#------------------------------------------------------------------------------
#$Date: 2017-08-01 05:11:09 +0300 (Tue, 01 Aug 2017) $
#$Revision: 199419 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/88/7228812.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7228812
loop_
_publ_author_name
'Chen, Jing'
'Voutier, Noémie'
'Rajabi, Jamshid'
'Crochet, Aurelien'
'Bassani, Dario'
'Fromm, Katharina'
_publ_section_title
;
 Influence of Anions and Solvent Molecules on the Packing and Emission
 Spectra of Coordination Polymers Based on Silver ions and an Anthracene
 Derivative
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/C7CE00846E
_journal_year                    2017
_chemical_formula_moiety         'C28 H20 Ag N3 O7, C H4 O'
_chemical_formula_sum            'C29 H24 Ag N3 O8'
_chemical_formula_weight         650.38
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-07-17 deposited with the CCDC.
2017-07-31 downloaded from the CCDC.
;
_cell_angle_alpha                93.942(4)
_cell_angle_beta                 96.876(4)
_cell_angle_gamma                91.701(4)
_cell_formula_units_Z            2
_cell_length_a                   8.2044(4)
_cell_length_b                   9.4246(4)
_cell_length_c                   16.7815(8)
_cell_measurement_reflns_used    23307
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.07
_cell_measurement_theta_min      1.22
_cell_volume                     1284.28(10)
_computing_cell_refinement       'X-Area (Stoe & Cie, 2009)'
_computing_data_collection       'X-Area (Stoe & Cie, 2009)'
_computing_data_reduction        'X-RED32(Stoe & Cie, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1374
_diffrn_reflns_av_unetI/netI     0.0683
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21429
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        24.579
_diffrn_reflns_theta_max         24.579
_diffrn_reflns_theta_min         1.225
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.845
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.682
_exptl_crystal_description       needle
_exptl_crystal_F_000             660
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.541
_refine_diff_density_min         -0.767
_refine_diff_density_rms         0.153
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         4296
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.084
_refine_ls_R_factor_all          0.0734
_refine_ls_R_factor_gt           0.0608
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0902P)²+1.1304P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1440
_refine_ls_wR_factor_ref         0.1512
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3622
_reflns_number_total             4296
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7ce00846e2.cif
_cod_data_source_block           complex1
_cod_database_code               7228812
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 0.27567(5) 0.50748(4) 0.97665(2) 0.03838(19) Uani 1 1 d . .
O1 O 0.3487(6) 0.9004(4) 0.6612(3) 0.0524(11) Uani 1 1 d . .
O2 O 0.4117(4) 0.6741(4) 0.6813(2) 0.0313(8) Uani 1 1 d . .
O3 O 0.0882(4) 0.3762(4) 0.2643(2) 0.0311(8) Uani 1 1 d . .
O4 O 0.1695(5) 0.1625(4) 0.3016(2) 0.0449(10) Uani 1 1 d . .
O5 O 0.1396(5) 0.2784(5) 0.8589(3) 0.0537(11) Uani 1 1 d . .
O6 O -0.0959(5) 0.1818(4) 0.8729(3) 0.0444(9) Uani 1 1 d . .
O7 O -0.0280(5) 0.3943(4) 0.9268(3) 0.0465(10) Uani 1 1 d . .
N1 N 0.2545(5) 0.6865(5) 0.9018(3) 0.0323(9) Uani 1 1 d . .
N2 N 0.3027(5) 0.3357(4) 0.0572(3) 0.0332(9) Uani 1 1 d . .
N3 N 0.0053(6) 0.2844(5) 0.8846(3) 0.0375(10) Uani 1 1 d . .
C1 C 0.1814(6) 0.8036(6) 0.9289(3) 0.0345(11) Uani 1 1 d . .
H1 H 0.1428 0.8043 0.9789 0.041 Uiso 1 1 calc R U
C2 C 0.1614(7) 0.9226(6) 0.8854(3) 0.0373(12) Uani 1 1 d . .
