#------------------------------------------------------------------------------
#$Date: 2017-04-27 07:40:46 +0300 (Thu, 27 Apr 2017) $
#$Revision: 195801 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/81/7228116.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7228116
loop_
_publ_author_name
'Song, Xue-Qin'
'Liu, Pan-Pan'
'Wang, Cai-yun'
'Liu, Yuan-An'
'Liu, Wei-Sheng'
'Zhang, Mo'
_publ_section_title
;
 Three sandwich-type zinc(ii)--lanthanide(iii) clusters: structures,
 luminescence and magnetic properties
;
_journal_issue                   37
_journal_name_full               'RSC Adv.'
_journal_page_first              22692
_journal_paper_doi               10.1039/C7RA01469D
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C94 H114 Eu4 N10 O42 Zn2'
_chemical_formula_weight         2794.62
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-05-29 deposited with the CCDC.
2017-04-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.355(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.6693(5)
_cell_length_b                   17.1718(5)
_cell_length_c                   20.9256(7)
_cell_measurement_reflns_used    4859
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.6900
_cell_measurement_theta_min      3.6920
_cell_volume                     5851.1(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 16.0733
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_unetI/netI     0.0926
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            21584
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.019
_diffrn_reflns_theta_min         3.438
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.599
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.85574
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_description       block
_exptl_crystal_F_000             2792
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         2.231
_refine_diff_density_min         -1.260
_refine_diff_density_rms         0.202
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     695
_refine_ls_number_reflns         11508
_refine_ls_number_restraints     828
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0916
_refine_ls_R_factor_gt           0.0571
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0646P)²+38.7758P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1419
_refine_ls_wR_factor_ref         0.1711
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8139
_reflns_number_total             11537
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7ra01469d2.cif
_cod_data_source_block           L10ZnEu
_cod_database_code               7228116
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Eu1 Eu -0.00257(2) 0.89289(2) 0.47450(2) 0.01840(13) Uani 1 1 d . .
Eu2 Eu 0.19207(3) 0.99934(2) 0.57925(2) 0.01939(13) Uani 1 1 d . .
Zn1 Zn -0.20881(6) 0.81161(6) 0.49504(5) 0.0231(2) Uani 1 1 d . .
C1 C 0.3097(8) 0.6133(7) 0.6981(7) 0.065(3) Uani 1 1 d . U
H1A H 0.3035 0.6277 0.7412 0.098 Uiso 1 1 calc R U
H1B H 0.3661 0.6003 0.6995 0.098 Uiso 1 1 calc R U
H1C H 0.2756 0.5690 0.6832 0.098 Uiso 1 1 calc R U
C2 C 0.2112(6) 0.7066(5) 0.6503(5) 0.0314(17) Uani 1 1 d . U
C3 C 0.1986(6) 0.7726(5) 0.6105(5) 0.0292(16) Uani 1 1 d . U
H3 H 0.2401 0.7901 0.5906 0.035 Uiso 1 1 calc R U
C4 C 0.1245(5) 0.8122(5) 0.6003(4) 0.0252(16) Uani 1 1 d . U
C5 C 0.0623(5) 0.7862(5) 0.6327(4) 0.0251(15) Uani 1 1 d . U
C6 C 0.0775(6) 0.7199(5) 0.6728(5) 0.0284(16) Uani 1 1 d . U
H6 H 0.0372 0.7026 0.6941 0.034 Uiso 1 1 calc R U
C7 C 0.1507(6) 0.6797(5) 0.6814(5) 0.0315(17) Uani 1 1 d . U
H7 H 0.1595 0.6354 0.7076 0.038 Uiso 1 1 calc R U
C8 C -0.0187(6) 0.8261(5) 0.6224(5) 0.0265(15) Uani 1 1 d . U
C9 C -0.1360(6) 0.8709(5) 0.6642(5) 0.0321(18) Uani 1 1 d . U
H9A H -0.1388 0.9109 0.6311 0.039 Uiso 1 1 calc R U
H9B H -0.1389 0.8964 0.7050 0.039 Uiso 1 1 calc R U
C10 C -0.2105(6) 0.8160(5) 0.6442(5) 0.0320(18) Uani 1 1 d . U
H10A H -0.2155 0.7837 0.6812 0.038 Uiso 1 1 calc R U
H10B H -0.2603 0.8465 0.6316 0.038 Uiso 1 1 calc R U
C11 C -0.1907(6) 0.6937(6) 0.6024(5) 0.0379(17) Uani 1 1 d . U
H11 H -0.1933 0.6794 0.6448 0.046 Uiso 1 1 calc R U
