#------------------------------------------------------------------------------
#$Date: 2017-11-10 05:14:17 +0200 (Fri, 10 Nov 2017) $
#$Revision: 203021 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/95/7229543.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7229543
loop_
_publ_author_name
'Seo, Sujin'
'Lee, Eunji'
'Ju, Huiyeong'
'Kim, Seulgi'
'Park, In-Hyeok'
'Jung, Jong Hwa'
'Lee, Shim Sung'
_publ_section_title
;
 Influence of mole-ratio on the coordination behaviour of a ditopic
 N2O2S2-macrocycle: endo/exocyclic silver(I) coordination polymer
 exhibiting desolvation-induced SCSC transformation
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/C7CE01540B
_journal_year                    2017
_chemical_formula_moiety         '5 H28 Ag2 F6 N2 O2 P S2, F6 P'
_chemical_formula_sum            'C25 H28 Ag2 F12 N2 O2 P2 S2'
_chemical_formula_weight         958.29
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2017-10-23 deposited with the CCDC.
2017-11-09 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 108.4080(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.6427(5)
_cell_length_b                   10.2297(3)
_cell_length_c                   16.2000(4)
_cell_measurement_reflns_used    9191
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.26
_cell_measurement_theta_min      2.39
_cell_volume                     3088.65(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0449
_diffrn_reflns_av_sigmaI/netI    0.0406
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            29728
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         2.19
_exptl_absorpt_coefficient_mu    1.610
_exptl_absorpt_correction_T_max  0.8556
_exptl_absorpt_correction_T_min  0.6438
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.061
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1888
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.10
_refine_diff_density_max         4.761
_refine_diff_density_min         -3.129
_refine_diff_density_rms         0.254
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     396
_refine_ls_number_reflns         7458
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      2.063
_refine_ls_R_factor_all          0.0871
_refine_ls_R_factor_gt           0.0771
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1391P)²+30.8733P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2288
_refine_ls_wR_factor_ref         0.2420
_reflns_number_gt                6329
_reflns_number_total             7458
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7ce01540b2.cif
_cod_data_source_block           2b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7229543
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.28192(5) 0.62152(10) 0.60597(6) 0.0253(3) Uani 1 1 d . . .
Ag2 Ag 0.27621(8) 0.53565(14) 0.88877(8) 0.0424(4) Uani 1 1 d . . .
N1 N 0.1642(6) 0.5760(11) 0.5305(7) 0.024(2) Uani 1 1 d . . .
N2 N 0.4109(6) 0.6318(11) 0.6473(7) 0.025(2) Uani 1 1 d . . .
H2 H 0.4239 0.5946 0.6021 0.030 Uiso 1 1 calc R . .
O1 O 0.1835(5) 0.8290(10) 0.6125(6) 0.030(2) Uani 1 1 d . . .
O2 O 0.2506(5) 0.3561(10) 0.5672(6) 0.0264(19) Uani 1 1 d . B .
S1 S 0.30853(18) 0.8569(3) 0.5351(2) 0.0248(7) Uani 1 1 d . . .
S2 S 0.31882(17) 0.5182(3) 0.7636(2) 0.0237(6) Uani 1 1 d . B .
C1 C 0.0824(9) 0.4655(19) 0.4086(10) 0.041(4) Uani 1 1 d . . .
H1A H 0.0734 0.3960 0.3676 0.049 Uiso 1 1 calc R . .
C2 C 0.0298(8) 0.553(2) 0.4068(12) 0.051(5) Uani 1 1 d . . .
H2A H -0.0157 0.5477 0.3632 0.061 Uiso 1 1 calc R . .
C3 C 0.0432(8) 0.6492(19) 0.4684(13) 0.044(4) Uani 1 1 d . . .
H3A H 0.0069 0.7107 0.4680 0.053 Uiso 1 1 calc R . .
C4 C 0.1098(8) 0.6569(15) 0.5315(10) 0.032(3) Uani 1 1 d . . .
C5 C 0.1233(9) 0.7467(17) 0.6083(12) 0.040(4) Uani 1 1 d . . .
H5A H 0.0803 0.8009 0.6023 0.048 Uiso 1 1 calc R . .
H5B H 0.1335 0.6948 0.6624 0.048 Uiso 1 1 calc R . .
C6 C 0.2293(8) 0.8629(13) 0.6932(9) 0.027(3) Uani 1 1 d . . .
C7 C 0.2216(10) 0.8288(16) 0.7729(10) 0.039(4) Uani 1 1 d . . .
H7A H 0.1813 0.7796 0.7753 0.046 Uiso 1 1 calc R . .
