#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:20:07 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229066 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/02/7230227.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7230227
loop_
_publ_author_name
'An, Yan-Yan'
'Lu, Li-Ping'
'Feng, Si-Si'
'Zhu, Miao-Li'
_publ_section_title
;
 Efficient pure white light emission based on a three-component
 La:Eu,Tb-doped luminescent lanthanide metal--organic framework
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2043
_journal_paper_doi               10.1039/C8CE00008E
_journal_volume                  20
_journal_year                    2018
_chemical_formula_moiety         '[Eu2(C16H9O7)2(C3H7ON)2(H2O)(CHOOH)]??3H2O'
_chemical_formula_sum            'C39 H41 Eu2 N2 O22'
_chemical_formula_weight         1193.66
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-02-11 deposited with the CCDC.
2018-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.059(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   28.4907(17)
_cell_length_b                   14.4061(9)
_cell_length_c                   13.6706(8)
_cell_measurement_reflns_used    9908
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.36
_cell_measurement_theta_min      2.82
_cell_volume                     5541.0(6)
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_unetI/netI     0.0287
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            26798
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.425
_diffrn_reflns_theta_min         2.822
_exptl_absorpt_coefficient_mu    2.312
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.431
_exptl_crystal_description       block
_exptl_crystal_F_000             2364
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.240
_refine_diff_density_max         1.435
_refine_diff_density_min         -0.932
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     317
_refine_ls_number_reflns         6939
_refine_ls_number_restraints     66
_refine_ls_restrained_S_all      1.116
_refine_ls_R_factor_all          0.0448
_refine_ls_R_factor_gt           0.0345
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0460P)²+33.8916P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0941
_refine_ls_wR_factor_ref         0.1014
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5818
_reflns_number_total             6939
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ce00008e2.cif
_cod_data_source_block           5R-Eu-RT
_cod_depositor_comments
'Adding full bibliography for 7230226--7230238.cif.'
_cod_database_code               7230227
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.596
_shelx_estimated_absorpt_t_max   0.607
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.18172(2) 0.28994(2) 0.45615(2) 0.02062(7) Uani 1 1 d . . . . .
O1 O 0.23458(10) 0.3487(2) 0.3495(2) 0.0354(7) Uani 1 1 d . . . . .
O2 O 0.30546(11) 0.2783(2) 0.3822(2) 0.0330(7) Uani 1 1 d . . . . .
O3 O 0.20543(10) 0.5734(2) 0.0627(3) 0.0380(7) Uani 1 1 d . . . . .
O4 O 0.26708(10) 0.66115(19) 0.0519(2) 0.0285(6) Uani 1 1 d . . . . .
O5 O 0.42241(12) 0.3551(3) 0.1471(3) 0.0571(11) Uani 1 1 d . U . . .
O6 O 0.61564(11) 0.3218(2) -0.0305(3) 0.0446(9) Uani 1 1 d . . . . .
O7 O 0.60610(11) 0.1776(2) 0.0141(3) 0.0431(8) Uani 1 1 d . . . . .
C1 C 0.29486(13) 0.3969(3) 0.2611(3) 0.0260(8) Uani 1 1 d . . . . .
C2 C 0.26425(13) 0.4590(3) 0.2051(3) 0.0273(8) Uani 1 1 d . . . . .
H2 H 0.232318 0.460761 0.212130 0.033 Uiso 1 1 calc R U . . .
C3 C 0.28135(14) 0.5184(3) 0.1387(3) 0.0263(8) Uani 1 1 d . . . . .
C4 C 0.32884(14) 0.5144(3) 0.1267(3) 0.0285(8) Uani 1 1 d . . . . .
H4 H 0.340214 0.554288 0.082327 0.034 Uiso 1 1 calc R U . . .
C5 C 0.35948(14) 0.4511(3) 0.1807(3) 0.0308(9) Uani 1 1 d . . . . .
C6 C 0.34240(14) 0.3932(3) 0.2490(3) 0.0289(8) Uani 1 1 d . . . . .
H6 H 0.362911 0.351947 0.286597 0.035 Uiso 1 1 calc R U . . .
C7 C 0.27684(14) 0.3359(3) 0.3374(3) 0.0274(8) Uani 1 1 d . . . . .
C8 C 0.24910(14) 0.5885(3) 0.0816(3) 0.0262(8) Uani 1 1 d . . . . .
C9 C 0.41084(15) 0.4480(3) 0.1653(4) 0.0376(10) Uani 1 1 d . . . . .