C12 C -0.1762(7) 0.6315(6) 0.5602(6) 0.0418(18) Uani 1 1 d . U
C13 C -0.1737(7) 0.5543(6) 0.5864(6) 0.051(2) Uani 1 1 d . U
H13 H -0.1819 0.5477 0.6286 0.062 Uiso 1 1 calc R U
C14 C -0.1601(8) 0.4909(6) 0.5525(6) 0.054(2) Uani 1 1 d . U
H14 H -0.1625 0.4415 0.5701 0.065 Uiso 1 1 calc R U
C15 C -0.1422(8) 0.4996(6) 0.4908(6) 0.053(2) Uani 1 1 d . U
H15 H -0.1308 0.4562 0.4676 0.063 Uiso 1 1 calc R U
C16 C -0.1418(7) 0.5732(6) 0.4644(6) 0.0438(19) Uani 1 1 d . U
C17 C -0.1606(7) 0.6407(6) 0.4971(6) 0.0427(19) Uani 1 1 d . U
C18 C -0.0917(8) 0.5241(7) 0.3735(6) 0.060(3) Uani 1 1 d . U
H18A H -0.0408 0.5071 0.4006 0.090 Uiso 1 1 calc R U
H18B H -0.0826 0.5405 0.3318 0.090 Uiso 1 1 calc R U
H18C H -0.1304 0.4819 0.3674 0.090 Uiso 1 1 calc R U
C19 C 0.6247(9) 0.8128(9) 0.7696(9) 0.090(4) Uani 1 1 d . U
H19A H 0.6602 0.8529 0.7598 0.135 Uiso 1 1 calc R U
H19B H 0.6516 0.7632 0.7705 0.135 Uiso 1 1 calc R U
H19C H 0.6121 0.8228 0.8116 0.135 Uiso 1 1 calc R U
C20 C 0.5060(6) 0.8789(6) 0.7087(5) 0.0353(18) Uani 1 1 d . U
C21 C 0.5318(6) 0.9460(6) 0.7422(5) 0.0364(17) Uani 1 1 d . U
H21A H 0.5801 0.9468 0.7742 0.044 Uiso 1 1 calc R U
C22 C 0.4846(6) 1.0126(6) 0.7275(5) 0.0324(17) Uani 1 1 d . U
H22 H 0.5031 1.0587 0.7490 0.039 Uiso 1 1 calc R U
C23 C 0.4102(5) 1.0132(5) 0.6815(4) 0.0255(15) Uani 1 1 d . U
C24 C 0.3822(5) 0.9425(5) 0.6477(4) 0.0262(16) Uani 1 1 d . U
C25 C 0.4338(5) 0.8763(6) 0.6630(5) 0.0299(16) Uani 1 1 d . U
H25 H 0.4181 0.8297 0.6412 0.036 Uiso 1 1 calc R U
C26 C 0.3624(5) 1.0847(5) 0.6673(4) 0.0274(15) Uani 1 1 d . U
C27 C 0.3592(6) 1.2269(5) 0.6581(5) 0.0301(18) Uani 1 1 d . U
H27A H 0.3827 1.2633 0.6924 0.036 Uiso 1 1 calc R U
H27B H 0.3017 1.2200 0.6592 0.036 Uiso 1 1 calc R U
C28 C 0.3654(6) 1.2608(6) 0.5928(5) 0.0374(19) Uani 1 1 d . U
H28A H 0.3339 1.3086 0.5852 0.045 Uiso 1 1 calc R U
H28B H 0.4222 1.2729 0.5929 0.045 Uiso 1 1 calc R U
C29 C 0.3869(6) 1.1680(6) 0.5172(5) 0.0331(16) Uani 1 1 d . U
H29 H 0.4398 1.1882 0.5269 0.040 Uiso 1 1 calc R U
C30 C 0.3751(6) 1.0978(6) 0.4767(5) 0.0331(16) Uani 1 1 d . U
C31 C 0.4380(6) 1.0718(6) 0.4471(5) 0.0388(18) Uani 1 1 d . U
H52 H 0.4826 1.1042 0.4468 0.047 Uiso 1 1 calc R U
C32 C 0.4356(6) 0.9999(6) 0.4185(5) 0.0382(18) Uani 1 1 d . U
H85 H 0.4764 0.9845 0.3971 0.046 Uiso 1 1 calc R U
C33 C 0.3722(6) 0.9516(6) 0.4220(5) 0.0392(18) Uani 1 1 d . U
H65 H 0.3713 0.9017 0.4044 0.047 Uiso 1 1 calc R U
C34 C 0.3095(6) 0.9744(6) 0.4509(5) 0.0326(17) Uani 1 1 d . U
C35 C 0.3072(6) 1.0503(6) 0.4749(5) 0.0297(16) Uani 1 1 d . U
C36 C 0.2530(6) 0.8463(5) 0.4530(5) 0.038(2) Uani 1 1 d . U
H36A H 0.2538 0.8329 0.4086 0.057 Uiso 1 1 calc R U
H36B H 0.2081 0.8202 0.4659 0.057 Uiso 1 1 calc R U
H36C H 0.3038 0.8306 0.4812 0.057 Uiso 1 1 calc R U
C37 C 0.0688(6) 0.9019(5) 0.3342(4) 0.0287(17) Uani 1 1 d . U
H37 H 0.1119 0.8873 0.3150 0.034 Uiso 1 1 calc R U
C38 C 0.0128(6) 0.9585(5) 0.2992(4) 0.0280(16) Uani 1 1 d . U
C39 C 0.0259(6) 0.9841(6) 0.2373(5) 0.0324(17) Uani 1 1 d . U
H39 H 0.0717 0.9668 0.2228 0.039 Uiso 1 1 calc R U
C40 C -0.0278(6) 1.0332(6) 0.1995(5) 0.0327(17) Uani 1 1 d . U
H40 H -0.0183 1.0504 0.1596 0.039 Uiso 1 1 calc R U
C41 C -0.0976(6) 1.0580(5) 0.2210(4) 0.0312(17) Uani 1 1 d . U
H41 H -0.1352 1.0905 0.1945 0.037 Uiso 1 1 calc R U
C42 C -0.1114(6) 1.0353(5) 0.2805(4) 0.0265(16) Uani 1 1 d . U
C43 C -0.0549(6) 0.9868(5) 0.3215(4) 0.0261(16) Uani 1 1 d . U
C44 C -0.2384(6) 1.1046(6) 0.2630(5) 0.036(2) Uani 1 1 d . U
H44A H -0.2123 1.1519 0.2539 0.054 Uiso 1 1 calc R U
H44B H -0.2822 1.1168 0.2846 0.054 Uiso 1 1 calc R U
H44C H -0.2602 1.0778 0.2228 0.054 Uiso 1 1 calc R U
C45 C 0.0504(7) 0.6903(6) 0.4656(6) 0.050(3) Uani 1 1 d . U
H45A H 0.1006 0.7097 0.4561 0.076 Uiso 1 1 calc R U
H45B H 0.0270 0.6522 0.4334 0.076 Uiso 1 1 calc R U
H45C H 0.0616 0.6667 0.5082 0.076 Uiso 1 1 calc R U
C46 C 0.2570(10) 0.9671(11) 0.2597(8) 0.089(4) Uani 1 1 d . U
H46A H 0.2415 0.9861 0.2985 0.134 Uiso 1 1 calc R U
H46B H 0.2344 1.0004 0.2235 0.134 Uiso 1 1 calc R U
H46C H 0.3158 0.9667 0.2662 0.134 Uiso 1 1 calc R U
C47 C 0.9031(7) 0.7365(8) 0.3033(6) 0.059(3) Uani 1 1 d . .