H2 H 0.1109 1.0017 0.9060 0.045 Uiso 1 1 calc R U
C3 C 0.2173(7) 0.9228(5) 0.8106(3) 0.0340(11) Uani 1 1 d . .
H3 H 0.2054 1.0016 0.7803 0.041 Uiso 1 1 calc R U
C4 C 0.2917(6) 0.8021(5) 0.7823(3) 0.0291(10) Uani 1 1 d . .
C5 C 0.3087(6) 0.6868(5) 0.8295(3) 0.0307(11) Uani 1 1 d . .
H5 H 0.3594 0.6068 0.8102 0.037 Uiso 1 1 calc R U
C6 C 0.3538(6) 0.8006(5) 0.7019(3) 0.0314(11) Uani 1 1 d . .
C7 C 0.4700(6) 0.6561(5) 0.6017(3) 0.0315(11) Uani 1 1 d . .
H7A H 0.5618 0.5935 0.6047 0.038 Uiso 1 1 calc R U
H7B H 0.5089 0.7478 0.5869 0.038 Uiso 1 1 calc R U
C8 C 0.3376(6) 0.5952(5) 0.5373(3) 0.0270(10) Uani 1 1 d . .
C9 C 0.2791(6) 0.4550(5) 0.5405(3) 0.0286(10) Uani 1 1 d . .
C10 C 0.3321(6) 0.3721(5) 0.6067(3) 0.0309(11) Uani 1 1 d . .
H10 H 0.4063 0.4130 0.6489 0.037 Uiso 1 1 calc R U
C11 C 0.2766(7) 0.2358(5) 0.6094(3) 0.0353(12) Uani 1 1 d . .
H11 H 0.3125 0.1848 0.6533 0.042 Uiso 1 1 calc R U
C12 C 0.1653(7) 0.1709(5) 0.5464(3) 0.0357(12) Uani 1 1 d . .
H12 H 0.1282 0.0774 0.5492 0.043 Uiso 1 1 calc R U
C13 C 0.1112(6) 0.2418(5) 0.4818(3) 0.0321(11) Uani 1 1 d . .
H13 H 0.0373 0.1968 0.4408 0.038 Uiso 1 1 calc R U
C14 C 0.1672(6) 0.3872(5) 0.4757(3) 0.0271(10) Uani 1 1 d . .
C15 C 0.1189(6) 0.4632(5) 0.4076(3) 0.0275(10) Uani 1 1 d . .
C16 C 0.1749(6) 0.6062(5) 0.4043(3) 0.0277(10) Uani 1 1 d . .
C17 C 0.1270(6) 0.6864(5) 0.3366(3) 0.0322(11) Uani 1 1 d . .
H17 H 0.0604 0.6430 0.2924 0.039 Uiso 1 1 calc R U
C18 C 0.1770(7) 0.8244(6) 0.3356(3) 0.0372(12) Uani 1 1 d . .
H18 H 0.1429 0.8750 0.2913 0.045 Uiso 1 1 calc R U
C19 C 0.2805(7) 0.8921(5) 0.4015(3) 0.0382(12) Uani 1 1 d . .
H19 H 0.3133 0.9871 0.4000 0.046 Uiso 1 1 calc R U
C20 C 0.3331(7) 0.8208(5) 0.4670(3) 0.0357(12) Uani 1 1 d . .
H20 H 0.4016 0.8671 0.5096 0.043 Uiso 1 1 calc R U
C21 C 0.2829(6) 0.6738(5) 0.4704(3) 0.0283(10) Uani 1 1 d . .
C22 C 0.0055(6) 0.3967(5) 0.3371(3) 0.0300(10) Uani 1 1 d . .
H22A H -0.0366 0.3053 0.3507 0.036 Uiso 1 1 calc R U
H22B H -0.0871 0.4570 0.3262 0.036 Uiso 1 1 calc R U
C23 C 0.1632(6) 0.2533(5) 0.2551(3) 0.0306(11) Uani 1 1 d . .