C8 C 0.2734(14) 0.8674(17) 0.8485(11) 0.052(5) Uani 1 1 d . . .
H8A H 0.2681 0.8446 0.9030 0.063 Uiso 1 1 calc R . .
C9 C 0.3318(12) 0.937(2) 0.8469(11) 0.052(5) Uani 1 1 d . . .
H9A H 0.3678 0.9600 0.8996 0.062 Uiso 1 1 calc R . .
C10 C 0.3384(10) 0.9744(16) 0.7681(11) 0.041(4) Uani 1 1 d . . .
H10A H 0.3786 1.0251 0.7668 0.050 Uiso 1 1 calc R . .
C11 C 0.2870(8) 0.9388(14) 0.6902(9) 0.029(3) Uani 1 1 d . . .
C12 C 0.2907(8) 0.9858(13) 0.6043(10) 0.029(3) Uani 1 1 d . . .
H12A H 0.3290 1.0526 0.6148 0.035 Uiso 1 1 calc R . .
H12B H 0.2447 1.0287 0.5726 0.035 Uiso 1 1 calc R . .
C13 C 0.4054(8) 0.8435(15) 0.5731(11) 0.034(3) Uani 1 1 d . . .
H13A H 0.4209 0.8019 0.5268 0.041 Uiso 1 1 calc R . .
H13B H 0.4259 0.9327 0.5823 0.041 Uiso 1 1 calc R . .
C14 C 0.4361(7) 0.7672(14) 0.6554(10) 0.030(3) Uani 1 1 d . . .
H14A H 0.4891 0.7678 0.6716 0.036 Uiso 1 1 calc R . .
H14B H 0.4227 0.8103 0.7028 0.036 Uiso 1 1 calc R . .
C15 C 0.4464(7) 0.5550(15) 0.7258(9) 0.029(3) Uani 1 1 d . B .
H15A H 0.4972 0.5827 0.7491 0.035 Uiso 1 1 calc R . .
H15B H 0.4458 0.4616 0.7095 0.035 Uiso 1 1 calc R . .
C16 C 0.4121(7) 0.5688(16) 0.7970(9) 0.030(3) Uani 1 1 d . . .
H16A H 0.4153 0.6613 0.8158 0.036 Uiso 1 1 calc R B .
H16B H 0.4395 0.5157 0.8477 0.036 Uiso 1 1 calc R . .
C17 C 0.3261(7) 0.3445(14) 0.7412(9) 0.028(3) Uani 1 1 d . . .
H17A H 0.3525 0.3337 0.6987 0.033 Uiso 1 1 calc R B .
H17B H 0.3533 0.2987 0.7955 0.033 Uiso 1 1 calc R . .
C18 C 0.2526(7) 0.2860(13) 0.7054(8) 0.025(2) Uani 1 1 d . B .
C19 C 0.2222(8) 0.2215(14) 0.7608(9) 0.030(3) Uani 1 1 d . . .
H19A H 0.2464 0.2198 0.8217 0.036 Uiso 1 1 calc R B .
C20 C 0.1561(9) 0.1596(16) 0.7264(10) 0.037(3) Uani 1 1 d . B .
H20A H 0.1352 0.1149 0.7639 0.044 Uiso 1 1 calc R . .
C21 C 0.1209(8) 0.1629(16) 0.6380(11) 0.035(3) Uani 1 1 d . . .
H21A H 0.0759 0.1201 0.6151 0.042 Uiso 1 1 calc R B .
C22 C 0.1504(7) 0.2280(14) 0.5821(9) 0.029(3) Uani 1 1 d . B .
H22A H 0.1261 0.2296 0.5213 0.035 Uiso 1 1 calc R . .
C23 C 0.2158(7) 0.2905(12) 0.6162(8) 0.023(2) Uani 1 1 d . . .
C24 C 0.2104(8) 0.3851(14) 0.4786(8) 0.027(3) Uani 1 1 d . . .
H24A H 0.1903 0.3030 0.4482 0.032 Uiso 1 1 calc R B .
H24B H 0.2429 0.4229 0.4490 0.032 Uiso 1 1 calc R . .
C25 C 0.1503(7) 0.4792(14) 0.4720(8) 0.027(3) Uani 1 1 d . B .
P2 P 0.42993(17) 0.2621(3) 0.5189(2) 0.0248(7) Uiso 1 1 d D . .
F7 F 0.4376(5) 0.3124(9) 0.4301(5) 0.045(2) Uiso 1 1 d D A .
F8 F 0.4229(5) 0.2115(9) 0.6077(5) 0.042(2) Uiso 1 1 d D A .
