#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:38:32 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185297 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/45/7224561.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224561
loop_
_publ_author_name
'Li, Quan-Quan'
'Zhang, Wen-Qian'
'Ren, Chun-Yan'
'Fan, Yan-Ping'
'Li, Jian-Li'
'Liu, Ping'
'Wang, Yao-Yu'
_publ_section_title
;
 Reaction-determined assemblies of 0D to 3D complexes: structural
 diversities and luminescence properties
;
_journal_issue                   19
_journal_name_full               CrystEngComm
_journal_page_first              3358
_journal_paper_doi               10.1039/C6CE00273K
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C29 H20 Ag2 N4 O12'
_chemical_formula_weight         832.23
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-12-25 deposited with the CCDC.
2016-03-09 downloaded from the CCDC.
;
_cell_angle_alpha                99.002(2)
_cell_angle_beta                 93.161(2)
_cell_angle_gamma                110.610(2)
_cell_formula_units_Z            2
_cell_length_a                   9.8097(14)
_cell_length_b                   11.9458(17)
_cell_length_c                   13.1508(19)
_cell_measurement_reflns_used    5997
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.58
_cell_volume                     1414.5(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0176
_diffrn_reflns_av_sigmaI/netI    0.0346
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6944
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    1.461
_exptl_absorpt_correction_T_max  0.7587
_exptl_absorpt_correction_T_min  0.7393
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.954
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       columnar
_exptl_crystal_F_000             824
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.629
_refine_diff_density_min         -0.752
_refine_diff_density_rms         0.179
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         4922
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0517
_refine_ls_R_factor_gt           0.0466
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1300P)²+3.0130P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1522
_refine_ls_wR_factor_ref         0.1727
_reflns_number_gt                4483
_reflns_number_total             4922
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce00273k2.cif
_cod_data_source_block           7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7224556--7224565.cif.
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               7224561
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.44050(4) 0.83078(4) 0.59942(3) 0.04118(19) Uani 1 1 d .
Ag2 Ag 0.73764(5) 0.96647(4) 0.53407(3) 0.04052(19) Uani 1 1 d .
C1 C 0.5649(4) 0.7499(4) 0.3747(3) 0.0204(8) Uani 1 1 d .
C2 C 0.5077(4) 0.6503(4) 0.2802(3) 0.0201(8) Uani 1 1 d .
C3 C 0.3646(5) 0.6225(4) 0.2338(3) 0.0248(9) Uani 1 1 d .
H3 H 0.3081 0.6657 0.2609 0.030 Uiso 1 1 calc R
C4 C 0.3078(5) 0.5302(4) 0.1472(3) 0.0265(9) Uani 1 1 d .
C5 C 0.3895(5) 0.4621(4) 0.1092(3) 0.0272(9) Uani 1 1 d .
H5 H 0.3496 0.3968 0.0541 0.033 Uiso 1 1 calc R
C6 C 0.5318(5) 0.4934(4) 0.1553(3) 0.0221(8) Uani 1 1 d .
C7 C 0.5942(4) 0.5893(4) 0.2394(3) 0.0206(8) Uani 1 1 d .
C8 C 0.1626(5) 0.5082(5) 0.0891(4) 0.0343(11) Uani 1 1 d .
C9 C 0.7485(4) 0.6269(4) 0.2907(3) 0.0204(8) Uani 1 1 d .
C10 C 0.8684(5) 0.7185(4) 0.2629(3) 0.0219(8) Uani 1 1 d .
C11 C 1.0075(5) 0.7588(4) 0.3164(4) 0.0257(9) Uani 1 1 d .
H11 H 1.0847 0.8186 0.2954 0.031 Uiso 1 1 calc R
C12 C 1.0318(5) 0.7098(4) 0.4016(3) 0.0245(9) Uani 1 1 d .
C13 C 0.9152(4) 0.6204(4) 0.4307(3) 0.0229(9) Uani 1 1 d .
H13 H 0.9303 0.5877 0.4881 0.027 Uiso 1 1 calc R
C14 C 0.7765(5) 0.5786(4) 0.3764(3) 0.0221(8) Uani 1 1 d .
C15 C 0.6560(5) 0.4755(4) 0.4079(4) 0.0256(9) Uani 1 1 d .
