#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:28:41 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185240 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/51/7225109.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7225109
loop_
_publ_author_name
'Yawer, Mohd'
'Kariem, Mukaddus'
'Sood, Puneet'
'Sheikh, Haq Nawaz'
_publ_section_title
;
 Lanthanide-based entangled coordination polymers connected by
 thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures,
 luminescence and magnetic properties
;
_journal_issue                   20
_journal_name_full               CrystEngComm
_journal_page_first              3617
_journal_paper_doi               10.1039/C6CE00321D
_journal_volume                  18
_journal_year                    2016
_chemical_absolute_configuration unk
_chemical_formula_sum            'C51 H47 Eu4 N3 O29 S6'
_chemical_formula_weight         1966.11
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-12-16 deposited with the CCDC.
2016-04-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.473(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.2547(5)
_cell_length_b                   17.5664(8)
_cell_length_c                   16.8496(9)
_cell_measurement_reflns_used    9883
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      29.3
_cell_measurement_theta_min      2.4
_cell_volume                     3325.1(3)
_computing_cell_refinement       'APEX2/SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT/XPREP (Bruker, 2004)'
_computing_molecular_graphics
'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SIR92 (Altornare et al., 1993)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker axs kappa apex2 CCD Diffractometer'
_diffrn_measurement_method       'ω and φ scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0236
_diffrn_reflns_av_unetI/netI     0.0295
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            38023
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         1.813
_diffrn_source                   'Sealed tube'
_exptl_absorpt_coefficient_mu    3.994
_exptl_absorpt_correction_T_max  0.854
_exptl_absorpt_correction_T_min  0.591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 1999)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.964
_exptl_crystal_description       block
_exptl_crystal_F_000             1908
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_refine_diff_density_max         2.178
_refine_diff_density_min         -1.240
_refine_diff_density_rms         0.148
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.219(16)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     855
_refine_ls_number_reflns         12956
_refine_ls_number_restraints     366
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0328
_refine_ls_R_factor_gt           0.0311
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+25.1797P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0710
_refine_ls_wR_factor_ref         0.0718
_reflns_Friedel_coverage         0.934
_reflns_Friedel_fraction_full    0.996
_reflns_Friedel_fraction_max     0.996
_reflns_number_gt                12470
_reflns_number_total             12956
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce00321d2.cif
_cod_data_source_block           s4
_cod_depositor_comments
'Adding full bibliography for 7225101--7225109.cif.'
_cod_database_code               7225109
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.502
_shelx_estimated_absorpt_t_max   0.825
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6296(12) -0.1380(8) 0.3591(9) 0.025(3) Uani 1 1 d . . . . .
C2 C 0.5737(13) -0.0666(7) 0.3302(7) 0.029(3) Uani 1 1 d . . . . .
C3 C 0.5819(17) -0.0328(9) 0.2579(9) 0.060(5) Uani 1 1 d . . . . .
H3 H 0.6190 -0.0548 0.2158 0.073 Uiso 1 1 calc R U . . .
C4 C 0.5269(16) 0.0401(9) 0.2546(9) 0.055(5) Uani 1 1 d . . . . .
H4 H 0.5253 0.0712 0.2099 0.067 Uiso 1 1 calc R U . . .
C5 C 0.4773(13) 0.0595(7) 0.3226(8) 0.028(3) Uani 1 1 d . . . . .
C6 C 0.4204(14) 0.1330(7) 0.3430(8) 0.025(3) Uani 1 1 d . . . . .
C7 C -0.1131(12) -0.1306(8) 0.4755(8) 0.025(3) Uani 1 1 d . . . . .
C8 C -0.0507(12) -0.0578(7) 0.4696(7) 0.027(3) Uani 1 1 d . . . . .
C9 C 0.0053(18) -0.0302(8) 0.4077(8) 0.059(5) Uani 1 1 d . . . . .
H9 H 0.0092 -0.0561 0.3597 0.071 Uiso 1 1 calc R U . . .
C10 C 0.0580(16) 0.0421(8) 0.4224(8) 0.055(5) Uani 1 1 d . . . . .
H10 H 0.1017 0.0683 0.3861 0.066 Uiso 1 1 calc R U . . .
C11 C 0.0367(12) 0.0682(7) 0.4960(7) 0.027(3) Uani 1 1 d . . . . .
C12 C 0.0772(10) 0.1418(7) 0.5309(8) 0.019(3) Uani 1 1 d . . . . .
C13 C 0.5757(12) -0.1242(7) 0.6770(8) 0.018(3) Uani 1 1 d . . . . .
C14 C 0.5301(13) -0.0474(7) 0.6518(8) 0.028(3) Uani 1 1 d . . . . .
C15 C 0.5546(16) -0.0095(8) 0.5856(8) 0.054(5) Uani 1 1 d . . . . .
H15 H 0.6086 -0.0267 0.5499 0.065 Uiso 1 1 calc R U . . .
C16 C 0.4897(17) 0.0591(9) 0.5756(9) 0.060(5) Uani 1 1 d . . . . .
H16 H 0.4938 0.0910 0.5318 0.072 Uiso 1 1 calc R U . . .
C17 C 0.4209(14) 0.0729(7) 0.6373(8) 0.032(3) Uani 1 1 d . . . . .
C18 C 0.3389(12) 0.1380(7) 0.6488(8) 0.022(3) Uani 1 1 d . . . . .
C19 C -0.1810(10) 0.6337(7) 0.8533(7) 0.017(3) Uani 1 1 d . . . . .
C20 C -0.1012(12) 0.5670(7) 0.8621(7) 0.023(3) Uani 1 1 d . . . . .
C21 C -0.0231(12) 0.5498(7) 0.9251(7) 0.034(3) Uani 1 1 d . . . . .
H21 H -0.0098 0.5809 0.9695 0.040 Uiso 1 1 calc R U . . .
C22 C 0.0335(12) 0.4810(7) 0.9151(7) 0.033(3) Uani 1 1 d . . . . .
H22 H 0.0893 0.4614 0.9527 0.040 Uiso 1 1 calc R U . . .
C23 C 0.0013(13) 0.4444(8) 0.8462(8) 0.029(3) Uani 1 1 d . . . . .
C24 C 0.0463(13) 0.3671(7) 0.8231(9) 0.021(3) Uani 1 1 d . . . . .
C25 C 0.5847(10) 0.6339(6) 0.9815(7) 0.017(2) Uani 1 1 d . . . . .
C26 C 0.5411(11) 0.5600(6) 1.0109(7) 0.022(3) Uani 1 1 d . . . . .
C27 C 0.5674(12) 0.5270(7) 1.0820(7) 0.032(3) Uani 1 1 d . . . . .
H27 H 0.6168 0.5492 1.1218 0.039 Uiso 1 1 calc R U . . .
C28 C 0.5124(13) 0.4548(7) 1.0901(8) 0.036(3) Uani 1 1 d . . . . .
H28 H 0.5235 0.4235 1.1345 0.043 Uiso 1 1 calc R U . . .
C29 C 0.4415(11) 0.4376(6) 1.0248(7) 0.020(2) Uani 1 1 d . . . . .
C30 C 0.3689(11) 0.3672(7) 1.0114(8) 0.020(3) Uani 1 1 d . . . . .
C31 C -0.0579(14) 0.6275(7) 1.1696(9) 0.022(3) Uani 1 1 d . . . . .