H47A H 0.9523 0.7576 0.3301 0.089 Uiso 1 1 calc R U
H47B H 0.8908 0.7636 0.2622 0.089 Uiso 1 1 calc R U
H47C H 0.9109 0.6822 0.2957 0.089 Uiso 1 1 calc R U
N1 N -0.0572(4) 0.8303(4) 0.6723(4) 0.0265(17) Uani 1 1 d . .
H1 H -0.0356 0.8091 0.7092 0.032 Uiso 1 1 calc R U
N2 N -0.2004(4) 0.7658(5) 0.5888(4) 0.0280(17) Uani 1 1 d . .
N3 N 0.4009(5) 1.1529(4) 0.6710(4) 0.0271(17) Uani 1 1 d . .
H3A H 0.4537 1.1530 0.6817 0.032 Uiso 1 1 calc R U
N4 N 0.3337(5) 1.2047(4) 0.5406(4) 0.0290(18) Uani 1 1 d . .
N5 N 0.3962(7) 0.7680(8) 0.3020(6) 0.065(3) Uani 1 1 d . .
O1 O 0.2872(6) 0.6735(6) 0.6567(4) 0.075(3) Uani 1 1 d . .
O2 O 0.1142(3) 0.8743(3) 0.5607(3) 0.0207(13) Uani 1 1 d . .
O3 O -0.0516(3) 0.8546(3) 0.5683(3) 0.0243(13) Uani 1 1 d . .
O4 O -0.1595(4) 0.7084(3) 0.4694(3) 0.0311(15) Uani 1 1 d . .
O5 O -0.1238(5) 0.5883(4) 0.4047(4) 0.0439(18) Uani 1 1 d . .
O6 O 0.5503(4) 0.8118(4) 0.7206(4) 0.056(2) Uani 1 1 d . .
O7 O 0.3127(4) 0.9367(3) 0.6051(3) 0.0272(14) Uani 1 1 d . .
O8 O 0.2843(3) 1.0817(3) 0.6519(3) 0.0274(14) Uani 1 1 d . .
O9 O 0.2417(3) 1.0712(3) 0.4975(3) 0.0221(13) Uani 1 1 d . .
O10 O 0.2434(4) 0.9275(4) 0.4579(3) 0.0332(16) Uani 1 1 d . .
O11 O 0.0666(4) 0.8700(4) 0.3868(3) 0.0279(14) Uani 1 1 d . .
O12 O -0.0698(3) 0.9681(3) 0.3791(3) 0.0209(13) Uani 1 1 d . .
O13 O -0.1791(4) 1.0556(3) 0.3048(3) 0.0241(13) Uani 1 1 d . .
O14 O -0.1430(3) 0.8634(3) 0.4375(3) 0.0198(12) Uani 1 1 d . .
H14A H -0.1004 0.8403 0.4201 0.024 Uiso 1 1 d R U
O15 O 0.0788(3) 1.0056(3) 0.4883(3) 0.0175(12) Uani 1 1 d . .
H15A H 0.0671 0.9773 0.4504 0.021 Uiso 1 1 d R U
O16 O -0.0057(4) 0.7527(3) 0.4643(3) 0.0321(15) Uani 1 1 d . .
H16 H -0.0491 0.7344 0.4572 0.039 Uiso 1 1 d R U
O17 O 0.3235(6) 0.7607(7) 0.3090(6) 0.099(4) Uani 1 1 d . .
O18 O 0.4175(7) 0.8291(8) 0.2802(7) 0.108(4) Uani 1 1 d . .
O19 O 0.4447(6) 0.7166(8) 0.3078(5) 0.091(4) Uani 1 1 d . .
O20 O 0.2252(7) 0.8873(7) 0.2457(7) 0.105(4) Uani 1 1 d . .
H20 H 0.2636 0.8563 0.2524 0.157 Uiso 1 1 calc R U
O21 O 0.8370(4) 0.7457(4) 0.3356(3) 0.0408(17) Uani 1 1 d . .
H21 H 0.8463 0.7204 0.3696 0.061 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O15 Eu1 O14 136.51(19) . .
O15 Eu1 O3 114.77(19) . .
O14 Eu1 O3 73.6(2) . .
O15 Eu1 O2 70.05(19) . .
O14 Eu1 O2 144.57(19) . .
O3 Eu1 O2 72.91(19) . .