C16 C 1.1819(5) 0.7566(4) 0.4643(4) 0.0281(10) Uani 1 1 d .
C17 C 0.6013(7) 1.0469(5) 0.7815(4) 0.0427(13) Uani 1 1 d .
H17 H 0.5639 1.0886 0.7404 0.051 Uiso 1 1 calc R
C18 C 0.6821(9) 1.1103(6) 0.8748(5) 0.0586(18) Uani 1 1 d .
H18 H 0.6969 1.1921 0.8965 0.070 Uiso 1 1 calc R
C19 C 0.7418(7) 1.0497(6) 0.9367(5) 0.0492(14) Uani 1 1 d .
C20 C 0.7048(7) 0.9282(6) 0.9031(4) 0.0502(15) Uani 1 1 d .
H20 H 0.7337 0.8825 0.9449 0.060 Uiso 1 1 calc R
C21 C 0.6254(6) 0.8722(5) 0.8081(4) 0.0404(12) Uani 1 1 d .
H21 H 0.6071 0.7899 0.7858 0.048 Uiso 1 1 calc R
C22 C 0.8366(8) 1.1191(7) 1.0377(5) 0.0586(17) Uani 1 1 d .
H22A H 0.8837 1.0685 1.0638 0.070 Uiso 1 1 calc R
H22B H 0.9130 1.1912 1.0244 0.070 Uiso 1 1 calc R
C23 C 0.7523(8) 1.1567(7) 1.1189(5) 0.0586(17) Uani 1 1 d .
H23A H 0.6897 1.0848 1.1422 0.070 Uiso 1 1 calc R
H23B H 0.6893 1.1926 1.0882 0.070 Uiso 1 1 calc R
C24 C 0.8502(7) 1.2488(6) 1.2138(4) 0.0444(13) Uani 1 1 d .
H24A H 0.9131 1.3203 1.1900 0.053 Uiso 1 1 calc R
H24B H 0.7878 1.2742 1.2594 0.053 Uiso 1 1 calc R
C25 C 0.9440(6) 1.2024(5) 1.2747(4) 0.0335(11) Uani 1 1 d .
C26 C 1.0910(6) 1.2672(5) 1.3051(4) 0.0408(12) Uani 1 1 d .
H26 H 1.1344 1.3435 1.2878 0.049 Uiso 1 1 calc R
C27 C 1.1754(6) 1.2207(5) 1.3611(4) 0.0386(11) Uani 1 1 d .
H27 H 1.2748 1.2663 1.3794 0.046 Uiso 1 1 calc R
C28 C 0.9747(6) 1.0501(5) 1.3624(4) 0.0347(11) Uani 1 1 d .
H28 H 0.9326 0.9756 1.3829 0.042 Uiso 1 1 calc R
C29 C 0.8880(6) 1.0907(5) 1.3065(4) 0.0364(11) Uani 1 1 d .
H29 H 0.7890 1.0431 1.2890 0.044 Uiso 1 1 calc R
N1 N 0.5732(5) 0.9295(4) 0.7463(3) 0.0334(9) Uani 1 1 d .
N2 N 1.1194(5) 1.1131(4) 1.3896(3) 0.0333(9) Uani 1 1 d .
N3 N 0.6132(5) 0.4208(4) 0.1103(4) 0.0361(10) Uani 1 1 d .
N4 N 0.8498(5) 0.7753(4) 0.1729(3) 0.0335(9) Uani 1 1 d .
O1 O 0.5296(4) 0.7189(3) 0.4601(2) 0.0323(7) Uani 1 1 d .
O2 O 0.6392(4) 0.8540(3) 0.3644(3) 0.0410(9) Uani 1 1 d .
O3 O 0.1018(5) 0.5823(4) 0.1193(4) 0.0593(13) Uani 1 1 d .
H3A H 0.0287 0.5687 0.0788 0.089 Uiso 1 1 calc R
O4 O 0.1093(5) 0.4222(4) 0.0166(4) 0.0551(12) Uani 1 1 d .
O5 O 0.5487(6) 0.3298(5) 0.0451(4) 0.0707(15) Uani 1 1 d .