H9A H 0.415317 0.486744 0.109423 0.045 Uiso 1 1 calc R U . . .
H9B H 0.431261 0.471051 0.223744 0.045 Uiso 1 1 calc R U . . .
C10 C 0.46502(16) 0.3380(4) 0.1156(5) 0.0467(13) Uani 1 1 d . . . . .
C11 C 0.4754(2) 0.2464(4) 0.1039(6) 0.0686(19) Uani 1 1 d . U . . .
H11 H 0.454506 0.200966 0.119350 0.082 Uiso 1 1 calc R U . . .
C12 C 0.5167(2) 0.2204(4) 0.0691(6) 0.0631(18) Uani 1 1 d . U . . .
H12 H 0.523248 0.157872 0.060935 0.076 Uiso 1 1 calc R U . . .
C13 C 0.54855(15) 0.2882(3) 0.0463(4) 0.0378(10) Uani 1 1 d . . . . .
C14 C 0.53806(15) 0.3796(3) 0.0610(4) 0.0393(11) Uani 1 1 d . . . . .
H14 H 0.559023 0.425346 0.046817 0.047 Uiso 1 1 calc R U . . .
C15 C 0.49669(16) 0.4056(3) 0.0967(4) 0.0423(11) Uani 1 1 d . . . . .
H15 H 0.490528 0.467879 0.107543 0.051 Uiso 1 1 calc R U . . .
C16 C 0.59277(14) 0.2610(3) 0.0075(4) 0.0334(9) Uani 1 1 d . . . . .
O8 O 0.14347(15) 0.4204(3) 0.3636(4) 0.0671(13) Uani 0.5 1 d . . P A 1
C17 C 0.1550(4) 0.4958(6) 0.3529(7) 0.092(3) Uani 0.5 1 d . U P A 1
H17 H 0.181164 0.515230 0.397737 0.111 Uiso 0.5 1 calc R U P A 1
N1 N 0.1371(4) 0.5600(6) 0.2869(7) 0.135(3) Uani 0.5 1 d . U P A 1
C18 C 0.1524(7) 0.6471(8) 0.2777(10) 0.084(5) Uani 0.5 1 d . U P A 1
H18A H 0.130573 0.689842 0.300134 0.127 Uiso 0.5 1 calc R U P A 1
H18B H 0.154480 0.659310 0.209520 0.127 Uiso 0.5 1 calc R U P A 1
H18C H 0.183247 0.654361 0.317031 0.127 Uiso 0.5 1 calc R U P A 1
C19 C 0.0997(9) 0.5358(18) 0.2155(18) 0.155(10) Uani 0.5 1 d . U P A 1
H19A H 0.091100 0.587730 0.172417 0.232 Uiso 0.5 1 calc R U P A 1
H19B H 0.073050 0.518169 0.246476 0.232 Uiso 0.5 1 calc R U P A 1
H19C H 0.108809 0.484553 0.177717 0.232 Uiso 0.5 1 calc R U P A 1
O9 O 0.15351(17) 0.2290(3) 0.2882(3) 0.0628(12) Uani 0.5 1 d . . P A 1
C20 C 0.1613(4) 0.2577(10) 0.2100(7) 0.055(3) Uani 0.5 1 d . U P A 1
H20 H 0.170709 0.319397 0.208446 0.066 Uiso 0.5 1 calc R U P A 1
N2 N 0.1580(5) 0.2115(10) 0.1260(7) 0.071(3) Uani 0.5 1 d . U P A 1
C21 C 0.1432(9) 0.1244(14) 0.1196(11) 0.113(6) Uani 0.5 1 d . U P A 1
H21A H 0.156422 0.091567 0.178605 0.169 Uiso 0.5 1 calc R U P A 1
H21B H 0.153300 0.095471 0.063159 0.169 Uiso 0.5 1 calc R U P A 1
H21C H 0.109138 0.123020 0.112280 0.169 Uiso 0.5 1 calc R U P A 1
C22 C 0.1632(10) 0.265(2) 0.0310(14) 0.142(8) Uani 0.5 1 d . U P A 1
H22A H 0.137923 0.248394 -0.020879 0.212 Uiso 0.5 1 calc R U P A 1
H22B H 0.193211 0.250620 0.011297 0.212 Uiso 0.5 1 calc R U P A 1
H22C H 0.161742 0.330867 0.043450 0.212 Uiso 0.5 1 calc R U P A 1
O8A O 0.14347(15) 0.4204(3) 0.3636(4) 0.0671(13) Uani 0.5 1 d . . P A 2
C17A C 0.1550(4) 0.4958(6) 0.3529(7) 0.092(3) Uani 0.5 1 d . . P A 2
H17A H 0.181164 0.515230 0.397737 0.111 Uiso 0.5 1 calc R U P A 2
O10 O 0.1371(4) 0.5600(6) 0.2869(7) 0.135(3) Uani 0.5 1 d . . P A 2
O9A O 0.15351(17) 0.2290(3) 0.2882(3) 0.0628(12) Uani 0.5 1 d . . P A 2
O11 O 0.000000 0.2682(19) 0.250000 0.333(10) Uiso 1 2 d S . P . .