C24 C 0.2361(6) 0.2397(5) 0.1775(3) 0.0291(10) Uani 1 1 d . .
C25 C 0.2981(6) 0.1085(5) 0.1540(3) 0.0321(11) Uani 1 1 d . .
H25 H 0.2970 0.0329 0.1868 0.039 Uiso 1 1 calc R U
C26 C 0.3610(6) 0.0936(5) 0.0810(3) 0.0342(11) Uani 1 1 d . .
H26 H 0.4022 0.0075 0.0637 0.041 Uiso 1 1 calc R U
C27 C 0.3616(6) 0.2086(5) 0.0346(3) 0.0325(11) Uani 1 1 d . .
H27 H 0.4043 0.1984 -0.0143 0.039 Uiso 1 1 calc R U
C28 C 0.2404(6) 0.3493(5) 0.1271(3) 0.0312(11) Uani 1 1 d . .
H28 H 0.1982 0.4360 0.1425 0.037 Uiso 1 1 calc R U
O8 O 0.4118(5) 0.7317(5) 0.1100(3) 0.0527(11) Uani 1 1 d . .
H8 H 0.3075 0.7470 0.1157 0.079 Uiso 1 1 d R U
C29 C 0.4808(8) 0.7097(8) 0.1894(4) 0.0525(16) Uani 1 1 d . .
H29A H 0.5926 0.6824 0.1891 0.079 Uiso 1 1 calc R U
H29B H 0.4187 0.6357 0.2100 0.079 Uiso 1 1 calc R U
H29C H 0.4781 0.7961 0.2229 0.079 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Ag1 N2 176.90(15) 1_556
C6 O2 C7 117.0(4) .
C23 O3 C22 116.0(4) .
C5 N1 C1 117.9(4) .
C5 N1 Ag1 123.6(3) .
C1 N1 Ag1 118.4(3) .
C28 N2 C27 118.4(4) .
C28 N2 Ag1 119.0(3) 1_554
C27 N2 Ag1 122.1(4) 1_554
O5 N3 O6 121.1(5) .
O5 N3 O7 119.6(5) .
O6 N3 O7 119.2(5) .
N1 C1 C2 122.6(5) .
N1 C1 H1 118.7 .
C2 C1 H1 118.7 .
C1 C2 C3 119.4(5) .
C1 C2 H2 120.3 .
C3 C2 H2 120.3 .
C2 C3 C4 118.2(5) .
C2 C3 H3 120.9 .
C4 C3 H3 120.9 .
C3 C4 C5 119.3(5) .
C3 C4 C6 119.0(4) .
C5 C4 C6 121.7(4) .
N1 C5 C4 122.5(5) .
N1 C5 H5 118.7 .
C4 C5 H5 118.7 .
O1 C6 O2 124.9(5) .
O1 C6 C4 123.7(5) .
O2 C6 C4 111.4(4) .
O2 C7 C8 112.4(4) .
O2 C7 H7A 109.1 .
C8 C7 H7A 109.1 .
O2 C7 H7B 109.1 .
C8 C7 H7B 109.1 .
H7A C7 H7B 107.9 .
C9 C8 C21 120.0(5) .
C9 C8 C7 118.9(4) .
C21 C8 C7 120.8(4) .
C8 C9 C10 121.7(5) .
C8 C9 C14 120.7(5) .
C10 C9 C14 117.6(4) .
C11 C10 C9 121.7(5) .
C11 C10 H10 119.2 .
C9 C10 H10 119.2 .
C10 C11 C12 120.5(5) .
C10 C11 H11 119.8 .
C12 C11 H11 119.8 .
C13 C12 C11 121.2(5) .
C13 C12 H12 119.4 .
C11 C12 H12 119.4 .
C12 C13 C14 120.6(5) .
C12 C13 H13 119.7 .
C14 C13 H13 119.7 .
C15 C14 C9 119.1(4) .
C15 C14 C13 122.4(5) .
C9 C14 C13 118.5(4) .
C14 C15 C16 120.7(4) .
C14 C15 C22 121.5(4) .