O15 Eu1 O15 72.0(2) . 3_576
O14 Eu1 O15 72.73(18) . 3_576
O3 Eu1 O15 68.36(19) . 3_576
O2 Eu1 O15 104.97(19) . 3_576
O15 Eu1 O11 82.5(2) . .
O14 Eu1 O11 108.6(2) . .
O3 Eu1 O11 153.3(2) . .
O2 Eu1 O11 96.3(2) . .
O15 Eu1 O11 138.3(2) 3_576 .
O15 Eu1 O16 146.5(2) . .
O14 Eu1 O16 75.9(2) . .
O3 Eu1 O16 78.0(2) . .
O2 Eu1 O16 86.1(2) . .
O15 Eu1 O16 138.99(19) 3_576 .
O11 Eu1 O16 76.9(2) . .
O15 Eu1 O12 79.42(19) . .
O14 Eu1 O12 66.14(19) . .
O3 Eu1 O12 130.07(19) . .
O2 Eu1 O12 148.31(19) . .
O15 Eu1 O12 72.29(19) 3_576 .
O11 Eu1 O12 70.9(2) . .
O16 Eu1 O12 117.2(2) . .
O15 Eu1 Eu2 93.43(13) . 3_576
O14 Eu1 Eu2 43.13(13) . 3_576
O3 Eu1 Eu2 88.09(14) . 3_576
O2 Eu1 Eu2 145.31(13) . 3_576
O15 Eu1 Eu2 40.36(13) 3_576 3_576
O11 Eu1 Eu2 112.05(15) . 3_576
O16 Eu1 Eu2 118.69(15) . 3_576
O12 Eu1 Eu2 42.16(13) . 3_576
O15 Eu1 Eu1 36.35(13) . 3_576
O14 Eu1 Eu1 105.05(13) . 3_576
O3 Eu1 Eu1 91.55(14) . 3_576
O2 Eu1 Eu1 87.24(13) . 3_576
O15 Eu1 Eu1 35.66(13) 3_576 3_576
O11 Eu1 Eu1 112.64(15) . 3_576
O16 Eu1 Eu1 168.91(16) . 3_576
O12 Eu1 Eu1 72.42(14) . 3_576
Eu2 Eu1 Eu1 64.015(13) 3_576 3_576
O15 Eu1 H14A 145.6 . .
O14 Eu1 H14A 23.4 . .
O3 Eu1 H14A 87.8 . .
O2 Eu1 H14A 144.0 . .
O15 Eu1 H14A 95.1 3_576 .
O11 Eu1 H14A 87.6 . .
O16 Eu1 H14A 59.9 . .
O12 Eu1 H14A 66.2 . .
Eu2 Eu1 H14A 60.2 3_576 .
Eu1 Eu1 H14A 124.2 3_576 .
O15 Eu1 H15A 22.5 . .
O14 Eu1 H15A 131.8 . .
O3 Eu1 H15A 137.3 . .
O2 Eu1 H15A 82.1 . .
O15 Eu1 H15A 86.0 3_576 .
O11 Eu1 H15A 61.5 . .
O16 Eu1 H15A 134.9 . .
O12 Eu1 H15A 66.3 . .
Eu2 Eu1 H15A 93.8 3_576 .
Eu1 Eu1 H15A 52.5 3_576 .
H14A Eu1 H15A 129.5 . .
O7 Eu2 O15 137.0(2) . .
O7 Eu2 O8 73.0(2) . .
O15 Eu2 O8 140.98(19) . .
O7 Eu2 O9 89.5(2) . .
O15 Eu2 O9 75.02(19) . .
O8 Eu2 O9 82.9(2) . .
O7 Eu2 O12 142.8(2) . 3_576
O15 Eu2 O12 72.25(19) . 3_576
O8 Eu2 O12 96.3(2) . 3_576
O9 Eu2 O12 125.29(18) . 3_576
O7 Eu2 O14 137.5(2) . 3_576
O15 Eu2 O14 70.41(18) . 3_576
O8 Eu2 O14 71.10(19) . 3_576
O9 Eu2 O14 64.28(18) . 3_576
O12 Eu2 O14 63.97(18) 3_576 3_576
O7 Eu2 O2 92.0(2) . .
O15 Eu2 O2 67.50(18) . .
O8 Eu2 O2 148.6(2) . .
O9 Eu2 O2 125.41(19) . .
O12 Eu2 O2 78.86(18) 3_576 .
O14 Eu2 O2 130.31(18) 3_576 .
O7 Eu2 O13 81.5(2) . 3_576
O15 Eu2 O13 122.77(18) . 3_576
O8 Eu2 O13 78.2(2) . 3_576
O9 Eu2 O13 160.70(19) . 3_576
O12 Eu2 O13 61.26(18) 3_576 3_576
O14 Eu2 O13 112.09(18) 3_576 3_576
O2 Eu2 O13 72.24(18) . 3_576
O7 Eu2 O10 67.5(2) . .
O15 Eu2 O10 70.97(18) . .
O8 Eu2 O10 120.34(19) . .
O9 Eu2 O10 54.73(18) . .
O12 Eu2 O10 141.12(18) 3_576 .
O14 Eu2 O10 113.58(18) 3_576 .
O2 Eu2 O10 75.87(17) . .
O13 Eu2 O10 134.19(17) 3_576 .
