7 Eu1 O3 71.09(10) . 7_566
O2W Eu1 O3 143.54(10) . 7_566
O2 Eu1 O3 74.74(9) 7_566 7_566
O5 Eu1 O3 119.54(11) . 7_566
O7 Eu1 O1W 145.41(10) . .
O2W Eu1 O1W 71.60(11) . .
O2 Eu1 O1W 70.67(10) 7_566 .
O5 Eu1 O1W 128.87(10) . .
O3 Eu1 O1W 74.78(10) 7_566 .
O7 Eu1 O3W 74.54(11) . .
O2W Eu1 O3W 78.25(11) . .
O2 Eu1 O3W 140.93(10) 7_566 .
O5 Eu1 O3W 74.73(11) . .
O3 Eu1 O3W 136.44(10) 7_566 .
O1W Eu1 O3W 131.07(11) . .
O7 Eu1 O3 76.11(10) . .
O2W Eu1 O3 123.27(10) . .
O2 Eu1 O3 138.82(9) 7_566 .
O5 Eu1 O3 145.51(10) . .
O3 Eu1 O3 66.65(10) 7_566 .
O1W Eu1 O3 85.51(10) . .
O3W Eu1 O3 79.85(10) . .
O7 Eu1 O4 113.96(10) . .
O2W Eu1 O4 74.29(9) . .
O2 Eu1 O4 139.80(9) 7_566 .
O5 Eu1 O4 131.41(11) . .
O3 Eu1 O4 107.92(9) 7_566 .
O1W Eu1 O4 71.58(10) . .
O3W Eu1 O4 63.57(10) . .
O3 Eu1 O4 49.12(8) . .
O7 Eu1 Eu1 70.37(7) . 7_566
O2W Eu1 Eu1 143.59(8) . 7_566
O2 Eu1 Eu1 108.15(7) 7_566 7_566
O5 Eu1 Eu1 142.58(8) . 7_566
O3 Eu1 Eu1 34.48(6) 7_566 7_566
O1W Eu1 Eu1 78.43(7) . 7_566
O3W Eu1 Eu1 108.16(8) . 7_566
O3 Eu1 Eu1 32.17(6) . 7_566
O4 Eu1 Eu1 76.99(6) . 7_566
N1 Zn1 N4 161.68(14) . 3_545
N1 Zn1 N2 100.87(13) . 4_545
N4 Zn1 N2 94.75(13) 3_545 4_545
N1 Zn1 O4 92.72(12) . 4_545
N4 Zn1 O4 100.19(13) 3_545 4_545
N2 Zn1 O4 76.74(11) 4_545 4_545
N1 Zn1 O6 93.11(12) . 3_545
N4 Zn1 O6 75.31(12) 3_545 3_545
N2 Zn1 O6 157.35(12) 4_545 3_545
O4 Zn1 O6 84.94(10) 4_545 3_545
N1 Zn1 O1 74.79(12) . .
N4 Zn1 O1 91.59(12) 3_545 .
N2 Zn1 O1 107.05(12) 4_545 .
O4 Zn1 O1 167.36(10) 4_545 .
O6 Zn1 O1 93.71(11) 3_545 .
O1 Zn2 N3 128.38(13) 7_556 .
O1 Zn2 O9 124.83(12) 7_556 .
N3 Zn2 O9 106.21(13) . .
O1 Zn2 O4W 91.70(15) 7_556 .
N3 Zn2 O4W 91.85(14) . .
O9 Zn2 O4W 94.15(15) . .
O1 Zn2 O8 86.90(12) 7_556 .
N3 Zn2 O8 78.52(12) . .
O9 Zn2 O8 97.79(14) . .
O4W Zn2 O8 166.36(13) . .
O10 S1 O10 112.2(3) 2 .
O10 S1 O9 110.66(19) 2 2
O10 S1 O9 109.29(19) . 2
O10 S1 O9 109.29(19) 2 .
O10 S1 O9 110.66(19) . .
O9 S1 O9 104.5(3) 2 .
C3 N1 C2 105.7(3) . .
C3 N1 Zn1 135.1(3) . .
C2 N1 Zn1 118.7(3) . .
C3 N2 C4 104.9(3) . .
C3 N2 Zn1 141.2(3) . 4
C4 N2 Zn1 113.7(3) . 4
C8 N3 C7 105.1(3) . .
C8 N3 Zn2 139.4(3) . .
C7 N3 Zn2 114.0(2) . .
C8 N4 C9 105.2(3) . .
C8 N4 Zn1 136.7(3) . 3_455
C9 N4 Zn1 117.8(3) . 3_455
O2 C1 O1 123.1(4) . .
O2 C1 C2 122.3(3) . .
O1 C1 C2 114.6(3) . .
N1 C2 C4 107.8(3) . .