C32 C 0.0014(13) 0.5537(7) 1.1835(8) 0.027(3) Uani 1 1 d . . . . .
C33 C 0.0696(12) 0.5335(7) 1.2509(7) 0.034(3) Uani 1 1 d . . . . .
H33 H 0.0790 0.5641 1.2959 0.040 Uiso 1 1 calc R U . . .
C34 C 0.1230(14) 0.4622(7) 1.2443(8) 0.039(3) Uani 1 1 d . . . . .
H34 H 0.1716 0.4397 1.2843 0.047 Uiso 1 1 calc R U . . .
C35 C 0.0950(12) 0.4294(7) 1.1714(7) 0.023(3) Uani 1 1 d . . . . .
C36 C 0.1400(10) 0.3567(6) 1.1397(7) 0.016(2) Uani 1 1 d . . . . .
C37 C -0.1110(11) 0.2734(8) 0.9836(9) 0.046(3) Uani 1 1 d D U . . .
H37 H -0.0901 0.3246 0.9847 0.055 Uiso 1 1 calc R U . . .
C38 C -0.3170(18) 0.3159(13) 0.9669(14) 0.092(6) Uani 1 1 d D U . . .
H38A H -0.2851 0.3622 0.9911 0.110 Uiso 1 1 calc R U . . .
H38B H -0.3851 0.3006 0.9957 0.110 Uiso 1 1 calc R U . . .
C39 C -0.357(3) 0.332(2) 0.8820(16) 0.151(11) Uani 1 1 d D U . . .
H39A H -0.4166 0.3712 0.8802 0.227 Uiso 1 1 calc R U . . .
H39B H -0.2907 0.3481 0.8534 0.227 Uiso 1 1 calc R U . . .
H39C H -0.3907 0.2864 0.8580 0.227 Uiso 1 1 calc R U . . .
C40 C -0.267(2) 0.1766(12) 0.9787(15) 0.089(5) Uani 1 1 d D U . . .
H40A H -0.3461 0.1762 0.9989 0.106 Uiso 1 1 calc R U . . .
H40B H -0.2146 0.1495 1.0166 0.106 Uiso 1 1 calc R U . . .
C41 C -0.272(2) 0.1347(17) 0.9021(16) 0.122(9) Uani 1 1 d D U . . .
H41A H -0.2992 0.0837 0.9102 0.183 Uiso 1 1 calc R U . . .
H41B H -0.3255 0.1601 0.8643 0.183 Uiso 1 1 calc R U . . .
H41C H -0.1937 0.1333 0.8821 0.183 Uiso 1 1 calc R U . . .
C42 C 0.5948(15) 0.2807(12) 0.5092(14) 0.090(6) Uani 1 1 d D U . . .
H42 H 0.5784 0.3324 0.5038 0.108 Uiso 1 1 calc R U . . .
C43 C 0.743(3) 0.185(2) 0.520(2) 0.171(9) Uani 1 1 d D U . . .
H43A H 0.6934 0.1535 0.5519 0.205 Uiso 1 1 calc R U . . .
H43B H 0.8213 0.1827 0.5470 0.205 Uiso 1 1 calc R U . . .
C44 C 0.759(4) 0.133(3) 0.450(2) 0.232(16) Uani 1 1 d D U . . .
H44A H 0.7893 0.0850 0.4689 0.349 Uiso 1 1 calc R U . . .
H44B H 0.6841 0.1260 0.4210 0.349 Uiso 1 1 calc R U . . .
H44C H 0.8147 0.1559 0.4160 0.349 Uiso 1 1 calc R U . . .
C45 C 0.775(3) 0.318(2) 0.585(2) 0.172(9) Uani 1 1 d D U . . .
H45A H 0.7415 0.3686 0.5785 0.207 Uiso 1 1 calc R U . . .
H45B H 0.8567 0.3183 0.5695 0.207 Uiso 1 1 calc R U . . .
C46 C 0.766(4) 0.288(2) 0.670(2) 0.216(15) Uani 1 1 d D U . . .
H46A H 0.8102 0.3206 0.7069 0.324 Uiso 1 1 calc R U . . .
H46B H 0.6840 0.2871 0.6831 0.324 Uiso 1 1 calc R U . . .
H46C H 0.7980 0.2373 0.6742 0.324 Uiso 1 1 calc R U . . .
C47 C 0.668(2) 0.275(4) 1.224(4) 0.099(7) Uani 0.30(8) 1 d D U P A 1
H47 H 0.6436 0.3015 1.2683 0.118 Uiso 0.30(8) 1 calc R U P A 1
C47' C 0.6732(19) 0.2888(18) 1.190(3) 0.097(7) Uani 0.70(8) 1 d D U P A 2
H47' H 0.6682 0.3414 1.1841 0.116 Uiso 0.70(8) 1 calc R U P A 2
C48 C 0.830(3) 0.1891(18) 1.192(2) 0.161(8) Uani 1 1 d D U . . .
H48A H 0.9139 0.1962 1.1827 0.193 Uiso 1 1 calc R U . . .
H48B H 0.7893 0.1760 1.1416 0.193 Uiso 1 1 calc R U . . .
C49 C 0.818(4) 0.123(2) 1.250(2) 0.188(13) Uani 1 1 d D U . . .
H49A H 0.8513 0.0779 1.2283 0.282 Uiso 1 1 calc R U . . .
H49B H 0.8604 0.1352 1.2997 0.282 Uiso 1 1 calc R U . . .
H49C H 0.7358 0.1150 1.2586 0.282 Uiso 1 1 calc R U . . .
C50 C 0.873(2) 0.318(2) 1.246(2) 0.166(9) Uani 1 1 d D U . . .
H50A H 0.8639 0.3628 1.2128 0.199 Uiso 1 1 calc R U . . .
H50B H 0.9521 0.2977 1.2414 0.199 Uiso 1 1 calc R U . . .
C51 C 0.857(4) 0.339(3) 1.331(2) 0.226(15) Uani 1 1 d D U . . .
H51A H 0.9149 0.3768 1.3483 0.338 Uiso 1 1 calc R U . . .
H51B H 0.7783 0.3600 1.3359 0.338 Uiso 1 1 calc R U . . .
H51C H 0.8662 0.2950 1.3644 0.338 Uiso 1 1 calc R U . . .
N1 N -0.2263(9) 0.2562(10) 0.9744(8) 0.067(3) Uani 1 1 d D U . . .
N2 N 0.7038(17) 0.2616(17) 0.5404(14) 0.138(6) Uani 1 1 d D U . . .
N3 N 0.7826(16) 0.2602(15) 1.2201(13) 0.132(5) Uani 1 1 d D U . . .
O1 O 0.6807(8) -0.1749(5) 0.3072(5) 0.029(2) Uani 1 1 d . . . . .
O2 O 0.6255(8) -0.1538(5) 0.4310(5) 0.0299(19) Uani 1 1 d . . . . .
O3 O 0.4440(8) 0.1877(4) 0.2965(5) 0.0299(19) Uani 1 1 d . . . . .
O4 O 0.3628(9) 0.1381(5) 0.4021(6) 0.035(2) Uani 1 1 d . . . . .
O5 O -0.1074(9) -0.1759(5) 0.4166(5) 0.031(2) Uani 1 1 d . . . . .