O7 Eu2 Eu1 175.17(16) . 3_576
O15 Eu2 Eu1 40.48(13) . 3_576
O8 Eu2 Eu1 107.16(14) . 3_576
O9 Eu2 Eu1 85.78(14) . 3_576
O12 Eu2 Eu1 42.00(13) 3_576 3_576
O14 Eu2 Eu1 40.22(12) 3_576 3_576
O2 Eu2 Eu1 90.09(13) . 3_576
O13 Eu2 Eu1 103.25(12) 3_576 3_576
O10 Eu2 Eu1 108.87(12) . 3_576
O7 Eu2 Zn1 112.61(16) . 3_576
O15 Eu2 Zn1 74.82(12) . 3_576
O8 Eu2 Zn1 69.17(15) . 3_576
O9 Eu2 Zn1 33.39(13) . 3_576
O12 Eu2 Zn1 95.41(13) 3_576 3_576
O14 Eu2 Zn1 31.70(13) 3_576 3_576
O2 Eu2 Zn1 141.88(13) . 3_576
O13 Eu2 Zn1 137.46(13) 3_576 3_576
O10 Eu2 Zn1 86.87(12) . 3_576
Eu1 Eu2 Zn1 63.456(18) 3_576 3_576
O14 Zn1 O4 85.7(2) . .
O14 Zn1 N4 118.8(3) . 3_576
O4 Zn1 N4 102.4(3) . 3_576
O14 Zn1 N2 142.7(3) . .
O4 Zn1 N2 88.3(3) . .
N4 Zn1 N2 98.5(3) 3_576 .
O14 Zn1 O9 78.7(2) . 3_576
O4 Zn1 O9 164.4(2) . 3_576
N4 Zn1 O9 84.2(3) 3_576 3_576
N2 Zn1 O9 104.8(3) . 3_576
O14 Zn1 Eu2 40.93(16) . 3_576
O4 Zn1 Eu2 125.60(17) . 3_576
N4 Zn1 Eu2 97.5(2) 3_576 3_576
N2 Zn1 Eu2 137.8(2) . 3_576
O9 Zn1 Eu2 38.88(15) 3_576 3_576
O1 C1 H1A 109.5 . .
O1 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
O1 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C7 124.3(9) . .
O1 C2 C3 114.5(9) . .
C7 C2 C3 121.1(9) . .
C4 C3 C2 120.4(9) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
O2 C4 C3 118.6(8) . .
O2 C4 C5 122.2(8) . .
C3 C4 C5 119.2(8) . .
C6 C5 C4 118.7(8) . .
C6 C5 C8 120.1(8) . .
C4 C5 C8 121.2(8) . .
C7 C6 C5 121.6(9) . .
C7 C6 H6 119.2 . .
C5 C6 H6 119.2 . .
C6 C7 C2 118.9(9) . .
C6 C7 H7 120.6 . .
C2 C7 H7 120.6 . .
O3 C8 N1 119.7(8) . .
O3 C8 C5 121.4(8) . .
N1 C8 C5 118.9(8) . .
N1 C9 C10 113.0(7) . .
N1 C9 H9A 109.0 . .
C10 C9 H9A 109.0 . .
N1 C9 H9B 109.0 . .
C10 C9 H9B 109.0 . .
H9A C9 H9B 107.8 . .
N2 C10 C9 110.3(7) . .
N2 C10 H10A 109.6 . .
C9 C10 H10A 109.6 . .
N2 C10 H10B 109.6 . .
C9 C10 H10B 109.6 . .
H10A C10 H10B 108.1 . .
N2 C11 C12 128.0(10) . .
N2 C11 H11 116.0 . .
C12 C11 H11 116.0 . .
C17 C12 C13 117.8(10) . .
C17 C12 C11 125.5(9) . .
C13 C12 C11 116.6(10) . .
C14 C13 C12 122.9(11) . .
C14 C13 H13 118.6 . .
C12 C13 H13 118.6 . .
C13 C14 C15 119.7(11) . .
C13 C14 H14 120.2 . .
C15 C14 H14 120.2 . .
C16 C15 C14 119.3(11) . .
C16 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
O5 C16 C15 123.9(10) . .
O5 C16 C17 113.6(9) . .
C15 C16 C17 122.4(11) . .
O4 C17 C12 122.8(10) . .
O4 C17 C16 119.4(10) . .
C12 C17 C16 117.8(9) . .
O5 C18 H18A 109.5 . .
O5 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
O5 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O6 C19 H19A 109.5 . .
O6 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
O6 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O6 C20 C21 121.3(9) . .
O6 C20 C25 117.4(9) . .
C21 C20 C25 121.3(9) . .
C20 C21 C22 118.6(10) . .
C20 C21 H21A 120.7 . .
C22 C21 H21A 120.7 . .
C21 C22 C23 122.6(10) . .
C21 C22 H22 118.7 . .
C23 C22 H22 118.7 . .
C22 C23 C24 118.7(8) . .
C22 C23 C26 120.9(9) . .
C24 C23 C26 120.4(8) . .
O7 C24 C25 120.0(9) . .
O7 C24 C23 123.3(8) . .
C25 C24 C23 116.7(8) . .
C20 C25 C24 122.0(9) . .
C20 C25 H25 119.0 . .
C24 C25 H25 119.0 . .
O8 C26 N3 120.3(8) . .
O8 C26 C23 120.2(8) . .
N3 C26 C23 119.5(8) . .
N3 C27 C28 112.6(8) . .
N3 C27 H27A 109.1 . .
C28 C27 H27A 109.1 . .
N3 C27 H27B 109.1 . .
C28 C27 H27B 109.1 . .
H27A C27 H27B 107.8 . .
N4 C28 C27 109.8(8) . .
N4 C28 H28A 109.7 . .
C27 C28 H28A 109.7 . .
N4 C28 H28B 109.7 . .
C27 C28 H28B 109.7 . .
H28A C28 H28B 108.2 . .