N1 C2 C1 118.1(3) . .
C4 C2 C1 134.2(4) . .
N2 C3 N1 113.7(4) . .
N2 C3 H3 123.1 . .
N1 C3 H3 123.1 . .
N2 C4 C2 107.9(3) . .
N2 C4 C5 116.8(3) . .
C2 C4 C5 135.1(4) . .
O3 C5 O4 119.4(4) . .
O3 C5 C4 123.4(4) . .
O4 C5 C4 117.2(4) . .
O7 C6 O8 123.3(4) . .
O7 C6 C7 121.3(4) . .
O8 C6 C7 115.4(4) . .
N3 C7 C9 108.5(3) . .
N3 C7 C6 117.2(3) . .
C9 C7 C6 134.2(4) . .
N3 C8 N4 113.5(4) . .
N3 C8 H8 123.2 . .
N4 C8 H8 123.2 . .
N4 C9 C7 107.7(4) . .
N4 C9 C10 117.3(3) . .
C7 C9 C10 134.6(4) . .
O5 C10 O6 123.0(4) . .
O5 C10 C9 121.7(4) . .
O6 C10 C9 115.2(4) . .
C1 O1 Zn2 121.8(3) . 7_556
C1 O1 Zn1 113.4(2) . .
Zn2 O1 Zn1 124.82(13) 7_556 .
C1 O2 Eu1 141.0(3) . 7_566
C5 O3 Eu1 134.7(2) . 7_566
C5 O3 Eu1 98.0(2) . .
Eu1 O3 Eu1 113.35(10) 7_566 .
C5 O4 Zn1 115.2(2) . 4
C5 O4 Eu1 93.4(2) . .
Zn1 O4 Eu1 149.17(12) 4 .
C10 O5 Eu1 150.9(3) . .
C10 O6 Zn1 114.0(3) . 3_455
C6 O7 Eu1 139.3(3) . .
C6 O8 Zn2 113.8(3) . .
S1 O9 Zn2 127.92(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.344(3) .
Eu1 O2W 2.401(3) .
Eu1 O2 2.390(3) 7_566
Eu1 O5 2.408(3) .
Eu1 O3 2.430(3) 7_566
Eu1 O1W 2.444(3) .
Eu1 O3W 2.505(3) .
Eu1 O3 2.584(3) .
Eu1 O4 2.675(3) .
Eu1 Eu1 4.1903(4) 7_566
Zn1 N1 2.024(3) .
Zn1 N4 2.031(3) 3_545
Zn1 N2 2.123(3) 4_545
Zn1 O4 2.191(3) 4_545
Zn1 O6 2.287(3) 3_545
Zn1 O1 2.317(3) .
Zn2 O1 2.016(3) 7_556
Zn2 N3 2.017(3) .
Zn2 O9 2.037(3) .
Zn2 O4W 2.091(3) .
Zn2 O8 2.184(3) .
S1 O10 1.457(3) 2
S1 O10 1.457(3) .
S1 O9 1.492(3) 2
S1 O9 1.492(3) .
N1 C3 1.341(5) .
N1 C2 1.359(5) .
N2 C3 1.331(5) .
N2 C4 1.380(5) .
N2 Zn1 2.123(3) 4
N3 C8 1.327(5) .
N3 C7 1.369(5) .
N4 C8 1.338(5) .
N4 C9 1.371(5) .
N4 Zn1 2.031(3) 3_455
C1 O2 1.249(5) .
C1 O1 1.287(5) .
C1 C2 1.472(5) .
C2 C4 1.398(5) .
C3 H3 0.9300 .
C4 C5 1.471(5) .
C5 O3 1.262(5) .
C5 O4 1.272(5) .
C6 O7 1.253(5) .
C6 O8 1.264(5) .
C6 C7 1.488(5) .
C7 C9 1.377(6) .
C8 H8 0.9300 .
C9 C10 1.472(6) .
C10 O5 1.242(5) .
C10 O6 1.270(5) .
O1 Zn2 2.016(3) 7_556
O2 Eu1 2.390(3) 7_566
O3 Eu1 2.430(3) 7_566
O4 Zn1 2.191(3) 4
O6 Zn1 2.287(3) 3_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N4 Zn1 N1 C3 139.8(5) 3_545 .
N2 Zn1 N1 C3 -72.2(4) 4_545 .
O4 Zn1 N1 C3 4.8(4) 4_545 .
O6 Zn1 N1 C3 89.9(4) 3_545 .
O1 Zn1 N1 C3 -177.1(4) . .
N4 Zn1 N1 C2 -48.7(6) 3_545 .
N2 Zn1 N1 C2 99.3(3) 4_545 .
O4 Zn1 N1 C2 176.3(3) 4_545 .