O6 O -0.1644(8) -0.1442(5) 0.5373(5) 0.031(2) Uani 1 1 d . . . . .
O7 O 0.1342(8) 0.1841(5) 0.4848(5) 0.032(2) Uani 1 1 d . . . . .
O8 O 0.0557(8) 0.1574(5) 0.6009(5) 0.028(2) Uani 1 1 d . . . . .
O9 O 0.6265(10) -0.1606(5) 0.6266(6) 0.039(3) Uani 1 1 d . . . . .
O10 O 0.5615(8) -0.1445(5) 0.7459(5) 0.033(2) Uani 1 1 d . . . . .
O11 O 0.3204(8) 0.1851(5) 0.5935(5) 0.0288(18) Uani 1 1 d . . . . .
O12 O 0.2900(9) 0.1421(5) 0.7133(6) 0.036(2) Uani 1 1 d . . . . .
O13 O -0.2388(8) 0.6442(5) 0.7883(5) 0.0268(18) Uani 1 1 d . . . . .
O14 O -0.1883(7) 0.6779(4) 0.9119(5) 0.0217(16) Uani 1 1 d . . . . .
O15 O 0.0521(9) 0.3510(5) 0.7508(5) 0.029(2) Uani 1 1 d . . . . .
O16 O 0.0745(8) 0.3259(5) 0.8793(5) 0.029(2) Uani 1 1 d . . . . .
O17 O 0.6439(7) 0.6745(5) 1.0311(5) 0.0236(18) Uani 1 1 d . . . . .
O18 O 0.5608(7) 0.6502(4) 0.9099(5) 0.0238(17) Uani 1 1 d . . . . .
O19 O 0.3711(7) 0.3178(4) 1.0654(5) 0.0249(17) Uani 1 1 d . . . . .
O20 O 0.3090(8) 0.3601(5) 0.9472(5) 0.030(2) Uani 1 1 d . . . . .
O21 O -0.1157(8) 0.6379(5) 1.1032(5) 0.0270(19) Uani 1 1 d . . . . .
O22 O -0.0470(8) 0.6762(5) 1.2236(5) 0.0253(19) Uani 1 1 d . . . . .
O23 O 0.1197(8) 0.3426(4) 1.0677(5) 0.0266(18) Uani 1 1 d . . . . .
O24 O 0.2013(7) 0.3150(5) 1.1897(5) 0.0236(18) Uani 1 1 d . . . . .
O25 O 0.2766(5) 0.2492(6) 0.8300(3) 0.0199(13) Uani 1 1 d . . . . .
O26 O -0.0319(7) 0.2272(5) 0.9905(6) 0.040(2) Uani 1 1 d D U . . .
O27 O 0.5176(7) 0.2378(8) 0.4880(5) 0.047(2) Uani 1 1 d D U . . .
O28 O 0.5915(8) 0.2560(10) 1.1730(6) 0.057(3) Uani 1 1 d D U . . .
O29 O 0.1708(7) 0.2454(8) 0.3386(4) 0.0325(16) Uani 1 1 d D . . . .
H29A H 0.158(13) 0.202(4) 0.319(7) 0.039 Uiso 1 1 d D U . . .
H29B H 0.178(13) 0.279(5) 0.303(6) 0.039 Uiso 1 1 d D U . . .
S1 S 0.4943(4) -0.01089(19) 0.3920(2) 0.0408(9) Uani 1 1 d . . . . .
S2 S -0.0428(3) 0.00510(18) 0.54777(18) 0.0318(7) Uani 1 1 d . . . . .
S3 S 0.4331(3) 0.00234(19) 0.7072(2) 0.0388(9) Uani 1 1 d . . . . .
S4 S -0.1011(3) 0.49765(17) 0.78948(18) 0.0299(7) Uani 1 1 d . . . . .
S5 S 0.4432(3) 0.50615(16) 0.95282(17) 0.0246(6) Uani 1 1 d . . . . .
S6 S 0.0041(3) 0.48578(17) 1.11203(18) 0.0295(7) Uani 1 1 d . . . . .
Eu1 Eu 0.30455(4) 0.25448(3) 0.46661(3) 0.01497(10) Uani 1 1 d . . . . .
Eu2 Eu 0.15232(4) 0.24679(4) 0.68949(2) 0.01308(9) Uani 1 1 d . . . . .
Eu3 Eu 0.17831(3) 0.24910(4) 0.96952(2) 0.01364(9) Uani 1 1 d . . . . .
Eu4 Eu 0.37964(4) 0.24515(3) 1.17997(2) 0.01496(10) Uani 1 1 d D . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 127.4(12) . .
O2 C1 C2 118.1(11) . .
O1 C1 C2 114.5(13) . .
C3 C2 C1 128.0(12) . .
C3 C2 S1 111.0(10) . .
C1 C2 S1 120.8(10) . .
C2 C3 C4 112.0(13) . .
C2 C3 H3 124.0 . .
C4 C3 H3 124.0 . .
C5 C4 C3 113.3(13) . .
C5 C4 H4 123.3 . .
C3 C4 H4 123.3 . .
C4 C5 C6 128.4(12) . .
C4 C5 S1 111.3(10) . .
C6 C5 S1 120.1(10) . .
O4 C6 O3 125.7(12) . .
O4 C6 C5 120.5(12) . .
O3 C6 C5 113.7(12) . .
O6 C7 O5 125.3(12) . .
O6 C7 C8 118.3(12) . .
O5 C7 C8 116.4(11) . .
O6 C7 Eu1 42.0(6) . 2_546
O5 C7 Eu1 84.7(7) . 2_546
C8 C7 Eu1 156.9(9) . 2_546
C9 C8 C7 128.1(11) . .
C9 C8 S2 111.1(9) . .
C7 C8 S2 120.8(9) . .
C8 C9 C10 113.4(12) . .
C8 C9 H9 123.3 . .
C10 C9 H9 123.3 . .
C11 C10 C9 111.6(12) . .
C11 C10 H10 124.2 . .
C9 C10 H10 124.2 . .
C10 C11 C12 126.2(11) . .
C10 C11 S2 112.1(9) . .
C12 C11 S2 121.7(9) . .
O8 C12 O7 125.5(11) . .
O8 C12 C11 119.6(11) . .
O7 C12 C11 114.9(11) . .
O9 C13 O10 126.1(12) . .
O9 C13 C14 116.1(12) . .
O10 C13 C14 117.8(11) . .
C15 C14 C13 126.7(12) . .
C15 C14 S3 111.7(10) . .
C13 C14 S3 121.6(10) . .
C14 C15 C16 113.0(13) . .
C14 C15 H15 123.5 . .
C16 C15 H15 123.5 . .
C17 C16 C15 112.2(13) . .
C17 C16 H16 123.9 . .
C15 C16 H16 123.9 . .
C16 C17 C18 128.7(12) . .
C16 C17 S3 111.8(10) . .
C18 C17 S3 119.4(10) . .
O12 C18 O11 123.1(12) . .
O12 C18 C17 117.9(11) . .
O11 C18 C17 119.0(12) . .
O12 C18 Eu2 53.4(6) . .
O11 C18 Eu2 69.9(7) . .
C17 C18 Eu2 169.4(10) . .
O13 C19 O14 122.6(11) . .
O13 C19 C20 118.9(11) . .
O14 C19 C20 118.5(11) . .