N4 C29 C30 128.0(9) . .
N4 C29 H29 116.0 . .
C30 C29 H29 116.0 . .
C35 C30 C31 118.9(9) . .
C35 C30 C29 120.5(8) . .
C31 C30 C29 119.9(9) . .
C32 C31 C30 121.8(10) . .
C32 C31 H52 119.1 . .
C30 C31 H52 119.1 . .
C33 C32 C31 118.5(9) . .
C33 C32 H85 120.7 . .
C31 C32 H85 120.7 . .
C32 C33 C34 121.6(10) . .
C32 C33 H65 119.2 . .
C34 C33 H65 119.2 . .
C33 C34 O10 125.0(9) . .
C33 C34 C35 120.4(9) . .
O10 C34 C35 114.7(7) . .
O9 C35 C30 123.9(9) . .
O9 C35 C34 117.8(8) . .
C30 C35 C34 118.2(8) . .
O10 C36 H36A 109.5 . .
O10 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
O10 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
O11 C37 C38 127.9(9) . .
O11 C37 H37 116.1 . .
C38 C37 H37 116.1 . .
C43 C38 C39 119.1(8) . .
C43 C38 C37 123.3(8) . .
C39 C38 C37 117.6(8) . .
C40 C39 C38 120.8(9) . .
C40 C39 H39 119.6 . .
C38 C39 H39 119.6 . .
C39 C40 C41 119.4(9) . .
C39 C40 H40 120.3 . .
C41 C40 H40 120.3 . .
C42 C41 C40 121.3(9) . .
C42 C41 H41 119.4 . .
C40 C41 H41 119.4 . .
C41 C42 O13 125.0(8) . .
C41 C42 C43 120.2(8) . .
O13 C42 C43 114.8(7) . .
O12 C43 C38 122.9(8) . .
O12 C43 C42 118.0(8) . .
C38 C43 C42 119.1(8) . .
O13 C44 H44A 109.5 . .
O13 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
O13 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O16 C45 H45A 109.5 . .
O16 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
O16 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
O20 C46 H46A 109.5 . .
O20 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
O20 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
O21 C47 H47A 109.5 . .
O21 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
O21 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C8 N1 C9 120.2(8) . .
C8 N1 H1 119.9 . .
C9 N1 H1 119.9 . .
C11 N2 C10 114.9(8) . .
C11 N2 Zn1 123.7(7) . .
C10 N2 Zn1 121.3(6) . .
C26 N3 C27 123.8(8) . .
C26 N3 H3A 118.1 . .
C27 N3 H3A 118.1 . .
C29 N4 C28 116.4(8) . .
C29 N4 Zn1 121.7(7) . 3_576
C28 N4 Zn1 122.0(6) . 3_576
O19 N5 O18 115.4(12) . .
O19 N5 O17 124.6(14) . .
O18 N5 O17 119.4(14) . .
C1 O1 C2 120.5(11) . .
C4 O2 Eu1 123.6(5) . .
C4 O2 Eu2 126.6(5) . .
Eu1 O2 Eu2 108.4(2) . .
C8 O3 Eu1 134.1(6) . .
C17 O4 Zn1 127.2(6) . .
C16 O5 C18 116.3(9) . .
C20 O6 C19 118.3(10) . .
C24 O7 Eu2 138.4(6) . .
C26 O8 Eu2 132.0(6) . .
C35 O9 Zn1 122.2(5) . 3_576
C35 O9 Eu2 123.4(5) . .
Zn1 O9 Eu2 107.7(2) 3_576 .
C34 O10 C36 117.3(7) . .
C34 O10 Eu2 102.5(5) . .
C36 O10 Eu2 120.5(6) . .
C37 O11 Eu1 136.0(6) . .
C43 O12 Eu1 137.1(5) . .
C43 O12 Eu2 127.1(5) . 3_576
Eu1 O12 Eu2 95.84(19) . 3_576
C42 O13 C44 115.7(7) . .
C42 O13 Eu2 118.7(5) . 3_576
C44 O13 Eu2 125.6(5) . 3_576
Zn1 O14 Eu1 122.1(3) . .
Zn1 O14 Eu2 107.4(2) . 3_576
Eu1 O14 Eu2 96.64(19) . 3_576
Zn1 O14 H14A 126.5 . .
Eu1 O14 H14A 56.3 . .
Eu2 O14 H14A 126.1 3_576 .
Eu1 O15 Eu2 113.6(2) . .
Eu1 O15 Eu1 108.0(2) . 3_576
Eu2 O15 Eu1 99.17(19) . 3_576
Eu1 O15 H15A 56.3 . .
Eu2 O15 H15A 131.0 . .
Eu1 O15 H15A 129.9 3_576 .
C45 O16 Eu1 138.5(6) . .
C45 O16 H16 106.3 . .
Eu1 O16 H16 115.1 . .
C46 O20 H20 109.5 . .
C47 O21 H21 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O15 2.345(5) .
Eu1 O14 2.358(5) .
Eu1 O3 2.375(6) .
Eu1 O2 2.376(6) .
Eu1 O15 2.384(5) 3_576
Eu1 O11 2.399(6) .
Eu1 O16 2.416(6) .
Eu1 O12 2.439(5) .
Eu1 Eu2 3.6260(6) 3_576
Eu1 Eu1 3.8260(8) 3_576
Eu1 H14A 1.9942 .
Eu1 H15A 1.9896 .
Eu2 O7 2.242(6) .
Eu2 O15 2.378(5) .
Eu2 O8 2.382(6) .
Eu2 O9 2.396(6) .