O6 O 0.7444(5) 0.4547(5) 0.1376(4) 0.0620(13) Uani 1 1 d .
O7 O 0.7314(5) 0.7435(5) 0.1237(4) 0.0589(12) Uani 1 1 d .
O8 O 0.9585(5) 0.8556(5) 0.1529(4) 0.0720(16) Uani 1 1 d .
O9 O 1.2814(4) 0.8497(3) 0.4453(3) 0.0389(8) Uani 1 1 d .
O10 O 1.2002(4) 0.6995(3) 0.5300(3) 0.0352(8) Uani 1 1 d .
O11 O 0.6569(4) 0.4870(3) 0.5084(2) 0.0304(7) Uani 1 1 d .
H11A H 0.5926 0.4275 0.5221 0.046 Uiso 1 1 calc R
O12 O 0.5701(4) 0.3922(3) 0.3453(3) 0.0378(8) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 O10 141.57(14) . 1_455
N1 Ag1 O1 123.08(14) . .
O10 Ag1 O1 87.59(12) 1_455 .
N1 Ag1 O9 143.62(15) . 1_455
O10 Ag1 O9 52.57(11) 1_455 1_455
O1 Ag1 O9 82.60(12) . 1_455
N1 Ag1 Ag2 76.80(11) . .
O10 Ag1 Ag2 141.59(9) 1_455 .
O1 Ag1 Ag2 62.76(8) . .
O9 Ag1 Ag2 97.23(8) 1_455 .
N2 Ag2 O9 135.05(14) 2_777 2_776
N2 Ag2 O2 110.76(15) 2_777 .
O9 Ag2 O2 110.93(14) 2_776 .
N2 Ag2 Ag1 101.77(11) 2_777 .
O9 Ag2 Ag1 96.81(9) 2_776 .
O2 Ag2 Ag1 86.45(9) . .
O2 C1 O1 124.9(4) . .
O2 C1 C2 119.2(4) . .
O1 C1 C2 115.9(4) . .
C7 C2 C3 120.9(4) . .
C7 C2 C1 121.0(4) . .
C3 C2 C1 118.0(4) . .
C4 C3 C2 119.5(4) . .
C4 C3 H3 120.2 . .
C2 C3 H3 120.2 . .
C5 C4 C3 120.3(4) . .
C5 C4 C8 118.9(4) . .
C3 C4 C8 120.6(4) . .
C6 C5 C4 118.7(4) . .
C6 C5 H5 120.7 . .
C4 C5 H5 120.7 . .
C5 C6 C7 122.2(4) . .
C5 C6 N3 116.1(4) . .
C7 C6 N3 121.7(4) . .
C2 C7 C6 118.1(4) . .
C2 C7 C9 118.1(4) . .
C6 C7 C9 123.8(4) . .
O4 C8 O3 123.6(5) . .
O4 C8 C4 120.2(5) . .
O3 C8 C4 116.2(4) . .
C14 C9 C10 116.6(4) . .
C14 C9 C7 120.2(4) . .
C10 C9 C7 123.0(4) . .
C11 C10 C9 122.2(4) . .
C11 C10 N4 117.2(4) . .
C9 C10 N4 120.6(4) . .
C10 C11 C12 120.0(4) . .
C10 C11 H11 120.0 . .
C12 C11 H11 120.0 . .
C13 C12 C11 118.8(4) . .
C13 C12 C16 120.3(4) . .
C11 C12 C16 120.9(4) . .
C12 C13 C14 121.4(4) . .
C12 C13 H13 119.3 . .
C14 C13 H13 119.3 . .
C13 C14 C9 121.1(4) . .
C13 C14 C15 118.9(4) . .
C9 C14 C15 119.9(4) . .
O12 C15 O11 125.0(4) . .
O12 C15 C14 122.3(4) . .
O11 C15 C14 112.7(4) . .
O10 C16 O9 123.6(4) . .
O10 C16 C12 117.2(4) . .
O9 C16 C12 119.2(4) . .
N1 C17 C18 123.9(6) . .
N1 C17 H17 118.0 . .
C18 C17 H17 118.0 . .
C17 C18 C19 118.8(6) . .
C17 C18 H18 120.6 . .
C19 C18 H18 120.6 . .