O13 C19 Eu4 53.1(6) . 2_557
O14 C19 Eu4 70.2(6) . 2_557
C20 C19 Eu4 167.9(8) . 2_557
C21 C20 C19 127.5(11) . .
C21 C20 S4 111.5(9) . .
C19 C20 S4 121.0(9) . .
C20 C21 C22 112.1(11) . .
C20 C21 H21 123.9 . .
C22 C21 H21 123.9 . .
C23 C22 C21 114.7(12) . .
C23 C22 H22 122.7 . .
C21 C22 H22 122.7 . .
C22 C23 C24 124.8(12) . .
C22 C23 S4 110.6(10) . .
C24 C23 S4 124.6(11) . .
O16 C24 O15 126.4(12) . .
O16 C24 C23 114.2(12) . .
O15 C24 C23 119.4(12) . .
O18 C25 O17 125.8(10) . .
O18 C25 C26 117.7(10) . .
O17 C25 C26 116.6(11) . .
C27 C26 C25 127.9(11) . .
C27 C26 S5 111.7(9) . .
C25 C26 S5 120.5(9) . .
C26 C27 C28 113.3(11) . .
C26 C27 H27 123.3 . .
C28 C27 H27 123.3 . .
C29 C28 C27 111.1(11) . .
C29 C28 H28 124.5 . .
C27 C28 H28 124.5 . .
C28 C29 C30 126.8(11) . .
C28 C29 S5 112.8(9) . .
C30 C29 S5 120.3(9) . .
O20 C30 O19 123.1(11) . .
O20 C30 C29 118.5(10) . .
O19 C30 C29 118.4(11) . .
O20 C30 Eu3 52.6(6) . .
O19 C30 Eu3 71.3(6) . .
C29 C30 Eu3 167.0(8) . .
O22 C31 O21 124.3(12) . .
O22 C31 C32 117.7(13) . .
O21 C31 C32 118.0(12) . .
C33 C32 C31 125.7(12) . .
C33 C32 S6 111.7(9) . .
C31 C32 S6 122.4(11) . .
C32 C33 C34 112.7(11) . .
C32 C33 H33 123.6 . .
C34 C33 H33 123.6 . .
C35 C34 C33 111.8(11) . .
C35 C34 H34 124.1 . .
C33 C34 H34 124.1 . .
C34 C35 C36 128.2(11) . .
C34 C35 S6 112.1(9) . .
C36 C35 S6 119.6(9) . .
O23 C36 O24 125.8(10) . .
O23 C36 C35 118.4(10) . .
O24 C36 C35 115.7(11) . .
O26 C37 N1 124.6(14) . .
O26 C37 H37 117.7 . .
N1 C37 H37 117.7 . .
N1 C38 C39 113(2) . .
N1 C38 H38A 109.0 . .
C39 C38 H38A 109.0 . .
N1 C38 H38B 109.0 . .
C39 C38 H38B 109.0 . .
H38A C38 H38B 107.8 . .
C38 C39 H39A 109.5 . .
C38 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C38 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
N1 C40 C41 115(2) . .
N1 C40 H40A 108.5 . .
C41 C40 H40A 108.5 . .
N1 C40 H40B 108.5 . .
C41 C40 H40B 108.5 . .
H40A C40 H40B 107.5 . .
C40 C41 H41A 109.5 . .
C40 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C40 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
O27 C42 N2 126(2) . .
O27 C42 H42 116.9 . .
N2 C42 H42 116.9 . .
N2 C43 C44 142(4) . .
N2 C43 H43A 101.4 . .
C44 C43 H43A 101.4 . .
N2 C43 H43B 101.4 . .
C44 C43 H43B 101.4 . .
H43A C43 H43B 104.6 . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
N2 C45 C46 101(3) . .
N2 C45 H45A 111.7 . .
C46 C45 H45A 111.7 . .
N2 C45 H45B 111.7 . .
C46 C45 H45B 111.7 . .
H45A C45 H45B 109.4 . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
O28 C47 N3 123(3) . .
O28 C47 H47 118.3 . .
N3 C47 H47 118.3 . .
O28 C47' N3 127(3) . .
O28 C47' H47' 116.3 . .
N3 C47' H47' 116.3 . .
N3 C48 C49 113(3) . .
N3 C48 H48A 108.9 . .
C49 C48 H48A 108.9 . .
N3 C48 H48B 108.9 . .
C49 C48 H48B 108.9 . .
H48A C48 H48B 107.7 . .
C48 C49 H49A 109.5 . .
C48 C49 H49B 109.5 . .
H49A C49 H49B 109.5 . .
C48 C49 H49C 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
N3 C50 C51 110(3) . .
N3 C50 H50A 109.8 . .
C51 C50 H50A 109.8 . .
N3 C50 H50B 109.8 . .
C51 C50 H50B 109.8 . .
H50A C50 H50B 108.2 . .
C50 C51 H51A 109.5 . .
C50 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C50 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
C37 N1 C38 121.2(17) . .
C37 N1 C40 120.9(15) . .
C38 N1 C40 117.7(15) . .
C42 N2 C45 120(3) . .
C42 N2 C43 114(3) . .
C45 N2 C43 126(3) . .
C47 N3 C48 125(3) . .
C47' N3 C48 122(3) . .
C47 N3 C50 120(3) . .
C47' N3 C50 116(2) . .
C48 N3 C50 115(2) . .
C1 O1 Eu2 133.8(9) . 2_646
C1 O2 Eu1 143.1(8) . 2_646
C6 O3 Eu4 142.4(8) . 1_554
C6 O4 Eu1 126.7(9) . .
C7 O5 Eu2 164.3(9) . 2_546
C7 O6 Eu1 117.5(8) . 2_546
C12 O7 Eu1 147.4(8) . .
C12 O8 Eu2 129.0(7) . .
C13 O9 Eu1 169.7(10) . 2_646
C13 O10 Eu4 133.0(8) . 2_647
C18 O11 Eu1 166.8(9) . .
C18 O11 Eu2 85.0(8) . .
Eu1 O11 Eu2 107.3(3) . .
C18 O12 Eu2 102.2(8) . .
C19 O13 Eu4 102.9(7) . 2_557
C19 O14 Eu3 171.2(8) . 2_557
C19 O14 Eu4 85.0(7) . 2_557
Eu3 O14 Eu4 103.8(3) 2_557 2_557
C24 O15 Eu2 129.7(8) . .
C24 O16 Eu3 163.9(9) . .
C25 O17 Eu3 135.8(7) . 2_657
C25 O18 Eu4 136.1(7) . 2_657
C30 O19 Eu4 169.8(8) . .
C30 O19 Eu3 84.4(7) . .
Eu4 O19 Eu3 103.2(3) . .
C30 O20 Eu3 103.9(7) . .
C31 O21 Eu3 133.4(8) . 2_557
C31 O22 Eu2 143.2(9) . 2_557
C36 O23 Eu3 138.6(7) . .
C36 O24 Eu4 132.3(7) . .
Eu3 O25 Eu2 124.0(2) . .
C37 O26 Eu3 126.6(8) . .
C42 O27 Eu1 131.9(12) . .
C47' O28 Eu4 147(2) . .
C47 O28 Eu4 130(3) . .
Eu1 O29 H29A 118(10) . .
Eu1 O29 H29B 118(10) . .