O6 Zn1 N1 C2 -98.6(3) 3_545 .
O1 Zn1 N1 C2 -5.6(3) . .
O1 Zn2 N3 C8 -111.7(4) 7_556 .
O9 Zn2 N3 C8 76.8(5) . .
O4W Zn2 N3 C8 -18.1(5) . .
O8 Zn2 N3 C8 171.7(5) . .
O1 Zn2 N3 C7 85.4(3) 7_556 .
O9 Zn2 N3 C7 -86.1(3) . .
O4W Zn2 N3 C7 179.0(3) . .
O8 Zn2 N3 C7 8.8(3) . .
C3 N1 C2 C4 -0.6(4) . .
Zn1 N1 C2 C4 -174.3(3) . .
C3 N1 C2 C1 178.9(3) . .
Zn1 N1 C2 C1 5.2(5) . .
O2 C1 C2 N1 -178.5(4) . .
O1 C1 C2 N1 0.5(5) . .
O2 C1 C2 C4 0.8(7) . .
O1 C1 C2 C4 179.8(4) . .
C4 N2 C3 N1 -0.8(5) . .
Zn1 N2 C3 N1 -173.9(3) 4 .
C2 N1 C3 N2 0.9(5) . .
Zn1 N1 C3 N2 173.1(3) . .
C3 N2 C4 C2 0.4(4) . .
Zn1 N2 C4 C2 175.6(2) 4 .
C3 N2 C4 C5 -175.9(3) . .
Zn1 N2 C4 C5 -0.6(4) 4 .
N1 C2 C4 N2 0.1(4) . .
C1 C2 C4 N2 -179.3(4) . .
N1 C2 C4 C5 175.4(4) . .
C1 C2 C4 C5 -4.0(8) . .
N2 C4 C5 O3 173.7(4) . .
C2 C4 C5 O3 -1.3(7) . .
N2 C4 C5 O4 -4.2(5) . .
C2 C4 C5 O4 -179.2(4) . .
C8 N3 C7 C9 -0.3(4) . .
Zn2 N3 C7 C9 168.3(3) . .
C8 N3 C7 C6 179.9(4) . .
Zn2 N3 C7 C6 -11.5(4) . .
O7 C6 C7 N3 -171.9(4) . .
O8 C6 C7 N3 7.0(6) . .
O7 C6 C7 C9 8.4(7) . .
O8 C6 C7 C9 -172.7(4) . .
C7 N3 C8 N4 0.1(5) . .
Zn2 N3 C8 N4 -163.8(3) . .
C9 N4 C8 N3 0.1(5) . .
Zn1 N4 C8 N3 173.9(3) 3_455 .
C8 N4 C9 C7 -0.3(5) . .
Zn1 N4 C9 C7 -175.5(3) 3_455 .
C8 N4 C9 C10 173.3(4) . .
Zn1 N4 C9 C10 -1.8(5) 3_455 .
N3 C7 C9 N4 0.4(5) . .
C6 C7 C9 N4 -179.9(4) . .
N3 C7 C9 C10 -171.7(4) . .
C6 C7 C9 C10 8.0(8) . .
N4 C9 C10 O5 -170.8(4) . .
C7 C9 C10 O5 0.7(8) . .
N4 C9 C10 O6 5.7(6) . .
C7 C9 C10 O6 177.2(4) . .
O2 C1 O1 Zn2 -7.9(5) . 7_556
C2 C1 O1 Zn2 173.2(2) . 7_556
O2 C1 O1 Zn1 174.0(3) . .
C2 C1 O1 Zn1 -4.9(4) . .
N1 Zn1 O1 C1 5.8(3) . .
N4 Zn1 O1 C1 173.4(3) 3_545 .
N2 Zn1 O1 C1 -91.1(3) 4_545 .
O4 Zn1 O1 C1 14.6(6) 4_545 .
O6 Zn1 O1 C1 98.0(3) 3_545 .
N1 Zn1 O1 Zn2 -172.2(2) . 7_556
N4 Zn1 O1 Zn2 -4.60(19) 3_545 7_556
N2 Zn1 O1 Zn2 90.86(19) 4_545 7_556
O4 Zn1 O1 Zn2 -163.4(4) 4_545 7_556
O6 Zn1 O1 Zn2 -79.98(18) 3_545 7_556
O1 C1 O2 Eu1 136.7(3) . 7_566
C2 C1 O2 Eu1 -44.4(6) . 7_566
O4 C5 O3 Eu1 -131.3(3) . 7_566
C4 C5 O3 Eu1 50.8(5) . 7_566
O4 C5 O3 Eu1 3.3(4) . .
C4 C5 O3 Eu1 -174.5(3) . .
O7 Eu1 O3 C5 138.3(2) . .
O2W Eu1 O3 C5 -6.7(3) . .