C20 C19 C18 116.6(6) . .
C20 C19 C22 123.6(6) . .
C18 C19 C22 119.7(6) . .
C19 C20 C21 120.6(6) . .
C19 C20 H20 119.7 . .
C21 C20 H20 119.7 . .
N1 C21 C20 123.4(5) . .
N1 C21 H21 118.3 . .
C20 C21 H21 118.3 . .
C23 C22 C19 113.2(6) . .
C23 C22 H22A 108.9 . .
C19 C22 H22A 108.9 . .
C23 C22 H22B 108.9 . .
C19 C22 H22B 108.9 . .
H22A C22 H22B 107.8 . .
C22 C23 C24 113.7(6) . .
C22 C23 H23A 108.8 . .
C24 C23 H23A 108.8 . .
C22 C23 H23B 108.8 . .
C24 C23 H23B 108.8 . .
H23A C23 H23B 107.7 . .
C25 C24 C23 115.0(5) . .
C25 C24 H24A 108.5 . .
C23 C24 H24A 108.5 . .
C25 C24 H24B 108.5 . .
C23 C24 H24B 108.5 . .
H24A C24 H24B 107.5 . .
C26 C25 C29 115.4(5) . .
C26 C25 C24 122.6(5) . .
C29 C25 C24 122.1(5) . .
C25 C26 C27 121.0(5) . .
C25 C26 H26 119.5 . .
C27 C26 H26 119.5 . .
N2 C27 C26 122.4(5) . .
N2 C27 H27 118.8 . .
C26 C27 H27 118.8 . .
N2 C28 C29 122.8(5) . .
N2 C28 H28 118.6 . .
C29 C28 H28 118.6 . .
C28 C29 C25 121.3(5) . .
C28 C29 H29 119.3 . .
C25 C29 H29 119.3 . .
C17 N1 C21 116.3(4) . .
C17 N1 Ag1 123.0(4) . .
C21 N1 Ag1 120.6(3) . .
C27 N2 C28 117.1(5) . .
C27 N2 Ag2 121.2(4) . 2_777
C28 N2 Ag2 121.5(3) . 2_777
O5 N3 O6 122.3(5) . .
O5 N3 C6 119.0(5) . .
O6 N3 C6 118.7(4) . .
O7 N4 O8 122.6(5) . .
O7 N4 C10 119.9(4) . .
O8 N4 C10 117.5(4) . .
C1 O1 Ag1 126.7(3) . .
C1 O2 Ag2 106.2(3) . .
C8 O3 H3A 109.5 . .
C16 O9 Ag2 122.7(3) . 2_776
C16 O9 Ag1 86.1(3) . 1_655
Ag2 O9 Ag1 111.81(15) 2_776 1_655
C16 O10 Ag1 97.4(3) . 1_655
C15 O11 H11A 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.178(4) .
Ag1 O10 2.358(3) 1_455
Ag1 O1 2.477(3) .
Ag1 O9 2.577(4) 1_455
Ag1 Ag2 3.0411(7) .
Ag2 N2 2.228(4) 2_777
Ag2 O9 2.244(4) 2_776
Ag2 O2 2.373(4) .
C1 O2 1.234(6) .
C1 O1 1.266(5) .
C1 C2 1.505(6) .
C2 C7 1.380(6) .
C2 C3 1.403(6) .
C3 C4 1.389(6) .
C3 H3 0.9300 .
C4 C5 1.389(7) .
C4 C8 1.494(6) .
C5 C6 1.387(6) .
C5 H5 0.9300 .
C6 C7 1.394(6) .
C6 N3 1.456(6) .
C7 C9 1.504(6) .
C8 O4 1.224(7) .
C8 O3 1.260(7) .
C9 C14 1.400(6) .
C9 C10 1.407(6) .
C10 C11 1.384(6) .
C10 N4 1.487(6) .
C11 C12 1.388(6) .
C11 H11 0.9300 .
C12 C13 1.383(6) .
C12 C16 1.518(6) .
C13 C14 1.383(6) .
C13 H13 0.9300 .
C14 C15 1.508(6) .
C15 O12 1.207(6) .
C15 O11 1.306(6) .
C16 O10 1.223(6) .