H29A O29 H29B 112(5) . .
C5 S1 C2 92.2(6) . .
C11 S2 C8 91.7(5) . .
C17 S3 C14 91.2(6) . .
C20 S4 C23 91.1(6) . .
C29 S5 C26 91.0(5) . .
C32 S6 C35 91.6(6) . .
O7 Eu1 O9 137.9(4) . 2_656
O7 Eu1 O6 81.4(3) . 2_556
O9 Eu1 O6 75.5(3) 2_656 2_556
O7 Eu1 O27 137.3(4) . .
O9 Eu1 O27 79.1(4) 2_656 .
O6 Eu1 O27 138.1(4) 2_556 .
O7 Eu1 O4 81.8(3) . .
O9 Eu1 O4 97.3(4) 2_656 .
O6 Eu1 O4 144.7(3) 2_556 .
O27 Eu1 O4 70.9(4) . .
O7 Eu1 O2 119.4(3) . 2_656
O9 Eu1 O2 87.0(3) 2_656 2_656
O6 Eu1 O2 73.3(3) 2_556 2_656
O27 Eu1 O2 72.7(3) . 2_656
O4 Eu1 O2 141.7(3) . 2_656
O7 Eu1 O11 68.7(3) . .
O9 Eu1 O11 153.3(4) 2_656 .
O6 Eu1 O11 114.1(3) 2_556 .
O27 Eu1 O11 78.0(3) . .
O4 Eu1 O11 88.0(3) . .
O2 Eu1 O11 73.2(3) 2_656 .
O7 Eu1 O29 68.2(3) . .
O9 Eu1 O29 71.0(4) 2_656 .
O6 Eu1 O29 70.6(3) 2_556 .
O27 Eu1 O29 130.2(3) . .
O4 Eu1 O29 74.4(4) . .
O2 Eu1 O29 141.3(4) 2_656 .
O11 Eu1 O29 135.2(3) . .
O7 Eu1 C7 73.4(3) . 2_556
O9 Eu1 C7 93.5(4) 2_656 2_556
O6 Eu1 C7 20.5(3) 2_556 2_556
O27 Eu1 C7 136.2(4) . 2_556
O4 Eu1 C7 152.6(4) . 2_556
O2 Eu1 C7 63.8(3) 2_656 2_556
O11 Eu1 C7 93.6(3) . 2_556
O29 Eu1 C7 85.6(3) . 2_556
O7 Eu1 Eu2 58.8(2) . .
O9 Eu1 Eu2 142.1(2) 2_656 .
O6 Eu1 Eu2 75.2(2) 2_556 .
O27 Eu1 Eu2 108.4(2) . .
O4 Eu1 Eu2 120.5(2) . .
O2 Eu1 Eu2 61.73(19) 2_656 .
O11 Eu1 Eu2 39.0(2) . .
O29 Eu1 Eu2 119.86(16) . .
C7 Eu1 Eu2 54.8(2) 2_556 .
O5 Eu2 O22 136.3(3) 2_556 2_547
O5 Eu2 O1 78.8(3) 2_556 2_656
O22 Eu2 O1 138.6(3) 2_547 2_656
O5 Eu2 O8 80.2(3) 2_556 .
O22 Eu2 O8 79.1(3) 2_547 .
O1 Eu2 O8 137.9(3) 2_656 .
O5 Eu2 O15 78.3(3) 2_556 .
O22 Eu2 O15 82.2(3) 2_547 .
O1 Eu2 O15 86.5(3) 2_656 .
O8 Eu2 O15 124.0(3) . .
O5 Eu2 O12 133.8(3) 2_556 .
O22 Eu2 O12 80.5(3) 2_547 .
O1 Eu2 O12 86.4(4) 2_656 .
O8 Eu2 O12 82.4(3) . .
O15 Eu2 O12 144.6(3) . .
O5 Eu2 O25 139.9(3) 2_556 .
O22 Eu2 O25 73.0(3) 2_547 .
O1 Eu2 O25 65.9(3) 2_656 .
O8 Eu2 O25 139.3(3) . .
O15 Eu2 O25 80.9(3) . .
O12 Eu2 O25 64.6(3) . .
O5 Eu2 O11 84.4(3) 2_556 .
O22 Eu2 O11 123.7(3) 2_547 .
O1 Eu2 O11 70.6(3) 2_656 .
O8 Eu2 O11 71.3(3) . .
O15 Eu2 O11 153.6(3) . .
O12 Eu2 O11 49.5(3) . .
O25 Eu2 O11 100.6(2) . .
O5 Eu2 C18 109.3(4) 2_556 .
O22 Eu2 C18 101.5(3) 2_547 .
O1 Eu2 C18 78.7(4) 2_656 .
O8 Eu2 C18 74.5(3) . .
O15 Eu2 C18 161.4(4) . .
O12 Eu2 C18 24.4(3) . .
O25 Eu2 C18 82.8(3) . .
O11 Eu2 C18 25.1(3) . .
O5 Eu2 Eu1 50.6(2) 2_556 .
O22 Eu2 Eu1 146.7(2) 2_547 .
O1 Eu2 Eu1 68.4(2) 2_656 .
O8 Eu2 Eu1 70.0(2) . .
O15 Eu2 Eu1 125.5(2) . .
O12 Eu2 Eu1 83.2(2) . .
O25 Eu2 Eu1 124.59(12) . .
O11 Eu2 Eu1 33.76(16) . .
C18 Eu2 Eu1 58.8(3) . .
O16 Eu3 O14 150.4(3) . 2_547
O16 Eu3 O21 91.1(3) . 2_547
O14 Eu3 O21 89.9(3) 2_547 2_547
O16 Eu3 O17 135.3(3) . 2_647
O14 Eu3 O17 73.5(3) 2_547 2_647
O21 Eu3 O17 76.7(3) 2_547 2_647
O16 Eu3 O26 74.3(3) . .
O14 Eu3 O26 77.9(3) 2_547 .
O21 Eu3 O26 71.8(3) 2_547 .
O17 Eu3 O26 137.0(3) 2_647 .
O16 Eu3 O23 84.6(3) . .
O14 Eu3 O23 77.5(3) 2_547 .
O21 Eu3 O23 144.2(3) 2_547 .
O17 Eu3 O23 129.0(3) 2_647 .
O26 Eu3 O23 72.8(3) . .
O16 Eu3 O20 73.8(3) . .
O14 Eu3 O20 123.2(3) 2_547 .
O21 Eu3 O20 136.3(3) 2_547 .
O17 Eu3 O20 85.8(3) 2_647 .
O26 Eu3 O20 137.1(3) . .
O23 Eu3 O20 76.3(3) . .
O16 Eu3 O25 68.7(3) . .
O14 Eu3 O25 138.6(3) 2_547 .
O21 Eu3 O25 70.9(3) 2_547 .
O17 Eu3 O25 66.6(3) 2_647 .
O26 Eu3 O25 125.9(3) . .
O23 Eu3 O25 137.8(3) . .
O20 Eu3 O25 65.4(3) . .
O16 Eu3 O19 117.3(3) . .
O14 Eu3 O19 75.6(2) 2_547 .
O21 Eu3 O19 144.7(3) 2_547 .
O17 Eu3 O19 68.4(3) 2_647 .
O26 Eu3 O19 133.3(3) . .