F9 F 0.474(3) 0.129(3) 0.527(4) 0.036(11) Uiso 0.26(7) 1 d PDU A 1
F10 F 0.388(3) 0.392(3) 0.531(3) 0.028(11) Uiso 0.26(7) 1 d PDU A 1
F11 F 0.3538(15) 0.193(5) 0.474(3) 0.025(11) Uiso 0.26(7) 1 d PDU A 1
F12 F 0.5018(18) 0.332(4) 0.579(2) 0.029(10) Uiso 0.26(7) 1 d PDU A 1
F9' F 0.4584(10) 0.1221(8) 0.5003(12) 0.036(4) Uiso 0.74(7) 1 d PDU A 2
F10' F 0.4013(11) 0.4023(10) 0.5344(10) 0.036(5) Uiso 0.74(7) 1 d PDU A 2
F11' F 0.3494(5) 0.219(2) 0.4681(9) 0.042(5) Uiso 0.74(7) 1 d PDU A 2
F12' F 0.5112(6) 0.304(2) 0.5656(9) 0.042(4) Uiso 0.74(7) 1 d PDU A 2
P1 P 0.0981(5) 0.5049(10) 0.8542(6) 0.119(3) Uiso 1 1 d D . .
F1 F 0.1686(10) 0.457(4) 0.9184(18) 0.087(11) Uiso 0.44(4) 1 d PDU B 1
F2 F 0.0544(15) 0.461(3) 0.9214(17) 0.084(11) Uiso 0.44(4) 1 d PDU B 1
F3 F 0.0180(10) 0.546(4) 0.7932(19) 0.099(13) Uiso 0.44(4) 1 d PDU B 1
F4 F 0.1306(11) 0.554(3) 0.7876(14) 0.052(7) Uiso 0.44(4) 1 d PDU B 1
F5 F 0.082(2) 0.366(2) 0.812(2) 0.26(3) Uiso 0.44(4) 1 d PDU B 1
F6 F 0.106(3) 0.642(2) 0.899(2) 0.21(2) Uiso 0.44(4) 1 d PDU B 1
F1' F 0.1694(5) 0.4253(15) 0.9034(9) 0.027(4) Uiso 0.56(4) 1 d PDU B 2
F2' F 0.0744(15) 0.514(3) 0.9397(12) 0.114(12) Uiso 0.56(4) 1 d PDU B 2
F3' F 0.0277(10) 0.585(3) 0.8029(16) 0.155(19) Uiso 0.56(4) 1 d PDU B 2
F4' F 0.1204(14) 0.499(3) 0.7675(11) 0.111(12) Uiso 0.56(4) 1 d PDU B 2
F5' F 0.0529(12) 0.3728(18) 0.829(2) 0.133(15) Uiso 0.56(4) 1 d PDU B 2
F6' F 0.1417(14) 0.6387(15) 0.880(2) 0.122(13) Uiso 0.56(4) 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 161.9(4) . .
N1 Ag1 S2 110.9(3) . .
N2 Ag1 S2 78.8(3) . .
N1 Ag1 S1 104.1(3) . .
N2 Ag1 S1 76.1(3) . .
S2 Ag1 S1 135.48(11) . .
S2 Ag2 F1 133.3(9) . .
S2 Ag2 F1' 125.1(4) . .
F1 Ag2 F1' 9.6(10) . .
S2 Ag2 S1 140.33(12) . 4_576
F1 Ag2 S1 86.2(9) . 4_576
F1' Ag2 S1 94.5(4) . 4_576
C25 N1 C4 118.4(12) . .
C25 N1 Ag1 118.3(9) . .
C4 N1 Ag1 122.3(9) . .
C14 N2 C15 111.9(11) . .
C14 N2 Ag1 111.2(8) . .
C15 N2 Ag1 112.8(8) . .
C6 O1 C5 118.3(12) . .
C23 O2 C24 117.5(10) . .
C13 S1 C12 103.3(7) . .
C13 S1 Ag2 106.3(5) . 4_575
C12 S1 Ag2 102.9(5) . 4_575
C13 S1 Ag1 96.2(5) . .
C12 S1 Ag1 105.8(5) . .
Ag2 S1 Ag1 138.07(14) 4_575 .
C16 S2 C17 101.6(7) . .
C16 S2 Ag2 108.2(5) . .
C17 S2 Ag2 107.8(5) . .
C16 S2 Ag1 96.7(5) . .
C17 S2 Ag1 102.2(4) . .
Ag2 S2 Ag1 135.57(14) . .
C2 C1 C25 119.1(16) . .