C16 O9 1.266(6) .
C17 N1 1.330(7) .
C17 C18 1.374(8) .
C17 H17 0.9300 .
C18 C19 1.400(9) .
C18 H18 0.9300 .
C19 C20 1.358(9) .
C19 C22 1.514(9) .
C20 C21 1.371(8) .
C20 H20 0.9300 .
C21 N1 1.328(7) .
C21 H21 0.9300 .
C22 C23 1.496(10) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 C24 1.544(9) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C25 1.488(8) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C26 1.375(8) .
C25 C29 1.393(8) .
C26 C27 1.387(8) .
C26 H26 0.9300 .
C27 N2 1.330(7) .
C27 H27 0.9300 .
C28 N2 1.348(7) .
C28 C29 1.353(8) .
C28 H28 0.9300 .
C29 H29 0.9300 .
N2 Ag2 2.228(4) 2_777
N3 O5 1.216(7) .
N3 O6 1.219(7) .
N4 O7 1.201(6) .
N4 O8 1.231(6) .
O3 H3A 0.8200 .
O9 Ag2 2.244(4) 2_776
O9 Ag1 2.577(4) 1_655
O10 Ag1 2.358(3) 1_655
O11 H11A 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Ag1 Ag2 N2 62.26(17) . 2_777
O10 Ag1 Ag2 N2 -119.95(18) 1_455 2_777
O1 Ag1 Ag2 N2 -76.45(14) . 2_777
O9 Ag1 Ag2 N2 -154.25(14) 1_455 2_777
N1 Ag1 Ag2 O9 -76.59(16) . 2_776
O10 Ag1 Ag2 O9 101.21(18) 1_455 2_776
O1 Ag1 Ag2 O9 144.70(14) . 2_776
O9 Ag1 Ag2 O9 66.90(16) 1_455 2_776
N1 Ag1 Ag2 O2 172.73(15) . .
O10 Ag1 Ag2 O2 -9.47(18) 1_455 .
O1 Ag1 Ag2 O2 34.03(13) . .
O9 Ag1 Ag2 O2 -43.77(13) 1_455 .
O2 C1 C2 C7 83.4(5) . .
O1 C1 C2 C7 -97.6(5) . .
O2 C1 C2 C3 -95.6(5) . .
O1 C1 C2 C3 83.4(5) . .
C7 C2 C3 C4 1.7(6) . .
C1 C2 C3 C4 -179.3(4) . .
C2 C3 C4 C5 2.8(7) . .
C2 C3 C4 C8 -173.0(4) . .
C3 C4 C5 C6 -4.2(7) . .
C8 C4 C5 C6 171.6(4) . .
C4 C5 C6 C7 1.2(6) . .
C4 C5 C6 N3 -178.4(4) . .
C3 C2 C7 C6 -4.5(6) . .
C1 C2 C7 C6 176.5(4) . .
C3 C2 C7 C9 177.8(4) . .
C1 C2 C7 C9 -1.2(6) . .
C5 C6 C7 C2 3.1(6) . .
N3 C6 C7 C2 -177.3(4) . .
C5 C6 C7 C9 -179.3(4) . .
N3 C6 C7 C9 0.3(6) . .
C5 C4 C8 O4 8.5(8) . .
C3 C4 C8 O4 -175.7(5) . .
C5 C4 C8 O3 -171.4(5) . .
C3 C4 C8 O3 4.5(7) . .
C2 C7 C9 C14 84.9(5) . .
C6 C7 C9 C14 -92.6(5) . .
C2 C7 C9 C10 -89.0(5) . .
C6 C7 C9 C10 93.4(5) . .
C14 C9 C10 C11 0.5(6) . .
C7 C9 C10 C11 174.7(4) . .
C14 C9 C10 N4 179.9(4) . .
C7 C9 C10 N4 -5.9(6) . .
C9 C10 C11 C12 -1.0(7) . .
N4 C10 C11 C12 179.6(4) . .
C10 C11 C12 C13 0.4(6) . .
C10 C11 C12 C16 -177.2(4) . .
C11 C12 C13 C14 0.7(6) . .
C16 C12 C13 C14 178.3(4) . .
C12 C13 C14 C9 -1.2(6) . .