O23 Eu3 O19 64.3(3) . .
O20 Eu3 O19 47.6(3) . .
O25 Eu3 O19 98.9(2) . .
O16 Eu3 C30 94.4(3) . .
O14 Eu3 C30 99.7(3) 2_547 .
O21 Eu3 C30 149.3(3) 2_547 .
O17 Eu3 C30 78.2(3) 2_647 .
O26 Eu3 C30 138.6(3) . .
O23 Eu3 C30 66.5(3) . .
O20 Eu3 C30 23.5(3) . .
O25 Eu3 C30 83.0(3) . .
O19 Eu3 C30 24.3(3) . .
O16 Eu3 Eu4 144.7(2) . .
O14 Eu3 Eu4 42.25(19) 2_547 .
O21 Eu3 Eu4 124.1(2) 2_547 .
O17 Eu3 Eu4 64.8(2) 2_647 .
O26 Eu3 Eu4 111.3(2) . .
O23 Eu3 Eu4 65.41(19) . .
O20 Eu3 Eu4 81.0(2) . .
O25 Eu3 Eu4 121.87(12) . .
O19 Eu3 Eu4 33.36(15) . .
C30 Eu3 Eu4 57.6(2) . .
O3 Eu4 O19 163.0(3) 1_556 .
O3 Eu4 O24 113.3(3) 1_556 .
O19 Eu4 O24 77.3(3) . .
O3 Eu4 O18 98.6(3) 1_556 2_647
O19 Eu4 O18 81.6(3) . 2_647
O24 Eu4 O18 133.0(3) . 2_647
O3 Eu4 O10 81.1(3) 1_556 2_657
O19 Eu4 O10 89.1(3) . 2_657
O24 Eu4 O10 75.6(3) . 2_657
O18 Eu4 O10 145.7(3) 2_647 2_657
O3 Eu4 O28 79.2(4) 1_556 .
O19 Eu4 O28 84.7(4) . .
O24 Eu4 O28 144.2(5) . .
O18 Eu4 O28 72.8(4) 2_647 .
O10 Eu4 O28 73.5(4) 2_657 .
O3 Eu4 O13 70.7(3) 1_556 2_547
O19 Eu4 O13 125.8(3) . 2_547
O24 Eu4 O13 78.4(3) . 2_547
O18 Eu4 O13 80.9(3) 2_647 2_547
O10 Eu4 O13 129.5(3) 2_657 2_547
O28 Eu4 O13 136.2(4) . 2_547
O3 Eu4 O14 118.4(3) 1_556 2_547
O19 Eu4 O14 77.4(2) . 2_547
O24 Eu4 O14 68.6(3) . 2_547
O18 Eu4 O14 66.0(2) 2_647 2_547
O10 Eu4 O14 143.6(3) 2_657 2_547
O28 Eu4 O14 136.9(3) . 2_547
O13 Eu4 O14 48.7(2) 2_547 2_547
O3 Eu4 C19 93.8(3) 1_556 2_547
O19 Eu4 C19 102.2(3) . 2_547
O24 Eu4 C19 74.1(3) . 2_547
O18 Eu4 C19 70.0(3) 2_647 2_547
O10 Eu4 C19 144.2(3) 2_657 2_547
O28 Eu4 C19 140.7(4) . 2_547
O13 Eu4 C19 24.0(3) 2_547 2_547
O14 Eu4 C19 24.8(3) 2_547 2_547
O3 Eu4 Eu3 151.9(2) 1_556 .
O19 Eu4 Eu3 43.4(2) . .
O24 Eu4 Eu3 67.91(19) . .
O18 Eu4 Eu3 67.83(19) 2_647 .
O10 Eu4 Eu3 124.3(2) 2_657 .
O28 Eu4 Eu3 117.1(2) . .
O13 Eu4 Eu3 82.55(19) 2_547 .
O14 Eu4 Eu3 33.96(14) 2_547 .
C19 Eu4 Eu3 58.8(2) 2_547 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.247(17) .
C1 O1 1.255(16) .
C1 C2 1.473(18) .
C2 C3 1.363(18) .
C2 S1 1.718(12) .
C3 C4 1.421(18) .
C3 H3 0.9300 .
C4 C5 1.349(19) .
C4 H4 0.9300 .
C5 C6 1.490(17) .
C5 S1 1.705(12) .
C6 O4 1.224(17) .
C6 O3 1.278(16) .
C7 O6 1.244(15) .
C7 O5 1.278(16) .
C7 C8 1.465(17) .
C7 Eu1 3.150(13) 2_546
C8 C9 1.343(18) .
C8 S2 1.717(11) .
C9 C10 1.417(18) .
C9 H9 0.9300 .
C10 C11 1.357(17) .
C10 H10 0.9300 .
C11 C12 1.481(16) .
C11 S2 1.699(12) .
C12 O8 1.250(15) .
C12 O7 1.275(15) .
C13 O9 1.232(15) .
C13 O10 1.235(15) .
C13 C14 1.496(17) .
C14 C15 1.342(18) .
C14 S3 1.717(13) .
C15 C16 1.414(18) .
C15 H15 0.9300 .
C16 C17 1.355(19) .
C16 H16 0.9300 .
C17 C18 1.489(17) .
C17 S3 1.710(13) .
C18 O12 1.249(16) .
C18 O11 1.255(15) .
C18 Eu2 2.951(13) .
C19 O13 1.253(14) .
C19 O14 1.264(14) .
C19 C20 1.478(16) .
C19 Eu4 2.999(12) 2_557
C20 C21 1.371(17) .
C20 S4 1.726(12) .
C21 C22 1.382(17) .
C21 H21 0.9300 .
C22 C23 1.357(18) .
C22 H22 0.9300 .
C23 C24 1.509(17) .
C23 S4 1.728(13) .
C24 O16 1.218(16) .
C24 O15 1.257(16) .
C25 O18 1.254(14) .
C25 O17 1.258(14) .
C25 C26 1.484(15) .
C26 C27 1.348(17) .
C26 S5 1.713(11) .
C27 C28 1.421(17) .
C27 H27 0.9300 .
C28 C29 1.353(17) .
C28 H28 0.9300 .
C29 C30 1.492(16) .
C29 S5 1.711(11) .
C30 O20 1.245(15) .
C30 O19 1.257(14) .
C30 Eu3 3.036(12) .
C31 O22 1.249(16) .
C31 O21 1.273(17) .
C31 C32 1.469(18) .
C32 C33 1.378(17) .
C32 S6 1.697(13) .
C33 C34 1.396(17) .
C33 H33 0.9300 .
C34 C35 1.375(17) .
C34 H34 0.9300 .
C35 C36 1.485(16) .
C35 S6 1.705(12) .
C36 O23 1.246(14) .
C36 O24 1.286(14) .
C37 O26 1.204(13) .
C37 N1 1.332(15) .
C37 H37 0.9300 .
C38 N1 1.463(19) .
C38 C39 1.50(2) .
C38 H38A 0.9700 .
C38 H38B 0.9700 .
C39 H39A 0.9600 .
C39 H39B 0.9600 .
C39 H39C 0.9600 .
C40 N1 1.48(2) .
C40 C41 1.48(2) .
C40 H40A 0.9700 .
C40 H40B 0.9700 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 O27 1.189(17) .
C42 N2 1.35(2) .
C42 H42 0.9300 .