Eu2 O12 2.447(5) 3_576
Eu2 O14 2.496(5) 3_576
Eu2 O2 2.496(5) .
Eu2 O13 2.655(6) 3_576
Eu2 O10 3.104(6) .
Eu2 Eu1 3.6260(6) 3_576
Eu2 Zn1 3.6358(10) 3_576
Zn1 O14 2.002(6) .
Zn1 O4 2.072(6) .
Zn1 N4 2.074(7) 3_576
Zn1 N2 2.091(7) .
Zn1 O9 2.100(6) 3_576
Zn1 Eu2 3.6358(10) 3_576
C1 O1 1.350(14) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 O1 1.368(12) .
C2 C7 1.392(13) .
C2 C3 1.395(13) .
C3 C4 1.386(12) .
C3 H3 0.9300 .
C4 O2 1.338(10) .
C4 C5 1.427(12) .
C5 C6 1.406(12) .
C5 C8 1.487(12) .
C6 C7 1.380(12) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 O3 1.248(10) .
C8 N1 1.339(11) .
C9 N1 1.464(11) .
C9 C10 1.544(13) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 N2 1.481(12) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 N2 1.274(12) .
C11 C12 1.439(14) .
C11 H11 0.9300 .
C12 C17 1.408(15) .
C12 C13 1.431(14) .
C13 C14 1.345(15) .
C13 H13 0.9300 .
C14 C15 1.394(17) .
C14 H14 0.9300 .
C15 C16 1.380(14) .
C15 H15 0.9300 .
C16 O5 1.372(13) .
C16 C17 1.415(14) .
C17 O4 1.301(11) .
C18 O5 1.440(12) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 O6 1.430(16) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 O6 1.364(11) .
C20 C21 1.368(14) .
C20 C25 1.369(13) .
C21 C22 1.386(13) .
C21 H21A 0.9300 .
C22 C23 1.397(12) .
C22 H22 0.9300 .
C23 C24 1.433(13) .
C23 C26 1.459(12) .
C24 O7 1.305(10) .
C24 C25 1.419(12) .
C25 H25 0.9300 .
C26 O8 1.273(10) .
C26 N3 1.331(11) .
C27 N3 1.445(11) .
C27 C28 1.509(13) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 N4 1.468(12) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 N4 1.268(12) .
C29 C30 1.461(14) .
C29 H29 0.9300 .
C30 C35 1.389(13) .
C30 C31 1.401(13) .
C31 C32 1.368(14) .
C31 H52 0.9300 .
C32 C33 1.358(14) .
C32 H85 0.9300 .
C33 C34 1.372(13) .
C33 H65 0.9300 .
C34 O10 1.397(11) .
C34 C35 1.400(13) .
C35 O9 1.329(10) .
C36 O10 1.408(11) .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 O11 1.237(10) .
C37 C38 1.434(13) .
C37 H37 0.9300 .
C38 C43 1.399(12) .
C38 C39 1.428(12) .
C39 C40 1.355(13) .
C39 H39 0.9300 .
C40 C41 1.401(13) .
C40 H40 0.9300 .
C41 C42 1.370(12) .
C41 H41 0.9300 .
C42 O13 1.378(10) .
C42 C43 1.404(13) .
C43 O12 1.321(10) .
C44 O13 1.442(10) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C45 O16 1.420(11) .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C46 O20 1.476(18) .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 O21 1.420(13) .
C47 H47A 0.9600 .
C47 H47B 0.9600 .
C47 H47C 0.9600 .
N1 H1 0.8600 .
N3 H3A 0.8600 .
N4 Zn1 2.074(7) 3_576
N5 O19 1.186(14) .
N5 O18 1.227(15) .
N5 O17 1.257(13) .
O9 Zn1 2.101(6) 3_576
O12 Eu2 2.447(5) 3_576
O13 Eu2 2.655(6) 3_576
O14 Eu2 2.496(5) 3_576
O14 H14A 0.9507 .
O15 Eu1 2.384(5) 3_576
O15 H15A 0.9155 .
O16 H16 0.7739 .
O20 H20 0.8200 .
O21 H21 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O1 C2 C3 C4 -179.4(9) .
C7 C2 C3 C4 -1.0(14) .
C2 C3 C4 O2 -178.7(8) .
C2 C3 C4 C5 2.0(13) .
O2 C4 C5 C6 179.3(8) .
C3 C4 C5 C6 -1.5(13) .
O2 C4 C5 C8 1.8(13) .
C3 C4 C5 C8 -179.0(8) .
C4 C5 C6 C7 0.0(14) .
C8 C5 C6 C7 177.5(8) .
C5 C6 C7 C2 1.1(14) .
O1 C2 C7 C6 177.7(10) .
C3 C2 C7 C6 -0.6(14) .
C6 C5 C8 O3 -142.6(9) .
C4 C5 C8 O3 34.8(13) .
C6 C5 C8 N1 36.4(13) .
C4 C5 C8 N1 -146.1(9) .
N1 C9 C10 N2 -48.6(10) .
N2 C11 C12 C17 7.7(19) .
N2 C11 C12 C13 -175.3(11) .
C17 C12 C13 C14 -2.3(18) .
C11 C12 C13 C14 -179.5(12) .
C12 C13 C14 C15 4(2) .
C13 C14 C15 C16 -2(2) .
C14 C15 C16 O5 179.0(11) .
C14 C15 C16 C17 -1.5(19) .
C13 C12 C17 O4 -178.4(10) .
C11 C12 C17 O4 -1.5(19) .
C13 C12 C17 C16 -1.4(17) .
C11 C12 C17 C16 175.5(11) .