C16 C15 C22 117.8(4) .
C15 C16 C17 122.0(5) .
C15 C16 C21 119.6(4) .
C17 C16 C21 118.4(5) .
C18 C17 C16 121.2(5) .
C18 C17 H17 119.4 .
C16 C17 H17 119.4 .
C17 C18 C19 120.4(5) .
C17 C18 H18 119.8 .
C19 C18 H18 119.8 .
C20 C19 C18 121.2(5) .
C20 C19 H19 119.4 .
C18 C19 H19 119.4 .
C19 C20 C21 120.2(5) .
C19 C20 H20 119.9 .
C21 C20 H20 119.9 .
C8 C21 C16 119.7(4) .
C8 C21 C20 121.7(5) .
C16 C21 C20 118.5(5) .
O3 C22 C15 112.2(4) .
O3 C22 H22A 109.2 .
C15 C22 H22A 109.2 .
O3 C22 H22B 109.2 .
C15 C22 H22B 109.2 .
H22A C22 H22B 107.9 .
O4 C23 O3 125.0(5) .
O4 C23 C24 123.2(5) .
O3 C23 C24 111.8(4) .
C28 C24 C25 118.8(5) .
C28 C24 C23 122.9(4) .
C25 C24 C23 118.3(4) .
C26 C25 C24 118.7(5) .
C26 C25 H25 120.7 .
C24 C25 H25 120.7 .
C27 C26 C25 118.9(4) .
C27 C26 H26 120.6 .
C25 C26 H26 120.6 .
N2 C27 C26 122.6(5) .
N2 C27 H27 118.7 .
C26 C27 H27 118.7 .
N2 C28 C24 122.7(5) .
N2 C28 H28 118.7 .
C24 C28 H28 118.7 .
C29 O8 H8 102.6 .
O8 C29 H29A 109.5 .
O8 C29 H29B 109.5 .
H29A C29 H29B 109.5 .
O8 C29 H29C 109.5 .
H29A C29 H29C 109.5 .
H29B C29 H29C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.170(4) .
Ag1 N2 2.179(4) 1_556
O1 C6 1.198(7) .
O2 C6 1.336(6) .
O2 C7 1.472(6) .
O3 C23 1.336(6) .
O3 C22 1.472(6) .
O4 C23 1.195(7) .
O5 N3 1.231(6) .
O6 N3 1.245(6) .
O7 N3 1.269(6) .
N1 C5 1.343(7) .
N1 C1 1.349(7) .
N2 C28 1.334(7) .
N2 C27 1.352(7) .
N2 Ag1 2.179(4) 1_554
C1 C2 1.383(8) .
C1 H1 0.9300 .
C2 C3 1.386(8) .
C2 H2 0.9300 .
C3 C4 1.389(7) .
C3 H3 0.9300 .
C4 C5 1.388(7) .
C4 C6 1.497(7) .
C5 H5 0.9300 .
C7 C8 1.507(7) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C9 1.400(7) .
C8 C21 1.423(7) .
C9 C10 1.434(7) .
C9 C14 1.438(7) .
C10 C11 1.356(7) .
C10 H10 0.9300 .
C11 C12 1.405(8) .
C11 H11 0.9300 .
C12 C13 1.349(7) .
C12 H12 0.9300 .
C13 C14 1.446(7) .
C13 H13 0.9300 .
C14 C15 1.412(7) .
C15 C16 1.418(7) .
C15 C22 1.503(7) .
C16 C17 1.430(7) .
C16 C21 1.434(7) .
C17 C18 1.353(8) .
C17 H17 0.9300 .
C18 C19 1.413(8) .
C18 H18 0.9300 .
C19 C20 1.360(8) .
C19 H19 0.9300 .
C20 C21 1.441(7) .
C20 H20 0.9300 .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 C24 1.496(7) .
C24 C28 1.382(7) .
C24 C25 1.400(7) .
C25 C26 1.385(8) .
C25 H25 0.9300 .
C26 C27 1.378(8) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 H28 0.9300 .