C43 N2 1.47(2) .
C43 C44 1.50(3) .
C43 H43A 0.9700 .
C43 H43B 0.9700 .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C45 N2 1.45(2) .
C45 C46 1.54(2) .
C45 H45A 0.9700 .
C45 H45B 0.9700 .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 O28 1.23(3) .
C47 N3 1.33(2) .
C47 H47 0.9300 .
C47' O28 1.110(19) .
C47' N3 1.40(2) .
C47' H47' 0.9300 .
C48 N3 1.45(2) .
C48 C49 1.53(3) .
C48 H48A 0.9700 .
C48 H48B 0.9700 .
C49 H49A 0.9600 .
C49 H49B 0.9600 .
C49 H49C 0.9600 .
C50 N3 1.48(2) .
C50 C51 1.50(3) .
C50 H50A 0.9700 .
C50 H50B 0.9700 .
C51 H51A 0.9600 .
C51 H51B 0.9600 .
C51 H51C 0.9600 .
O1 Eu2 2.327(8) 2_646
O2 Eu1 2.454(8) 2_646
O3 Eu4 2.286(8) 1_554
O4 Eu1 2.424(9) .
O5 Eu2 2.277(8) 2_546
O6 Eu1 2.376(8) 2_546
O7 Eu1 2.318(8) .
O8 Eu2 2.382(8) .
O9 Eu1 2.332(9) 2_646
O10 Eu4 2.378(8) 2_647
O11 Eu1 2.458(8) .
O11 Eu2 2.782(9) .
O12 Eu2 2.422(9) .
O13 Eu4 2.459(8) 2_557
O14 Eu3 2.353(7) 2_557
O14 Eu4 2.833(8) 2_557
O15 Eu2 2.414(8) .
O16 Eu3 2.298(8) .
O17 Eu3 2.392(7) 2_657
O18 Eu4 2.376(7) 2_657
O19 Eu4 2.311(8) .
O19 Eu3 2.890(8) .
O20 Eu3 2.485(8) .
O21 Eu3 2.390(8) 2_557
O22 Eu2 2.302(8) 2_557
O23 Eu3 2.449(8) .
O24 Eu4 2.367(7) .
O25 Eu3 2.657(5) .
O25 Eu2 2.677(6) .
O26 Eu3 2.444(8) .
O27 Eu1 2.420(8) .
O28 Eu4 2.402(8) .
O29 Eu1 2.560(7) .
O29 H29A 0.85(3) .
O29 H29B 0.85(3) .
Eu1 O9 2.332(9) 2_656
Eu1 O6 2.376(8) 2_556
Eu1 O2 2.454(8) 2_656
Eu1 C7 3.150(13) 2_556
Eu1 Eu2 4.2233(6) .
Eu2 O5 2.277(8) 2_556
Eu2 O22 2.302(8) 2_547
Eu2 O1 2.327(8) 2_656
Eu3 O14 2.353(7) 2_547
Eu3 O21 2.390(8) 2_547
Eu3 O17 2.392(7) 2_647
Eu3 Eu4 4.0915(6) .
Eu4 O3 2.286(8) 1_556
Eu4 O18 2.376(7) 2_647
Eu4 O10 2.378(8) 2_657
Eu4 O13 2.459(8) 2_547
Eu4 O14 2.833(8) 2_547
Eu4 C19 2.999(12) 2_547
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C4 H4 O18 0.93 2.59 3.473(16) 159.1 2_646
C4 H4 S5 0.93 3.01 3.581(15) 121.0 2_646
C9 H9 O15 0.93 2.54 3.419(15) 157.7 2_546
C9 H9 S4 0.93 2.93 3.588(14) 128.7 2_546
C28 H28 O10 0.93 2.58 3.412(15) 149.8 2_657
C28 H28 S3 0.93 3.02 3.533(13) 116.5 2_657
C33 H33 S2 0.93 2.88 3.461(12) 121.5 2_557
C44 H44A S2 0.96 2.65 3.51(5) 149.4 1_655
C47 H47 O10 0.93 2.49 3.01(3) 115.2 2_657
O29 H29A O13 0.85(3) 2.30(10) 2.918(13) 130(10) 2_546
O29 H29B O24 0.85(3) 2.05(6) 2.830(12) 153(11) 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 C3 169.8(17) . .
O1 C1 C2 C3 -8(2) . .
O2 C1 C2 S1 -5(2) . .
O1 C1 C2 S1 177.2(11) . .
C1 C2 C3 C4 -173.3(16) . .
S1 C2 C3 C4 2(2) . .
C2 C3 C4 C5 -1(2) . .
C3 C4 C5 C6 175.1(16) . .
C3 C4 C5 S1 -1(2) . .
C4 C5 C6 O4 168.4(17) . .
S1 C5 C6 O4 -16(2) . .
C4 C5 C6 O3 -15(2) . .
S1 C5 C6 O3 160.3(10) . .
O6 C7 C8 C9 -176.8(17) . .
O5 C7 C8 C9 5(2) . .
Eu1 C7 C8 C9 -150(2) 2_546 .
O6 C7 C8 S2 2.9(19) . .
O5 C7 C8 S2 -175.4(10) . .
Eu1 C7 C8 S2 30(3) 2_546 .
C7 C8 C9 C10 -179.3(16) . .
S2 C8 C9 C10 1(2) . .
C8 C9 C10 C11 -2(3) . .
C9 C10 C11 C12 -179.3(15) . .
C9 C10 C11 S2 2(2) . .
C10 C11 C12 O8 -176.9(16) . .
S2 C11 C12 O8 2.2(18) . .
C10 C11 C12 O7 2(2) . .
S2 C11 C12 O7 -178.8(10) . .
O9 C13 C14 C15 -11(2) . .
O10 C13 C14 C15 167.3(16) . .
O9 C13 C14 S3 167.1(11) . .
O10 C13 C14 S3 -14.3(19) . .
C13 C14 C15 C16 175.0(16) . .
S3 C14 C15 C16 -3(2) . .
C14 C15 C16 C17 3(3) . .
C15 C16 C17 C18 -179.1(16) . .
C15 C16 C17 S3 -1(2) . .
C16 C17 C18 O12 -175.1(17) . .
S3 C17 C18 O12 6.6(19) . .
C16 C17 C18 O11 6(3) . .
S3 C17 C18 O11 -172.3(11) . .
C16 C17 C18 Eu2 153(5) . .
S3 C17 C18 Eu2 -26(6) . .
O13 C19 C20 C21 173.4(13) . .
O14 C19 C20 C21 -7(2) . .
Eu4 C19 C20 C21 -141(4) 2_557 .
O13 C19 C20 S4 -8.3(16) . .
O14 C19 C20 S4 171.5(9) . .
Eu4 C19 C20 S4 38(5) 2_557 .
C19 C20 C21 C22 177.1(13) . .
S4 C20 C21 C22 -1.2(16) . .
C20 C21 C22 C23 -0.1(19) . .
C21 C22 C23 C24 -177.3(14) . .
C21 C22 C23 S4 1.4(17) . .
C22 C23 C24 O16 28(2) . .
S4 C23 C24 O16 -150.4(12) . .
C22 C23 C24 O15 -151.6(15) . .
S4 C23 C24 O15 30(2) . .
O18 C25 C26 C27 171.6(13) . .