O12 O 0.0534(6) 0.5023(11) 0.4654(11) 0.270(7) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Eu1 O2 73.50(10) 4_545 7_556
O4 Eu1 O1 78.43(10) 4_545 .
O2 Eu1 O1 133.16(10) 7_556 .
O4 Eu1 O8 144.12(13) 4_545 .
O2 Eu1 O8 142.23(13) 7_556 .
O1 Eu1 O8 71.60(12) . .
O4 Eu1 O8A 144.12(13) 4_545 .
O2 Eu1 O8A 142.23(13) 7_556 .
O1 Eu1 O8A 71.60(12) . .
O4 Eu1 O7 137.80(11) 4_545 8_456
O2 Eu1 O7 78.13(12) 7_556 8_456
O1 Eu1 O7 142.44(11) . 8_456
O8 Eu1 O7 71.10(13) . 8_456
O4 Eu1 O9 77.98(14) 4_545 .
O2 Eu1 O9 133.78(14) 7_556 .
O1 Eu1 O9 72.87(13) . .
O8 Eu1 O9 74.74(17) . .
O7 Eu1 O9 101.18(15) 8_456 .
O4 Eu1 O9A 77.98(14) 4_545 .
O2 Eu1 O9A 133.78(14) 7_556 .
O1 Eu1 O9A 72.87(13) . .
O8A Eu1 O9A 74.74(17) . .
O7 Eu1 O9A 101.18(15) 8_456 .
O4 Eu1 O3 122.36(10) 4_545 6_566
O2 Eu1 O3 78.21(12) 7_556 6_566
O1 Eu1 O3 86.44(11) . 6_566
O8 Eu1 O3 75.52(16) . 6_566
O7 Eu1 O3 80.28(11) 8_456 6_566
O9 Eu1 O3 147.87(14) . 6_566
O4 Eu1 O6 88.61(11) 4_545 8_456
O2 Eu1 O6 71.09(12) 7_556 8_456
O1 Eu1 O6 144.97(12) . 8_456
O8 Eu1 O6 104.75(15) . 8_456
O7 Eu1 O6 52.46(11) 8_456 8_456
O9 Eu1 O6 72.64(14) . 8_456
O3 Eu1 O6 127.27(11) 6_566 8_456
O4 Eu1 O4 73.12(10) 4_545 6_566
O2 Eu1 O4 70.18(10) 7_556 6_566
O1 Eu1 O4 66.13(10) . 6_566
O8 Eu1 O4 110.55(14) . 6_566
O7 Eu1 O4 124.75(11) 8_456 6_566
O9 Eu1 O4 133.41(13) . 6_566
O3 Eu1 O4 50.14(9) 6_566 6_566
O6 Eu1 O4 140.46(12) 8_456 6_566
O4 Eu1 C16 112.93(12) 4_545 8_456
O2 Eu1 C16 71.15(12) 7_556 8_456
O1 Eu1 C16 155.60(12) . 8_456
O8 Eu1 C16 89.09(14) . 8_456
O8A Eu1 C16 89.09(14) . 8_456
O7 Eu1 C16 26.33(12) 8_456 8_456
O9 Eu1 C16 88.02(15) . 8_456
O9A Eu1 C16 88.02(15) . 8_456
O3 Eu1 C16 103.41(12) 6_566 8_456
O6 Eu1 C16 26.22(12) 8_456 8_456
O4 Eu1 C16 136.82(11) 6_566 8_456
C7 O1 Eu1 137.2(3) . .
C7 O2 Eu1 135.7(3) . 7_556
C8 O3 Eu1 98.8(2) . 6_565
C8 O4 Eu1 161.4(3) . 4
C8 O4 Eu1 89.5(2) . 6_565
Eu1 O4 Eu1 106.88(10) 4 6_565
C10 O5 C9 118.0(4) . .