O2 Eu1 O3 C5 -124.8(2) 7_566 .
O5 Eu1 O3 C5 104.7(3) . .
O3 Eu1 O3 C5 -146.6(3) 7_566 .
O1W Eu1 O3 C5 -71.3(2) . .
O3W Eu1 O3 C5 61.9(2) . .
O4 Eu1 O3 C5 -1.8(2) . .
Eu1 Eu1 O3 C5 -146.6(3) 7_566 .
O7 Eu1 O3 Eu1 -75.12(13) . 7_566
O2W Eu1 O3 Eu1 139.87(12) . 7_566
O2 Eu1 O3 Eu1 21.8(2) 7_566 7_566
O5 Eu1 O3 Eu1 -108.66(19) . 7_566
O3 Eu1 O3 Eu1 0.0 7_566 7_566
O1W Eu1 O3 Eu1 75.34(12) . 7_566
O3W Eu1 O3 Eu1 -151.54(13) . 7_566
O4 Eu1 O3 Eu1 144.77(17) . 7_566
O3 C5 O4 Zn1 -171.3(3) . 4
C4 C5 O4 Zn1 6.7(4) . 4
O3 C5 O4 Eu1 -3.2(4) . .
C4 C5 O4 Eu1 174.8(3) . .
O7 Eu1 O4 C5 -41.1(2) . .
O2W Eu1 O4 C5 177.5(2) . .
O2 Eu1 O4 C5 123.0(2) 7_566 .
O5 Eu1 O4 C5 -131.8(2) . .
O3 Eu1 O4 C5 35.6(2) 7_566 .
O1W Eu1 O4 C5 102.1(2) . .
O3W Eu1 O4 C5 -98.0(2) . .
O3 Eu1 O4 C5 1.8(2) . .
Eu1 Eu1 O4 C5 20.2(2) 7_566 .
O7 Eu1 O4 Zn1 117.5(2) . 4
O2W Eu1 O4 Zn1 -23.8(2) . 4
O2 Eu1 O4 Zn1 -78.3(3) 7_566 4
O5 Eu1 O4 Zn1 26.8(3) . 4
O3 Eu1 O4 Zn1 -165.7(2) 7_566 4
O1W Eu1 O4 Zn1 -99.2(3) . 4
O3W Eu1 O4 Zn1 60.7(2) . 4
O3 Eu1 O4 Zn1 160.5(3) . 4
Eu1 Eu1 O4 Zn1 178.8(3) 7_566 4
O6 C10 O5 Eu1 -161.1(4) . .
C9 C10 O5 Eu1 15.1(9) . .
O7 Eu1 O5 C10 -32.5(6) . .
O2W Eu1 O5 C10 127.2(7) . .
O2 Eu1 O5 C10 -145.9(7) 7_566 .
O3 Eu1 O5 C10 -89.9(6) 7_566 .
O1W Eu1 O5 C10 176.2(6) . .
O3W Eu1 O5 C10 45.3(6) . .
O3 Eu1 O5 C10 1.3(7) . .
O4 Eu1 O5 C10 76.4(7) . .
Eu1 Eu1 O5 C10 -54.8(7) 7_566 .
O5 C10 O6 Zn1 170.1(3) . 3_455
C9 C10 O6 Zn1 -6.3(5) . 3_455
O8 C6 O7 Eu1 118.6(4) . .
C7 C6 O7 Eu1 -62.5(6) . .
O2W Eu1 O7 C6 28.6(5) . .
O2 Eu1 O7 C6 123.7(4) 7_566 .
O5 Eu1 O7 C6 62.2(4) . .
O3 Eu1 O7 C6 -168.6(4) 7_566 .
O1W Eu1 O7 C6 -158.9(4) . .
O3W Eu1 O7 C6 -15.8(4) . .
O3 Eu1 O7 C6 -98.9(4) . .
O4 Eu1 O7 C6 -66.9(4) . .
Eu1 Eu1 O7 C6 -132.0(4) 7_566 .
O7 C6 O8 Zn2 179.6(3) . .
C7 C6 O8 Zn2 0.7(5) . .
O1 Zn2 O8 C6 -135.4(3) 7_556 .
N3 Zn2 O8 C6 -5.2(3) . .
O9 Zn2 O8 C6 99.8(3) . .
O4W Zn2 O8 C6 -51.0(7) . .
O10 S1 O9 Zn2 74.1(3) 2 .
O10 S1 O9 Zn2 -49.9(3) . .
O9 S1 O9 Zn2 -167.4(3) 2 .
O1 Zn2 O9 S1 -149.9(2) 7_556 .
N3 Zn2 O9 S1 22.0(3) . .
O4W Zn2 O9 S1 115.1(3) . .
O8 Zn2 O9 S1 -58.2(3) . .