C1 C2 C3 119.3(14) . .
C2 C3 C4 120.0(16) . .
N1 C4 C3 121.4(15) . .
N1 C4 C5 116.8(13) . .
C3 C4 C5 121.7(15) . .
O1 C5 C4 109.0(12) . .
O1 C6 C11 113.8(12) . .
O1 C6 C7 126.1(14) . .
C11 C6 C7 120.1(14) . .
C8 C7 C6 119.1(17) . .
C9 C8 C7 121.6(16) . .
C8 C9 C10 119.4(17) . .
C9 C10 C11 120.9(18) . .
C6 C11 C10 118.8(15) . .
C6 C11 C12 119.5(13) . .
C10 C11 C12 121.6(14) . .
C11 C12 S1 114.4(10) . .
C14 C13 S1 115.3(10) . .
N2 C14 C13 112.6(12) . .
N2 C15 C16 113.9(11) . .
C15 C16 S2 113.4(9) . .
C18 C17 S2 109.7(9) . .
C19 C18 C23 119.7(13) . .
C19 C18 C17 119.7(12) . .
C23 C18 C17 120.5(12) . .
C18 C19 C20 119.5(13) . .
C21 C20 C19 120.1(13) . .
C20 C21 C22 120.8(15) . .
C23 C22 C21 119.1(13) . .
O2 C23 C22 124.2(12) . .
O2 C23 C18 115.1(11) . .
C22 C23 C18 120.6(12) . .
O2 C24 C25 112.1(10) . .
N1 C25 C1 121.6(14) . .
N1 C25 C24 116.4(12) . .
C1 C25 C24 122.0(13) . .
F8 P2 F7 179.6(5) . .
F8 P2 F10' 90.8(6) . .
F7 P2 F10' 89.4(6) . .
F8 P2 F12' 91.1(6) . .
F7 P2 F12' 88.6(6) . .
F10' P2 F12' 92.0(8) . .
F8 P2 F11' 91.3(6) . .
F7 P2 F11' 89.1(6) . .
F10' P2 F11' 89.2(7) . .
F12' P2 F11' 177.4(9) . .
F8 P2 F9' 90.8(6) . .
F7 P2 F9' 88.9(6) . .
F10' P2 F9' 178.3(8) . .
F12' P2 F9' 88.4(7) . .
F11' P2 F9' 90.4(8) . .
F8 P2 F9 81.6(19) . .
F7 P2 F9 98.1(19) . .
F10' P2 F9 165(2) . .
F12' P2 F9 75.5(18) . .
F11' P2 F9 103.7(19) . .
F9' P2 F9 16(2) . .
F8 P2 F11 86.3(17) . .
F7 P2 F11 94.0(17) . .
F10' P2 F11 98.4(19) . .
F12' P2 F11 169.3(19) . .
F11' P2 F11 10.5(19) . .
F9' P2 F11 81.3(18) . .
F9 P2 F11 94(2) . .
F8 P2 F10 87.6(17) . .
F7 P2 F10 92.7(17) . .
F10' P2 F10 10(2) . .
F12' P2 F10 101.5(19) . .
F11' P2 F10 80(2) . .
F9' P2 F10 170(2) . .
F9 P2 F10 169(3) . .
F11 P2 F10 89(2) . .
F8 P2 F12 84.6(15) . .
F7 P2 F12 95.2(16) . .
F10' P2 F12 77.7(18) . .
F12' P2 F12 15.8(17) . .
F11' P2 F12 166(2) . .
F9' P2 F12 102.9(17) . .
F9 P2 F12 89(2) . .
F11 P2 F12 170(2) . .
F10 P2 F12 87(2) . .
F4 P1 F1 95.6(10) . .
F4 P1 F5 94.0(11) . .
F1 P1 F5 91.4(11) . .
F4 P1 F6 91.7(10) . .
F1 P1 F6 92.3(11) . .
F5 P1 F6 172.9(13) . .
F4 P1 F4' 23.8(13) . .
F1 P1 F4' 98.4(15) . .
F5 P1 F4' 70.3(15) . .
F6 P1 F4' 115.1(15) . .
F4 P1 F1' 91.4(12) . .
F1 P1 F1' 14.9(16) . .
F5 P1 F1' 77.4(18) . .
F6 P1 F1' 106.8(18) . .
F4' P1 F1' 88.8(8) . .
F4 P1 F2' 155.5(13) . .
F1 P1 F2' 82.9(15) . .
F5 P1 F2' 110.4(15) . .
F6 P1 F2' 64.0(14) . .
F4' P1 F2' 178.5(10) . .