C16 O6 Eu1 91.6(3) . 8
C16 O7 Eu1 93.8(3) . 8
C6 C1 C2 119.7(3) . .
C6 C1 C7 120.2(3) . .
C2 C1 C7 120.1(3) . .
C3 C2 C1 120.1(3) . .
C3 C2 H2 120.0 . .
C1 C2 H2 120.0 . .
C4 C3 C2 119.9(4) . .
C4 C3 C8 119.7(3) . .
C2 C3 C8 120.4(3) . .
C3 C4 C5 120.4(4) . .
C3 C4 H4 119.8 . .
C5 C4 H4 119.8 . .
C4 C5 C6 119.4(3) . .
C4 C5 C9 119.0(4) . .
C6 C5 C9 121.6(4) . .
C1 C6 C5 120.4(4) . .
C1 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
O2 C7 O1 126.6(4) . .
O2 C7 C1 117.1(3) . .
O1 C7 C1 116.3(3) . .
O3 C8 O4 121.3(4) . .
O3 C8 C3 120.0(3) . .
O4 C8 C3 118.7(4) . .
O3 C8 Eu1 56.4(2) . 6_565
O4 C8 Eu1 65.1(2) . 6_565
C3 C8 Eu1 174.0(3) . 6_565
O5 C9 C5 108.1(4) . .
O5 C9 H9A 110.1 . .
C5 C9 H9A 110.1 . .
O5 C9 H9B 110.1 . .
C5 C9 H9B 110.1 . .
H9A C9 H9B 108.4 . .
C11 C10 O5 115.4(4) . .
C11 C10 C15 120.0(4) . .
O5 C10 C15 124.6(5) . .
C10 C11 C12 120.7(5) . .
C10 C11 H11 119.7 . .
C12 C11 H11 119.7 . .
C11 C12 C13 120.1(5) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C14 C13 C12 118.2(4) . .
C14 C13 C16 121.2(4) . .
C12 C13 C16 120.6(4) . .
C13 C14 C15 121.6(4) . .
C13 C14 H14 119.2 . .
C15 C14 H14 119.2 . .
C10 C15 C14 119.2(4) . .
C10 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
O6 C16 O7 121.7(4) . .
O6 C16 C13 119.2(4) . .
O7 C16 C13 119.1(4) . .
O6 C16 Eu1 62.2(2) . 8
O7 C16 Eu1 59.9(2) . 8
C13 C16 Eu1 173.6(4) . 8
C17 O8 Eu1 133.1(6) . .
O8 C17 N1 130.7(11) . .
O8 C17 H17 114.6 . .
N1 C17 H17 114.6 . .
C17 N1 C18 128.0(13) . .
C17 N1 C19 118.4(13) . .
C18 N1 C19 113.6(14) . .
N1 C18 H18A 109.5 . .
N1 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N1 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N1 C19 H19A 109.5 . .
N1 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N1 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C20 O9 Eu1 128.9(6) . .
O9 C20 N2 127.2(12) . .
O9 C20 H20 116.4 . .
N2 C20 H20 116.4 . .
C20 N2 C21 121.0(12) . .
C20 N2 C22 118.5(15) . .
C21 N2 C22 119.6(14) . .
N2 C21 H21A 109.5 . .
N2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N2 C22 H22A 109.5 . .
N2 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N2 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C17A O8A Eu1 133.1(6) . .
O8A C17A O10 130.7(11) . .
O8A C17A H17A 114.6 . .
O10 C17A H17A 114.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O4 2.373(3) 4_545
Eu1 O2 2.394(3) 7_556
Eu1 O1 2.408(3) .
Eu1 O8 2.426(4) .
Eu1 O8A 2.426(4) .
Eu1 O7 2.455(3) 8_456
Eu1 O9 2.472(4) .
Eu1 O9A 2.472(4) .
Eu1 O3 2.479(3) 6_566
Eu1 O6 2.505(3) 8_456
Eu1 O4 2.668(3) 6_566
Eu1 C16 2.831(4) 8_456
O1 C7 1.255(5) .
O2 C7 1.254(5) .
O3 C8 1.249(5) .
O4 C8 1.260(5) .
O5 C10 1.372(5) .
O5 C9 1.410(6) .
O6 C16 1.251(6) .
O7 C16 1.259(6) .
C1 C6 1.391(5) .
C1 C2 1.392(5) .
C1 C7 1.513(5) .
C2 C3 1.391(5) .
C2 H2 0.9300 .