C12 C13 C14 C15 176.2(4) . .
C10 C9 C14 C13 0.5(6) . .
C7 C9 C14 C13 -173.8(4) . .
C10 C9 C14 C15 -176.8(4) . .
C7 C9 C14 C15 8.8(6) . .
C13 C14 C15 O12 -137.1(5) . .
C9 C14 C15 O12 40.2(6) . .
C13 C14 C15 O11 42.4(5) . .
C9 C14 C15 O11 -140.2(4) . .
C13 C12 C16 O10 11.3(6) . .
C11 C12 C16 O10 -171.2(4) . .
C13 C12 C16 O9 -170.0(4) . .
C11 C12 C16 O9 7.5(6) . .
N1 C17 C18 C19 1.3(11) . .
C17 C18 C19 C20 -5.2(11) . .
C17 C18 C19 C22 177.4(7) . .
C18 C19 C20 C21 6.4(11) . .
C22 C19 C20 C21 -176.3(6) . .
C19 C20 C21 N1 -3.8(11) . .
C20 C19 C22 C23 -107.7(9) . .
C18 C19 C22 C23 69.5(9) . .
C19 C22 C23 C24 -168.4(6) . .
C22 C23 C24 C25 -63.6(8) . .
C23 C24 C25 C26 132.3(6) . .
C23 C24 C25 C29 -48.8(7) . .
C29 C25 C26 C27 1.6(8) . .
C24 C25 C26 C27 -179.4(5) . .
C25 C26 C27 N2 -1.1(9) . .
N2 C28 C29 C25 -0.9(8) . .
C26 C25 C29 C28 -0.7(7) . .
C24 C25 C29 C28 -179.7(5) . .
C18 C17 N1 C21 1.5(9) . .
C18 C17 N1 Ag1 178.6(6) . .
C20 C21 N1 C17 -0.3(9) . .
C20 C21 N1 Ag1 -177.5(5) . .
O10 Ag1 N1 C17 -98.1(5) 1_455 .
O1 Ag1 N1 C17 124.2(4) . .
O9 Ag1 N1 C17 -4.5(6) 1_455 .
Ag2 Ag1 N1 C17 79.7(4) . .
O10 Ag1 N1 C21 78.9(5) 1_455 .
O1 Ag1 N1 C21 -58.9(4) . .
O9 Ag1 N1 C21 172.4(4) 1_455 .
Ag2 Ag1 N1 C21 -103.3(4) . .
C26 C27 N2 C28 -0.6(8) . .
C26 C27 N2 Ag2 174.0(4) . 2_777
C29 C28 N2 C27 1.5(8) . .
C29 C28 N2 Ag2 -173.0(4) . 2_777
C5 C6 N3 O5 -8.7(7) . .
C7 C6 N3 O5 171.6(5) . .
C5 C6 N3 O6 169.6(5) . .
C7 C6 N3 O6 -10.0(7) . .
C11 C10 N4 O7 179.8(5) . .
C9 C10 N4 O7 0.5(7) . .
C11 C10 N4 O8 -1.2(7) . .
C9 C10 N4 O8 179.5(5) . .
O2 C1 O1 Ag1 43.7(6) . .
C2 C1 O1 Ag1 -135.2(3) . .
N1 Ag1 O1 C1 -107.5(4) . .
O10 Ag1 O1 C1 97.2(4) 1_455 .
O9 Ag1 O1 C1 44.6(3) 1_455 .
Ag2 Ag1 O1 C1 -57.5(3) . .
O1 C1 O2 Ag2 11.3(6) . .
C2 C1 O2 Ag2 -169.9(3) . .
N2 Ag2 O2 C1 61.3(4) 2_777 .
O9 Ag2 O2 C1 -135.9(3) 2_776 .
Ag1 Ag2 O2 C1 -39.9(3) . .
O10 C16 O9 Ag2 -118.5(4) . 2_776
C12 C16 O9 Ag2 62.9(5) . 2_776
O10 C16 O9 Ag1 -5.0(5) . 1_655
C12 C16 O9 Ag1 176.4(4) . 1_655
O9 C16 O10 Ag1 5.5(5) . 1_655
C12 C16 O10 Ag1 -175.8(3) . 1_655