F1' P1 F2' 92.6(8) . .
F4 P1 F6' 65.7(13) . .
F1 P1 F6' 78.3(17) . .
F5 P1 F6' 155.8(15) . .
F6 P1 F6' 31.3(15) . .
F4' P1 F6' 89.4(8) . .
F1' P1 F6' 89.6(8) . .
F2' P1 F6' 90.2(8) . .
F4 P1 F5' 115.1(13) . .
F1 P1 F5' 102.6(17) . .
F5 P1 F5' 25.5(15) . .
F6 P1 F5' 147.4(15) . .
F4' P1 F5' 91.5(8) . .
F1' P1 F5' 91.5(8) . .
F2' P1 F5' 88.9(8) . .
F6' P1 F5' 178.6(9) . .
F4 P1 F3' 87.1(14) . .
F1 P1 F3' 165.6(18) . .
F5 P1 F3' 102.5(19) . .
F6 P1 F3' 73.5(19) . .
F4' P1 F3' 89.7(8) . .
F1' P1 F3' 178.5(9) . .
F2' P1 F3' 88.9(8) . .
F6' P1 F3' 90.0(8) . .
F5' P1 F3' 89.0(8) . .
F4 P1 F3 91.5(10) . .
F1 P1 F3 172.9(13) . .
F5 P1 F3 86.9(10) . .
F6 P1 F3 88.7(10) . .
F4' P1 F3 87.5(15) . .
F1' P1 F3 164.2(17) . .
F2' P1 F3 91.2(15) . .
F6' P1 F3 105.8(18) . .
F5' P1 F3 73.2(18) . .
F3' P1 F3 15.9(19) . .
F4 P1 F2 173.5(11) . .
F1 P1 F2 90.7(10) . .
F5 P1 F2 87.7(10) . .
F6 P1 F2 86.2(10) . .
F4' P1 F2 156.2(14) . .
F1' P1 F2 95.1(13) . .
F2' P1 F2 24.0(14) . .
F6' P1 F2 114.0(14) . .
F5' P1 F2 65.0(14) . .
F3' P1 F2 86.4(15) . .
F3 P1 F2 82.3(9) . .
P1 F1 Ag2 114.6(13) . .
P1 F1' Ag2 111.0(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.296(11) .
Ag1 N2 2.410(12) .
Ag1 S2 2.645(3) .
Ag1 S1 2.787(3) .
Ag2 S2 2.432(3) .
Ag2 F1 2.45(3) .
Ag2 F1' 2.458(14) .
Ag2 S1 2.506(3) 4_576
N1 C25 1.338(18) .
N1 C4 1.356(19) .
N2 C14 1.463(18) .
N2 C15 1.471(18) .
O1 C6 1.377(17) .
O1 C5 1.436(18) .
O2 C23 1.375(15) .
O2 C24 1.434(16) .
S1 C13 1.810(15) .
S1 C12 1.834(14) .
S1 Ag2 2.506(3) 4_575
S2 C16 1.814(14) .
S2 C17 1.829(14) .
C1 C2 1.36(3) .
C1 C25 1.41(2) .
C2 C3 1.36(3) .
C3 C4 1.39(2) .
C4 C5 1.50(2) .
C6 C11 1.39(2) .
C6 C7 1.39(2) .
C7 C8 1.38(3) .
C8 C9 1.36(3) .
C9 C10 1.38(3) .
C10 C11 1.39(2) .
C11 C12 1.50(2) .
C13 C14 1.50(2) .
C15 C16 1.51(2) .
C17 C18 1.501(19) .
C18 C19 1.391(19) .
C18 C23 1.397(17) .
C19 C20 1.39(2) .
C20 C21 1.38(2) .
C21 C22 1.39(2) .
C22 C23 1.384(19) .
C24 C25 1.50(2) .
P2 F8 1.576(8) .
P2 F7 1.579(8) .
P2 F10' 1.590(7) .
P2 F12' 1.594(8) .
P2 F11' 1.596(8) .
P2 F9' 1.600(7) .
P2 F9 1.601(18) .
P2 F11 1.609(17) .
P2 F10 1.610(17) .
P2 F12 1.611(17) .
P1 F4 1.502(14) .
P1 F1 1.524(15) .
P1 F5 1.560(15) .
P1 F6 1.566(15) .
P1 F4' 1.598(2) .
P1 F1' 1.599(2) .
P1 F2' 1.599(2) .
P1 F6' 1.599(2) .
P1 F5' 1.599(2) .
P1 F3' 1.599(2) .
P1 F3 1.628(15) .
P1 F2 1.648(15) .