C3 C4 1.389(5) .
C3 C8 1.499(5) .
C4 C5 1.392(6) .
C4 H4 0.9300 .
C5 C6 1.395(5) .
C5 C9 1.512(5) .
C6 H6 0.9300 .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.367(8) .
C10 C15 1.380(7) .
C11 C12 1.389(7) .
C11 H11 0.9300 .
C12 C13 1.401(7) .
C12 H12 0.9300 .
C13 C14 1.373(6) .
C13 C16 1.494(6) .
C14 C15 1.396(6) .
C14 H14 0.9300 .
C15 H15 0.9300 .
O8 C17 1.150(9) .
C17 N1 1.337(11) .
C17 H17 0.9300 .
N1 C18 1.340(15) .
N1 C19 1.37(2) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
O9 C20 1.198(10) .
C20 N2 1.317(15) .
C20 H20 0.9300 .
N2 C21 1.32(2) .
N2 C22 1.54(2) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
O8A C17A 1.150(9) .
C17A O10 1.337(11) .
C17A H17A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -1.3(6) . .
C7 C1 C2 C3 176.7(4) . .
C1 C2 C3 C4 1.4(6) . .
C1 C2 C3 C8 -177.1(4) . .
C2 C3 C4 C5 0.1(7) . .
C8 C3 C4 C5 178.6(4) . .
C3 C4 C5 C6 -1.7(7) . .
C3 C4 C5 C9 179.5(4) . .
C2 C1 C6 C5 -0.3(7) . .
C7 C1 C6 C5 -178.3(4) . .
C4 C5 C6 C1 1.8(7) . .
C9 C5 C6 C1 -179.5(4) . .
Eu1 O2 C7 O1 -31.2(7) 7_556 .
Eu1 O2 C7 C1 148.4(3) 7_556 .
Eu1 O1 C7 O2 3.2(8) . .
Eu1 O1 C7 C1 -176.4(3) . .
C6 C1 C7 O2 -5.3(6) . .
C2 C1 C7 O2 176.7(4) . .
C6 C1 C7 O1 174.3(4) . .
C2 C1 C7 O1 -3.6(6) . .
Eu1 O3 C8 O4 4.1(4) 6_565 .
Eu1 O3 C8 C3 -174.5(3) 6_565 .
Eu1 O4 C8 O3 149.0(6) 4 .
Eu1 O4 C8 O3 -3.8(4) 6_565 .
Eu1 O4 C8 C3 -32.4(10) 4 .
Eu1 O4 C8 C3 174.9(3) 6_565 .
Eu1 O4 C8 Eu1 152.7(8) 4 6_565
C4 C3 C8 O3 154.2(4) . .
C2 C3 C8 O3 -27.3(6) . .
C4 C3 C8 O4 -24.4(6) . .
C2 C3 C8 O4 154.1(4) . .
C10 O5 C9 C5 170.0(5) . .
C4 C5 C9 O5 -129.0(5) . .
C6 C5 C9 O5 52.3(6) . .
C9 O5 C10 C11 176.9(6) . .
C9 O5 C10 C15 -2.7(9) . .
O5 C10 C11 C12 177.7(7) . .
C15 C10 C11 C12 -2.6(11) . .
C10 C11 C12 C13 0.5(12) . .
C11 C12 C13 C14 1.1(11) . .
C11 C12 C13 C16 -179.1(6) . .
C12 C13 C14 C15 -0.6(9) . .
C16 C13 C14 C15 179.6(5) . .
C11 C10 C15 C14 3.0(9) . .
O5 C10 C15 C14 -177.3(5) . .
C13 C14 C15 C10 -1.4(9) . .
Eu1 O6 C16 O7 -6.9(5) 8 .
Eu1 O6 C16 C13 172.9(4) 8 .
Eu1 O7 C16 O6 7.1(5) 8 .
Eu1 O7 C16 C13 -172.7(4) 8 .
C14 C13 C16 O6 -14.3(8) . .
C12 C13 C16 O6 166.0(6) . .
C14 C13 C16 O7 165.5(5) . .
C12 C13 C16 O7 -14.2(8) . .
Eu1 O8 C17 N1 165.3(7) . .
O8 C17 N1 C18 -179.5(11) . .
O8 C17 N1 C19 -3(2) . .
Eu1 O9 C20 N2 158.7(10) . .
O9 C20 N2 C21 3(3) . .
O9 C20 N2 C22 172.0(16) . .
Eu1 O8A C17A O10 165.3(7) . .