O5 C16 C17 O4 0.0(16) .
C15 C16 C17 O4 -179.6(11) .
O5 C16 C17 C12 -177.1(10) .
C15 C16 C17 C12 3.3(18) .
O6 C20 C21 C22 179.3(9) .
C25 C20 C21 C22 -2.0(15) .
C20 C21 C22 C23 2.4(15) .
C21 C22 C23 C24 -0.8(14) .
C21 C22 C23 C26 -179.9(9) .
C22 C23 C24 O7 178.4(8) .
C26 C23 C24 O7 -2.6(14) .
C22 C23 C24 C25 -1.1(13) .
C26 C23 C24 C25 177.9(8) .
O6 C20 C25 C24 178.9(9) .
C21 C20 C25 C24 0.1(15) .
O7 C24 C25 C20 -178.0(9) .
C23 C24 C25 C20 1.5(13) .
C22 C23 C26 O8 -147.3(9) .
C24 C23 C26 O8 33.7(13) .
C22 C23 C26 N3 32.1(13) .
C24 C23 C26 N3 -146.9(9) .
N3 C27 C28 N4 56.0(10) .
N4 C29 C30 C35 -18.9(16) .
N4 C29 C30 C31 170.5(10) .
C35 C30 C31 C32 -2.3(15) .
C29 C30 C31 C32 168.5(10) .
C30 C31 C32 C33 -3.2(16) .
C31 C32 C33 C34 2.8(16) .
C32 C33 C34 O10 -178.3(10) .
C32 C33 C34 C35 3.2(16) .
C31 C30 C35 O9 -175.3(9) .
C29 C30 C35 O9 13.9(15) .
C31 C30 C35 C34 8.1(14) .
C29 C30 C35 C34 -162.6(9) .
C33 C34 C35 O9 174.6(9) .
O10 C34 C35 O9 -4.1(13) .
C33 C34 C35 C30 -8.7(14) .
O10 C34 C35 C30 172.7(8) .
O11 C37 C38 C43 0.3(16) .
O11 C37 C38 C39 -176.9(9) .
C43 C38 C39 C40 -2.0(15) .
C37 C38 C39 C40 175.4(9) .
C38 C39 C40 C41 -1.2(15) .
C39 C40 C41 C42 2.0(15) .
C40 C41 C42 O13 -178.6(9) .
C40 C41 C42 C43 0.5(15) .
C39 C38 C43 O12 -177.6(8) .
C37 C38 C43 O12 5.2(14) .
C39 C38 C43 C42 4.5(14) .
C37 C38 C43 C42 -172.8(9) .
C41 C42 C43 O12 178.2(8) .
O13 C42 C43 O12 -2.5(12) .
C41 C42 C43 C38 -3.8(14) .
O13 C42 C43 C38 175.5(8) .
O3 C8 N1 C9 -2.5(13) .
C5 C8 N1 C9 178.5(8) .
C10 C9 N1 C8 93.7(10) .
C12 C11 N2 C10 -177.3(10) .
C12 C11 N2 Zn1 6.2(15) .
C9 C10 N2 C11 112.9(9) .
C9 C10 N2 Zn1 -70.5(9) .
O8 C26 N3 C27 -0.4(13) .
C23 C26 N3 C27 -179.7(8) .
C28 C27 N3 C26 -105.0(10) .
C30 C29 N4 C28 164.7(9) .
C30 C29 N4 Zn1 -17.0(14) 3_576
C27 C28 N4 C29 -103.5(10) .
C27 C28 N4 Zn1 78.2(9) 3_576
C7 C2 O1 C1 -3.9(17) .
C3 C2 O1 C1 174.5(11) .
C3 C4 O2 Eu1 130.7(7) .
C5 C4 O2 Eu1 -50.1(10) .
C3 C4 O2 Eu2 -64.5(10) .
C5 C4 O2 Eu2 114.7(8) .
N1 C8 O3 Eu1 161.5(6) .
C5 C8 O3 Eu1 -19.4(13) .
C12 C17 O4 Zn1 -17.9(15) .
C16 C17 O4 Zn1 165.1(8) .
C15 C16 O5 C18 -9.8(17) .
C17 C16 O5 C18 170.6(10) .
C21 C20 O6 C19 0.6(16) .
C25 C20 O6 C19 -178.1(11) .
C25 C24 O7 Eu2 158.1(6) .
C23 C24 O7 Eu2 -21.3(14) .
N3 C26 O8 Eu2 135.9(7) .
C23 C26 O8 Eu2 -44.7(12) .
C30 C35 O9 Zn1 24.6(12) 3_576
C34 C35 O9 Zn1 -158.8(7) 3_576
C30 C35 O9 Eu2 -123.2(8) .
C34 C35 O9 Eu2 53.4(10) .
C33 C34 O10 C36 19.6(14) .
C35 C34 O10 C36 -161.9(8) .
C33 C34 O10 Eu2 154.0(9) .
C35 C34 O10 Eu2 -27.4(9) .
C38 C37 O11 Eu1 -15.6(15) .
C38 C43 O12 Eu1 3.9(14) .
C42 C43 O12 Eu1 -178.2(6) .
C38 C43 O12 Eu2 -172.9(6) 3_576
C42 C43 O12 Eu2 5.1(11) 3_576
C41 C42 O13 C44 -0.1(13) .
C43 C42 O13 C44 -179.3(8) .
C41 C42 O13 Eu2 178.7(7) 3_576
C43 C42 O13 Eu2 -0.6(10) 3_576
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.500 603 118 ' '
2 0.500 0.500 1.000 603 118 ' '