O8 C29 1.416(7) .
O8 H8 0.8876 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C5 N1 C1 C2 -0.3(8) .
Ag1 N1 C1 C2 -179.6(4) .
N1 C1 C2 C3 0.4(8) .
C1 C2 C3 C4 0.1(8) .
C2 C3 C4 C5 -0.5(8) .
C2 C3 C4 C6 -179.7(5) .
C1 N1 C5 C4 -0.1(7) .
Ag1 N1 C5 C4 179.2(4) .
C3 C4 C5 N1 0.5(8) .
C6 C4 C5 N1 179.7(4) .
C7 O2 C6 O1 -1.4(8) .
C7 O2 C6 C4 177.4(4) .
C3 C4 C6 O1 3.0(8) .
C5 C4 C6 O1 -176.2(5) .
C3 C4 C6 O2 -175.9(4) .
C5 C4 C6 O2 5.0(7) .
C6 O2 C7 C8 -92.7(5) .
O2 C7 C8 C9 -67.4(6) .
O2 C7 C8 C21 118.2(5) .
C21 C8 C9 C10 179.6(4) .
C7 C8 C9 C10 5.1(7) .
C21 C8 C9 C14 1.8(7) .
C7 C8 C9 C14 -172.7(4) .
C8 C9 C10 C11 -179.3(5) .
C14 C9 C10 C11 -1.4(7) .
C9 C10 C11 C12 0.5(8) .
C10 C11 C12 C13 0.2(8) .
C11 C12 C13 C14 0.2(8) .
C8 C9 C14 C15 1.1(7) .
C10 C9 C14 C15 -176.8(4) .
C8 C9 C14 C13 179.6(4) .
C10 C9 C14 C13 1.7(6) .
C12 C13 C14 C15 177.3(5) .
C12 C13 C14 C9 -1.1(7) .
C9 C14 C15 C16 -2.3(7) .
C13 C14 C15 C16 179.3(4) .
C9 C14 C15 C22 178.5(4) .
C13 C14 C15 C22 0.0(7) .
C14 C15 C16 C17 -179.4(4) .
C22 C15 C16 C17 -0.1(7) .
C14 C15 C16 C21 0.6(7) .
C22 C15 C16 C21 179.9(4) .
C15 C16 C17 C18 177.6(5) .
C21 C16 C17 C18 -2.4(7) .
C16 C17 C18 C19 1.1(8) .
C17 C18 C19 C20 0.3(8) .
C18 C19 C20 C21 -0.3(8) .
C9 C8 C21 C16 -3.5(7) .
C7 C8 C21 C16 170.9(4) .
C9 C8 C21 C20 176.5(4) .
C7 C8 C21 C20 -9.1(7) .
C15 C16 C21 C8 2.3(7) .
C17 C16 C21 C8 -177.7(4) .
C15 C16 C21 C20 -177.7(4) .
C17 C16 C21 C20 2.3(7) .
C19 C20 C21 C8 179.0(5) .
C19 C20 C21 C16 -1.1(7) .
C23 O3 C22 C15 88.4(5) .
C14 C15 C22 O3 -113.0(5) .
C16 C15 C22 O3 67.7(5) .
C22 O3 C23 O4 -1.2(7) .
C22 O3 C23 C24 177.2(4) .
O4 C23 C24 C28 -174.5(5) .
O3 C23 C24 C28 7.0(7) .
O4 C23 C24 C25 7.4(8) .
O3 C23 C24 C25 -171.0(4) .
C28 C24 C25 C26 -0.2(7) .
C23 C24 C25 C26 178.0(4) .
C24 C25 C26 C27 0.6(7) .
C28 N2 C27 C26 -0.5(8) .
Ag1 N2 C27 C26 -172.0(4) 1_554
C25 C26 C27 N2 -0.2(8) .
C27 N2 C28 C24 1.0(7) .
Ag1 N2 C28 C24 172.7(4) 1_554
C25 C24 C28 N2 -0.6(8) .
C23 C24 C28 N2 -178.7(5) .