O17 C25 C26 C27 -8(2) . .
O18 C25 C26 S5 -9.5(16) . .
O17 C25 C26 S5 171.2(9) . .
C25 C26 C27 C28 -178.5(13) . .
S5 C26 C27 C28 2.5(16) . .
C26 C27 C28 C29 -2.6(18) . .
C27 C28 C29 C30 -179.8(12) . .
C27 C28 C29 S5 1.5(16) . .
C28 C29 C30 O20 -179.5(13) . .
S5 C29 C30 O20 -0.8(17) . .
C28 C29 C30 O19 1(2) . .
S5 C29 C30 O19 179.2(9) . .
C28 C29 C30 Eu3 137(3) . .
S5 C29 C30 Eu3 -45(4) . .
O22 C31 C32 C33 -1(2) . .
O21 C31 C32 C33 178.5(14) . .
O22 C31 C32 S6 -174.3(11) . .
O21 C31 C32 S6 5(2) . .
C31 C32 C33 C34 -174.7(14) . .
S6 C32 C33 C34 -0.6(17) . .
C32 C33 C34 C35 0.3(19) . .
C33 C34 C35 C36 175.7(13) . .
C33 C34 C35 S6 0.0(17) . .
C34 C35 C36 O23 -168.2(13) . .
S6 C35 C36 O23 7.2(16) . .
C34 C35 C36 O24 9(2) . .
S6 C35 C36 O24 -175.4(9) . .
O26 C37 N1 C38 179.7(16) . .
O26 C37 N1 C40 5(3) . .
C39 C38 N1 C37 98(3) . .
C39 C38 N1 C40 -88(3) . .
C41 C40 N1 C37 -88(2) . .
C41 C40 N1 C38 97(2) . .
O27 C42 N2 C45 -162(3) . .
O27 C42 N2 C43 23(4) . .
C46 C45 N2 C42 107(3) . .
C46 C45 N2 C43 -78(4) . .
C44 C43 N2 C42 53(7) . .
C44 C43 N2 C45 -122(6) . .
O28 C47 N3 C48 -40(11) . .
O28 C47 N3 C50 141(6) . .
O28 C47' N3 C48 37(7) . .
O28 C47' N3 C50 -174(4) . .
C49 C48 N3 C47 -72(6) . .
C49 C48 N3 C47' -104(4) . .
C49 C48 N3 C50 107(3) . .
C51 C50 N3 C47 57(6) . .
C51 C50 N3 C47' 87(4) . .
C51 C50 N3 C48 -122(4) . .
O2 C1 O1 Eu2 -30(2) . 2_646
C2 C1 O1 Eu2 147.3(10) . 2_646
O1 C1 O2 Eu1 2(3) . 2_646
C2 C1 O2 Eu1 -174.5(10) . 2_646
O4 C6 O3 Eu4 -95.6(17) . 1_554
C5 C6 O3 Eu4 88.4(17) . 1_554
O3 C6 O4 Eu1 -12(2) . .
C5 C6 O4 Eu1 163.4(10) . .
O6 C7 O5 Eu2 61(4) . 2_546
C8 C7 O5 Eu2 -121(3) . 2_546
Eu1 C7 O5 Eu2 50(3) 2_546 2_546
O5 C7 O6 Eu1 -17.3(19) . 2_546
C8 C7 O6 Eu1 164.6(9) . 2_546
O8 C12 O7 Eu1 52(2) . .
C11 C12 O7 Eu1 -127.3(13) . .
O7 C12 O8 Eu2 -19.9(19) . .
C11 C12 O8 Eu2 158.9(9) . .
O10 C13 O9 Eu1 63(6) . 2_646
C14 C13 O9 Eu1 -118(5) . 2_646
O9 C13 O10 Eu4 1(2) . 2_647
C14 C13 O10 Eu4 -177.0(9) . 2_647
O12 C18 O11 Eu1 -163(3) . .
C17 C18 O11 Eu1 15(5) . .
Eu2 C18 O11 Eu1 -158(4) . .
O12 C18 O11 Eu2 -5.0(14) . .
C17 C18 O11 Eu2 173.8(12) . .
O11 C18 O12 Eu2 5.8(16) . .
C17 C18 O12 Eu2 -173.0(11) . .
O14 C19 O13 Eu4 -10.7(13) . 2_557
C20 C19 O13 Eu4 169.1(9) . 2_557
O13 C19 O14 Eu4 9.1(11) . 2_557
C20 C19 O14 Eu4 -170.7(10) . 2_557
O16 C24 O15 Eu2 -13(2) . .
C23 C24 O15 Eu2 166.5(10) . .
O15 C24 O16 Eu3 59(4) . .
C23 C24 O16 Eu3 -121(3) . .
O18 C25 O17 Eu3 -42.5(19) . 2_657
C26 C25 O17 Eu3 136.7(10) . 2_657
O17 C25 O18 Eu4 9.6(19) . 2_657
C26 C25 O18 Eu4 -169.7(8) . 2_657
O20 C30 O19 Eu4 -148(4) . .
C29 C30 O19 Eu4 32(5) . .
Eu3 C30 O19 Eu4 -139(5) . .
O20 C30 O19 Eu3 -9.5(12) . .
C29 C30 O19 Eu3 170.5(11) . .
O19 C30 O20 Eu3 11.3(14) . .
C29 C30 O20 Eu3 -168.7(9) . .
O22 C31 O21 Eu3 21(2) . 2_557
C32 C31 O21 Eu3 -158.5(9) . 2_557
O21 C31 O22 Eu2 63(2) . 2_557
C32 C31 O22 Eu2 -117.9(14) . 2_557
O24 C36 O23 Eu3 -6(2) . .
C35 C36 O23 Eu3 170.9(8) . .
O23 C36 O24 Eu4 40.1(17) . .
C35 C36 O24 Eu4 -137.0(9) . .
N1 C37 O26 Eu3 161.2(11) . .
N2 C42 O27 Eu1 159.9(18) . .
N3 C47' O28 Eu4 134(3) . .
N3 C47 O28 Eu4 162(5) . .
C4 C5 S1 C2 1.9(14) . .
C6 C5 S1 C2 -174.4(13) . .
C3 C2 S1 C5 -2.4(14) . .
C1 C2 S1 C5 173.6(13) . .
C10 C11 S2 C8 -0.8(14) . .
C12 C11 S2 C8 -180.0(12) . .
C9 C8 S2 C11 -0.2(14) . .
C7 C8 S2 C11 -179.9(12) . .
C16 C17 S3 C14 -1.0(15) . .
C18 C17 S3 C14 177.5(13) . .
C15 C14 S3 C17 2.6(14) . .
C13 C14 S3 C17 -176.0(13) . .
C21 C20 S4 C23 1.7(11) . .
C19 C20 S4 C23 -176.8(11) . .
C22 C23 S4 C20 -1.7(12) . .
C24 C23 S4 C20 176.9(13) . .
C28 C29 S5 C26 -0.1(11) . .
C30 C29 S5 C26 -178.9(11) . .
C27 C26 S5 C29 -1.4(11) . .
C25 C26 S5 C29 179.5(11) . .
C33 C32 S6 C35 0.5(12) . .
C31 C32 S6 C35 174.9(13) . .
C34 C35 S6 C32 -0.3(12) . .
C36 C35 S6 C32 -176.4(11) . .
